TCVN

TIU CHUN VIT NAM

TCVN 5507 : 2002

Sot xt ln 2

Ho cht nguy him Qui phm an ton trong sn xut, kinh doanh, s dng, bo qun v vn chuyn
Hazardous chemicals Code of practice for safety in production, commerce, use, handling and transportation

H Ni - 2002

TCVN 5507 : 2002

Mc lc

Trang 1 Phm vi p dng ............................................................................................................... 5 2 Tiu chun trch dn .......................................................................................................... 5 3 Thut ng ......................................................................................................................... 6 4 Qui nh chung ................................................................................................................... 7 5 Yu cu an ton trong sn xut, kinh doanh v s dng ho cht nguy him ................... 10 6 Yu cu an ton trong bo qun ho cht nguy him ....................................................... 16 7 Yu cu an ton trong vn chuyn ho cht nguy him.................................................... 18 8 Yu cu an ton trong lao ng, v sinh lao ng v bo v mi trng .......................... 20 Ph lc A ............................................................................................................................. 21 Ph lc B ............................................................................................................................. 30 Ph lc C ............................................................................................................................ 31 Ph lc D ............................................................................................................................. 37 Ph lc E ............................................................................................................................ 39

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Li ni u
TCVN 5507 : 2002 thay th TCVN 5507 :1991. TCVN 5507 : 2002 do Tiu ban k thut tiu chun

TCVN/TC 47/SC3 An ton ho cht hon thin trn c s d tho ca Cng ty Ho cht, B Thng mi ngh, Tng Cc Tiu chun o lng Cht lng xt duyt, B Khoa hc v Cng ngh ban hnh.

TCVN 5507 : 2002

TCVN 5507 : 2002

Tiu chun vit nam

TCVN 5507 : 2002

Sot xt ln 2

Ho cht nguy him Qui phm an ton trong sn xut, kinh doanh, s dng, bo qun v vn chuyn
Hazardous chemicals Code of practice for safety in production, commerce, use, handling and transportation

1 Phm vi p dng
Tiu chun ny p dng cho cc c s c cc hot ng sn xut, kinh doanh, s dng, bo qun v vn chuyn ho cht nguy him, k c ho cht bo v thc vt dng trong nng nghip. Tiu chun ny khng p dng cho cht n v cht phng x

2 Tiu chun vin dn

TCVN 2290 - 78 Thit b sn xut. Yu cu chung v an ton. TCVN 2622 : 1995 Phng chy, chng chy cho nh v cng trnh Yu cu thit k. TCVN 3147 - 1990 Qui phm an ton trong cng tc xp d Yu cu chung. TCVN 3255 - 86 An ton n. Yu cu chung. TCVN 3288 - 79 H thng thng gi. Yu cu chung. TCVN 4512 - 88 Qui phm vn chuyn hng nguy him bng ng bin. TCVN 4604 - 88 X nghip cng nghip. Nh sn xut. Tiu chun thit k. TCVN 5939 : 1995 Cht lng khng kh Tiu chun kh thi cng nghip i vi bi v cc cht v c. TCVN 5940 : 1995 Cht lng khng kh Tiu chun kh thi cng nghip i vi bi v cc cht hu c. TCVN 5945 : 1995 Nc thi cng nghip Tiu chun thi. TCVN 6304 : 1997 Chai cha kh t ho lng Yu cu an ton trong bo qun, xp d, vn chuyn. TCVN 6406 : 1998 S dng bao b trong sn xut Yu cu chung v an ton. 5

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3 Thut ng
Tiu chun ny c s dng cc thut ng sau: 3.1 Ho cht nguy him (Hazardous chemicals) L nhng ho cht trong qu trnh sn xut, kinh doanh, s dng, bo qun, vn chuyn v thi b c th gy ra chy, n, n mn, kh phn hu trong mi trng gy nhim c cho con ngi, ng thc vt v nhim mi trng. 3.1.1 Ho cht d chy, n (Explosive flammable chemicals) L nhng ho cht c th/hoc t phn gii gy chy, n hoc cng cc cht khc to thnh hn hp chy, n trong iu kin nht nh v thnh phn, nhit , m, p sut. Ch thch Trong tiu chun ny cc cht d chy, n c phn nhm theo nhit bng chy v theo
gii hn n trong ph lc B v C.

3.1.2 Ho cht n mn (Corrosive chemicals) L nhng ho cht c tc dng ph hu dn cc dng vt cht nh: kt cu xy dng v my mc, thit b, ng ng hu hoi da v gy bng i vi ngi v sc vt. 3.1.3 Ho cht c (Toxic chemicals) L nhng ho cht gy c hi, nh hng xu trc tip hoc gin tip n ngi v sinh vt. Ho cht c c th xm nhp vo c th qua da, qua ng tiu ho, qua ng h hp, gy nhim/ng c cp tnh hoc mn tnh, gy nhim c cc b hoc ton thn; c th l nhng ho cht c kh nng gy ung th, d tt... 3.2 S c ho cht (Event of chemical hazards) S vic bt thng xy ra lin quan ti ho cht gy chy, n, c hi, n mn hoc nhim mi trng. 3.3 Cht thi nguy hi (hazardous waste) L cht thi c cha cc n cht hoc hp cht c mt trong cc c tnh gy nguy hi trc tip (d chy, n, gy ng c, d n mn, d gy nhim mi trng v cc c tnh nguy hi khc) hoc tng tc vi cc cht khc gy nguy hi ti mi trng, ng thc vt v sc kho con ngi.

TCVN 5507 : 2002 4 Qui nh chung

4.1 Yu cu chung 4.1.1 C s sn xut, kinh doanh, s dng, bo qun v vn chuyn ho cht nguy him (sau

y c gi tt l: c s c ho cht nguy him) phi tun theo cc qui nh trong tiu chun ny cng vi cc qui nh php l hin hnh khc c lin quan. Danh mc cc ho cht nguy him thng dng theo ph lc A. 4.1.2 C s c ho cht nguy him phi bit r c cc tnh cht nguy him, phng php

phng nga v x l s c nguy hi xy ra ca tng loi ho cht; c trch nhim cung cp nhng thng tin nguy him v ho cht cho c quan qun l an ton lao ng c thm quyn, nhng i tng s dng trc tip v nhng i tng c lin quan trong hot ng ho cht . 4.1.3 Ti mi phn xng, kho tng c hot ng lin quan n ho cht nguy him phi c bng hng dn c th v qui trnh thao tc an ton v t v tr d c. 4.1.4 Nhng ngi lm vic tip xc vi ho cht nguy him phi c o to v c cp th

an ton lao ng theo qui nh hin hnh ca php lut. nh k, c s c ho cht nguy him phi m lp b tc kin thc, nghip v v an ton lao ng, v sinh lao ng v x l s c ho cht cho cn b cng nhn vin ca mnh. 4.1.5 C s c ho cht nguy him phi trang b y phng tin bo v c nhn ph hp vi

tnh cht cng vic, mc c hi ca tng loi ho cht. Phi hng dn cho cng nhn cch s dng v bo qun cc phng tin ny. Cm s dng cc phng tin bo v c nhn b h hng. 4.1.6 C s c ho cht nguy him phi trang b y phng tin v cht cha chy ph hp

vi tnh cht ca ho cht nguy him. Phi hun luyn, hng dn cho cng nhn bit cch s dng thnh tho v bo qun cc trang thit b, dng c . 4.1.7 C s c ho cht nguy him phi c trch nhim thc hin cc qui nh php lut v bo

v mi trng, m bo an ton v sinh mi trng. 4.1.8 Tt c cc trng hp tai nn lao ng, s c xy ra do ho cht nguy him u phi c x l kp thi, khai bo, iu tra, lp bin bn v bo co vi c quan c thm quyn theo ng qui nh. 4.1.9 Trng hp xy ra s c ho cht, (chy, n, v...) ngi chu trch nhim v hng ho

hoc lnh o c s ni xy ra tai nn, phi bo ngay cho c quan c thm quyn theo qui nh hin hnh.

TCVN 5507 : 2002

Phi t chc canh gc v cm bin khoanh vng v cch ly hin trng (khu vc c ho cht bn ra, v, chy...) phi tin hnh v hon thnh mt cch trit vic x l hin trng. 4.1.10 Ch nhng ngi hiu r tnh cht nguy him ca ho cht, bit phng php x l v c phng tin bo v c nhn mi c x l s c. 4.1.11 Nhng c s c ho cht nguy him, khi xy ra s c ho cht c kh nng gy tc hi nghim trng n cng ng v mi trng, phi lp v trin khai thc hin k hoch x l v ng cu khn cp. 4.2 Yu cu v nh kho, nh xng 4.2.1 Nh xng, kho tng ca cc c s c ho cht nguy him, khi thit k xy dng mi hoc

ci to li phi theo cc qui nh trong TCVN 2622 : 1995 ; TCVN 4604 :1988 v phi m bo khong cch an ton vi khu dn c theo cc qui nh hin hnh. Nu t cc c s ny gn sng, phi t sau dng chy ca khu dn c v cui ngun nc. Khng c b tr nh xng, kho tng u hng gi thuc hng gi u th so vi c s. Nu b tr cc c s ny trong hang hm th phi c cc bin php m bo yu cu v an ton lao ng v v sinh lao ng. H thng thng gi nh xng, kho tng phi theo cc qui nh TCVN 3288 : 1979. 4.2.2 Nh xng, kho ho cht nguy him phi kh ro khng thm, dt, phi c h thng thu li

chng st, phi nh k kim tra h thng ny theo cc qui nh hin hnh. 4.2.3 Kho ho cht nguy him phi c kim tra nh k hng nm v an ton v bin php m bo an ton trc ma ma, bo. 4.2.4 Ho cht nguy him nht thit phi trong kho. Kho cha ho cht nguy him phi qui

hoch khu vc sp xp theo tnh cht ca tng loi ho cht. Khng c xp trong cng mt kho cc ho cht c kh nng phn ng vi nhau, hoc c phng php cha chy khc nhau. 4.2.5 Bn ngoi kho, xng phi c bin "cm la", "cm ht thuc", ch to, mu ; bin

ghi k hiu cht cha chy. Cc bin ny phi r rng v ch d thy nht. 4.2.6 Khi xp ho cht trong kho phi m bo yu cu an ton cho ngi lao ng v hng ho

nh sau: i vi hng ng bao phi xp trn bc hoc trn gi , cch tng t nht 0,5 m, ho cht k m phi xp trn bc cao ti thiu 0,3 m;

