Ti liu bi dng kin thc ph thng

-1-

Trn Ngc Phc_ THPT Vinh Xun

AMIN_ ANILIN.
Kin thc c bn: .
I. AMIN: 1. Khi nim v amin: Thay nguyn t H trong phn t NH3 bng gc hydrocacbon.
CH3

CH3-NH2 (am ba 1); CH3-NH (am ba 2); CH3-N in c in c

CH3 CH3

(am ba 3); C6H5-NH2 (am thm in c in )

2. Cng thc tng qut amin bc I: CnH2n+2-2k-x(NH2)x hay CnH2n+2-2k+xNx trong n l s nguyn t C (n 1, nguyn); k l tng s lin kt v vng c trong phn t (k 0); x l s nhm amino ( cng chnh l s nguyn t N) tha mn 1. 3. Bc amin: + Mt nguyn t H trong NH3 b thay th bng gc HC, ta c amin bc I: CH3 NH2; C6H5 NH2 + Hai nguyn t H trong NH3 b thay th bng gc HC, ta c amin bc II: CH3NHCH2CH3 (Etylmetyl amin) + Ba nguyn t H trong NH3 b thay th bng gc HC, ta c amin bc III: (CH3)3N 4. Gi tn: Tn gc-chc: tn gc hyrocacbon + amin. VD. (CH3)2NH imetylamin ; C6H5 NH2 phenylamin Tn thay th: CH3NH2: metanamin ; (CH3)2NH: N-metylmetan amin ; CH3CH2CH(NH)2CH3 : butan-2-amin Mt s tn vn dng: C6H5 NH2 Anilin CH3 C6H4 NH2 (o - ; m-; p -) Toluin. 5.Tnh cht chung: + Amin c tnh baz: CH3NH2 + HCl CH3NH3Cl + Dung dch amin mch h lm i mu qu tm sang xanh. + Amin phn ng vi axit to mui. II. ANILIN (C6H7N; C6H5NH2; M = 93) NH2 NH2 1. Cng thc cu to.
Cog th ca ta n c u o C6H5-NH2

2.Tnh cht: - Lng khng mu, lu trong khng kh ng sang mu nu en v b xiha, hi nng hn nc, rt t tan trong nc, tan nhiu trong ru v benzen ,te...c, c mi kh chu. * L mt baz yu, do nh hng nhm NH 2 m vng benzen d dng tham gia phn ng th vi nhiu cht (halogen, HNO3) a.Tnh Baz : C6H5-NH2 + HCl C6H5-NH2.HCl (phenylamoni clorua) *Tnh baz ca Anilin < NH3 (do nhmC6H5- l nhm ht electron) cho nn Anilin khng lm xanh qu tm. *Dung dch kim c th y anilin ra khi mui: C6H5-NH3Cl + NaOH C6H5- NH2 + NaCl + H2O b. Phn ng th nhn thm.
NH2 Br NH2 Br

3 Br2

3HBr

Br

2,4,6-tribrom anilin

3. iu ch:

C6H5- NO2 + 6[H]

Fe , HCl

>

C6H5- NH2 + 2H2O

. Bi tp vn dng:
L Thuyt. Cu 1. Cng thc ca amin cha 15,05% khi lng nit l: A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3NH Cu 2. Cng thc phn t C3H9N c bao nhiu ng phn? A. hai ng phn B. bn ng phn C. ba ng phn D. nm ng phn Cu 3. Cho amin c cng thc cu to: CH3-CH(CH3)-NH2. Tn ng ca amin l: A. n-propylamin B. etylamin C. imetylamin D. isopropylamin Cu 4. C bao nhiu ng phn amin ng vi cng thc phn t C3H7N ? A. 1 ng phn B. 5 ng phn C. 4 ng phn D. 3 ng phn Cu 5. Ch ra cu sai trong s cc cu sau y: A. Etylamin d tan trong nc do c lin kt hidro nh sau (Et: etyl):
H N Et H O H H H N Et H

B. Tnh cht ho hc ca etylamin l c kh nng to mui vi baz mnh. C. Etylamin tan trong nc to dung dch c kh nng sinh ra kt ta vi dung dch FeCl3. D. Etylamin c tnh baz do nguyn t nit cn cp electron cha lin kt c kh nng nhn proton. Cu 6. Tn gi ca C6H5NH2 l:
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

Ti liu bi dng kin thc ph thng

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Trn Ngc Phc_ THPT Vinh Xun

A. Benzil amoni B. Benzyl amoni C. Hexyl amoni D. Anilin Cu 7. Pht biu no sau y khng ng? A. Amin c cu thnh bng cch thay th H ca amoniac bng mt hay nhiu gc hidrocacbon. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc cu trc ca gc hidrocacbon c th phn bit amin thnh amin no, cha no v thm. D. Amin c t hai nguyn t cacbon trong phn t bt u xut hin hin tng ng phn. Cu 8. Amin no di y l amin bc hai? A. CH3-CH2-NH2 B. (CH3)2CH-NH2 C. CH3-NH-CH3 D. (CH3)N-CH2CH3 Cu 9. Cng thc no di y l cng thc cho dy ng ng amin thm (cha 1 vng benzen), n chc, bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 10. Tn gi ca amin no sau y khng ng? A. CH3NHCH3 , dimetylamin B. CH3CH2CH2NH2 , n-propylamin C. (CH3)2CHNH2 , propylamin D. C6H5NH2 , anilin Cu 11.Amin no di y c bn ng phn cu to? A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 12. Pht biu no di y v tnh cht vt l ca amin l khng ng? A. Metyl-, etyl-, dimetyl-, trimetylamin l nhng cht kh, d tan trong nc. B. Cc amin kh c mi tng t amoniac, c. C. Anilin l cht lng, kh tan trong nc, mu en. D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng. Cu 13. Cc gii thch quan h cu trc - tnh cht no sau khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do -NH2 y electron nn anilin d tham gia phn ng th vo nhn thm v u tin v tr o-, p-. C. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin RNH2, gc R- ht electron lm tng mnh tnh baz v ngc li. Cu 14. Nhn xt no di y khng ng ? A. Phenol l axit cn anilin l baz B. Dung dch phenol lm qu tm ho axit cn cn dung dch anilin lm qu tm ho xanh. C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dd brom. D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hidro. Cu 15. S d anilin c tnh baz yu hn NH3 l do: A. nhm NH2 cn mt cp electron cha lin kt. B. nhm NH2 c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. phn t khi ca anilin ln hn so vi NH3. Cu 16. Hy ch ra iu sai trong cc nhn xt sau: A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng vi axit cho mui D. Amin l hp cht hu c c tnh cht lng tnh Cu 17. Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. Dimetylamin Cu 18. Cht no sau y c tnh baz mnh nht? A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 Cu 19. Sp xp cc hp cht sau theo th t gim dn tnh baz: (1)C6H5NH2; (2)C2H5NH2; (3)(C6H5)NH; (4)(C2H5)2NH (5)NaOH ; (6) NH3. A. (1) > (3) > (5) > (4) > (2) > (6) B. (6) > (4) > (3) > (5) > (1) > (2) C. (5) > (4) > (2) > (1) > (3) > (6) D. (5) > (4) > (2) > (6) > (1) > (3) Cu 20. Tnh baz gim dn theo dy sau: A. imetylamin; metylamin; amoniac; p-metylanilin; anilin; p-nitroanilin B. imetylamin; metylamin; anilin; p-nitroanilin; amoniac; p-metylanilin C. p-nitroanilin; anilin; p-metylanilin; amoniac; metylamin; imetylamin D. anilin; p-metylanilin; amoniac; metylamin; imetylamin; p-nitroanilin Cu 21. Tnh baz ca cc cht tng dn theo th t: A. C6H5NH2; NH3; CH3NH2; (CH3)2NH B. NH3; CH3NH2; (CH3)2NH; C6H5NH2 C. (CH3)2NH; CH3NH2; NH3; C6H5NH2 D. NH3; C6H5NH2; (CH3)2NH; CH3NH2 Cu 22. Tnh baz ca cc cht tng dn theo th t: A. NH3 < C6H5NH2 < CH3NHCH3 < CH3CH2NH2 B. NH3 < CH3CH2NH2 < CH3NHCH3< C6H5NH2 C. C6H5NH2 < NH3 < CH3CH2NH2 < CH3NHCH3 D. C6H5NH2 < NH3 < CH3NHCH3 < CH3CH2NH2 Cu 23. Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

Ti liu bi dng kin thc ph thng

3+ +

-3-

Trn Ngc Phc_ THPT Vinh Xun

C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 24. Dung dch cht no di y khng lm i mu qu tm? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 Cu 25. Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. 3CH3NH2 + 3H2O + FeCl3 Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe + 7HCl C6H5NH3Cl + 3FeCl2 + 2H2O Cu 26. Dung dch etylamin tc dng c vi dung dch nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 27. Dung dch etylamin khng tc dng vi: A. axit HCl B. dung dch FeCl3 C. nc brom D. Cu(OH)2 Cu 28. Dung dch etylamin tc dng c vi: A. giy o pH B. dung dch AgNO3 C. Thuc th Felinh D. Cu(OH)2 Cu 29. Dung dch nc brom khng phn bit c hai cht trong cp no sau y? A. Dung dch anilin v dung dch amoniac B. Anilin v xiclohexylamin (C6H11NH2) C. Anilin v phenol D. Anilin v benzen Cu 30. Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l: A. 3. B. 2. C. 1. D. 4. Cu 31. Cho dung dch metylamin n d vo cc dung dch sau: FeCl3, CuSO4, Zn(NO3)2, CH3COOK th s lng kt ta thu c l: A. 0. B. 1. C. 2. D. 3. Cu 32. Hp cht hu c X to bi cc nguyn t C, H v N. X l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO2 v c th tc dng vi nc Br2 to ra kt ta. Cng thc phn t ca X l A. C2H7N. B. C6H13N. C. C6H7N. D. C4H12N2. Cu 33. Nhn nh no sau y khng ng? A. Cc amin u c tnh baz. B. Tnh baz ca cc amin u mnh hn NH3. C. Metyl amin c tnh baz mnh hn anilin. D. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk. Cu 34. Cc hin tng no sau y c m t khng chnh xc? A. Nhng qu tm vo dung dch etyl amin thy qu chuyn mu xanh. B. Phn ng gia kh metyl amin v kh hidroclorua lm xut hin "khi trng". C. Nh vo git nc brom vo ng nghim ng dung dch anilin thy c kt ta trng. D. Thm vi git phenol phtalein vo dung dch dimetyl amin xut hin mu xanh. Cu 35. Khng th dng thuc th trong dy no sau y phn bit cc cht lng phenol, anilin v benzen? A. Dung dch brom B. Dung dch HCl v dung dch NaOH C. Dung dch HCl, dung dch brom D. Dung dch NaOH, dung dch brom Cu 36. tch ring hn hp kh CH4 v CH3NH2 ta dng: A. HCl. B. HCl, NaOH. C. NaOH, HCl. D. HNO2. Cu 37. tinh ch anilin t hn hp phenol, anilin, benzen, cch thc hin no di y l hp l? A. Ha tan trong dung dch HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan trong dung dch brom d, lc kt ta, halogen ha thu c anilin. C. Ha tan trong dung dch NaOH d, chit phn tan, thi CO2 vo n d thu c anilin tinh khit. D. Dng dung dch NaOH tch phenol, sau dng brom tch anilin ra khi benzen. Cu 38. Cch thun li nht nhn bit l ng dung dch CH3NH2 l A. nhn bit bng mi. B. thm vi git dung dch H2SO4. C. thm vi git dung dch Na2CO3 D. a u a thu tinh nhng vo dung dch HCl m c ln pha trn ming l ng dung dch CH3NH2. Cu 39. phn bit phenol, anilin, benzen, stiren ngi ta ln lt s dng cc thuc th: A. Qu tm, dung dch brom B. Dung dch NaOH, dung dch brom C. Dung dch brom, qu tm D. Dung dch HCl, qu tm t chy hon ton amin no n chc X, thu c 16,8 lt CO2 ; 2,8 lt N2 (ktc) v 20,25 g H2O. Cng thc phn t ca X l. A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. Cu 41. Trung ho 3,1 gam mt amin n chc X cn 100 ml dung dch HCl 1 M. X l: A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 42. t chy hon ton mt amin no, n chc, mch h thu c t l khi lng ca CO2 so vi nc l 44 : 27. Cng thc phn t ca amin l A. C3H7N B. C3H9N C. C4H9N D. C4H11N
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

Ton c bn Cu 40.

