Bi tp HNO3

Dng 1: TNH KHI LNG MUI KHAN:

1/. Ho tan hon ton 11,4g hn hp X: M(I) v N(II) vo dd H2SO4 v HNO3 c nng thu
c 4,48 lt hn hp kh v Y( ktc): NO2 v SO2 c t khi hi ca Y so vi H2 l 28,625.
C cn dung dch thu c sau phn ng c m (g) mui khan. Xc nh m.(S:28,05g).
2/. Cho 3,35 g hn hp Mg, Al, Cu tc dng hon ton vi dd H2SO4 c nng d thu c
2,8 lt SO2 (ktc). Khi t 3,35g hn hp trn trong Cl2 d thu c m(g) mui khan. Xc
nh m. (S: 12,225g)
3/. Ho tan 6,25g hn hp Zn v Al vo 275ml dd HNO3 thu c dd X (khng cha mui
amoni), rn Y gm cc kim loi cha tan ht nng 2,516g v 1,12 lt hn hp Z (ktc) gm:
NO, NO2 c t khi so vi H2 l 16,75. Tnh CM ca HNO3 v khi lng mui khan thu c
khi c cn dd .(S: 0,65M v 11,68g).
4/. Ho tan hon ton 9,75g Zn v 2,7g Al vo 200ml dd HNO3 2,5M v H2SO4 0,75 M sau
phn ng ch thu c kh NO l sn phm kh duy nht (ktc) v dd X. Tnh khi lng
mui khan thu c sau phn ng. (S: 45,45g).
5/. Hn hp X : Fe v Cu vi t l % khi lng l 4:6, ho tan m(g) X bng dd HNO3 thu
c 0,448 lt NO( ktc, sn phm kh duy nht), dd Y v c 0,65m (g) kim loi khng tan.
Tnh khi lng mui khan trong dd X. (S:5,4g)
6/. Cho m(g) hn hp :Mg, Zn, Cu tc dng vi dd HNO3 thu c (m+62)g mui khan.
Nung nng hn hp trn thu c bao nhiu g cht rn? (S: m +8 (g))

7/. Cho 3,35g hn hp Mg, Al, Cu tc dng hon ton vi dd H2SO4 c, nng, d thu
c 2,8 lt kh SO2 (ktc). Khi t 3,35g hn hp trn trong Cl2 d (S: 12,225g)
8/. Ho tan 10,71 g hn hp: Al, Zn, Fe vo 4 lt dd HNO3 va thu c dd A v 1,792 lt
hn hp kh gm N2 v N2O c t l mol 1:1. C cn dd A thu c bao nhiu g mui khan
(S: 55,35g)
8/. Cho 12,9 g hn hp bt kim loi Al vfa Mg phn ng ht vi 100 ml dd hn hp 2 axit
HNO3 4M v H2SO4 7M thu c 0,1 mol mi kh SO2, NO, N2O. C cn dd sau phn ng
thu c bao nhiu g mui khan (S: 76,7g)
Dng 2:Xc nh lng HNO3 phn ng:
1/. Ho tan hon ton 13,92g Fe3O4 vo dd HNO3 thu c dd X v 0,448 lt NxOy (sn phm
kh duy nht, ktc). Tnh khi lng HNO3 nguyn cht? (S: 35,28g)
2/. Ho tan ht 4,43g hn hp Al, Mg vo dd HNO3 thu c dd X (khng cha mui amoni)
v 1,568 lt (ktc) hn hp 2 kh u khng mu c m=2,59g trong c mt kh b ho thnh
mu nu trong khng kh. Tnh s mol HNO3 phn ng? (S:0,49 mol).
3/. Cho mt lung kh CO i qua ng s ng Fe2O3 nung nng. Sau mt thi gian thu c
44,64g hn hp X Fe, FeO, Fe2O3, Fe3O4. X tc dng va vi dd HNO3 0,1M thu c dd
Y v 3,136 lt NO (sn phm kh duy nht, ktc). Tnh V dd HNO3 (S: 19,4 lt)
4/. Ho tan 1,52g hn hp Fe v Cu vo 200 ml dd HNO3 thu c dd X; 224 ml NO (sn
phm kh duy nht, ktc) v 0,64g rn khng tan. Tnh CM HNO3? (S: 0,2M)
5/. t chy 6,72 g Fe trong khng kh thu c m(g) hn hp X: FeO, Fe2O3, Fe3O4 , Fe d.
Hn hp X cn va ht 255ml dd HNO3 2M thu c V lt kh NO2 (sn phm kh duy nht,
ktc). Xc nh m, V (S: 8,4 v 3,36 lt)
6/. Ho tan ht 4,431g hn hp gm Al v Mg trong HNO3 long thu c dd A v 1,568 lt
(ktc) hn hp hai kh u khng mu c khi lng 2,59g, trong c mt kh b ho nu
trong khng kh. Tnh s mol HNO3 tham gia phn ng. (S: 0,49)
7/.Oxi ho chm m g Fe ngoi khng kh thu c 12 g hn hp A gm FeO, Fe2O3, Fe3O4 v
Fe d. Ho tan A va bi 200ml dd HNO3 thu c 2,24 lt NO duy nht (ktc). X m v
CM ca HNO3 (S: 10,08g v 3,2M)
8/. Cho 3 kim loi Al, Fe, Cu vo 2 lt dd HNO3 phn ng va thu c 1,792 lt kh X
(ktc) gm N2 vag NO2 c t khi ca X so vi He l 9,25. X CM ca dd HNO3 ban u.
(S:0,28M)

