Anton Paar 620

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Instruction Manual
CarboQC
Lab and At-line Beverage Carbonation Meter
Firmware Version : V2.00D

Instruction Manual
CarboQC
Lab and At-line Beverage Carbonation Meter
Firmware Version: V2.00D

Anton Paar GmbH assumes no liability for technical or printing errors or omissions in this document.
Nor is any liability assumed for damages resulting from information contained in the document.
Anton Paar GmbH reserves the right to perform changes to the content. This also extends to changes
to delivery volumes or any features of delivered parts.
All rights reserved (including translation). This document, or any part of it, may not be reproduced,
changed, copied, or distributed by means of electronic systems in any form (print, photocopy, microfilm
or any other process) without prior written permission by Anton Paar GmbH.
Trademarks, registered trademarks, trade names, etc. may be used in this manual without being marked
as such. They are the property of their respective owner.
Published by Anton Paar
Printed: Anton Paar, Austria
Copyright 2010 Anton Paar GmbH, Graz, Austria
Address: Anton Paar GmbH
Anton-Paar-Str. 20
A-8054 Graz / Austria Europe
Tel: +43 316 257-0
Fax: +43 316 257-257
E-Mail: info@anton-paar.com
Web: www.anton-paar.com
Date: June 15, 2010
Document number: C26IB001EN-A.fm
C26IB001EN-A 5
Contents
1 About the Instruction Manual ......................................................................................................... 7
2 Safety Instructions........................................................................................................................... 8
2.1 General Safety Instructions ..................................................................................................... 8
2.2 Special Safety Instructions for CarboQC in Combination with PFD Filling Device .................. 9
2.3 Warning Signs and Mandatory Signs on the PFD Filling Device........................................... 10
3 About CarboQC and PFD Filling Device...................................................................................... 11
4 Checking the Supplied Parts ........................................................................................................ 12
5 Functional Components................................................................................................................ 14
5.1 Front View.............................................................................................................................. 14
5.2 CarboQC Components .......................................................................................................... 14
5.2.1 Measuring Chamber............................................................................................... 14
5.2.2 Display.................................................................................................................... 15
5.2.3 Keypad ................................................................................................................... 16
5.3 Rear View.............................................................................................................................. 17
5.4 Integrated Battery .................................................................................................................. 17
6 Putting CarboQC into Operation.................................................................................................. 18
6.1 Installing CarboQC ................................................................................................................ 18
6.2 Switching the Instrument on and off ...................................................................................... 21
7 Instrument Settings....................................................................................................................... 23
7.1 Menu Access ......................................................................................................................... 23
7.2 Setting Date and Time........................................................................................................... 23
7.3 Setting the Units .................................................................................................................... 23
8 Measurement.................................................................................................................................. 24
8.1 Preconditions......................................................................................................................... 24
8.2 Preparing CarboQC............................................................................................................... 24
8.3 Transferring the Sample into the Measuring Chamber .......................................................... 25
8.4 Measurement Using the PFD Filling Device.......................................................................... 25
8.4.1 Setting the Correct Flow......................................................................................... 25
8.4.2 Measurement Procedure........................................................................................ 27
8.5 Checking for a Correct Measurement Procedure and Avoiding Errors.................................. 30
9 Checking the System..................................................................................................................... 31
9.1 Influencing Factors ................................................................................................................ 31
9.2 Zero Point Check................................................................................................................... 31
9.3 Check with Carbonated Liquid............................................................................................... 31
9.4 Beginning of the Shift/Day ..................................................................................................... 33
9.5 Entering a Pressure Offset .................................................................................................... 34
10 Cleaning the System...................................................................................................................... 35
10.1 End of the Shift/Day............................................................................................................... 35
10.2 Weekly Maintenance ............................................................................................................. 36
6 C26IB001EN-A
10.3 Cleaning the Filter.................................................................................................................. 37
10.4 Cleaning the Measuring Chamber ......................................................................................... 37
10.4.1 Required Devices................................................................................................... 37
10.4.2 Rinsing ................................................................................................................... 37
10.4.3 Cleaning the Entire Measuring Chamber Volume .................................................. 38
10.5 Cleaning the Instrument Housing and Display....................................................................... 38
11 Menu Operation.............................................................................................................................. 39
11.1 Using the Keys on the Keypad .............................................................................................. 39
11.2 Menu Description and Function............................................................................................. 39
11.2.1 Displaying the Measurement Data ......................................................................... 39
11.2.2 Accessing the Menu............................................................................................... 40
11.2.3 "adjustment" Submenu........................................................................................... 40
11.2.4 "instrument" Submenu............................................................................................ 41
11.2.5 "methods" Submenu............................................................................................... 43
11.2.6 "data memory" Submenu ....................................................................................... 47
11.2.7 "service" Submenu................................................................................................. 48
12 Technical Background................................................................................................................... 49
13 CarboQC Methods ......................................................................................................................... 50
13.1 Available Methods with CarboQC.......................................................................................... 50
13.1.1 Standard Methods .................................................................................................. 50
13.1.2 Customer-Specific Methods ................................................................................... 50
13.2 Establishing Customer-Specific Formulae............................................................................. 50
13.2.1 Converting the CO
2
Result into a Customer-Specific Result.................................. 50
2
Concentration into a Customer-Specific Unit ......................... 52
13.2.3 Using a Customer-Specific Solubility Coefficient.................................................... 52
13.3 Transformation of the Determined Air Content ...................................................................... 53
13.4 Calculation of the Package Pressure at a Reference Temperature....................................... 54
Appendix A: Technical Data ........................................................................................................... 56
A.1 CarboQC............................................................................................................. 56
A.2 PFD Filling Device............................................................................................... 57
Appendix B: Wetted Parts............................................................................................................... 58
Appendix C: Measuring At-line ...................................................................................................... 59
C.1 Connecting CarboQC to the Production Line or Tank ......................................... 59
C.2 Measurement ...................................................................................................... 61
C.3 Cleaning the Measuring Chamber....................................................................... 61
Appendix D: Interface Commands for Communication between a PC and CarboQC .............. 63
Appendix E: Error Messages ......................................................................................................... 64
Appendix F: Troubleshooting ........................................................................................................ 65
Appendix G: Firmware Versions .................................................................................................... 66
Appendix H: Declaration of Conformity ........................................................................................ 67
Appendix I: Menu Tree................................................................................................................... 68
Index..................................................................................................................................................... 69
1 About the Instruction Manual
C26IB001EN-A 7
1 About the Instruction Manual
This instruction manual informs you about the installation and the safe handling
and use of the product. Pay special attention to the safety instructions and
warnings in the manual and on the product.
