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=mx .
Trong :
y : nng phn mol ca NH
3
trong dng kh iu kin cn bng .
x : nng phn mol kh ha tan trong pha lng .
P : p sut ring phn ca cu t kh ha tan khi cn bng .
P
t
: p sut tng ca h hp thu .
H : h s Henry .
V 35
o
C khng c trong bng nn ly xp x 30
0
C : H = 0,00241 x 10
6
(mmHg) Tra bng IX.1 (s tay cng ngh ha cht tp 2).
m : h s phn b .
m =
t
P
H
=
760 . 8 , 5
10 . 00241 , 0
6
= 0,5467
y =
Y
Y
+ 1
x =
X
X
+ 1
Thay vo trn ta c : y = m.
X
X
+ 1
=>
Y
Y
+ 1
=m.
X
X
+ 1
Y =
X m
mX
) 1 ( 1 +
=
X
X
). 5467 , 0 1 ( 1
. 5467 , 0
+
M : y = y
d
= 0,26 ; X = X
cmax
y = m.
X
X
+ 1
=> 0,26 = 0,5467.
X
X
+ 1
7
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
=> X = X
cmax
= 0,9069
Theo thc nghim ta c: L
= (1,2 1,3)L
min
.
Chn L= 1,2L
min
=> L
min
= L
tr
/1,2 = 23,88/1,2 = 19,9
Hp thu NH
3
bng nc , chn dung mi sch khi vo thp nn : X
d
= 0
G
tr
= 59,09
G
d
= G
tr
/(1 y
d
) = 59,09/(1 0,26) = 43,73 (kmol/h)
G
c
= G
tr
/(1 - y
c
) = 59,09/(1 0,0436) = 56,51(kmol/h)
G
d
=
RT
PV
> V
d
= G
d
.RT/P= 43,7266 x 0,082 x 35/5,8 = 21,63 (m
3
/h)
Phng trnh cn bng vt cht c dng ;
G
tr
.Y
+ L
tr
.X
= G
tr
.Y
c
+ L
tr
.X
c
Suy ra :
d c
c d
tr
tr
X X
Y Y
G
L
Suy ra : X
c
=
tr
tr
c d
G
L
Y Y
=
7559 , 0
404 , 0
0456 , 0 351 , 0
(mol NH
3
/KmolH
2
O)
x
c
= X
c
/(1 + X
c
) = 0,7559/(1 + 0,7559) = 0,4305.
III. TNH TON CC THNG S CA THP
III.1. Thng s vt l
III.1.1. Thng s vt l pha kh
- Lu lng kh trung bnh i trong thp hp thu :
2
c d
ytb
V V
V
+
V
d
, V
c
lu lng kh vo v ra khi thp , m
3
/h .
V
c
= V
tr
x ( 1 + Y
c
)
=
( ) ( ) ( ) ( ) 704 , 16 0436 , 0 1 . 26 , 0 1 . 63 , 21 1 . 1 + +
c d d
Y y x V
(m
3
/h)
Suy ra : V
ytb
=
16 , 19
2
7 , 16 63 , 21
+
(m
3
/h) .
- KLR trung bnh ca pha kh :
( ) [ ]
T
M y M y
tb tb
ytb
. 4 . 22
273 . . 1 .
2 1 1 1
+
8
Yc Yd
Xd Xc
L G
tr
max
min
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
Trong :
+ M
1
, M
2
: Khi lng mol ca NH
3
v khng kh .
+ T : nhit lm vic trung bnh ca thp hp thu . T = 35
0
C
+ y
tb1
: nng phn mol ca NH
3
ly theo gi tr trung bnh.
2
1 1
1
c d
tb
y y
y
+
Vi y
d1
, y
c1
: nng phn mol ca NH
3
vo v ra khi thp .
y
d1
= y
d
= 0,26
0436 , 0
1
1
+
c
c
c
Y
Y
y
Suy ra :
1518 , 0
2
0436 , 0 26 , 0
1
+
tb
y
+ M
1
= M
NH3
= 17 (g/mol)
M
2
= M
kkh
= 28.8 (g/mol)
Suy ra : ytb
=
( ) [ ]
( )
068 , 1
35 273 . 4 , 22
273 . 8 , 28 . 1518 , 0 1 17 . 1518 , 0
+
+
kg/m
3
- nht trung bnh pha kh (ca hn hp kh):
2
2 2
1
1 1
. .