Ti liu bi dng kin thc ph thng

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Trn Ngc Phc_ THPT Vinh Xun

t chy mt ng ng ca metylamin, ngi ta thy t l th tch cc kh v hi ca sn phm sinh ra VCO2 : VH2O = 2 : 3. Cng thc phn t ca amin l: A. C3H9N B. CH5N C. C2H7N D. C4H11N Cu 44. t chy hon ton mt amin cha no, n chc cha mt lin kt C=C thu c CO2 v H2O theo t l mol nCO2 : nH2O = 8 : 9. Cng thc phn t ca amin l: A. C3H6N B. C4H8N C. C4H9N D. C3H7N Cu 45. t chy hon ton mt amin n chc, bc mt thu c CO 2 v H2O theo t l mol nCO2 : nH2O = 6 : 7. Amin c th c tn gi l: A. propylamin B. phenylamin C. isopropylamin D. propenylamin Cu 46. trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H7N B. CH5N C. C3H5N D. C3H7N Cu 47. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxy (ktc). Cng thc ca amin l: A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 48. Cho 9,3 gam mt ankylamin tc dng vi dung dch FeCl 3 d thu c 10,7 gam kt ta. Ankylamin l: A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 Cu 49. t chy hon ton 100 ml hn hp gm imetylamin v 2 hydrocacbon ng ng k tip thu c 140 ml CO2 v 250 ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca 2 hydrocacbon l: A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 50. t chy hon ton hn hp 2 amin no n chc ng ng lin tip, ta thu c t l th tch VCO2 : VH2O(h) ( cng k) = 8 : 17. Cng thc ca 2 amin l: A. C2H5NH2 , C3H7NH2 B. C3H7NH2 , C4H9NH2 C. CH3NH2 , C2H5NH2 D. C4H9NH2 , C5H11NH2 Cu 51. t chy hon ton mt amin n chc X c 8,4 lt CO 2, 1,4 lt N2 (cc th tch kh c o ktc) v 10,125 gam H2O. Cng thc ca X l A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. Cu 52. Cho 1,52 gam hn hp hai amin n chc no (c trn vi s mol bng nhau) tc dng va vi 200 ml dung dch HCl; thu c 2,98g mui. Kt lun no sau y khng chnh xc? A. Nng mol dung dch HCl bng 0,2 M B. S mol mi cht l 0,02 mol C. Cng thc ca hai amin l CH5N v C2H7N D. Tn gi hai amin l metylamin v etylamin Cu 53. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l: A. 100 ml B. 50 ml C. 200 ml D. 320 ml Cu 54. Cho 20 gam hn hp gm 3 amin no n chc, ng ng lin tip tc dng va vi dung dch HCl 1M, c cn dung dch thu c 31,68 gam hn hp mui. Bit phn t khi cc amin u < 80, cng thc phn t ca cc amin l A. CH3NH2 ; C2H5NH2 v C3H7NH2 B. C2H3NH2 ; C3H5NH2 v C4H7NH2 C. C2H5NH2 ; C3H7NH2 v C4H9NH2 D. C3H7NH2 ; C4H9NH2 v C5H11NH2 Cu 55. Cho 11,25 gam C2H5NH2 tc dng vi 200 ml dung dch HCl x(M). Sau khi phn ng xong thu c dung dch c cha 22,2 gam cht tan. Gi tr ca x l A. 1,3M B. 1,25M C. 1,36M D. 1,5M Cu 56. Phn tch nh lng 0,15 g hp cht hu c X thy t l khi lng C : H : O : N l 4,8 : 1: 6,4 : 2,8. Nu phn tch nh lng m g cht X th t l khi lng C : H : O : N l: A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 Cu 57. Ngi ta iu ch anilin bng cch nitro ho 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on l 78%? A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 58. Cho m gam alanin phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c 11,1 gam. Gi tr m dng l (Cho H = 1, C = 12, O = 16, Na = 23) A. 9,9 gam. B. 9,8 gam. C. 8,9 gam. D. 7,5 gam. Cu 59. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H 2SO4 long, lng mui thu c bng: A. 7,1 gam B. 14,2 gam C. 19,1 gam D. 28,4 gam Cu 60. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br 2 to kt ta. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt bng: A. 0,01 mol; 0,005 mol v 0,02 mol B. 0,005 mol; 0,005 mol v 0,02 mol C. 0,005 mol; 0,02 mol v 0,005 mol D. 0,01 mol; 0,005 mol v 0,02 mol
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

Cu 43.

Ti liu bi dng kin thc ph thng

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Trn Ngc Phc_ THPT Vinh Xun

BT Nng cao.
1. Pht biu khng ng l A. Axit axetic phn ng vi NaOH, ly mui thu c cho tc dng vi CO2 li thu c axit axetic. B. Anilin phn ng vi dung dch HCl, ly mui thu c cho tc dng vi dung dch NaOH li thu c anilin. C. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta thu c tc dng vi dung dch NaOH li thu c natri phenolat. D. Phenol phn ng vi dung dch NaOH, ly mui thu c cho tc dng vi dung dch HCl li thu c phenol. 2. Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, anilin, phenylamoniclorua, ancol benzylic, p crezol. Trong cc cht trn, s cht tc dng vi dung dch NaOH l A. 3. B. 4. C. 5. D. 6. 3. Cho cc cht sau: (1) NH3; (2) CH3NH2; (3) (CH3)2NH; (4) C6H5NH2; (5) (C6H5)2NH. Trnh t tng dn tnh baz ca cc cht trn l. A. (4)<(5)<(1)<(2)<(3). B. (1)<(4)<(5)<(2)<(3). C. (5)<(4)<(1)<(2)<(3). D. (1)<(5)<(2)<(3)<(4). C6H6 X C6H5NH2 Y Z C6H5NH2 . X, Y, Z ln lt l 4. Cho s sau: A. C6H5Cl, C6H5NO2, C6H5NH3Cl. B. C6H5NO2, C6H5Br, C6H5NH3Cl. C. C6H5NO2, C6H5NH3Cl, C6H5NH3NO3. D. C6H5CH3, C6H5NO2, (C6H5NH3)2SO4. 5. Dng nc Br2 khng phn bit c 2 cht trong cp no sau y? A. Anilin v amoniac. B. Anilin v phenol. C. Anilin v alylamin(CH2=CHCH2NH2). D. Anilin v stiren. 6. Cho anilin tc dng vi cc cht sau: dung dch Br2, H2, CH3I, dung dch HCl, dung dch NaOH, HNO2. S phn ng xy ra l: A. 3. B. 4. C. 5. D. 6. 7. B thuc th no sau y c th phn bit c cc dung dch mt nhn sau: C2H5NH2, C6H5NH2, glucoz, glixerol: A. Qi tm, dung dch Br2. B. Phenolphtalein, Cu(OH)2. C. AgNO3/NH3, dung dch Br2, qi tm. D. C A, B, C u ng. 8. tinh ch anilin t hn hp phenol, anilin, benzen cch thc hin no di y l ng: A. Ha tan trong dung dch Br2 d, lc ly kt ta, tch halogen c anilin. B. Ha tan trong dung dch HCl d, chit ly phn tan. Thm dung dch NaOH d vo phn tan thu c trn v chit ly anilin tinh khit. C. Dng dung dch NaOH tch phenol, sau dng dung dch Br2 tch anilin ra khi benzen. D. Ha tan trong dung dch NaOH d, chit ly phn tan. Thi CO2 d vo phn tan s c anilin tinh khit. 9. t chy hon ton 1 amin thm X bc 1 c 3,08 gam CO2; 0,99 gam H2O v 336 ml N2 ( ktc). trung ho 0,1 mol X cn 600 ml dung dch HCl 0,5M. Cng thc cu to ca X l A. CH3C6H2(NH2)3. B. H2NCH2C6H3(NH2)2. C. CH3NHC6H3(NH2)2. D. A, B, C u ng 10. trung ho 25 gam dung dch ca 1 amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l: A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N. 11. C hai amin bc 1: X (ng ng ca anilin) v Y (ng ng ca metylamin). t chy hon ton 3,21
gam amin X c 336 ml N2 ( ktc). Khi t chy amin Y thy VCO2 : VH2O = 2:3. Cng thc phn t ca X, Y ln lt l A.C6H5NH2 v C2H5NH2. B.CH3C6H4NH2 v C3H7NH2 C.CH3C6H4NH2 v C2H5NH2. D.C6H5NH2 v C3H7NH2. 12. Cho hn hp X cha NH3, C6H5OH, C6H5NH2. trung ho 1 lt dung dch X cn 0,1 mol HCl hoc 0,01 mol NaOH. Mt khc 1 lt dung dch X phn ng vi nc Br 2 d c 5,41 gam kt ta. Nng mol ca NH 3, C6H5OH v C6H5NH2 c trong dung dch X ln lt l A. 0,036; 0,01; 0,064. B. 0,018; 0,01; 0,032. C. 0,036; 0,02; 0,064. D. 0,09; 0,02; 0,04. 13. t chy hon ton m gam mt amin X bng lng khng kh va , thu c 0,4 mol CO 2; 0,7 mol H2O v 3,1 mol N2. Gi s khng kh ch gm N2 v O2 trong N2 chim 80% th tch. Cng thc phn t ca X l A. CH3NH2. B. C3H7NH2. C. C2H5NH2. D. C4H14N2. 14. Dung dch X cha HCl v H2SO4 c pH = 2. trung ha hon ton 0,59 gam hn hp hai amin no, n chc, bc 1 (c s nguyn t C nh hn hoc bng 4 v cc cht c cng s mol) phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin ln lt l A. CH3NH2 v C4H9NH2. B. C2H5NH2 v C4H9NH2. C. C3H7NH2 v C4H9NH2. D. CH3CH2CH2NH2 v CH3CH(CH3)NH2. 15. t chy hon ton 0,02 mol mt amin bc 1 (X) vi lng O2 va , cho ton b sn phm chy qua bnh cha Ca(OH)2 d thy khi lng bnh tng 3,02 gam v cn li 0,224 lt ( ktc) mt cht kh khng b hp th. Khi lc dung dch thu c 4 gam kt ta. Cng thc cu to ca X l A. CH3CH2NH2. B. (CH2)2(NH2)2. C. CH3CH(NH2)2. D. CH2 = CHNH2. 16. X l hp cht hu c mch h cha cc nguyn t C, H, N trong N chim 23,72%. X tc dng vi dung dch HCl theo t l mol 1:1. X c s ng phn l A. 2. B. 3. C. 4. D. 5.
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17.

Cho 0,76 gam hn hp hai amin no n chc c s mol bng nhau tc dng va vi 200 ml dung dch HCl c 1,49 gam mui. Kt lun no sau y khng chnh xc: A. Nng mol ca dung dch HCl bng 0,1M. B. S mol ca mi cht l 0,01 mol. C. Cng thc ca hai amin l CH5N v C2H7N. D. Tn gi ca hai amin l metylamin v etylamin. 18. t chy hon ton 100 ml hn hp gm imetylamin v 2 hydrocacbon ng ng k tip thu c 140 ml CO 2 v 250 ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng: A. 20%; 20% v 60% B. 25%; 25% v 50% C. 30%; 30% v 40% D. 20%; 60% v 20% 19. (A-CD07) trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N. 20. (H A-09) t chay hoan toan 0,1 mol mt amin no, mach h X bng oxi va u thu c 0,5 mol hn hp Y gm khi va hi. Cho 4,6g X tac dung vi dung dich HCl (d), s mol HCl phan ng la A. 0,1 B. 0,4 C. 0,3 D. 0,2 21. (A-09) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l: A. 8. B. 7. C. 5. D. 4. 22. (H A-10) Hn hp khi X gm imetylamin va hai hirocacbon ng ng lin tip. t chay hoan toan 100 ml hn hp X bng mt lng oxi va u, thu c 550 ml hn hp Y gm khi va hi nc. Nu cho Y i qua dung dich axit sunfuric c (d) thi con lai 250 ml khi (cac th tich khi va hi o cung iu kin). Cng thc phn t cua hai hirocacbon la. A. C2H6 va C3H8 B. C3H6 va C4H8 C. CH4 va C2H6 D. C2H4 va C3H6