The instruction manual is a part of the product. Keep this instruction manual for
the complete working life of the product and make sure it is easily accessible to
all people involved with the product. If you receive any additions or revisions to
this instruction manual from Anton Paar GmbH, these must be treated as part of
the instruction manual.
Conventions for safety messages
The following conventions for safety messages are used in this instruction
manual:
NOTICE Notice indicates a situation which, if not avoided, could result in damage to
property.
TIP Tip gives extra information about the situation at hand.
Typographical conventions
The following typographical conventions are used in this instruction manual:
DANGER
Danger indicates a hazardous situation which, if not avoided, will result in
death or serious injury.
WARNING
Warning indicates a hazardous situation which, if not avoided, could result in
death or serious injury.
CAUTION
Caution indicates a hazardous situation which, if not avoided, could result in
minor or moderate injury.
Convention Description
<key> The names of keys and buttons are
written inside angle brackets.
"Menu Level 1 > Menu Level 2" Menu paths are written in bold, inside
straight quotation marks. The menu
levels are connected using a closing
angle bracket.
2 Safety Instructions
8 C26IB001EN-A
2.1 General Safety Instructions
Read this instruction manual before using CarboQC.
Follow all hints and instructions contained in this instruction manual to
ensure the correct use and safe functioning of CarboQC.
Liability
This instruction manual does not claim to address all safety issues
associated with the use of the instrument and samples. It is your
responsibility to establish health and safety practices and determine the
applicability of regulatory limitations.
Anton Paar GmbH only warrants the proper functioning of CarboQC if no
adjustments have been made to the mechanics, electronics, and firmware.
Only use CarboQC for the purpose described in this instruction manual.
Anton Paar GmbH is not liable for damages caused by incorrect use of
CarboQC.
Installation and Use
CarboQC is not an explosion-proof instrument and therefore must not be
operated in areas with risk of explosion.
The installation procedure shall only be carried out by authorized personnel
who are familiar with the installation instructions.
Do not use any accessories or wearing parts other than those supplied or
approved by Anton Paar GmbH.
Make sure all operators are trained to use the instrument safely and correctly
before starting any applicable operations.
In case of damage or malfunction, do not continue operating CarboQC. Do
not operate the instrument under conditions which could result in damage to
goods and/or injuries and loss of life.
Check CarboQC for chemical resistance to the samples and cleaning
agents.
Neither CarboQC nor, if applicable, the PFD Filling Device shall be used for
or filled with acids and alkalis above 5 %w/w, hydrofluoric acid, solvent and
other poisonous liquids.
Do not place CarboQC on a wet or humid bench because humidity entering
the housing could damage the instrument.
C26IB001EN-A 9
Do not place CarboQC and, if applicable, the PFD Filling Device such that
there is a danger of accidentally dropping the equipment or tearing off the
pressurized hoses and fittings. Dropping the equipment increases the risk of
the pressurized container bursting.
Do not expose CarboQC and the PFD Filling Device to direct sunlight for
extended periods of time.
Maintenance and Service
Due to the nature of the measurement, the measuring results not only
depend on the correct use and functioning of the CarboQC and, if applicable,
the PFD Filling Device, but may also be influenced by other factors. We
therefore recommend you have the results checked (e.g. plausibility tested)
by skilled personnel before consequential actions are taken.
Service and repair procedures may only be carried out by authorized
personnel or by Anton Paar GmbH.
Disposal
Dispose of CarboQC and, if applicable, the PFD Filling Device according to
the country-specific legal requirements.
Dispose of samples and cleaning liquids according to the country-specific
legal requirements.
2.2 Special Safety Instructions for CarboQC in
Combination with PFD Filling Device
Do not supply compressed gas with more than 6.5 bar (95 psi) pressure to
the PFD Filling Device.
Use only clean and oil-free compressed air ("instrument air").
In the unlikely event that a bottle or can bursts, immediately push the
activating lever of the PFD Filling Device to the de-energized position. Turn
off the compressed gas supply and then disconnect the PFD Filling Device
from the compressed gas supply. Renew the safety shield and discard the
old one. Damage of the instrument or parts thereof may be the consequence
of a burst container. Therefore, do not continue to use the PFD Filling Device
unless it has been checked by authorized service personnel. Contact your
local Anton Paar representative.
