Tai Lieu On Thi Dai Hoc Mon Hoa Nam 2012MatdanhLHVHCCHM

TI LIU N THI I HC MN HA NM 2012 Mn: HA HC; Khi A, B
Matdanh_LHVH_CCHM
CC CU N TP THI TH I HC NM 2012 Cu 1: Cc ng phn ng vi cng thc phn t C8H8O2 (u l dn xut ca benzen) tc dng vi NaOH thu c mui v ancol l: A. 3 B. 2 C. 7 D. 4 Cu 2: Cc ng phn ng vi cng thc phn t C9H8O2 (u l dn xut ca benzen) tc dng vi NaOH d cho hai mui v cng hp vi Br 2 theo t l 1 : 1. A. 1 B. 3 C. 5 D. 6 Cu 3: Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,75M thu c 0,45 mol mui v 0,15 mol ancol. Lng NaOH d c th trung ha ht 0,75 lt dung dch HCl 0,4M. Cng thc tng qut ca A l: A. RCOOR B. (RCOO)2R C. (RCOO)3R D. R(COOR)3 Cu 4: Cho 32,7 gam cht hu c X ch cha mt loi nhm chc tc dng vi 1,5 lt dung dch NaOH 0,5M thu c 36,9 gam mui v 0,15 mol ancol. Lng NaOH d c th trung ha ht 0,5 lt dung dch HCl 0,6M. Cng thc cu to thu gn ca X l: A. CH3COOC2H5 B. (CH3COO)2C2H4 C. (CH3COO)3C3H5 D. C3H5(COOCH3)3 Cu 5: un nng axit axetic vi ancol isoamylic (CH3)2CH-CH2-CH2OH c H2SO4 c xc tc thu c isoamylic axetat (du chui). Lng du chui thu c t 198,525 gam axit axetic un nng vi 300 gam ancol isoamylic (bit hiu sut phn ng l 68%) l: A. 146,25 gam B. 292,49 gam C. 438,75 gam D. 238,50 gam Cu 6: un mt lng d axit axetic v 20,7 gam ancol etylic (c axit H 2SO4) c lm xc tc). n khi phn ng dng li thu c 16,5 gam este. Hiu sut ca phn ng este ha l: A. 75% B. 62,5% C. 60% D. 41,67% Cu 7: Thc hin phn ng este ha hn hp gm 322,5 gam axit metacrylic v 150 gam ancol metylic vi hiu sut t 60%. Khi lng metyl metacrylat thu c l: A. 187,5 gam B. 225 gam C. 262,5 gam D. 300 gam Cu 8: X phng ha hon ton 14,55 gam hn hp hai este n chc X, Y cn 150ml dung dch NaOH 1,5M. Sau phn ng c cn dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht. Cng thc cu to thu gn ca hai este l: A. HCOOCH3 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H5COOCH3 v C2H5COOC2H5 D. C3H7COOCH3 v C4H9COOC2H5 Cu 9: Cho 52,8 gam hn hp gm hai este no, n chc l ng phn ca nhau c t khi hi so vi H2 bng 44, tc dng vi 2 lt dung dch NaOH 0,6M, ri c cn dung dch va thu c cn li 66,9 gam cht rn B. Cng thc cu to thu gn ca hai este l: A. HCOOC2H5 v CH3COOCH3 B. C2H5COOCH3 v CH3COOC2H5 C. HCOOC3H7 v CH3COOC2H5 D. HCOOC3H7 v CH3COOCH3 Cu 10: Este X c cng thc phn t C7H12O4, khi cho 51,9 gam X tc dng vi 300 gam dung dch NaOH 4% th thu c mt ancol hai chc Y v 26,7 gam hn hp hai mui. Cng thc cu to thu gn ca X l: A. HCOO-(CH2)4-OOCH3 B. CH3COO-(CH2)3-OOCCH3 C. C2H5COO-(CH2)3-OOCH D. CH3COO-(CH2)2-OOCC2H5 Cu 11: Cho 2,64 gam mt este ca axit cacboxylic n chc v ancol n chc phn ng va ht vi 60ml dung dch NaOH 0,5M thu c cht X v cht Y. t chy hon ton m gam cht Y cho 3,96 gam CO2 v 2,16 gam H2O. Cng thc cu to ca este l: A. CH3COOCH2CH2CH3 B. CH2=CHCOOCH3 C. CH3COOCH=CH3 D. HCOOCH2CH2CH3
ng bao gi nhng tht vng ca ngy hm qua che m nhng gic m rc sng ca ngy mai
Trang 1 - Cunconhocmai
Cu 12: Hp cht hu c X cha mt loi nhm chc c cng thc phn t C8H14O4. Khi thy phn X trong dung dch NaOH thu c mt mui v hn hp hai ancol A, B. Phn t ancol B c s nguyn t C gp i phn t ancol A. Khi un nng vi H 2SO4 c iu kin thch hp, A cho mt olefin v B cho ba olefin ng phn. Cng thc thu gn ca X l: A. CH3OOCCH2CH2COOCH2CH3 B. C2H5OCO-COOCH2CH2CH3 C. HOCOCH2CH2CH2CH2COOCH3 D. C2H5OCO-COOCH2CH(CH3)2 Cu 13: Thy phn cht X c cng thc phn t C8H14O5 thu c ancol etylic v cht hu c Y. Cho bit s mol X bng s mol ancol etylic v bng 1/2 s mol Y. Y c iu ch trc tip t glucoz bng phn ng ln men, trng ngng Y thu c mt loi polime. Cng thc cu to thu gn ca X l: A. C2H5OCOCH(OH)CH2COOC2H5 B. CH2(OH)CH2COOCH2CH2COOC2H5 B. C2H5OCOCH-COOC2H5 D. CH3CH(OH)COOCHCOOC2H5 CH2OH Cu 14: Hn hp X gm hai este n chc mch h l ng phn ca nhau. Cho m gam X tc dng va vi 100ml NaOH 1M thu c mt mui ca axit cacboxylic v hn hp hai ancol. Mt khc nu t chy hon ton m gam X th thu c 8,96 lt CO 2 ( iu kin tiu chun) v 7,2 gam H2O. Cng thc cu to ca hai este l: A. CH3COOCH2CH2CH3 v CH3COOCH(CH3)2 B. HCOOCH(CH3)2 v HCOOCH2CH2CH3 C. CH3COOCH2CH2CH2CH3 v CH3COOCH(CH3)CH2CH3 D. CH3COOCH(CH3)C2H5 v CH3COOCH(C2H5)2 Cu 15: Hn hp X gm hai cht hu c A v B ch cha mt loi nhm chc. Cho m gam X tc dng ht vi NaOH thu c mt mui ca axit hu c n chc v hn hp hai ancol, tch nc hon ton hai ancol ny iu kin thch hp ch thu c mt anken lm mt mu 24 gam Br 2. Bit A, B cha khng qu 4 nguyn t C trong phn t. Gi tr ca m: A. 11,1 B. 22,2 C. 13,2 D. 26,4 0 Cu 16: Trn 100ml axit axetic 1M nguyn cht vi 10ml ru etylic 46 (D = 0,8 gam/ml). un nng hn hp ny sau mt thi gian ri cho tc dng vi Na d th thy c c 3,584 lt hiro ( iu kin tiu chun). Khi lng este sinh ra l: A. 14,08 B. 28,16 C. 9,48 D. 1,76 Cu 17: Mt loi m cha 40% olein, 20% panmitin v 40% stearin. X phng ha hon ton m gam m trn thu c 138 gam glixerol. Gi tr ca m l: A. 1209,00 B. 1304,27 C. 1326,00 D. 1335,00 Cu 18: Hp cht hu c mch h X l este n chc, khng no, c mt ni i gia cacbon vi cacbon. Trong phn t X c s nguyn t cacbon ng vi s nguyn t cacbon ca hirocacbon iu kin thng th kh. un X vi dung dch NaOH c mui X 1 v cht hu c X2, em X2 tc dng vi nc clo c cht hu c X3 c kh nng ha tan Cu(OH)2. X c tn l: A. metyl acrylat B. metyl metacrylat C. anlyl fomat D. vinyl axetat Cu 19: X l hn hp hai este ca cng mt ancol no, n chc v hai axit no, n chc ng ng k tip. t chy hon ton 0,1 mol X cn 6,16 lt O 2 ( iu kin tiu chun). un nng 0,1 mol X vi 50 gam dung dch NaOH 20% n phn ng hon ton, ri c cn dung dch sau phn ng c m gam cht rn. Gi tr ca m l: A. 13,5 B. 7,5 C. 15 D. 37,5 Cu 20: Mt loi m cha 70% olein (glixerol triolein), v 30% stearin (glixerol tristearat) v khi lng. Khi lng x phng Na thu c khi x phng ha hon ton 100 kg m l: A. 90,8 kg B. 68,0 kg C. 103,16 kg D. 110,5 kg Cu 21: x phng ha hon ton 3,28 gam hn hp hai este c to ra t hai axit n chc, mch h v mt ancol n chc, mch h cn dng 500ml dung dch NaOH 0,1M. Khi lng mui thu c sau phn ng x phng ha l: A. 6,38 gam B. 3,68 gam C. 5,28 gam D. 2,98 gam
Cu 22: Chia m gam hn hp X gm hai ancol A, B (MA < MB) thnh hai phn bng nhau. Phn 1 cho tc dng vi Na (d) thu c 2,8 lt H2 ( iu kin tiu chun). Phn 2 em oxi ha hon ton bi CuO un nng c hai anehit tng ng. t chy hon ton hai anehit ny thu c 15,68 lt CO2 ( iu kin tiu chun) v 12,6 gam H2O. Mt khc nu cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3 th thu c 75,6 gam kt ta. Cng thc ca ancol B l: A. C5H11OH B. C2H5OH C. C3H7OH D. C4H9OH Cu 23: Mt hn hp gm hai este n chc, c ba nguyn t C, H, O. Ly 0,25 mol este ny phn ng vi 250ml dung dch 2M un nng th thu c mt anehit no mch h v 28,6 gam hai mui hu c. Cho bit khi lng mui ny bng 4,4655 ln khi lng mui kia. phn ng ht vi NaOH cn d cn dng 100ml dung dch HCl 1M, Phn trm khi lng ca oxi trong anehit l 27,58%. Cng thc phn t ca hai este l: A. C4H6O2 v C7H6O2 B. C3H4O2 v C8H8O2 C. C2H2O2 v C4H8O2 D. C5H8O2 v C6H12O2 Cu 24: Hai cht hu c A, B cha C, H, O u c 53,33% oxi theo khi lng. Khi lng phn t ca B gp 1,5 ln khi lng phan t ca A. t chy ht 0,04 mol Hn hp A, B cn 0,1 mol oxi. Mt khc, khi cho s mol bng nhau ca A v B tc dng vi lng d dung dch NaOH th khi lng to ra t B gp 1,1952 ln khi lng mui to thnh t A. Bit cc phn ng xy ra hon ton. Tm cng thc phn t ca A v B l: A. C4H8O2 v C6H12O3 B. C3H6O2 v C6H7O2 C. C2H4O2 v C3H6O3 D. C3H4O2 v C4H8O4 Cu 25: A l axit hu c mch thng, B l ancol n chc bc mt c nhnh. Khi trung ha hon ton A th s mol NaOH cn trung ha gp i s mol A. Khi t chy B to ra CO 2 v H2O c t s mol tng ng l 4 : 5. Khi cho 0,1 mol A tc dng vi B hiu sut 73,5% thu c 14,847 gam cht hu c E. Gi tn A. A. axit oxalic B. axit aipic C. axit metacrylic D. Khng c p n no Cu 26: A l axit hu c mch thng, B l ancol n chc bc mt c nhnh. Khi trung ha hon ton A th s mol NaOH cn trung ha gp i s mol A. Khi t chy B to ra CO 2 v H2O c t s mol tng ng l 4 : 5. Khi cho 0,1 mol A tc dng vi B hiu sut 73,5% thu c 14,847 gam cht hu c E. Tnh khi lng B. A. 10,31 gam B. 6,615 gam C. 14,33 gam D. Khng c p n no Cu 27: A l axit hu c mch thng, B l ancol n chc bc mt c nhnh. Khi trung ha hon ton A th s mol NaOH cn trung ha gp i s mol A. Khi t chy B to ra CO 2 v H2O c t s mol tng ng l 4 : 5. Khi cho 0,1 mol A tc dng vi B hiu sut 73,5% thu c 14,847 gam cht hu c E. Tnh khi lng A. A. 5,439 gam B. 10,878 gam C. 12,76 gam D. Khng c p n no Cu 28: Cht A cha C, H, O c khi lng phn t bng 74. Xc nh cng thc phn t ca A, bit. - A tc dng vi dung dch NaOH v dung dch AgNO3 trong NH3. - Khi t chy 7,4 gam A thy th tch CO2 thu c vt qu 4,7 lt ( iu kin tiu chun). A. C2H2O3 B. C3H6O2 C. C4H10O D. Tt c u ng Cu 29: Cho xenluloz phn ng vi anhirit axetic (c H2SO4 c lm xc tc) thu c 11,1 gam hn hp X (gm: xenluloz trixetat, xenluloz iaxetat) v 6,6 gam CH 3COOH. Thnh phn phn trm theo khi lng ca xenluloz triaxetat v xenluloz iaxetat trong X ln lt l: A. 77% v 23% B. 77,84% v 22,16% C. 76,84% v 23,16% D. 70% v 30% Cu 30: C bao nhiu ng phn l dn xut benzen, c cng thc phn t C8H8O2. C kh nng tham gia phn ng trng gng v tc dng c vi natri kim loi. A. 16 B. 15 C. 14 D. 17
ng bao gi nhng tht vng ca ngy hm qua che m nhng gic m rc sang ca ngy mai
Cu 31: Khi thc hin phn ng este ha 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 75% (tnh theo ancol) khi tin hnh este ha 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ha thc hin cng nhit ). A. 2,14 B. 0,482 C. 0,762 D. 0,295 Cu 32: Trong mt bnh kn cha hi este X n no, mch h v O2 (s mol O2 gp 1,2 ln s mol cn cho phn ng chy) 139,90C, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v 270C, p sut trong bnh lc ny l 0,4162 atm. S ng phn ca X c th lm mt mu nc Br2 l: A. 4 B. 2 C. 3 D. 1 Cu 33: S ng phn cu to ng vi cng thc phn t C5H8O2 mch h, khng tc dng vi Na, to kt ta gch vi Cu(OH)2/NaOH d un nng l: A. 6 B. 4 C. 9 D. 8 Cu 34: Cho 7,04 gam este n chc X tc dng hon ton vi 500ml dung dch gm KOH 0,2M v NaOH 0,1M. C cn dung dch thu c 12,08 gam hn hp cht rn khan. Cng thc ca X l: A. C2H5COOCH3 B. CH3COOCH3 C. HCOOC2H5 D. C3H7COOC2H5 Cu 35: S ng phn este ng vi cng thc phn t C5H10O2 l: A. 5 B. 6 C. 9 D. 4 Cu 36: Cho 0,1 mol cht hu c A (c s C b hn 6) tc dng va vi 0,2 mol KOH thu c H2O v hn hp mui. t chy hon ton hn hp mui thu c H 2O, K2CO3 v 13,2 gam CO2. Cng thc phn t ca A c th l: A. C3H4O4 B. C4H6O4 C. C4H8O2 D. C5H8O4 Cu 37: Thy phn hon ton 0,1 mol cht hu c A c cng thc phn t l C xHyOz trong mi trng axit. S mol H2O tham gia trong phn ng l 0,2 mol. Sn phm thu c gm hai cht hu c B v C. B c th tc dng vi Na, C va tc dng vi Na va tc dng vi NaOH. Cng thc phn t ca B v C ln lt l C2H6O v C2H4O3. S mol B bng s mol A, s mol C bng s mol H2O. Tm cng thc phn t ca A. A. C6H10O6 B. C6H12O3 C. C4H6O3 D. C6H10O5 Cu 38: Hn hp X gm axit CH3COOH v axit CH2=CH-COOH (t l mol 2 : 1). Ly 12,8 gam hn hp X cho tc dng vi 18 gam C3H7OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut cc phn ng este ha u bng 60%). Gi tr ca m l: A. 12,72 gam B. 18,36 gam C. 19,08 gam D. 21,2 gam Cu 39: Chia hn hp gm hai este mch h (cha C, H, O) l ng phn ca nhau thnh hai phn bng nhau. Cho bay hi hon ton phn th nht thu c mt th tch hi bng th tch ca 0,96 gam O2 trong cng iu kin v nhit v p sut. em x phng ha hon ton phn th hai bng 400ml dung dch NaOH 0,1M ri tin hnh chng ct th thu c 1,1 gam hn hp hai ancol. C cn dung dch cn li sau chng ct th thu c 2,14 gam cht rn. Cng thc phn t ca hai este l: A. C3H6O2 B. C4H8O2 C. C6H10O4 D. C5H10O2 Cu 40: Cho hn hp X gm hai este A, B n chc to bi hai axit n chc v C 2H5OH (MA < MB). Cho X tc dng vi 0,45 mol NaOH thu c 0,35 mol C2H5OH v dung dch D. C cn dung dch D thu c 31,7 gam cht rn. Trong X, nA : nB = 4 : 3. Cng thc cu to ca A, B l: A. HCOOC2H5; CH2=CH-COOC2H5 B. CH3COOC2H5; CH3-CH2-COO-C2H5 C. HCOOC2H5; CH3-COO-C2H5 D. CH3CH2-COOC2H5; CH2=CH-COOC2H5 Cu 41: Thy phn hon ton 0,15 mol este A bng 0,25 mol NaOH. C cn dung dch sau phn ng thu c 14,2 gam cht rn khan. t chy hon ton 0,1 mol A ri cho sn phm chy ln lt qua bnh 1 cha P2O5 v bnh 2 cha dung dch Ba(OH)2. Bnh 2 thu c 19,7 gam kt ta, thm tip NaOH d vo bnh 2 thu thm 19,7 gam kt ta na. Cng thc cu to ca A l: A. C2H5-COOCH3 B. HCOOC2H5 C. CH3COOCH3 D. HCOOC3H5 Cu 42: Khi thc hin phn ng este ha 1 mol CH3COOH vi 1 mol C2H5OH, hiu sut phn ng t 66,67%. Cng trong iu kin nhit nh trn t hiu sut 80% (tnh theo ancol) cn tin hnh este ha 1 mol axit vi bao nhiu mol ancol ?. A. 0,625 mol B. 0,875 mol C. 1,25 mol D. 0,9 mol