BI TP T KIM TRA.
Cu 1: S ng phn amin c cng thc phn t C2H7N l A. 4. B. 3. C. 2. D. 5. Cu 2: S ng phn amin c cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cu 3: S ng phn amin c cng thc phn t C4H11N l A. 5. B. 7. C. 6. D. 8. Cu 4: S ng phn amin bc mt ng vi cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cu 5: S ng phn amin bc mt ng vi cng thc phn t C4H11N l A. 4. B. 3. C. 2. D. 5. Cu 6: C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N ? A. 3 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 7: Anilin c cng thc l A. CH3COOH. B. C6H5OH. C. C6H5NH2. D. CH3OH. Cu 8: Trong cc cht sau, cht no l amin bc 2? A. H2N-[CH2]6NH2 B. CH3CH(CH3)NH2 C. CH3NHCH3 D. C6H5NH2 Cu 9: C bao nhiu amin bc hai c cng cng thc phn t C5H13N ? A. 4 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 10: Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2? A. Metyletylamin. B. Etylmetylamin. C. Isopropanamin. D. Isopropylamin. Cu 11: Trong cc tn gi di y, cht no c lc baz mnh nht ? A. NH3 B. C6H5CH2NH2 C. C6H5NH2 D. (CH3)2NH Cu 12: Trong cc tn gi di y, cht no c lc baz yu nht ? A. C6H5NH2 B. C6H5CH2NH2 C. (C6H5)2NH D. NH3 Cu 13: Trong cc tn gi di y, tn no ph hp vi cht C6H5-CH2-NH2? A. Phenylamin. B. Benzylamin. C. Anilin. D. Phenylmetylamin. Cu 14: Trong cc cht di y, cht no c tnh baz mnh nht ? A. C6H5NH2. B. (C6H5)2NH C. p-CH3-C6H4-NH2. D. C6H5-CH2-NH2 Cu 15: Cht khng c kh nng lm xanh nc qu tm l A. Anilin B. Natri hiroxit. C. Natri axetat. D. Amoniac. Cu 16: Cht khng phn ng vi dung dch NaOH l A. C6H5NH3Cl. B. C6H5CH2OH. C. p-CH3C6H4OH. D. C6H5OH. Cu 17: tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng c,iu kin th nghim y ) l A. dung dch NaOH, dung dch HCl, kh CO2. B. dung dch Br2, dung dch HCl, kh CO2. C. dung dch Br2, dung dch NaOH, kh CO2. D. dung dch NaOH, dung dch NaCl, kh CO2. Cu 18: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit.
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C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 19: Kt ta xut hin khi nh dung dch brom vo A. ancol etylic. B. benzen. C. anilin. D. axit axetic. Cu 20: Cht lm giy qu tm m chuyn thnh mu xanh l A. C2H5OH. B. CH3NH2. C. C6H5NH2. D. NaCl. Cu 21: Anilin (C6H5NH2) phn ng vi dung dch A. NaOH. B. HCl. C. Na2CO3. D. NaCl. Cu 22: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. Cu 23: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A. dung dch NaCl. B. dung dch HCl. C. nc Br2. D. dung dch NaOH. Cu 24: Dung dch metylamin trong nc lm A. qu tm khng i mu. B. qu tm ha xanh. C. phenolphtalein ho xanh. D. phenolphtalein khng i mu. Cu 25: Cht c tnh baz l. A. CH3NH2. B. CH3COOH. C. CH3CHO. D. C6H5OH. Cu 26: Cho 500 gam benzen phn ng vi HNO3 (c) c mt H2SO4 c, sn phm thu c em kh thnh anilin. Nu hiu sut chung ca qu trnh l 78% th khi lng anilin thu c l A. 456 gam. B. 564 gam. C. 465 gam. D. 546 gam. Cu 27: Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 11,95 gam. B. 12,95 gam. C. 12,59 gam. D. 11,85 gam. Cu 28: Cho 5,9 gam etylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu c l A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam. Cu 29: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. Cu 30: Cho anilin tc dng va vi dung dch HCl thu c 38,85 gam mui. Khi lng anilin phn ng l A. 18,6g B. 9,3g C. 37,2g D. 27,9g. Cu 31: Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 32: Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1g. B. 14,2g. C. 19,1g. D. 28,4g. Cu 33: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 8. B. 7. C. 5. D. 4. Cu 34: t chy hon ton 0,2 mol metylamin (CH3NH2), sinh ra V lt kh N2 ( ktc). Gi tr ca V l A. 4,48. B. 1,12. C. 2,24. D. 3,36. Cu 35: t chy hon ton m gam metylamin (CH3NH2), sinh ra 2,24 lt kh N2 ( ktc). Gi tr ca m l A. 3,1 gam. B. 6,2 gam. C. 5,4 gam. D. 2,6 gam. Cu 36: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C 146,1ml. D. 16,41ml. Cu 37: Mt amin n chc c cha 31,111%N v khi lng. Cng thc phn t v s ng phn ca amin tng ng A. CH5N; 1 ng phn. B. C2H7N; 2 ng phn. C. C3H9N; 4 ng phn. D. C4H11N; 8 ng phn. Cu 38: Cho m gam Anilin tc dng ht vi dung dch Br2 thu c 9,9 gam kt ta. Gi tr m dng l A. 0,93 gam B. 2,79 gam C. 1,86 gam D. 3,72 gam Cu 39: Ba cht lng: C2H5OH, CH3COOH, CH3NH2 ng trong ba l ring bit. Thuc th dng phn bit ba cht trn l A. qu tm. B. kim loi Na. C. dung dch Br2. D. dung dch NaOH. Cu 40. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri sang phi l A. CH3NH2, NH3, C6H5NH2. B. CH3NH2, C6H5NH2, NH3. C. C6H5NH2, NH3, CH3NH2. D. NH3, CH3NH2, C6H5NH2. Tham kho (A-CD07) trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C3H5N. B. C2H7N. C. CH5N. D. C3H7N. 24. (H A-09) t chay hoan toan 0,1 mol mt amin no, mach h X bng oxi va u thu c 0,5 mol hn hp Y gm khi va hi. Cho 4,6g X tac dung vi dung dich HCl (d), s mol HCl phan ng la A. 0,1 B. 0,4 C. 0,3 D. 0,2 Gii : Gi CT ca amin: CnH2n+xNx CnH2n+2+ xNx +O2 nCO2 + (n + 1+ 0,5x)H2O + 0,5xN2 0,1 0,1n (n + 1+ 0,5x).0,1 0,5x.0,1 0,2n + 0,1 + 0,1x = 0,5 2n + x = 4 n = 1; x = 2 tha mn: nHCl = 2nCH6N2 = 0,2 mol 25. (A-09) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l
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Ti liu bi dng kin thc ph thng A. 8. mHCl = 15 10 = 5g B. 7. GII C. 5.

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Trn Ngc Phc_ THPT Vinh Xun

D. 4.

5 36,5 10.36, 5 M amin = = 73 5

n amin = nHCl = t cng thc ca amin l RNH2. R + 16 = 73 R = 57 => R l C4H9 => X l C4H9NH2 26. (H A-10) Hn hp khi X gm imetylamin va hai hirocacbon ng ng lin tip. t chay hoan toan 100 ml hn hp X bng mt lng oxi va u, thu c 550 ml hn hp Y gm khi va hi nc. Nu cho Y i qua dung dich axit sunfuric c (d) thi con lai 250 ml khi (cac th tich khi va hi o cung iu kin). Cng thc phn t cua hai hirocacbon la A. C2H6 va C3H8 B. C3H6 va C4H8 C. CH4 va C2H6 D. C2H4 va C3H6

AMINOAXIT V PROTIT
I. AMINO AXIT: L hp cht hu c tp chc, trong phn t cha ng thi nhm chc amino (-NH 2) v nhm chc cacboxyl (-COOH). Vd: NH2CH2COOH; CH3CH(NH2)COOH l hai amono axit 1. TN GI : Axit + v tr nhm -NH2 + amino + tn ca axitcacboxylic tng ng V tr nhm NH2 xc nh theo qui c

C-C-C-C-C-C-N H

H2NCH2COOH axit aminoaxetic (axit -aminoaxetic; glixin hay licocol) CH3CH(NH2)COOH axit -aminopropionic (alanin) CH2(NH2)CH2CH2CH2CH2COOH axit -aminocaproic HOOCCH2CH2CH2CH(NH2)COOH axit -aminoglutaric (axit glutamic). CH2(NH2) CH2 CH2 CH2 CH2 CH2 COOH Axit -aminoenantonic . 2. CNG THC TNG QUT * (NH2)bCnH2n+2-2k-a-b(COOH)a hay (NH2)bR(COOH)a hay (NH2)bCxHy(COOH)a Cng th l NbCxHy(COOH)a hay NbR(COOH)a Amino axit va c tnh baz (-NH2 ) va c tnh axit (-COOH) 3. TNH BAZ: H2NCH2COOH + HCl ClH3N CH2 COOH 4. TNH AXIT: H2NCH2 COOH + NaOH NH2CH2COONa + H2O HCl H2NCH2COOH + C2H5OH H2NCH2COOC2H5 + H2O 5. PHN NG TRNG NGNG: khi b un nng cc phn t amino axit c th tc dng vi nhau
n H2NCH2COOH t0, p, xt
*

NHCH2CO

nH2O

II. PROTEIN 1. THNH PHN V CU TO + THNH PHN: Cc protit u cha cacbon, hidro, oxi v nit. Ngoi ra cn c thm S, Fe, P, Ca, Mg, Zn + CU TO: Polime phc tp, khi lng phn t ca protit rt ln, phn t protit gm cc mch di - cc chui - poli petit hp thnh 2. KH NNG HA TAN: kh nng ha tan ca cc protit khc nhau trong cc dung mi khc nhau th khc nhau 3. S NG T: S kt ta protit bng nhit gi l s ng t
Amino axit Polipeptit 4. PHN NG THU PHN PROTIT: Protit 5. PHN NG MU C TRNG: Dung dch lng trng trng + HNO3 m c vng m Dung dch lng trng trng + Cu(OH)2 ( xanh) tm xanh 6. TC DNG CA NHIT CAO : protit chy c mi c trng H2O, t0 H2O, t0

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I.

AMINOAXIT PROTIT
Cu 1. .

L Thuyt.

Pht biu no di y v amino axit l khng ng? A. Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v cacboxyl. B. Hp cht H2NCOOH l amino axit n gin nht C. Amino axit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-). D. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit. Cu 2. . Tn gi ca amino axit no di y l ng?

A. H2N CH2 COOH(glixerin)

B. CH3 CH COOH(anilin) NH2 HOOC [CH2]2 CH COOH D.

C. CH3 CH CH COOH(valin) NH2 (axit glutaric) CH3 NH2 Cu 3. . Khng nh v tnh cht vt l no ca amino axit di y khng ng?

A. Tt c u l cht rn B. Tt c u l tinh th, mu trng C. Tt c u tan trong nc D. Tt c u c nhit nng chy cao Cu 4. . Amino axit khng th phn ng vi loi cht no di y? A. Ancol B. Dung dch brom C. Axit (H+) v axit nitr D. Kim loi, oxit baz, baz v mui Cu 5. . 0,01 mol amino axit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. Cng thc ca A c dng: A. H2NRCOOH B. (H2N)2RCOOH C. H2NR(COOH)2 D. (H2N)2R(COOH)2 Cu 6. . Cho 0,1 mol A (-amino axit dng H2NRCOOH) phn ng ht vi HCl to 11,15 gam mui. A l: A. Glixin B. Alanin C. Phenylalanin D. Valin Cu 7. . Cho -amino axit mch thng A c cng thc H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. A l: A. Axit 2-aminopropandioic B. Axit 2aminobutandioic C. Axit 2-aminopentandioic D. Axit 2-aminohexandioic Cu 8. . Cho cc dy chuyn ha: NaOH H l H l NaOH Glixin + A + C X ; Glixin + C B + Y X v Y ln lt l: A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 9. Mt hp cht hu c X c t l khi lng C,H,O,N l 9:1,75:8:3,5 tc dng dd NaOH v dd HCl u theo t l mol 1:1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng dd NaOH v dd HCl theo t l mol 1:1 nhng ng phn ny c kh nng lm mt mu dd brom. Cng thc phn t ca X, cng thc cu to ca X, Y ln lt l: A.C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3. B.C3H7O2N; H2N-C2H4-COOH; CH2=CHCOONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D.C3H5O2N; H2N-C2H2-COOH; CH C-COONH4 Cu 10. (X) l hp cht hu c c cng thc phn t C5H11O2N. un X vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng cho phn ng trng gng. Cng thc cu to ca (X) l: A. CH3(CH2)4NO2 B. NH2 - CH2COO - CH2 - CH2 - CH3 C. NH2 - CH2 - COO - CH(CH3)2 D. H2N - CH2 - CH2 - COOC2H5 Cu 11. X l mt -aminoaxit no ch cha mt nhm NH2 v mt nhm -COOH. Cho 10,3 gam X tc dng vi dung dch HCl d thu c 13,95 gam mui clohirat ca X. Cng thc cu to thu gn ca X l: A. CH3CH(NH2)COOH B. H2NCH2COOH C. H2NCH2CH2COOH D. CH3CH2CH(NH2)COOH Cu 12. . Cho cc cht sau: (X1) C6H5NH2 ; (X2) CH3NH2 ; (X3) H2NCH2COOH (X4) HOOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH Dung dch no sau y lm qu tm ho xanh A. X1, X2, X5 B. X2, X3, X4 C. X2, X5 D. X1, X5, X4 Cu 13. Dung dch no lm qu tm ho : (1) H2NCH2COOH ; (2) Cl NH3+-CH2COOH ; (3) H2NCH2COO (4) H2N(CH2)2CH(NH2)COOH ; (5) HOOC(CH2)2CH(NH2)COOH
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