The safety shield of the PFD Filling Device is subject to aging, and has to be
replaced after 5 years at the latest.
10 C26IB001EN-A
2.3 Warning Signs and Mandatory Signs on the PFD
Filling Device
Warning sign on the rear side of the PFD Filling Device
On the front side of the PFD Filling Device
Mandatory signs
WARNING
Bursting bottles/cans may damage the safety shield and chippings may be
hurled through the gap at the rear of the safety shield. Injuries, especially of
eyes and face, and hearing damage possible.
Therefore, place the PFD Filling Device with a distance of 0.5 m (20
inches) with its back to the wall.
The PFD Filling Device has to be placed so nobody can stand between
the PFD Filling Device and the wall.
During installation and operation of the PFD Filling Device, only the
operator, equipped with appropriate protective clothing, may be located
directly in front of the PFD Filling Device. All other personnel has to keep a
distance of at least 3 m to the PFD Filling Device.
If a container bursts, the vicinity might get sprayed with sample. The PFD
Filling Device has to be positioned so that there are no power outlets or
ventilation slots behind the PFD Filling Device.
In case of damage, the safety shield has to be replaced by trained service
personnel.
WARNING
Do not pressurize empty bottles or cans. The safety shield is only
dimensioned for gas volumes resulting from the depth of immersion of the
sample tube.
Do not pressurize glass bottles with a volume higher than 1 L.Otherwise,
the protection through the safety shield is not ensured.
Do not pressurize bottles/cans which show cracks or substantial
scratches. Adhere to specifications of bottle manufacturers.
In the unlikely case of a bottle/can bursting, the safety shield may get
damaged and therefore has to be replaced by a new one. Renew the
safety shield and discard the old one.
Wear safety goggles:
Wear safety goggles when handling the PFD Filling Device.
Wear ear protection:
Wear ear protection when handling the PFD Filling Device.
3 About CarboQC and PFD Filling Device
C26IB001EN-A 11
3 About CarboQC and PFD Filling
Device
CarboQC uses the patented "Multiple Volume Expansion" (MVE) method to
eliminate the influence of dissolved air on the determined carbon dioxide content.
The analysis is based on highly accurate absolute pressure and temperature
measurements.
CarboQC can determine the CO
2
content of sugar based soft drinks, soft drinks
with low sugar concentration, diet drinks, beer, strong beer, sparkling wine and
mineral water.
CarboQC can be used in a laboratory environment as well as at-line. The
instrument is equipped with rechargeable batteries to provide the required power
for a limited period of time.
To perform a measurement, connect the instrument to the PFD Filling Device in
the laboratory or to a production line or tank, select the proper method, and press
the <Start> key. Within approx. 2 minutes the CO
2
concentration is shown on the
display and transferred to the data memory. The measuring result can also be
printed out immediately or later from the data memory.
TIP For detailed information about the PFD Filling Device, see the PFD Filling Device
instruction manual.
4 Checking the Supplied Parts
12 C26IB001EN-A
CarboQC was tested and packed carefully before shipment. However, damage
may occur during transport.
1. Keep the packaging material (box, foam piece, transport protection) for
possible returns and further questions from the transport and insurance
company.
2. Check the delivery for completion by comparing the supplied parts to those
noted in Table 4.1.
3. For checking the supplied parts of the PFD Filling Device, see the PFD
Filling Device instruction manual.
4. If a part is missing, contact your Anton Paar representative.
5. If a part is damaged, contact the transport company and your Anton Paar
representative.
Table 4.1: Supplied parts
Symbol Pcs. Article Description Mat. No.
1 CarboQC 14805
1 Instruction manual
English or
German
16605
16606
1 Power adapter incl. cable 14869
4m Hose 2.5x4 polyurethane
transparent
15272/
1m
1 Filter incl. 1# sieve
1# Sieve D = 8 mm for filter
20054
16118
1 Straight fitting R1/8" 4 mm 15274
C26IB001EN-A 13
1 T-Hose connector 4 mm 17756
1 Wrench 10 3636
Table 4.1: Supplied parts
Symbol Pcs. Article Description Mat. No.
Optional accessories
Mat. No.
Printer RS-232C 64434
Printer interface cable for CarboQC 5-pole incl. Dsub adapter 25pin/
9pin
22434
Power adapter IP76 incl. cable
Splash-proof power supply with European standard power plug
23672
Customer functions upon
request
Fruit pulp filter incl. housing and 10# filter cartridges
10# Filter cartridges for fruit pulp filter
21167
21168
All-purpose filter incl. 1# filter cartridge
1# Filter cartridge for all-purpose filter
25483
25391
Filter with male hose filling nozzle for at-line operation 18829
Carrying strap 16012
Protective boot CarboQC 90079
Carry case for CarboQC, 440 x 250 x 170 mm 23888
5 Functional Components
14 C26IB001EN-A
5.1 Front View
Fig. 5 - 1 Front view
1 ... Flow valve
2 ... Sample outlet
3 ... Sample inlet
4 ... Lugs for carrying strap
5 ... Keypad
6 ... Display
7 ... Measuring chamber
5.2 CarboQC Components
5.2.1 Measuring Chamber
Fig. 5 - 2 Measuring chamber
1
2
3
4
5
6
7
Flow valve
Sample outlet
Sample inlet
Piston
to adjust the sample flow
with integrated stirrer
C26IB001EN-A 15
5.2.2 Display
Fig. 5 - 3 Alphanumerical LCD display (4 lines, 16 characters)
1 ... Activated method
2 ... Battery status symbol
3 ... Sample number
4 ... CO
2
concentration
5 ... Air content
6 ... Package pressure (pt) or measuring temperature (tm)
The 4
th
line either displays the measuring temperature or the package pressure.