Cu 43: Cho hn hp X gm hai este n chc A, B to bi axit n chc v mt ancol khng no n gin nht. Cho 0,7 mol X (0,4 mol A v 0,3 mol B) tc dng va vi NaOH thu c 55,4 gam hn hp mui. Bit MA < MB. Khi lng mi cht trong hn hp X l: A. 29,6 gam v 40,4 gam B. 31,4 gam v 36,6 gam C. 33,6 gam v 34,4 gam D. 33,6 gam v 40 gam Cu 44: Thy phn hon ton 4,4 gam este n chc A bng 25 gam dung dch NaOH 10%. Lng NaOH ny c d 25% so vi l thuyt. Sn phm sau phn ng c mt ancol cha 50% oxi v khi lng trong phn t. Cng thc cu to ca A l: A. HCOOC3H7 B. CH3COOCH3 C. C2H5COOCH3 D. CH3COOC2H5 Cu 45: phn ng vi 100 gam lipit c ch s axit bng 7 phi dng 17,92 gam KOH. Tnh lng mui thu c l: A. 98,25 gam B. 109,813 gam C. 108,265 gam D. Kt qu khc Cu 46: Cho este n chc E tc dng va vi NaOH thu c 12,3 gam mui v 0,15 mol ancol. t chy hon ton ancol ny ri hp th sn phm vo bnh cha 3 lt dung dch Ba(OH) 2 0,125M thu c 59,1 gam kt ta. Cng thc cu to E c th. A. CH3COOC2H5 hay CH3COOC3H7 B. HCOOCH3 hay HCOOC4H9 C. CH3COOC2H5 hay CH3COOC4H9 D. C2H5COOCH3 hay C2H5COOC3H7 Cu 47: Trong mt bnh kn cha hi cht hu c X (l ng ng ca metyl acrylat) v O 2 (s mol O2 gp i s mol O2 cn cho phn ng chy) 1670C, p sut trong bnh 1,3 atm. t chy hon ton X ri a v nhit ban u, p sut trong bnh lc ny l 1,5 atm. Cng thc phn t ca X l: A. C5H8O2 B. C6H10O2 C. C4H6O2 D. C4H8O2 Cu 48: Hn hp E gm mt ancol n chc X, mt axit n chc Y v mt este Z to bi X v Y. Ly 0,15 mol hn hp E cho phn ng va vi dung dch KOH un nng thu c p gam ancol X. Ha hi p gam X ri dn qua CuO un nng thu c anehit F. Cho ton b F tc dng ht vi AgNO3/NH3 d un nng thu c 0,4 mol Ag. Gi tr ca p l: A. 3,2 B. 4,6 C. 6,4 D. 9,2 Cu 49: Khi lng x phng cha 72% mui natri sn sut c t 2,5 tn cht bo trung tnh c ch s x phng ha bng 196 l: A. 5537,8 kg B. 3758,5 kg C. 3558,7 kg D. 3586 kg Cu 50: X phng ha hon ton a gam cht bo c ch s axit bng 12,6 ch s x phng ha bng 264,6 to ra 1570,425 gam mui natri ca axit bo. Gi tr ca a l: A. 1650 B. 1500 C. 1480 D. 1400 Cu 51: Cho xeluloz phn ng vi anhirit axetic (c H2SO4 c lm xc tc) thu c 19,32 gam hn hp X gm xenluloz triaxetat, xenluloz iaxetat v 11,4 gam axit axetic. Thnh phn phn trm theo khi lng ca xenluloz triaxetat trong X l: A. 74,53% B. 29,81% C. 63,66% D. 25,47% Cu 52: Cho xeluloz phn ng vi 2 mol axit nitric (c H2SO4 c lm xc tc thu c 333 gam hn hp X gm xenluloz mononitrat v xenluloz initrat. Thnh phn phn trm theo khi lng ca xenluloz initrat trong hn hp X l: A. 31,1% B. 62,16% C. 75,68% D. 37,84% Cu 53: C 0,15 mol hn hp hai este n chc phn ng va vi 0,25 mol NaOH v to thnh hn hp hai mui v mt ru c khi lng tng ng l 23,9 gam v 2,3 gam. Vy hai mui l: A. CH3COOC6H5 v CH3COOC2H5 B. CH3COOC6H5 v CH3COOCH3 C. HCOOC6H5 v CH3COOH D. HCOOC6H5 v HCOOH Cu 54: 0,05 mol este E phn ng va 100 gam dung dch NaOH 6%, ta thu c 10,2 gam mui v 4,6 ru. Bit ru hoc axit to thnh E n chc. Vy cng thc cu to ca E l: A. CH3COO(-CH2-)2OOCH3 B. (CH3COO)2C3H6 C. (HCOO)3C3H5 D. (C3H5COO)3CH
Cu 55: X phng ha este X n chc no ch thu c mt cht hu c Y cha Na. C cn, sau thm vi ti xt vo ri nung nhit cao c mt ru C v mt mui v c. t chy hon ton ru ny c CO2 v hi nc theo t l v th tch l 2/3. Tm cng thc phn t ca este. A. C4H6O2 B. C3H4O2 C. C5H8O2 D. C6H10O2 Cu 56: x phng ha 10 kg cht bo c ch s axit bng 5, ngi ta un cht bo vi dung dch cha 1,420kg NaOH. Sau khi phn ng hon ton, mun trung ha hn hp cn 500ml HCl 1M. Tnh khi lng glixerin v khi lng x phng ha nguyn cht to ra. A. 1035 gam v 10342,5 gam B. 2070 gam v 20685 gam C. 517,5 gam v 5171,25 gam D. 690 gam v 6895 gam Cu 57: Thy phn hon ton 0,1 mol este X (ch cha chc este) cn va 100 gam dung dch NaOH 12% thu c 20,4 gam mui axit hu c v 9,2 gam ru. Cng thc phn t ca axit to nn este (bit ru hoc axit l n chc) l: A. HCOOH B. CH3COOH C. C2H3COOH D. C2H5COOH Cu 58: S ng phn este c cha nhn thm c cng cng thc phn t C8H8O2 l: A. 4 B. 5 C. 6 D. 7 Cu 59: Cho m gam mt este Y n chc (khng c chc khc) tc dng vi dung dch NaOH (d). Sau khi kt thc phn ng ngi ta cho thm 100ml dung dch HCl 1M th trung ha va lng NaOH d. em chng ct dung dch sau khi trung ha th c hi ca ru Z v cn li 15,25 gam mui khan. Dn ton b hi ca ru Z qua CuO nung nng (d) sau khi phn ng hon ton c cht hu c Q. Cho ton b Q tc dng vi lng d AgNO 3 (NH3) th thu c 43,2 gam Ag. Cng thc cu to ca Y l: A. CH3COOCH3 B. C2H5COOCH3 C. C2H3COOCH3 D. CH3COOC2H5 Cu 60: Khi thy phn 0,01 mol este X (ch cha chc este) cn va 1,2 gam NaOH thu c ru a chc v mt mui ca axit n chc. Mt khc thy phn 6,35 gam X cn 3 gam NaOH v c 7,05 gam mui. Este X l: A. (C2H3COO)3C3H5 B. (CH3COO)3C3H5 C. (HCOO)3C3H5 D. (C2H5COO)3C3H5 Cu 61: S cc cht ng phn c nhn thm c cng cng thc phn t C8H8O2 khi tc dng vi dung dch NaOH d to ra hai mui v nc l: A. 2 B. 3 C. 4 D. 5 Cu 62: Hn hp gm hai este ng phn u c to ra t axit no n chc v ru n chc. Trong cng iu kin 1 lt hi hn hp X nng bng 2 ln 1 lt CO 2. Khi thy phn 35,2 gam hn hp X bng 4 lt dung dch NaOH 0,2M sau c cn th c 44,6 gam cht rn khan. Cng thc ca hai este trong X l: A. C2H5COOCH3 v CH3COOC2H5 B. HCOOC3H7 v CH3COOC2H5 C. HCOOC3H7 v C2H5COOCH3 D. Ch c B, C ng Cu 63: 0,01 mol este X (Ch cha chc este) tc dng va vi 20ml dung dch NaOH 1M to sn phm ch c mt ru v mt mui c s mol bng nhau. Mt khc khi x phng ha 1,29 gam este X cn va 60ml dung dch KOH 0,25M v thu c 1,665 gam mui. Este X c cng thc l: A. (COO)2C2H4 B. CH2(COO)2C2H4 C. C2H4(COO)2C2H4 D. C4H8(COO)2C2H4 Cu 64: t chy hon ton 1,46 gam cht X gm c C, H, O thu c 1,344 lt kh CO2 ( iu kin tiu chun) v 0,90 gam H2O. T khi hi ca X so vi hiro bng 73. Bit khi thy phn 0,1 mol X bng dung dch KOH, ta thu c 0,2 mol ru etylic v 0,1 mol mui Y. Cht X c cng thc cu to l: A. CH3COOC2H5 B. HCOOC2H5 C. H2C COOC2H5 D. COOC2H5 COOC2H5 COOC2H5 Cu 65: Cho hn hp X gm mt ru n chc no v mt ru n cha phn t c mt lin kt i, c khi lng m gam. Khi np m gam hn hp vo mt bnh kn Y dung tch 6 lt v cho X bay hi 136,50C. Khi X bay hi hon ton th p sut trong bnh l 0,28 atm. Nu cho m gam X este ha vi 45 gam axit axetic th hiu sut phn ng t h%. Tng khi lng este thu c theo m v h l: A. (2m + 4,2)h% B. (1,5m + 3,15)h% C. (m + 2,1)h% D. (3m + 3,5)h%
Cu 66: Mt hn hp gm hai este u n chc, c ba nguyn t C, H, O. Ly 0,25 mol hai este ny phn ng vi 250ml dung dch NaOH 2M un nng th thu c mt anehit no, mch h v 25,6 gam hai mui hu c. Cho bit khi lng mui ny bng 1,4655 ln khi lng mui kia. phn ng ht vi NaOH cn d cn dng 150ml dung dch HCl 1M. Phn trm khi lng ca oxi trong anehit l 27,58%. Xc nh cng thc cu to ca hai este. A. CH3COOCH=CH-CH3 v HCOOC6H5 B. HCOO-CH=CH-CH2 v HCOO-C6H5 C. HCOO-CH=CH-CH2 v CH3COOC6H5 D. C2H5COOCH=CH2 v CH3COOC6H5 Cu 67: Cho 2,76 gam cht hu c A cha C, H, O tc dng vi dung dch NaOH va , sau chng kh th phn bay hi ch c nc, phn cht rn khan cn li cha hai mui ca natri chim khi lng 4,44 gam. Nung nng hai mui ny trong oxi d, sau khi phn ng hon ton, ta thu c 3,18 gam Na2CO3, 2,464 lt kh CO2 (iu kin tiu chun) v 0,9 gam H2O. Tm cng thc phn t A. A. C7H6O3 B. C8H8O3 C. C8H8O2 D. C7H6O2 Cu 68: X phng ha hon ton 8,8 gam este bng NaOH thu c mui A v ru B. Khi nung ton b mui A vi O2 thu c 5,3 gam Na2CO3, kh CO2 v H2O. Chng ct ly ru B khan. Cho lng ru B tc dng ht vi Na thu c 6,8 gam mui v kh H 2 c th tch bng 1/2 th tch hi ru B phn ng (o cng iu kin nhit v p sut). Tm cng thc cu to ca este. A. CH3COOC2H5 B. C2H5COOC2H5 C. C2H3COOCH3 D. HCOOC3H7 Cu 69: Mt este C c cng thc l R-COOR (vi R c 6 nguyn t C) c t khi hi i vi O 2 nh hn 4,5. Khi x phng ha X bng dung dch NaOH ta thu c hai mui c t l khi lng l 1,4146. Tm cng thc cu to ca X. A. C2H5-COO-C6H5 B. CH3-COO-C6H5 C. C3H7COOC6H5 D. C4H9COOC6H5 Cu 70: T 10 kg go np (c 80% tinh bt), khi ln men s thu c bao nhiu lt cn 96 0 ?. Bit rng hiu sut ca qu trnh ln men t 80% v cn 960 c khi lng ring D = 0,807 g/ml. A. 4,7 lt B. 4,5 lt C. 7,4 lt D. 5,4 lt Cu 71: Ngi ta dng mt tn khoai cha 75% bt v bt ny cha 20% nc lm ru. Khi lng ring ca ru l 0,8 g.ml. Tnh th tch ru 95 0 iu ch c. A. 336 lt B. 448 lt C. 672 lt D. 224 lt Cu 72: Hn hp A gm glucoz v saccaroz. Thy phn ht 7,02 gam hn hp A trong mi trng axit thnh dung dch B. Trung ha ht axit trong dung dch B ri cho tc dng vi lng d dung dch AgNO3/NH3 th thu c 6,48 gam Ag kt ta. Phn trm khi lng saccaroz trong hn hp A l: A. 57,4% B. 48,7% C. 24,35% D. 12,17% Cu 73: t chy hon ton 13,60 gam cht hu c E n chc (thnh phn C, H, O) to thnh 17,92 lt kh CO2 (iu kin tiu chun) v 7,20 gam H2O. Mt khc, cng ly lng cht E nh trn un nng vi 200ml dung dch KOH 1M, sau khi phn ng xy ra hon ton c cn dung dch, lm kh sn phm thu c mt ancol v mt vt rn cn nng 21,60 gam. Xc nh cng thc phn t ca E, bit mui to thnh ca phn ng x phng ha E l mt cht thm. A. C8H8O3 B. C8H8O2 C. C9H10O2 D. C9H10O3 Cu 74: Mt hn hp gm hai axit cacboxylic n chc. Cho 10,6 gam hn hp tc dng va vi 100ml dung dch NaOH 2M. Mt khc, 10,6 gam hn hp hai axit tc dng vi 23 gam ancol etylic (xc tc H2SO4 c, un nng hn hp) to m gam hn hp hai este vi hiu sut mi phn ng u bng 80%. Gi tr ca m l A. 23,3 gam B. 20,3 gam C. 12,96 gam D. 10,96 gam Cu 75: Mt hn hp gm ancol etylic v mt cht ng ng ca ancol etylic. - Cho 3,90 gam hn hp tc dng vi natri d to 1,12 lt H2 ( iu kin tiu chun). - Cho 3,90 gam hn hp cho tc dng vi 30 gam CH3COOH (xc tc H2SO4 c, un nng) to m gam hn hp hai este vi hiu sut cc phn ng u bng 75% m gam l: A. 10,50 gam B. 9,50 gam C. 6,075 gam D. Khng xc nh c