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Trn Ngc Phc_ THPT Vinh Xun

A. (3)

B. (2) C. (2), (5) D. (1), (4) Cu 14. X l cht hu c c cng thc phn t C5H11O2N. un A vi dung dch NaOH thu c mt hn hp cht c CTPT C2H4O2Na v cht hu c B. Cho hi ca B qua CuO/t0 thu c cht D c kh nng cho phn ng trng gng. Cng thc cu to thu gn ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 Cu 77. . Este X c iu ch t aminoaxit Y v ru etylic. T khi hi ca X so vi hidro bng 51,5. t chy hon ton 10,3 gam X thu c 17,6 gam kh CO2, 8,1 gam nc v 1,12 lt Nit (ktc). Cng thc cu to thu gn ca X l A. H2N-(CH2)2-COO-C2H5 B. H2N-CH2-COO-C2H5 C. H2N-CH(CH3)-COOH D. H2N-CH(CH3)COOC2H5 Cu 78. . Cht hu c X c cha 15,7303% nguyn t N; 35,9551% nguyn t O v khi lng v cn cc nguyn t C v H. Bit X c tnh lng tnh v tc dng vi dung dch HCl ch xy ra mt phn ng. Cu to thu gn ca X l A. H2N-COO-CH2CH3 B. H2N-CH2CH(CH3)-COOH C. H2N-CH2CH2-COOH D. H2N-CH2-COO-CH3 Cu 79. . Trong bn ng nghim mt nhn cha ring bit tng dung dch: glixerin, lng trng trng, tinh bt, x phng. Th t ho cht dng lm thuc th nhn ra ngay mi dung dch l A. qu tm, dung dch iot, Cu(OH)2, HNO3 c B. Cu(OH)2, dung dch iot, qu tm, HNO3 c C. dung dch iot, HNO3 c, Cu(OH)2, qu tm D. Cu(OH)2, qu tm, HNO3 c, dung dch iot Cu 80. . Cu no sau y khng ng: A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng B. Phn t cc protit gm cc mch di polipeptit to nn C. Protit rt t tan trong nc v d tan khi un nng D. Khi cho Cu(OH)2 vo lng trng trng thy xut hin mu tm xanh Cu 81. . Mt hp cht cha cc nguyn t C, H, O, N c phn t khi = 89. t chy hon ton 1 mol hp cht thu c 3 mol CO2, 0,5 mol N2 v a mol hi nc. Cng thc phn t ca hp cht l: A. C4H9O2N B. C2H5O2N C. C3H7NO2 D. C3H5NO2 Cu 82. Thu phn hp cht: H2N CH2 CO NH CH CO NH CH CO NH CH2 COOH
CH2 COOH CH2 C6H5 thu c cc aminoaxit no sau y: A. H2N - CH2 COOH B. HOOC - CH2 - CH(NH2) - COOH C. C6H5 - CH2 - CH(NH2)- COOH D. Hn hp 3 aminoaxit A, B, C Cu 83. Trong cc cht sau: Cu, HCl, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxetic tc dng c vi: A. Tt c cc cht B. HCl, HNO2, KOH, Na2SO3, CH3OH/ kh HCl C. C2H5OH, HNO2, KOH, Na2SO3, CH3OH/ kh HCl, Cu D. Cu, KOH, Na2SO3, HCl, HNO2, CH3OH/ kh HCl Cu 84. X l mt aminoaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 0,89 gam X tc dng vi HCl va to ra 1,255 gam mui. Cng thc cu to ca X l: A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH C. CH3-CH(NH2)-CH2-COOH D. C3H7-CH(NH2)COOH Cu 85. . Cho dung dch cha cc cht sau: C6H5 - NH2 (X1) (C6H5 l vng benzen); CH3NH2 (X2) ; H2N - CH2 - COOH (X3) ; HOOC - CH2- CH2- CH(NH2)- COOH (X4) ; H2N - (CH2)4- CH(NH2)- COOH (X5) Nhng dung dch lm giy qu tm ho xanh l: A. X1 ; X2 ; X5. B. X2 ; X3 ; X4. C. X2 ; X5. D. X3 ; X4 ; X5. Cu 86. X l mt - aminoaxit no ch cha 1 nhm NH2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l: A.C6H5-CH(NH2)-COOH B.CH3-CH(NH2)-COOH C.CH3-CH(NH2)-CH2-COOH D.C3H7-CH(NH2)COOH Cu 87. . Protein c th c m t nh: A. Cht polime trng hp B. Cht polieste C. Cht polime ng trng hp D. Cht polime ngng t Cu 88. . Dng lng trng trng g lm trong mi trng (aga, nc ng), ta ng dng tnh cht no sau y:
C cng mi st c ngy nn kim Nhn dy km, dy thm, luyn thi. Lin h s 0984351647

Ti liu bi dng kin thc ph thng

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Trn Ngc Phc_ THPT Vinh Xun

2.

3.

4.

6.

7.

8.

00.

A. Tnh baz ca protit B. Tnh axit ca protit C. Tnh lng tnh ca protit D. Tnh ng t nhit cao v ng t khng thun nghch ca abumin. Cu 89. . X l mt -aminoaxit no ch cha mt nhm NH2 v mt nhm -COOH. Cho 23,4 g X tc dng vi dung dch HCl d thu c 30,7 g mui. Cng thc cu to thu gn ca X l: A. CH3-CH(NH2)-COOH B.H2N-CH2-COOH C.H2N-CH2CH2-COOH D.CH2=C(CH3)-CH(NH2)COOH Cu 90. . Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dung dch Br2 c CTCT: A. CH3CH(NH2)COOH B. H2NCH2CH2COOH C. CH2=CHCOONH4 D. CH2=CH-CH2COONH4 Cu 91. . Aminoaxit l nhng hp cht hu c trong phn t cha : A. nhm amino B.nhm Cacboxyl C. 1 nhm Amino v 1 nhm Cacboxyl D.1 hoc nhiu nhm Amino v 1 hoc nhiu nhm Cacboxyl - Aminoaxit l Aminoaxit m nhm amino gn cacbon th A. 1 B. 2 C. 3 D. 4 Cho cc cht : X : H2N-CH2-COOH T : CH3 -CH2-COOH Y : H3C-NH-CH2-CH3 Z : C6H5-CH(NH2)-COOH G : HOOC-CH2CH(NH2)COOH P : H2N-CH2-CH2-CH2-CH(NH2)COOH Aminoaxit l : A. X , Z , T , P B. X, Y, Z, T C. X, Z, G, P. D. X, Y, G, P C4H9O2N c s ng phn aminoaxit (vi nhm amin bc nht) l : A. 2 B. 3 C. 4 D. 5 Cho qu tm vo mi dung dch di y: dung dch lm qu tm ho xanh l : A. CH3COOH B. H2N-CH2-COOH C. H2N-CH2(NH2)COOH D. HOOC-CH2 -CH2 -CH(NH2)COOH Tn gi ca hp cht C6H5-CH2-CH(NH2)-COOH l : A. Axit Aminophenylpropionic B. Axit 2-Amino-3-phenylpropionic C. phenylAlanin D. Axit 2-Amino-3-phenylpropanoic Cho dung dch qu tm vo 2 dung dch sau : X : H2N-CH2-COOH Y : HOOC-CH(NH2)-CH2-COOH A. X v Y u khng i mu qu tm. B. X lm qu chuyn mu xanh, Y lm qu chuyn mu . C. X khng i mu qu tm, Y lm qu chuyn mu . D. c hai u lm qu chuyn sang mu . . C3H7O2N c s ng phn Aminoaxt (vi nhm amin bc nht) l: A. 2 B. 3 C. 4 D. 5 Phn ng gia Alanin v Axit clohidric cho cht no sau y : A.H2N-CH(CH3)-COCl B.H3C-CH(NH2)-COCl C.HOOC-CH(CH3)-NH3Cl D.HOOC-CH(CH2Cl)NH2 Axit - Aminopropionic tc dng c vi tt c cc cht trong dy no sau y : A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2N-CH2-COOH B. HCl, NaOH, CH3OH c mt HCl ,, H2N-CH2-COOH , Cu C. HCl , NaOH, CH3OH c mt HCl , H2N-CH2-COOH D. HCl, NaOH, CH3OH c mt HCl ,, H2N-CH2-COOH , NaCl Cu 101. Cht A c % khi lng cc nguyn t C,H,O,N, ln lt l 32 % , 6,67% , 42,66% , 18,67% . T khi hi ca A so vi khng kh nh hn 3 . A va tc dng NaOH va tc dng dung dch HCl . A c cu to : A. CH3 -CH(NH2)-COOH . B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D.H2N-(CH2)3COOH. Cu 102. . Cht X c thnh phn % cc nguyn t C, H, N ln lt l 40,45% 7,86% , 15,73% cn li l oxy . Khi lng mol phn t ca X < 100 . X tc dng c NaOH v HCl , c ngun gc t thin nhin . X c cu to l : A. CH3-CH(NH2)-COOH . B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3COOH. Cu 103. Cng thc tng qut ca cc Aminoaxit l : A. R(NH2) (COOH) B. (NH2)x(COOH)y C. R(NH2)x(COOH)y D. H2N-CxHy-COOH Cu 104. Khi un nng, cc phn t -Alanin (Axit -aminopropionic) c th tc dng vi nhau to sn phm no sau y:

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Ti liu bi dng kin thc ph thng A. -HN-CH 2-CO-HN-CH-CH 2COOH

Cu 105.

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Trn Ngc Phc_ THPT Vinh Xun

C.

-HN-CH-COCH 3 n

B.

-CH 2-CH-CONH 2 n

D.

Pht biu no sau y ng : (1) Protit l hp cht cao phn t thin nhin c cu trc phc tp : (2) Protit ch c trong c th ngi v ng vt . (3) C th ngi v ng vt khng th tng hp c protit t nhng cht v c m ch tng hp c t cc aminoaxit (4) Protit bn i vi nhit , i vi axit v kim . A. (1),(2) B. (2), (3) C. (1) , (3) D. (3) , (4) Cu 106. S kt ta protit bng nhit c gi l protit A. s trng ngng . B. s ngng t C. s phn hu . D. s ng t Cu 107. Khi nh axit HNO3 m c vo dung dch lng trng trng ,un nng hn hp thy xut hin , cho ng (II) hyroxit vo dung dch lng trng trng thy mu .. xut hin . A. kt ta mu trng ; tm xanh . B. kt ta mu vng ; tm xanh . C. kt ta mu xanh; vng D. kt ta mu vng ; xanh . Cu 108. Thu phn n cng protit ta thu c . A. cc aminoaxit B. cc aminoaxit C. cc chui polypeptit D. hn hp cc aminoaxit Cu 109. Khi ung nng protit trong dung dch axit hoc kim hoc di tc dng cc men , protit b thu phn thnh cc ., cui cng thnh cc : A. phn t protit nh hn; aminoaxit . B. chui polypeptit ; _aminoaxit C. chui polypeptit ; hn hp cc aminoaxit D. chui polypeptit ; aminoaxit . Cu 110. Sn phm hoc tn gi ca cc cht trong phn ng polime no sau y l ng?
A. n H2N[CH2]5COOH axit -aminocaproic HN[CH2]5CO
CH2 CH2 C

B.

n H2N[CH2]5COOH

Tnilon-7
O

+ nH2O

axit -aminoenantoic HN[CH2]6CO Tenan

+ nH2O

C.

n CH2 CH2 CH2 NH caprolactam HN[CH2]5CO T capron n + nH2O

D.

n H2N[CH2]6COOH axit 7-aminoheptanoic HN[CH2]6CO Tnilon-7

+ nH2O

Cu 111. ng dng no ca amino axit di y c pht biu khng ng? A. Amino axit thin nhin (hu ht l -amino axit) l c s kin to protein ca c th sng. B. Mui dinatri glutamat l gia v thc n (gi l bt ngt hay m chnh). C. Axit glutamic l thuc b thn kinh, methionin l thuc b gan. D. Cc amino axit (nhm amin v tr s 6, 7, ...) l nguyn liu sn xut t nilon. Cu 112. Pht biu no sau y KHNG ng? A. Nhng hp cht hnh thnh bng cch ngng t hai hay nhiu -amino axit c gi l peptit. B. Phn t c hai nhm -CO-NH- c gi l dipeptit, ba nhm th c gi l tripeptit. C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc amino axit c sp xp theo mt th t xc nh. Cu 113. Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu vC). B.Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc - v -amino axit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axit nucleic,... Cu 114. Thy phn peptit:

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Trn Ngc Phc_ THPT Vinh Xun

(CH2)2COOH CH3 CH COOH H2N CH2 C N CH C N O H O H Sn phm no di y l khng th c? A. Ala B. Gli-Ala C. Ala-Glu D. Glu-Gli Cu 115. Cho bit sn phm thu c khi thy phn hon ton policaproamit trong dung dch NaOH nng, d. A. H2N[CH2]5COOH B. H2N[CH2]6COONa C. H2N[CH2]5COONa D. H2N[CH2]6COOH Cu 116. Cho bit sn phm thu c khi thy phn hon ton t enan trong dung dch HCl d. A. ClH3N[CH2]5COOH B. ClH3N[CH2]6COOH C. H2N[CH2]5COOH D. H2N[CH2]6COOH Cu 117. M t hin tng no di y l khng chnh xc? A. Nh vi git axit nitric c vo dung dch lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dung dch NaOH v mt t CuSO4 thy xut hin mu c trng. C. un nng dung dch lng trng trng thy hin tng ng t li, tch ra khi dung dch. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. Cu 118. Pht biu no di y v enzim l khng chnh xc? A. Hu ht enzim c bn cht protein. B. Enzim c kh nng xc tc cho cc qu trnh ha hc. C. Mi enzim xc tc cho rt nhiu chuyn ha khc nhau. D. Tc phn ng nh xc tc enzim thng nhanh hn n 109-1011 ln nh xc tc ha hc. Ton c bn

BT Nng cao.