The package pressure is calculated from the determined concentration of CO
2
and other dissolved gases.
To switch the display from package pressure to measuring temperature, press the
<Menu> key (see Fig. 5 - 4) for approx. 5 seconds.
Battery status symbol
/
(blinking)
The battery is being charged.
The battery is fully charged and the power adapter is connected.
The battery is fully charged and the power adapter is not
connected.
The battery is charged approx. 66 %.
The battery is charged approx. 33 %.
(blinking)
The battery is empty. The battery has to be charged again by
connecting CarboQC to the mains via the power adapter.
1 2 3
4
5
6
16 C26IB001EN-A
5.2.3 Keypad
Fig. 5 - 4 Keypad
In the measuring mode the functions <Sample>, <Menu>, <Print>, <Method>,
<Rinse>, <Start> and <Stop> are active.
In the menu mode the functions <ESC>, <t>, and <Enter> are active.
Key functions in the measuring mode
Special key functions activated with a long push (approx. 5 sec.)
Menu/t To access the menu.
Method/Enter To select one of 7 predefined or one of 17 customer-
specific methods.
Print/u To start a printout of the actual measuring result.
Rinse To rinse the measuring chamber. Further short pushes
activate/deactivate the integrated stirrer.
Sample/ESC For entering a sample number. This number will be
increased each time you press <Start>.
Start To start a measurement.
Stop To stop a measurement, rinsing or cleaning procedure.
Menu Switches between measuring temperature and package
pressure.
Print To print out all measuring results stored in the data memory of
CarboQC.
Rinse To rinse the measuring chamber according to the settings in the
menu "instrument > rinse".
Start To clean the measuring chamber at its maximum volume
expansion.
Stop Alternative possibility to start a measurement.
C26IB001EN-A 17
5.3 Rear View
Fig. 5 - 5 Rear view
1 ... Handle
2 ... COM1 interface for PC or printer
3 ... Type plate with serial number
4 ... On/off switch
5 ... COM2 interface for printer or data transfer to a PC with AP-SoftPrint
6 ... Cover
7 ... Supply inlet
5.4 Integrated Battery
CarboQC has an integrated rechargeable battery. Up to 200 measurements can
be performed with a completely charged battery.
TIP To extend the lifetime of the internal battery, perform a battery service procedure
once every 3 months (see Chapter 11.2.4).
A battery service can be performed on-site.
To perform this service, select the menu "instrument > battery" and set
"service" to "on".
The battery service will take a few hours and is best performed overnight. It
switches itself off upon completion.
If the battery has to be exchanged by an authorized service technician, make sure
that the battery service is performed, even if the newly installed battery is fully
charged.
1
2
3
4
5
6
7
6 Putting CarboQC into Operation
18 C26IB001EN-A
6.1 Installing CarboQC
CarboQC can be used in the laboratory as well as at-line. In any case, sample
has to be transferred into the measuring chamber of CarboQC without the loss of
carbon dioxide during the transfer. Subsequently, the installation of CarboQC in
combination with a PFD Filling Device is described.
The PFD Filling Device pierces the bottle closure or the base of the can and
forces the beverage into the measuring chamber of CarboQC using compressed
gas (60.5 bar relative/877 psi). In the unlikely event that a bottle or can bursts,
the operator is protected by a safety shield which is moved vertically over a bottle
or can. A safety pin on the bottom of the safety shield ensures that the system
cannot be pressurized as long as the safety shield is not in the protective position.
NOTICE Do not operate CarboQC without the filter being installed (see Fig. 6 - 1).
Do not place CarboQC on a wet or humid bench because humidity entering
the housing could damage the instrument.
TIP If required, fasten the PFD Filling Device to the bench with clamps using the
opening in the front of the base plate or with a bolt through the corresponding hole
in the base plate.
WARNING
If a container bursts, chippings may be hurled through the gap on the back
of the PFD Filling Device. Therefore place the PFD Filling Device with a
distance of 0.5 m (20 inches) with its back to the wall. The PFD Filling
Device has to be placed so nobody can stand between the PFD Filling
Device and the wall.
WARNING
Compressed gas is used. Loose hoses may lead to injuries, especially of eyes
and face.
If CarboQC is operated in combination with a PFD Filling Device, do not
activate the compressed gas supply before all hoses are properly
connected.
C26IB001EN-A 19
Compressed gas supply
CarboQC and PFD Filling Device are best operated with compressed air. In case
a dissolved oxygen meter is also connected, use compressed nitrogen as
compressed air might influence the oxygen result.
If there is no in-house supply of compressed gas available, the PFD Filling Device
can also be operated with compressed gas from a gas cylinder.
The hoses of the PFD Filling Device have an outer diameter of 6 mm. If the
compressed gas outlet does not match the required diameter for PFD Filling
Device operation, check for pressure adapters at your local supplier.