Cu 76: Mt hn hp gm CH3COOH v C2H5OH. Thc nghim cho thy rng: - a gam hn hp tc dng va vi mt dung dch c cha 4 gam NaOH. - a gam hn hp khi tc dng ht bng mt kim loi kim gii phng 3,36 lt kh hiro ( iu kin tiu chun) - Khi un nng a gam hn hp trn c xc tc H2SO4 c to thnh m gam este vi hiu sut 80%. Gi tr ca m l: A. 9,44 B. 7,04 C. 6,50 D. 5,20 Cu 77: Cht hu c A (thnh phn C, H, O), phn t A cha mt loi nhm chc. Thc nghim cho thy 21,80 gam cht A tc dng va vi 0,3 mol NaOH to 24,60 gam mui ca mt axit hu c n chc v mt lng ancol. Lng ancol cho bay hi to mt th tch 2,24 lt ( iu kin tiu chun). Cu to cu to ca cht A l: A. (CH3COO)3C3H5 B. (CH3COO)2C2H4 C. (HCOO)3C3H5 D. CH3COOC2H5 Cu 78: Cht hu c E (thnh phn C, H, O) phn t c mt loi nhm chc. un nng 0,01 mol E trong dung dch NaOH d, sau phn ng thu c 1,34 gam mui ca mt axit cacboxylic v 0,64 gam mt ancol. Lm bay hi ht lng ancol thu c 448ml hi iu kin tiu chun. Cng thc cu to ca E l: A. CH3COOCH3 B. COO-CH3 C. H2C-COO-CH2 D. (CH3COO)3C3H5 COO-CH3 COO-CH2 Cu 79: un nng hn hp X gm 60,00 gam CH 3COOH, 46 gam C2H5OH v 9,80 gam H2SO4 (xc tc). Phn ng ha este xy ra khi t trng thi cn bng thu c hn hp B, trong B c 2/3 mol este etyl axetat. Phn trm khi lng ca este v ancol c trong B ln lt l: A. 50,65% v 13,24% B. 48,00% v 13,10% C. 13,10% v 50,91% D. 40,00% v 15,10% Cu 80: un nng hn hp A gm 1 mol CH3COOH, 1 mol C2H5OH (xc tc H2SO4 c). Khi cn bng hiu sut phn ng l 2/3. t hiu sut phn ng l 85% (tnh theo axit CH 3COOH), khi thc hin phn ng ha este 2 mol CH3COOH, s mol C2H5OH cn l (nhit phn ng nh nhau). A. 6,5 mol B. 5,11 mol C. 4,11 mol D. 3,75 mol Cu 81: T butan, cc cht v c, bng phng php ha hc iu ch c ankanal A (mch C ngn hn). T A iu ch hai cht tng ng ankanol B, ankanoic D, t B v D iu ch c este E tng ng. - Khi thc hin phn ng x phng ha ca m gam este E trong dung dch KOH va to m1 gam mui kali. Nu thc hin trong dung dch Ca(OH) 2 va to m2 gam mui canxi v m2 < m < m1. - Khi nung m1 gam mui kali vi hn hp KOH v CaO va to 2,24 lt kh G ( iu kin tiu chun). Khi lng m gam este l: A. 9,8 gam B. 8,8 gam C. 12,6 gam D. 7,4 gam Cu 82: 3,52 gam este E to bi mt axit cacboxylic no, n chc v mt ancol no, n chc (mch h) phn ng va ht vi 20 ml dung dch NaOH 2M thu c hai cht hu c A v B. t chy 1,2 gam cht B to 1,344 lt CO2 ( iu kin tiu chun) v 1,44 gam H2O. Khi oxi ha B t t bng CuO to sn phm hu c c phn ng trng bc. Cng thc cu to thu gn ca E l: A. CH3COOCH2CH3 B. CH3CH2COOCH3 C. HCOOCH=CH-CH3 D. HCOOCH2CH2CH3 Cu 83: Hn hp X gm axit axetic v mt ng ng. Thc nghim cho thy: - 10,6 gam hn hp X tc dng va vi 100ml dung dch NaOH 2M. - Cho 10,6 gam X tc dng vi 23 gam ancol etylic (xc tc H 2SO4, un nng) thu c m gam este, hiu sut cc phn ng u bng 80%. Gi tr ca m l: A. 20,20 B. 19,5 C. 14,90 D. 12,96 Cu 84: X phng ha hon ton 20 gam mt loi cht bo trung tnh cn 0,07 mol NaOH. Khi x phng ha ht 1 tn cht bo trn thu c m (kg) x phng 72%. Gi tr ca m l: A. 2034,5 B. 1620,20 C. 1434,26 D. 130
Cu 85: t chy hon ton 5,50 gam cht hu c X thu c 13,20 gam CO2 v 2,70 gam hi nc. Mt khc 5,50 gam X trung ha bng dung dch NaOH to 7,70 gam mui Y. Xc nh X c bao nhiu ng phn tha mn iu kin trn, bit rng M X MY = 44. A. 6 B. 5 C. 4 D. 3 Cu 86: Hn hp A gm hai anehit ng ng vi anehit fomic. Ly m gam A thc hin phn ng hiro ha (xc tc Ni, t0) thu c hn hp hai ancol. - 1/2 lng ancol cho tc dng vi Na d to 2,80 lt kh iu kin tiu chun. - 1/2 lng ancol c oxi ha ht to hn hp hai axit tng ng. Dng dung dch NaOH trung ha hai axit to 23,35 gam hn hp mui (hiu sut cc phn ng l 100%). Xc nh m gam. A. 1,6 B. 2,8 C. 5,6 D. 27,7 Cu 87: Hn hp M gm hai ancol no, n chc, mch h A v B: - Khi lm bay hi m gam M thu c mt th tch hi bng th tch ca 2,24 gam kh O 2 (cc V o cng iu kin nhit , p sut). - Khi ly m gam M tc dng ht bng Na to 1,232 lt kh nhng nu t chy th to 3,808 lt CO2 (cc V o cng iu kin tiu chun). - Bit s nhm chc OH ca B ln hn ca A l 1 n v. Gi tr ca m l: A. 6,82 B. 5,50 C. 4,28 D. 4,82 Cu 88: Hn hp M gm hai ancol no, n chc, mch h A v B: - Khi lm bay hi m gam M thu c mt th tch hi bng th tch ca 2,24 gam kh O 2 (cc V o cng iu kin nhit , p sut). - Khi ly m gam M tc dng ht bng Na to 1,232 lt kh nhng nu t chy th to 3,808 lt CO2 (cc V o cng iu kin tiu chun). - Bit s nhm chc OH ca B ln hn ca A l 1 n v. Cng thc phn t ca A v B ln lt l: A. C3H7OH v C2H4(OH)2 B. C2H5OH v C2H4(OH)2 C. C2H4(OH)2 v C3H5(OH)3 D. C3H6(OH)2 v C3H5(OH)3 Cu 89: Hn hp M gm hai axit hu c no, mch h A v B. S nhm chc ca B nhiu hn ca A 1 n v. - 0,03 mol hn hp M trung bnh va 100ml dung dch NaOH 0,5M. - t chy hon ton 0,03 mol hn hp M to 1,344 lt CO2 ( iu kin tiu chun). Cng thc cu to thu gn ca A, B ln lt l: A. HCOOH v HOOC-COOH B. CH3COOH v HOOC-COOH C. HCOOC-COOH v (HCOO)3C3H5 D. A, B, C u sai Cu 90: Hn hp M gm hai axit hu c no, mch h A v B. S nhm chc ca B nhiu hn ca A 1 n v. - 0,03 mol hn hp M trung bnh va 100ml dung dch NaOH 0,5M. - t chy hon ton 0,03 mol hn hp M to 1,344 lt CO2 ( iu kin tiu chun). Phn trm khi lng ca A v B trong M ln lt l: A. 50% v 50% B. 40% v 60% C. 30% v 70% D. 25% v 75% Cu 91: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp rn khan. Cng thc phn t cu X l: A. C2H5COOH B. CH3COOH C. HCOOH D. C3H7COOH Cu 92: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2N7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( iu kin tiu chun) gm hai kh (u lm xanh giy qu tm). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l: A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam
Cu 93: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l: A. 0,92 B. 0,32 C. 0,64 D. 0,46 Cu 94: un dung dch cha 10 gam NaOH vo 20 gam cht bo trung tnh, sau khi phn ng kt thc, ly 1/10 dung dch thu c em trung ha bng dung dch HCl 0,2M thy tn ht 95ml dung dch axit. Khi lng x phng thu c l: A. 21,86 gam B. 30 gam C. 26,18 gam D. 28,16 gam Cu 95: t chy hon ton m gam hn hp X gm CH4, C3H6 v C4H10 thu c 4,4 gam CO2 v 2,52 gam H2O. Gi tr ca m l: A. 1,48 gam B. 2,48 gam C. 14,8 gam D. 24,7 gam Cu 96: X l hiro cacbon mch h c cng thc phn t C7H8. Khi cho X tc dng vi dung dch AgNO3/NH3 th thu c mt cht Y c khi lng phn t ln hn X l 214 gam. X c cng thc cu to l: A. CH C-CH2-CH2-CH2-C CH B. CH C-CH2-CH=CH-CH=CH2 C. CH C-CH2-CH(CH3)-C CH D. A v C ng Cu 97: Thy phn 0,01 mol este ca mt ancol a chc vi mt axit n chc tiu tn ht 1,2 gam NaOH. Mt khc khi thy phn 6,35 gam este th tiu tn ht 3 gam NaOH v thu c 7,05 gam mui. Cng thc phn t v cng thc cu to ca este l: A. (CH3COO)3C3H5 B. (C2H3COO)3C3H5 C. C3H5(COOCH3)3 D. C3H5(COOC2H3)3 Cu 98: Mt hn hp gm metanal v etanal. Khi oxi ha m gam hn hp A thu c hn hp B gm hai axit hu c tng ng c t khi hi so vi A bng x. Bit hiu sut phn ng bng 100%. Khong gii hn ca x l: A. 1,33 < x < 1,53 B. 1,53 < x < 1,73 C. 1,36 < x < 1,46 D. 1,36 < x < 1,53 Cu 99: Cht A l este ca glixerin vi axit cacboxylic n chc mch h A1. un nng 5,45 gam A vi NaOH cho ti phn ng hon ton thu c 6,15 gam mui. Cng thc phn t ca A1 l: A. HCOOH B. CH3COOH C. C2H5COOH D. C3H7COOH Cu 100: Khi thy phn hon ton 0,05 mol este ca mt axit a chc vi mt ru n chc tiu tn ht 5,6 gam KOH. Mt khc, khi thy phn 5,475 gam este th tiu tn ht 4,2 gam KOH v thu c 6,225 gam mui. Vy cng thc cu to este l: A. (COOC2H5)2 B. (COOCH3)2 C. (COOCH2CH2CH3)2 D. Kt qu khc Cu 101: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trng dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag 2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l: A. 7,8 B. 8,8 C. 7,4 D. 9,2 Cu 102: t chy hon ton mt th tch kh thin nhin gm metan, eatn, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO 2 ( iu kin tiu chun) v 9,9 gam nc. Th tch khng kh ( iu kin tiu chun) nh nht cn dng t chy hon ton lng kh thin nhin trn l: A. 70,0 lt B. 78,4 lt C. 84,0 lt D. 56,0 lt Cu 103: Cho 4,48 lt hn hp X ( iu kin tiu chun) gm hai hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca hai hirocacbon l: A. C2H2 v C4H6 B. C2H2 v C4H8 C. C3H4 v C4H8 D. C2H2 v C3H8 Cu 104: Cho hn hp hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( iu kin tiu chun) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H 2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l: A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam
Cu 105: Hn hp kh A (iu kin tiu chun) gm hai olefin. t chy 7 th tch A cn 31 th tch oxi (iu kin tiu chun). Bit rng olefin cha nhiu C hn chim khong 40 50% th tch ca A. Cng thc phn t ca hai olefin l: A. C2H4 v C3H6 B. C2H4 v C4H8 C. C3H6 v C4H8 D. C3H6 v C5H10 Cu 106: Cho hn hp X gm metanol v hai axit k tip nhau trong dy ng ng ca axit axetic tc dng ht vi Na to 0,3 mol H2. Nu un nng X (xc tc H2SO4 c) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam este. Cng thc phn t cc axit trong hn hp X l: A. HCOOH; CH3COOH B. CH3COOH; C2H5COOH C. C2H5COOH; C3H7COOH D. C3H3COOH; C4H9COOH Cu 107: Hn hp X gm hai hirocacbon thuc cng dy ng ng, u th kh (iu kin tiu chun). t chy hon ton X cn 20,16 lt oxi (iu kin tiu chun) thu c 7,2 gam H2O v a lt CO2 (iu kin tiu chun). X tc dng vi dung dch AgNO3/NH3 d to ra 62,7 gam kt ta. Cng thc phn t ca hai hirocacbon l: A. C2H2 v C3H4 B. C2H2 v C4H6 C. C3H4 v C4H6 D. C4H6 v C5H8 Cu 108: Hn hp X gm C2H2, C2H6 v C3H6. t chy hon ton 24,8 gam hn hp X thu c 28,8 gam nc. Mt khc 0,5 mol hn hp ny tc dng va vi 500 gam dung dch brom 20%. Thnh phn % v th tch ca mi kh trong hn hp l: A. 25%; 25%; 50% B. 25%; 50%; 25% C. 50%; 25%; 25% D. 60%; 20%; 20% Cu 109: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,90C, p sut trong bnh l 0,8 atm t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l: A. C2H4O2 B. CH2O2 C. C4H8O2 D. C3H6O2 Cu 110: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l: A. CH2=CHCOONH4 B. H2NCOOCH2CH3 C. H2NCH2COO- CH3 D. H2NC2H4COOH Cu 111: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n. Vy cng thc phn t ca X: A. C6H8O6 B. C3H4O3 C. C12H16O12 D. C9H12O9 Cu 112: t chy hon ton 2,79 gam cht hu c Y ri cho cc sn phm chy i qua cc bnh ng CaCl2 khan v KOH, thy bnh CaCl2 tng thm 1,89 gam v bnh KOH tng thm 7,92 gam. Mt khc, khi t chy 0,186 gam Y th thu c 224ml kh N2 (iu kin tiu chun). Bit Y ch cha 1 nguyn t nit. Cng thc phn t ca Y l: A. C6H7ON B. C6H7N C. C5H9N D. C5H7N Cu 113: t chy hon ton 0,1 mol hp cht hu c A ch cha C, H, O vi oxi theo t l 1 : 2. Ton b sn phm chy c cho qua bnh I ng dung dch PbCl2 d ri qua bnh II ng dung dch Ca(OH)2 d. Sau th nghim, bnh I tng 0,4 gam v xut hin 21,2 gam kt ta, cn bnh II c 30 gam kt ta. Cng thc phn t ca A l: A. C2H4O B. C3H4O2 C. C2H6O2 D. C3H6O2 Cu 114: hiro ha mt hirocacbon A mch h cha no thnh no phi dng 1 th tch H 2 gp i th tch hi hirocacbon dng. Mt khc, t chy 1 th tch hi hirocacbon trn thu c 9 th tch hn hp CO2 v hi H2O (cc th tch o cng iu kin). Cng thc phn t ca A l: A. C3H6 B. C5H8 C. C6H10 D. C4H8 Cu 115: t chy 200ml hi mt cht hu c A cha C, H, O trong 900ml O 2, th tch hn hp kh thu c 1,3 lt. Sau khi cho hi nc ngng t, ch cn 700ml. Tip theo cho qua dung dch KOH c ch cn 100ml (cc th tch o cng iu kin). Cng thc phn t ca A l: A. C3H6O B. C3H6 C. C3H8O D. C3H8
Cu 116: Trn 400 cm3 hn hp hp cht hu c A v nit vi 900cm3 oxi d ri t. Th tch hn hp sau phn ng l 1,4 lt. Sau khi cho hi nc ngng t th cn 800 cm3, tip tc cho qua dung dch KOH th cn 400 cm3. Cng thc phn t ca A l: A. C2H4 B. CH4 C. C2H6 D. C3H8 Cu 117: t chy 1,08 gam hp cht hu c X, ri cho ton b sn phm chy vo dung dch Ba(OH)2, thy bnh nng thm 4,6 gam ng thi to thnh 6,475 gam mui axit v 5,91 gam mui trung ha. T khi hi ca X i vi he l 13,5. Cng thc phn t ca X l: A. C3H6O2 B. C4H6 C. C4H10 D. C3H8O2 3 Cu 118: Cho vo kh thin nhin 10 cm cht hu c A (cha C, H, N), 25 cm3 H2 v 40 cm3 O2. Bt tia la in cho hn hp n. Chuyn hn hp kh nhn c v iu kin ban u , H 2O ngng t ht, thu c 20 cm3 hn hp kh, trong c 10 cm3 b NaOH hp th v 5 cm3 b photpho hp th. Cng thc phn t ca A l: A. CH5N B. C2H7N C. C3H9N D. C4H11N Cu 119: 3H6, CH4 24 ml CO2 4 : A. 12,9 B. 25,8 C. 22,2 D. 11,1 Cu 120: 2SO4 : A. C3H8 B. C3H6 C. C4H8 D. C3H4 Cu 121: H6, C3H8 2 3H6, C4H8
2 2
A. C. Cu 122:
: 0,25 0,15
1 14
B. D.
14
0,2 0,1
1
A. 18,6 gam Cu 123: 1, : A. 240,8 gam C. 193,6 gam Cu 124:
B. 20,4 gam (xc tc
0,1 mol X2 : C. 16,8 gam D. 8,0 gam : 0,1 mol benzen; 0,2 mol toluen; 0,3 mol
B. 260,2 gam D. 0,06 mol C2H2 0,04 mol H2 iu kin tiu chun :
2
A. 1,04 gam Cu 125:
B. 1,32 gam
C. 1,64 gam
D. 1,20 gam
iu kin tiu chun). A. CH4 C. CH4 Cu 126:

2H4 3H6
2 3 H4 3 H6
B. C2H6 D. C2H6 iu kin tiu chun

2
: A. C2H2 C. C3H4 v
4H6 4H8
B. C2H2 D. C2H2 Trang 12 - Cunconhocmai
4 H8 3 H8
Cu 127: ) th
2SO4
A. C2H5 C. C2H5 Cu 128:
). 3H7OH 4H9OH
B. C3H7 4H9OH D. C4H9 5H11OH ; 0,1 mol axetilen, 0,2 mol etilen, 0,1 m
A. 13,26 gam Cu 129:
B. 10,28 gam
? C. 9,58 gam
D. 8,20 gam
A. 22,4 gam B. 44,8 gam Cu 130: Nung 0,04 mol C2H2 0,05 mol H2 2O/NH3 : A. 0,02 B. 0,01 Cu 131:
C. 51,2 gam
: D. 41,6 gam
C. 0,03
2
D. 0,015
1l 8,8 gam CO2 5,4 gam H2 A. C2H4 B. C2H2 Cu 132: Ag2O/NH3 A. 0,56 gam Cu 133: A. Cu 134: 75% B. 0,13 gam C. 0,28 gam 2H2, C2H6 2 % C2H2 : 2 B. 7, 25% C. 75%
2 2 : D. 0,26 gam
: C. C3H4
D. C4H4
D.
25%
2
: A. C2H4 C. C3H6 Cu 135: : A. 75% Cu 136: dm3 (iu kin tiu chun A. 50% Cu 137: B. 25% C. 80% D. 90% 12,6 gam H2 D. 25% 11,2
3H6
; 27,58% 4H8 ; 27,58%
B. C2H4 D. C3H6 0,
3 H6
; 28,57% 4H8 ; 28,57%
: B. 40% 2H2, C2H6
C. 30%
3H6
: A. 50%, 30%, 20% C. 50%, 25%, 25% B. 30%, 50%, 20% D. 25%, 50%, 25% Trang 13 - Cunconhocmai
Cu 138:
2 2
: A. 3 Cu 139: NH3
B. 4 iu kin tiu chun
C. 2
3
D. 5
2
iu kin tiu chun)
4,5 gam
H2 A. 11,2 Cu 140:
: B. 13,44 C. 5,60 D. 8,96 0,6 mol CO2 0,3 mol H2 3/NH3
: A. 3-metyl penta-1,4-iin C. Hexa-1,3-ien-5-in Cu 141: B. Hexa-1,5-iin D. ,
: A. 93,00 gam Cu 142: A. C4H6 Cu 143: A. 5 Cu 144:
B. 129,50 gam
C. 116,25 gam
B. C5H8
2 2
C. C6H10 C. 7
D. 103,60 gam 2O/NH3 : D. C4H4 : D. 8
B. 6
: A. C5H12 B. C4H10 Cu 145:

