BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 Cu 1: Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh

hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit nhm l A. 60%. B. 90%. C. 70%. D. 80%. Vit phng trnh phn ng nhit nhm : 8Al + 3Fe3O4 4Al2O3 + 9Fe B : 0,4 0,15 Phn ng: 8x 3x 9x Sau phn ng : Al 1,5H2 0,4-8x 0,6-1,2x Fe H2 9x 9x 9x + 0,6 1,2x = 0,48 x = 0,04 H =80% Cu 2: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 6. B. 5. C. 7. D. 4. Cu 3: t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l A. 11,20. B. 14,56. C. 4,48. D. 15,68. n = 2,5 => c 2 nhm OH nancol = 0,2 mol noxi = (0,716+0,532-0,232)/32 = 0,65 Voxi = 14,56 Cu 4: Hai hp cht hu c X v Y c cng cng thc phn t l C3 H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. axit 2-aminopropionic v axit 3-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. amoni acrylat v axit 2-aminopropionic. Vi cu ny c th dng phng php loi tr nh sau : - X phi l mui ca baz yu hn NaOH (amin hoc NH3) - Y l amino axit Chn p n D Cu 5: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 112,2. B. 171,0. C. 165,6. D. 123,8. Alanin : H2NCH(CH3)COOH : x mol Axit glutamic : HOOC-(CH2)2CH(NH2)COOH : y mol Bi ny c th lp h phng trnh nh sau : ( x+y = 1 v x+2y = 1,4) x = 0,6 v y = 0,4 m = 0,6*89 +0,4*147 =112,2 gam Cu 6: Cho s chuyn ho sau: xt H2 ,t o Z C2H2 X Y o Cao su buna -N o t Pd , PbCO3 t , xt , p Cc cht X, Y, Z ln lt l: A. benzen; xiclohexan; amoniac. B. axetanehit; ancol etylic; buta-1,3-ien. C. vinylaxetilen; buta-1,3-ien; stiren. D. vinylaxetilen; buta-1,3-ien; acrilonitrin. C2H2 imeha to ra Vinyl axetilen Cu 7: Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 1

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 A. C3H6. B. C2H4. C. CH4. D. C2H2. Cu ny rt d : nH2O = nCO2 hirocacbon l anken s nguyn t cacbon trung bnh = 2 C2H4 v nY < nX Cu 8: Cc cht u khng b thu phn trong dung dch H2SO4 long nng l: A. t capron; nilon-6,6; polietilen. B. poli(vinyl axetat); polietilen; cao su buna. C. nilon-6,6; poli(etylen-terephtalat); polistiren. D. polietilen; cao su buna; polistiren. Cu 9: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 45. B. 60. C. 120. D. 30. Cng thc ca X l : H2N(CnH2n)2CONHCOOH Cng thc ca Y l : H2N(CnH2n)3(CONH)2COOH(3n+3)CO2 + (3n+2,5)H2O (3n+3)44+(3n+2,5)18=549 n=2 t chy 0,2 mol X 1,2 mol CO2 m kt ta 120 gam. Cu 10: Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca x l A. 1,0. B. 0,9. C. 1,2. D. 0,8. Cu ny ch cn p dng cng thc : S mol Al3+ = (s mol kt ta +s mol KOH)/4 = 0,12 x = 1,2 Cu 11: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l A. 4. B. 5. C. 8. D. 9. Cu ny i hi k nng vit ng phn v xc nh cht cn vit l este v axit cacboxilic * Este c 5 cng thc nh sau : - CH3COOC3H7 (2 cng thc) - C2H5COOC2H5 (1 cng thc) - C3H7COOCH3 (2 cng thc) * axit c 4 cng thc p n : 9 cng thc Cu 12: Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn ng oxi ho - kh l A. 5. B. 4. C. 6. D. 3. Cu 13: t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht Xvo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7 gam kt ta.Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 23,2. B. 12,6. C. 18,0. D. 24,0. FeS2 2SO2 SO2 + OH- HSO3- ( v cho NaOH vo Y thy xut hin kt ta) SO2 + 2OH- SO32- + H2O nOH = 0,4 mol nkt ta = 0,1 mol nSO2 = 0,3 nFeS2 = 0,15 m = 18 gam Cu ny phi bit vn dng phng php gii bi ton (CO2,SO2) + dung dch baz Cu 14: Cc dung dch phn ng c vi Cu(OH)2 nhit thng l: A. lng trng trng, fructoz, axeton. B. anehit axetic, saccaroz, axit axetic. C. fructoz, axit acrylic, ancol etylic. D. glixerol, axit axetic, glucoz. Cu 15: Cc cht m phn t khng phn cc l: A. NH3, Br2, C2H4. B. Cl2, CO2, C2H2. C. HBr, CO2, CH4. D. HCl, C2H2, Br2. Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 2