Mounting the hoses
For the hose connections between CarboQC and PFD Filling Device, use the
delivered polyurethane hose 2.5 x 4 mm.
NOTICE Keep the hoses between the instruments as short as possible. This reduces
sample consumption as well as the risk of CO
2
diffusing through the hoses thus
influencing the results.
To connect a hose
To connect a hose to a fitting, push the hose into the fitting as far as it will go.
TIP When reconnecting a hose, cut off a few millimeters of the hose if the color of the
hose is changed to achieve tight seal.
To disconnect a hose
To remove the connection, press the ring of the fitting towards the fitting and
then pull out the hose.
NOTICE Only take apart connections if it is really necessary to do so as frequent handling
may destroy the fitting.
20 C26IB001EN-A
Fig. 6 - 1 CarboQC and PFD Filling Device
1 ... PFD Filling Device sample tube outlet
2 ... Connection to compressed gas supply
2a PFD Filling Device outlet for compressed gas
2b PFD Filling Device inlet for compressed gas
3 ... Hose coming from the PFD Filling Device sample tube outlet
4 ... Filter
5 ... CarboQC sample inlet
6 ... CarboQC sample outlet
7 ... Hose with T-hose connector to be led to the waste vessel
**) according to your requirements
2
4
5
7
1
1
2a 2b 3
6
Hose
Inner
diameter
Outer
diameter
Connects
Recommended
length
Nylon hose
4.0 mm
(0.16")
6.0 mm
(0.24")
PFD Filling Device compressed
gas inlet with compressed gas
supply
**)
PFD Filling Device compressed
gas outlet with T-hose connector
to be led into the waste vessel
**)
Polyurethane hose,
transparent
2.5 mm
(0.1")
4.0 mm
(0.16")
PFD Filling Device sample tube
outlet with filter inlet
1000 mm (40")
Filter outlet with
CarboQC sample inlet
100 mm (4")
CarboQC sample outlet with
T-hose connector to be led into
the waste vessel
**)
C26IB001EN-A 21
To connect the PFD Filling Device to the compressed gas supply
1. Connect the compressed gas supply to the inlet (2b) of the PFD Filling
Device with a nylon hose 4x6 mm of the required length.
2. Connect another nylon hose 4x6 mm to the exhaust (2a) of the PFD Filling
Device.
3. Connect the other end to a T-hose connector 6 mm (supplied with the PFD
Filling Device) and lead the hose into the waste vessel (omission to connect
the T-hose connector will cause the hose to jump when releasing the
pressure from the PFD Filling Device).
To connect the PFD Filling Device with CarboQC
1. Connect a polyurethane hose 2.5 x 4 mm of approx. 1000 mm (40") length to
the sample tube outlet (1) of the PFD Filling Device and to the inlet of the
filter (4).
Mount the filter in the correct flow direction (indicated on the filter with an
arrow).
2. Connect a polyurethane hose 2.5 x 4 mm of approx. 100 mm (4") length to
the outlet of the filter and the sample inlet (5) of CarboQC.
3. Connect a polyurethane hose 2.5 x 4 mm to the sample outlet (6) of
CarboQC.
4. Connect the T-hose connector 4 mm (supplied with CarboQC) to the other
end (7) and put it into the waste vessel.
5. When all hoses are connected properly, activate the compressed gas supply.
6.2 Switching the Instrument on and off
NOTICE Before connecting the power adapter to the mains and switching the instrument
on, make sure that the correct line voltage is available (AC 100 to 240 V, 50 to 60
Hz). If large voltage fluctuations are to be expected, we recommend using a
constant voltage source (UPS).
WARNING
Serious injuries are possible due to high voltage at parts of the instrument/
measuring system unless the following instructions are followed:
Make sure that the non-fused earth conductor of the power cord is
connected to earth.
For proper insulation to the mains only use the original power adapter
which is supplied with the instrument.
The power adapter is not suitable for operation under wet at-line or
outdoor conditions! Do not connect the power adapter of CarboQC to the
mains under wet ambient conditions.
22 C26IB001EN-A
1. Connect the power adapter to the supply inlet of CarboQC and the mains.
NOTICE When connecting the plugs to CarboQC, tighten them with your fingers solely! Do
not use any tools for tightening!
TIP When operating under laboratory conditions, the power adapter can be
permanently connected to CarboQC.
Fig. 6 - 2 Supply inlet and on/off switch
2. To switch CarboQC on, use the on/off switch.
3. If the display does not immediately light up, press the on/off switch for 10
seconds.
4. To switch CarboQC off, use the on/off switch.
If CarboQC is operated from the battery, it switches off automatically after 10
minutes if not used.
Power supply
inlet
To the
mains
Power adapter
On/off switch
7 Instrument Settings
C26IB001EN-A 23
7 Instrument Settings
7.1 Menu Access
A password has to be entered to access the menu. The default password is
"0000".
1. Press <Menu>, , select "menu-access" and press <Enter>.
2. To enter the password, enter the characters individually using the <t> and
 keys, and confirm each setting with <Enter>.
3. After finishing all the required entries or changes in the menu, exit the menu
mode by pressing <ESC> up to 3 times.
7.2 Setting Date and Time
1. Set date and time in the menu "instrument > date & time".
2. Select the formats "mmddyy" or "ddmmyy" for the date and "24h" or "am/
pm" for the time.