BI TP T KIM TRA.

1 Cho s chuyn ho sau: . + 3OH / HCl CH Cht Z l

+ NH3 + HNO2 Alanin X Y Z

A. CH3 CH(OH) COOH. C. H2N CH2 COOCH3.

B. CH3 CH(OH) COOCH3. D. H2N CH(CH3) COOCH3.

2 chng minh glyxin C2H5O2N l mt aminoaxit, ch cn cho phn ng vi: . A. NaOH. B. HCl. C. CH3OH/HCl. D. NaOH v HCl. 3 C3H7O2N c bao nhiu ng phn aminoaxit (vi nhm amin bc 1)? . A. 2. B. 3. C. 4. 4 Cho cc phn ng: . D. 5.

H2NCH2COOH + HCl Cl H3N + CH2COOH H2NCH2COOH + NaOH H2NCH2COONa +H2O

Hai phn ng trn chng t axit aminoaxetic A. c tnh lng tnh. B. ch c tnh baz.
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Ti liu bi dng kin thc ph thng C. ch c tnh axit. D. va c tnh oxi ho, va c tnh kh. 5 . Hp cht khng lm i mu giy qu m l A. CH3NH2. C. H2N CH2 CH(NH2)COOH. B. C6H5ONa.

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Trn Ngc Phc_ THPT Vinh Xun

D. H2NCH2COOH.

6 ng dng no ca aminoaxit di y khng ng? . A. Aminoaxit thin nhin (hu ht l - aminoaxit) l c s kin to nn cc loi protein ca c th sng. B. Cc axit amin c nhm NH2 t v tr s 6 tr ln l nguyn liu sn xut t nilon. C. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt). D. Axit glutamic l thuc b thn kinh. 7 Cho dy chuyn ho sau: .

+ NaOH + HCl Glyxin Z X + HCl + NaOH Glyxin T Y

X v Y ln lt l A. u l ClH3NCH2COONa. B. ClH3NCH2COOH v ClH3NCH2COONa. C. ClH3NCH2COONa v H2NCH2COONa. D. ClH3NCH2COOH v H2NCH2COONa. 8 Cho Tirozin (HOC6H4CH2CH(NH2)COOH) (X) phn ng vi cc cht sau, trng hp no phng trnh ho hc . vit khng ng:

NH A. X +2HCl Cl C H CH CH(COOH) 3 Cl +H O 6 4 2 2 B. X + 2NaOH NaOC H CH CH(NH )COONa + 2H O 6 4 2 2 2

C. X + HNO HO C H CH 2 6 4 2

CH(OH)COOH + N + H O 2 2 CH CH(NH )COOC H + H O 2 2 2 5 2

D. X + C H OH 2 5

khHCl

HO C H 6 4

9 Nhn nh no sau y khng ng? . A. Cc aminoaxit l nhng cht rn, c nhit nng chy cao v d tan trong nc v chng tn ti dng ion lng cc. B. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc H3N+RCOO-. C. Aminoaxit l hp cht tp chc m phn t cha ng thi nhm cacboxyl v nhm amino. D. Nhit nng chy ca H2NCH2COOH > CH3(CH2)3NH2 > CH3CH2COOH. 1 Cht X c cng thc phn t C3H7O2N. X c th tc dng vi NaOH, HCl v lm mt mu dung dch Brom. Cng 0 thc cu to ca X l . A. CH2 = CHCOONH4. B. CH3CH(NH2)COOH. C. H2NCH2CH2COOH. D. CH3CH2CH2NO2. 1 Dung dch cht no sau y khng lm chuyn mu qu tm? 1 A. H2N(CH2)2CH(NH2)COOH. B. CH3 CHOH COOH. . C. H2N CH2 COOH. D. C6H5NH3Cl.
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Trn Ngc Phc_ THPT Vinh Xun

1 0,1 mol aminoaxit X phn ng va vi 0,2 mol HCl hoc 0,1 mol NaOH. 2 Cng thc ca X c dng l . A. H2NRCOOH. B. (H2N)2RCOOH. C. H2NR(COOH)2. D. (H2N)2R(COOH)2. 1 0,01 mol aminoaxit Y phn ng va vi 0,01 mol HCl c cht Z. Cht Z phn ng va vi 0,02 mol 3 NaOH. Cng thc ca Y c dng l . A. H2NR(COOH)2. B. H2NRCOOH. C. (H2N)2RCOOH. D. (H2N)2R(COOH)2. 1 Phn t khi ca mt cht hu c X nm trong khong 140 < M < 150. 1 mol X phn ng c vi 2 mol NaOH 4 nhng ch phn ng c vi 1 mol HCl. X c th l . A. H2N(CH2)4CH(NH2)COOH. B. H2NCH2CH(NH2)COOH. C. HOOCCH2CH(NH2)COOH. D. HOOC(CH2)2CH(NH2)COOH. 1 X l cht hu c c cng thc phn t C5H11O2N. un X vi dung dch NaOH thu c mt hn hp cht c cng 5 thc phn t C2H4O2NNa v cht hu c Y. Cho hi Y qua CuO, t0 c cht Z c kh nng trng gng. Cng . thc cu to ca X l A. CH3(CH2)4NO2. C. H2NCH2COOCH2CH2CH3. B. H2NCH2CH2COOC2H5. D. H2NCH2COOCH(CH3)2.

1 Este X c iu ch t aminoaxit Y (cha C, H, N, O) v ancol metylic, t khi hi ca X so vi H2 bng 44,5. t 6 chy hon ton 8,9 gam este X c 0,3 mol CO2; 0,35 mol H2O v 0,05 mol N2. Cng thc cu to ca X l . A. H2NCH2COOCH3. B. H2NCH2COOC2H5. C. H2NCH(CH3)COOCH3. D. H2NCOOC2H5. 1 Cht X (cha C, H, O, N) c thnh phn % cc nguyn t C, H, O ln lt l 40,45%; 7,86%; 35,96%. X tc dng 7 vi NaOH v vi HCl. X c ngun gc t thin nhin v MX <100. . Cng thc cu to ca X l A. CH3CH(NH2)COOH. C. H2NCH2CH2COOH. B. H2NCH2COOH. D. H2NCH2CH(NH2)COOH.

1 Hp cht X (cha C, H, O, N) c cng thc phn t trng vi cng thc n gin nht, va tc dng vi axit va 8 tc dng vi kim. Trong X, % khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%. . Khi cho 4,45 gam X phn ng hon ton vi NaOH (un nng) c 4,85 gam mui khan. Cng thc cu to ca X l A. CH2 = CHCOONH4. C. H2NCH2COOCH3. B. H2NCOOC2H5. D. H2NC2H4COOH.

1 Cht X tc dng vi dung dch NaOH to ra cht Y. t chy hon ton 11,1 gam cht Y c 0,3 mol hn hp 9 CO2 v N2 c t khi so vi H2 bng 20,667, ngoi ra cn 0,3 mol H2O v 0,05 mol Na2CO3. Bit X c tnh lng . tnh v Y ch cha 1 nguyn t N. Cng thc cu to ca Y l A. CH2 = CHCOONH4. B. CH3CH(NH2)COOONa. C. H2NCH2COONa. D. H2NCH = CHCOOONa. 2 28,1 gam hn hp propylamin, axit aminoaxetic v etylaxetat c th phn ng vi 6,72 lt hiroclorua ( ktc).
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Cng mt lng hn hp trn c th phn ng vi 100 ml dung dch KOH 1M (cc phn ng va ). % khi lng ca aminoaxit trong hn hp l A. 22%. C. 54,7%. B. 23,3%. D. 26,69%.

2 Cho 100 ml dung dch aminoaxit X 0,2M tc dng va vi 80 ml dung dch NaOH 0,25M. Sau phn ng c 1 2,5 gam mui khan. Mt khc ly 100 gam dung dch aminoaxit ni trn c nng 20,6% phn ng va vi . 400 ml dung dch HCl 0,5M. Cng thc phn t ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NCH(CH3)COOH. D. H2N(CH2)2COOH. 2 Hp cht hu c X c cng thc tng qut C xHyOzNt. Thnh phn % khi lng ca N v O trong X ln lt l 2 15,730% v 35,955%. Khi X tc dng vi HCl ch to ra mui R(Oz)NH3Cl (R l gc hirocacbon). Bit X c trong . thin nhin v tham gia phn ng trng ngng. Cng thc cu to ca X l A. H2NCH2COOCH3. B. H2NCH2CH2COOH. C. H2NCH(CH3)COOH. D. CH2 = CHCOONH4. 2 Hp cht X gm cc nguyn t C, H, O, N vi t l khi lng tng ng l 3 : 1 : 4 : 7. Bit X c 2 nguyn t N. 3 Cng thc phn t ca X l . A. CH4ON2. B. C3H8ON2. C. C3H8O2N2. D. C3H7O2N2. 2 Cho 0,1 mol hp cht X tc dng va vi 80 ml dung dch HCl 1,25M, sau c cn dung dch thu c 18,75 4 gam mui. Mt khc, cho 0,1 mol X tc dng vi NaOH va ri c cn th c 17,3 gam mui. Bit X l mt . - aminoaxit v c kh nng phn ng vi Br2/Fe cho hp cht C8H9O2NBr. Cng thc cu to ca X l A. C6H5CH(NH2)COOH. B. H2NC6H4CH2COOH. C. H2NCH2C6H4COOH. D. H2NC6H4COOH. 2 Cho hn hp X gm 2 cht hu c c cng cng thc phn t C 2H7NO2 tc dng va vi dung dch NaOH v 5 un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm 2 kh (u lm xanh qu m). T khi hi ca Z . i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. 2 -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl d thu c 13,95 gam mui khan. 6 Cng thc cu to ca X l . A. H2NCH2COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. 2 Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy 7 gm cc hp cht u tc dng c vi dung dch NaOH v u tc dng vi dung dch HCl l . A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. 2 t chy hon ton 1 lng cht hu c X thu c 3,36 lt CO 2; 0,56 lt N2 (cc kh o ktc) v 3,15 gam H 2O. Khi X 8 tc dng vi dung dch NaOH thu c sn phm c mui C2H4O2NNa. Cng thc cu to ca X l
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Ti liu bi dng kin thc ph thng A. H2NCH2COOC3H7. B. H2NCH2COOCH3. C. H2NCH2CH2COOH. D. H2NCH2COOC2H5.

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2 Hy chn mt thuc th sau y phn bit cc dung dch: glucoz, glixerol, etanol, lng trng trng. 9 A. Dung dch NaOH. . B. Dung dch AgNO3/NH3. C. Cu(OH)2. D. Dung dch HNO3. 3 Chn phng php tt nht phn bit dung dch cc cht: Glixerol, glucoz, anilin, alanin, anbumin. 0 A. Dng Cu(OH)2 ri un nng nh, sau dng dung dch Br2. . B. Dng ln lt cc dung dch CuSO4, H2SO4, I2. C. Dng ln lt cc dung dch AgNO3/NH3, CuSO4, NaOH. D. Dng ln lt cc dung dch HNO3, NaOH, H2SO4. 3 S ipeptit to thnh t glyxin v alanin l 1 A. 1. . C. 3. B. 2. D. 4.

