BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Li ni u
Dehydrate ha l mt qu trnh quan trng trong cng ngh x l kh xa b cng nh
trong cc nh my ch bin kh. Kh c loi b nc t ngoi khi hn ch kh
nng to nt hydrate trong vn chuyn bng ng ng v cc qu trnh lm vi kh m.
Cc vn c th xy ra:
n mn
Hnh thnh nc dng lng
Hnh thnh Ice
Hnh thnh Hydrate kh
Bi nhng kh nng gy nguy him t hydrate kh nn chng phi c loi b. C mt
s phng php loi b s hnh thnh hydrate kh:
Loi b nc
Tng nhit
Gim p sut
Thm cc cht c ch
Loi b nc l phng php hiu qu nht ngn nga s hnh thnh hydrate,
nhng n thc t n b hn ch bi phi c mt phn xng trung tm loi
hydrate.C 2 phng php chnh loi b nc l: hp th, hp ph...Hp ph
thng s tch c lng nc nhiu hn bi s dng cc vt liu mao qun (
Alumina, Silicagel, Zeolit...) .Tuy nhin, n b gii hn bi vt liu hp ph t hn v
i hi s ti sinh phc tp hn. V th phng php ph bin nht hin ny l hp th,
dng cc dung dch glycol hp th nc ra khi dng kh, sau dung mi hp th c
ti sinh d dng bng phng php chng ct.
Chng ta s Thit k v m phng quy trnh Dehydration bng phng php hp th s
dng dung mi hp th l TEG - Trietylenglycol bng phn mm Aspen Hysys ca
hng Aspen Technology (Cambridge, USA). Phn mm ny chuyn dng tnh ton v
thit k cc quy trnh cng ngh trong lnh vc du kh v ha du vi chnh xc
cao , thun tin v c nhiu u im.

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Li ni u ............................................................................................................................................ 1
1.1. Mc ch, vai tr ca thit k m phng ....................................................................................... 3
1.2. Tng quan qu trnh cng ngh .................................................................................................... 3
1.3. Phng php hp th ................................................................................................................... 7
Chng 2: C s ca vic thit k tnh ton m hnh ............................................................................ 10
2.1. Thp Separator .......................................................................................................................... 10
2.2. Thp hp th TEG Contactor ..................................................................................................... 12
2.3. Van VLV-100 ........................................................................................................................... 16
2.4. Tnh ton thit b trao i nhit .................................................................................................. 21
2.5. Thp ti sinh TEG Regenerator ................................................................................................. 24
2.6. Thit b trn MIX-100................................................................................................................ 26
2.7. Bm P-100 ............................................................................................................................... 27
2.8. Thp Remove TEG ................................................................................................................... 27
2.9. Bnh Remove H2O .................................................................................................................... 29
2.10. Cc thit b iu khin RCY-1v ADJ-1 .................................................................................. 34
Chng 3. M phng qu trnh tch nc trong kh t nhin bng dung mi hp th TEG vi phn
mm Hysys ......................................................................................................................................... 36
3.1. Thit k m phng .................................................................................................................... 36
3.2. Kt qu v nhn xt ................................................................................................................... 43
Chng4. Ph lc ................................................................................................................................ 45
Kt lun .............................................................................................................................................. 50
Ti liu tham kho ............................................................................................................................... 51

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Chng 1: Gii thiu tng quan

1.1. Mc ch, vai tr ca thit k m phng

*Thit k m phng l qu trnh thit k vi s tr gip ca my tnh vi cc phn
mm chuyn nghip.
*M phng l 1 cng c cho php ngi k s tin hnh cng vic 1 cch hiu qu hn
khi thit k 1 qu trnh mi hoc phn tch, nghin cu cc yu t nh hng n 1 qu
trnh ang hot ng trong thc t.
*Mc ch ca thit k m phng:
- m hnh ha:
Chia nh qu trnh
c tnh qu trnh
- Thit k 1 qu trnh mi
- Th li, kim tra li cc qu trnh ang tn ti
- Hiu chnh cc qu trnh ang vn hnh.
- Ti u ha cc qu trnh ang vn hnh.
*u im ca m phng
chnh xc cao
Thay i b s hiu u vo
Ti u ha ch cng ngh(T,P..)
Nhanh chng, chnh xc, kim tra
Thn thin.
1.2. Tng quan qu trnh cng ngh
Chng ta bit nc v hydrocarbon c th hnh thnh hydrat, m c th lm tc
nghn van v ng ng. V th vic xy dng cc thp loi nc trong kh c s
dng rng ri trong cc nh my x l kh hin nay. Nc cng c th gy ra s n
mn trong kh do c cha thnh phn axit. Cho n tn ngy nay, th cc phng php
loi nc ph bin loi nc l hoc l hp th hoc l hp ph. Trong phn bi
tp trnh by di y chnh l phng php loi nc m s kt hp c 2 qu trnh
3

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

hp th v hp ph, trong tri-ethylene glycol (TEG) v silica gel c hp th v

hp th tng ng. Mt n v phng th nghim s hp th, hp ph l nghin cu v
kh t nhin (mtan) tc dng chy v nhit hot ng vi t l loi b nc.
Cng vic th nghim bt u nhit phng bng cch kim sot cc van ca t l
lu lng kh m-tan ti 2,5 m3/gi ban u v sau cho php cc kh thng qua cc
n v hp th, hp ph. Trong khi , tri-ethylene glycol (TEG) chy 120 L / gi t
mt my bm lu thng. Th nghim c lp li vi tc dng chy kh m-tan v
nhit hot ng khc nhau trong phm vi ca 30oC n 50oC. Kt qu thc nghim
cho thy, ngy cng tng ca tc dng chy kh m-tan gy ra ngy cng tng ca
loi b nc trong khi ngy cng tng ca nhit hot ng cho mt kt qu ca
gim loi b nc. Nh vy, trong phn tch hiu qu kh, vic loi nc trong mt
n v hp th, hp ph, cc thng s nh tc dng chy kh (methane) v nhit
hot ng l mt trong nhng c xem xt tin cy v li ch kinh t.
a. Mc ch
Mc ch ca m phng l kim tra phng trnh nhit ng lc hc c kh nng m
phng hn hp nc/glycol mt cch chnh xc.
b. S cng ngh

