UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Ordinary Level

CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

5070/12
May/June 2010 1 hour

*6031804592*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.

This document consists of 16 printed pages.

IB10 06_5070_12/RP UCLES 2010

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2 1 The diagram shows a simple laboratory apparatus for the preparation and collection of a dry gas.

anhydrous calcium chloride

What is the gas? A B C D 2 carbon dioxide chlorine hydrogen hydrogen chloride

What correctly describes the molecules in very dilute sugar solution at room temperature? sugar molecules A B C D close together, moving at random widely separated, moving at random widely separated, moving at random widely separated, not moving water molecules close together, moving at random close together, moving at random close together, not moving widely separated, moving at random

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3 3 A mixture containing equal volumes of two liquids that mix completely but do not react together is placed in the apparatus shown and heated until the thermometer first shows a steady reading. At which position will there be the highest proportion of the liquid with the higher boiling point?

thermometer

water out

B A cold water in

heat

Which is an anion that is present in the solution formed when an excess of dilute hydrochloric acid is added to calcium carbonate? A Ca2+ B Cl C
2 CO 3

H+

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4 5 Which graph shows the number of electrons in the outer shell of an atom, plotted against the proton (atomic) number for the first ten elements in the Periodic Table?

A 10 8 number of 6 electrons in outer shell 4 2 0 0 2 4 6 8 10 proton number 10 8 number of 6 electrons in outer shell 4 2 0 0

2 4 6 8 10 proton number

C 10 8 number of 6 electrons in outer shell 4 2 0 0 2 4 6 8 10 proton number 10 8 number of 6 electrons in outer shell 4 2 0 0

2 4 6 8 10 proton number

A metal consists of a lattice of positive ions in a sea of electrons. What changes, if any, take place to the electrons and positive ions in a metal wire when an electric current is passed through it? electrons A B C D replaced by new electrons replaced by new electrons unchanged unchanged positive ions replaced by new ions unchanged replaced by new ions unchanged

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5 7 Which pair of elements, when combined together, do not form a covalent compound? A B C D 8 caesium and fluorine nitrogen and chlorine phosphorus and fluorine sulfur and chlorine

The diagram shows the structure of a covalent compound containing the element hydrogen, H, and the unknown elements X, Y and Z.
H H X H X Y Z H Y H

To which groups of the Periodic Table do these three elements, X, Y and Z, belong? X A B C D 1 4 4 5 Y 5 5 6 1 Z 6 1 5 4

Two different hydrocarbons each contain the same percentage by mass of hydrogen. It follows that they have the same A B C D empirical formula. number of isomers. relative molecular mass. structural formula.

10 What is the mass of one mole of carbon-12? A 0.012 g B 0.024 g C 1g D 12 g

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6 11 The diagram shows the electrolysis of a concentrated aqueous solution containing both copper(II) ions and sodium ions.

solution
Which metal is deposited at the negative electrode and why? metal deposited A B C D copper copper sodium sodium reason copper is less reactive than sodium copper is more reactive than hydrogen copper is less reactive than hydrogen copper is more reactive than sodium

12 The diagram shows the apparatus used to electrolyse lead(II) bromide using inert electrodes.

lamp

lead(II) bromide

Why does the lamp light up only when the lead(II) bromide is melted? A B C D Bromine atoms in the lead(II) bromide are converted to ions when it is melted. Electrons flow through the lead(II) bromide when it is melted. The ions in lead(II) bromide are free to move only when the solid is melted. There are no ions in solid lead(II) bromide.

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7 13 When a solution containing silver ions is added to a solution containing iron(II) ions, an equilibrium is set up. Ag+(aq) + Fe2+(aq) Ag(s) + Fe3+(aq)

The addition of which substance would not affect the amount of silver precipitated? A Ag+(aq) B Fe2+(aq) C Fe3+(aq) D H2O(l)

14 Which reaction does not involve either oxidation or reduction? A B C D CH4(g) + 2O2(g) CO2(g) + 2H2O(g) Cu2+(aq) + Zn(s) Cu(s) + Zn2+(aq) CuO(s) + H2SO4(aq) CuSO4(aq) + H2O(l) Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g)

15 A student performs two reactions. reaction 1 reaction 2 10 g of magnesium ribbon with excess 2.0 mol / dm3 dilute hydrochloric acid 5 g of magnesium powder with excess 2.0 mol / dm3 dilute hydrochloric acid

In both experiments, the volume of hydrogen produced, V, is measured against time, t, and the results plotted graphically. Which set of graphs is correct?
A V
reaction 2 reaction 1

B V
reaction 1 reaction 2

0 0 t

0 0 t

C V
reaction 1

D V
reaction 1 reaction 2

reaction 2

0 0 t

0 0 t

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8 16 Which statement about catalysts is correct for a typical equilibrium reaction? A B C D A catalyst can be either an inorganic or an organic species. A catalyst does not take part in the reaction. A catalyst only speeds up the forward reaction. A catalyst provides the energy required to start a reaction.