M m M m M
hh
hh
+
+ M
hh
, M
1
, M
2
: khi lng phn t ca hn hp kh , ca NH
3
v khng kh ,
kg/kmol .
M
1
= 17(kg/kmol)
M
2
=
M
kk
= 28.8 (kg/kmol) .
( ) ( ) 008 , 27 8 , 28 . 1518 , 0 1 17 . 1518 , 0 . 1 .
2 1 1 1
+ + M y M y M
tb tb hh
(kg/kmol) .
+ m
1
, m
2
: nng ca NH
3
, khng kh tnh theo phn h tch.
m
1
= y
tb1
= 0,1518
m
2
= 1 y
tb1
= 1 0,1518 = 0,8482
+ 35
0
c :
2
=
kk
= 0,024.10
-3
(kg/m.s).
1
=
3
NH
= 0,0173.10
-3
(kg/m.s).
9
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
Thay vo ta c :
2
2 2
1
1 1
. .
M m M m M
hh
hh
+
=> 3 3
10 024 , 0
8 , 28 8482 , 0
10 0173 , 0
17 1518 , 0 008 , 27
hh
Suy ra :
5
10 3142 , 2
hh
(kg/m.s).
- Lu lng khi lng pha kh trung bnh:
2
c d
ytb
G G
G
+
, kg/s
G
d
, G
c
: lu lng kh vo v ra khi thp , kg/s .
Suy ra :
12 , 50
2
51 , 56 73 , 43
ytb
G
(kmol/h) = 50,12/3600 = 0,0139222
(kg/s)
III.1.2. Thng s vt l pha lng
- V
xtb
: lu lng dng lng trung bnh.
Do lng cu t ho tan trong dung dch nh , xem qu trnh hp thu khng lm
thay i ng k th tch nn :
tr
tr tr tr xtb
M L V V
1
. .
Vi : tr
= 994,2 (kg/m
3
) .
M
tr
: khi lng phn t ca H
2
O , kg/kmol .
L
tr
: lu lng nc , kmol/h .
Suy ra :
0175 , 3
2 , 994
1
18
18
300
xtb
V
m
3
/h
- Khi lng ring trung bnh ca pha lng :
( )
2 1 1 1
. 1 .
tb tb tb tb xtb
V V +
1 tb
, 2 tb
O H xtb
(kg/m.s).
- Lu lng khi lng trung bnh ca pha lng:
2
xc xd
xtb
G G
G
+
xd
G
, xc
G
: lu lng khi lng dng lng vo v ra khi thp .
5 , 1
3600
1
. 18 . 300 *
tr tr xd
M L G
(kg/s) .
( )
3600
17 7559 , 0 300 18 300
* * *
2
+
+
SO c tr tr tr xc
M X L M L G
= 2,5708 (kg/s).
Suy ra : G
xtb
=
0354 , 2
2
5708 , 2 5 , 1
2
+
+
xc xd
G G
(kg/s).
III.2. Tnh ng knh thp hp th
Tc bt u to nh tng , cn gi l tc o pha W
s
(m/s ) c xc nh
theo cng thc :
8
1
4
1
16 . 0
3
2
. ) .( 75 , 1
. .
. .
lg
,
_
1
1
]
1
,
_
xtb
ytb
y
x
n
x
xtb d
ytb d p
G
G
A
V g
W
Vi :
+ G
x
, G
y
: lu lng dng lng v kh trung bnh , kg/s .
G
x
= G
xtb
= 2,0354 (kg/s).
G
y
= G
ytb
= 0,0139 (kg/s).
+
xtb
,
ytb
: khi lng ring trung bnh ca pha lng v kh .
xtb
= 994,2 (kg/m
3
) .
ytb
= 1,068 (kg/m
3
) .
+
x
: nht trung bnh pha lng theo nhit trung bnh.
x
=
xtb
= 0,7679 10
-3
(kg/m.s).
+
n
: nht ca nc 20
0
C .
n
= 1,005.10
-3
(kg/m.s) .