TCVN 5507 : 2002

ho cht dng lng cha trong phuy, can... v ho cht dng kh cha trong cc bnh chu p lc phi c xp ng qui nh; cc l hng khng c xp st trn kho v khng cao qu 2 m; li i chnh trong kho rng ti thiu 1,5 m; khng c xp cc l hng nng qu ti trng ca nn kho; khng c cc bao b dng, cc vt liu d chy trong kho; thng xuyn kim tra cc l hng, thng gi, thot m, lp ho cht cui cng khng b hng. 4.3 Yu cu v thit b 4.3.1 Thit b sn xut, bo qun, vn chuyn, s dng ho cht nguy him phi theo cc qui

nh trong TCVN 2290 : 1978. 4.3.2 Khi thay th, b sung cc chi tit nh: thit b n l, ng ng, cc van, kho hm s

dng vi ho cht nguy him phi m bo bn c hc, ho hc, chu la, chu nhit, kn theo ng ch tiu k thut qui nh. 4.3.3 Thit b vn chuyn (bng ti, bng nng) phi c h thng pht tn hiu cnh bo trc

khi khi ng. 4.3.4 B mt nng ca thit b v ng dn c th gy bng cho ngi lm vic, phi c che

chn cch ly. 4.3.5 Trong khi vn hnh, s dng cc thit b lm vic c p lc cn thc hin ng nhng yu

cu trong h thng tiu chun Vit Nam v cc thit b chu p lc. 4.3.6 H thng o lng, kim sot cng ngh ca cc thit b trong cc qu trnh sn xut ho cht nguy him phi c kim tra nh k, hiu chun sai s m bo cho thit b vn hnh n nh. 4.4 Yu cu v bao b 4.4.1 Vt liu, chng loi, kt cu v kim tra bao b phi theo cc qui nh trong TCVN 6406 : 1998. 4.4.2 Vt cha, bao b phi m bo kn v chc chn. Bao b khi dng ht phi bo qun ring.

Trng hp s dng li bao b th phi lm sch, bo m khng gy nh hng n ho cht mi hoc gy nguy him. Vt liu k, y phi c nh du phn bit tng loi ho cht, khng c dng ln ln.

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4.4.3 Vt cha, bao b cha ng ho cht nguy him phi c nhn hng ho ghi y cc ni dung theo qui nh ca Qui ch ghi nhn hng ho. Cc biu trng an ton theo qui nh trong ph lc E. 4.4.4 Nhn ca ho cht phi m bo r, d c v khng b rch. Trng hp nhn b mt,

khng phn bit c l cht g, phi phn tch, xc nh r tn v thnh phn chnh ca ho cht v b sung nhn mi trc khi a ra lu thng hoc a vo s dng. 4.5 Yu cu v qun l 4.5.1 C s c ho cht nguy him thuc danh mc cc mt hng hn ch kinh doanh, kinh

doanh c iu kin, ngoi vic p dng tiu chun ny cn phi thc hin theo cc qui nh hin hnh ca php lut. 4.5.2 C s c ho cht nguy him phi c qui ch qun l cht ch trong xut, nhp. Ch c

ngi c trnh chuyn mn ph hp c giao trch nhim qun l ho cht nguy him mi c php giao, nhn. Phi c s theo di xut, nhp, tn kho hng ngy, khi thy thiu, tha, sai qui cch phi bo ngay vi cp trn. 4.5.3 Khi giao nhn ho cht nguy him, chng t phi ghi r ngy, thng, nm, h tn, c ch k ngi giao hng, nhn hng v xc nhn ca c s c hng. Ch c giao, nhn hng c bao b nguyn vn v y nhn hng ho vi y cc thng tin theo qui nh hin hnh. 4.5.4 Ho cht ht thi hn s dng hoc mt phm cht phi c x l, nu hu b phi tun

th nghim ngt cc quy nh hin hnh ca Nh nc.

5 Yu cu an ton trong sn xut, kinh doanh v s dng ho cht nguy him

5.1 Ho cht d chy, n 5.1.1 C s c ho cht nguy him, c bit l ho cht d chy, n u phi thc hin ng cc qui trnh k thut m bo hn hp kh, hi, bi ca cc ho cht ny vi khng kh lun ngoi vng gii hn chy n theo qui nh trong ph lc B, C v bo qun theo ph lc D. 5.1.2 C s c ho cht d chy, n phi ng k vi c quan c thm quyn a phng v

phi lp v thc hin k hoch phng chng chy, n, bo v mi trng theo qui nh. 5.1.3 Khi xy dng cc kho cha, cc c s sn xut, s dng ho cht d chy, n phi tun

theo cc qui nh v c ly an ton, cc cp bc chu la ca cng trnh v vic b tr giao thng i li ca ngi v phng tin phi theo cc qui nh trong TCVN 2622 : 1995.

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5.1.4 Ni sn xut, s dng ho cht d chy, n phi c li thot nn, phi c cc bung ph.

Nhng bung ph ny phi cch ly vi bung chnh bng cc cu kin ngn chn c gii hn chu la nh nht l 1,5 gi. 5.1.5 C s c ho cht d chy, n ngoi vic phi trang b y cc phng tin v cht

cha chy thch hp, phi trang b thm cc phng tin bo v c nhn chng c thch hp khi cha chy. 5.1.6 Trong khu vc sn xut, s dng v kho tng cha cc ho cht d chy, n phi qui nh

cht ch ch dng la. Khi cn thit sa cha c kh, hn in hay hn hi phi c quy trnh lm vic an ton phng chng chy, n, c xc nhn bo m ca cn b an ton lao ng. 5.1.7 H thng in nhng ni c ho cht d chy, n phi m bo cc yu cu sau: dng c in, thit b in u phi l loi an ton chy, n v c cp phng n tng ng vi mi trng hi, kh d chy n; khng c t dy cp in trong cng mt ng rnh ngm hoc ni c ng dn hi kh, cht lng d chy, n. Khng c dng cc ng ng ny lm vt ni t t nhin; cu dao, cu ch, cm in phi t ngoi khu vc cha cc ho cht d chy, n. Bt k nhnh dy in no cng u phi c cu ch hay thit b bo v tng ng; h thng in chiu sng phi l loi phng n, phi ngn nga s xm nhp ca hi kh, bi d chy, n vo thit b chiu sng; khi sa cha, thay th thit b in thuc nhnh no th phi ct in dn vo nhnh v treo bng cm ng in. Ch ngi chu trch nhim, c k thut v in mi c lm vic ny. 5.1.8 My mc, thit b lm vic trong khu vc ho cht d chy, n u phi an ton phng

chng chy, n. Khi thit k, ch to, vn hnh phi ph hp vi yu cu ca TCVN 3255 : 1986 Dng c lm vic trong khu vc ho cht d chy, n u phi lm bng vt liu khng pht sinh tia la do ma st hay va p. 5.1.9 Trc khi a vo ng ng hay thit b mt cht c kh nng gy chy, n, hoc trc v sau khi sa cha u phi thc hin nghim ngt cc qui trnh phng chng chy, n: th kn, th p (nu cn); thng ra bng mi cht thch hp hoc kh tr; xc nh hm lng xy, khng kh hoc cht chy, n cn li sao cho khng cn kh nng to hn hp chy, n.

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5.1.10 Thit b, bao b cha ho cht lng d chy, n u phi gi ng h s y quy nh tu

theo c tnh ho l ca cht lng . Thit b ln phi c van x mt chiu, van ngt la km bch an ton phng n. Bch an ton phng n lm bng vt liu khng chy, n. u ng dn ho cht d chy, n vo phi st mp hoc st y thit b. Thit b c p sut, phi c van an ton x qu p. Phi thng xuyn kim tra cc thit b ny. 5.1.11 Khng ho cht d chy, n cng ch vi cc cht duy tr s chy (nh xy hoc cc cht nh xy...). ng ng dn ho cht d chy, n khng i chung vi gi ng ng xy, khng kh nn. 5.1.12 Khng dng kh nn c xy nn y ho cht d chy, n t thit b ny sang thit b khc. Khi san rt ho cht d chy, n t bnh ny sang bnh khc, phi tip t bnh cha v bnh rt. 5.1.13 Cm thit b, ng ng cha ho cht d chy, n gn ngun pht nhit. i vi

trng hp c nh nng mt tri chiu trc tip, phi c bin php h nhit (sn phn x hoc ti nc...). 5.1.14 Khng c un nng ho ho cht lng d chy bng ngn la trc tip. Ch c m

np sau khi un xong v hn hp bn trong ngui. 5.1.15 Khi pha dung mi vo khi ho cht lng thit b h phi cch xa vng c la t nht

10 m. Ch c pha dung mi vo khi ho cht lng khi nhit khi ho cht lng thp hn nhit si ca dung mi. 5.1.16 Khng dng ngn la trc tip soi sng tm ch h ca ng ng dn, thit b cha

ho cht d chy, n m phi dng nc x phng hay cc cht khc khng c kh nng gy chy, n vi cc ho cht trong ng dn, thit b. 5.1.17 Trong qu trnh sn xut hoc s dng cc ho cht d chy, n, vic s dng cc cht

thm vo phi m bo cc yu cu sau: thc hin ng qui trnh cng ngh sn xut; bit r nh hng ca cht thm vo i vi tnh chu nhit, tnh d chy, n ca loi ho cht d chy, n ; cht thm vo khng c tp cht l (b nhim bn).