3 Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l 2 A. Protit lun cha chc hiroxyl. . B. Protit lun cha nit. C. Protit lun l cht hu c no. D. Protit c khi lng phn t ln hn. 3 Ch dng Cu(OH)2 c th phn bit dy no di y cha cc dung dch ring bit ? 3 A. Glucoz, lng trng trng, glixerol, ancol etylic. . B. Glucoz, mantoz, glixerol, anehit axetic. C. Lng trng trng, glucoz, fructoz, glixerol. D. Saccaroz, glixerol, anehit axetic, ancol etylic. 3 Ghp cc cm t ct 1 vi cc cm t ct 2 ph hp sao cho khng c cm t no tha: 4 Ct 1 Ct 2 . 1 p nitroanilin A kh [A(NH3)2]OH cho Ag. 2 3 4 5 Lng trng trng ng mch nha Xenluloz Tinh bt B C E thu phn n cng cho glucoz, tham gia phn ng trng gng. phn ng vi [Cu(NH3)4](OH)2. nhn bit bng dung dch HNO3 c. B. 1b, 2e, 3c, 4a, 5d. D. 1d, 2e, 3c, 4a, 5b.

D khng lm mt mu giy qu tm.

Th t ghp ng l A. 1d, 2e, 3a, 4c, 5b. C. 1c, 2b, 3e, 4a, 5d.

3 Nhn nh no sau y cha chnh xc? 5 A. Peptit l nhng hp cht c hnh thnh bng cch ngng t hai hay nhiu phn t -aminoaxit. . B. Protein l nhng polipeptit cao phn t c vai tr l nn tng v cu trc v chc nng ca mi s sng.
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C. Enzim l nhng cht hu ht c bn cht protein, c kh nng xc tc cho cc qu trnh ho hc, c bit trong c th sinh vt. D. Tc phn ng nh xc tc enzim rt chm, mi enzim ch xc tc cho mt s chuyn ho. 3 Trong 4 ng nghim mt nhn cha ring bit tng cht: glixerol, lng trng trng, h tinh bt, x phng. Th t 6 cc cht dng lm thuc th nhn ra mi cht trn l A. dung dch I2, Cu(OH)2. . B. qy tm, dung dch HNO3 c, dung dch NaOH. C. dung dch HNO3 c, qy tm, dung dch Br2. D. dung dch Br2, dung dch HNO3 c, dung dch I2. 3 C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng trong bn l mt nhn ring bit. 7 Ha cht dng phn bit c 4 cht trn l . A. Dung dch HNO3 c. B. Dung dch I2. C. Dung dch AgNO3/NH3. D. Cu(OH)2/OH-. 3 Khi thy phn hon ton mt polipeptit ta thu c cc aminoaxit X, Y, Z, E, F. Cn khi thu phn tng phn th 8 thu c cc i- v tripeptit XE, ZY, EZ, YF, EZY. Trnh t cc aminoaxit trong polipeptit trn l . A. X Z Y E F. B. X E Y Z F. C. X E Z Y F. D. X Z Y F E. 3 Thy phn hon ton polipeptit sau thu c bao nhiu aminoaxit? 9 H2N - CH2- CO - NH - CH - CO - NH - CH - CO - NH - CH2- COOH . CH2- C6H5 CH2COOH

A. 2. C. 4.

B. 3. D. 5.

4 Sn phm cui cng ca qu trnh thu phn cc protein n gin nh xc tc thch hp l 0 A. aminoaxit. B. aminoaxit. . C. Axit cacboxylic. D. Este. 4 Trong phn t hp cht hu c no sau y c lin kt peptit? 1 A. alanin. B. Protein. . C. Xenluloz. D. Glucoz. 4 Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l 2 A. Saccaroz. B. Xenluloz. . C. Protit. D. Tinh bt. 4 Nhn nh no sau y khng ng? 3 A. Protein d tan trong nc to thnh dung dch keo. . B. Lp vng ni ln khi nu tht, c l hin tng ng t protein. C. Vi lng trng trng, Cu(OH)2 phn ng vi cc nhm peptit CO NH cho sn phm mu tm . D. Sa ti lu s b vn cc, to thnh kt ta do b ln men lm ng t protein. 4 Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng ng. Bit mi 4 cht u cha mt nhm NH2 v mt nhm COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho . sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2
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Ti liu bi dng kin thc ph thng aminoaxit l A. H2NCH(CH3)COOH, C2H5CH(NH2)COOH. B. H2NCH2COOH, H2NCH(CH3)COOH. C. H2NCH(CH3)COOH, H2N(CH2)3COOH. D. H2NCH2COOH, H2NCH2CH2COOH.

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Trn Ngc Phc_ THPT Vinh Xun

4 Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau: CH 3NH2, H2NCH2COOH, 5 CH3COONH4, anbumin. . A. Qi tm, dung dch HNO3 c, dung dch NaOH. B. Cu(OH)2, qy tm, ung dch Br2. C. Dung dch Br2, dung dch HNO3 c, dung dch I2. D. Dung dch AgNO3/NH3, dung dch Br2, dung dch HNO3 c. 4 S ng phn tripeptit to thnh t glyxin, alanin v phenylalanin l 6 A. 3. . B. 4. C. 5. D. 6. 4 Cho hp cht sau: H3N+ - CH(COOH) COO- tc dng vi cc cht sau: HNO2, CH3OH (d)/HCl, NaOH d, 7 CH3COOH, CuO. S phn ng xy ra l . A. 2. B. 3. C. 4. D. 5. 4 Axit glutamic (HOOC[CH2]2CH(NH2)COOH) l cht c tnh 8 A. axit . B. baz C. lng tnh. D. trung tnh. CHNG III. AMIN AMINO AXIT PROTEIN Cu 3.1 S sp xp theo trt t tng dn tnh baz gia etylamin, phenylamin v amoniac ng l A. amoniac < etylamin < phenylamin. B. etylamin < amoniac < phenylamin. C. phenylamin < amoniac < etylamin. D. phenylamin < etylamin < amoniac. Cu 3.2 Cch thun li nht nhn bit l ng dung dch CH3NH2 l A. nhn bit bng mi. B. thm vi git dung dch H2SO4. C. thm vi git dung dch Na2CO3 D. a u a thu tinh nhng vo dung dch HCl m c ln pha trn ming l ng dung dch CH3NH2. Cu 3.3 S lng ng phn ng vi cng thc phn t C3H9N l: A. 2. B. 3. C. 4. D. 5. Cu 3.4 S lng ng phn amin bc 2 ng vi cng thc phn t C4H11N l A. 2. B. 3. C. 4. D. 5. Cu 3.5 S lng ng phn amin c cha vng benzen ng vi cng thc phn t C7H9N l A. 2. B. 3. C. 4. D. 5. Cu 3.6 Amino axit l mt hp cht hu c tp chc, trong phn t ca n va c nhm (1)va c nhm (2)nn va c tnh cht (3)va c tnh cht (4). Amino axit thng tn ti di dng (5)cn bng vi dng (6) (1) (2) (3) (4) (5) (6) A. amin cacbonyl oxi ho Axit phn t phn t B. amino cacboxyl baz Axit ion lng cc phn t
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C. hiroxyl metylen kh oxi ho cation anion D. xeton metyl axit lng tnh nguyn t cation Cu 3.7 C 3 cht hu c gm NH2CH2COOH, CH3CH2COOH v CH3[CH2]3NH2. nhn ra dung dch ca cc hp cht trn, ch cn dng thuc th no sau y?A. NaOH. B. HCl. C. CH3OH/HCl. D. qu tm. Cu 3.8 Este A c iu ch t amino axit B (ch cha C, H, O, N) v ancol metylic. T khi hi ca A so vi H2 l 44,5. t chy hon ton 8,9g este A thu c 13,2g CO2, 6,3g H2O v 1,12 lt N2 (ktc). Cng thc cu to thu gn ca A, B ln lt l A. CH(NH2)2COOCH3; CH(NH2)2COOH. B. CH2(NH2)COOH; CH2(NH2)COOCH3. C. CH2(NH2)COOCH3; CH2(NH2)COOH. D. CH(NH2)2COOH; CH(NH2)2COOCH3. Cu 3.9 Thuc th no di y dng phn bit cc dung dch glucoz, glixerol, etanol v lng trng trng? A. NaOH. B. AgNO3/NH3. C. Cu(OH)2. D. HNO3. Cu 3.10 Khi thu phn 500g protein A thu c 170g alanin. Nu phn t khi ca A l 50.000, th s mt xch alanin trong phn t A l bao nhiu? A. 189. B. 190. C. 191. D. 192. Cu 3.11 Cht no sau y khng c phn ng vi dung dch C2H5NH2 trong H2O? A. HCl. B. H2SO4. C. NaOH. D. qu tm. Cu 3.12 Glixin phn ng c vi tt c cc cht trong nhm cht no sau y (iu kin phn ng xem nh c ): A. Qu tm , HCl , NH3 , C2H5OH. B. NaOH, HCl, C2H5OH, H2N- CH2 - COOH C. Phenoltalein , HCl , C2H5OH , Na. D. Na , NaOH , Br2 , C2H5OH. Cu 3.13 Tm cng thc cu to ca hp cht hu c X cha 32% C; 6,667% H; 42,667% O; 18,666% N. Bit phn t X c mt nguyn t N v X c kh nng tham gia phn ng trng ngng. A. H2NCH2COOH. B. C2H5NO2. C. HCOONH3CH3. D. CH3COONH4. Cu 3.14 Hp cht hu c A c cng thc phn t l C3H7O2N, A tc dng c vi dung dch NaOH, dung dch HCl v lm mt mu dung dch brom. Cng thc cu to ng ca A l A. CH3CH(NH2)COOH. B. CH2=CHCOONH4. C. HCOOCH2CH2NH2. D. H2NCH2CH2COOH. Cu 3.15 Cho cc cht: etylen glicol (1), axit aminoaxetic (2), axit oxalic (3), axit acrylic (4). Nhng cht c th tham gia phn ng trng ngng l: A. (1), (2), (3).B. (1), (2). C. Ch c (2). D. C bn cht. Cu 3.16 C cc dung dch cha trong cc l mt nhn sau: Lng trng trng, h tinh bt, glixerol. Thuc th c th dng phn bit cc dung dch trn l: A. Cu(OH)2. B. I2. C. AgNO3. D. c A, B u ng. Cu 3.17 S ng phn ca hp cht hu c thm c cng thc phn t C7H7NO2 l: A. 7. B. 6. C. 5. D. 8. Cu 3.18 S ng phn ca cc cht c cng thc phn t C4H10O (1), C4H9Cl (2), C4H10 (3), C4H11N (4) theo chiu tng dn l: A. (3), (2), (1), (4). B. (4), (1), (2), (3). C. (2), (4), (1), (3). D. (4), (3), (2), (1).
NaOH Cu 3.19 Cho s phn ng: C9H17O4N (X) C5H7O4NNa2 (Y) + 2C2H5OH.

Cng thc cu to thu gn ca X, Y ln lt l A. C2H5OOCCH2CH(NH2)CH2COOC2H5, NaOOCCH2CH(NH2)CH2COONa. B. CH3OOCCH2CH(NH2)CH2COOC3H7, NaOOCCH2CH(NH2)CH2COONa. C. HOOCCH2CH(NH2)CH2COOC4H9, NaOOCCH2CH(NH2)CH2COONa. D. CH3OOCCH2CH(NH2)CH2COOCH(CH3)2, NaOOCCH2CH(NH2)CH2COONa. Cu 3.20 Chn pht biu ng v hp cht tp chc: A. Hp cht hu c c t hai loi nhm chc tr ln. B. Hp cht hu c c t hai nhm chc tr ln. C. Hp cht hu c c nhiu nhm chc. D. Hp cht hu c c hai nhm chc. Cu 3.21 Trong s sau, cng thc cu to thu gn ph hp ca A, B, C, D, E ln lt l
+ O2 + Cl 2 + O2 + Cl 2 + NH 3 + dd NaOH Etan A B C D E Glixin. 1:1 Cu 1:1 Mn2+