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 Cu ny tuy rt d nhng nu khng nm vng c kin thc lp 10 th b tay Cu 16: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 16,3%. B. 65,2%. C. 48,9%. D. 83,7%. Khi lng trung bnh = 46 c 1 ancol l CH3OH vy 3 ancol l : CH3OH (x mol) , CH3CHOHCH3(y mol) , CH3CH2CH2OH (z mol) C h : x + y + z = 0,2 ( v nO = nCuO = nancol) 4x + 2z = 0,45 ( v HCHO 4Ag v CH3CH2CHO 2Ag) 32x + 60y + 60z = 46*0,2=9,2 Gii h : z = 0,025 %m propan -1-ol = (0,025*60)*100/9,2 = 16,3% Cu 17: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l A. metyl propionat. B. metyl axetat. C. etyl axetat. D. vinyl axetat. p n C v D th qu quen thuc i vi chng ta . Vi p n B cn phi nh uwocj phng trnh : CH3OH + CO CH3COOH Cu 18: Pht biu no sau y khng ng? A. m chy magie c th c dp tt bng ct kh. B. Dung dch m c ca Na2SiO3 v K2SiO3 c gi l thy tinh lng. C. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho. (NH4NO2 N2 + H2O) D. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon. p n A khng chnh xc v c phng trnh phn ng (SiO2 + Mg MgO + Si) nn khng dng dp tt c m chy. Cu 19: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12. B. 0,16. C. 0,18. D. 0,14. Cu ny ch cn p dng cng thc nHNO3 = ne nhn + nNO = 0,18 mol Cu 20: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C2H3COOH v 43,90%. B. C3H5COOH v 54,88%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12%. - Axit tc dng c vi AgNO3/NH3 l HCOOH : HCOOH 2Ag mHCOOH = 4,6 gam mX = 3,6 gam %mY = 43,9% Cu 21: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,45. B. 0,60. C. 0,36. D. 0,54. Cng thc 2,4,6-trinitrophenol : C6H2(NO2)3OH 1,5H2 + 1,5N2 + 6(CO,CO2) Tng s mol : 0,54 mol Cu 22: Mt ion M3+c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l A. [Ar]3d 54s1. B. [Ar]3d64s2. C. [Ar]3d 34s2. D. [Ar]3d 64s1. Cu ny ch cn lp h : (2p + n = 82 v 2p n = 22) n = 30 v p = 26 s e = 26 Cu 23: Pht biu no sau y khng ng? A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht. B. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng. C. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh. D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng. Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 3

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 NH3 ha tan c kt ta ca cc kim loi Cu, Zn v Ag Cu 24: Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH Phn ng ny chng t C6H5-CHO A. ch th hin tnh oxi ho. B. khng th hin tnh kh v tnh oxi ho. C. va th hin tnh oxi ho, va th hin tnh kh. D. ch th hin tnh kh. lm c cu ny phi vit cc cht hu c trn di dng cng thc phn t sau xc inh s oxi ha theo nguyn tc ( O = -2 , H = +1) Cu 25: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch A. AgNO3. B. NaOH. C. NaHS. D. Pb(NO3)2. Cc p n A, B, D u phn ng c vi c HCl v H2S p n C : NaHS + HCl NaCl + H2S Cu 26: in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l A. 1,50. B. 3,25. C. 2,25. D. 1,25. Phng trnh in phn : CuSO4 + H2O Cu + 0,5O2 + H2SO4 64a + 16a = 8 a = 0,1 mol Fe + H2SO4 FeSO4 + H2 0,1 0,1 Fe + CuSO4 FeSO4 + Cu 0,15 0,15 Tng s mol CuSO4 = 0,25 mol x = 1,25 Cu 27: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca nhm v crom? A. Nhm c tnh kh mnh hn crom. B. Nhm v crom u bn trong khng kh v trong nc. C. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui. D. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. Cr + HCl CrCl2 + H2 Cu 28: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 3. B. 5. C. 4. D. 6. Cu 29: Cho cc cn bng sau: (I) 2HI (k) H2 (k) + I2 (k); (II) CaCO3 (r) CaO (r) + CO2 (k); (III) FeO (r) + CO (k) Fe (r) + CO2 (k); (IV) 2SO2 (k) + O2 (k) 2SO3 (k). Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l A. 3. B. 4. C. 1. D. 2. Da vo s phn t kh trc v sau phn ng ( trc > sau s tun theo nguyn tc trn) Cu 30: C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni. S trng hp xut hin n mn in ho l A. 2. B. 4. C. 3. D. 1. Nhng trng hp tc dng vi Ni to ra kim loi th s xut hin n mn in ha. Cu 31: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ho tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l A. FeO. B. CrO. C. Fe3O4. D. Cr2O3. Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 4