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5.1.18 hn thit b, ng dn trc y c cha ho cht d chy, n, phi m ht cc np

thit b, mt bch ng dn v lm thot ht kh d chy, n ra ngoi, thau ra sch m bo khng cn kh nng to thnh hn hp chy, n khi mi c tin hnh hn. 5.1.19 Khi sn x, nht l sn trong din tch kn phi m bo hn hp sn vi khng kh ngoi vng gii hn n v trnh hin tng tnh in gy ra chy, n. 5.1.20 Trong qu trnh sn xut, kinh doanh, s dng ho cht d chy, n phi m bo yu cu v sinh an ton lao ng. Phi c ng dn nc, h thng thot nc; trnh s ng ca cc loi ho cht d gy chy, n. 5.1.21 Trong khu vc c ho cht d chy, n u phi thng thong bng thng gi t nhin hoc cng bc. B tr thit b thng gi ph hp vi mt bng sn xut v t trng ca hi, kh d chy n trnh s tch t ca hi, kh d chy n . 5.1.22 Khi xy ra chy khu vc c my thng gi ang hot ng phi lp tc dng my thng

gi li chy khng lan rng ra nhng vng khc, ri p dng cc bin php cha chy ph hp. 5.1.23 Khi xy ra s c chy, n, mi ngi c mt u phi dng phng tin bo v c nhn

tham gia cu cha ngi b nn v cha chy. Nhng ngi khng c phng tin bo v c nhn m bo an ton khng c tham gia cha chy. Ngi gi in thoi bo cng an phng chy cha chy v y t cp cu, phi ch dn a ch r rng v trc n dn ng nhanh nht. 5.2 ho cht n mn 5.2.1 C s c ho cht n mn phi c bin php hn ch s n mn, bo v cng trnh xy

dng. Phi c h thng cng rnh thot cht thi n mn, h thng thu hi x l. 5.2.2 Thit b, ng ng cha cht n mn phi c lm bng vt liu thch hp, m bo kn.

Cc v tr van v ca m phi v tr an ton cho ngi thao tc v i li. Trng hp cha trong thit b chu p lc, phi nh k kim tra theo qui nh. 5.2.3 ng i pha trn thit b c ho cht n mn phi c ro chn vng chc, c tay vn.

Thnh thit b, b cha phi cao hn v tr ngi thao tc t nht 0,9 m, khng c xy bc hoc k bt c vt g lm gim chiu cao ni trn. 5.2.4 Khng c m, vc trc tip ho cht n mn gy nguy him cho ngi lm vic. Khi nng ln cao ng rt, di chuyn phi c thit b chuyn dng.

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5.2.5 Khi ty ra, sa cha thit b, ng dn ho cht n mn phi c phng n lm vic an

ton, c tin hnh di s ch dn ca nhng ngi am hiu v k thut, bit cch x l nhng s c c th xy ra trong khi thc hin. 5.2.6 Ti ni c ho cht n mn phi c t thuc cp cu, vi nc, thng cha ho cht trung

ho thch hp (v d dung dch natri bicacbonat (NaHCO3) nng 0,3 %, dung dch axit axetic ( CH3COOH ) nng 0,3 %) cp cu kp thi khi xy ra tai nn. 5.2.7 Phi thng xuyn kim tra, tu sa my mc, thit b, khng ho cht n mn lm mn

my, ng dn v m my. 5.2.8 Tt c cc cht thi n mn u phi c x l khng cn tc dng n mn trc khi thi. 5.3 Ho cht c 5.3.1 Tu theo nng , tnh cht v s lng ho cht c, c s sn xut, kinh doanh, s dng, bo qun ho cht c (sau y c gi tt l: c s c ho cht c) u phi thc hin vic ng kim theo qui nh php l hin hnh. 5.3.2 C s phi c ni qui xut nhp ho cht c nghim ngt, s xut nhp ghi chp y ,

m bo qun l chnh xc v khi lng ho cht c cha trong kho so vi s sch. Thc hin nghim chnh ch kim k hng thng, hng qu. 5.3.3 Ni c hi kh c, bi c phi thng gi t nhin v kt hp vi cc bin php thng gi

cng bc m bo nng cht c trong mi trng lm vic khng vt qu nng gii hn cho php theo qui nh php l hin hnh 1). 5.3.4 C s c ho cht c phi thc hin nghim chnh cc qui nh php lut v bo v mi TCVN

trng. Nc thi, kh thi phi c x l t tiu chun qui nh: TCVN 5945:1995, 5939:1995, TCVN 5940:1995.

Cht thi c hi khc pht sinh trong qu trnh sn xut, lu thng, s dng phi c thu gom x l. Cm chn lp, thiu hu tu tin hoc ln vi cht thi thng thng khc. 5.3.5 C s c ho cht c phi c ch nh k kim tra nng cht c hi trong mi

trng lm vic. Phi trang b phng tin k thut, y t cn thit, ng cu x l kp thi khi xy ra tai nn lao ng, s c ho cht.

1)

Hin nay B y t ang son tho qui nh ny.

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5.3.6 Khi tip xc vi ho cht c, phi c mt n phng c. Khi s dng mt n phng c

phi theo nhng qui nh sau y: ph hp vi loi ho cht c; ph hp vi kch thc ngi s dng; m bo thi gian qui nh cht lng ho cht dng kh c; cm dng mt n ht tc dng.

Phi ct gi mt n ni c t kh c v phi nh k kim tra tc dng ca mt n. 5.3.7 Khi tip xc vi bi c phi dng qun o kn may bng loi vi bng dy c khu trang

chng bi, qun o bo v chng hi bi. Khi tip xc vi cht lng c cn phi che kn c tay, chn, ngc. Khi lm vic vi dung mi hu c ho tan phi mang qun o bo v khng thm v mt n cch ly. Phng tin bo v c nhn phi trong t kn cm mang v nh trnh nhim c. 5.3.8 Nghim cm s dng li cc dng c, bnh cha, bao b ng ho cht c cha ng

cc cht khc. Cc bnh cha, bao b ng ho cht c trc khi thi loi ra u phi kh c v tiu hu ng qui nh. 5.3.9 My, thit b, ng dn ho cht c u phi c bo m bn v kn, cc ng dn kh

phi c thit k sao cho hn ch c ti a cc ch ni, ch, ni d phng. 5.3.10 Ni c ho cht c phi c cc tn hiu bo ng tnh trng thiu an ton ca my, thit

b, bo hiu cc chng sn xut c bit, bo hiu cm nh cm ng m my, cm tho hi nc ... trong qu trnh sn xut. 5.3.11 Trong qu trnh sn xut ho cht c, khi ly mu trong p lc cao th, cn dng my gim p gim p lc. Cc thit b sn xut ho cht lng, phi c thit b o mc ho cht. 5.3.12 Cm ht dung dch ho cht c bng ming. Khi ly mu cht lng trong thit b, phi s

dng nhng dng c qui nh. Khng c tip xc trc tip ho cht c. Cc dng c cn, ong ho cht c sau khi dng phi c lau ra sch s. 5.3.13 Trc khi a ngi vo lm vic ni kn, c ho cht c, phi kim tra khng kh ni

hoc dng ng vt (chim b cu, th) th nghim. Phi kh c bng bin php ph hp, m bo nng cht c cn li nh hn nng gii hn cho php, mi cho ngi vo lm vic.

15

TCVN 5507 : 2002

Khi lm vic nhng ni phi c t hai ngi tr ln, mt ngi vo lm vic, mt ngi ng ngoi gim st cp cu kp thi khi cn thit. 5.3.14 Thit b cha ho cht c d bc hi, d sinh bi phi tht kn, nu khng do qui trnh

sn xut bt buc th khng c t cng vi b phn khc khng c ho cht c.

6 Yu cu an ton trong bo qun ho cht nguy him

6.1 Bo qun ho cht d chy, n 6.1.1 Phi chia thnh nhiu khu vc, kho ring theo mc d chy, n ca cc nhm ho cht,

bo qun c an ton theo qui nh trong ph lc D. 6.1.2 Kho cha ho cht d chy, n phi cch ly vi la v ngun nhit. Phi chp hnh nghim ngt cc qui nh sau: cm em cc vt gy ra la vo kho, cm chiu sng bng la, ch c chiu sng bng n phng chy, n. Cm hn hoc lm nhng vic pht ra tia la gn kho di 20 m; khng i giy inh hoc c ng c st vo kho. Khi vn chuyn cha bng kim loi, cm qung qut, ko l trn sn cng, cm dng cc dng c gy ra tia la; cm cc vi lau, gi bn dnh du m trong kho; cc xe chy bng c qui, thit b nng, xc bng in phi lp ng c an ton phng n.

6.1.3 Kho phi kh ro, thng thong, phi c h thng thng gi t nhin hay cng bc. i vi cc cht d b xy ho, bay hi, chy, n, bt la nhit thp phi thng xuyn theo di m v nhit . 6.1.4 Bao b cha ng ho cht d chy, n di tc dng ca nh sng, phi bng vt liu

hoc c mu cn c nh sng hoc c bc bng cc vt liu ngn nga nh sng chiu vo. Cc ca knh ca nh kho phi sn cn nh sng hoc dng knh m. 6.1.5 Cht lng d chy, bay hi phi cha trong cc thng khng r r v trong hang hm

hoc trong kho thong mt, khng tn cha cng cc cht xy ho trong mt kho. 6.1.6 Khi rt ho cht lng d chy vo thng kim loi phi tip t v thng bng ming ng

hoc nhm, khng c tip t bng kim loi en. 6.1.7 Vic s dng in trong kho phi tun theo iu 5.1.7 ca tiu chun ny.

16

TCVN 5507 : 2002

6.2 Bo qun ho cht n mn 6.2.1 Kho cha ho cht n mn phi lm bng cc vt liu khng b cht n mn ph hu. Nn

nh kho phi bng phng, xung quanh ch phi c g cao t nht 0,1 m hoc ri mt lp ct dy 0,2 - 0,3 m. 6.2.2 Cm cc cht hu c (nh rm, v bo, mn ca, giy), cht xy ho, cht d chy, n

trong cng mt kho vi ho cht n mn. Phi phn chia khu vc bo qun ho cht n mn theo tnh cht ca chng. Ho cht n mn v c c tnh axit, ho cht n mn hu c c tnh axit, cht n mn c tnh kim v cc cht n mn khc phi bo qun nhng khu vc hoc kho ring. 6.2.3 Mi loi axit phi theo tng khu vc ring trong kho. Cc bnh axit phi theo tng l v phi c th kho theo di. Gia cc l phi li i rng t nht l 1 m. Khi sp xp ho cht n mn phi ng chiu qui nh. 6.2.4 Bao b cha ho cht n mn phi lm bng vt liu khng b ho cht n mn ph hu, phi m bo kn; ho cht n mn dng lng, khng c np y qu h s y theo qui nh. 6.2.5 Nhng ngi lm vic trong kho phi thng xuyn kim tra kn ca bao b, thit b cha

ng ho cht n mn, nh k kim tra cht lng ho cht v c bin php x l kp thi. Khi tip xc phi dng phng tin bo v c nhn. 6.3 Bo qun ho cht c 6.3.1 Ho cht c phi bo qun trong kho c tng v nn khng thm nc, khng b nh

hng ca l lt, xa ni ng dn c, m bo khong cch an ton theo qui nh, kho phi c kho bo m, chc chn. 6.3.2 Khi bo qun, nu cn san rt, ng gi li bao b, khng c thao tc trong kho m

phi lm ni thng thong, m bo v sinh an ton, hoc ni c trang b h thng ht hi kh c. 6.3.3 Khi s dng cc phng tin cn ong ho cht c, m bo khng lm ri vi hoc tung

bi ra ngoi. 6.3.4 Trc khi vo kho ho cht c phi m thng cc ca lm thong kho. Khi vo kho phi

trang b y phng tin bo v c nhn.