A. C2H5Cl, C2H5OH , CH3CHO, CH3COOH , CH3COOCl. B. C2H5Cl, C2H5OH , CH3CHO, CH3COOH, CH2ClCOOH. C. C2H5Cl, C2H5OH , CH3 COCH3, CH3COOH, CH2ClCOOH. D. C2H5Cl, C2H5OH , CH3COOH, CH3COCH3, CH2ClCOOH. Cu 3.22 Cho 3 cht hu c: NH2CH2COOH (1); CH3CH2CH2CH2NH2 (2); CH3CH2COOH (3). Nhit nng chy ca chng c xp theo trnh t gim dn l A. (2) < (3) < (1). B. (1) > (3) > (2). C. (3) < (2) < (1). D. (2) > (1) > (3).
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Cu 3.23 Hp cht a chc v hp cht tp chc ging nhau ch A. u l hp cht c nhiu nhm chc. B. u l hp cht cha cc nhm chc ging nhau. C. phn t lun c lin kt . D. mch cacbon trong phn t c lin kt . D. axit glutamic. Cu 3.24 X l mt axit -monoamino monocacboxylic, c t khi hi so vi khng kh l 3,07. X l A. glixin. B. alanin. C. axit - aminobutiric. Cu 3.25 Khi un nng cht bo vi dung dch kim .... A. lun thu c glixerol v phn ng xy ra thun nghch. B. lun thu c glixerol, phn ng xy ra nhanh hn v mt chiu. C. lun thu c mui ca axit bo v phn ng xy ra thun nghch. D. lun thu c x phng, phn ng xy ra chm hn. Cu 3.26 Amino axit l A. hp cht hu c a chc, c cha 2 nhm chc COOH v NH2. B. hp cht hu c a chc, c cha 2 loi nhm chc COOH v NH2. C. hp cht hu c tp chc, c cha 2 nhm chc COOH v NH2. D. hp cht hu c tp chc, c cha 2 loi nhm chc COOH v NH2. Cu 3.27 Cng thc tng qut ca amino axit l A. RCH(NH2)COOH. B. R(NH2)x(COOH)y. C. R(NH2)(COOH). Cu 3.28 Chn cu pht biu sai: A. Amino axit l hp cht hu c tp chc. B. Tnh baz ca C6H5NH2 yu hn NH3. C. Cng thc tng qut ca amin no, mch h, n chc l CnH2n + 3N (n 1). D. Dung dch ca cc amino axit u lm qu tm chuyn sang mu . Cu 3.29 Hai phng trnh phn ng ho hc sau, chng minh c nhn nh rng: H2NCH2COOH + NaOH H2NCH2COONa + H2O. H2NCH2COOH + HCl HOOCCH2NH3Cl. A. Glixin l mt axit. B. Glixin l mt baz. C. Glixin l mt cht lng tnh. D. Glixin l mt cht trung tnh. Cu 3.30 Hp cht hu c X c cng thc cu to thu gn: HOOCCH2CH2CH(NH2)COOH. Tn gi ca X l A. glixin. B. alanin. C. axit aipic. D. axit glutamic. Cu 3.31 Cho s chuyn ho sau:

D. RCH(NH3Cl)COOH.

H2SO4 - Na2SO4

C2H5OH, H2SO4, to - Na2SO4

CH3

CH

COO

C2H5

NH3HSO4
CH COONa, CH3 CH COOH.

Cng thc cu to ph hp ca X, Y ln lt l
A. CH3 C. CH3 CH COONa, CH3 CH COOH. B. CH3 D. CH3 NH2 CH COONa, CH3 NH2 NH2 CH COOH. NH3HSO4
H+, to

NH3HSO4 CH COOH, CH3 NH3HSO4

NH2 CH COOH. NH2

Cu 3.32 Phng trnh phn ng ho hc sau chng minh c rng:

H2NCH2COOH + C2H5OH

H2NCH2COOC2H5 + H2O.

A. H ni vi O ca ancol linh ng hn axit. B. Glixin c nhm NH2. C. H ni vi O ca axit linh ng hn ancol. D. Glixin c nhm COOH. Cu 3.33 iu khng nh no sau y l sai ? A. Phn t khi ca mt amin n chc lun l s chn. B. Amino axit c tnh lng tnh. C. Amino axit tham gia phn ng trng ngng. D. Amin n chc u cha mt s l nguyn t H trong phn t. Cu 3.34 Mui ca axit glutamic dng lm bt ngt (cn gi l m chnh), c cng thc cu to thu gn l A. HOOC CH2 CH2 CH(NH2) COOH. B. NaOOC CH2 CH2 CH(NH2) COOH.
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C. HOOC CH2 CH2 CH(NH2) COONH4. D. NaOOC CH2 CH2 CH(NH2) COONa. Cu 3.35 Cng thc cu to thu gn ca axit 2 amino 3 phenylpropanoic l A. CH2 CH COOH. B. CH2 CH COOH.

NH2 C6H5 C. CH3 CH2 CH C6H5 NH2

COOH.

C6H5 NH2 D. CH3 CH2 CH NH2 C6H5

COOH.

Cu 3.36 Chn cu pht biu sai: A. Protein c trong mi b phn ca c th ng vt l hp cht hu c a chc. B. Cc protein u cha cc nguyn t C , H , O , N. C. nhit thng di tc dng ca men, protein b thu phn to ra cc amino axit. D. Mt s protein b ng t khi un nng. Cu 3.37 iu ch glixin theo s : Axit axetic axit cloaxetic glixin. Cn dng thm cc cht phn ng no sau y (khng k xc tc): A. Hiroclorua v amoniac. B. Clo v amin. C. Axit clohiric v mui amoni. D. Clo v amoniac. Cu 3.38 Tnh baz ca amin no trong s cc amin sau y l yu nht ? A. anilin. B. iphenylamin. C. triphenylamin. D. khng xc nh c. Cu 3.39 Sn phm ca phn ng este ho gia amino axit X v metanol thu c este c t khi hi so vi propin bng 2,225. Tn gi ca X l A. alanin. B. glixin. C. axit glutamic. D. tt c A, B, C u sai. Cu 3.40 Cho dung dch metylamin n d vo cc dung dch sau: FeCl3, CuSO4, Zn(NO3)2, CH3COOK th s lng kt ta thu c l: A. 0. B. 1. C. 2. D. 3. Cu 3.41 Cho 15g hn hp cc amin gm anilin, metylamin, imetylamin, ietylmetylamin tc dng va vi 50ml dung dch HCl 1M. Khi lng sn phm thu c c gi tr l A. 16,825g. B. 20,18g. C. 21,123g. D. khng d kin tnh. Cu 3.42 Cho dung dch metylamin n d vo cc dung dch sau: (CH3COO)2Cu, (CH3COO)2Pb, (CH3COO)2Mg, CH3COOAg, th s lng kt ta thu c l: A. 0. B. 1. C. 2. D. 3. Cu 3.43 Khi nu canh cua, riu cua ni ln c gii thch l do: A. Cc cht bn trong cua cha c lm sch ht. B. C phn ng ho hc ca NaCl vi cht c trong nc lc khi xay (gi) cua. C. S ng t ca protit. D. Tt c cc nguyn nhn nu A, B, C. Cu 3.44 iu ch anilin bng cch kh nitrobenzen th dng cht kh no sau y ? A. NH3. B. kh H2. C. cacbon. D. Fe + dung dch HCl. Cu 3.45 Hn hp (X) gm hai amin n chc. Cho 1,52g X tc dng va vi 200ml dung dch HCl thu c 2,98g mui. Tng s mol hai amin v nng mol/l ca dung dch HCl l A. 0,04 mol v 0,2M. B. 0,02 mol v 0,1M. C. 0,06 mol v 0,3M. D. kt qu khc. Cu 3.46 Cho 3,04g hn hp Y gm hai amin n chc, no, mch h tc dng va vi dung dch HCl thu c 5,96g mui. Bit trong hn hp, s mol hai amin bng nhau. Cng thc phn t ca hai amin l A. CH5N v C2H7N. B. C3H9N v C2H7N. C. C3H9N v C4H11N. D. kt qu khc. Cu 3.47 Hp cht hu c (X) c cng thc phn t CxHyNO c khi lng phn t bng 113u. X c c im cu to v cc tnh cht sau: phn t c mch cacbon khng phn nhnh, khng lm mt mu dung dch Br2, khi tc dng vi dung dch NaOH ch thu c sn phm hu c duy nht. Ngoi ra, X cn c kh nng tham gia phn ng trng hp. Cng thc cu to ca X l

A.

CH2 CH2

CH2 CH2

CH2 C = O. NH

B. CH3

CH2

CH2

CH2

C NH2. O

C. H2N[CH2]4 CHO. D. kt qu khc. Cu 3.48 Hy ch ra cu sai trong cc cu sau: A. Cc amin u kt hp vi proton. B. Tnh baz ca cc amin u mnh hn NH3. C. Metylamin c tnh baz mnh hn anilin. D. Cng thc tng qut ca amin no, mch h l CnH2n+2+kNk.
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Cu 3.49 t chy hon ton hn hp hai amin no, n chc, l ng ng lin tip, thu c 2,24 lt kh CO2 (ktc) v 3,6g H2O. Cng thc phn t ca 2 amin l A. CH5N v C2H7N. B. C2H7N v C3H9N. C. C3H9N v C4H11N. D. kt qu khc. Cu 3.50 C hai amin bc mt gm A (ng ng ca anilin) v B (ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra kh CO2, hi H2O v 336 cm3 kh N2 (ktc). Khi t chy amin B thy VCO2 : VH2O = 2 : 3 . Bit rng tn ca A c tip u ng para. Cng thc cu to ca A, B ln lt l
NH2 NH2

A.
CH3

, C4H9-NH2.

B.
CH3

, CH3-CH2-CH2-NH2.

C. CH3-C6H4-NH2 , CH3-CH2-CH2-NH2.

D. CH3-C6H4-NH2 , CH3-CH-NH2.
CH3

Cu 3.51 t chy hon ton m g mt amin A bng lng khng kh va , thu c 17,6g kh cacbonic, 12,6g hi nc v 69,44 lt kh nit. Gi thit khng kh ch gm nit v oxi, trong nit chim 80% th tch (cc V o ktc). Gi tr m v tn gi ca amin l A. 9, etylamin. B. 7, imetylamin. C. 8, etylamin. D. 9, etylamin hoc imetylamin. Cu 3.52 Khi t chy hon ton mt amin n cht X, ngi ta thu c 10,125g H2O, 8,4 lt kh CO2 v 1,4 lt N2 (cc V o ktc). X c cng thc phn t l A. C4H11N. B. C2H7N. C. C3H9N. D. C5H13N. Cu 3.53 Cho 20g hn hp gm 3 amin no, n chc l ng ng lin tip ca nhau, tc dng va vi dung dch HCl, c cn dung dch thu c 31,68g hn hp mui. Nu 3 amin trn c trn theo t l s mol 1:10:5 v th t phn t khi tng dn th cng thc phn t ca 3 amin l A. C2H7N, C3H9N, C4H11N. B. C3H9N, C4H11N, C5H13N. C. C3H7N, C4H9N, C5H11N. D. CH3N, C2H7N, C3H9N. Cu 3.54 Dung dch X cha HCl v H2SO4 c pH = 2. trung ho hon ton 0,59g hn hp 2 amin no, n chc, bc I (c s nguyn t C nh hn hoc bng 4) phi dng mt lt dung dch X. Cng thc phn t ca hai amin ln lt l: A. CH3NH2 v C4H9NH2. B. C3H7NH2 v C4H9NH2. C. C2H5NH2 v C4H9NH2. D. A v C ng. Cu 3.55 Khi t chy mi ng ng ca ankylamin, th t l th tch X = VCO2 : VH2O bin i nh th no theo s lng nguyn t cacbon tng dn trong phn t ? A. 0,4 X < 1,2. B. 0,8 X < 2,5. C. 0,4 X < 1. D. 0,75 < X 1. Cu 3.56 t chy hon ton mt amin thm X thu c 3,08g CO2, 0,99g H2O v 336ml N2 (ktc). trung ho 0,1 mol X cn 600ml dung dch HCl 0,5M. Bit X l amin bc I, cng thc cu to thu gn c th c ca X l A. CH3C6H2(NH2)3. B. CH3NHC6H3(NH2)2. C. H2NCH2C6H3(NH2)2. D. c A, C u ng. Cu 3.57 Cc cht A, B, C c cng cng thc phn t C4H9O2N. Bit A tc dng vi c HCl v Na2O; B tc dng vi H mi sinh to ra B; B tc dng vi HCl to ra B; B tc dng vi NaOH to ra B; C tc dng vi NaOH to ra mui v NH3. Cng thc cu to thu gn ca A, B, C ln lt l A. C4H9NO2, H2NC3H6COOH, C3H5COONH4. C. C3H5COONH4, H2NC3H6COOH, C4H9NO2. B. H2NC3H6COOH, C3H5COONH4, C4H9NO2. D. H2NC3H6COOH, C4H9NO2, C3H5COONH4.

