MATERIAL SAFETY DATA SHEET

CFS-SOLVO
Certified to MINISTRY OF HEALTH 26-00-500/1995
DATE: October 2010 Rev.02 CAS: 39290-78-3 EINECS: 254 400 -7

REPUBLIC OF BULGARIA

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY/ UNDERTAKING

Product Name Chemical Family Product Use Supplier Emergency Telephone Number Chemical name of substance Formula Synonyms Classification & Symbol Trade Names: CFS, CFSm, CFS-SOLVO Polynuclear inorganic salt Coagulant for potable water treatment. SOLVO Ltd Address: Bulgaria, Sofia 1784, Mladost 1-13-643; tel.: +359 2 8770281 +359 112

2. COMPOSITION / INFORMATION ON INGREDIENTS

Polyaluminum Chloride Hydroxide Sulfate EINECS: 254 - 400 -7
(liquid) and other proprietary ingredients.* Al(OH)xCl(3-x-2y)(SO4)y, where 0.6 < x < 2.5 and 0.05 < y < 0.5 and (x+y/2) < 2.4; Al2O3.HCl.zH2O, = 1, 0.9< <1.3, M=y/x; Basicity:(6-M)/6*100 = 78 to 85. (Active ingredient, expressed as Al203);

Aluminum Chlorohydrate Sulfate R 36 / 38

*NOTE: Specific identity of product ingredients is withheld as a trade secret. Ingredient identity is available to health and others professionals. Only the most restrictive data for the ingredients in this product.

3. HAZARDS IDENTIFICATION
Most Important hazards Specific hazards Eye and skin irritant. Swallow is harmful. -

4. FIRST AID MEASURES

Inhalation Skin Contact Eye Contact Ingestion No data available. S28-Long term contact cause irritation. Wash toughly with soap and water. S26-Irritant for eye. Wear safety goggles at all times. Rinse eyes with running water for 15 minutes with eyelids held open and contact a doctor. Swallowing cause nausea. Immediately induce vomiting by giving 2 glasses of water and sticking a finger down the throat. Get immediately medical assistance.

5. FIRE - FIGHTING MEASURES

Suitable extinguishing media Extinguishing media which must not be used for safety reasons Specific hazards Specific methods Special protective equipment for fire fighters Water, CO2, dry chemicals and foam. Polyaluminium Chloride is non- flammable but may decompose in a fire to liberate hydrochloric acid, toxic gas. Move containers from fire area if it can be done without risk. Use water to keep fire exposed containers cool. Wear MSHA/NIOSH-approved self-contained breathing apparatus and full protective clothing including face and eye protection if this product is exposed to fire.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Avoid contact with eye and skin. Wear self contained breathing apparatus and full protective clothing.

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MATERIAL SAFETY DATA SHEET

Environmental Precautions

Restrict access to area until completion of cleanup. Stop leak if you can do so without risk. Contain by dicing with soil or other non-combustible absorbent material. With clean shovel, carefully place material into clean, labeled, ridged, plastic or plastic coated, dry container and cover; remove from area. Comply with all applicable governmental regulations on spill reporting, handling and disposal of waste. Avoid contact with eyes, skin, clothing. Avoid breathing dust or mist. Store in cool (20 C), dry and well ventilated area. Protect containers from physical damage. Polyaluminium chloride solution should be stored ideally in plastic (PE,PP,PVC) or fiberglass vessels. Other tanks (eg. Mild steel, galvanised steel) must be lined with anti-corrosive material. Keep containers tightly closed when not in use. Always obey hazard warning and handle empty containers as if they were full. Handling and storage area requires safety shower and eye bath. Use in well ventilated area to minimize exposure. Not applicable No exposure limit has been established for this material. Wear a NIOSH or European Standard EN-149 approved respirator appropriate for the vapor or mist concentration at the point of use. Rubber or PVC gloves. Safety glasses or face shield. Rubber coated clothing and boots. Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking or using toilet facilities. Clear to turbid liquid. Colorless to pale yellow. Slight its own special odor. 105 C -12 C 3.5 - 6.5
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7. HANDLING AND STORAGE

Handling Storage Packaging material

Other Precautions

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures Hygiene measures Exposure limits Personal protection equipment - Respiratory system - Hand protection - Eye protection - Skin and body protection

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical appearance Color Odor Boiling point Freezing point(10%Al2O3) pH (5 % solution, 20C)

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MATERIAL SAFETY DATA SHEET

Density Flammability limits Water solubility

1.12 1.30 g/cm3 Not classified Complete

10. STABILITY AND REACTIVITY

Stability Conditions to avoid Materials to avoid Hazardous decomposition products Stable in room temperature and atmospheric pressure Keep away from unsuitable material. Do not rise temperature above 40 C and freeze. Metals Hydrogen chloride.

11. TOXICOLOGICAL INFORMATION

Acute toxicity Oral LD50 : Not classified Dermal LD50 : Not classified Inhalation LC50 : Not classified Polyaluminum chloride solution is not in lists of ACGIH, IARC, NIOSH, NTP and OSHA. Not classified Not classified No data available

Carcinogenicity

12. ECOLOGICAL INFORMATION

Ecotoxicity effects Acute fish toxicity Further Information

13. DISPOSAL CONSIDERATIONS

Further information Treatment, storage, transportation and disposal must be in accordance with applicable State and Local regulations. Do not flush to surface water or sanitary system. If approved, recover or drain neutralized washing to a waste treatment plant.

14. TRANSPORT INFORMATION

UN no Classification Shipping Name: Not regulated Hazard Class: Not hazardous

15. REGULATORY INFORMATION

EINECS-NO R-phrases R-36 254-400-7 Directive 67/548/EEC Irritant for eye

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CFS- SOLVO

MATERIAL SAFETY DATA SHEET

R-38 S phrases S-26 S-28

Irritant for skin Directive 67/548/EEC In case of eye contact : Immediately flush with water, for at least 15 minutes. GET MEDICAL ATTENTION. After contact with skin, wash immediately with plenty of soap and water Wear safety glasses / face screen and protective gloves

GHS/CLP (EC Regulation 1272/2008) Hazard-Statement: Further Information

Signal word and indications of hazard: Warning (Eye Irritation

Cat 2 and Skin Irritation Cat 2)

H319 : Causes serious eye irritation; H315 : Causes skin irritation -

16. OTHER INFORMATION

Legislation Warning Story First publication date Previous publication date Version Written by 2 SOLVO ltd October 2003

All information presented herein is believed to be accurate, however, it is the user's responsibility to determine in advance of need that the information is current and suitable for their circumstances. No warranty or guarantee, expressed or implied is made by SOLVO Ltd as to this information, or as to the safety, toxicity or effect of the use of this product.

FOR MORE INFORMATION ON THE USE OR THE PERFORMANCE OF OUR PRODUCTS, OR FOR SAMPLE REQUESTPLEASE CONTACT SOLVO Ltd, BULGARIA, Sofia 1784, Mladost 1-13-6-43, tel.: +359 2 8770281 e-mail: office@solvobg.com www.solvobg.com

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