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on- site technic al support d uring all sta ges of producti on. Technical sup por t incl udes on-site testing and results. PRODUCT SAFETY All Chemiphase International products are thoroughly researched and tested. All products are also COSHH registered and come complete with delivery. For more information on any of our products or services please visit us on the Web at:
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CP 2622

Ship Waste Treatment Sludge Conditioner

DESCRIPTION
CP 2622 has been specifically designed for the shipping industry, Chemiphase International sludge conditioner can help maritime operators reclaim the expense of dealing with tank sludge, bilge water and slop oil. CP 2622 consists of a carefully formulated mixture of demulsifying chemicals that force the water and solids away from the oil. When separated the water forms a forms a clear layer below the oil which can be drained off, leaving a dry clear oil. By the time the process is complete, the oil mixture comprises of approximately 10% water and 90% oil which can then be sold as is or processed further using mechanical oil/water splitters. This will then create a commodity that most disposal companies will pay for putting an end to expensive sludge tank drainage. From fishing fleets to cruise liners, this product is extremely versatile and could be used across the whole maritime industry. CP 2622 is ideal for use in cargo or passenger ships which empty their sludge tanks every 2-3 days. CP 2622 contains a unique blend of chemicals that combine to form the most effective demulsifier on the market. You can be sure you will maximize the value of your sludge oil for the most cost effective solution.

BENEFITS
Efficient Low-cost Easy to apply Environmentally friendly Inversion of cut to 95% oil / 5% water Cuts sludge disposal costs Clear oil / water split CP 2622 remains in oil phase and not lost when removing water cut Greater distances between tanking off Versatile can be used on almost any ship Turns a by-product into a valuable commodity. With 95% oil content improves on-board incineration. And, by cutting waste and recycling run-off sludge oil, CP 2622 can also ensure that the maritime industry is kinder to the environment.

Phone :
+44 (0) 8456 432900

Email :
sales@chemiphase.co.uk

PR ODU CT R ANG E : FUEL TREATMENT FUEL CETANE ENHANCEMENT BIOLOGICAL CONTROL SOOT CLEANER SOOT CLEANER LIQUID SHIP MAINTENANCE DECK CLEANER CEMENT REMOVER LIME CLEANER TANK CLEANER SLOP OIL TREATMENT PENETRATING OILS GENERAL CLEANING CARBON REMOVER DESCALER LIQUID OIL SPILL EMULSIFIER OIL AND GREASE REMOVER LIQUID SOAP HAND CLEANER ODOUR CONTROL TANK CLEANING TANK CLEANER SOLVENT TANK CLEANER BOILER WATER TREATMENT ALKALINITY CONTROL BOILER SLUDGE CONDITIONER PHOSPHATE CONTROL

CP 2622
Ship Waste Treatment Sludge Conditioner

How To Use CP 2622 Ship sludge conditioner is easy to use. In essence sludge conditioner is added to the tank, left for 2-3 days, and then heated to 65-85C, using the standard heating equipment fitted to the ship. After this, the water can be drained off. The quantity required to treat the sludge depends on the capacity of the sludge tank or the volume of the sludge normally disposed of onshore. Capacity of Sludge Tank 10,000 Litres (2641 US gallons) 20,000 Litres (5282 US gallons) 50,000 Litres (13,205 US gallons) Quantity of CP2622 Required (2000 ppm) 20 Litres 40 Litres 100 Litres

Once added, the product will mix naturally with the incoming sludge, aided by the normal motion of the ship. CP 2622 is oil soluble and will remain in the sludge oil throughout its time in the sludge tank. If the correct dose of conditioner has been used, this will continue to act on new incoming sludge as before. If there is no separation of the new incoming sludge then more conditioner can be added at any stage. This process of heating/ cooling/ draining can be repeated over a period of several days for maximum efficiency.

DISCLAIMER : The information and all further technical advice is based on our present knowledge and experience. However, they imply no liability or other legal responsibility on our part, including with regards to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied of guarantee of product properties is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out by qualified experts in the sole responsibility of the customer.