Cu 3.58 Mt hp cht hu c A mch thng c cng thc phn t l C3H10O2N2. A tc dng vi kim to thnh NH3. Mt khc, A tc dng vi dung dch axit to thnh mui amin bc I. Cng thc cu to ca A l A. H2NCH2CH2COONH4. B. CH3CH(NH2)COONH4. C. A v B u ng. D. A v B u sai. Cu 3.59 Nhng t hay cm t thch hp vi nhng ch trng cc cu trong on vn sau l Amin l nhng hp cht hu c c to thnh (1)mt hay nhiu (2)trong phn t amoniac bi (3). Amino axit l loi hp cht hu c ...(4)m phn t cha (5). V c nhm (6) v nhm (7) trong phn t, amino axit biu hin tnh cht (8)v tnh cht c bit l phn ng (9) (1) A. khi thay th (2) nguyn t hiro (3) mt hay nhiu gc hirocacbon (4) lung tnh (5) ng thi nhm cacboxyl v nhm amino (6) tp chc (7) cacboxyl (8) amino (9) trng ngng

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mt hay ng thi nhm tp nguyn lung trng nhiu gc cacboxyl v amino chc t hiro tnh ngng hirocacbon nhm amino mt hay ng thi nhm khi thay nguyn t tp lung trng C. nhiu gc cacboxyl v amino cacboxyl th hiro chc tnh ngng hirocacbon nhm amino mt hay ng thi nhm nguyn khi thay th tp lung trng D. nhiu gc cacboxyl v amino cacboxyl t hiro chc tnh ngng hirocacbon nhm amino Cu 3.60 Amino axit X cha mt nhm chc amin bc I trong phn t. t chy hon ton mt lng X thu c CO2 v N2 theo t l th tch 4:1. X l hp cht no sau y? A. H2NCH2COOH. B. H2NCH2CH2COOH. C. H2NCH(NH2)COOH.D. tt c u sai. Cu 3.61 Khi t chy hon ton ng ng X ca axit aminoaxetic, thu c VCO 2 : VH 2O = 6 : 7 . Cng thc cu to thu gn c th c ca X l A. CH3CH(NH2)COOH, H2NCH2CH2COOH, CH3NHCH2COOH. B. H2N[CH2]3COOH, CH3CH(NH2)CH2COOH, CH3NH[CH2]2COOH. C. H2N[CH2]4COOH, H2NCH(NH2)[CH2]2COOH, CH3NH[CH2]3COOH. D. kt qu khc. Cu 3.62 Hp cht X cha cc nguyn t C, H, O, N v c phn t khi l 89. Khi t chy 1 mol X thu c hi nc, 3 mol CO2 v 0,5 mol N2. Bit rng, X va tc dng c vi dung dch HCl va tc dng c vi dung dch NaOH, ngoi ra cn tc dng c vi nc brom. X l hp cht no sau y? A. H2N-CH=CH-COOH. B. CH2=C(NH2)-COOH. C. CH2=CH-COONH4. D. c A, B, C u sai. Cu 3.63 Hp cht hu c X c phn t khi nh hn phn t khi ca benzen, ch cha nguyn t C, H, O, N trong hiro chim 9,09%, nit chim 18,18%. t chy 7,7g cht X, thu c 4,928 lt kh CO2 (o 27,3oC, 1atm). Bit X tc dng vi dung dch NaOH v dung dch HCl. Cng thc cu to thu gn ca X l A. H2NCH2COOH. B. CH3COONH4 hoc HCOONH3CH3. C. C2H5COONH4 hoc HCOONH3CH3. D. c A, B, C u sai. Cu 3.64 Cho a g hn hp hai amino axit A, B u no, mch h, khng phn nhnh , cha 1 chc axit, 1 chc amino tc dng vi 40,15g dung dch HCl 20% c dung dch A. tc dng ht vi cc cht trong dung dch A, cn 140ml dung dch KOH 3M. Mt khc, t chy a g hn hp hai amino axit trn v cho sn phm chy qua dung dch NaOH d, th thy khi lng bnh ny tng thm 32,8g. Bit rng, khi t chy thu c kh nit dng n cht. Cho t l phn t khi ca chng l 1,37. Cng thc cu to thu gn ca hai amino axit ln lt l A. H2N[CH2]3COOH, H2NCH2COOH. B. H2NCH2COOH, H2N[CH2]3COOH. C. H2N[CH2]4COOH, H2NCH2COOH. D. c A, B u ng. Cu 3.65 A l mt amino axit trong phn t ngoi cc nhm cacboxyl v amino khng c nhm chc no khc. Bit 0,1 mol A phn ng va ht vi 100ml dung dch HCl 1M to ra 18,35g mui. Mt khc, 22,05g A khi tc dng vi mt lng NaOH d, to ra 28,65g mui khan. Bit A c cu to mch khng phn nhnh v nhm amino v tr . Cng thc cu to thu gn ca A l A. HOOCCH(NH2)COOH. B. HOOCCH2CH(NH2)COOH. C. HOOCCH2CH2CH(NH2)COOH. D. CH3CH2CH(NH2)COOH. Cu 3.66 X l mt -amino axit no ch cha mt nhm NH2 v mt nhm COOH. Cho 15,1g X tc dng vi dung dch HCl d, thu c 18,75g mui ca X. Cng thc cu to ca X l A. CH3CH(NH2)COOH. B. H2NCH2CH2COOH. C. CH3CH2CH(NH2)COOH. D. kt qu khc. Cu 3.67 Chn pht biu sai: A. Thu phn protein bng axit khi un nng s cho mt hn hp cc amino axit. B. Phn t khi ca mt amino axit (gm 1 chc amino v 1 chc cacboxyl) lun lun l s l. C. Cc amino axit u tan trong nc. D. Dung dch amino axit khng lm giy qu i mu. Cu 3.68 Hy in nhng t hoc cm t thch hp vo cc ch trng cc cu sau - Protein c trong - Cc protein u cha cc nguyn t - nhit thng di tc dng ca men, protein to ra cc amino axit.
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- Mt s protein b khi un nng hoc khi cho thm mt s ho cht. (1) mi b phn ca c th; (2) b thu phn; (3) cacbon, hiro, oxi, nit; (4) ng t Nhng t hoc cm t thch hp theo trnh t t trn xung l A. (1), (2), (3), (4). B. (1), (3), (2), (4). C. (1), (4), (3), (2). D. (4), (2), (3), (1). Cu 3.69 Cu khng nh no sau y lun ng: A. Phn t khi ca mt amin n chc lun l s chn. B. Amin lun lun phn ng vi H+. C. Mi amin n chc u cha mt s l s nguyn t H trong phn t. D. B v C u ng. Cu 3.70 Cho cc cht: (1) amoniac; (2) anilin; (3) p-nitroanilin; (4) p-nitrotoluen; (5) metylamin; (6) imetylamin. Trnh t tnh baz tng dn theo chiu t tri sang phi l A. (1) < (4) < (3) < (2) < (5) < (6). B. (2) < (1) < (3) < (4) < (5) < (6). C. (4) < (3) < (2) < (1) < (5) < (6). D. (1) < (2) < (4) < (3) < (5) < (6). Cu 3.71 t chy hon ton 0,02 mol mt amin bc I (X) vi lng oxi va , thu ton b sn phm qua bnh cha nc vi trong d, thy khi lng bnh ng nc vi trong tng 3,2g v cn li 0,448 lt (ktc) mt kh khng b hp th, khi lc dung dch thu c 4,0g kt ta. X c cng thc cu to no sau y? A. CH3CH2NH2. B. H2NCH2CH2NH2. C. CH3CH(NH2)2. D. B, C u ng. Cu 3.72 Amino axit (Y) c cng thc dng NCxHy(COOH)m. Ly mt lng axit aminoaxetic (X) v 3,82g (Y). Hai cht (X) v (Y) c cng s mol. t chy hon ton lng (X) v (Y) trn, th tch kh oxi cn dng t chy ht (Y) nhiu hn t chy ht (X) l 1,344 lt (ktc). Cng thc cu to thu gn ca (Y) l A. CH3NHCH2COOH. B. H2NCH2CH2COOH. C. N(CH2COOH)3. D. NC4H8(COOH)2. Cu 3.73 Hp cht X cha cc nguyn t C, H, O, N vi t l khi lng tng ng l 3:1:4:7. Bit phn t X c 2 nguyn t nit. Cng thc phn t ca X l: A. CH4ON2. B. C3H8ON2. C. C3H8O2N2. D. kt qu khc. 49. 50. Cho s chuyn ho sau: Cht Z l A. CH3 CH(OH) COOH. B. CH3 CH(OH) COOCH3. C. H2N CH2 COOCH3. D. H2N CH(CH3) COOCH3. 51. chng minh glyxin C2H5O2N l mt aminoaxit, ch cn cho phn ng vi: A. NaOH. B. HCl. C. CH3OH/HCl. D. NaOH v HCl. 52. C3H7O2N c bao nhiu ng phn aminoaxit (vi nhm amin bc 1)? A. 2. B. 3. C. 4. D. 5. 53. Cho cc phn ng:
+ 3OH / HCl CH + NH3 + HNO2 Alanin X Y Z

H2NCH2COOH + HCl Cl H3N + CH2COOH H2NCH2COOH + NaOH H2NCH2COONa +H2O

Hai phn ng trn chng t axit aminoaxetic A. c tnh lng tnh. B. ch c tnh baz. C. ch c tnh axit. D. va c tnh oxi ho, va c tnh kh. 54. Hp cht khng lm i mu giy qu m l A. CH3NH2. B. C6H5ONa. C. H2N CH2 CH(NH2)COOH. D. H2NCH2COOH. 55. ng dng no ca aminoaxit di y khng ng? A. Aminoaxit thin nhin (hu ht l - aminoaxit) l c s kin to nn cc loi protein ca c th sng. B. Cc axit amin c nhm NH2 t v tr s 6 tr ln l nguyn liu sn xut t nilon. C. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt). D. Axit glutamic l thuc b thn kinh. 56. Cho dy chuyn ho sau:
+ NaOH + HCl Glyxin Z X + HCl + NaOH Glyxin T Y

X v Y ln lt l A. u l ClH3NCH2COONa.
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B. ClH3NCH2COOH v ClH3NCH2COONa. C. ClH3NCH2COONa v H2NCH2COONa. D. ClH3NCH2COOH v H2NCH2COONa. 57. Cho Tirozin (HOC6H4CH2CH(NH2)COOH) (X) phn ng vi cc cht sau, trng hp no phng trnh ho hc vit khng ng: NH A. X +2HCl Cl C H CH CH(COOH) 3 Cl +H O 6 4 2 2

B. X + 2NaOH NaOC H CH CH(NH )COONa + 2H O 6 4 2 2 2

C. X + HNO HO C H CH 2 6 4 2
khHCl

CH(OH)COOH + N + H O 2 2

58.

59.

60.

61.

D. X + C H OH HO C H CH CH(NH )COOC H + H O 2 5 6 4 2 2 2 5 2 28,1 gam hn hp propylamin, axit aminoaxetic v etylaxetat c th phn ng vi 6,72 lt hiroclorua ( ktc). Cng mt lng hn hp trn c th phn ng vi 100 ml dung dch KOH 1M (cc phn ng va ). % khi lng ca aminoaxit trong hn hp l A. 22%. B. 23,3%. C. 54,7%. D. 26,69%. Hp cht X gm cc nguyn t C, H, O, N vi t l khi lng tng ng l 3 : 1 : 4 : 7. Bit X c 2 nguyn t N. Cng thc phn t ca X l A. CH4ON2. B. C3H8ON2. C. C3H8O2N2. D. C3H7O2N2. Cho hn hp X gm 2 cht hu c c cng cng thc phn t C 2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm 2 kh (u lm xanh qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc hp cht u tc dng c vi dung dch NaOH v u tc dng vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T.

B-10Cu 39: Hn hp X gm alanin va axit glutamic. Cho m gam X tac dung hoan toan vi dung dich NaOH (d), thu c dung dich Y cha (m+30,8) gam mui. Mt khac, nu cho m gam X tac dung hoan toan vi dung dich HCl, thu c dung dich Z cha (m+36,5) gam mui. Gia tri cua m la A. 112,2 B. 165,6 C. 123,8 D. 171,0 Gii: Gi s mol: ala x Glu y + Tc dng NaOH ta c: x + 2y = 1,4 (*) + Tc dng HCl ta c: x + y = 1 (2*) Gii (*), (2*) x = 0,6 mol; y = 0,4 mol m = 0,6. 89 + 0,4. 147 = 112,2 gam
A-09Cu 9: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m 1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2m1=7,5. Cng thc phn t ca X l A. C4H10O2N2. B. C5H9O4N. C. C4H8O4N2. D. C5H11O2N. GII t cng thc ca amino axit X l (H2N)xR(COOH)y. Y l (ClH3N)xR(COOH)y, Z l (H2N)xR(COONa)y 16x + R + 67y - 51,5x + R + 45y) = 7,5 22y 36,5x = 7,5 y=

7,5 + 36,5 x 22

x=,y=2 X l H2NR(COOH)2 CD09 : Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C 3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH2(CH3)2. B. CH3COONH3CH3.
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C. HCOONH3CH2CH3. D. CH3CH2COONH4.

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