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VT LIU CAO SU

Cao su thin nhin Cao su tng hp Cao su nhit do

Gi tn cc cao su ASTM D 1418-9


Cao su Poliisopren C/s thin nhin Polibutadien Copolime Butadien-Stiren Copolime Butadien-Acylonitril Policloropren Copolime Isobutadien-Isopren Tertpolime etilenpropilen-dien K hiu IR NR BR SBR NBR CR IIR EPDM
*

Cng thc ha hc
CH3 * C H2 C C H H2
n

Tg -700 -750

C C C C H2 H H H2
CH CH C H2
n

*
H C

-800 -1050
m

C H2

C H2
H C

C6H5
* C H2 C H C H C H2
n

-540 -600 -90 -400 -430 -450

C H2

CN

Cl * C H2 C C H H2
n

CH3 * C H2
n

CH3 C H2 C H C H2
m

CH3

-650 -750 -500 -600

CC PHNG PHP SN XUT CAO SU


Cao su Nh tng Dung dch

Cation

Anion

ZN

Huyn ph ZN

SBR NBR BR IR CR IIR EPDM

CAO SU THIN NHIN


Tg = -700C -750C

CH3 * C H2 C C H H2
n

C cu lp th

CAO SU THIN NHIN

c im cu trc: 98% dng cis 1,4


Mn= (2,55 - 27,09) x 105; Mw= (3,4 - 10,17) x 106

Chng loi:
T latex: cc loi 3L, 3, 5L, 5 v CV T m ng: cc loi 10, 20

Tnh cht gia cng:


D gia cng, phi c giai on s luyn (tr chng loi CV)

H lu ha thng dng:
H lu ha lu hunh. C th dng h peroxid

M (LATEX) CSTN
Cc ht phn t CS trong latex: Chng c cu to thnh 2 lp: bn trong l cc ht CS polyizoprene (C5H8 [C5H8]n C5H8); bn ngoi l lp cht b mt (protein,) xc nh tnh n nh, s kt hp ca th huyn ph, l i din c trng kh nng tch in: S ng c latex: ng c t nhin ng c bng acid ng c bng mui hay cht in gii ng c bng cn/ aceton ....

CAO SU THIN NHIN


bn v tnh bt dnh ca cao su sng cao. Tnh cht cao su lu ha cao. Nhit sinh ni thp. Cao su vn gi tnh mm do nhit thp. Kt dnh tt vi si. Chu nc, acid v baz long. Khng lo ha km i vi cc tc nhn nh nhit, oxi, ozon, UV. Khng chu du, cc dung mi hidrocarbon

CAO SU THIN NHIN

Khong nhit s dng:

T -600C n +700C.

Phm vi ng dng:
Phn ln s dng trong cng nghip sn xut v xe. Cc sn phm k thut chu lc cao, th d m gim chn, khp ni mm

QUI TRNH SN XUT CAO SU


M vn cy Latex
C c: -Bc hi -Kem ha - Li tm To crp, t Sy kh nng xng khi ng t Cn ra To cm, bn Sy kh nng ng bnh RSS ADS Crp trng Cao su khi 3, 5, CV, L Cao su khi 10, 20

M ng
Ngm Cn x - Cn ra To crp Sy kh nng

Latex c c

Crp nu

X l m

TIU CHUN VIT NAM CHO CSU KHI


Tnh cht Hm lng bn (%, max) Hm lng tro (%, max) Hm lng cht bay hi (%, max) Hm lng nit (%, max) do ban u (P0 , min) do cn li PRI Ch s mu nht Mooney ML(1-4) 1000C SVR 60CV 0.03 0.03 0.05 0.05 0.08 0.08 0.06 0.06 60 60 605 505 35 35 60 60 25 26 60 50 0.06 0.06 30 30 40 0.08 0.08 0.06 0.06 30 0.04 0.05 0.08 0.08 0.06 SVR 50CV SVR L 0.02 0.03 0.05 0.75 0.08 SVR 3L SVR 5 0.05 0.08 1.00 SVR 10 SVR 20 0.16 Tiu chun o TCVN 6089:1995 TCVN 6087:1995 TCVN 6088: 1995 TCVN 6091: 1995 TCVN 6092: 1995 TCVN 6092: 1995 TCVN 6093: 1995 TCVN 6090:1995