17

TCVN 5507 : 2002

7 Yu cu an ton trong vn chuyn ho cht nguy him

7.1 Yu cu chung 7.1.1 Khi vn chuyn ho cht nguy him phi theo cc qui nh TCVN 4512 : 1988, cc vn bn qui nh hin hnh v cc qui nh trong tiu chun ny. 7.1.2 Khi vn chuyn ho cht nguy him, c quan c hng phi gi km cc giy t theo qui

nh hin hnh, thng bo cho c quan tip nhn v c quan chu trch nhim bc d. 7.1.3 Khi vn chuyn ho cht nguy him, nhn vin p ti hoc ngi vn chuyn, phi bit r

tnh cht ho l ca ho cht, bin php phng v cch gii quyt cc s c. Khi i theo hng, nhn vin p ti hoc ngi vn chuyn phi mang theo y phng tin bo v c nhn. 7.1.4 Khi chuyn ch ho cht nguy him phi m bo cc yu cu i vi vt cha sau: vt cha phi bng vt liu khng gy phn ng ho hc vi ho cht bn trong, khng b ho cht bn trong ph hu; vt cha bng g th bn trong phi lt bng th vt liu bn m bo ho cht khng thm, lt ra ngoi; vt cha bng thu tinh, snh s phi l loi tt, nt kn, khng rn nt. Cc bnh ny phi t trong st, hp hoc ci g chn bng cc vt liu mm; vt cha bng kim loi phi c np kn, nu cn phi cp ch nim phong; vt cha cc ho cht lng v dng keo phi kn, m bo khng ho cht thm chy ra ngoi. Cc kin hng phi ng gn chc chn xp d d dng; 7.1.5 vt cha l loi chu p lc phi chn, chng va p. Bao b rng trc y cha ng ho cht nguy him, ch sau khi lm sch c bn

trong v bn ngoi th khi vn chuyn mi c coi nh hng ho bnh thng, nu cha lm sch, vn phi coi nh hng ho nguy him. 7.1.6 Trc khi hng n ga, cng, c quan vn chuyn phi thng bo cho c quan nhn hng

bit c k hoch tip nhn kp thi. 7.2 Yu cu khi xp d 7.2.1 Trc khi tin hnh xp d, ngi ph trch xp, d phi kim tra bao b, nhn hiu v trc

tip iu khin hng dn bin php lm vic an ton.

18

TCVN 5507 : 2002

7.2.2 Cm xp cc loi ho cht c kh nng phn ng vi nhau, k nhau hoc cch cha chy

khc nhau trn cng mt xe, mt toa tu, mt x lan, mt thuyn. Cc kin hng phi xp kht vi nhau, phi chn lt trnh ln , x dch. 7.2.3 Khi xp d hng phi theo cc qui nh TCVN 3147 : 1990. Trn ng vn chuyn, nu bc d bt hng xung, phn cn li phi chn buc cn thn m bo khng ln, x dch mi c tip tc vn chuyn. 7.2.4 Trong qu trnh xp d khng c ko l, qung vt, va chm lm v. Khng c m

vc ho cht nguy him vo ngi. Cc bao b t ng chiu k hiu qui nh. 7.2.5 Phi kim tra thit b nng chuyn bo m an ton mi c tin hnh xp d cc

kin hng. 7.3 Yu cu an ton trong vn chuyn 7.3.1 Trc khi xp ho cht nguy him ln phng tin vn chuyn, ngi c hng v ngi ph trch phng tin vn chuyn phi cng kim tra, nu phng tin vn chuyn m bo an ton mi c xp hng ln. 7.3.2 Khi vn chuyn cc bnh kh nn, kh ho tan hay kh ho lng phi theo cc qui nh: Yu

cu an ton trong vn chuyn ca TCVN 6304 : 1997. 7.3.3 Cm vn chuyn cc bnh xy cng vi bnh kh d chy v cc cht d chy khc. 7.3.4 Xe chuyn dng vn chuyn cc cht lng d chy phi c s dng dy tip t v c bin

cm la. Trn xe phi trang b phng tin cha chy thch hp. Ho cht d chy, n nguy him khi vn chuyn phi c giy php vn chuyn hng chy, n ca c quan c thm quyn. 7.3.5 Khi vn chuyn ho cht nguy him, xe phi c mui hoc bt che trnh ma, nng... 7.3.6 Cm vn chuyn ho cht nguy him chung vi ngi, gia sc v cc hng ho khc. 7.3.7 Trn ng vn chuyn ho cht nguy him, ch phng tin khng c dng phng

tin ni cng cng ng ngi (ch, trng hc, bnh vin...). i vi ho cht nguy him b nhit tc ng, khi vn chuyn khng c dng, ni pht sinh ra ngun nhit v khng c lu di tri nng gt.

19

TCVN 5507 : 2002

8 Yu cu an ton lao ng, v sinh lao ng v bo v mi trng

8.1 Khng kh cp thng hi nh xng, nh kho phi ht t vng kh sch, hoc qua lc sch. 8.2 Ngi lm vic trong mi trng ho cht nguy him phi c sc kho m bo yu cu qui nh. Ngi khng c trch nhim khng c vo ni c ho cht nguy him. Cm n, ung, ht thuc, ngh ngi, hi hp ni c ho cht nguy him. 8.3 C s c ho cht nguy him phi nh k khm sc kho cho ngi lao ng, theo di

nhim c ho cht, kp thi pht hin bnh ngh nghip v t chc tt vic iu tr. 8.4 Khi pht hin c cc sinh vt, gia sc, cy ci rau qu b nhim c khu vc c ho cht nguy him phi c bin php tiu hu chng m bo an ton v sinh v phi c bin bn v vic x l . Nghim cm vic mua, bn trao i cc loi cho ngi tiu dng trong sinh hot v n ung. 8.5 C s c ho cht nguy him phi c h thng thu hi v x l hi, kh, bi ca cc ho cht

nguy him m bo mi trng ni lm vic phi t gii hn cho php theo qui nh php l hin hnh. Kh thi ra ngoi mi trng phi t TCVN 5939 : 1995 v TCVN 5940 : 1995. 8.6 Cn c h thng thu gom ring nc ma khu vc nh xng, kho cha ho cht nguy

him. Nc thi t cc nh xng, kho cha ho cht nguy him phi cho vo h thng ring x l trc khi thi vo h thng chung sao cho khi thi ra ngoi mi trng phi theo cc qui nh TCVN 5945 : 1995. 8.7 Nhng cht thi nh: ho cht ht thi hn s dng, ho cht mt phm cht, ho cht ri

vi, bao b ph thi phi c tp trung vo ni quy nh x l kp thi bng phng php ph hp theo qui nh php l hin hnh, trnh gy nhim v s c mi trng. 8.8 Bi cha cht thi t qu trnh sn xut phi t ngoi khu vc sn xut, xa khu nh , khu dn c, xa ngun cung cp nc. B phn lc sch x l nc thi, cht thi phi b tr xa cc khu nh sinh hot ca ngi lao ng, xa khu dn c vi khong cch m bo v sinh an ton theo qui nh hin hnh. 8.9 C s c ho cht nguy him phi c k hoch ngn nga v x l s c ho cht: phi u tin p dng cng ngh sn xut sch, thay th ho cht c hi bng ho cht khng c hi hoc t c hi hn; phi c k hoch hnh ng khn cp, t ng cu v cc bin php h tr t bn ngoi, nhm ng cu v khc phc kp thi khi xy ra s c ho cht.

20

TCVN 5507 : 2002 Ph lc A

(qui nh)

Danh mc cc ho cht nguy him thng dng

Bng A.1 Danh mc cc ho cht nguy him thng dng
T T 1 2 3 4 5 6 7 8 Tn ting Vit Axit axetic, 80% v ln hn (dng bng hoc dung dch) Axit axetic c cha 50%-80% axit tinh khit Anhydrit axetic Axeton Axetonitril Acrolein, cht c ch Acrylonitril Amoniac khan ho lng v dung dch amonic 50% v ln hn Dung dch amoniac (35%-50%) Dung dch amoniac (10%-35%) Amoni biflorua, cht rn Amoni biflorua, dung dch Antimon pentaclorua, dng lng (SbCl5) Antimon pentaclorua, dung dch khng nc Antimon pentaflorua Antimon triclorua (SbCl 3) Asen triclorua Asin Benzen Bo triclorua Bo triflorua Brom, dung dch brom Butadien Butan Butyl acrylat Butyl isoxyanat, thng Butyl isoxyanat, bc 3 Cacbon dioxit, lng, lm lnh su Cacbon disunfua Cacbon tetraclorua Tn ting Anh Acetic acid 80% and greater (glacial or solution) Acetic acid containing 50% to 80% pure acid Acetic anhydride Acetone Acetonitrile Acrolein, inhibited Acrylonitrile Ammonia anhydrous liquefied and ammonia solutions 50% and greater Ammonia solutions (35%-50%) Ammonia solution (10%-35%) Ammonium bifluoride, solid Ammonium bifluoride, solution of Antimony pentachloride, liquid (SbCl5) Antimony pentachloride, non aqueous, solutions of Antimony pentafluoride Antimony trichloride (SbCl3) Arsenic trichloride Arsine Benzene Boron trichloride Boron trifluoride Bromine, bromine solutions Butadienes Butane Butyl acrylate Butyl isocyanate, normal Butyl isocyanate, tertiary Carbon dioxide, liquid, deeply refrigerated Carbon disulphide Carbon tetrachloride CO2 CS 2 CCl 4 SbF5 SbCl3 AsCl 3 AsH3 C6H6 BCl 3 BF 3 Br2 CH2=CHCH=CH2 CH3CH2CH2CH3 CH2CHCOOC4H9 C4H9CNO SbCl5 NH4FHF (CH2CO)2O (CH 3)2CO CH3CN CH2=CHCHO CH2=CHCN NH3 Cng thc ho hc CH3COOH S UN 2789 2790 1715 1090 1648 1092 1093 1005 108-24-7 67-64-1 75-05-8 107-02-8 107-13-1 7664-41-7 S CAS 64-19-7

