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HU 7 - 2011
- My trc quang s dng bc sng 880 nm, cuvet c b dy 1 cm - Cc dng c thy tinh pha ch v bo qun thuc th... 4.2. Ha cht Dung dch H2SO4 5 N: pha long 70 ml H2SO4 c thnh 500 ml bng nc ct. Dung dch kali antimonyl tatrat: ha tan 1,3715 g K(SbO)C4H4O6.H2O vo 400 ml nc ct trong bnh nh mc 500 ml, sau nh mc thnh 500 ml. Bo qun trong bnh c nt thy tinh. Dung dch amoni molypdat: ha tan 20 g (NH4)6Mo7O24.4H2O trong 500 ml nc ct. Bo qun dung dch trong bnh thy tinh c nt. Dung dch axit ascorbic 0,01 M: ha tan 1,76 g axit ascorbic trong 100 ml nc ct. Dung dch bn trong 1 tun khi bo qun 4oC. Dung dch thuc th hn hp: trn cn thn theo th t sau: 50 ml dung dch H2SO4 5 N, 5 ml dung dch kali antimonyl tatrat, 15 ml dung dch amoni molypdat v 30 ml dung dch axit ascorbic. Lc u sau khi thm mi thuc th. Nu trong qu trnh trn hn hp, dung dch b c, th lc v yn vi pht n trong, sau mi thm tip dung dch thuc th mi vo. Thuc th hn hp bn trong 4 gi. Dung dch gc photphat: ha tan 219,5 mg KH2PO4 khan v nh mc n 1000 ml bng nc ct. 1,00 ml dung dch ny cha 50,0 g P-PO43- (nng : 50 mg P-PO43-/l). Dung dch photphat trung gian: pha long 10,0 ml dung dch photphat gc thnh 100 ml bng nc ct. 1,00 ml dung dch ny cha 5,0 g P- PO43 (nng : 5,0 mg P-PO43-/l). Dung dch photphat lm vic: pha long 5,0 ml dung dch photphat trung gian thnh 100 ml bng nc ct. 1,00 ml dung dch ny cha 0,25 g P- PO43- (nng : 0,25 mg P-PO43-/l). 5. Quy trnh phn tch Ly 10,0 ml mu vo ng nghim hay bnh tam gic, thm 1 git ch th phenolphtalein, nu dung dch c mu hng, th thm tng git H2SO4 5 N n lc mt mu. Thm 1,6 ml dung dch thuc th hn hp, lc cn thn. yn 10 pht (nhng khng qu 30 pht), ri em o mt quang 880 nm, vi dung dch mu trng lm dung dch so snh. Xy dng ng chun: Pha dy dung dch chun c nng t 0,01 0,25 mg P-PO43-/l theo bng sau: STT Th tch dd photphat lm vic (ml) Th tch dd thuc th hn hp (ml) Th tch nc ct (ml) Nng photphat (mg P-PO43-/l) 1 0,4 1,6 9,6 0,01 2 2,0 1,6 8,0 0,05 3 4,0 1,6 6,0 0,10 4 6,0 1,6 4,0 0,15 5 8,0 1,6 2,0 0,20 6 10,0 1,6 0 0,25
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Cch tin hnh xc nh photphat trong cc mu chun nh quy trnh trn Mu trng: tng t nh mu chun nhng thay dung dch lm vic bng nc ct Xy dng phng trnh ng chun A = f(CP-PO43-) Nng photphat trong mu c xc nh da vo phng trnh ng chun 6. Ti liu tham kho Clesceri L.S., Greenberg A.E., Eaton A.D. (1998), Standard methods for the examination of water and wastewater (4500-P E Ascorbic Acid Method), 20th Ed., APHA, USA.
P trong dung dch phn hy ( dng octo photphat) c xc nh bng phng php axit ascorbic (phng php 4500-P E). Xy dng ng chun vi nng photphat trong khong 0,05 1,0 mg P-PO43-/l). 5. Ti liu tham kho Clesceri L.S., Greenberg A.E., Eaton A.D. (1998), Standard methods for the examination of water and wastewater (4500-P B Sample Preparation), 20th Ed., APHA, USA.
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