5H11Cl 4H9Cl
B. C5H12 D. C4H10 6,16 gam CO2

2O/NH3
5H10Cl2 4H8Cl2
1,62 gam H2 CCH2CH3 3C CCH3 (iu kin tiu chun
: A. CH CH 3C CCH3 C. CH 3C CH Cu 146: Cho 2,2 gam C3H8 X = 1,3894mY : A. C. Cu 147: 1,13 gam 1,57 gam
3/NH3
B. CH D. CH3C 3,55 gam Cl2
B. D.
1,27 gam 1,13 gam 2/H2
: A. CH2=C=CHC CH C. CH3C CCH2C CH Cu 148:
B. CH CCH2C CH D. CH3C CCH2C CH (iu kin tiu chun

3/NH3 2
: A. 1,12 gam B. 2,24 gam C. 0,42 gam D. 0,56 gam

Cu 149: 11,2 gam Br2 CO2 A. 5,22 gam Cu 150: A. 0 < d < 1 Cu 151: (iu kin tiu chun : B. 6,96 gam
C. 5,80 gam
D. 4,64 gam ?
B. d > 1
C. d = 1 D. 1 < d < 2 m H2, CH4, C2H4, C3H6, C4H8 C. 75% D. 85% 4, C2H4, C3H6, H2
2
A. 25% Cu 152: A. 11,58 Cu 153:
: B. 60% 8,8g C3H8 ta thu 90% C3H8 B. 15,58
3H8
C. 11,85
D. 18,55
A. 30% Cu 154:
2
B. 50% (iu kin tiu chun B. 85%

2 2
? C. 25%
D. 40% (iu kin tiu chun
10,8 gam H2 C. 90% D. 95%
: A. 80% Cu 155:
14,4g H2 B. CH3CH(CH3)2 D. CH3CH2CH2CH3
? A. CH3CH2CH2CH2CH3 C. CH3CH2CH(CH3)2 Cu 156:
: A. 8,7 gam Cu 157: B. 5,8 gam C. 6,96 gam (CH3)2CHCH2CH2 68%. C. 292,5 gam D. 10,44 gam 2SO4 D. 159,0 gam
A. 195 gam Cu 158:
B. 192,0 gam
A. 58,875% Cu 156:
3/NH3
: B. 38,095%
C. 42,405%
D. 36,405%
A. 55,7% B. 60% C. 57,5% D. 75% Cu 157: Khi lng axit axetic cha trong gim n thu c khi ln men 100 lt ancol etylic 80 thnh gim n l bao nhiu gam, bit khi lng ring ca ancol etylic l 0,8g/ml v gi s phn ng ln men gim t hiu sut 80%. A. 8347,8 gam B. 6678,3 gam C. 6778,3 gam D. 8437,8 gam
Cu 158: : A. CH4O Cu 159:

2 3
(CH3O)n B. C3H8O3 13,75). : B. 8,8 C. 7,4 D. 9,2 O2 C. C2H6O2 D. C4H12O4
A. 7,8 Cu 160: :
A. C2H5C6H4OH C. HOCH2C6H4COOH Cu 161:
B. HOC6H4CH2OH D. C6H4(OH)2
7H8O2 2
1 : 1. Cng t : A. C6H5CH(OH)2 Cu 162: : A. 3 Cu 163: AgNO3 B. 4 1,2 gam CH3 , H2 3