9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

2073 2672 1727 2817 1730 1731 1732 1733 1560 2188 1114 1741 1008 1744 1010 1011 2348 2485 2484 2187 1131 1846 124-38-9 75-15-0 56-23-5 7637-07-2 7726-95-6 106-99-0 106-97-8 141-32-2 As(744038-2) 7784-42-1 71-43-2 sb(744036-0)

21

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 31 32 33 34 35 36 37 38 39 40 41 42 43 44 Tn ting Vit Cacbon tetraflorua (tetraflometan) Clo Axit cromic, dung dch Crom(III) florua, rn Crom (III) florua, dung dch Cresol Axit cresylic Cumen hydroperoxit - tinh khit k thut Xyanua, hydro xyanua khan, bn Xyanua (v c) Xyanua, dung dch Xyclo hexan Xyclo hexanon Xyclo hexanon peroxit - nng hn 90% vi t hn 10% nc Xyclo hexanon peroxit - nng cc i 72% trong dung dch oxy hu hiu khng nhiu hn 9% Xyclo hexanon peroxit - nng 90% hoc t hn vi t nht 10% nc. Xyclo hexanon peroxit khng nhiu hn 72% bt nho c oxy hu hiu khng nhiu hn 9% Xyclohexen Di-benzyol peroxit - nng hn 80% nhng t hn 95% vi nc Di-benzyol peroxit - nng t 30% n ti a 52% vi cht rn tr. Di-benzyol peroxit - tinh khit k thut thoc nng hn 52% vi cht rn tr. Di-benzyol peroxit nng hn 77% trong nc Di-bezyol peroxit - nng khng hn 72% bt nho Di-laurol peroxit - tinh khit k thut Di-lauroyl peroxit - 42% s khuch tn bn ti a trong nc Tn ting Anh Carbon tetrafluoride (tetrafluoromethane) Chlorine Chromic acid, solution of Chromic fluoride, solid Chromic fluoride,solution of Cresols Cresylic acid Cumene hydroperoxide technical pure Cyanides, hydrogen cyanide anhydrous, stabilised Cyanides, (inorganic, n.o.s) Cyanides, solutions Cyclohexane Cyclohexanone Cyclohexanone peroxide - in a concentration of more than 90% with less than 10% water Cyclohexanone peroxide maximum concentration of 72% in solution with not more than 9% available oxygen Cyclohexanone peroxide - in a concentration of 90% or less with at least 10% water Cyclohexanone peroxide - not more than 72% as a paste with not more than 9% available oxygen Cyclohexene Di-benzyol peroxide concentration of more than 80% but less than 95% with water Di-benzyol peroxide concentration from 30% to maximum 52% with inert solid Di-benzyol peroxide - technical pure or in a concentration of more than 52% with inert solid Di-benzyol peroxide,concentration of more than 77% with water Di-benzyol peroxide - concentration of not more than 72% as a paste Di-lauroyl peroxide - technical pure Di-lauroyl peroxide-42% maximum stable dispersion in water C 6H10 (C6H5CHOH)2O2 C 6H12 C 6H10O (C6H7O)O2 Cng thc ho hc CF4 Cl2 H2CrO4 (CrO3) CrF3 4H2O CrF3 CH3C6H4OH CH3C6H3COOH C6H5C(CH3)2OOH HCN S UN 1982 1017 1755 1756 1757 2076 2022 2116 1051 1588 1935 1145 1915 2117 110-82-7 108-94-1 95-48-7 7782-50-5 1333-82-0 S CAS

45

2118

46

2119

47

2896

48 49

2256 2088

110-83-8

50

2089

51

2085

52 53 54 55

2090 2087 2124 2893

22

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 56 57 58 59 Tn ting Vit Di-tert butyl peroxit - tinh khit k thut Diboran Diclorua silan Dicumyl peroxit - tinh khit k thut hoc hn hp vi cht rn tr Du diesel - im chp chy 560C-1000C Epiclohydrin Etanolamin (hoc dung dch etanolamin) Etyl axetat Etyl mecaptan Etylen diclorua Etylen glycol monobutyl ete Etylen glycol monoetyl ete Etylen glycol monoetyl ete axetat Etylen oxit vi nit Etylenimin, cht c ch St (III) clorua khan St (III) clorua, dung dch nc Focmaldehyt, dung dch nc, cha khng di 5% focmaldehyt, cng cha khng hn 35% metanol. C im chy gia 210C v 550C (bao gm cc gi tr gii hn) Focmaldehyt, dung dch nc, cha khng t hn 5% focmaldehyt, cng khng cha nhiu hn 35%metanol. C im chp chy trn 550C Axit focmic Gecmani Heli, lng, lm lnh su Hexan Hydrazin khan hoc hydrazin dung dch nc nhiu hn 64% trng lng Axit clohydric Dung dch axit flohydric Hydro, lng, lm lnh su Tn ting Anh Di-tert butyl peroxid-technical pure Diborane Dichlorosilane Dicumyl peroxide - technical pure or in a mixture with inert solid Diesel oil (fuel)-flash point 560C1000C inclusive Epichlorohydrin Ethanolamine (or ethanolamine solutions) Ethyl acetate Ethyl mercaptan Ethylene dichloride Ethylene glycol monobutyl ether Ethylene glycol monoethyl ether Ethylene glycol monoethyl ether acetate Ethylene oxide with nitrogen Ethyleneimine, inhibited Ferric chloride anhydrous Ferric chloride, aqueous solutions of Formaldehyde, aqueous solutions of, containing not less than 5% formaldehyde, also containing not more than 35% methanol-having a flash point between 210C & 550C (limit values included) Formaldehyde, aqueus solutions of, containing not less than 5% formaldehyde also containing not more than 35% methanol-having flash point above 55oC Formic acid Germane Helium, liquid, deeply refrigerated Hexanes Hydrazine anhydrous or hydrazine aqueous solutions more than 64% weight Hydrochloric acid Hydrofluoric acid solution Hydrogen, liquid, deeply refrigerated C3H5OCl NH2CH2CH2OH CH3COOC2H5 CH3CH2SH ClCH 2CH2Cl HOCH2CH2OC4H9 HOCH2CH2OC2H5C2H5 HOCH2CH2OC2H5OC2H4C C2H4O C2H4NH FeCl3 FeCl3 HCHO Cng thc ho hc [C(CH3)3]2O2 B2H6 SinH2nCl2 S UN 2102 1911 2189 2121 19287-45-7 S CAS

60 61 62 63 64 65 66 67 68 69 70 71 72 73

2023 2491 1173 2363 1184 2369 1171 1172 1040 1185 1773 2582 1198 75-21-8 151-56-4 106-89-8 141-43-5 141-78-6 75-08-1 107-06-2

74

HCHO

2209

50-00-0

75 76 77 78 79

HCOOH GeH4 He C6H14 H2NNH2

1779 2192 1963 1208 2029

64-18-6 7782-65-2

110-54-3 302-01-2

80 81 82

HCl HF H2

1789 1790 1966

23

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 83 84 Tn ting Vit Hydro clorua, khan Hydro xyanua,khan, hp th bn trong vt liu tr xp Hydro peroxit dung dch nc nng bn trn 60% peroxit Hydro peroxit, dung dch nc vi khng t hn 8%, khng nhiu hn 20% Hydro peroxit khng t hn 20%, khng nhiu hn 60% Hydro peroxit, rn (ure hydro peoxit) Hydro selenua, khan Hydro sunfua Dung dch hypoclorit cha khng di 16% clo hu hiu Dung dch hypoclorit cha nhiu hn 5% nhng t hn 16% clo hu hiu Ru isobutylic Isoxyanat v dung dch ca chng, c im chp chy nh hn 230C Isoxyanat c im si di 3000C v im chp chy 230C v dung dch ca chng Isoxyanat c im si bng v cao hn 3000C v dung dch ca chng Ru isopropylic Ru metylic Metyl bromua Metyl etyl keton Metyl etyl keton peroxit - nng cc i 60% Metyl etyl keton peroxit nng cc i 50%, cha khng nhiu hn 10% oxy hu hiu Metyl etyl keton peroxit nng cc i 50%, cha nhiu hn 10% oxy hu hiu Metyl isobutyl keton Metyl mecaptan Tn ting Anh Hydrogen chloride, anhydrous Hydrogen cyanide, anhydrous, stabilised absorbed in a porous inert material Hydrogen peoxide aqueous solutions stabilised concentrations of over 60% peroxide Hydrogen peroxide aqueous solution with not less than 8% and not more than 20% Hydrogen peroxide not less than 20% and not more than 60% Hydrogen peroxide, solid (ure hydrogen peroxide) Hydrogen selenide, anhydrous Hydrogen sulphide Hypochlorite solutions containing not less than 16% available chlorine Hypochlorite solutions containing more than 5% but less than 16% available chlorine Isobutyl alcohol (Isobutanol) Isocyanates and their solutions, with a flash point of less than 230C n.o.c Isocyanates with a boiling point below 3000C and a flash point of 230C and a flash point 230C c.c or above, and their solutions n.o.s Isocyanates with a boiling point of 3000C and above and their solutions, n.o.s Isopropyl alcohol (Isopropanol) Methanol Methyl bromide Methyl ethyl ketone Methyl ethyl ketone peroxides maximum concentration 60% Methyl ethyl ketone peroxides maximum concentration 50%, containing not more than 10% available oxygen Methyl ethyl ketone peroxides maximum concentration 50%, with more than 10% available oxygen Methyl isobutyl ketone Methyl mercaptan CH3COC4H9 CH3SH C8H1604 (CH3)2CHOH CH3OH CH3Br CH3COC2H5 (CH3)2CHCH2OH R=N=C=O (R: alkyl hoc aryl) Cng thc ho hc HCl HCN S UN 1050 1614 S CAS 7647-01-0 74-90-8

