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Name
_______________________
Exam I Form A
Section
_______________________
Student No.
_______________________
IMPORTANT: On the scantron (answer sheet), you MUST clearly fill your name, your
student number, section number, and test form (white cover = test form A; yellow
cover = test form B). Use a #2 pencil.
There are 25 questions on this exam. Check that you have done all of the problems and
filled in the first 25 bubbles on the scantron. The maximum score on this exam is 25
points. Your score will be reported in percent (max 100%).
Exam policy
Hints
As you read the question, underline or circle key words to highlight them for
yourself. Avoid errors from "mis-reading" the question.
Pay attention to units and magnitudes (decimal places) of numbers obtained from
calculations.
There is no penalty for guessing.
392.0 kJ/mol
19.0 kJ/mol
373.0 kJ/mol
373.0 kJ/mol
411.0 kJ/mol
------------------------------------------------------------------------------------------------------------
2.63 M s-1
0.095 M s-1
0.0361 M s-1
0.380 M s-1
0.436 M s-1
a strong acid.
a strong base.
a weak acid.
a weak base.
not an acid or a base.
-----------------------------------------------------------------------------------------------------------5. What are the conjugate acid and conjugate base of the following ion, H2PO4:
A.
B.
C.
D.
E.
[OH] = 0.5 M
B.
C.
D.
E.
[H+] = 0.3 M
pOH = 5.9
pH = 1.2
[H+] = 1 x 104 M
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------7. Based on the following reaction profile, which of the following is correct?
1 and 2 only
1 and 3 only
2 only
3 only
2 and 3 only
-----------------------------------------------------------------------------------------------------------8. Consider the following equilibria and their respective equilibrium constants:
C(s) + CO2 (g)
CO(g) + O2 (g)
2 CO(g)
2.7 107
CO2 (g)
5.2 1026
What is the equilibrium constant Keq for the reaction shown below?
C(s) + O2 (g)
A.
1.4 1020
B.
1.18 1010
C.
1.9 1033
D.
2.7 1023
E.
7.14 1020
CO(g)
Keq = ???
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------9. The data in the table below were obtained for the reaction:
A + B P
Experiment
Number
1
2
3
[A] (M)
0.273
0.273
0.819
[B] (M)
0.763
1.526
0.763
Initial Rate
(M/s)
2.83
2.83
25.47
38.0
0.278
13.2
42.0
2.21
NO 2 (g) ! NO (g) +
1
O 2 (g)
2
The reaction is second order in NO2 with a rate constant of 0.543M1 s 1at 300C. If
the initial [NO2] is 0.260 M how long will it take for the concentration to drop to
0.100 M?
A.
B.
3.34 s
8.8 102 s
C.
0.611s
D.
E.
0.299 s
11.3 s
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------11. It requires 50 seconds for a first-order reaction to go 75% of the way to completion.
What is the half-life of the reaction?
A. 25 seconds
B. 120 seconds
C. 20 seconds
D. 100 seconds
E. None of the above is within 5% of the correct answer.
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------For the next two questions, consider the following mechanism which involves the
oxidation of iodide ion by hydrogen peroxide in acid solution:
Step 1 (slow) H2O2(aq) + I(aq) H2O(l) + OI(aq)
Step 2 (fast)
------------------------------------------------------------------------------13. For the mechanism above to be consistent with the kinetic data, what must be the
experimental rate equation?
A.
B.
C.
D.
E.
-----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
1, 2, and 4 only
1, 2, and 3 only
1 and 2 only
1, 4, and 5 only
All of these (1, 2, 3, 4, and 5)
-----------------------------------------------------------------------------------------------------------15. The rate constant for the reaction between CO2 and OH in aqueous solution to give
the HCO3 ion is 1.50 1010 L mol-1 s-1 at 25.0 C. Calculate the rate constant at
37.0C (body temperature), given that the activation energy for the reaction is 38.0
kJ/mol.
A.
B.
C.
D.
E.
4.36 109
8.27 109
1.50 1010
2.72 1010
3.66 1089
-----------------------------------------------------------------------------------------------------------16. The removal of sulfur from coal and natural gas can be done by the reaction of H2S
with oxygen after the combustion of the fuel.
2H2S(g) + O2(g)
2S(s) + 2H2O(g)
If the removal of H2S is a desirable result, which one of the following will NOT
promote this process?
A.
B.
C.
D.
E.
increasing O2 pressure
condensing H2O(g) to H2O(l)
removing some of the S(s)
increasing the total pressure by compressing the system
decreasing the pressure of H2O(g)
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------17. What is the expression for the equilibrium constant for the following reaction?
NOCl(g)
A.
B.
[ NOCl]
[Cl2 ] [NO]
[ NOCl]
K eq =
[ NO] [Cl2 ]
K eq =
C.
1 [Cl2 ][ NO]
K eq = 2
[ NOCl]
D.
K eq =
!
E.
[ NO] [Cl2 ]
[ NOCl]
[ NOCl]
K eq =
1 [Cl2 ][ NO]
2
A(g) + 2 B(g)
C(g)
at room temperature, Kp = 1 102. If 1.0 atm of A(g), 1.0 atm of B(g), and 1.0 atm
of C(g) are introduced into a 1 L flask and allowed to react
A.
B.
C.
D.
E.
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------19. The pKw of water at 200C is 11.2. What is the pH of pure water at 200C?
A.
B.
C.
D.
E.
11.2
7.0
5.6
4.2
3.3
-----------------------------------------------------------------------------------------------------------20.
42.3 mL of 0.472M HCl is mixed with 78.1 mL of 0.156M HNO3. What is the pH
of the final solution?
A.
B.
C.
D.
E.
0.323
0.573
0.807
1.32
1.86
-----------------------------------------------------------------------------------------------------------21.
HZ is a weak acid. An aqueous solution of HZ is prepared by dissolving 0.020
mol of HZ in sufficient water to yield 1.00 L of solution. The pH of the solution
was 4.34 at 25oC. What is Ka of HZ?
A.
4.6 105
B.
6.9 109
C.
2.8 1012
D.
1.4 1010
E.
1.0 107
-----------------------------------------------------------------------------------------------------------22. What are the spectator ions in the solution after the complete neutralization reaction
occurs when mixing the strong base NaOH(aq) and the weak acid HClO2(aq)?
A.
ClO2
B.
OH and Na+
C.
H+ and OH
D.
E.
Na+
Na+ and ClO2
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------23. A student studies a first order reaction under several different conditions and gets the
results shown in the plot below. Which of the following conclusions about these
experiments are correct?
only 1 is correct
only 2 is correct
only 3 is correct
1 and 3 are correct.
2 and 3 are correct.
------------------------------------------------------------------------------------------------------------
-----------------------------------------------------------------------------------------------------------24. B is a weak base. Which reaction corresponds to the equilibrium constant Kb for
B(aq)?
A. B(aq) + H3O+(aq)
B. HB+(aq) + OH(aq)
C. HB+(aq) + H2O(l)
D. HB+(aq) + OH(aq)
E. B(aq) + H2O(l)
HB+(aq) + H2O(l)
B(aq) + H2O(l)
H3O+(aq) + B(aq)
B(aq) + H2O(l)
HB+(aq) + OH(aq)
END OF EXAM