7.3 Setting the Units
Different units for the temperature (C or F), pressure (bar or psia =
"absolute psi"), and CO
2
(g/L or another unit) can be selected in the menu
"instrument > unit".
8 Measurement
24 C26IB001EN-A
8 Measurement
8.1 Preconditions
CarboQC determines the amount of dissolved carbon dioxide in a beverage. To
get a correct measurement, the instrument has to be in good working condition
(see Chapter 9.2).
In addition, the sample package has to be in equilibrium. As carbon dioxide in a
package can be found in the liquid phase as well as in the head space,
equilibration is essential for repeatable and well defined measurement results.
Equilibration can be achieved by gently shaking the bottle horizontally about 15
times back and forth. This will ensure that the net transfer of CO
2
between liquid
and head space is zero, in short, in equilibrium.
8.2 Preparing CarboQC
CarboQC is equipped with 7 standard methods to account for the different
solubility of carbon dioxide in different beverages (see Chapter 13.1.1). The
selected method is displayed in the top left corner of the display and has to be
selected manually prior to a measurement by pressing the <Method> key,
selecting the desired method and confirming with <Enter>.
If necessary, press <Method> on CarboQC to select the appropriate method for
the sample to be measured from 7 standard methods or 17 customer-specific
methods. For customer-specific methods, see also Chapter 13.
The 7 standard methods are:
The standard methods do not compensate for any temperature effect that
influences the CO
2
distribution between headspace and liquid of the bottles or
cans. Therefore, they should only be applied within a small range (e.g. 3 C/5 F
around reference temperature) of package temperatures.
Method Sample Concentration range
00 MINERAL Mineral water
02 DIET Diet drinks 0-3 Brix
04 BEER Beer 10-14 Plato
06 ST.BEER Strong beer >14 Plato
08 COLA Sugar-based soft drinks 8-12 Brix
10 SPARKL. Sparkling wine 9-13% vol. alc.
12 MID Sugar-based soft drinks 3-8 Brix
8 Measurement
C26IB001EN-A 25
Compensation of the headspace-related temperature effect and therefore
measurements in a wider range of package temperatures can be achieved with
the 17 customer-specific methods once they are properly set up. For more
information, see Chapter 11.2.5.
8.3 Transferring the Sample into the Measuring
Chamber
Sample transfer always carries the risk of loss of carbon dioxide or introduction of
other dissolved gases. Thus, sample transfer is best performed in combination
with a filling system that avoids these risks.
The PFD Filling Device is equipped with a seal to close off a small area of the
package, bottle or can. This small area is pierced with a knife to allow introduction
of a sample tube.
Applying pressurized gas to the head space of the container allows the transfer
of sample to the CarboQC measuring chamber without the loss of CO
2
.
Subsequently, the measurement of CO
2
with CarboQC in combination with a PFD
Filling Device is described in detail.
TIP Piercing the package with a PFD Filling Device might result in the pierced disk
falling into the container. The filter between PFD Filling Device and CarboQC will
keep this particle from entering the measuring chamber.
8.4 Measurement Using the PFD Filling Device
8.4.1 Setting the Correct Flow
The flow through the measuring chamber should be such that 100 to 150 mL of
sample are consumed when the filling time is set to 20 seconds. Considerably
lower or higher flow rates may cause erroneous measurements due to sample
carry-over or gas bubbles in the measuring chamber.
Fig. 8 - 1 Measuring chamber and flow valve
Flow valve
8 Measurement
26 C26IB001EN-A
To adjust the flow, insert a suitable tool (e.g. screwdriver, ... ) into the cavity of the
flow valve and turn it clockwise for decreased and counterclockwise for increased
sample flow.
With a graduated vessel
1. Use a beaker or graduated cylinder to check the correct flow.
2. Insert the T-hose connector of the sample outlet hose into the beaker.
3. Select the menu "instrument > rinse" and set the rinsing time to 20
seconds.
4. Position the flow valve (see Fig. 8 - 1) at about 10% flow, i.e. close to the
minimum flow position.
5. Carry out a measurement as described in Chapter 8.4.2.
6. Check the volume of liquid consumed: It should be 100 to 150 mL.
7. If the volume is not in the required range, slightly open or close the flow valve
(see Fig. 8 - 1) and repeat steps 5 to 7 until the volume/weight is within the
required range.
With a marked bottle
1. Make volume markings "0" and "150 mL" on a transparent 0.5 L (16 oz) or
similar size PET bottle.
Use water and a graduated cylinder or a balance to correctly place these
markings on the bottle.
2. Fill the bottle up to the "0" mark with deionized water and close it.
3. Insert it into the PFD Filling Device.
4. Perform steps 3 to 7 as described above.
Via weighing
1. Weigh a full beverage bottle or can and make a note of the weight.
2. Insert the package into the PFD Filling Device.
3. Perform steps 3 to 5 as described above.
4. Remove the package from the PFD Filling Device and weigh it again.
The weight should have decreased by 100 to 150 g.
8 Measurement
C26IB001EN-A 27
8.4.2 Measurement Procedure
NOTICE Make sure that the bottles/cans are in equilibrium prior to putting them into the
PFD Filling Device. Equilibrium is e.g. achieved by shaking the bottle/can 15
times horizontally.