9/. m g bt Fe trong khng kh thu c 3 g hn hp cht rn X: FeO, Fe2O3, Fe3O4 v Fe

d. Ho tan ht 3g X trong trong 500 ml dd HNO3 thu c 0,56 lt NO duy nht (ktc). Tnh
CM ca dd HNO3 dng (0,32 M)
Dng 3: Xc nh sn phm kh v tnh lng kh to thnh
1/. t chy 5,6g bt Fe trong bnh oxi thu c 7,36g hn hp A gmFe2O3, Fe3O4 v mt
phn Fe cn li. Ho tan hon ton hn hp A bng dd HNO3 thu c V lt kh B: NO v
NO2 c t khi so vi H2 l 19. X V( S: 0,896 lt)
2/. Hn hp X gm hai kim loi A, B c ho tr khng i, khng tan trong nc, ng trc
Cu trong dy in ho. Ly m(g) X cho tan vo dd CuSO4 d, ton b lng Cu thu c cho
tan vo HNO3 d nhn c 1,12 lt NO (duy nht ktc). Ly m (g) X phn ng vi HNO3
d thu c V lt N2 (duy nht ktc). X V (S: 0,336 lt)
3/.Ho tan 5,95g hn hp Zn v Al c t l mol 1: 2 bng dd HNO3 long d thu c 0,896
lt mt sn phm kh duy nht cha N2 . Xc nh X (S: N2)
Dng 4: Bi tp tng hp khc
1/.Ho tan 7,68g Cu vo 150ml dd hn hp HNO3 0,8M v H2SO4 0,4M thu c dd A v V
lt kh NO duy nht (ktc).
a) Xc nh V (S: 1,344 lt)
b) C cn dd A thu c bao nhiu g mui khan (S: 17,16g)
2/.Hn hp X gm Fe v kim loi M c ho tr khng i. Ho tan ht 3,61g X trong dd HCl
thu c 2,128 lt H2 (ktc). Nu ho tan ht 3,61g X vo dd HNO3 thu c 1,792 lt NO duy
nht (ktc). Xc nh kim loi M (S: Al).
3/. Cho lung kh CO i qua ng s ng m(g) Fe2O3 nhit cao mt thi gian ngi ta
thu c 6,72g hn hp A gm 4 cht rn khc nhau. em ho tan hn hp ny vo dd HNO3
d thy to thnh 0,448 lt kh B duy nht c t khi so vi H2 l 15. Xc nh m (s: 7,2g)
4/. Nung m (g) Fe trong khng kh, sau mt thi gian thu c 104,8g hn hp rn A gm Fe,
FeO, Fe3O4, Fe2O3. Ho tan hon ton A trong HNO3 d thu c dd B v 12,096 lt hn hp
kh NO v NO2 (ktc) c t khi so vi He l 10,167. X m (S: 78,4g)
5/. Hn hp A gm: Cu v Fe c t l khi lng mCu : mFe = 7 : 3. Ly m g A cho phn ng
vi dd HNO3 thy c 44,1g HNO3 phn ng thu c 0,75m (g) cht rn X, dd Y v 5,6 lt
kh Z (ktc) gm NO v NO2.
a) X m (50,4g)
b) C cn dd Y thu c bao nhiu g mui khan (S: 40,5g)
6/. Ho tan a g hn hp X : Mg, Al vo axit HNO3 c ngui d thu c 0,336 lt NO2 (00C,
2 atm). Cng a g hn hp trn khhi ho tan trong HNO3 long d thu c 0,168 lt NO (00C,
4 atm). X a (S: 0,9).
7/. Ho tan hon ton m g Al vo dd HNO3 long, d thu c 1,344 lt kh N2 (ktc) v dd X.
Thm NaOH d vo dd X v un si th thu c 1,344 lt kh NH3. X m (S: 9,72g)
8/. Hn hp X: FeS2 v MS c s mol bng nhau (M l kim loi ho tr II). Cho 6,51 g X tc
dng hon ton vi lng d dd HNO3 un nng thu c dd A1 v 13,216 lt (ktc) hn hp
kh A2 gm: NO v NO2 c khi lng 26,34g. Xc inh M (S:Zn)