Tt c hc sinh hc gii Ha Hc u bit rng:Mnh phi hc gii l thuyt

BI TP HON THNH PTP , LUN CTCT V IU CH HIROCACBON Cu 1.Vit cc phng trnh phn ng biu din chui bin ha sau: CH3COONa
1 4

CH4
5

C C2H6

3 6

CH4 C2H5Cl

8 7

CH3Cl

C4H10

Cu 2.Hon thnh cc phng trnh phn ng sau: a.CH3-CH2-CH(CH3)-CH3 + Cl2 b.CH3-CH2-CH2-CH2-CH3 (Nung) c.CH3-CH2-CH2Cl + CH3-CHCl-CH3 + Na d.C2H5COONa + NaOHrn e.HO-CH2-CH2-COONa + NaOHrn f.COONa COONa + NaOHrn + H2 (Ni,T0) Sn phm chnh

g.Metyl xiclopropan

h. Etyl xiclopropan + dung dch Br2 i. Xiclopropan + Br2 khan (askt)

Cu 3.Trong cc ng phn ca C5H12, ng phn no khi th clo (askt) ch cho ra mt dn xut monoclo duy nht? ng phn no cho ra 4 dn xut monoclo? Cu 4.Cho cht A c cu to nh sau: CH3 a.Hi khi cho A tc dng vi dung dch Br2 th cho ra my sn phm? b.Khi cho A th Clo (askt xc tc) cho ra my dn xut monoclo?

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Tt c hc sinh hc gii Ha Hc u bit rng:Mnh phi hc gii l thuyt

Cu 5.T CH4, cc cht v c v cc iu kin cn thit, hy vit cc ptp iu ch mi cht sau: a.C2H6 b.CH3-CH2-CH3 c.isobutan d. xiclopropan e.xiclobutan f.CH3 - CH(CH3) - CH2 CH3 Cu 6.T C2H4 ,v cc cht v c, cc iu kin cn thit hy vit cc phn ng iu ch: a.P.E (Polietilen) b.C4H10 c.C4H8 d.P.P (Polipropilen) Cu 7.Vit phn ng trng hp cc cht sau: a. CH3 CH = CH CH3 b.CH2 = C(CH3) CH3 c. CH3 CH(CH3) CH = CH2 d. (CH3)2CH CH = CH CH3 Cu 8.Vit cc phn ng biu din chui bin ha: C2H5OH
4

a.C2H4
5

C2H5Cl

C2H4

C2H4Br2

C2H4(OH)2 b.C3H8
1

C3H6
3

(C3H6)n C3H7Cl

4 5

C3H6Br2 C3H6(OH)2
2

c. Isopentan

Isopren

Cao su isopren

Cu 9.Vit phn ng trng hp cc cht sau: a. CH3 CH2 C CH b. ( - CH = CH - )n Cu 10.Hon thnh cc phng trnh phn ng: a.CH2 = CH CH2-CH3 + H2 (Ni,T0) b.CH3 - CH = CH CH3 c.CH3 CH = C(CH3)2 + + Br2 HCl Sn phm chnh

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Tt c hc sinh hc gii Ha Hc u bit rng:Mnh phi hc gii l thuyt

d.CH3 CH2 CH = CH2 e.CH2 = CH CH3

H2O

Sn phm chnh

+ Cl2 (450-5000C) KMnO4 + H2O

f.CH2 = CH CH2 CH3 +

Cu 11.Anken no c cng thc phn t C4H8 khi tc dng vi dung dch Br2 cho ra hp cht : a.1,2-ibrom butan b.2,3-ibrom butan Cu 12.T CH4 v cc iu kin cn thit, hy vit phng trnh phn ng iu ch: a.PVC, Cao su buna, Cao su Isopren, Cao su buna-N b.Cao su Cloropren: ( - CH2 CH = CCl-CH2 - )n Cu 13. Hon thnh cc phng trnh phn ng sau: a.CH C CH3 + Br2 b. CH C CH3 + HCld c. CH C CH3 + d. CH C CH3 + HCl (T l 1:1)

dung dch AgNO3/NH3

e. CH C CH3 + H2O f. CH3 - C C CH3 + H2O Cu 14. Vit cc phn ng trong chui bin ha sau: C2H2Br4
6 12 4

CH3COOCH = CH213 PVA C2H3Cl

8 5

a.CaCO3

CaO

CaC2 C6H6

3 7

C2H2

PVC
9 11

C2Ag2

C2H2
10

C2H4

C2H6 Cu 15.T C2H2 v cc cht v c, cc iu kin cn thit, hy vit cc phng trnh phn ng iu ch :
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Tt c hc sinh hc gii Ha Hc u bit rng:Mnh phi hc gii l thuyt

a.PA d.Etyl benzen

b.Benzen e.Cao su buna-S

c.Stiren

Cu 16.Xc nh A,B,C,D ph hp cho cc phn ng sau: A + HCl B + HCl D B D PVC + C

Cu 17.B tc phn ng sau: a. B B F b.A C D +

KOH, T0

+ + +

KMnO4 H2 KMnO4 C Br2 H + F

G H2O D

c. A B + 2D E + nE

B + C H2O D E + F + H2O F A Cao su buna

Cu 18.Xc nh cc cht A,B,D,M,N,Q,X,Y ph hp vi chui bin ha sau:

10

Q A
5 2

CH4

B N

3 7

Cao su buna
8

C4H6Br2 (X,Y)

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Tt c hc sinh hc gii Ha Hc u bit rng:Mnh phi hc gii l thuyt

Cu 19. Vit cc phn ng biu din chui bin ha: C6H6Cl6 (Thuc tr su 6.6.6)
6

C2H2

C6H6
7

C6H5Br

toluen
8

C6H5COOK

C6H5COOH

TNB TNT Cu 20.Hon thnh cc phn ng sau: a.C6H5 C2H5 + Cl2 (askt, 1:1) b.C6H5OH c.C6H5NO2 d.C6H5OH + + + Br2 Br2 HNO3 (H2SO4 c nng) Br2 (xt) + KMnO4 (T0)

e. p-metyl toluen + f. Isopropyl benzen g. o-etyl toluen +

KMnO4 (T0)

Cu 21. T C2H2 vi cc cht v c v iu kin cn thit, hy vit cc phn ng iu ch: a.Thuc tr su 6.6.6 b.Etyl benzen c.Thuc n TNT d.Isopropyl benzen

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