3
B. HOC6H4CH2OH
C. CH3C6H3(OH)2
D. CH3OC6H4OH
C. 2
D. 1
2O
(trong
3
: (ancol)
A. 76,6% B. 80,0% Cu 164: etylic 460 0,8 g/ml). A. 5,4 kg B. 5,0 kg Cu 165: 0,3 mol CO2 0,425 mol H2 0,15 mol H2 A. C2H6O2 H8O2 3 C. C3H6 4H8O Cu 166: CO2
C. 65,5%
D. 70,4%
C. 6,0 kg
D. 4,5 kg
B. C2H6 D. C2H6 (OH)2
: O 4 3H8O
550 ga : A. 550 B. 810 B. 650 D. 750 Cu 167: Hn hp X gm ba ancol n chc A, B, C; trong B, C l hai ancol ng phn. t chy hon ton 0,04 mol hn hp X thu c 1,98 gam H2O v 1,568 lt CO2 ( iu kin tiu chun). S mol ancol bng 5/3 tng s mol hai ancol B v C. Cng thc phn t ca A, B l: A. CH4O v C3H6O B. CH4O v C3H8O C. CH4O v C4H10O D. C2H6O v C3H8O Cu 167: 0,5 mol C2H5 0,7 mol C3H7 H2SO4 2 2O : A. 1 mol B. 1,1 mol C. 1,2 mol D. 0,6 mol Cu 168: Oxi ha 4,6 gam ru etylic bng CuO t nng, thu c 6,6 gam hn hp gm anehit, axit, ru cha phn ng v nc. Hn hp ny tc dng vi natri d sinh ra 1,68 lt kh hiro ( iu kin tiu chun). Phn trm khi lng ru chuyn ha thnh anehit, thnh axit l: A. 25% B. 50% C. 75% D. 33%
Cu 169: Cho 10ml ru (ancol) etylic 920 tc dng ht vi Na thu c V lt H2 ( iu kin tiu chun). Bit khi lng ring ca nc l 1 g/ml v ca ru l 0,8 g/ml. Gi tr ca V l: A. 2,24 B. 1,68 C. 1,792 D. 2,285 Cu 170: Oxi ha m gam ru etylic bng CuO t nng, thu c 33 gam hn hp gm anehit, axit, ru cha phn ng v nc. Hn hp ny tc dng vi Na d sinh ra 8,4 lt kh hiro ( iu kin tiu chun) v thu c 29 gam mui . Tnh phn trm ru chuyn ha thnh axit. A. 25% B. 30% C. 50% D. 75% Cu 171: (C2H3O)n : A. C2H3O B. C4H6O2 C. C6H9O3 D. C8H12O4 Cu 172: d 3/NH3 : A. 3CHO B. CH3 2H5CHO C. C2H5 3H7CHO D. C3H7 4H9CHO Cu 173: 2
A. B. C. D. Cu 174: AgNO3
3
2 3 2
: C. C2H5CHO D. C4H9CHO
3 3
A. C3H7CHO Cu 175: Ag2 A. CH3CHO C. CH3CH2CHO Cu 176: NH3 A. HCHO Cu 177: anehit: A. B. C. D. Cu 178:
B. HCHO
3
: B. HCHO D. CH2=CHCHO
3 2
B. CH3CHO
: C. OHC CHO D. CH3CH(OH)CHO o ra b mol CO2 2
2 H4
2 2H4
2,
A. 70% Cu 179:
3/NH3
o CH3 B. 50%
C. 60%
CuCl2 7,1 gam CH3 : D. 80% :
A. C.
3CHO 3H7CHO
B. D. CH3 Trang 17 - Cunconhocmai
2H5CHO 2H5CHO
Cu 180: Trong bnh kn dung tch 10 lt (khng i) cha 4,8 gam kh oxi v a gam mt hirocacbon X 00C, p sut trong bnh l 0,448 atm. Bt tia la in t chy ht X, gi nhit trong bnh 136,50C, p sut trong bnh l P. Dn kh trong bnh sau khi t qua bnh 1 ng H2SO4 c, bnh 2 c ng dung dch Ba(OH)2 d, thy bnh 1 tng 1,8 gam, bnh 2 c 9,85 gam kt ta. p sut trong bnh sau khi t v cng thc phn t ca X l: A. 0,267 atm; CH4 B. 0,726 atm; C2H2 C. 0,627 atm; C2H2 D. 0,672 atm; CH4 Cu 181: Mt bnh kn dung tch 10 lt ng hn hp hiro v axetilen ( 0 0C; 1,792 atm) v mt t bt niken. Nung nng bnh mt thi gian sau a v nhit ban u 0 0C, p sut trong bnh l P. Nu cho mt na kh trong bnh sau khi nung nng i qua dung dch AgNO 3 trong NH3 th c 1,2 gam kt ta mu vng nht. Nu cho na cn li qua bnh dung dch brom d thy khi lng bnh tng 0,41 gam. Lng axetilen cha phn ng v lng etilen c trong bnh sau phn ng l: A. C2H2 = 0,26 gam v C2H4 = 0,56 gam B. C2H2 = 0,56 gam v C2H4 = 0,28 gam C. C2H2 = 0,52 gam v C2H4 = 0,56 gam D. C2H2 = 0,26 gam v C2H4 = 0,28 gam Cu 182: Hn hp kh A gm H2 v hai olefin ng ng lin tip. Cho 19,04 lt hn hp kh A ( iu kin tiu chun) i qua bt Ni nung nng ta thu c hn hp kh B (gi s hiu sut phn ng t 100%) v tc phn ng ca hai olefin nh nhau. Cho mt t hn hp kh B i qua nc brom thy brom b nht mu. Mt khc, t chy 1/2 hn hp kh B th thu c 43,5 gam CO 2 v 20,43 gam nc. Cng thc phn t v phn trm th tch cc kh trong hn hp A l: A. C3H6 v C4H8. %C3H6 = 29,43%; %C4H8 = 35,99% B. C2H4 v C3H6. %C2H4 = 29,43%; %C3H6 = 35,99% C. C3H6 v C4H8. %C3H6 = 28,55%; %C4H8 = 71,45% D. C2H4 v C3H6. %C2H4 = 28,55%; %C3H6 = 71,45% Cu 183: t chy hon ton 4,48 lt hn hp kh gm propan v mt hirocacbon khng no Y thy sinh ra 22 gam CO2 v 10,8 gam H2O. Th tch khng kh cn dng t chy hn hp (bit trong khng kh oxi chim 20% th tch) v cng thc phn t ca Y l: A. 86,9 lt; C2H6 B. 96,8 lt; C4H8 C. 89,6 lt; C2H4 D. 98,6 lt C2H2 Cu 183: Hn hp X gm mt hirocacbon trong iu kin thng th kh v hiro. T khi ca X so vi hiro bng 6,7. Cho hn hp i qua Ni nung nng, sau khi hirocacbon phn ng ht thu c hn hp Y c t khi vi hiro bng 16,75. Cng thc phn t ca hirocacbon l: A. C3H4 B. C3H6 C. C4H8 D. C4H6 Cu 185: Oxi ha 4 gam ancol n chc th c 5,6 gam mt hn hp X gm anehit, nc v ancol d. S gam Ag khi cho hn hp X tc dng ht vi dung dch AgNO3 trong NH3 d l: A. 43,20 gam B. 21,60 gam C. 20,52 gam D. 10,80 gam Cu 186: Cho hn hp HCHO v H2 i qua ng ng bt Ni nung nng. Dn ton b hn hp thu c sau phn ng vo bnh nc lnh ngng t hi cht lng v ha ton cc cht c th tan c, thy khi lng bnh tng 11,8 gam. Khi lng CH3OH to ra trong phn ng hp hiro ca HCHO l 10,3 gam. Ly dung dch bnh cho tc dng hon ton vi dung dch AgNO 3 trong NH3 thu c m gam bc kim loi. Gi tr ca m: A. 21,6gam B. 2,16 gam C. 10,8gam D. 1,08 gam Cu 187: t chy hon ton a gam hn hp hai ankan A, B hn km nhau k nguyn t cacbon th thu c b gam kh cacbonic. Cng thc phn t ca A, B l: A. CH4, C5H12 v C3H8, C8H18 B. C5H12, C7H16 v C6H14, C8H18 B. C4H10, C6H14 v C5H12, C7H16 D. C3H8, C5H12 v C4H10, C6H14 Cu 188: E l hn hp ca hai ng phn c to thnh t axit n chc v ru n chc. cng iu kin nhit v p sut, 1 lt hi E nng gp 2 ln 1 lt kh CO 2. Thy phn 35,2 gam E bng 4 lt dung dch NaOH 0,2M c dung dch A. C cn dung dch A c 44,6 gam cht rn khan. Cng thc phn t v phn trm s mol mi este trong hn hp E l: A. HCOOC3H7: 75%; CH3COOC2H5: 25% B. HCOOC3H7: 87,5%; CH3COOC2H5: 12,5% C. CH3COOC2H5: 50%; C2H5COOCH3: 50% D. A, B u ng
Cu 189: Hn hp A gm ba este ca cng mt axit hu c n chc v ba ru n chc (trong c hai ru c phn t khi hn km nhau 28 vC v mt ru khng no cha mt ni i). Cho hn hp A tc dng vi 100 gam dung dch NaOH 10% sau c cn th c 18,4 gam cht rn khan. Ngng t phn ru bay hi, lm khan, ri chia thnh hai phn bng nhau: - Phn 1: Tc dng ht vi Na gii phng 1,12 lt H2 ( iu kin tiu chun). - Phn 2: em t chy thu c 7,04 gam CO2 v 4,32 gam H2O. Cng thc phn t axit, cng thc phn t v s mol mi ru to thnh trong phn ng x phng ha hn hp A l: A. CH3COOH; C2H5OH: 0,05 mol; C4H9OH: 0,03 mol; C3H5OH: 0,02 mol B. CH3COOH; CH3OH: 0,14 mol; C3H7OH: 0,02 mol; C3H5OH: 0,04 mol C. HCOOH; CH3OH: 0,07 mol; C3H7OH: 0,02 mol; C3H5OH: 0,02 mol D. C2H3COOH; C2H5OH: 0,1 mol; C4H9OH: 0,04 mol; C4H7OH: 0,06 mol Cu 190: Khi cho 9,2 gam hn hp ru n-propylic v mt ru B thuc dy ng ng ru no n chc tc dng vi natri d thy c 2,24 lt kh thot ra ( iu kin tiu chun). Cng thc phn t ca ru B v phn trm khi lng ca mi ru trong hn hp X l: A. CH3OH; %CH3OH = 34,78%; %C3H7OH = 63,22% B. C2H5OH; % C2H5OH = 35,67%; %C3H7OH = 64,33% C. CH3OH; %CH3OH = 25,78%; %C3H7OH = 74,22% D. C2H5OH; % C2H5OH = 33,33%; %C3H7OH = 66,67% Cu 191: t chy hon ton a lt hn hp A gm hai hirocacbon l cht kh iu kin thng v c khi lng phn t hn km nhau 28 vC. Sn phm chy c hp th hon ton vo dung dch Ca(OH)2 d thy c 30 gam kt ta. Khi lng bnh ng dung dch Ca(OH) 2 tng 22,2 gam. Cng thc phn t ca hai hirocacbon v thnh phn phn trm th tch ca mi cht trong hn hp A. A. CH4 v C3H8; 75% v 25% B. C4H6 v C3H8; 50% v 50% C. C2H4 v C4H8; 65% v 35% D. C2H2 v C2H4; 55% v 45% Cu 192: Hn hp X gm hai hirocacbon thuc dy ng ng, u th kh ( iu kin tiu chun). t chy hon ton X cn 20,16 lt oxi, thu c 7,2 gam H 2O v a lt CO2 (iu kin tiu chun). X tc dng c vi dung dch Ag2O trong NH3 d to ra 62,7 gam kt ta. Cng thc phn t ca hai hirocacbon l: A. C2H2 v C2H4 B. C4H6 v C2H2 C. CH4 v C2H6 D. C2H2 v C3H4 Cu 193: t chy hon ton 6,66 gam cht X cn 9,072 lt oxi ( iu kin tiu chun). Sn phm chy c dn qua bnh 1 ng H2SO4 c, bnh 2 ng Ca(OH)2 d thy bnh 1 tng 3,78 gam, bnh 2 tng m gam v c a gam kt ta. MX < 250. Gi tr m, a v cng thc phn t ca X l: A. m: 14,85 gam; a: 35 gam; C6H6O2 B. m: 18,54 gam; a: 34 gam; C6H6O2 C. m: 15,84 gam; a: 36 gam; C12H14O4 D. m: 15,48 gam; a: 33 gam; C12H14O4 Cu 194: t chy hon ton 10 gam hp cht A sinh ra 33,85 gam CO2v 6,94 gam H2O. T khi hi i vi khng kh l 2,69. t chy 0,282 gam hp cht B v cho cc sn phm sinh ra i qua cc bnh cha ng CaCl2 v KOH thy bnh CaCl2 tng thm 0,194 gam, cn nit (o iu kin tiu chun). Phn t cht ch cha mt nguyn t nit. Cng thc phn t ca A v B l: A. C6H7N B. C3H7O2N C. C5H6N D. C2H5ON Cu 195: Hn hp kh A gm H2 v hai olefin l ng ng lin tip. Cho 19,04 lt hn hp kh A ( iu kin tiu chun) i qua bt Ni nung nng ta thu c hn hp kh B. (Gi s hiu sut phn ng t 100%) v tc phn ng ca hai olefin nh nhau. Cho mt t hn hp kh B qua nc brom thy brom b nht mu. Mt khc, t chy 1/2 hn hp kh B th thu c 43,56 gam CO 2 v 20,43 gam H2O. Cng thc phn t hai olefin l: A. C5H10 v C6H12 B. C2H4 v C3H6 C. C3H6 v C4H8 D. C4H8 v C5H10 Cu 196: Chia 7,8 gam hn hp ru etylic v mt ru ng ng thnh hai phn bng nhau. Phn 1 cho tc dng ht vi Na thu c 1,12 lt H2 ( iu kin tiu chun). Phn 2 un nng vi 15 gam axit axetic (c H2SO4 m c xc tc). Bit hiu sut cc phn ng este u bng 80%. Khi lng este thu c l: A. 4,86 gam B. 4,68 gam C. 6,48 gam D. 6,84 gam
Cu 197: Hn hp M cha ba axit cacboxylic n chc mch h, trong hai cht l axit no k tip nhau trong dy ng ng v mt cht l axit khng no c mt lin kt i gc hirocacbon. Cho 29,60 gam M tc dng vi dung dch NaOH ri c cn, thu c 40,60 gam hn hp mui khan. t chy hon ton 8,88 gam M thu c 6,72 lt CO2 ( iu kin tiu chun). Tn v phn trm khi lng tng cht trong hn hp M l: A. axit metanoic: 31,1%; axit etanoic: 20,0%; axit propenoic: 48,6% B. axit metanoic: 40,0%; axit etanoic: 20,0%; axit acrylic: 40,0% C. axit etanoic: 31,0%; axit propinoic: 24,3%; axit propenoic: 44,7% D. axit metanoic: 25,0%; axit etanoic: 25,0%; axit butenoic: 50,0% Cu 198: C mt hn hp X gm hirocacbon A v N2. t 300 cm3 hn hp Y v 725 cm3 O2 ly d trong mt kh nhin k ngi ta thu c 1100 cm3 hn hp kh. Cho hn hp ny lm lnh th tch cn 650 cm3 v sau tip tc li qua KOH th ch cn 200 cm3. Cng thc phn t ca A l: A. C3H4 B. C3H6 C. C3H8 D. C4H6 Cu 199: t chy 0,1 mol cht hu c A ch cha C, H, O vi oxi theo t l mol 1 : 2. Ton b sn phm chy c cho qua bnh 1 cha dung dch PbCl2 d, ri bnh 2 cha dung dch Ca(OH)2 d. Sau th nghim bnh 1 tng 0,4 gam v xut hin 21,2 gam kt ta, cn bnh 2 c 30 gam kt ta. Cng thc phn t ca A l: A. C2H4O B. C3H4O2 C. C2H6O D. C3H6O2 Cu 200: Oxi ha hon ton 0,42 gam cht hu c X ch thu c kh cacbonic v nc m khi dn ton b vo bnh cha nc vi trong ly d th khi lng bnh tng thm 1,86 gam ng thi xut hin 3 gam kt ta. Mt khc khi ha hi mt lng cht X ngi ta thu c mt th tch va ng bng 2/5 th tch ca kh nit c khi lng tng ng cng iu kin nhit v p sut. Cng thc phn t ca X l: A. C4H10 B. C4H10O C. C5H10 D. C5H10O Cu 201: Mt hn hp kh gm ba hirocacbon A, B, C trong B, C c cng s nguyn t cacbon trong phn t v s mol A gp 4 ln tng s mol B v C trong hn hp. t chy hon ton 1,12 lt hn hp kh trn ( iu kin tiu chun) thu c 3,08 gam CO 2 v 2,2025 gam H2O. Cng thc phn t ca A, B, C c th l: A. C3H6, C3H8, C3H4 B. CH4, C3H6, C3H4 C. C2H4, C3H6, C2H2 D. CH4, C3H8, C3H4 Cu 202: Hn hp kh A ( iu kin tiu chun) gm hai olefin l ng ng lin tip. t chy 8,96 lt hn hp kh A ri cho sn phm chy ln lt i qua ng 1 dng P 2O5 v ng 2 ng KOH rn thy khi lng bnh 1 tng m gam, cn binh 2 tng (m + 39) gam. Cng thc phn t v phn trm v th tch ca mi olefin trong hn hp A l: A. C5H10 v C6H12; 35% v 65% B. C2H4 v C3H6; 66% v 34% C. C3H6 v C4H8; 25% v 75% D. C4H8 v C5H10; 67% v 33% Cu 203: Mt hn hp gm ankaien lin hp A v oxi c d (oxi chim 9/10 th tch hn hp) np y vo mt kh k to p sut 2 atm. t chy hon ton A ri a v nhit ban u cho hi nc ngng t ht th p sut gim 1/4 so vi p sut ban u. Cng thc phn t v cng thc cu to. A. C5H8; CH2=CH-CH=CH-CH3 B. C4H6; CH2=CH-CH=CH2 C. C5H8; CH2=C(CH3)-CH=CH2 D. C4H6; CH3-CH=C=CH2 Cu 204: Hn hp X cha hai hirocacbon A, B thuc loi ankan, anken, ankin. T l khi lng phn t ca chng l 22 : 13. t chy hon ton 0,3 mol hn hp X v cho tt c sn phm chy hp th vo dung dch Ba(OH)2 d th khi lng bnh tng thm 46,5 gam v c 147,75 gam kt ta. Cng thc phn t hn hp X: A. C2H2 v C2H4 B. C2H2 v C3H8 C. C3H8 v C4H6 D. C4H6 v C5H8 Cu 205: Hn hp kh A cha nit v hai hirocacbon k tip nhau trong mt dy ng ng. Khi lng hn hp A l 18,30 gam v th tch ca n l 11,20 lt. Trn A vi mt lng d oxi ri t chy, thu c 11,70 gam H2O v 21,28 lt CO2. Cc th tch o iu kin tiu chun. Cng thc phn t ca hirocacbon trong hn hp A l: A. C3H4 v C4H6 B. C4H6 v C5H8 C. C7H9 v C4H6 D. C2H4 v C3H6
Cu 206: Nhit phn 2,8 lt (iu kin tiu chun) etan 12000C ri cho mt na hn hp kh thu c sc qua bnh ng nc brom (d) th thy khi lng bnh ny tng thm 1,465 gam. Cho na hn hp kh cn li phn ng vi dung dch AgNO3 trong NH3 th thu c 0,6 gam kt ta mu vng. Bit rng phn ng nhit phn to ra etilen, axetilen l phn ng khng hon ton, cc phn ng tip sau u xy ra hon ton. Thnh phn phn trm v th tch ca hn hp kh thu c l: A. %C2H4 = 20%; %C2H2 = 25%; %H2 = 15%; C2H6 = 40% B. %C2H4 = 42,55%; %C2H2 = 2,13%; %H2 = 46,8%; C2H6 = 8,52% C. %C2H4 = 25%; %C2H2 = 25%; %H2 = 10%; C2H6 = 40% D. %C2H4 = 24%; %C2H2 = 21%; %H2 = 30%; C2H6 = 25% Cu 207: Hn hp X gm ba hirocacbon A, B, C u l cht kh iu kin thng. Nu t hn hp gm A hoc B hoc C vi oxi va th sn phm thu c 1350C c th tch bng th tch ca hn hp ban u. Nu dn 3,36 lt kh X (iu kin tiu chun) t t i vo dung dch AgNO 3 trong NH3 d thu c 7,35 gam kt ta. t chy phn kh cn li thu c 6,60 gam CO 2 v 3,60 gam H2O. Cng thc phn t ca A, B, C l: A. CH4, C2H4, C3H4 B. C2H6, C3H6, C4H6 C. CH4, C3H4, C5H8 D. CH4, C2H4, C4H4 Cu 208: Mt ru no a chc A c t khi so vi ru no n chc B bng 2. Khi dng cng mt lng A hoc B tc dng vi natri d th th tch khi thot ra t A gp 1,5 ln th tch kh thot ra t B. Nu t chy hon ton hn hp cha 1,15 gam mi ru th c 1,96 lt CO 2 (iu kin tiu chun). Cng thc phn t ca mi ru l: A. C3H8O3 v C2H5OH B. C4H9OH v C2H5OH C. CH3OH v C4H9OH D. C3H5(OH)3 v C4H9OH Cu 209: Cho glucoz ln men thnh ru etylic vi hiu sut 70%. Hp th ton b sn phm kh thot ra vo 1 lt dung dch NaOH 2M (d = 1,05 g/ml) thu c dung dch cha hai mui c nng 12,27%. Khi lng glucoz ng l: A. 192,86 gam B. 182,96 gam C. 94,5 gam D. 385,72 gam Cu 210: Oxi ha mt ru n chc A bng O2 (c mt cht xc tc) thu c hn hp X gm anehit, axit tng ng, nc v ru cn li. Ly m gam hn hp X tc dng va ht vi Na thu c 8,96 lt H2 ( iu kin tiu chun) v hn hp Y. Cho Y bay hi th cn li 48,8 gam cht rn. Mt khc ly 4m gam hn hp X tc dng vi Na2CO3 d cng thu c 8,96 lt kh ( iu kin tiu chun). Tnh phn trm ru b oxi ha thnh axit. A. 33,33% B. 25% C. 66,67% D. 75% Cu 211: Oxi ha mt ru n chc A bng O2 (c mt cht xc tc) thu c hn hp X gm anehit, axit tng ng, nc v ru cn li. Ly m gam hn hp X tc dng va ht vi Na thu c 8,96 lt H2 ( iu kin tiu chun) v hn hp Y. Cho Y bay hi th cn li 48,8 gam cht rn. Mt khc ly 4m gam hn hp X tc dng vi Na2CO3 d cng thu c 8,96 lt kh ( iu kin tiu chun). Tm cng thc phn t ca A (bit rng khi cho m gam hn hp X tc dng vi AgNO3 trong NH3 d to thnh 21,6 gam Ag) ?. A. C3H7OH B. C2H5OH C. C2H4OH D. C3H6OH
Cc cu thi i hc
Cu 212: Cho 200 gam mt loi cht bo c ch axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gam Cu 213: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn cc tnh cht trn l: A. 4 B. 5 C. 6 D. 2 Cu 214: hiro ha hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H2 ( iu kin tiu chun). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l: A. OHC-CH2-CHO v OHC-CHO B. H-CHO v OHC-CH2-CHO C. CH2=C(CH3)-CHO v OHC-CHO D. CH2=CH-CHO v OHC-CH2-CHO
Cu 215: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H 2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l: A. 5,85 B. 3,39 C. 6,6 D. 7,3 Cu 216: Hn hp X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l: A. 3 : 5 B. 5 : 3 C. 2 : 1 D. 1 : 2 Cu 217: Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 ( iu kin tiu chun). Tn ca Z l: A. anehit propionic B. anehit butyric C. anehit axetic D. anehit acrylic Cu 218: Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (iu kin tiu chun) v 6,3 gam H2O. - un nng phn 2 vi H2SO4 c 1400C to thnh 1,25 gam hn hp ba este. Ha hi hon ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N 2 (trong cng iu kin nhit , p sut). Hiu sut phn ng to ete ca X, Y ln lt l: A. 30% v 30% B. 25% v 35% C. 40% v 20% D. 20% v 40% Cu 219: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l: A. 25% B. 27,92% C. 72,08% D. 75% Cu 220: Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l: A. 20% B. 50% C. 40% D. 30% Cu 221: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l: A. 8 B. 9 C. 5 D. 7 Cu 222: X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (iu kin tiu chun). Gi tr ln nht ca V l: A. 22,4 B. 5,6 C. 11,2 D. 13,44 Cu 223: Cht hu c mch h X c dng H2N-R-COOR (R, R l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ha thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l: A. 2,67 B. 4,45 C. 5,34 D. 3,56 Cu 224: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol ti a phn ng l: A. 0,48 mol B. 0,36 mol C. 0,60 mol D. 0,24 mol Cu 225: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H 2O. Mt khc nu cho a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn phn trm theo khi lng ca Y trong X l: A. 46,67% B. 40,00% C. 25,41% D. 74,59%
Cu 226: Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu xut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l: A. 0,090 mol B. 0,095 mol C. 0,12 mol D. 0,06 mol Cu 227: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l; A. 0,24 B. 0,96 C. 0,72 D. 0,48 Cu 228: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l: A. 17,5 B. 15,5 C. 14,5 D. 16,5 Cu 229: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) 2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng dung dch Ca(OH) 2 ban u thay i nh th no ?. A. Tng 2,70 gam B. Gim 7,74 gam C. Tng 7,92 gam D. Gim 7,38 gam Cu 230: t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi z = y x ). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2 . Tn ca E l: A. axit fomic B. axit acrylic C. axit oxalic D. axit aipic. Cu 231: Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l: A. 3 B. 4 C. 2 D. 1 Cu 232: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (iu kin tiu chun). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (iu kin tiu chun), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l: A. 0,6 B. 0,8 C. 0,2 D. 0,3 Cu 233: S ng phn amino axit c cng thc phn t C3H7O2N l: A. 2 B. 3 C. 4 D. 1 Cu 234: t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l: A. anehit no, mch h, hai chc B. anehit fomic C. anehit axetic D. anehit khng no, mch h, hai chc Cu 235: Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn ?. A. 4 B. 5 C. 6 D. 2 Cu 236: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh ( iu kin tiu chun) c t khi so vi H2 l 8. Th tch O2 ( iu kin tiu chun) cn t chy hon ton hn hp Y l: A. 22,4 lt B. 44,8 lt C. 26,88 lt D. 33,6 lt Cu 237: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn ?. A. 9 B. 3 C. 7 D. 10 Cu 238: Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi ( iu kin tiu chun) cn dng l: A. 1,12 lt B. 4,48 lt C. 3,36 lt D. 2,24 lt