11
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
A : h s , A = 0,022
Chn m vng Raschig bng s, kch thc 12 x 12 x 1,8mm cc thng s ca
m :
d
: b mt ring
d
= 360 m
2
/m
3
V
d
: th tch t do
V
d
= 0,67 m
3
/m
3
d
d
= 800 kg/m
3
8
1
4
1
16 . 0
3
2
. ) .( 75 , 1
. .
. .
lg
,
_
1
1
]
1
,
_
xtb
ytb
y
x
n
x
xtb d
ytb d p
G
G
A
V g
W
Thay s vo ta c:
lg
8
1
4
1
16 . 0
3
3
3
2
2 , 994
299 , 1
.
0139 , 0
0345 , 2
. 75 , 1 022 . 0
10 . 005 , 1
10 . 7679 , 0
.
2 , 994 . 67 , 0 . 81 , 9
068 , 1 . 360 .
,
_
,
_
1
1
]
1
,
_
p
W
p dng cng thc logarit: log
a
N = y => N = a
y
W
p
= 0,1364 (m/s).
Chn tc lm vic :
12272 , 0 9 , 0
p tb
W
(m/s).
ng knh thp c xc nh theo cng thc :
23 , 0
396 , 0 3600
16 , 19 4
3600
4
tb
tb
V
D
(m) .
III.3. H s khuch tn
III.3.1. H s khuch tn pha lng
( )
6 . 0
'
5 . 0
12
.
. . 10 . 4 , 7
A
B
x
V
T M
D
, m
2
/s .
Trong : M
B
l khi lng mol ca dung mi , M
B
=
18
2
O H
M
(kg/kmol)
l h s kt hp cho dung mi , = 2.6 cho dung mi l nc .
T = 273 + 35 = 308
0
K , nhit khuch tn .
V
A
= 25,8 cm
3
/mol , l th tch mol ca dung cht .
: l d nht ca dung dch .
12
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
=
7679 , 0
2
O H
(Cp) .
Suy ra :
( )
10
6 . 0
3 . 0 12
10 . 61135 , 9
8 , 44 . 7679 , 0
305 . 18 . 6 , 2 10 . 4 , 7
x
D (m
2
/s)
III.3.2. H s khuch tn pha kh
2
1
2
3
1
3
1
2
3
7
1 1
.
. 10 . 3 , 4
,
_
,
_
B A
B A
y
M M
V V P
T
D
.
Trong : T = 273 +35 = 308
0
K
P = 1 at , Ap sut khuch tn .
M
A
, M
B
: l khi lng mol kh NH
3
v khng kh .
M
A
=
2
SO
M
= 17 (kg/kmol) .
M
B
= M
kk
= 28,8 (kg/kmol) .
V
A
, V
B
: th tch mol ca SO
2
v ca khng kh .
V
A
= 25,8 (cm
3
/mol). Tra bng 1.4 gio trnh /trang 21
V
B
= 29,9 (cm
3
/mol) . Tra bng 1.4 gio trnh/trang 21
2
1
2
3
1
3
1
2
3
7
1 1
.
. 10 . 3 , 4
,
_
,
_
B A
B A
y
M M
V V P
T
D
Th vo ta c :
6
2
1
2
3
1
3
1
2
3
7
10 339 , 3
8 , 28
1
17
1
9 , 29 8 , 25 . 8 , 5
308 . 10 . 3 , 4
,
_
,
_
y
D
(m
2
/s).
III.4. Mt s thng s khc
+ G
y
, L
x
l tc khi lng ca kh v lng tng ng mt n v tit din ngang
ca thp (kg/m
2
.s).
Tit din ngang ca thp : 04 , 0
4
23 , 0
4
2 2
D
F
t
(m
2
)
3475 , 0
04 , 0
0139 , 0
t
ytb
y
F
G
G
(kg/m
2
.s).
885 , 50
04 , 0
0354 , 2
t
xtb
x
F
G
L
(kg/m
2
.s).
13
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
+
y
=0,0173.10
-3
kg/m.s , l nht pha kh.
+
y
=
ytb
= 1,068 kg/m
3
l khi lng ring pha kh.
+ D
x
, D
y
: l h s khuch tn trong pha kh v trong pha lng (m
2
/s).