Case Study 432

Ship Name : Stena Line Europe na Fuel Type 380 cst Customer of Chemiphase International for 10 Years Contact - Don Maclean (Chief Engineer of Stena Europe) Stena Line Europe have been using Chemiphase Internationals CP 2622 for over 10 years with excellent results. Below is a brief explanation of how they use the product and a brief outline of their process when handling sludge :

Stena have modified their internal tanking system to process sludge, slop and waste lubricating oils within the ship. This has resulted in longer time intervals between discharge into port side collection tanks and substantial cost saving. Sludge Tank The main sludge tank collects the oil/water from the Heavy Fuel Oil Purifier which sits directly above the tank. This ship has two 7 MT Lubricating Oil sludge tanks, each containing a Lubricating Oil Purifier above them. Once a week the contents of the Lubricating Oil Sludge tanks are transferred to e the main sludge tank. Bilge Tank Bilges are pumped to a bilge holding tank via a 100 ppm separator. Once the oil level in this separator rises it dumps this oil/ water mixture to the main sludge tank. water A Bilge holding tank pumps overboard via a 15ppm filter, with anything fluid registering above 15 ppm being directed to the main sludge tank. The main tank has a steam coil and can be heated.

Case Study 432

Separation Tanking This tank is where our main separation takes place. It is filled from the Main Sludge Tank with Chemiphase Internationals CP 2622 dosed directly at this point. The tank is heated to about 70 degrees and left to separat The tank is drained at separate. regular intervals during the day to run off the water that has been separated by the CP2622. The water that is removed is sent back to the bilge, and eventually ends up back in bilge holding tank and discharged to sea. Discharge Tank Once the separation tank has been drained of water, we transfer the waterless oil into a discharge tank, which is the final holding place before we discharge to our onshore road tanker. This final waste oil is dry and contains minimal water.

CP-2622 is designed to remain in 2622 the oil phase so it will keep working until the tank contents are emptie emptied.

Example: Ferry Services Before CP-2622 UK Cost of pumping slop oil 50/ MT Annual quantity: Cost per month: Cost per annum: 10 ships Every 3 days x 10 MT 5,000 60,000 600,000 Using CP-2622 50/ MT Every month 10 MT 500 6,000 60,000

Chemiphase International Ltd Unit 2 Ringtail Industrial Estate, Burscough, Lancashire, L40 8JY Tel : +44 (0)8456) 432 900 Fax : +44 (0) 1744 886633 8456) Web : www.rsintl.eu / www.chemiphase.co.uk Email : sales@chemiphase.co.uk

Case Study 432

Revision date: March 2015

SAFETY DATA SHEET

CP 2622 (Ship Sludge Conditioner)

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY UNDERTAKING
PRODUCT NAME: PRODUCT Description: APPLICATION SUPPLIER

CP 2622 Raw Material (Ship Sludge Conditioner) Raw Material

Ship Sludge Conditioner Chemiphase Ltd Unit 2 Ringtail Industrial Estate Burscough Lancashire, L40 8JY T: +44 (0) 01744 886622 F: +44 (0) 01744 886633 EMERGENCY TELEPHONE (24 HR) 00 44 (0) 1744 886622

2. COMPOSIITON INFORMATION ON INGREDIENTS

NAME 2-BUTOXYETHANOL XYLENE EC No 203-905-0 215-535-7 CAS No 111-76-2 1330-20-7 CONTENT 8-15% 15-22% CLASSIFICATION XnR20/21/22 Xi,R36/38 R10 Xn, R10/R20/21 Xi, R38 & S16

The Full Text for all R- Phrases are displayed in Section 16

3. HAZARDS IDENTIFICATION
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes and skin. CLASSIFICATION Xn; R20/21/22. Xi;R36/38

4. FIRST AID MEASURES

GENERAL INFORMATION Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. INHALATION Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Keep the affected person warm and at rest. Get prompt medical attention. INGESTION NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Remove victim immediately from source of exposure. Rinse mouth thoroughly. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention immediately.

EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eyelids. Continue to rinse for at least 15 minutes and get medical attention.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA Use: Powder, Carbon dioxide (CO2). Water spray. Foam SPECIAL FIRE FIGHTING PROCEDURES Avoid water in straight hose stream; will scatter and spread fire. Use water to keep fire exposed containers cool and disperse vapours. Keep run-off water out of sewers and water sources. Dike for water control. SPECIFIC HAZARDS By heating and fire, irritating vapours/gases may be formed. PROTECTIVE MEASURES IN FIRE Wear personal protective equipment. Wear self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin and eyes. Provide adequate ventilation. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, watercourses or onto the ground. SPILL CLEAN UP METHODS Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Do not contaminate water sources or sewer.

