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Table I: Thermal Transitions of Homopolymers: Glass Transition (Tg) & Melting Point (Tm) Temperatures
Repeating Unit Tg (C) Tm (C) Repeating Unit Tg (C) Tm (C)
Acenaphthylene Acetaldehyde 4-Acetoxystyrene Acrylamide Acrylic acid Acrylonitrile, syndiotactic Allyl glycidyl ether Benzyl acrylate Benzyl methacrylate Bisphenol A-alt-epichlorohydrin Bisphenol A terephthalate Bisphenol carbonate Bisphenol F carbonate Bisphenol Z carbonate 4-Bromostyrene cis-Butadiene trans-Butadiene 1-Butene N-tert-Butylacrylamide Butyl acrylate sec-Butyl acrylate tert-Butyl acrylate 2-tert-Butylaminoethyl methacrylate Butyl glydicyl ether Butyl methacrylate tert-Butyl methacrylate 4-tert-Butylstyrene tert-Butyl vinyl ether Butyl vinyl ether -Caprolactone Cellulose nitrate Cellulose tripropionate cis-Chlorobutadiene trans-Chlorobutadiene 2-Chlorostyrene 3-Chlorostyrene 4-Chlorostyrene Chlorotrifluoroethylene 2-Cyanoethyl acrylate Cyclohexyl acrylate Cyclohexyl methacrylate Cyclohexyl vinyl ether 2,6-Dichlorostyrene Diethylaminoethyl methacrylate
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214 -32 116 165 105 125 -78 6 54 100 205 174 147 175 118 102 -58 -24 128 -54 -26 43-107 33 -79 20 118 127 88 -55 -60 53 -20 -40 119 90 110 52 4 19 92 81 167 20
165
319
1 148 171
193
250 64
80 101
214
N,N-Dimethylacrylamide Dimethylaminoethyl methacrylate 2,6-Dimethyl-1,4-phenylene oxide Dimethylsiloxane 2,4-Dimethylstyrene 2,5-Dimethylstyrene 3,5-Dimethylstyrene Dodecyl acrylate Dodecyl methacrylate Dodecyl vinyl ether Epibromohydrin Epichlorohydrin 1,2-Epoxybutane 1,2-Epoxydecane 1,2-Epoxyoctane 2-Ethoxyethyl acrylate 4-Ethoxystyrene Ethyl acrylate Ethyl cellulose Ethylene, HDPE Ethylene adipate Ethylene-trans-1,4-cyclohexyldicarboxylate Ethylene isophthatate Ethylene malonate Ethylene 2,6-napthalenedicarboxylate Ethylene oxide Ethylene terephthalate 2-Ethylhexyl acrylate 2-Ethylhexyl methacrylate 2-Ethylhexyl vinyl ether Ethyl methacrylate Ethyl vinyl ether 4-Fluorostyrene Formaldehyde Hexadecyl acrylate Hexadecyl methacrylate Hexyl acrylate Hexyl methacrylate 2-Hydropropyl methacrylate Hydroquinone-alt-epichlorohydrin 2-Hydroxyethyl methacrylate Indene Isobornyl acrylate Isobornyl methacrylate
89 19 167 -127 112 143 104 -3 -65 -62 -14 -22 -70 -70 -67 -50 86 -24 43 -125 -46 18 51 -29 113 -66 72 -50 -10 -66 65 -43 95 -82 35 15 57 -5 76 60 57 85 94 110
-40
130 54
66 265
86 181
See catalog numbers Z41,247-3, Z41,255-4, Z22,171-6, Z40,603-1 and Z22,195-3 in the Book section.
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Isobutyl acrylate -24 Isobutylene -73 Isobutyl methacrylate 53 Isobutyl vinyl ether -19 cis-Isoprene -63 trans-Isoprene -66 N-Isopropylacrylamide 85-130 Isopropyl acrylate, isotactic -11 Isopropyl methacrylate 81 Methacrylic acid 228 Methacrylic anhydride 159 Methacrylonitrile 120 2-Methoxyethyl acrylate -50 4-Methoxystyrene 113 Methyl acrylate 10 Methyl cellulose Methyl glycidyl ether -62 Methyl methacrylate, atactic 105,120 Methyl methacrylate, syndiotactic 115 4-Methylpentene 29 Methylphenylsiloxane -86 Methylstyrene 20 3-Methylstyrene 97 4-Methylstyrene 97 Methyl vinyl ether -31 Nylon 4,6 (tetramethylene adipamide) 43 Nylon 6 (-caprolactam) 52 Nylon 6,6 (hexamethylene adipamide) 50 Nylon 6,9 (hexamethylene azelamide) 58 Nylon 6,10 (hexamethylene sebacamide) 50 Nylon 6,12 (hexamethylene dodecane46 diamide) Nylon 11 (undecanamide) 42 Nylon 12 (-dodecanamide) 41 1-Octadecene 55 Octadecyl methacrylate -100 1-Octene -63 Octyl methacrylate -20 Oxy-4,4'-biphenyleneoxy-1,4phenylenesulfonyl-1,4-phenylene 230 Oxy-1,4-phenylenesulfonyl-1,4-phenyleneoxy1,4-phenyleneisopropylidene-1,4-phenylene 165 Oxy-1,4-phenylenesulfonyl1,4-phenylene ether 214 p-Phenylene isophthalamide 225
165 28 65 162
200 250
189 179
p-Phenylene terephthalamide Phenylene vinylene Phenyl methacrylate Phenyl vinyl ketone Potassium acrylate Propylene, atactic Propylene, isotactic Propylene, syndiotactic Propylene oxide Propyl vinyl ether Sodium acrylate Sodium methacrylate Styrene, atactic Styrene, isotactic Tetrabromobisphenol A carbonate Tetrafluoroethylene Tetrahydrofuran Tetramethylene adipate Tetramethylene terephthalate Thio-1,4-phenylene 2,2,2-Trifluoroethyl acrylate Trimethylene oxide Trimethylsilyl methacrylate 2,4,6-Trimethylstyrene Vinyl acetal Vinyl acetate Vinyl alcohol Vinyl benzoate Vinyl 4-tert-butylbenzoate Vinyl butyral Vinyl carbazole Vinyl chloride Vinyl cyclohexanoate Vinylferrocene Vinyl fluoride Vinyl formal Vinylidene chloride Vinylidene fluoride 2-Vinyl naphthalene Vinyl pivalate Vinyl propionate 2-Vinylpyridine 4-Vinylpyridine 1-Vinyl-2-pyrrolidone Vinyl trifluoroacetate
345 80 110 74 194 -13 -8 -8 -75 -49 230 310 100 100 157 117 -84 -118 17 97 -10 -78 68 162 355 30 85 71 101 322 227 81 76 189 41 105 -18 -40 151 86 10 104 142 54 46
380
176 66 76
240 327
232 285
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