Quy trnh chun KMnO4 XC NH COD TRONG NC BIN 1. Thuc th: a. Dung dch (COOH)2 0.1 M: 0.

.9G (COOH)2/100ml nc b. KMnO4 0.1M: 0.136g KMnO4 + 1.6g NaOH/100ml n nh trong ti vi ngy, lc qua bng thy tinh, sau chun li bng (COOH)2, bo qun lnh c. Na2S2O3 0.1M: 1.581g Na2S2O3/100ml. Thm 0.1g Na2CO3 bo qun. n nh mt ngy trc khi chun d. H2SO4 2M e. KI 10%: 10g KI trong 90ml nc f. Dung dch h tinh bt 1%: un nng 1g h tinh bt/100ml nc n khi tan 2. Quy trnh chun : Bc 1: Cm l phn hy COD l t ti 100oC. Bc 2: Cho 5ml mu (blank cho 5ml nc ct) vo ng COD, thm 0.5 ml KMnO4 vo mi ng. Lau sch bn ngoi ng, vn cht np v cho vo l nung COD trong vng 1h. Ch : Mi mu nn lm lp 2 ln, v khong cch nung gia cc mu (k c blank) cch nhau khong 15 pht phn hy m bo sau thi gian lm ngui l mu c th em chun ngay lp tc. Bc 3: Ly cc ng ra khi l, ngui 10 pht. mu trong ng ra bnh tam gic, trng sch lng mu bn trong bng nc ct. Thm 0.5 ml KI 10%, sau thm 1ml H2SO4 2M. Bc 4: Chun hn hp thu c bng Na2S2O3 0.1M (s dng pipet 1ml, chun chm) n khi dung dch c mu vng nht th thm 5 git dung dch h tinh bt, thy dung dch chuyn sang mu xanh. Tip tc chun n khi mu xanh bin mt. Ghi li lng thuc th dng vi blank v vi mu. 3. Tnh kt qu:

Ct: nng cht chun (M)

Vab: th tch Na2S2O3 dng chun blank (ml) Vas : th tch Na2S2O3 dng chun mu (ml) Vs: th tch mu (ml)