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 nM = 0,06 mol ( p dng bo ton e, M nhng 3 e v SO2 nhn 2 e) nCO = 0,08 mol nO = 0,08 mol nO/nM = 4/3 Fe3O4 Cu 32: Dy gm cc cht u tc dng vi H2 (xc tc Ni, t ), to ra sn phm c kh nng phn ng vi Na l: A. C2H3CHO, CH3COOC2 H3, C6H5COOH. B. C2H3CH2OH, CH3COCH3, C2H3COOH. C. CH3OC2 H5, CH3CHO, C2H3COOH. D. C2H3CH2OH, CH3CHO, CH3COOH. Nhng cht khng no v xeton hoc anehit Cu 33: Ho tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 26,23%. B. 13,11%. C. 39,34%. D. 65,57%. Cu ny tng i kh : FexOy c th l FeO hoc Fe3O4(FeO+Fe2O3) Trng hp l FeO Fe+2 -1e Fe+3 x Cu 2e Cu+2 y S+6 + 2e S+4 0,0225

Lp c h phng trnh : ( x + 2y = 0,045 v 200x + 160y = 6,6) y = 0.01 %mCu = 26,23%. - Vi trng hp Fe3O4 v Fe2O3 loi. Hoc c th dng phng php khc l lp h vi FexOy = amol , Cu = b mol sau lp h phng trnh 3 n tm x v y. Cu 34: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,010. B. 0,015. C. 0,020. D. 0,005. Lp h phng trnh s thy c ngay kt qu : x + y +z = 0,04 16x + 18y + 18z = 0,68 16x + 18y + 16z = 0,65 z = 0,015 Cu 36: Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat, cn li gm cc cht khng cha photpho. dinh dng ca loi phn ln ny l A. 39,76%. B. 42,25%. C. 45,75%. D. 48,52%. 234*100 = 336,11 69,62 dinh dng = MP2O5 = 42,35% Mphn M phn = Cu 37: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. C2H5OCO-COOCH3. B. CH3OCO-CH2-CH2-COOC2H5. C. CH3OCO-CH2-COOC2 H5. D. CH3OCO-COOC3H7. Cu ny rt d : Loi ngay p n D, m s C ca cc p n A, B, C s thu c kt qu l C Cu 38: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,2. B. 0,1. C. 0,3. D. 0,4. Cng thc chung ca amin no mch h : CnH2n+2+xNx 2n+2+x x Phng trnh : CnH2n+2+xNx + O2 nCO2 + H2O + N2 2 2 Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 5

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 2n+2+x x + = 5 => n= 1 v x = 2 ( CH6N2 l amin 2 chc) 2 2 CH6N2 + 2HCl CH8N2Cl2 => nHCl = 0,2 mol ( p n A) Cu 39: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C4 H8. B. C2H6 v C2H4. C. CH4 v C2H4. D. CH4 v C3H6. M = 22,5 => ankan l CH4 n+ 4,5x+22,5y-ny=0 Ta lp h : x+y=0,2 x+ny=0,3 x=0,15 => y=0,05 n=3 =>C3H6

Cu 40: Ha tan hon ton 2,45 gam hn hp X gm hai kim loi kim th vo 200 ml dung dch HCl 1,25M, thu c dung dch Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X A. Mg v Ca. B. Be v Mg. C. Mg v Sr. D. Be v Ca. Gi x l s mol hn hp M + 2HCl M Cl2 + H2 x 2x x Cc cht tan c nng bng nhau gm : 2 mui v HCl x 1 mui c s mol , S mol HCl d 025-2x 2 x =0.25-2x => x=0,1 => M = 24,5 => p n D 2 II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Pht biu no sau y ng? A. Khi un C2H5Br vi dung dch KOH ch thu c etilen. B. un ancol etylic 140o (xc tc H2SO4 c) thu c imetyl ete. C. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng. D. Dy cc cht: C2 H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi. KOH/C2H5OH p n A khng ng v : C2H5Br C2H4 to p n B khng ng v un ancol etylic 140o (xc tc H2SO4 c) thu c i etyl ete. p n C khng ng v Dung dch phenol khng lm chuyn mu phenolphtalein v c tnh axit. p n D ng v khi lng cng ln th nhit si cng tng. Cu 42: Dung dch X cha cc ion: Ca2+, Na+, HCO3- v Cl-, trong s mol ca ion Cl- l 0,1.Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m l A. 7,47. B. 9,21. C. 8,79. D. 9,26. OH- + HCO3- CO32- + H2O dung dch X tc dng vi NaOH d to 2 gam CaCO3 => nCa2+ = 0,02 mol dung dch X tc dng vi Ca(OH)2 d to ra 3 gam CaCO3 => nHCO3- = 0,03 mol =>nNa+ =0.03*1+0.05*1-0.02*2=0,04 * khi un nng : 2HCO3- CO32- + H2O + CO2 M = 0,04*40 + 0,08*23+ 0,1*35,5+0,03*60 = 8,79 gam Cu 43: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc tc Ni, to)? A. 2. B. 5. C. 4. D. 3. C cc cht sau : CH2=C(CH3)-CH2-CHOH-CH3, CH3-C(CH3)=CH-CHOH-CH3 CH2=C(CH3)-CH2-CO-CH3, CH3-C(CH3)=CH-CO-CH3 v CH3-C(CH3)-CH2-CO-CH3 Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 6