TIU CHUN VIT NAM CHO CAO SU LATEX


Tnh cht Latex ammonia cao 61.5 60 2.0 0.60 min 650 8.0 0.2 1.0 Latex ammonia thp 61.5 60 2.0 0.29 max 650 8.0 0.2 1.0 Tiu chun o ISO 124 ISO 126 ISO 125 ISO 35 ISO 7780 ISO 506 ISO 127

Hm lng rn TSC (%, min) Hm lng cao su kh DRC (%, min) Hm lng rn phi cao su (%, min)

Tng lng kim NH3 (% latex) bn c hc (giy, min)

Hm lng mangan (mg/Kg TSC, max) Acid bo bay hi VFA (% max) Hm lng KOH (% latex, max)

CAO SU SBR
* C C C C H2 H H H2
m

H C C H2

n x

Tg = -540C -640C

CAO SU SBR

Phng php sn xut:


Trng hp gc t do trong nh tng 50C hay 500C. Trng hp anion trong dung dch.

Dng thng phm:

Ty thuc cc thng s sn xut, thng s dng loi S1500 v S1700.

Tnh cht gia cng:


D dng, thng trn ngui (60 -1300C) sau khi cn do khong 30 giy. t bt dnh, cng lc cao su sng nh.

H lu ha:

Ging cao su thin nhin

CAO SU SBR
Loi Tnh cht Trng hp nh tng 50C Cha cht phng lo khng nhum mu nht Mooney thp Hm lng stiren cao nht Moonet cao Trng hp nh tng 50C, c du Cha 37,5 phr du naptenic Cha 37,5 phr du aromatic Cha 50 phr du aromatic Cha 50 phr du naptenic Nhm SBR 1000 Trng hp nh tng 500C Nhm SBR 1500 SBR 1502 SBR 1509 SBR 1516 SBR 1570 Nhm SBR 1700 SBR 1700 SBR 1700 SBR 1700 SBR 1700

CAO SU SBR
Loi Tnh cht

Trng hp nh tng 500C, cha than en v Nhm SBR 1600 du hm lng < 14 phr Trng hp nh tng 50C, cha than en v Nhm SBR 1800 du hm lng > 14 phr Nhm SBR 1900 SBR c hm ng stiren tht cao Nhm SBR 1200 Trng hp dung dch Nhm SBR 2000 Latex SBR trng hp 500C Nhm SBR 2100 Latex SBR trng hp nhit 50C

CAO SU SBR
Tnh cht thp nu khng c n. Khi c n tng cng tnh cht ngang vi cao su NR (ngoi t khng x thp hn). khng mn, khng un gp cao. Nhit sinh ni cao hn NR Khng lo ha, khng du, dung mi yu.

CAO SU SBR
Khong nhit s dng: -500 +800C S dng trong nhiu lnh vc, nht l ch to v xe. Nh sn xut:

Shell, Polysar, Huls, Enichem

CAO SU BUTADIEN
CH2 H C CH2 trans 1-4 C H CH2 cis 1-4 CH2 H C C CH2 H CH2 CH C H
1-2

Cu trc Trans 1,4Cis 1,4Isotactic 1,2Syndiotactic 1,2

Tm(0C) 145 3 128 156

Tg(0C) -106 -107 -15

CAO SU BUTADIEN

Phng php sn xut


Trng hp nh tng: t s dng Trng hp dung dch:

Xc tc Ziegler-Natta:hm lng vinil 1,2 thp Xc tc anionic.

c tnh cu trc: thay i theo xc tc. H lu ha:


Thng dng h lu hunh ging cao su thin nhin

CAO SU BUTADIEN
Tnh cht c ca BR c n thp nhiu so vi NR v SBR. Nhit sinh ni rt thp. Tnh khng mn, khng nt cao (n vi CSTN lm v xe) Tnh khng x thp Khng du, dung mi km bm dnh tng khi c phi trn vi CSTN; Khng lo ha tng khi c phi trn vi CSTN

CAO SU BUTADIEN

Khong nhit s dng:

T -800 +800C

Phm vi s dng: Sn xut v xe, sn phm chu bn va p, bng ti c tnh x rch, tnh khng mn, khng nhit tt v tnh khng un khc dp nt tt hn khi c phi hp BR vi NR Nh sn xut:

Phillips Petrol, Anic S.P.A , Goodrich-Gulf, Huls A.G, Japan Synthetic Rubber (J.S.R), Shell, J.S.R, Goodyear.