G
x
= G
xtb
= 2,0354 (kg/s).
G
y
= G
ytb
= 0,0139 (kg/s).
36 , 7
10 7679 , 0 360 04 , 0
0354 , 2 04 , 0 04 , 0
Re
3
x t
x
x
F
G
75 , 12
10 0173 , 0 07 , 0 360
0139 , 0 4 , 0
4 , 0
Re
3
y t
y
y
F
G
61 , 803
10 . 61135 , 9 2 , 994
10 . 7679 , 0
Pr
10
3
x x
x
x
D
851 , 4
10 . 339 , 3 068 , 1
10 0173 , 0
Pr
6
3
y y
y
y
D
III.5. H s thm t
-U
tt
=
t
x
F
V
l mt ti thc t , (m
3
/m
2
.h) .
Trong : V
x
= V
xtb
= 3,0175 (m
3
/h) .
F
t
= 0,04 (m
2
) .
Suy ra :
4375 , 75
04 , 0
0175 , 3
tt
U
(m
3
/m
2
h) .
-Mt ti thch hp U
th
:
U
th
= B.
d
, (m
3
/m
2
h) .
B = 0,158 (m
3
/m.h)
d
= 360 m
2
/m
3
Suy ra : U
th
= 0.158 x 360 = 56,88 (m
3
/m
2
h) .
Vy :
3261 , 1
88 , 56
43 , 75
th
tt
U
U
Khi mt ti ln > 5m
3
/m
2
.h, ta chn = 1 dung mi thm t u ln
m.
14
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
III.6. Chiu cao thp mm chp
H
d
= m
y
.h
y
Chiu cao mt n v thp
h
Y
= h
G L
h
l
m
+
m = 0,5467
Vi :
404 , 0
tr
tr
G
L
G
L
l
Suy ra :
2 , 1 8009 , 0
404 , 0
5467 , 0
1161 , 0 +
Y
h
(m) (1)
Xc nh m
y
:
y
d
= y
d
m.x
c
= 0,26 0,5467 x 0,4350.10
-3
= 0,26
y
c
= y
c
y
c
*
= 0,0436 0,000237 = 0,043353
Da vo phng trnh y=mx=
y
c
*
= =0,000237
X
c
= 0,00534
Lp t s: y
d
/y
c
= 5,997 > 2
y
tb
=
c
d
c d
y
y
y y
ln
= 0,1209
m
y
= (y
d
y
c
)/ y
tb
= (0,26 0,0436)/0,1209 = 1,789 (2)
T (1) v (2), ta c
H
d
= m
y
.h
y
= 2,147 m
15
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
III.7. Tr lc thp
III.7.1. Tr lc a kh
(cng thc tra s tay truyn nhit tp 2 trang 192)
Trong :
: h s tr lc
= 4,5 5
ytb
= 1,068 khi lng ring pha kh(kg/m
3
)
12272 , 0
0
tb
: tc i qua rnh chp (m/s)
k
P
=
036 , 0
2
12272 , 0 068 , 1
5 , 4
2
3.7.2. Tr lc ca a do sc cng b mt s
p
(cng thc tra s tay truyn nhit tp 2 trang 192)
d
td
= ng knh tng ng ca khe rnh chp m
: sc cng b mt
= 360 m
2
/m
3
Chn m vng Raschig bng s, kch thc 12 x 12 x 1,8mm
B H f
12 x 1,8 = 21,6 (rnh hnh ch nht)
Khi rnh chp m hon ton
50 , 27
6 , 21 4 4
f
d
td
s
p
= (4 x 360)/27,5 = 52,36
Tng tr lc
P = s
p
+ k
P
= 52,36 + 0,036= (N/m
2
).
16
Bi bo co: Dng thp mm chp hp thu NH3 GVHD: Nguyn HuTrung
TI LIU THAM KHO
1. Khoa my v thit b ha hc , gio trnh Qu trnh & Thit b truyn khi, H
CNG NGHIP TP.HCM 2011 .
2. Cc tc gi , S tay Qu trnh & Thit b tp 1 , NXB KHKT H Ni 1999
3. Cc tc gi , S tay Qu trnh & Thit b tp 2 , NXB KHKT H Ni 1999
17