Cu 239: t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO 2 (iu kin tiu chun) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l: 28 28 28 28 A. V = x 30 y B. V = x 30 y C. V = x 62 y D. V = x 62 y 55 55 95 95 Cu 240: Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l: A. 3,67 tn B. 2,20 tn C. 2,97 tn D. 1,10 tn Cu 241: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CH C-CH3, CH2=CH-C CH B. CH C-CH3, CH2=C=C=CH2 C. CH2=C=CH2, CH2=C=C=CH2 D. CH2=C=CH2, CH2=CH-C CH Cu 242: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l; A. 66,44 B. 111,74 C. 81,54 D. 90,6 Cu 243: Ha hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln hn mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N 2 (o cng trong iu kin nhit , p sut). Nu t chy hon ton b hn hp hai axit trn th thu c 10,752 lt CO2 ( iu kin tiu chun). Cng thc cu to ca X, Y ln lt l: A. CH3-CH2-COOH v HCOO-COOH B. CH3-COOH v HCOO-CH2-CH2-COOH B. H-COOH v HOOC-COOH D. CH3-COOH v HOOC-CH2-COOH Cu 244: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l: A. 405 B. 486 C. 324 D. 297 Cu 245: Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thun dung dch, th lng mui khan thu c l: A. 7,09 gam B. 16,30 gam C. 8,15 gam D. 7,82 gam Cu 246: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l: A. 4 B. 2 C. 6 D. 5 Cu 247: Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3 , thu c 23,76 gam Ag. Hai ancol l: A. C2H5OH v C2H5CH2OH B. C2H5OH v C3H7CH2OH C. CH3OH v C2H5CH2OH D. CH3OH v C2H5OH Cu 248: Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (iu kin tiu chun) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l: A. 34,20 B. 27,36 C. 22,80 D. 18,24 Cu 249: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (iu kin tiu chun) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l: A. 0,328 B. 0,205 C. 0,585 D. 0,620
Cu 250: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l: A. C2H6 v C3H8 B. C3H6 v C4H8 C. CH4 v C2H6 D. C2H4 v C3H6 Cu 251: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l: A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH C. C2H5COOH v C3H7COOH D. HCOOH v C2H5COOH Cu 252: ho 0,15 mol H2NC3H5(COOH) (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l: A. 0,50 B. 0,65 C. 0,70 D. 0,55 Cu 253: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l: A. 7,20 B. 6,66 C. 8,88 D. 10,56 Cu 254: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l: A. 8 v 1,0 B. 8 v 1,5 C. 7 v 1,0 D. 7 v 1,5 Cu 255: T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l: A. 80% B. 10% C. 90% D. 20% Cu 256: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l: A. 10,9 B. 14,3 C. 10,2 D. 9,5 Cu 257: Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l: A. axit propanoic B. axit metanoic C. axit etanoic D. axit butanoic Cu 258: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l: A. CH2=CH-NH-CH3 B. CH3-CH2-NH-CH3 C. CH3-CH2-CH2-NH2 D. CH2=CH-CH2-NH2 Cu 259: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H 2 (iu kin tiu chun). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l: A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH C. C2H5COOH v C3H7COOH D. C2H7COOH v C4H9COOH Cu 269: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l: A. CH3-CH2-CH(OH)-CH3 B. CH3-CH2-CH2-CH2-OH C. CH3-CH2-CH2-OH D. CH3-CH(OH)-CH3
Cu 261: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l: A. CH3OCO-CH2-COOC2H5 B. C2H5OCO-COOCH3 C. CH3OCO-COOC3H7 D. CH3OCO-CH2-CH2-COOC2H5 Cu 262: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (iu kin tiu chun) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l: A. 0,015 B. 0,010 C. 0,020 D. 0,005 Cu 263: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l: A. 120 B. 60 C. 30 D. 45 Cu 264: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l: A. C3H5COOH v 54,88% B. C2H3COOH v 43,90% C. C2H5COOH v 56,10% D. HCOOH v 45,12% Cu 265: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o iu kin tiu chun). Cng thc ca ankan v anken ln lt l: A. CH4 v C2H4 B. C2H6 v C2H4 C. CH4 v C3H6 D. CH4 v C4H8 Cu 266: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l: A. 65,2% B. 16,3% C. 48,9% D. 83,7% Cu 267: Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO 2 (iu kin tiu chun) v 7,2 gam H2O. Hirocacbon Y l: A. CH4 B. C2H2 C. C3H6 D. C2H4 Cu 268: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l: A. 0,1 B. 0,4 C. 0,3 D. 0,2 Cu 269: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l: A. metyl propionat B. metyl axetat C. etyl axetat D. vinyl axetat Cu 270: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l: A. 4 B. 5 C. 8 D. 9 Cu 271: t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o iu kin tiu chun). Gi tr ca V l: A. 14,56 B. 15,68 C. 11,20 D. 4,48 Cu 272: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m + 30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m + 36,5) gam mui. Gi tr ca m l: A. 112,2 B. 165,6 C. 123,8 D. 171,0
Cu 273: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc tc Ni, t0 )?. A. 3 B. 5 C. 2 D. 4 Cu 274: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l: A. HCOOH v CH3OH B. CH3COOH v CH3OH C. HCOOH v C3H7OH D. CH3COOH v C2H5OH Cu 275: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l: A. Gly-Phe-Gly-Ala-Val B. Gly-Ala-Val-Val-Phe C. Gly-Ala-Val-Phe-Gly D. Val-Phe-Gly-Ala-Gly Cu 276: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l: A. H2NCH2CH2CH2CH2NH2 B. CH2CH2CH2NH2 C. H2NCH2CH2NH2 D. H2NCH2CH2CH2NH2 Cu 277: t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (iu kin tiu chun) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l: A. 7,85 gam B. 7,40 gam C. 6,50 gam D. 5,60 gam Cu 278: Cho hn hp kh X gm HCHO v H2 i qua ng sng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( iu kin tiu chun). Phn trm theo th tch ca H 2 trong X l: A. 46,15% B. 35,00% C. 53,85% D. 65,00% Cu 279: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l: A. C3H5(OH)3 v C4H7(OH)3 B. C2H5OH v C4H9OH C. C2H4(OH)2 v C4H8(OH)2 D. C2H4(OH)2 v C3H6(OH)2 Cu 280: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l: A. CH3COOCH3 v CH3COOC2H5 B. C2H5COOC2H5 C. CH3COOC2H5 v CH3COOC3H7 D. HCOOCH3 v HCOOC2H5 Cu 281: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l: A. 3 B. 6 C. 4 D. 5 Cu 282: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l: A. 4 B. 8 C. 5 D. 7 Cu 283: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( iu kin tiu chun) v a gam H2O. Biu thc lin h gia m, a v V l: V V V V A. m 2a B. m 2a C. m a D. m a 22, 4 11, 2 5,6 5,6 Cu 284: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l: A. 20,0 B. 30,0 C. 13,5 D. 15,0
Cu 285: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( iu kin tiu chun). S mol, cng thc phn t ca M v N ln lt l: A. 0,1 mol C2H4 v 0,2 mol C2H2 B. 0,2 mol C2H4 v 0,1 mol C2H2 C. 0,1 mol C3H6 v 0,2 mol C3H4 D. 0,2 mol C3H6 v 0,1 mol C3H4 Cu 286: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO 2 ( iu kin tiu chun) v 7,2 gam H2O. Hai ancol l: A. C2H5OH v CH2=CH-CH2-OH B. C2H5OH v CH3OH C. CH3OH v C3H7OH D. CH3OH v CH2=CH-CH2-OH Cu 287: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO 3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t 0) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l: A. CnH2n(CHO)2 (n 0) B. CnH2n + 1CHO (n 0) C. CnH2n 1CHO (n 2) D. CnH2n 3CHO (n 2) Cu 288: X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H 2SO4 c 1400C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l: A. 4,05 B. 8,10 C. 18,00 D. 16,20 Cu 289: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa B. HCOONa, CHC-COONa v CH3-CH2-COONa C. CH2=CH-COONa, HCOONa v CHC-COONa D. CH3-COONa, HCOONa v CH3-CH=CH-COONa Cu 290: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O 2 ( iu kin tiu chun). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l: A. 9,8 v propan-1,2-iol B. 4,9 v propan-1,2-iol C. 4,9 v propan-1,3-iol D. 4,9 v glixerol Cu 291: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( iu kin tiu chun). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-COOH B. HCOOH, HOOC-CH2-COOH C. HCOOH, C2H5COOH D. HCOOH, CH3COOH Cu 292: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH to ra kt ta l: A. 3 B. 4 C. 5 D. 2 Cu 293: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l: A. 10,8 B. 9,4 C. 8,2 D. 9,6 Cu 294: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l: A. HCOOC(CH3)=CHCH3 B. CH3COOC(CH3)=CH2 C. HCOOCH2CH=CHCH3 D. COOCH=CHCH2CH3
Cu 295: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l: A. etylen glicol B. axit aipic C. ancol o-hiroxibenzylic D. axit 3-hiroxipropanoic Cu 296: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( iu kin tiu chun), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l: A. C2H4O2 v C5H10O2 B. C2H4O2 v C3H6O2 C. C3H4O2 v C4H6O2 D. C3H6O2 v C4H8O2 Cu 297: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( iu kin tiu chun). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l: A. CH3COOH v CH3COOC2H5 B. C2H5COOH v C2H5COOCH3 C. HCOOH v HCOOC2H5 D. HCOOH v HCOOC3H7 Cu 298: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l: A. H2N=NC2H3(COOH)2 B. H2NC3H5(COOH)2 C. (H2N)2C3H5COOH D. H2NC3H6COOH Cu 299: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H NCH COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l: A. CH3OH v NH3 B. CH3OH v CH3NH2 C. CH3NH2 v NH3 D. C2H5OH v N2 Cu 300: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( iu kin tiu chun). Cng thc cu to ca X l: A. O=CH-CH2-CH2OH B. HOOC-CHO C. CH3COOCH3 ` D. HCOOC2H5 Cu 301: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l: A. 3 B. 1 C. 2 D. 4 Cu 302: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H bng 13. Cng thc cu to ca anken l: A. CH2=C(CH3)2 B. CH2=CH2 C. CH2=CH-CH2-CH3 D. CH3-CH=CH-CH3 Cu 303: t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( iu kin tiu chun). Bit X c phn ng vi Cu(OH) 2 trong mi trng kim khi un nng. Cht X l: A. O=CH-CH=O B. CH2=CH-CH2OH C. CH3COCH3 D. C2H5CHO Cu 304: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H 2 ( iu kin tiu chun). Cng thc cu to thu gn ca X l: A. HO-C6H4-COOCH3 B. CH3-C6H3(OH)3 C. HO-CH2-C6H4-OH D. HO-C6H4-COOH
Cu 305: Cho hn hp X gm CH4, C2H4 v C2H4. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( iu kin tiu chun) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l: A. 20% B. 50% C. 25% D. 40% Cu 306: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H 2 ( iu kin tiu chun). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l: A. HOOC-CH2-COOH v 70,87% B. HOOC-CH2COOH v 54,88% C. HOOC-COOH v 60,00% D. HOOC-COOH v 42,86% Cu 307: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO B. HOCH2CH2CHO v HOCH2CH2CH2CHO C. HOCH(CH3)CHO v HOOCCH2CHO D. HCOOCH3 v HCOOCH2CH3 Cu 308: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l: A. 27,75 B. 24,25 C. 26,25 D. 29,75 Cu 309: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( iu kin tiu chun). Gi tr ca m l: A. 17,8 B. 24,8 C. 10,5 D. 8,8 Cu 310: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l: A. but-1-en B. xiclopropan C. but-2-en D. propilen Cu 311: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br 2 theo t l mol 1 : 1. Cng thc cu to ca X l: A. HO-CH2-CH2-CH=CH-CHO B. HOOC-CH=CH-COOH C. HO-CH2-CH=CH-CHO D. HO-CH2-CH2-CH2-CHO Cu 312: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 54 gam Ag. Gi tr ca m l: A. 15,3 B. 13,5 C. 8,1 D. 8,5 Cu 313: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l: A. 0,56 gam B. 1,44 gam C. 0,72 gam D. 2,88 gam Cu 314: Cho dung dch X cha hn hp gm CH 3COOH 0,1M v CH3COONa 0,1M. Bit 250C, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l: A. 1,00 B. 4,24 C. 2,88 D. 4,76 Cu 315: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l: A. 113 v 152 B. 113 v 114 C. 121 v 152 D. 121 v 114
Cu 316: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l: A. 8,64 gam B. 6,80 gam C. 6,84 gam D. 4,90 gam Cu 317: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thigian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( iu kin tiu chun) c t khi so vi O 2 l 0,5. Khi lng bnh dung dch brom tng l: A. 1,64 gam B. 1,20 gam C. 1,04 gam D. 1,32 gam Cu 318: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l: A. 16,80 gam B. 18,60 gam C. 20,40 gam D. 18,96 gam Cu 319: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag 2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, iu kin tiu chun). Cng thc ca X l: A. C3H7CHO B. HCHO C. C4H9CHO D. C2H5CHO Cu 320: Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau: - Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X) Pht biu khng ng l: A. un Z vi dung dch H2SO4 c 1700C thu c anken. B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO 2 v 2 mol H2O. C. Cht Y tan v hn trong nc. D. Cht X thuc loi este no, n chc Cu 321: Sng phn este ng vi cng thc phn t C4H8O2 l: A. 4 B. 5 C. 6 D. 2 Cu 322: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H 2 c s mol bng s mol Z phn ng. Cht X l anehit: A. khng no (cha mt ni i C=C), n chc. B. no, n chc. C. khng no (cha mt ni i C=C), hai chc. D. no, hai chc Cu 323: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l: A. 2 B. 4 C. 1 D. 3 Cu 324: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l: A. 8,8 B. 7,8 C. 9,2 D. 7,4 Cu 325: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l: A. 5 B. 4 C. 3 D. 2 Cu 326: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l: A. 3 B. 5 C. 4 D. 2
Cu 327: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H 2 bng 12. Cng thc phn t ca X l: A. C6H14 B. C4H10 C. C3H8 D. C5H12 Cu 328: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l: A. 2,25 gam B. 1,80 gam C. 1,44 gam D. 1,82 gam Cu 329: S ng phn xeton ng vi cng thc phn t C5H10O l: A. 6 B. 5 C. 3 D. 4 Cu 330: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l: A. CH3COO(CH2)2COOC2H5 B. CH3OOC(CH2)2COOC2H5 C. CH3OOC(CH2)2COOC3H7 D. CH3COO(CH2)2OOCC2H5 Cu 331: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH , c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l: A. 76,6% B. 80,0% C. 70,4% D. 65,5% Cu 332: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2 . Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o iu kin tiu chun): A. CH4 v C3H6 B. C2H6 v C3H6 C. CH4 v C3H4 D. CH4 v C2H4 Cu 333: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l: A. C12H16O12 B. C6H8O6 C. C3H4O3 D. C9H12O9 Cu 334: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l: A. 16,68 gam B. 18,24 gam C. 18,38 gam D. 17,80 gam Cu 335: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu cn chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l: A. 46 B. 85 C. 45 D. 68 Cu 336: un nng mt ru (ancol) n chc X vi dung dch H 2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y A. C3H8O B. C4H8O C. C2H6O D. CH4O Cu 337: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l: A. H2NCH2COOCH3 B. CH2=CHCOONH4 C. HCOOH3NCH=CH2 D. H2NCH2CH2COOH Cu 338: Khi t chy hon ton mt este no, n chc th s mol CO 2 sinh ra bng s mol O2 phn ng. Tn gi ca este l: A. metyl fomiat B. etyl axetat C. n-propyl axetat D. metyl axetat Cu 339: Hirocacbon mch hX trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l: A. 4 B. 2 C. 3 D. 5 Cu 340: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml). A. 4,5 kg B. 5,4 kg C. 6,0 kg D. 5,0 kg
Cu 341: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO 3 b hao ht l 20 %): A. 81 lt B. 49 lt C. 70 lt D. 55 lt Cu 342: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 1400C. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l: A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C. C3H7OH v C4H9OH D. C3H5OH v C4H7OH Cu 343: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l: A. C2H5COOH B. CH3COOH C. HCOOH D. C3H7COOH Cu 344: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng: A. ankin B. ankan C. ankaien D. anken Cu 345: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l: A. C2H4 B. CH4 C. C2H6 D. C3H8 + Cu 346: Mui C6H5N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-50C). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l: A. 0,1 mol v 0,1 mol B. 0,1 mol v 0,4 mol C. 0,1 mol v 0,2 mol D. 0,1 mol v 0,3 mol Cu 347: Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H 2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, (CH3)2CO, CH3=CH-CH2OH B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH D. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO Cu 348: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l: A. 0,92 B. 0,32 C. 0,64 D. 0,46 Cu 349: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l: A. 1 B. 4 C. 3 D. 2 Cu 350: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,90C, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l: A. C2H4O2 B. CH2O2 C. C4H8O2 D. C3H6O2 Cu 351: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C 2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l: A. 2 B. 5 C. 4 D. 3 Cu 352: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l: A. 2 B. 4 C. 3 D. 1 Cu 353: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l: A. 42 kg B. 10 kg C. 30 kg D. 21 kg
Cu 354: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( iu kin tiu chun), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l: A. 8,96 B. 11,2 C. 6,72 D. 4,48 Cu 355: l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l: A. HCOOCH2CH2CH3 B. C2H5COOCH3 C. CH3COOC2H5 D. HCOOCH(CH3)2 Cu 356: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l: A. CH3COOH B. HCOOH C. C2H5COOH D. C3H7COOH Cu 357: Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l: A. 6 B. 3 C. 5 D. 4 Cu 358: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l: A. C2H5C6H4OH B. OHCH2C6H4COOH C. HOC6H4CH2OH D. C6H4(OH)2 Cu 359: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l: A. C2H4(OH)2 B. C3H7OH C. C3H5(OH)3 D. C3H6(OH)2 Cu 360: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l: A. 4 B. 6 C. 5 D. 3 Cu 361: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO 2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit: A. no, n chc B. khng no c hai ni i, n chc C. khng no c mt ni i, n chc D. no, hai chc Cu 362: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l: A. HCOOC2H5 v CH3COOCH3 B. C2H3COOC2H5 v C2H5COOC2H3 C. C2H5COOCH3 v HCOOCH(CH3)2 D. HCOOCH2CH2CH3 v CH3COOC2H5 Cu 363: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c thiu ch trc tip ra Y. Vy cht X l: A. ru metylic B. etyl axetat C. axit fomic D. ru etylic Cu 364: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l: A. HCHO B. C2H3CHO C. C2H5CHO D. CH3CHO Cu 365: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l: A. 3,3-imetylhecxan B. 2,2-imetylpropan C. isopentan D. 2,2,3-trimetylpentan Cu 366: Oxi ho 4,48 lt C2H4 ( iu kin tiu chun) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l: A. 70% B. 50% C. 60% D. 80% (Matdanh_LHVH_CCHM)
-------THE END------ng bao gi nhng tht vng ca ngy hm qua che m nhng gic m rc sang ca ngy mai