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 Cu 44: Cho mt s nhn nh v nguyn nhn gy nhim mi trng khng kh nh sau: (1) Do hot ng ca ni la. (2) Do kh thi cng nghip, kh thi sinh hot. (3) Do kh thi t cc phng tin giao thng. (4) Do kh sinh ra t qu trnh quang hp ca cy xanh. (5) Do nng cao ca cc ion kim loi: Pb2+, Hg2+, Mn2+, Cu 2+ trong cc ngun nc. Nhng nhn nh ng l: A. (2), (3), (5). B. (2), (3), (4). C. (1), (2), (3). D. (1), (2), (4). Nhn nh 4 sai v : kh sinh ra t qu trnh quang hp ca cy xanh l kh Oxi Nhn nh 5 sai v : nng cao ca cc ion kim loi: Pb 2+, Hg2+, Mn2+, Cu2+ trong cc ngun nc th khng lin quan g n khng kh. Cu 45: Cho cc cp cht vi t l s mol tng ng nh sau: (a) Fe3O4 v Cu (1:1); (b) Sn v Zn (2:1); (c) Zn v Cu (1:1); (d) Fe2(SO4)3 v Cu (1:1); (e) FeCl2 v Cu (2:1); (g) FeCl3 v Cu (1:1). S cp cht tan hon ton trong mt lng d dung dch HCl long nng l A. 5. B. 4. C. 2. D. 3. (a) tan hon ton v : Fe3O4 2FeCl3 2FeCl3 + Cu CuCl2 + 2FeCl2 (b) tan hon ton v Sn v Zn ng trc H trong dy hot ng ha hc. (d) tan hon ton v : 2Fe3+ + Cu 2Fe2+ + Cu2+ Cu 46: Hn hp bt X gm Cu, Zn. t chy hon ton m gam X trong oxi (d), thu c 40,3 gam hn hp gm CuO v ZnO. Mt khc, nu cho 0,25 mol X phn ng vi mt lng d dung dch KOH long nng, th thu c 3,36 lt kh H2 (ktc). Phn trm khi lng ca Cu trong X l A. 59,44%. B. 39,63%. C. 19,81%. D. 29,72%. Zn=xmol Gi Cu=ymol => 81x + 80y = 40,3 0,25 0,15 mol Zn v 0,1 mol Cu => x = 1,5y => x=0,3 v y=0,2 mol => %Cu = 39,63% Cu 47: Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l: A. (1), (3), (5), (6). B. (1), (4), (5), (6). C. (1), (2), (4), (5). D. (1), (2), (4), (6). Nhng cht c nhm OH gn trc tip vo vng benzen th thuc loi phenol Cu 48: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Ala-Val-Phe-Gly. B. Gly-Phe-Gly-Ala-Val. C. Val-Phe-Gly-Ala-Gly. D. Gly-Ala-Val-Val-Phe. Cu ny dng phng php suy lun Cu 49: Hn hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dung dch HCl (d), sau phn ng thu c dung dch cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hn hp kh thu c sau phn ng li t t qua dung dch Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l A. 76,755. B. 78,875. C. 147,750. D. 73,875. 80x+160y=44 Gi CuO=xmol Fe2O3=ymol => => x=0,15 v y = 0,2 mol 135x+325y=85,25 22 gam X c s mol O l : 0,075+0,1*3 = 0,375 = nCO2 = > m =mBaCO3= 73,875 gam Cu 50: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l A. CH3COOH v C2H5OH. B. CH3COOH v CH3 OH. C. HCOOH v C3H7OH. D. HCOOH v CH3OH. Mmui = 82 => Mui l CH3COONa loi p n C v D Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 7