85

H2O2

2015

7722-84-1

86

H2O2

2984

7722-84-1

87 88 89 90 91

H2O2 CO(NH2)2H2O2 H2Se H2S ClO3

2014 1511 2202 1053 1791

7722-84-1

7783-07-5 7783-06-4

92

1791

93 94

1212 2478

78-83-1

95

2206

96

2207

97 98 99 100 101 102

1219 1230 1062 1193 2127 2550

67-63-0 67-56-1 74-83-9

1338-23-4

103

2563

104 105

1245 1064

108-10-1 74-93-1

24

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 106 107 108 109 110 111 112 113 114 Tn ting Vit Metyl methacrylate, n phn t, cht c ch Diclorua metan Naptha, dung mi Axit nitric, bc khi nu khc nhau, mi nng Axit nitric, khi nu Oxit nit Nit, lng, lm lnh su Oleum (axit sunfuric, bc khi) Peroxit hu c (mu v s lng th nh ch i vi mc ch kim tra) Peroxit hu c, hn hp Oxy, lng, lm lnh su Perclorometyl mecaptan Thuc tr su, cacbamat rn Thuc tr su, cacbamat - lng c im chp chy di 210C Thuc tr su, cacbamat-lng c im chp chy 210C-550C Thuc tr su, cacbamat-lng khng bt chy hoc c im chp chy trn 550C Thuc tr su, cacbamat - lng khng bt chy hoc c im bc chy di 550C Thuc tr su, hydrocacbon clo ha - rn Thuc tr su-hydrocacbon clo ha - lng c im chp chy di 210C Thuc tr su, hydrocacbon clo ho- lng, im chp chy 210C-550C Thuc tr su, hydrocacbon clo ho-lng, khng bt chy c im chp chy trn 550C Thuc tr su, clo phenoxyaxetic cc dn xut -rn Thuc tr su, clo phenoxyaxetic cc dn xut lng, c im chp chy di 210C Tn ting Anh Methyl methacrylate, monomer, inhibited Methylene chloride (dichloromethane) Naptha, solvent Nitric acid, other than red fuming, all concentrations Nitric acid, red fuming Nitric oxide Nitrogen, liquid, deeply refrigerated Oleum (sulphuric acid, fuming) Organic peroxides n.o.s (samples and small trial quantities for test puposes only) Organic peroxides, mixtures Oxygen, liquid, deeply refrigerated Perchloromethyl mercaptan Pesticides, carbamates - solid Pesticides, carbamates-liquid, having a flash point below 210C Pesticides, carbamates-liquid, having a flash point of 21 - 550C Pesticides, carbamates-liquid, not flammable or having a flash point above 550C Pesticides, carbamates-liquid, not flammable or having a flash poin below 550C Pesticides, chlorinated hydrocarbons - solid Pesticides, chlorinated hydrocarbons - liquid, flash point below 210C Pesticides, chlorinated hydrocarbons-liquid, flash point of 210C-550C Pesticides, chlorinated hydrocarbons-liquid, not flammable having flash point above 550C Pesticides, chloro phenoxyacetic derivatives-solid Pesticides, chloro phenoxyacetic derivativesliquid, having a flash point below 210C O2 Cl 3CSCl HNO3 HNO3 NO N2 H2SO4 Cng thc ho hc CH2=C(CH3)COOCH3 CH2Cl2 S UN 1247 1593 1256 2031 2032 1660 1977 1831 2255 10102-43-9 S CAS 80-62-6 75-09-2 8030-30-6 7697-37-2

115 116 117 118 119 120 121

2756 1073 1670 2757 2758 2991 2992 594-42-3

122

2992

123 124

2761 2762

125

2995

126

2996

127 128

2765 2766

25

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 129 Tn ting Vit Thuc tr su, clo phenoxyaxetat lng c im chp chy 210C550C Thuc tr su, clo phenoxyaxetat lng khng bt chy hoc c im chp chy trn 550C Thuc tr su, cc dn xut ca bipyridyl-rn Thuc tr su, cc dn xut ca bipyridyl-lng, im chp chy di 210C Thuc tr su, cc dn xut ca bipyridyl-lng, im chp chy t 210C n 550C Thuc tr su, cc dn xut ca bipyridyl-lng, khng bt chy hoc c im chp chy trn 550C Thuc tr su, cc hp cht v c asen - rn Thuc tr su, cc hp cht v c ca asen lng, c im chp chy di 210C Thuc tr su, cc hp cht v c ca asen lng, im chp chy 210C-550C Thuc tr su, cc hp cht v c ca asen lng, khng bt chy hoc c im chp chy trn 500C Thuc tr su, cc hp cht v c ca ng - rn Thuc tr su, cc hp cht v c ca ng lng, c im chp chy di 210C Thuc tr su, cc hp cht v c ca ng lng, c im chp chy 210C-550C Thuc tr su, cc hp cht v c ca ng- lng, khng bt chy hoc c im chp chy trn 550C Thuc tr su, cc hp cht v c ca thu ngn-rn Thuc tr su, cc hp cht v c ca thu ngn-lng, c im chp chy di 210C Thuc tr su, cc hp cht v c ca thu ngn-lng, c im chp chy 210C-550C Thuc tr su, cc hp cht v c ca thu ngn-lng, khng bt chy hoc c im chp chy trn 550C Tn ting Anh Pesticides, chloro phenoxyacetate-liquid, having a flash point of 210C-550C Pesticides, chloro phenoxyacetate-liquid, not flammable of having a flash point above 550C Pesticides, derivatives of bipyridyl-solid Pesticides, derivatives of bipyridyl-liquid, having a flash point below 210C Pesticides, derivatives of bipyridyl-liquid, having a flash point of 210C to 550C Pesticides, derivatinves of bipyridyl-liquid, not flammable or having a flash point above 550C Pesticides, inorganic compounds of arsenic-solid Pesticides, inorganic compounds of arsenic-liquid, having a flash point below 210C Pesicides, inorganic compounds of arsenic-liquid, having a flash point of 210C-550C Pesticides, inorganic compounds of arsenic-liquid, not flammable of having a flash point above 550C Pesticides, inorganic compounds of copper-solid Pesticides, inorganic compounds of copper-liquid, having a flash point below 210C Pesticides, inorganic compounds of copper-liquid, having a flash point of 210C-550C Pesticides, inorganic compounds of copper-liquid, not inflammable or having a flash point above 550C Pesicides, inorganic compounds of mercury-solid Pesticides, inorganic compounds of mercury-liquid, having a flash point below 210C Pesticides, inorganic compounds of mercury-liquid, having a flash point of 210C-550C Pesticides, inorganic compounds of mercury-liquid, not flammable of having a flash point above 550C Cng thc ho hc S UN 2999 S CAS

130

3000

131 132

2781 2782

133

3015

134

2016

135 136

2759 2760

137

2993

138

2994

139 140

2775 2776

141

3009

142

3010

143 144

2777 2778

145

3011

146

3012

26

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 147 148 Tn ting Vit Thuc tr su, cc hp cht phospho v c -rn Thuc tr su, cc hp cht phospho hu c - lng, im chp chy di 210C Thuc tr su, phospho hu c lng im chp chy 210C-550C Thuc tr su, phospho hu c lng khng bt chy trong im chp chy 500C Thuc tr su, cc hp cht thic hu c - rn Thuc tr su, cc hp cht thic hu c -lng, c im chp chy di 210C Thuc tr su, cc hp cht thic hu c - lng, im chy bc 210C-550C Thuc tr su, cc hp cht thic hu c - lng, khng chy hoc im chp chy trn 550C Thuc tr su, thiocacbamat -rn Thuc tr su, thiocacbamat -lng, c im chp chy di 210C Thuc tr su, thiocacbamat lng, im chp chy 210C-550C Thuc tr su, thiocacbamat lng, khng bt chy hoc im chp chy trn 550C Xng Du th, im chp chy di 210C Du th, im chp chy gm 560C-1000C Du th, im chp chy 210C550C Phenol Phenol, nng chy Dung dch phenol Phosgen Phosphin Phospho oxyclorua Phospho pentaclorua Phospho triclorua Kali xyanua Kali hydroxit, dung dch Tn ting Anh Pesticides, inorgano phosphrus compounds - solids Pesticides. Organo phosphorusliquid, flash point below 210C Pesticides. Organo phosphorusliquid, flash point 210C-550C Pesticides, organo phosphorusliquid, not flammable in having flash point of 500C Pesticides, organtin compoundssolid Pesticides, organotin compounds liquid having a flash point below 210C Pesticides, organotin compoundsliquid, having a flash point 210C550C Pesticides, organotin compoundsliquid, not flammable or having a flash point above 550C Pesicides, thiocarbamates-solid Pesticides, thiocarbamates-liquid, having a flash point below 210C Pesicides, thiocarbamates-liquid, having a flash point of 210C-550C Pesticides, thiocarbamates-liquid, not flammable or having a flash point above 550C Petrol (gasoline) Petroleum crude oil-flash point below 210C Petroleum crude oil-flash point 560C-1000C inclusive Petroleum crude oil-flash point 21oC-550C Phenol Phenol, molten Phenol solutions Phosgene Phosphine Phosphorus oxychloride Phosphorus pentachloride Phosphorus trichloride Potassium cyanide Potassium hydroxide, solution COCl2 PH 3 POCl3 PCl5 PCl3 KCN KOH C6H5OH Cng thc ho hc S UN 2783 2784 S CAS

149 150

3017 3018

151 152

2786 2787

153

3019

154

3020

155 156 157 158

2771 2772 3005 3006

159 160 161 162 163 164 165 166 167 168 169 170 171 172

1203 1267 1267 1267 1671 2312 2821 1076 2199 1810 1806 1809 1680 1814 75-44-5 7803-51-2 10025-87-3 10026-13-8 7719-12-2 151-50-8 1310-50-8 108-95-2