Qu trnh loi nc c th c chia thnh hai phn, loi nc trong kh v ti sinh

glycol.
Qu trnh loi nc

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Loi nc lun lun bao gm mt thp ra u vo v mt contactor(b tip xc). i kh

trc khi loi nc ta c th h thp nhit dng kh u vo th thch hp hn. do ,
do u vo c th lp t thm mt thp lm mt.
Qu trnh ti sinh
Cc chc nng chnh trong h thng ti sinh glycol c th c chia thnh ba loi:
1. t c c tnh p sut v nhit ti u trong ti sinh dng glycol giu
2. Tisinh Glycol
3. iu chnh li p sut v nhit dng glycol ti u c vic loi nc trong
Glycol Contactor.
Ngoi ba im chnh, c mt s tnh nng b sung c xem xt khi thit k mt
phn xng loi nc:
Ci t mt thp tch nhanh trc thp ti sinh. B phn tch ny loi b phn
ln cc b hydrocarbonb ha tan trong glycol.
B lc glycol giu nu c cc ht rn hoc hydrocarbon lng trong glycol
Tch hp cc b trao i nhit, v vy cc glycol ngho c lm lnh bng
cch nhm cc glycol phong ph, do gim thiu tiu th nng lng.
Glycol hnh thnh s thay th cc glycol mt i, v d trong b cha
Bi v nhng nhn xt ny thit k ca qu trnh ti sinh khc nhau vi thit k ca nh
my. S tch hp ca b trao i nhit l c bit quan trng, bi v iu ny lm gim
tiu th nng lng tng th ca nh my.
M t quy trnh
Qu trnh ny c m t bi cc thit b c s dng trong nh my glycol.
Thp lm mt u vo
Mt b lm mt kh vo c th c s dng bi v vic loi nc s hiu qu hn
khi nhit thp. Mt li ch ca lm mt u vo l mt s nc (hydrocarbon)
trong kh s ngng t, v c loi b trong ch sn u vo, thay v trong cc tip
xc.
Mt b lm mt u vo c s dng khi nhit kh u vo l cao hn so vi
nhit mong mun trong contactor. N cng l mt cng c hu ch trong m phng nu
nhit trong contactor cn phi ti u .
5

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Thp ra
Thp ra s loi b loi b cc git cht lng v cht lng trong kh, c trong nc v
hydrocarbon. Loi b dng nc lng trong thp ra s gip gim bt loi b nc
trong contactor. iu ny s lm gim kch thc ca contactor(b tip xc) v lng
glycol cn thit, t c iu kin yu cu vi dng kh ra khi thp.
Hydrocarbon lng cng l mt vn trong tip xc bi v chng lm tng xu hng
to glycols bt, qua lm gim hiu sut trong contactot v v tng s mt mt
glycol trong contactor v trong h thng ti sinh. Mt vn khc l cc hydrocarbon
c th c tch ly trong glycol gy nhim mi trng v qua lm gim hiu
sut loi nc.
Contactor
Contactor l thp hp th kh kh bng glycol. Glycol ngho vo pha trn ca
contactor trong khi glycol giu c rt ra di cng ca contactor v gi n thp
ti sinh. Kh m vo cc contactor y , trong khi dng kh kh ra khi nh.
Nhit dng glycol vo contactor phi t t 3-11 C (5 n 20 F) cao hn kh
vo Contactor gim thiu s ngng t hydrocarbon vo glycol. Trong thp
contactor th nhit m di 10 C (50 F) th TEG tr nn qu nht, lm gim
hiu sut thp. Nhit contactor c th c cao ti 66 C (150 F), nhng dng
glycol mt mt bay hi thng c coi l khng th chp nhn c mc cao trn
38C (100 F) B5. Cc dng chy glycol vo contactor c quyt nh bi lng
hm lng nc trong kh v s a trong thp. Mt dng chy glycol thng thng l
0,017 n 0,042 m3 nc TEG mi kg nc trong kh (2-5 gal TEG Nc / lb). Thp
contactor vi 4-6 a thng lm vic vi 0,025 m3 TEG / kg nc (3 gal / lb), trong
cc thp ln hn vi 8 hoc nhiu hn 8 a th lu lng thng gim xung cn
0,017 m3/kg (2 gal / lb)
Thp ti sinh
Thp ti sinh l mt thp chng ct, glycol v nc c tch ra. Glycol giu c
nung nng trc trong b trao i nhit trc khi dng nguyn liu i vo thp ti
sinh. nh thp s b ngng t mt phn ti sinh. Hi nc ri khi bnh ngng v
thng ra pha kh quyn. Nhit trong bnh ngng c a ra l 98,9C
(210F)Nng lng cn thit tch glycol v nc c thay th bi reboiler
trong thp ti sinh. i vi TEG nhit ti a c ngh trong reboiler l 204 C

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

(400 F). Cc glycol ngho c ly t cc reboiler v chuyn ti b cha trc khi n

c ti ch hoc c sinh trc tip t reboiler.
p sut trong h thng ti sinh cao hn p sut kh quyn, iu ny l m bo
rng khng c khng kh c th xm nhp vo h thng t l thng kh quyn. Cc
iu kin hot ng i vi nh hng ti to tinh khit ca glycol. 204 oC hiu
sut TEG ca dng glycol ngho t khong 98,6% wt [B4]. Nu tinh khit ca
glycol l khng y , n c th c ci thin bng cch s dng k thut ti to
tin tin hn.
1.3. Phng php hp th
u nhc im ca phng php hp th
u im

S n gin, d tnh ton thit k, d vn hnh, qu trnh lin tc

nn c th t ng ha c, gi thnh thit b thp, t tiu hao tc
nhn lm kh kh, cc cht hp th d ch to. t hiu qu kinh t
cao v c s dng lm lnh kh n im sng -25oC
30oC.

Nhc
im

Khng loi c trit nc nn s rt kh khn khi ch bin kh

nhng giai on sau, im sng cn cao do khng loi trit
hi nc ra khi kh. h im sng xung thp hn nn dng
phng php hp th.

ng dng

Phng php hp th c s dng rng ri lm khan kh trong

cc thit b u ni ca ng ng dn chnh v nh my ch bin
kh.