7. HANDLING AND STORAGE

Usage precautions Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. STORAGE PRECAUTIONS Store in tightly closed original container in a cool dry well-ventilated place. Use container made of : Stainless steel. Suitable plastic material. Do NOT use container made of: Carbon steel.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

Name XYLENE 2-BUTOXYETHANOL Std OES OES LT - ppm 50 ppm (Sk) 25 PPM(Sk) LT mg/m3 220 mg/m3 (Sk) ST - ppm 100 ppm(Sk) 50 ppm(Sk) ST mg/m3 441 mg/m3(Sk)

INGREDIENT COMMENTS OES = Occupational Exposure Standard. 2 Butoxyethanol (EGMBE) has a Biological Monitoring Guidance Value. See UK HSE EH40 Table 3 PROTECTIVE EQUIPMENT Goggles and Gloves ENGINEERING MEASURES Provide adequate general and local exhaust ventilation RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. Wear respiratory protection with combination filter (dust and gas filter). HAND PROTECTION Use protective gloves. Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.

EYE PROTECTION Wear approved safety goggles. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap and water if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE COLOUR ODOUR: MELTING POINT (Oc) Ph, VALUE, DILUTED SOLUTION FLASH POINT (OC) Liquid Slightly hazy Slight Aromatic Pour Point , -20 Boiling Point/ range (OC) RELATIVE DENSITY 137-143 0.990 @ 20OC

6.5-8.5, 5% in water 25

VISCOSITY AUTOFlammability (OC)

< 100 mPas @ 20oC 480

10. STABILITY AND REACTIVITY

STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition MATERIAL TO AVOID Strong oxidising substances. Strong acids HAZARDOUS DECOMPOSITION PRODUCTS During fire, toxic gases (CO, CO2) are formed.

11. TOXICOLOGICAL INFORMATION

TOXIC DOSE 1 LD50 >4000 mg/kg (oral rat)

INHALATION Harmful by inhalation. In high concentrations, vapours are anaesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Upper respiratory irritation. Vapours may cause headache, fatigue, dizziness and nausea. INGESTION Harmful if swallowed. Gastrointestinal symptoms, including upset stomach. May cause nausea, headache, dizziness and intoxication. SKIN CONTACT Harmful in contact with skin. Irritating to skin. EYE CONTACT Irritating to eyes. Spray and vapour in the eyes may cause irritation and smarting. Other Health Effects No sensitising effects known.

12. ECOLOGICAL INFORMATION

ECOTOXICITY The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. MOBILITY The product is insoluble in water BIOACCUMULATION No data available DEGRADABILITY The product is expected to be biodegradable WATER HAZARD CLASSIFICATION WGK 1

13. DISPOSAL CONSIDERATIONS

GENERAL INFORMATION Empty containers should be taken for local recycling, recovery or waste disposal DISPOSAL METHODS Recover and reclaim or recycle, if practical. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.

14. TRANSPORT INFORMATION

GENERAL ADR/RID Packing Group: III Shipping name n/a Labelling: 3 IMDG/IMO Packing Group: III Marine Pollutant: NO IATA/ICAO Packing Group: III Marine Pollutant: NO HS Code UN no: 1307 Hazard ID no: 30 UN no: 1307 UN no: 1307 Classification code: F1 ADR Class: 3

Class: 3

EMS:F-E, S-D Labelling: 3 Class: 3

Packing Instructions; 309(p&CA):310(CAO) Labelling: 3 270730

15. REGULATORY INFORMATION

LABELLING

Harmful

CONTAINS RISK PHRASES

2-BUTOXYETHANOL, Xylene R20/21/22 R10 R36/38 Harmful by inhalation, in contact with skin and if swallowed Flammable Irritating to eyes and skin Wear suitable protective clothing and gloves Keep away from sources of ignitionNO SMOKING This material and its container must be disposed of as hazardous waste Do not breathe vapour/spray In case of contact with eyes, rinse immediately with plenty of water and see

SAFETY PHRASES

S36/37 S16 S60 S23 S26

medical advice S51 S24/25 UK REGULATORY REFERENCES Approved Supply List STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Occupational Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply. Use only in well-ventilated areas Avoid contact with skin and eyes

16. OTHER INFORMATION

REVISION COMMENTS General revision ISSUED BY CES REVISION DATE REVISED SDS GENERATED RISK PHRASES IN FULL R10 R20/21 R20/21/22 R36/38 R38 Flammable Harmful by inhalation and in contact with skin Harmful by inhalation, in contact with skin and if swallowed Irritating to eyes and skin Irritating to skin MARCH 2015 MARCH 2010