27

TCVN 5507 : 2002

Bng A.1 (tip theo)
T T 173 174 175 176 177 178 179 180 181 Propan Axit propionic (axit tinh khit 50%) Propylen imin, cht c ch Oxit propylen, cht c ch Silan Natri xyanua Natri hydroxit, dung dch Styren n phn t, c ch Axit sunfuric cha khng nhiu hn 51% axit Axit sunfuric cha nhiu hn 51% axit Axit sunfuric, thi T-butyl hydroperoxit - nng trn 72% n cc i 90% trong nc T-butyl hydroperoxit-nng cc i 72% trong nc T-butyl hydroperoxit - nng cc i 80% trong di-tert-butyl peroxit hoc dung mi T-butyl per-2 etyl hexanoat - tinh khit k thut T-butyl peoxit benzoat vi t nht 50% cht rn v c tr T-butyl peoxit benzoat tinh khit k thut hoc nng trong dung dch ln hn 75% T-butyl peoxit benzoat nng cc i 75% trong dung dch T-butyl perpivalate-nng cc i 77% trong dung dch Ch tretraetyl/ ch tetrametyl (hn hp nhin liu ng c t) Toluen Triclo etylen Tn ting Vit Propane Propionic acid ( 50% pure acid) Propyleneimine, inhibited Propylene oxide inhibited Silane Sodium cyanide Sodium hydroxide, solution Styrene monomer,inhibited Sulphuric acid containing not more than 51% acid Sulphuric acid containing more than 51% acid Sulphuric acid, spent T-butyl hydroperoxide in a concentration over 72% to a maximum 90% with water T-butyl hydroperoxide - maximum concentration 72% with water T-butyl hydroperoxide - maximum concentration 80% in di-tert-butyl peroxide and/or solvent T-butyl per-2 ethyl hexanoate - technical pure T-butyl peroxy benzoate - with at least 50% inert inorganic solid T-butyl peroxy benzoate - technical pure or in a concentration of more than 75% in solution T-butyl peroxy benzoate -maximum concentration 75% in solution T-butyl perpivalate - maximum concentration 77% in solution Tetraethyl lead/Tetramethyl lead (motor fuel anti-knock mixture) Toluene Trichloroethylene Pb(C2H5)4/Pb(CH3)4 C4H9O2C6H5COO C4H9-OOH NaCN NaOH C 6H5CH=CH2 H2SO4 Tn ting Anh Cng thc ho hc CH3CH2CH3 CH3CH2COOH C3H7N C3H6O S UN 1978 1848 1921 1280 2203 1689 1824 2055 1830 143-33-9 1310-73-2 100-42-5 7664-93-9 S CAS 74-98-6 79-09-4 75-55-8 75-56-9

182

1830

183 184

1832 2094

185

2093

186

2092

187

2143

188

2890

189

2097

190

2098

191

2110

192

1649

193 194

C6H5CH3 ClCH=CCl2

1294 1710

108-88-3 79-01-6

28

TCVN 5507 : 2002

Bng A.1 (kt thc)
T T 195 Tn ting Vit 2,4,4 tri-metyl pentyl-2 hydro peoxit, (mu) (Vinyl axetat) Etylenaxetat Vinyl clorua n phn t, c ch o-xylen m-xylen p-xylen Tn ting Anh 2,4,4 tri-methyl pentyl-2 hydroperoxide, (samples) Vinyl acetate Vinyl chloride monomer, inhibited Xylenes (m-,o-,p-) CH2=CHOOCCH3 CH2=CHCl C6H4(CH3)2 Cng thc ho hc S UN 2255 S CAS

196 197 198

1301 1086 1307

108-05-4 75-01-4 95-47-6 108-38-3 106-42-3

Ch thch:
1) S CAS (Chemical Abstracts Service) s ng k ha cht trch yu. 2) S UN s Lin Hip Quc: l s do Ban Chuyn gia Lin Hip Quc son tho trong phin bn ln th 9 v Khuyn ngh vn chuyn cc hng ha nguy him.

29

TCVN 5507 : 2002 Ph lc B

(qui nh)

Phn nhm ho cht d chy, n

Bng B.1 - Phn nhm cht d chy theo nhit bng chy Nhm 1 2 3 4 Nhit bng chy, 0C Nh hn 28 T 28 n 45 Ln hn 45 n 120 Ln hn 120

Bng B.2 - Phn nhm cht d n theo gii hn n Nhm 1 2 Gii hn n, % th tch so vi khng kh Nh hn 10 % Bng, ln hn 10 %

Bng B.3 - Phn cp bi d n v d chy theo gii hn n v nhit bng chy Cp Bi l lng: Cp 1 Cp 2 nh hn 15 t 15 n 65 Gii hn n, g/m3 khng kh Nhit bng chy, oC

Bi lng: Cp 1 Cp 2 nh hn 25 bng, ln hn 25

30

TCVN 5507 : 2002 Ph lc C

(qui nh)

Cc ch s nguy him d chy n

Bng C.1 - Cc ch s nguy him i vi cc cht d chy, n Tnh cht d chy v d n (k hiu) Nhit bng chy, o C -178 CCK CLDC CLDC CLDC CLDC CC CCL CCK CLDC CNN CLDC CLDC CLDC CLDC CCK CCK CLDC CCK CCK CLDC CCK CCK CCK CLDC CLDC CLDC CKC CLDC -26 11 -8 58 2,35 31 47 -43 38 -10 29 -12 28 -40 153 73 -38 -18 -2 49 25 -18 17,0 1,48 1,08 1,49 2,0 1,32 1,32 4,12 2,91 2,5 3,33 5,5 1,43 1,42 1,4 1,02 1,799 1,85 1,81 1,85 1,33 12,5 12,0 4,0 0,70 5,4 1,77 13,0 9,3 52,6 74,0 29,0 57,0 7,5 8,0 7,0 10,0 8,0 10,10 57,0 11,0 80,0 17,0 10,0 10,5 25,0 Gii hn n di, % th tch Gii hn n trn, % th tch

STT

Tn cht

Cng thc ho hc

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

Acrolein Amoniac Amyl hydroxit (ru hu c) Amyl axetat Amylen Anhydrit axetic Anhydrit phtalic Anilin Axetandehyt Axeton Axetylen Axit axetic Axit axetic kh Axit butylaxetic Benzen Benzen clorua 1,3 Butadien Butan Butyl clorua Buten 1 Buten 2 Cacbon disunfua Cacbon oxit Cacbonyl sunfua Crotonandehyt Decan Sym-dicloetylen Dietylamin Diclodiflometan Dimetylamin Dimetylformamit

CH2=CHCHO NH3 C5H11OH CH3COOC5H11 C5H10 (CH3CO)2O C6H4(CO)2O C6H5NH2 CH3CHO CH3COCH3 CHCH CH3COOH CH3COOH C5H11COOH C6H6 C6H5Cl C4H6 C4H10 C4H9Cl C4H8 C4H8 CS2 CO COS CH3CH=CHCHO C10H22 CHCl=CHCl (C2H5)2NH CCl2F2 (CH3)2NH C3H7NO

TCVN 5507 : 2002

Bng C.1 (tip theo) Tnh cht d chy v d n (k hiu) CCL CCL CLDC CLDC CCK CLDC CLDC CCK CLDC CLDC CLDC CLDC CLDC CLDC CLDC CCK CLDC CLDC CLDC CNN CNN KC CCK CCL CCL CLDC CLC CNN CCK CCK CCK CLDC CCK CCK CLDC 77 -52 23 153 54-93 198 112 -4 128 38 7,0 3,09 4,29 1,074 0,473 4,7 4,09 4,00 5,6 1,0 1,81 1,78 1,36 7,50 75,0 45,5 57,0 10,0 6,0 24 -3 24 -25 43 28 -41 -30 Nhit bng chy, oC Gii hn n di, % th tch 0,634 3,6 4,6 2,14 3,07 1,9 1,4 3,49 2,0 2,0 3,55 2,28 1,03 6,75 2,0 3,92 2,7 1,7 1,8 3,11 3,66 13,5 9,0 4,0 28,5 80,0 11,2 22,0 12,5 36,0 21,0 18,0 36,5 10,0 13,95 9,0 12,0 Gii hn n trn, % th tch

STT

Tn cht

Cng thc ho hc

32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 32

Dodecan 1,1 Dicloetan 1,2 Dicloetan 1,4 Dioxan Etan Ete dietyl Ete diisopropyl Ete dimetyl Ete divinyl Ete metyl etyl Etyl amin Etyl axetat Etyl benzen Etyl bromua Etyl celosel Etyl clorua Etyl focmiat Etyl glycol axetat Etyl glycol Etylen Etylen oxit Triclo flo metan Formaldehyt Glyxerin Glycol Heptan Hexandecan Hydrazin Hydro Hydro sunfua Hydro xyanua Isoamyl axetat Isobutan Isobutylen Isopentan

C12H26 C2H4Cl2 C2H4Cl2 (CH2)4O2 C2H6 C2H5OC2H5 (C3H7)2O CH3OCH3 (CH2=CH)2O CH3OC2H5 C2H5NH2 CH3COO C2H5 C6H5CH2CH3 C2H5Br C4H10C2 C2H5Cl HCOOC2H5
CH3COC2H4OC2H5

77 -29 12 11 -18 -43

C2H5OCH2CH2OH CH2=CH2 C2H4O CCl3F HCHO CH2OHCHOHCH2OH C2H6O2 C7H16 C16H34 N2H4 H2 H2S HCN CH2COOC5H11 C4H10 C4H8 C5H12

TCVN 5507 : 2002

Bng C.1 (tip theo) Tnh cht d chy v d n (k hiu) CLDC CLDC CCK CLDC CLDC CLDC CCL CLDC CCL CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CCL CLDC CCL CCL CC CLDC CLDC CLDC CCK CCK CLDC CNN CLDC CLDC CCL CCL CLDC CLDC -17,8 17 21 38 -28,9 39 20 20 -23 31 14 -44 15 4 90 62 81 6 -6 4,5 -17,8 36 2 Nhit bng chy, oC Gii hn n di, % th tch 1,8 0,93 5,28 2,5 4,95 3,1 13,5 1,2 7,6 1,90 1,7 1,49 5,0 1,242 0,843 0,945 1,147 0,505 1,25 0,585 0,692 0,906 2,2 1,43 1,85 2,310 2,30 4,36 2,0 2,0 1,8 2,60 3,4 2,5 1,81 12,4 9,35 10,3 7,2 22,0 10,35 8,0 11,90 14,5 18,0 5,90 9,2 16,0 7,40 2,90 3,20 7,50 15,0 14,0 20,75 16,0 14,5 8,0 17,4 3,50 8,2 Gii hn n trn, % th tch 8,0

STT

Tn cht

Cng thc ho hc

67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101

Isopropyl axetat Isopropyl benzen Metan Metyl glycol Metyl amin Metyl axetat Metyl bromua Metyl butyl keton Metyl clorua Metyl etyl keton Metyl glycol axetat Metyl propyl keton Monoclo etanol n Hexan n Nonan n Octan n Pentan n Pentandecan n Tetradecan n Tridecan n Undecan Naphtalen O diclobenzen Picolin Piridin Propan Propylen Propylen bromua Propylen oxit Propyl amin Propyl axetat Propyl clorua Propylen diclorua Ru alylic Ru butylic (butanol)