At CarboQC
1. Check the sample flow and adjust, if necessary (see Chapter 8.4.1).
2. Select the required method on CarboQC.
3. Select the sample number, if necessary.
At the PFD Filling Device
1. Move the sample tube of the PFD Filling Device to the highest position (see
the PFD Filling Device instruction manual).
2. Push the safety shield upwards completely.
3. Insert/remove the PET bottle adapter, if required.
4. Adjust the position of the piercing head, if required.
5. Make sure that the bottle/can is equilibrated (see Chapter 8.1).
6. Insert the PET bottle/can/glass bottle.
7. Push the safety shield down until the safety pin engages.
8. Hold the safety shield down and pull the activating lever to pierce the
package.
9. Lower the sample tube of the PFD Filling Device into the package.
10. If the sample tube touches the bottom of the package, lift it slightly.
11. Fasten the sample tube.
At CarboQC
1. Press <Start> to start the measurement.
Wear safety goggles:
Wear safety goggles when handling the PFD Filling Device.
Wear ear protection:
Wear ear protection when handling the PFD Filling Device.
8 Measurement
28 C26IB001EN-A
The measuring chamber is first rinsed and filled with 100 to 150 mL of the
new sample.
2. Check the measuring chamber visually for bubble-free sample flow.
It must be free of bubbles before the actual analysis starts. If the bubbles do
not disappear after approx. 15 seconds, clean the filter (see Chapter 10.3).
3. Check the pressure of the compressed gas supply. It shall be 60.5 bar
relative (877 psi).
Once the rinsing is finished, the analysis will start. The piston will move down
to a first halt and then to a second halt with the stirrer permanently in
operation.
NOTICE If the sample has a high content of particles (e.g. pulp), the sieve of the filter tends
to clog. This will lower the pressure in the measuring chamber. Check the
pressure indicated at CarboQC during sample filling. When using a PFD Filling
Device, the pressure should not go below 5 bar/70 psia. If the sieve is completely
clogged, bubbles and foam form in the hose between filter and measuring
chamber and in the measuring chamber itself. Clean the filter as described in
Chapter 10.3.
4. Wait approx. 90 seconds for the measurement result.
The measurement result will be displayed, stored in the memory and
optionally printed out. The piston will then move up, but the measuring
chamber will remain closed.
TIP If a measurement was carried out with an incorrect method, the current result can
be recalculated using the correct method as long as this result is still displayed.
Press <Method>, select the correct method and press <Enter>. The recalculated
result will be shown on the display. To store and optionally print out this
recalculated result, press <Print>.
At the PFD Filling Device
1. Move the sample tube up to the highest position and fasten it.
2. Push the activating lever to de-energize the system.
3. Move the safety shield up to the highest position and remove the package.
4. If the package sticks to the piercer, rotate it counterclockwise and pull it down
simultaneously.
5. Optionally, check with a balance whether the correct amount of sample was
taken from the bottle or can.
Now CarboQC and the PFD Filling Device are ready for the next
measurement.
6. If no further measurements are performed, clean the system (see Chapter
10).
8 Measurement
C26IB001EN-A 29
NOTICE If the instrument is not in use for more than 30 minutes after the last sample
measurement, rinse the instrument with deionized water.
Measurement Procedure
Equilibrate the package.
Check the sample flow.
Select the required method on CarboQC and the sample number, if
necessary.
Move the sample tube to the highest position.
Push the safety shield upwards completely.
Insert/remove the PET bottle adapter, if required.
Adjust the position of the piercing head, if required.
Insert the PET bottle/can/glass bottle.
Push the safety shield down until the safety pin engages. Hold it down.
Pull the activating lever.
Lower the sample tube into the package.
Press <Start> on CarboQC.
Wait approx. 90 seconds for the measurement result and optional printout.
Move the sample tube up and push back the activating lever.
Move the safety shield up and remove the package.
Perform the next measurement or clean the system.
8 Measurement
30 C26IB001EN-A
8.5 Checking for a Correct Measurement Procedure
and Avoiding Errors
Zero point checks
Regular zero point checks of CarboQC with deionized water are recommended
to survey faultless functionality of the instrument. The water check with CarboQC,
when carried out correctly with deionized water, is the precondition for a correct
measurement result. The result has to be 0 0.02 vol (0 0.03 g/L).
If the zero point check and adjustment are carried out with water that contains
CO
2
, the consequence will be an unjustified offset. Consequences are systematic
errors of results.
Sample equilibration
Only transfer equilibrated sample to the measuring chamber of CarboQC. If
samples are not equilibrated (shaken) prior to analysis, the consequence might
be erroneous results or poor repeatabilities.
Correct measurement method
Check whether the correct measuring method is chosen on CarboQC. A wrong
method will lead to a wrong result.
Correct sample flow
Check the correct flow. The volume consumption per measurement is
recommended to be 120 to 150 mL, and for identical samples at least 100 mL.
Too low sample volume consumption causes sample carry-over.
Correct filling pressure
The filling pressure displayed on the CarboQC display has to be 5.5 to 6 bar
relative (79 psi to 87 psi) and the measuring chamber has to be filled without
bubbles. Too low sample pressures during sample filling causes bubbles in the
sample chamber. As a consequence, the starting volume will consists partially of
gas bubbles thus yielding incorrect results.
Measuring chamber filled without bubbles
Bubbles in the measuring chamber can falsify the result. The most common
cause for bubbles is a clogged filter. To clean the filter, see Chapter 10.3.