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 - Nu ancol l C2H5OH => ta c h : x+y=0,2 v x +y = 0,175 => x=0,05 v y = 0,015 2

x - Nu ancol l CH3OH => ta c h x+y=0,2 v +y = 0,25156 v nghim (loi) 2 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l A. xenluloz. B. mantoz. C. glucoz. D. saccaroz. - Cacbohirat lm mt mu nc brom : Glucoz v fructoz (loi A v D) - Cacbohirat c lin kt glicozit l mantoz Cu 52: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2NH2. D. H2NCH2CH2CH2CH2NH2. - Nu amin bc 1 n chc : namin = nHCl = 0,24 mol => M = 37 => 12x + y = 23 (loi) - Nu amin bc 1 hai chc : namin = 2nHCl = 0,12 mol => M = 74 => x = 3 v y = 10 v N = 2 Cu 53: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 8,96. B. 4,48. C. 10,08. D. 6,72. Phng trnh phn ng nh sau : 3Cu + 8H+ + 2NO-3 3Cu2+ + 2NO + 4H2O 0,3 0,8 0,2 0,2 3Fe2+ + 4H+ + NO-3 3Fe3+ + NO + 2H2O 0,6 0,9 0,2 0,2 Tng s mol NO = 0,4 mol => V = 8,96 lt Cu 54: Cho s chuyn ho: Fe3O4 + dung dch HI (d) X + Y + H2O. Bit X v Y l sn phm cui cng ca qu trnh chuyn ho. Cc cht X v Y l A. FeI3 v FeI2. B. Fe v I2. C. FeI2 v I2. D. FeI3 v I2. Phng trnh phn ng nh sau : Fe3O4 +8 HI 3FeI2 + I2 + 4H2O Cu 55: Cho s phn ng: +CuO Br2 +H O Stiren +2 o X Y Z to H ,t H Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l: A. C6H5CH2CH2OH, C6H5CH2 CHO, m-BrC6H4CH2COOH. B. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3. C. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH. D. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br. Cu 56: Pht biu no sau y khng ng? A. Do Pb 2+/Pb ng trc 2H+/H2 trong dy in ho nn Pb d dng phn ng vi dung dch HCl long ngui, gii phng kh H2. B. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh chuyn thnh muiCr(VI). C. Ag khng phn ng vi dung dch H2SO4 long nhng phn ng vi dung dch H2SO4 c nng. D. CuO nung nng khi tc dng vi NH3 hoc CO, u thu c Cu. p n A sai : Do Pb 2+/Pb ng trc 2H+/H2 trong dy in ho nhng khng tc dng vi HCl do mui ch PbCl2 khng tan bao bc ngoi kim loi. Cu 57: Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng? A. Khi pha long dung dch trn th in li ca axit fomic tng. B. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4. C. in li ca axit fomic trong dung dch trn l 14,29%. D. in li ca axit fomic s gim khi thm dung dch HCl. Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng 8

BI GII THI TUYN SINH I HC NM 2010- MN HA HC KHI B M :937 Tuy pha long ln 10 ln nhng v HCOOH l mt axit yu (cht in li yu nn phn li khng hon ton) => pH khng th bng 4. Cu 58: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho mn s chuyn ho sau: o X H 2, Y CH (SO4dac) Este c mi chui chn ( Ni t ) 3COH H 2 Tn ca X l A. 2,2-imetylpropanal. B. 3-metylbutanal. C. pentanal. D. 2-metylbutanal. Este c mi chui chn l isoamyl axetat : CH3COOCH2CH2CH(CH3)2 Cu 59: nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t nc, c c ri thm dung dch Na2S vo thy xut hin kt ta mu vng. Hin tng trn chng t nc thi b nhim bi ion A. Cd 2+. B. Fe2+. C. Cu2+. D. Pb2+. Cc kt ta FeS, CuS v PbS c mu en. Cu 60: t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l A. 6,50 gam. B. 7,85 gam. C. 7,40 gam. D. 5,60 gam. nH2O = 0,65 mol , nCO2 = 0,4 mol => ba ancol l no n chc => mancol = mH2O - 4nCO2 =10,1 gam => nancol = 0,65 - 0,4 = 0,25 mol - Khi tch nc 2 mol ancol ->1 mol H2O => nH2O = 0,125 => mH2O = 2,25 gam => mete = mancol - mH2O = 7,85 gam

Li gii : Gv Phan Vn Tn THPT Trng Chinh Nhn C- kRLp - kNng