CH3COOCH(CH3)2 C9H12 CH4 CH2OC2H4OH CH3NH2 CH3COOCH3 CH3Br CH3COC4H9 CH3Cl C4H8O
CH3COOC2H4OCH3

C5H10O CH2ClCH2OH C6H14 C9H20 C8H18 C5H12 C15H32 C14H30 C13H28 C11H24 C10H8 C6H4Cl2 C6H7N C5H5N C3H8 C3H6 C3H5Br C3H6O C3H7NH2 CH3COOC3H7 C3H7Cl C3H6Cl2 CH2=CHCH2OH C4H9OH

33

TCVN 5507 : 2002

Bng C.1 (kt thc) Tnh cht d chy v d n (k hiu) CLDC CLC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CLDC CCK CCK CLDC CLDC 54 -18 -0 -5 38 28 13 8 23 31 -6 6 Nhit bng chy, oC Gii hn n di, % th tch 3,61 1,23 1,70 1,81 2,23 6,7 2,34 1,66 1,78 1,27 1,25 2,00 1,0 2,6 4,0 6,0 3,2 1,31 42,6 9,0 8,0 3,4 6,7 7,90 11,60 36,5 15,5 18,0 0,0 Gii hn n trn, % th tch 19,0

STT

Tn cht

Cng thc ho hc

102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119

Ru etylic (etanol) Ru hexylic (hexanol) Ru isobutylic (isobutanol) Ru isobutylenic (isobutenol) Ru isopropylic ( isopropanol) Ru metylic (methanol) Ru n propylenic Stirol Tetrahydrofuran Toluen Trietyl amin Trimetyl amin 2,2,4 Trimetylpentan Vinyl axetat Vinyl clorua Xyanogen Xyclo hexanon Xyclohexan

C2H5OH C6H13OH C4H9OH C4H7OH C3H7OH CH3OH C3H5OH C8H8 C4H8O C6H5CH3 (C2H5)3N (CH3)3N C8H18 CH3COOCH=CH2 C2H3Cl (CN)2 CH2(CH2)4CO C6H12

13 63

34

TCVN 5507 : 2002

Bng C.2 Cc ch s nguy him i vi cc hn hp, sn phm d chy, n Tnh cht d chy n (k hiu) CLDC CLDC CLDC CLDC
0,04 0,34

STT

Tn sn phm

Cng thc tng qut

Nhit bng chy, 0 C 40 35 40 40 150 170 170 130-35

Gii hn n di, % th tch 0,52 0,61 0,55 0,64 0,29 8,38 0,43

Gii hn n trn, % th tch

1 2 3 4 5 6 7 8 9

Du diezen 1 Du diezen 3 Du ho KO 20 Du ho KO 22 Du bin th Du AMT 300 TY Du AMT- 300 T Du khong cht Dung mi ho tan M gm:
n Butylaxetat Etylaxetat Ru etylic Ru isobutylic 30% 5% 60% 5%

C C C C C C

14,151 12,343 13,395 10,914 21,74 22,25

H H H H

29 180 23,889 26,860 21,832

5,0 5,0

H H

42,28 33,48

S S

CCL

0,07

CCL CCL

C 19,04 H 24,58 S 0,196 N 0,04

2,76

7,147

1,187

CLDC

2,79

11

Dung mi ho tan gm:

Butyl axetat Etyl axetat Xylen Toluen Ru Etylic Ru Butylic Etylxeloxol 9% 16% 21% 21% 16% 3% 13%

4,791

8,318

0,971

CLDC

1,72

12

Dung mi ho tan RMT

Butylaxetat Xylen Toluen Ru Butylic Etylxeloxol 18% 25% 25% 15% 17%

5,962

H 9,799 O

0,845

CLDC

16

1,25

Dung mi P4
Xylen Toluen Axeton 15% 70% 15%

C 5,452 H

7,606

0,233

CLDC

-4

1,38

35

TCVN 5507 : 2002

Bng C.2 (kt thc) Tnh cht d chy n (k hiu) CLDC Nhit bng chy, 0C Gii hn n di, % th tch Gii hn n trn, % th tch 1,57

STT

Tn sn phm

Cng thc tng qut

13

Dung mi
Xylen Butylaxetat Axeton

P5
40% 30% 30%

C 5,309 H

8,655

0,89

-9

14

Dung mi
Butylaxetat Xylen Toluen

P12
30% 10% 60%

C 6,837 H

9,217

0,515

CLDC

-10

1,26

15 16 17 18 19 20 21 22 23 24

Kh than t (kh hi nc) Kh l cao Kh l cc Kh thin nhin Mazut Xng 83 Xng 92 Xng hng khng Xylen (hn hp ng phn) Vazolin HO(C2H4)3OH 150 C C C C
7,991 7,024 7,267 7,99

7,12 35 4,4 3,8 60-100 H H H

13,108 13,706 23,889

66-72 74 34 13,2 5,16 8,0

CLDC CLDC CLDC CLDC

-36 -36 -34 24

1,08 1,06 0,92 1,00

9,98

Ch thch :
1. CLDC - Cht lng d chy - Cht lng c kh nng t duy tr s chy sau khi tch b ngun la v c nhit bng chy khng qu 61 oC (trong cc kn) hay qu 66 oC (trong cc h). 2. CCK - Cht chy kh - Cht kh c kh nng to ra mt hn hp chy v n vi khng kh nhit khng qu 55 oC. 3. CNN - Cht nguy him n - Cht c kh nng n hay kch n khng cn c s tham gia ca xy khng kh. 4. CCL - Cht chy lng - Cht lng c kh nng t chy sau khi tch b ngun la v c nhit bng chy cao hn 61 oC (trong cc kn) hay qu 66 oC (trong cc h). 5. CC - Cht chy - Cht c kh nng tip tc chy sau khi tch b ngun la.

36

TCVN 5507 : 2002 Ph lc D

(qui nh) Bng D.1 Bo qun cc nhm ho cht d chy, n Cc nhm ho cht khng c bo qun chung

Nhm

Cc cht

Loi nh bo qun

Cc cht c kh nng to thnh cc hn hp n: I Kali nitrat, canxi nitrat, natri nitrat, bari nitrat, kali peclorat, mui IIa, IIb III, IVa, VI Phng cch ly ca nh kho c tnh chu la cao

bectole Cc loi kh nn v kh ho lng a. Cc loi kh chy v nguy him n: Axetylen, amoniac, II metylclorua, hyro, dihyro etylen oxit, kh metan, sunfua, butylen, I, IIb, III, IVa, IVb, V, VI Nh kho chuyn dng c tnh chu la cao hoc ngoi tri c mi che. Cho php bo qun chung vi cc loi kh tr v kh khng chy.

butan, propan... b. Cc loi kh duy tr s chy: Oxy, khng kh ho lng v nn. Cc cht c kh nng t t chy v t bt chy khi tc dng vi nc v khng kh a. Kali, natri, canxi, canxi cacbua, III canxi pht phua, natri pht phua, bi km, bi peoxit, bi nhm, bt nhm, cht xc tc niken , I, IIa, IIb, II IVa, IVb, V, VI Trong cc phng nh kho chng chy c tnh chu la cao Pht pho bo qun ring trong nc. I, IIa, IIb, IIIa, IVa, IVb, V, VI Nh kho chuyn dng c tnh chu la cao. I, IIa, III IVa, IVb, V, VI Trong phng cch ly ca nh kho chung

phospho trng, vng b. Nhm clorua trietyl, nhm clorua, dietyl, trizobutyl nhm v.v

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TCVN 5507 : 2002

Bng D.1 (kt thc) Cc nhm ho cht khng c bo qun chung

Nhm

Cc cht

Loi nh bo qun

Cc cht chy v d bt chy a. Cht lng: Xng, benzen, cacbon isunfua, I, IIa, IIb, IV, IVb, V, VI Nh kho chuyn dng c tnh chu la cao, hm cha, b cha, xitc, thng kim loi.

axeton, du thng, toluen, xylen, amyl axetat, nguyn liu du m IV nh, ligroin, du ho, cn, este etyl, du hu c ... b. Cc cht rn: Xenlulo, phospho , naphtalin (long no ...) Cc cht c kh nng gy ra chy: V Brom, anhydrit romic, kalipermanganat. Cc cht d chy: VI Bng, rm, si gai, than bn, g, du m thc vt.

I, IIa, IIb, III, IVa, V, VI

Nh kho chuyn dng c tnh chu la cao.

I, IIa, III, IVa, V, VI

Cch ly vi cc cht thuc cc nhm khc.

I, IIa, IIb, III IVa, IVb, V

Cch ly vi cc cht thuc cc nhm khc.

Ch thch Khi cn thit bo qun cc ho cht d chy n m khng c nu trong bng trn, th
vic bo qun chung hay khng i vi cc cht thuc nhm no th phi lm r mc nguy him chy n ca cc cht v phi c s ng thng qua ca c quan phng chy cha chy.

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TCVN 5507 : 2002 Ph lc E

(qui nh)

Cc biu trng an ton

E.1 Cc mu biu trng
Cc biu trng an ton i vi ho cht nguy him c qui nh trong bng E.1. Bng E.1 Cc mu biu trng S biu trng 1 Mu biu trng ngha Cht d chy hay t chy Hnh v m t B uc mu en, ngn la

Cht chy

gp

nc

bc

Chic d en, di d c b uc en

Cht n, nguy him

Hnh qu bom mu en, c tia la

Cht kh

Bnh cha cht kh, mu en

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TCVN 5507 : 2002

Bng E.1 (kt thc) S biu trng 5 Mu biu trng ngha Cht n mn Hnh v m t Bnh ln mu en to khi en, ng trong st mu trng.

Cht c

Trong hnh vung en v u lu trng

D v

Cc thu tinh cao chn mu

Khng c xp ln ngc

Hai mi tn en u hng ln trn

Trnh nc

Chic d en

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E.2 Mu sc, kch thc v ng nt

Ch ghi trn biu trng l mu en; Kch thc, ng nt nhn dn trn kin hng tun theo qui ch ghi nhn hng ho.

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