Tai Lieu On Thi Dai Hoc Mon Hoa Nam 2012MatdanhLHVHCCHM

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Tai Lieu On Thi Dai Hoc Mon Hoa Nam 2012MatdanhLHVHCCHM

Uploaded by

Copyright:

Available Formats

TI LIU N THI I HC MN HA NM 2012 Mn: HA HC; Khi A, B

A. 18,6 gam Cu 123: 1, : A. 240,8 gam C. 193,6 gam Cu 124:

B. 20,4 gam (xc tc

A. 1,04 gam Cu 125:

iu kin tiu chun). A. CH4 C. CH4 Cu 126:

B. C2H6 D. C2H6 iu kin tiu chun

B. C2H2 D. C2H2 Trang 12 - Cunconhocmai

A. C2H5 C. C2H5 Cu 128:

A. 13,26 gam Cu 129:

; 27,58% 4H8 ; 27,58%

; 28,57% 4H8 ; 28,57%

: B. 40% 2H2, C2H6

B. 4 iu kin tiu chun

iu kin tiu chun)

: B. 13,44 C. 5,60 D. 8,96 0,6 mol CO2 0,3 mol H2 3/NH3

: A. 3-metyl penta-1,4-iin C. Hexa-1,3-ien-5-in Cu 141: B. Hexa-1,5-iin D. ,

: A. 93,00 gam Cu 142: A. C4H6 Cu 143: A. 5 Cu 144:

D. 103,60 gam 2O/NH3 : D. C4H4 : D. 8

: A. C5H12 B. C4H10 Cu 145:

B. C5H12 D. C4H10 6,16 gam CO2

1,62 gam H2 CCH2CH3 3C CCH3 (iu kin tiu chun

B. CH D. CH3C 3,55 gam Cl2

1,27 gam 1,13 gam 2/H2

: A. CH2=C=CHC CH C. CH3C CCH2C CH Cu 148:

B. CH CCH2C CH D. CH3C CCH2C CH (iu kin tiu chun

: A. 1,12 gam B. 2,24 gam C. 0,42 gam D. 0,56 gam

A. 25% Cu 152: A. 11,58 Cu 153:

: B. 60% 8,8g C3H8 ta thu 90% C3H8 B. 15,58

B. 50% (iu kin tiu chun B. 85%

D. 40% (iu kin tiu chun

10,8 gam H2 C. 90% D. 95%

14,4g H2 B. CH3CH(CH3)2 D. CH3CH2CH2CH3

? A. CH3CH2CH2CH2CH3 C. CH3CH2CH(CH3)2 Cu 156:

A. 195 gam Cu 158:

Cu 158: : A. CH4O Cu 159:

(CH3O)n B. C3H8O3 13,75). : B. 8,8 C. 7,4 D. 9,2 O2 C. C2H6O2 D. C4H12O4

A. C2H5C6H4OH C. HOCH2C6H4COOH Cu 161:

1 : 1. Cng t : A. C6H5CH(OH)2 Cu 162: : A. 3 Cu 163: AgNO3 B. 4 1,2 gam CH3 , H2 3

B. C2H6 D. C2H6 (OH)2

: C. OHC CHO D. CH3CH(OH)CHO o ra b mol CO2 2

CuCl2 7,1 gam CH3 : D. 80% :

B. D. CH3 Trang 17 - Cunconhocmai

You might also like