Cc cht hp th thng dng

Lm kh kh bng cc cht hp th da trn s chnh lch p sut hi nc trong kh v
cht hp th. Kh s c sy bng cch cho kh v dung mi tip xc ngc dng trong
thp hp th, dung mi phi c i lc mnh vi nc.
Yu cu ca dung mi hp th :
C kh nng hp th hi nc trong khong rng nng , p sut v nhit
C p sut hi bo ha thp mt mt trong qu trnh l t nht
Nhit si khc xa nhit si ca nc
nht thp m bo tip xc tt vi hn hp kh trong thp hp th
7

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

C chn lc cao i vi cc cu t kh c mt trong kh, ngha l c kh

nng hp th hi nc cao, ng thi kh nng hp th HC l thp
Tnh n mn km
Khng c hi
Gi thnh r
Mt s cht hp th thng dng:
Cc i lng ha l

EG

DEG

TEG

PG

Khi lng phn t

62,7

106,12

150,18

76,09

T trng tng i 2020

1,116

1,118

1,125

1,034

Nhit si (1atm) C

197,3

244,8

278,3

188,2

Nhit nng chy, C

-13

-8

-7,2

-60

Nhit bt u phn
hy,oC

164

206

Nhit ti sinh, oC

165

164

206

nht 20oC, cP

20,9

35,7

47,8

56,0

Nhit dung ring,

kj/kg.C

2,35

2,09

2,20

2,47

u nhc im ca cc cht hp th:

u im

Nhc im
DEG (Dietylenglycol)

ht m cao, kh bn khi c mt cc
cht: S,O2, CO2 nhit thng

Tiu hao do tht thot cao hn so vi

TEG. Khi ti sinh kh thu c dung dch
c nng DEG ln hn 95%. im
sng thp hn so vi khi s dng TEG

MEA (Monotanolamin) 10-30%, DEG 60-80%, H 2O 5 - 10%

Cht hp th c th tch nc H 2S, CO2 tht thot ln hn so vi khi s dng
ra khi kh, tc l ng thi sy kh v TEG. Ch s dng sy v lm sch kh
lm sch kh. Kh nng to mng thp
Acid. D gy n mn kim loi nhit
ti sinh, im sng ca kh thp
TEG (Trietylenglycol)
ht m cao, to im sng cho kh
sy cao (27,8 - 47,3) , bn cao khi c
mt hp cht lu hunh, oxy v CO 2

i hi chi ph u t cao. Dung dch

TEG c kh nng to mng khi c mt
cc cht lng HC nh. ha tan ca cc
8

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

nhit bnh thng. Khi ti sinh, d

dng thu c dung dch c nng

HC trong TEG cao hn so vi DEG.

cao, trn 99%

La chn cht hp th
Vi thnh phn kh vo nh sau:
Cu t

Phn mol

N2

0.0010

H2S

0.0010

CO2

0.0020

C1

0.8989

C2

0.0310

C3

0.0148

i-C4

0.0059

n-C4

0.0030

i-C5

0.0010

n-C5

0.0005

H2O

0.0409

Nh vy thnh phn kh c cha kh Acid (H2S v CO2) nh vy s khng s dng DEG

v n c th b phn hy bi cc tc nhn ny nhit thc hin ti sinh
(khong
o
206 C). Mt khc nng kh Acid khng qu cao nn ta c th ch cn s dng TEG.
Ngoi ra n c s tht thot trong qu trnh hp th v ti sinh kh nh. Nh vy ta chn
TEG lm cht hp th.

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Chng 2: C s ca vic thit k tnh ton m hnh

2.1. Thp Separator
Thp Separator dng tch nc t do i cng vi kh ra khi hi hp trc khi i vo
thp hp th.
Dng vo:
Tn dng

Inlet Gas

Nhit [C]

30

p sut [kPa]

6200

Lu lng mole
[kgmole/h]

500

Thnh phn
Cu t

Phn mole

N2

0.0010

H2S

0.0010

CO2

0.0020

C1

0.8989

C2

0.0310

C3

0.0148

i-C4

0.0059

n-C4

0.0030

i-C5

0.0010

n-C5

0.0005

H2O

0.0409

TEG
0.0000
y l mt thp tch vt l n thun dng cc tm chn c tc dng gi li nc t do
i theo dng kh. Vi ng knh trung bnh khong 0,05 m.
Vi tn hao p sut:

Dng Inlet : 100 kPa

Dng Vapour Outlet : 100 kPa

p sut cc dng :
PCondensate = PInlet - PInlet = 6200 - 100 = 6100 kPa
10

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

PGas to Contactor = PInlet - (PVapour Outlet + PInlet) = 6200 - 200 = 6000 kPa
Nh vy qua thit b ny nhit ca dng kh gim xung v nhit hydrate ca
dng kh nh hn ti v mt lng kh ln H2O cng H2S c tch ra dng lng v ra
y ca thp.
Dng ra:
y
Tn dng

Condensat

Nhit ( C)

29.60

p sut (kPa)

6100

Lu lng mole
(kgmole/h)

20.04

Thnh phn

Phn mole

H2 S

0.0001

H2 O

0.9999

nh:
Tn dng

Gas to Contactor

Nhit (oC)

29.16

p sut (kPa)

6000

Lu lng mole
(kgmole/h)

480,0

Thnh phn

Phn mole

Nitrogen

0.0010

H2S

0.0010

CO2

0.0021

Methane

0.9364

Ethane

0.0323

Propane

0.0154

i-Butane

0.0061

n-Butane

0.0031

i-Pentane

0.0010

n-Pentane

0.0005
11

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

H2O

0.0009

TEGlycol

0.0000

2.2. Thp hp th TEG Contactor

Kh nguyn liu:
Lu lng 480kgmole/h, 100% pha hi
Nhit : 30oC
p sut : 6200 kpa
Thnh phn ca nguyn liu nh sau:
Cu t

Phn mole

N2

0.0010

H2 S

0.0010

CO2

0.0021

C1

0.9364

C2

0.0323

C3

0.0154

iC4

0.0061

nC4

0.0031

i C5

0.0010

n C5

0.0005

H2 O

0.0009

TEG

0.0000

Dung mi TEG
Lu lng : 6.519 kgmole/h, 100% lng
Nhit : 35oC
p sut : 6200 Kpa
Thnh phn dung mi
Cu t