SO SNH NR, SBR V BR


Tnh cht
Tnh gia cng

NR
Rt tt Cn ha do Tn n/lng gia cng 0.92 Cao Cao 30 90 70 - 50 > 25 Tt Rt cao Nh Rt cao Trung bnh

SBR
Rt tt t ha do D t lu 0.94 Trung bnh Thp 40 90 80 - 50 > 20 Rt tt Cao Trung bnh Trung bnh Tt

BR
Trung bnh Kh bm trc Phi s/dng vi cao su khc 0.90 Thp Rt thp 80 - 90 ~18 Rt tt Rt cao Rt nh Thp Rt tt

Khi lng ring Tnh bt dnh C tnh c/su sng cng (Shore A) T0C s dng, max T0C s dng, min Khng t (MPa) Khng mn Tng ny Nhit sinh ni Khng x Khng un gp

CAO SU NBR (NITRIL BUTADIEN RUBBER)


H C C H2 CN

C C C C H2 H H H2

n x

Tg = -90 -450C

CAO SU NBR

Phng php sn xut:


Trng hp gc t do trong nh tng.

Dng thng phm khc nhau ch yu : Tnh cht s dng:

Hm lng acrylonitril: 18 50% nht Mooney: ML(1+4)1000C t 35 n 140 D dng Trn nhit thp sau khi cn do nhanh Kh phn tn lu hunh Bt dnh km. Cng lc cao su sng thp. Ch yu l h lu hunh C th dng h peroxid

H lu ha:

CAO SU NBR
L polime v nh hnh. Khi c tng cng tnh cht c hc tt v ph thuc vo hm lng acrilonitril trong copolime. Khng du, khng dung mi tt. Thay i theo hm lng acrilonitril. Khng ozon v UV km.

CAO SU NBR

Khong nhit s dng:

T -400 n +1300C

S dng nhiu cho cc chi tit tip xc vi du nh trong CN xe hi,CN du ha, xy dng, tu bin . Cc nh sn xut:

Polysar, Bayer, Goodyear, Goodrich, Nipol .

CAO SU IIR (ISOPREN ISOBUTIDIEN RUBBER)


CH3 CH2 C CH3 m CH2 C CH3 CH CH2 n x

Tg = -670 -750C

CAO SU IIR

Phng php sn xut:

Trng hp cationic trong dung dch

Dng thng phm:


Theo bt bo ha ca phn t polime Theo nht MOONEY C halogen ha hay khng (clo- hay brom butil)

Tnh cht gia cng: kh gia cng


Trn nng Khng cn ha do Kh phn tn ph gia Bt dnh thp, cng lc cao su sng thp

H lu ha:
Thng dng h lu hunh C th dng h khc tng tnh chu nhit.

CAO SU IIR
Polime v nh hnh. C tnh tng khng nhiu khi dng n tng cng. Khng thm kh tt. Khng du, dung mi km. Khng lo ha, ozon tt. Chu nc, acid v baz tt

CAO SU IIR

Khong nhit s dng.

T - 500 n 1100C (1500C nu dng h lu ha nha).

Phm vi s dng:
Cng ngh sn xut v rut xe. Sn xut nt chai dc phm. m chng rung.

Nh sn xut:

Polysar, Esso, Total .

TNH THM KH TNG I


Cao su Silicon 2700 NBR (TB) 8.5 NBR (Cao) 3.4

NR 100

EPDM 83

SBR 76

CR 15

IIR 4.8

CO 2.4

CAO SU CR (CLOREN RUBBER)


Cl * C H2 C C H H2
n

Tg = -43 -450C

CAO SU CR

Phng php sn xut:


Trng hp gc t do trong nh tng.

Dng thng phm:


Loi bin tnh bng lu hunh hay mercaptan. nht MOONEY ML(4+1)100 t 30 n 130. Tc lu ha t rt chm n nhanh.

Tnh cht gia cng:


Bt dnh tt, cng lc cao su sng cao (thua NR). Trn nhit thp sau khi cn do nhanh. S dng cht hp thu acid (MgO). Nhy lu ha.

