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1100 International Pkwy. Suite 100 Sunrise FL 33323 800-998-3200

GraphLine Inc.
MATERIAL SAFETY DATA SHEET
Call CHEMTREC 1-800-424-9300 (24 Hour)

IN CASE OF TRANSPORTATION EMERGENCY (Spill, Leak, Fire, Exposure, Accident)

SECTION 1: IDENTIFICATION
Name: Silver Violet Developer Product Number 6018127200 Size 5 Gallons Formula: Aqueous Mixture Revision 12/17/2008

SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS


C.A.S. # 123-31-9 1310-73-2 7732-18-5 7757-83-7 INGREDIENTS HYDROQUINONE SODIUM HYDROXIDE Water Sodium Sulfite
OSHA TWA 2 mg/m3 2 mg/m3 None None STEL None None None None TWA 2 mg/m3 None None None ACGIH STEL None None None None TWA 2 mg/m3 None None None

% 1- 5 1-5 0 70- 80 10- 15


CANADA STEL 4 mg/m3 None None None

EXPOSURE LIMITS HYDROQUINONE SODIUM HYDROXIDE Water Sodium Sulfite

Source of Exposure Limit Data: OSHA: Occupational Safety and Health Administration ACGIH: American Conference of Governmental Industrial Hygienists CANADA: Province of Alberta's Occupational and Health and Safety Act.

ADDITIONAL EXPOSURE INFORMATION


SKIN DESIGNATION * CAS. NUMBER 123-31-9 1310-73-2 7732-18-5 7757-83-7 OSHA No No No No ACGIH No No No No CANADA No No No No IARC No No No No CARCINOGENS NTP No No No No OSHA No No No No PRIMARY HAZARD Not classified Sensory irritation Not classified Not classified IDLH (ppm) Unknown 250 mg/m3 None None

* For substances designated as a 'Skin' hazard, protective measures are recommended to prevent or reduce skin absorbtion. These measures may include the use of gloves, aprons, goggles or other equipment , as well as engineering controls or work practices.

SECTION 3: HAZARDS IDENTIFICATION


EYES CONTACT: Vapor may cause irritation. Contact may cause burns. SKIN CONTACT: Repeated and prolonged contact may cause irritation. INHALATION: Low hazard for ordinary industrial handling. INGESTION:
ABBREVIATIONS: N/D= Not Determined - N/A= Not Applicable - N/E=Not Established

GraphLine

Product Number: 6018127200

REVISION:

12/17/2008

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DO NOT take internally. May be harmful if swallowed. H.M.I.S. CODES: HEALTH: 3 FIRE: 0 REACTIVITY: 0 PROTECTION: B

SECTION 4: FIRST AID MEASURES


EYE CONTACT: Flush with large amounts of water for 15 minutes. If irritation occurs, seek medical attention. SKIN CONTACT: Wash skin with soap and water. If irritation occurs, seek medical attention. INHALATION: Move to fresh air. INGESTION: Drink water to dilute concentration. Induce vomiting only as directed by medical personnel. Seek medical attention immediately giving full details of amount ingested and toxicity.

SECTION 5: FIRE FIGHTING MEASURES


Flash point (F) : None Extinguishing media: Special fire fighting procedures : Use protective clothing to prevent contact with skin and eyes. FLAMMABILITY LELUse appropiate agent for surrounding fire. UEL-

Unusual fire and explosion hazards : When heated to decomposition, it can emit fumes of SO2 and CO2 NATIONAL FIRE PROTECTION ASSOC. CODES HEALTH: 2 FIRE: 1 REACTIVITY: 0 SPECIAL: NA

SECTION 6: ACCIDENTAL RELEASE MEASURES


SPILL RESPONSE: Wear protective clothing as specified in Section VII. Neutralize with sodium bicarbonate. If federal,state and local laws permit, flush to sewer with large amounts of water. Otherwise, dispose of contaminated product and materials used in cleaning up the spill in a manner approved for this material. Consult proper federal, state and/or local regulatory agencies to ascertain proper disposal procedures.

SECTION 7: HANDLING AND STORAGE


Do not consume food, drink or tobacco in surrounding area. Keep tightly sealed. Store above 40 degrees F. Avoid unnecessary personel contact. Avoid incompatible substances. Wash thoroughly after handling.

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION


Respiratory Protection (Specify Type ): Should not be necessay under normal conditions. If exposed to vapors that TLV or PEL, wear approved vapor respirator. Protective Equipment: Gloves: Impervious gloves. Eyes: Wear protective goggles. Other: Eyewash facilities in vicinity of use.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


Boiling point (F) : N/A Melting point: >212 Volatile Organic Compounds: N/A 17.0 Vapor pressure: 0.6 Vapor density: Complete Solubility in water: pH: 12.7 Odor: odorless

75 Percent volatile by volume : N/A Evaporation rate: Specific gravity (water = 1) : 1.24 Appearance : Pale yellow

ABBREVIATIONS: N/D= Not Determined - N/A= Not Applicable - N/E=Not Established

GraphLine

Product Number: 6018127200

REVISION:

12/17/2008

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SECTION 10: STABILITY AND REACTIVITY


Stability: Stable Incompatibility (materials to avoid): Hazardous decomposition products: Hazardous polymerization: Will not occur

Strong acids, strong bases. When heated to decomposition, it can emit toxic fumes of SO2 and CO2.

SECTION 11: DISPOSAL CONSIDERATIONS


Neutralize with sodium bicarbonate. I federal, state and/or local laws permit, flush to sewer with large amounts of water. Otherwise, dispose of contaminated product and materials used in cleaning up the spill in a manner approved for this material. Consult proper federal, state and/or local regulatory agencies to ascertain proper disposal procedures.

SECTION 12: TRANSPORTATION INFORMATION


SHIPPING NAME: SODIUM HYDROXIDE, SOLUTION UN ID-#: 1824 MAJOR CLASS: 8 MINOR CLASS: N/A REMARKS: PACKING GROUP: II PRIMARY LABEL: CORROSIVE SECONDARY LABEL: N/A

* Reference: CFR 49, Table 172.102 (highway)

SECTION 13: REGULATORY INFORMATION


CAS. NUMBER 123-31-9 1310-73-2 7732-18-5 7757-83-7 CERCLA Yes Yes No No SARA-EHS Yes No No No SARA-313 Yes No No No RCRA No No No No CAL-PROP 65 No No No No N.J. Yes No No No FLA. Yes Yes No No

* Specific CAS Number references from these regulatory tables: CERCLA: 40 CFR. Table 302.4 SARA-EHS: 40 CFR. 355 Appendices A B SARA-313: 40 CFR. section 372.65 RCRA: 40 CFR. section 261.3 CAL-PROP 65: California Proposition 65, Developmental and Reproductiv New Jersey Right to Know Florida Right to Know

SECTION 14: OTHER INFORMATION


Comments:

None

The data in this Material Safety Data form relates to the specific material designated herein and to the standard use of same in combination with other materials or processes. The hazards covered are beleived to be those most likely to occur in the reasonable, contemplated, or ordinary use of these chemicals. No warranty is made or implied in respect of other hazards which may occur as a result of unreasonable, abnormal, or unusual usage, or non-standard application of these materials. The information accumulated herein is beleived to be accurate, but GraphLine Inc. expressly denies any warranty to such effect. Customers or recipients are advised to confirm, in advance that the information is current, applicable and suitable to their circumstances. This information is furnished as a service only.

ABBREVIATIONS: N/D= Not Determined - N/A= Not Applicable - N/E=Not Established

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