Phn mole

N2

0.0000

H2 S

0.0000
12

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

CO2

0.0000

C1

0.0000

C2

0.0000

C3

0.0000

i C4

0.0000

n C4

0.0000

i C5

0.0000

nC5

0.0000

H2 O

0.4901

TEG

0.5099

Vy ta c lu lng ring ca dung mi l m =

= 6.127 kg/kg H2O.

p sut nh thp l 6190 kpa, y l 6200 kpa. Thp gm c 8 a l thuyt Bi

ton cn tnh nhng thng s sau:
Nhit , lu lng, p sut, thnh phn dng TEG giu
Nhit , lu lng, p sut, thnh phn kh kh
Nng cc cu t trong dng kh kh c tnh theo cng thc sau:
Yi = (

Trong :
B = A1A2Ai-1 + A2A3Ai-1 + Ai
C = A1A2Ai-1
D = A1A2Ai
Xo

: nng cu t cn hp th trong dung mi

Vi Ai, l yu t hp th ca cu t trn mm i, do thp hp th ta nhit nh coi nh ng

nhit nn A1 = A2 = An
Ai =

Aj =

Vi
13

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Kj - hng s cn bng pha ca cu t cn hp th nhit trung bnh ca

qu trnh
hp th
L - lu lng dung mi i vo thp hp th (mol/h) G lu lng kh nguyn liu (mol/h)
Aj - yu t hp th ca cu t j
Thng th ta gi s lng mole hi v lng ra khi a bng nhau. Khi A c tnh
nh sau:
Aj
Thnh phn cc cu t trong dung mi bo ha ra khi thp c tnh nh sau:
Xj =

Yj

Phn mole ca H2O c tnh bng cch ly 1 tr phn mole cc cu t cn li.

Theo nhng cng thc nh trn ta tnh ton c bng s liu sau:
Cu t

H s K

Yj

Xj

N2

6.415

0.0007

0.0001

H2 S

9.203

0.0014

0.0010

CO2

8.524

0.0020

0.0005

C1

19.52

0.9360

0.0106

C2

19.43

0.0329

0.0008

C3

14.70

0.0156

0.0005

iC4

13.81

0.0060

0.0001

n C4

13.50

0.0032

0.0001

i C5

13.05

0.0010

0.0001

n C5

13.04

0.0007

0.0001

0.0003

0.4985

0.0000

0.4877

H2 O
TEG

8.816

Nhit ca cc sn phm c ly sp x bng vi nhit ca kh nguyn liu l

30oC.

14

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

p sut ca kh ly bng p sut trn nh thp l 6190 Kpa, ca TEG bo ly bng p sut
ca y l 6200 Kpa.
Lu lng cc dng sn phm c tnh nh sau:
Bit thnh phn nguyn liu vo ta bit c d = 2,848 kgmole/dm3, ta c :
V=

= 168,54.10-3 m3/h.

Bit thnh phn dung mi bo ta xc nh c d = 13.55 kgmole/m3. Tnh

lu lng ca dung mi bo ra khi y thp bng cng thc :
L = V( w1 - w2 )( m + 1 )
Trong : w1 = 0.45.10-3 kg/m3 - hm m ca kh nguyn liu
w2 = 0.03.10-3 kg/m3 - hm m ca kh kh ra nh thp Vy
tnh ra c :
L = 168.54. 103 ( 0.45. 10-3 - 0.03. 10-3 )( 6.127 + 1 ) = 560,01 kg/h ( hay 6,79
kgmole/h )
Trong thp ta c :
Vnl + Lnl = Vsp + Lsp
Vy lu lng dng kh kh l :
Vnl = 480 + 6.519 - 6.79 = 479.729 kgmole/h

15

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

2.3. Van VLV-100

Dng vt cht i qua van, bm, v cc thit b trao i nhit xem nh c thnh phn v
lu lng khng i.
Do , ta c:
(

Bit p sut dng u vo, chnh lch p sut P, tnh c p sut dng u ra:
(

Tnh nhit u ra dng LP TEG.

p dng phng trnh Peng-Robinson:

Trong :

16

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

)(

Trong :
P: Pressure
Vm: Molar Volume
T: Temperature
Tc : Critical temperature
Pc : Critical pressure
a : Peng-Robinson
constant a b : PengRobinson constant b
: Acentric fractor
R : Molar gas constant

17

)+

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Tra cc thng s ca dng TEG, ta c bng s liu sau:

Cu t

Phn mol xi

Acentric fractor

Tc (K)

N2

8,99E-05

0,0372

126

Pc (kPa)
3400

H2 S

1,02E-03

0,0948

373

8960

CO2

4,87E-04

0,2667

304

7380

Metan

1,07E-02

0,0104

191

4600

Etan

8,67E-04

0,0979

305

4880

Propan

5,55E-04

0,1522

370

4250

i-Butan

8,08E-05

0,1852

408

3650

n-Butan

4,69E-05

0,1995

425

3800

i-Pentan

9,71E-06

0,228

460

3390

n-Pentan

5,26E-06

0,2514

470

3370

H2 O

0,49865285

0,3443

647

22060

TEG

0,48746342

0,563

806

3958

Acentric fractor ca hn hp:

Nhit ti hn ca hn hp:

( )

p sut ti hn ca hn hp:

Tnh cc thng s ca phng trnh:

)(

18

)+

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

)+

)+

Th tch mol ca hn hp Vm lun thay i ty theo nhit v p sut. Ta cho c

nh p sut, th mt vi gi tr ca T tm mi quan h Vm = f(T).
P = 180kPa.
T (K)

Vm.100 (l/mol)

250

3,82665

270

3,85929

280

3,87667

290

3,8948

300

3,91373

310

3,9335

320

3,95417

19

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Vm.100 3,94
(l/mol)
Molar
Volume 3,92

y = 0,0018x + 3,3798

3,9
3,88
3,86
3,84
3,82
3,8
150

250

200

300

350

Temperature (K)

Ta c phng trnh lin h Vm v T nh sau:

Vm.100 = 0,0018T +3,3798
Thay Vm vo phng trnh Peng-Robinson

*
(

Ta c T=310,56K (hay 37,4oC).

20

)+

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

2.4. Tnh ton thit b trao i

nhit Thit b trao i nhit TEG
- Ex

TEG to Recycle
Dng th nht:
Nhit (oC )

Pump out

> 35

51.42

Nhit dung ring (j/kg.)