H lu ha:
Ch yu bng oxid kim loi (ZnO), xc tin thioure Mt s trng hp c th dng h lu hunh

CAO SU CR
Polime bn kt tinh. Tnh cht cao su ton gm rt tt. Khi c n tng cng tnh cht c hc rt tt (thua NR). Tnh cht bt chy: t tt Khng du v dung mi tt, tr hp cht thm Khng ozon tt.

CAO SU CR

Khong nhit s dng:

T -40 n 1000C CN xe hi Kt cu xy dng Cp Keo dn Bao b Du Pont, Distugil, Bayer, Denka .

Phm vi s dng:

Nh sn xut:

CAO SU CR
Chng loi Bin tnh lu hunh Bin tnh mercaptan c tnh cht cao Tin lu ha Keo dn Du Pont (neoprene) G(N,S,RT..) W(HV,RT ...) T(W, RT ) WB AD Distugil (Butaclor) SC(10,22 M(C, H ) DE ME MA Bayer (Baypren) 610, 710 210, 230 ... 215 214 320,321 Denkikagaru (denka) PM M MT EM A

CAO SU EPDM (ETYLEN PROPYLEN DIEN RUBBER)


* C C H2 H2 H C C n * H2 CH3 Dien

Tg = -500 -600C

CAO SU EPDM

Dicyclo pentadien Etiliden norbomen

CH3

CAO SU EPDM

Phng php sn xut:


Trng hp dung mi, xc tc Ziegler-Natta

Dng thng phm (co hay tertpolime)

Phn trm bt bo ha (dien t 3 10%) nht MOONEY(1+)100 t 20 n > 100 Hm lng etilen (t 50 n > 65) Loi dien (ENB; DCPD; HD 1,4; ) Ph thuc chng loi, khng cn do c. Trn nhit thp n 1000C. Thng ng dng phng php trn ngc. Bt dnh km, cng lc cao su sng nh.

Tnh cht gia cng

H lu ha:

Dng h lu hunh hay peroxid

CAO SU EPDM
Plolime v nh hnh Khi c n tng cng, tnh cht c hc t trung bnh n tt ph thuc hm lng n v du s dng. Khng du v dung mi yu. Khng lo ha v ozon tt. Khng acid, baz long v mt s du thy lc tt.

CAO SU EPDM

Khong nhit s dng:

T -60 n 1500C

Phm vi s dng:
CN xe hi. Kt cu xy dng. Cp. Sn phm k thut.

Nh sn xut:

Esso, Du Pont, DSM; Huls; Total .

CAO SU NHIT DO
Cao su nhit do va l nha nhit do, va l cao su Vt liu kt hp tnh nng gia cng ca nha nhit do, tnh nng s dng v tnh cht ca cao su. Gia cng nh nha nhit do, tnh nng s dng nh cao su.

SO SNH CAO SU NHIT DO V CAO SU


Khng i hi phi hn luyn. Gia cng n gin. Chu k gia cng ngn. Tiu tn t nng lng gia cng. C th ti sinh. Kim sot cht lng sn phm d dng. Khi lng ring thp. S dng cc phng php gia cng ca nha nhit do nh n, p phun.

CC LOI CAO SU NHIT DO


Copolime khi trn nn stiren. T hp ca poliolefin (TPO). Poliuretan nhit do Copoliester nhit do. Poliamid nhit do.

TNH CHT
cng t 30 shore A n 75 shore D. Nhit s dng t -350C n 1700C. Ngoi tr lnh vc v xe, c ng dng nhiu trong cc sn phm gia dng, giy, bc cp in, tm, trong xy dng, thc phm.

SO SNH CC LOI TPE


Copolime SBS -SIS Mch mm Mch cng TPU TPO EPM / EPDM polipropilen 100 130 50 65 16 20 100 650 100 1300 - 600C 1400C Tt TB n tt Rt tt Co-polieser v copolieter Polialkilen eter glicol Etilen / tetrametilen tereptalat / poliamid 70 > 130 40 70 25 40 350 680 20 400 - 700C 1400C Tt Rt tt Tt

Butadien / Poliester / isopren polieter poliol Stiren Diol + isocianat 75 160 80 20 60 300 650 Rt tt - 400C 1000C Tt Tt Tt

30 -80 cng (shore A) (shore D) bn ko (MPa) 13 33 700 1300 dn t (%) Modun un (MPa) khng mn Nhit ha dn Nhit s dng Khng ozon / oxi Khng dung mi Khng acid / baz - 900C 600C TB TB Tt

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