17 Which pair of compounds could be used in the preparation of calcium sulfate? A B C D calcium carbonate and sodium sulfate calcium chloride and ammonium sulfate calcium hydroxide and barium sulfate calcium nitrate and lead(II) sulfate

18 Titration of an acid against a base is a method often used in the preparation of salts. Which properties of the acid, the base and the salt are required if this method is to be used? acid A B C D insoluble soluble soluble soluble base insoluble insoluble soluble soluble salt insoluble insoluble insoluble soluble

19 A metal reacts with dilute hydrochloric acid to produce a gas. What is used to identify this gas? A B C D a glowing splint a lighted splint damp blue litmus paper limewater

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9 20 The oxide of an element X increases the rate of decomposition of hydrogen peroxide. At the end of the reaction the oxide of X is unchanged. Which details are those of X? proton number A B C D 18 20 25 82 mass number 40 40 55 207

21 Which element is sodium? melting point in C A B C D 1535 1083 113 98 electrical conduction good good poor good density in g / cm3 7.86 8.92 2.07 0.97

22 Which row shows the correct number of protons and electrons in the ion of an element in Group II of the Periodic Table? number of protons A B C D 9 12 14 16 number of electrons 10 10 14 18

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10 23 The diagram shows part of the Periodic Table.

P Q T R S

Which pair of letters represents elements that are in the same period? A P and R B P and S C Q and T D R and S

24 From your knowledge of the manufacture of both aluminium and iron, what is the order of chemical reactivity of aluminium, carbon and iron towards oxygen? most reactive A B C D aluminium aluminium carbon carbon carbon iron aluminium iron least reactive iron carbon iron aluminium

25 An alloy of copper and zinc is added to an excess of dilute hydrochloric acid. Which observations are correct? residue A B C D grey none none red-brown filtrate blue solution blue solution colourless solution colourless solution

26 In the extraction of iron, carbon monoxide acts as A B C D a catalyst. an inert gas. an oxidising agent. a reducing agent.

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11 27 Which substances react together to give hydrogen? A B C D calcium oxide and water copper and dilute sulfuric acid copper and steam magnesium and steam

28 The diagram shows apparatus for measuring the volume of hydrogen given off when an excess of dilute hydrochloric acid is added to powdered metal. The volume of gas is measured at room temperature and pressure.

dilute hydrochloric acid tap

graduated tube

water metallic powder

The experiment is carried out three times, using the same mass of powder each time but with different powders: pure magnesium pure zinc a mixture of magnesium and zinc

Which powder gives the greatest volume of hydrogen and which the least volume? greatest volume of H2 A B C D magnesium magnesium zinc zinc least volume of H2 zinc the mixture magnesium the mixture

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12 29 Which gas burns in air to form only one product? A B C D ammonia carbon monoxide hydrogen chloride methane

30 Why is carbon used in the purification of drinking water? A B C D It desalinates the water. It disinfects the water. It filters out solids. It removes tastes and odours from the water.

31 Which compound will not produce ammonia when heated with ammonium sulfate? A B C D calcium oxide magnesium oxide sodium hydroxide sulfuric acid

32 These reactions are used in the manufacture of sulfuric acid. P Q R S + O2 SO2 2SO2 + O2 2SO3

SO3 + H2O H2SO4

Which reactions are speeded up by using a catalyst? A P only B Q only C R only D Q and R

33 Which substances will burn in air and give carbon dioxide amongst the combustion products? 1 2 3 4 A calcium carbonate ethane ethanol methanol B 2 and 3 only C 1, 2 and 3 only D 2, 3 and 4 only

1 and 2 only

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13 34 The two statements are about the fractional distillation of crude oil. The statements may or may not be correct. They may or may not be linked. statement 1 statement 2 Fractional distillation is used to separate crude oil into useful fractions. The fractions with lower boiling points are found at the top of the fractionating column.

What is correct about these two statements? A B C D Both statements are correct and statement 2 explains statement 1. Both statements are correct but statement 2 does not explain statement 1. Statement 1 is correct but statement 2 is incorrect. Statement 1 is incorrect but statement 2 is correct.

35 When butanol, represented by C4HwOH, burns in air, carbon dioxide and water are formed. C4HwOH + xO2 4CO2 + yH2O Which values of w, x and y balance the equation? w A B C D 8 9 9 10 x 6 6 6 7 y 4 4 5 5

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14 36 An aqueous solution of a compound of formula C2H4O2 reacts with sodium carbonate, liberating carbon dioxide. What is the structural formula of the compound?
A H C H O C O H H H H C O B O C H H

C H H C H C O H O

D O H C O H C H H

37 How does the number of carbon, hydrogen and oxygen atoms in an ester differ from the total number of carbon, hydrogen and oxygen atoms in the alcohol and carboxylic acid from which the compound was derived? carbon atoms A B C D less less same same hydrogen atoms less same less same oxygen atoms less less less same

38 The list shows three chemical reactions. 1 2 3 combustion of ethanol fermentation of glucose reaction of ethanol with ethanoic acid to give an ester

In which reactions is water a product? A 1 and 2 only B 1 and 3 only C 2 and 3 only D 1, 2 and 3

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15 39 The diagram shows a reaction scheme.

acidified potassium dichromate(VI)

ethene + steam

catalyst

compound X

compound Y

compound X

compound Z

What is the final compound, Z? A B C D a carboxylic acid an alcohol an alkene an ester

40 The macromolecules of proteins, fats and carbohydrates can all be broken down into their simple units by a similar process. What is the process called? A B C D esterification hydrolysis oxidation reduction

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 UCLES 2010

DATA SHEET The Periodic Table of the Elements

Group III IV
1

I H
Hydrogen

II

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity.

University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
49 201 204 50 207 51 209 52 53 54

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Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir
79

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).