Thnh phn

% Phn mol

H2O

0.490126

971

TEGlycol

0.509874

1032

Ta c nhit dung ring trung binh (C ):

C1

=0.490126 971 +0.5098741032= 1002

(j/kg.)
Lu lng khi lng :

G1

= 556.7
O

Vt1 =51.42 -35 = 16.42

Dng th hai:

Nhit (

( kg/h)

( C)

Dry Gas

Sala Gas:

30.63

*
2c (nhit cn tm bng tay

so snh)
Lu lng khi lng

Thnh phn

2 = 8392 (kg/h)

% s mol (%

ni )

Nhit dung ring (J/kg.)(

Ci )

21

BI TP LN TIN NG DNG

Nito
H 2S

GROUP 4 - LHD K52

0.001041

6783

0.001025

1812

CO

0.002076

847

CH

0.936858

932

0.032302

1005

0.012420

854

0.006149

814

0.003127

913

0.001042

1038

0.00521

1235

H2 O

0.000439

971

TEG

000

000

C 2 H6
C3H

i-C4
n-C4
i-C5
n-C5

Ta tnh c nhit dung ring trung bnh ca dng 2 nh sau:

8

C
2

i= 1

C n
i

=0.001416783+0.0010251012.=1214 (J/kg )

p dng cng thc: Q = G1 C 1(t1d - t2 c) = G2C 2 ( t *2c - t2d )

Thay s vo ta c : 556.7100216.42 =1214 8392 (

(CT 2-21 Ha cng 1)

t* c2 - 30.63 )

lch do lm trn.

t2c

= 31.56 ( C ) 31.53 ( C ) (gi tri tnh ton theo Hysis) ch

22

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Thit b trao i nhit L/R HEX

Dng th nht :
Nhit (OC )
Lu lng (kg/h)

Regen Bttms

131.7

Lean from L/R

52.90

556.7

556.7

Thnh phn

% mol

TEGlycol

0.509851

H2O

0.490149

Dng th hai :

Nhit (

Lu lng:
Thnh phn

LPTEG

Regen Feed

**
2c 110

562.4 (Kg/h)
% s mol (% ni )

Nhit dung ring (J/kg.)(

Ci

Nito
H 2S

0.000090

6783

0.001021

1812

CO

0.000487

847

CH

0.010721

932

0.000867

1005

0.000555

854

C 2 H6
C3H

23

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

i-C4

0.000081

814

n-C4

0.000047

913

i-C5

0.000010

1038

n-C5

0.000015

1235

0.498653

971

0.487463

000

H2 O

TEG

Tnh ton tng t nh thit b trao i nhit th nht:p dng cng thc (2-22 SGK
HC1)
Ta tnh c

**
2c = 35.32 (OC )

2.5. Thp ti sinh TEG Regenerator

Thit b ti sinh l mt thp chng ct, TEG v nc c tch ra. p sut trong h
thng ti sinh cao hn p sut kh quyn iu ny m bo rng khng c khng kh c
th xm nhp vo h thng t l thng kh quyn. Cc iu kin hot ng c nh hng
ti ti to tinh khit ca Glycol.
Nh ta t iu kin th p sut hot ng ca thp ti sinh cao hn p sut kh
quyn mt cht trong khong 110 kPa - 150 kPa.
Trong khi nhit nh khng thp hn 100 oC, m bo nc dng hi s c
tch ra nh thp v nhit khng c vt qu 206 oC ti v qu nhit ny th
TEG b phn hy, nh vy s gy mt mt lng TEG ln hn.
Cn bng vt liu :
Dng kh (ch yu l nc dng hi) ra nh ca thp ti sinh:

Dng TEG ra khi y ca thp ti sinh:

w

kgmole/h

Tnh ton Rmin

24

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

T s liu s tay ha cng tp 2 ta c gin lng hi ca hn hp cu t. T gin ta

xc nh c m, vy ta c:
= m = 0.075
Vy:

Rmin = 0.5714

M theo gi thit m phng trong HYSYS ta chn gi tr R = 0,6

= 1,28
1,28 l gi tr chp nhn c
Cn bng nhit:
Ta c bng nhit dung ring ca cc cu t nh sau :
Cu t

Cp(cal/molK)

CH4

8,54

C2H6

12,58

C3H8

17,57

n-C4H10

23,29

i-C4H10

23,14

n-C5H12

28,73

i-C5H12

28,39

N2

6,96

H2S

8,17

CO2

8,87

Da vo bng trn tnh c nhit dung ring ca cc dng Regen feed, Sour Gas,
Regen Bttms nh sau :
C

Dng

Regen Feed

240,1

Sour Gas

37,57

Regen Bttms

259,7

C C pi C
P

25

(KJ/Kmole.oC)

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

p dng cc cng thc tnh nhit lng

QcondQ = C.L.( t2 - t1 ) ta c bng gi tr sau : Q =
C.L.t
QrebQ = 2.107 - 1,5.C.L.t
Trong :
C - nhit dung ca dng tng ng
t - nhit ca dng
L - lu lng ca dn
Dng

Nhit lng ( KJ/h )

CondQ

5,681.104

Reboiler

2,000.107

Regen feed

3,510.106

Sour Gas

5,681.104

Regen Bttms

2,245.104

RebQ

5,819.104

Nhit lng ca ton thp c tnh nh sau:

Q = QRegen Feed + QrebQ - QcondQ - QRegen

Bttms

- QSour

Gas

= 3,43.10 ( KJ/h )
6

2.6. Thit b trn MIX-100

Trong qu trnh lm vic s c mt lng nh TEG b mt mt, v th yu cu to mt
sng chc chn rng dng nguyn liu cn bng c duy tr.
y s tnh ton lng dng TEG:
(Lng TEG)TEG to Pump = (Lng TEG)Makeup TEG + (Lng TEG)Lean From L/R
<-> FTEG to Pump . C%TEG to Pump = FMakeup TEG . C%Makeup TEG + FLean From L/R . C%Lean to L/R
F

Pump

(FC%)

(FC%)

Makeup

C % Pump

Lean

Trong :
FPump , FMakeup , FLean: Lu lng mol ca dng TEG to Pump, Makeup TEG,
Lean
to
R/L

26

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

C%Pump ,C%Makeup, C%Lean : Nng phn mol ca TEG trong dng TEG to
Pump, Makeup TEG, Lean to R/L
p dng: FPump = 6,519 kgmole/h
Tng t vi p sut v nhit : TPump = 52,9 oC v PPump =80 kPa.
2.7. Bm P-100

Qu trnh tnh ton lu lng, p sut, nhit u ra tng t nh vi van VLV-100

2.8. Thp Remove TEG
Mt tiu chun xc nh hiu qu ca qu trnh tch nc l im sng kh kh. Vn
ny c th c kim tra bng vic tm nhit ca kh m ti nc bt u
ngng t. Trc ht tt c TEG phi c loi b bi TEG c nh hng ti im sng
ca nc. Vn ny c thc hin bi vic s dng thit b Component Splitter.
Dng hi ra ngoi c lm lnh v nhit ra ca n c iu khin bi thit b
Adjust tm im sng ca dng kh.
Nhim v ca thp Remove l tch loi trit TEG trong hn hp sn phm nh ca thp
TEG Contactor.TEG sau khi c tch s ra khi nh thp dng lng cn sn phm y
chnh l hn hp kh.
Stream Feed:
Name

Sale Gas

Nhit oC

31,54

p sut kPa

6155

Lu lng mol (kmol/h)

479,7

Lu lng khi lng (kg/h)

83,92
27

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Vapour

1,0

Thnh phn
Cu t

Phn mol

N2

0.001041

H2S

0.001025

C02

0.002076

C1

0.936858

C2

0.032302

C3

0.015420

iC4

0.006149

nC4

0.003127

iC5

0.001042

nC5

0.000521

H20

0.000439

TEG

0.000000

Total

Do thnh phn ban u ca nguyn liu ca thp lng TEG rt khng ng k phn mol
= 0 do phn mol ca sn phm y cng s khng thay i.Lu lng mol,lu lng
khi lng ca dng sn phm y cng s khng thay i.
Sn phm y s ging nh dng nguyn liu vo:
Cu t

Phn mol

N2

0.001041

H2S

0.001025

C02

0.002076

C1

0.936858

C2

0.032302

C3

0.015420

iC4

0.006149

nC4

0.003127

iC5

0.001042

nC5

0.000521

H20

0.000439
28

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

TEG

0.000000

Total

V sn phm nh s duy nht c TEG.vi phn mol=1 v cc cu t khc =0.

Thp thc hin iu kin ng p P=6155 kPa bng vi p sut ca dng nguyn liu
vo cng nh 2 dng sn phm.
TTEG =100C v TWaterdew-point= -32.53 oC.
2.9. Bnh Remove H2O
Thit b ny s loi b nc ngng ra khi dng kh.

2
1

L
A

L'

3
D'
D

5
1 - Thit b phn phi u vo
2 - B tch sng m
3 - u vo
4 - u ra ca dng kh
5 - u ra ca dng lng
Cc d kin bit:
Dng kh vo: Water Dewpoint
Thnh phn pha: lng-kh
Nhit : -32,53oC
p sut: 6155 KPa
29

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Lu lng: 26,67 m3/h

Thnh phn v mole ca cc cu t:
STT

Cu t

% mole (Ci)

Nito

1,041.10-3

H2S

1,025.10-3

CO2

2,076.10-3

CH4

936,858.10-3

C2H6

32,302.10-3

C3H8

15,4240.10-3

7
8

i-C4H10
n-C4H10

6,149.10-3
3,127.10-3

i-C5H12

1,042.10-3

10

n-C5H12

0,512.10-3

11

H2O

0,439.10-3

12

TEG

Tnh ton:
T bng s liu v thnh phn phn mole cc cu t trn ta tnh c:
- Khi lng phn t trung bnh dng Water Dewpoint:

Ta c:

Trong Z l h s nn ca kh ta chn Z =1 Do
khi lng ring ca dng vo:

30

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

- Tng t ta tnh c khi lng ring ca dng kh vo l k = 79,48 Kg/m3

- Lu lng ca dng vo (Water Dewpoint) Qw = 8392 (Kg/h) hay 479,7
(Kmole/h)
- Lu lng ca lng vo bnh l: 0.0038 m3/h
- Lu lng ca kh vo bnh l: 26,6662 m3/h
T s ha tan ca CO2 trong nc l 1,45Kg/1000KgH2O ( y ta coi lng CO2 ha
tan trong nc l bng khng do lng nc nh)
Do t s ca pha lng trn pha hi l nh cho nn ta chon kiu bnh tch nm
ngang nh hnh trn. Ta la chon thi gian lu trong thit b l 2 pht ( cc bong kh
c th thot ra khi nc ) v t s L/D= 3.
Khi ta c:
- Khng gian dnh cho khi lng l:

- Khng gian dnh cho pha kh l:

Tc cc i ca dng kh cho php tch cc git lng trong mt bnh tch nm
ngang l:

Trong K l h s xc nh biu 4.36 (trang 136- Gio trnh cng ngh lc du

- Phan T Bng - Nh xut bn xy dng - H ni 2002)
Lu lng kh Qv c tnh:
( )(

)(

)(

Trong : Pb: p sut tiu chun 1atm

Tb: nhit tiu chun 289K
Qv m3/ngy
31

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

T y ta c S = 0.1956 m2
S y l din tch ca dng kh m2
dm bo s hot ng tt ca bnh tch thng cn them mt khng gian dm gia
vng dnh cho lng v vng anh cho kh. Vng m c th cha n khong 25%
vng dnh cho kh. V vy ta chn din tch S* = S + 25%S l din tch vng kh. Ta
c s d sau:
Gi S1 l din tch vng lng th S1= Vl/L
L l chiu di ca thit b (tm chp nhn L/D = L/D =3)

s*
h

snc
R l bn knh hinh trn. (D=2R)
Vi cc php tnh hnh hc thng thng ta tinh c: Bn
knh ca bnh R = 0.28 m
ng knh ca bnh D = 0.56 m
Chiu di ca bnh L = 1.68 m
Tit din bnh tch 0.246 m2
Tit din vng kh 0.1956 m2
Tit din vng lng 1,5.10-3 m2
Tit din vng m l 0.0489 m2
32

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

+ La chn li vo v li ra:
Li vo v li ra phi tun th cc cng thc sau:

Trong : u, uk , unc l tc di ca dng vo kh v nc ra

v k l khi lng ring ca dng vo v kh ra.
Mt khc: u = Q/Si
Si l din tch ca li vo (ng dn vo) o ta c th chn cc kch thc li vo v ra
nh sau:
ng knh ng li vo: 4 cm
ng knh ng li ra ca kh: 3,5 cm
ng knh li ra ca lng: 1 cm
Ch :
- Trong qu trnh tch nhit v p sut khng thay i
- Lu lng dng lng v kh vo xp x bng vi vi lu lng dng lng kh ra. V l
bnh tch lng kh (tch nc ra khi hn hp kh) trong qu trnh ny cn bng vt cht v
vt liu l khng i. Coi nh tch hon ton (tch hon ton nc ra v coi lng CO 2 ha
tan khng ng k) hn hp ny thnh 2 pha do thnh phn phn mole ca tung cu t
trong tng dng (pha) thay i nhng hm lng khng thay i v ta c th tnh ton
c d dang cc dng ra nh sau:
+ Dng lng: ch c nc v 1 phn nh CO2:
STT

XS H2O (pha lng)

Nhit

-32,53 oC

33

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

p sut

6115 KPa

Lu lng

0.0038 m3/h

Thnh phn

Ch yu l nc.

+ Dng kh:
STT

GAS OUT (pha kh)

Nhit

-32,53oC

p sut

6155 KPa

Lu lng

26,6662 m3/h

Thnh phn (phn mole)

N2

1,042.10-3

H2 S

1,026.10-3

CO2

2,077.10-3

CH4

937,260.10-3

C 2 H6

32,316.10-3

C 3 H8

15,426.10-3

i-C4H10

6,152.10-3

n-C4H10

3,128.10-3

i-C5H12

1,043.10-3

n-C5H12

0,521.10-3

2.10. Cc thit b iu khin RCY-1v

ADJ-1 Thit b iu khin RCY-1

34

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Thit b RCY-1 c thit lp dng Block vi cc dng qu trnh. Nguyn liu vo trong
khi c tnh ton dng tun hon, v a ra cc s liu gi nh cho dng tun hon.Cc
bc Hysys tnh ton nh sau:
Hysys s dng cc iu khin ca dng v gii quyt vi s dng ph
hp vi dng tnh ton
Hysys s so snh cc gi tr ca dng c tnh ton vi cc gi tr tng
ng ca dng gi nh
Trn c s s khc nhau gia cc gi tr, Hysys s bin i cc gi tr dng
gi nh
Qu trnh tnh ton s lp li cho ti khi cc gi tr c tnh ton gp cc gi
tr tng ng ca dng gi nh vi sai s nh hn sai s cho php c
thit lp
Trong trng hp ny, dng lean TEG (TEG Feed) l c lng gc s c thay th vi
dng lean TEG mi c tnh ton (TEG to Recycle) v hai thp TEG Contactor v TEG
Regenerator s chy cho ti khi vng tun hon hi t.
Thit b iu khin ADJ-1
y, thit b iu khin ADJ-1 s bin i nhit ca im ngng t nc ti cc gi
tr im sng c thit lp ph hp vi dng Gas Out.
Thm thit b iu khin iu khin nhit im sng ca dng ti khi dng XS
H2O ln hn 0 v ln hn gi tr lm vic ca dng c thit khng qu 0.01 kg/h.
Nh vy chng trnh s lp li ti khi nhit im sng trong kh t yu cu thit
lp l - 32,53 oC.

35

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Chng 3. M phng qu trnh tch nc trong kh t nhin bng dung

mi hp
th TEG vi phn mm Hysys
3.1. Thit k m phng
Over View Processing:

Thit lp cu t, gi cht lu:

Composition
Components

N2
H2S
CO2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
H2O
TEG
Peng - Robinson

Fluid Pkgs
Nhp dng Inlet Gas:
36

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Worksheet/Conditions
Name
Temperature [C]
Pressure [kPa]
Molar Flow [kgmole/h]
Worksheet/Composition
Component
N2
H2S
CO2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
H2O
TEG

Inlet Gas
30
6200
500
Mole Fractions
0.0010
0.0010
0.0020
0.8989
0.0310
0.0148
0.0059
0.0030
0.0010
0.0005
0.0409
0.0000

Nhp thit b tch Separator:

Design/Connections
Name
Inlets
Vapour Outlet
Liquid Outlet
Design/Parameters/Delta P
Inlet
Vapour Oulet

Separator
Inlet Gas
Gas to Contactor
Condensat
100 kPa
100 kPa

Nhp dng TEG Feed:

Worksheet/Conditions
Name
Temperature [C]
Pressure [kPa]
Vol Flow [m3/h]
Worksheet/Composition
Component
H2O
TEG

TEG Feed
35
6200
0.5
Mole Fractions
0.49
0.51

37

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Thit b hp th TEG Contactor:

Design/Connections
Name
Num of Stages
Top Stage Inlet
Bottom Stage Inlet
Ovhd Vapour Outlet
Bottoms Liquid Outlet
Parameters
Pressure Stage Top [kPa]
Pressure Stage Bottoms [kPa]
Parameters/Solver
Damping

TEG Contactor
8
TEG Feed
Gas to Contactor
Dry Gas
Rich TEG
6190
6200
Fixed

Nhp Van VLV-100:

Design/Connections
Name
Inlet
Outlet

VLV-100
Rich TEG
LP TEG

Nhp thit b trao i nhit L/R HEX:

Design/Connections
Name
Tube Side Inlet
Tube side Outlet
Shell Side Inlet
Shell Side Outlet
Design/Parameters
Heat Exchanger Model
Tube Side - Delta P
Shell Side - Delta P
Worksheet/Conditions/Regen Feed
Temperature [C]
Pressure [kPa]

L/R HEX
Regen Bttms
Learn from L/R
LP TEG
Regen Feed
Exchanger Design (Weighted)
70 kPa
70 kPa
110
110

Nhp thp ti sinh TEG Regenerator:

Design/Connections
Column Name
Num of Stages

TEG Regenerator
8
38

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Inlet Streams - Inlet Stage

Regen Feed, Stage 2
Cond Energy Stream
Cond Q
Reboiler Energy Stream
Reb Q
Condenser
Full Reflux
Ovhd Vapour Oulet
Sour Gas
Bttms Liquid Outlet
Regen Bttms
Design/Specs/Column Specifications
Name
Reflux Ratio
Spec Value
1.5
Active
Check
Design/Specs/Draw Spec
Name
Ovhd Vap Rate
Draw
Sour Gas
Spec Value
0.4870 kgmole/h
Active
Check
Design/Spec/Temprature Spec
Name
Condenser Temp
Stage
Condenser
Spec Value
100 oC
Use As Estimate
Check
Design/Spec/Column Temperature
Name
Reboiler Temp
Stage
Reboiler
Spec Value
205 oC
Use As Estimate
Check
Design/Specs/Duty Spec
Name
Reboiler Duty
Energy Stream
Reb Q
Spec Value
2.0e+007 kJ/h
Use As Estimate
Check
Design/Specs/Comp Frac Spec
Name
TEG Purity
Stage
Reboiler
Phase
Liquid
Spec Value
0.95
Components
TEGlycol
Use As Estimate
Check
Parameters
Condenser Pressure [kPa]
110
Reboiler Pressure [kPas]
150
Condenser Delta Pressure [kPa]
15
Parameters/Solve
Damping
Adaptive
Run
39

BI TP LN TIN NG DNG

GROUP 4 - LHD K52

Nhp dng Makeup TEG:

Worksheet/Conditions
Name
Temperature [C]
Composition
Component
H2O
TEG

Makeup TEG
15
Mole Fractions
0.01
0.99

Nhp thit b trn MIX-100:

Design/Connections
Name
Inlet

MIX-100
Learn from L/R
Makeup TEG
TEG to Pump

Outlet
Parameters
Automatic Pressure Asignment
Worksheet/Conditions
Makeup TEG
Temperature [C]

Equalize All
15

Nhp bm P-100:
Design/Connections
Name
Inlet
Outlet
Energy
Design/Parameter
Adiabatic Efficiency
Worksheet/Conditions
Pump out
Pressure [kPa]
TEG to Pump
Vol Flow [m3/h]

P-100
TEG to Pump
Pump out
Pump Q
75%
6270
0.5

Thit b trao i nhit TEG-Ex:

Design/Connections
Name
Tube Side Inlet

TEG-Ex
Pump out
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Tube Side Outlet

Shell Side Inlet
Shell Side Inlet
Design/Parameter
Heat Exchanger Model
Tube Side/Delta P
Shell Side/Delta P
Worksheet/Conditions
TEG to Recycle
Temperature [oC]

TEG to Recycle
Dry Gas
Sale Gas
Exchanger Design (Weighted)
70 kPa
35 kPa
35

Nhp thit b Recycle RCY-1:

Connections/Connections
Name
Inlet
Outlet
Parameters/Variables
Composition/Sensitivities

RCY-1
TEG to Recycle
TEG Feed
0.1

Kim tra im sng ca Slae Gas vi Hydrat Formation Utility

Three ways to attach Utilities to Sale Gas :
Tool
Press
Double -Click
Attachments

The first way

Utilities/Utilities view
The second way
Ctrl +U/ Utilities view
The last way
A Stream
Utilities/Create button/Utilities view

Attach a Hydrate Formation Utility to Sale Gas

Utilities view
Design/Connections
Design/Connections/Hydrate
Model
Performance/Formation T/P
Equilibrium Phase

Hydrate Formation Utility

Add Utility
Select Stream button
Calculation Sale Gas
Vapour Only Model
Vapour Phase

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Nhp thit b chit thnh phn Remove TEG:

Design/Connections
Name
Inlets
Overhead Outlet
Bottoms Outlet
Energy Streams
Worksheet/Conditions
TEG only
Temperature [C]
Pressure [kPa]

Remove TEG
Sale Gas
TEG only
Water Dewpoint
Split Q
10
6155

Nhp thit b tch Remove H2O:

Design/Connections
Name
Inlet
Vapour Outlet
Liquid Outlet
Worksheet/Conditions
Water Dewpoint
Temperature [C]
Pressure [kPa]

Remove H2O
Water Dewpoint
Gas Out
XS H2O
-32.53
6155

Nhp thit b iu khin ADJ-1:

Connections/Connections
Adjust Name
Adjusted Variable
Object /Variable
Target Variable
Object/Variable/Variable Specifics
Target Value
Source
Specified Target Value
Parameters/Parameters
Solving Parameters
Method
Step Size
Minimum (Optional)
Maximum (Optional)
Maximum Iterations

ADJ-1
Water Dewpoint/Temperature
XS-H2O/Master Comp Mass Flow/H2O
User Supplied
0.01 kg/h
Secant
5 oC
-50 oC
10 oC
10
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3.2. Kt qu v nhn xt
Kt qu :
Dng Gas Out

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Nhn xt:
So snh kt qu tnh ton v m phng c s sai s ,tuy nhin l do tnh ton bng tay
c s sai lch trong thc hin php tnh v lm trn
Tuy nhin dung sai nm trong gii hn cho php.

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Chng4. Ph lc

Hnh 1: PFD ca quy trnh tch nc dng kh t nhin bng dung mi hp th

TEG

Hnh 2: Thp hp th kh dng TEG

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Hnh 3: Thp ti sinh TEG

Hnh 4: Thng s hot ng ca cc thit b

46

BI TP LN TIN NG DNG

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Hnh 5: Thnh phn ca cc dng nguyn liu v sn phm

Bng 1: iu kin hot ng ca cc dng

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Bng 2: Thnh phn ca cc dng

Bng 3: Cc dng nng lng

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Bng 4: Dng ca cc thit b

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Kt lun
Trong qu trnh thc hin nhm t c mt s kt qu nh sau:
Tnh ton s b c qu trnh Dehydrate bng tay
M phng thnh cng quy trnh Dehydrate s dng dung mi hp th l TEG
Tuy nhin vi thi gian hn ch nhm gp phi mt vn : Qu trnh ti sinh dung mi
hp th TEG vn cha t c tinh khit cao ( 90%).

50

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Ti liu tham kho

1. Bi ging tin ng dng - Ks. on Vn Hun
2. Advanced Process Modeling using Hysys - Aspentech
3. Aspen Hysys 2006 - Tutorial

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