9 Checking the System
C26IB001EN-A 31
9.1 Influencing Factors
Mechanical functionality of CarboQC is essential for a correct result. CarboQC
has three parameters that act as a precondition for a correct result.
pressure
temperature
volume expansion of the measuring chamber
9.2 Zero Point Check
A zero point check is necessary before starting the determinations. The zero point
check is a measurement with deionized (or distilled) water. The CO
2
result has to
be 00.02 vol (00.03 g/L).
The deionized water must not contain any dissolved carbon dioxide and is ideally
free of ions such as calcium that could cause deposits in the measuring chamber
of CarboQC.
Sometimes, deionized water contains CO
2
absorbed from the ambience and
CarboQC displays the amount of the CO
2
absorbed. Either heat up and boil the
water and cover it up while cooling down or do the water check with tap water. In
case of using tap water, rinse the measuring chamber with deionized water
afterwards.
In case the measurement of deionized water does give a CO
2
reading out of
tolerance, always check the water first before inserting a pressure offset (see
Chapter 9.5) into CarboQC.
In general, the zero point check with CO
2
-free water is sufficient to ensure correct
functioning of the instrument in-between service intervals.
9.3 Check with Carbonated Liquid
Sometimes checkups are required with test samples at elevated carbon dioxide
contents. Usually these checkups are provided within the periodical service and
maintenance procedure. In case more frequent tests are required, continuous
surveillance can be performed on a day-to-day basis.
There are two ways to perform an instrument check with carbonated liquids.
The first is the use of a CO
2
standard. This procedure shall only be carried out by
an authorized Anton Paar representative or service technician.
The second is the use of a control chart and internal standards.
32 C26IB001EN-A
NOTICE Only use cans as internal standards. Do not use bottles as their CO
2
content
might change.
Cans of diet soft drink or other cans of a non-sucrose based, non-inverting soft
drink with > 3 vol (6 g/L) CO
2
content are suitable to be used as internal
standards.
If filling cans, provide 36 cans for initial preparation of the standards plus a
sufficient number of cans for one check measurement per day over the time span
between instrument calibrations by Anton Paar service representatives. Only use
cans from the same production minute(s).
If purchasing cans, make sure that the required number of cans is from the same
batch.
To prepare internal standards
1. Immediately after calibration of CarboQC by an Anton Paar service
representative, draw 6 cans from the beginning, 6 cans from the middle, and
6 cans from the end section of a production run and measure them.
2. Calculate the mean values for every 6 measurements for the beginning,
middle and end sections.
The 3 mean values may only differ by 0.02 vol (0.04 g/L).
3. If the mean values are suitable, provide a sufficient number of cans from this
production run to be kept as internal standards.
4. If the mean values are not suitable, measure another 3 times 6 cans as
above.
5. Determine the 3 mean values of the 12 respective measurements (for each
mean value take the 6 measurements from the first selection plus the 6
measurements from the second selection).
These 3 mean values may only differ by 0.015 vol (0.03 g/L).
6. If the mean values are suitable, provide a sufficient number of cans from this
production run to be kept as internal standards.
7. If the mean values are not suitable, the cans are not suitable as internal
standards and cans from a different, more stable production run have to be
used.
To draw and use the control chart
1. Calculate the mean m and standard deviation sd of all 18 (or 36)
measurements.
The standard deviation shall be 0.025 vol (0.05 g/L) maximum based on the
above limitations.
C26IB001EN-A 33
2. Draw a control chart with sample number on the x-axis and CO
2
concentration on the y-axis ranging from (m - 3 * sd) to (m + 3 * sd) as the
control limits.
3. Draw control limit lines, mean line and auxiliary lines as appropriate. This
can either be done on paper or using a suitable computer software.
4. Measure one can of the internal standards per production day and draw a
corresponding point in the control chart.
5. If a clear trend away from the mean becomes visible over time or the control
limit of 3 * sd is exceeded successively, call for service immediately.
9.4 Beginning of the Shift/Day
Check for the correct sample flow with
deionized water. A volume of 100 to 150 mL is
recommended.
NOK Adjust the sample flow.
See Chapter 8.4.1.
OK
Check the zero point: Fill a clean 0.5 L PET
bottle with deionized water, close the bottle and
measure it (see Chapter 8.4.2). The CO
2
result
has to be 00.02 vol (00.03 g/L).
OK
NOK Rinse with glassware cleaner (pH <10) and
then with deionized water.
OK
Check the zero point with deionized water again
(see Chapter 8.4.2). The CO
2
result has to be
00.02 vol (00.03 g/L).
CarboQC is ready for
routine measurements.
OK
NOK
Contact your Anton Paar representative.
34 C26IB001EN-A
9.5 Entering a Pressure Offset
With the menu "auto p-offset", an offset for the pressure sensor can be
determined semiautomatically. Enter a pressure offset if the CO
2
result of a zero
point check with deionized water is out of specification (see Chapter 9.2).
TIP Sometimes, deionized water contains CO
2
which has been absorbed from the air,
and this CO
2
content is displayed. Before carrying out an automatic pressure
offset, make sure that the displayed CO
2
is not caused by the water, but by the
pressure sensor. Boiling and cooling the water before measurement will eliminate
dissolved CO
2
.
Example:
A zero point check with deionized water yields (even after cleaning the system) a
CO
2
value of 0.05 g/L. The maximum allowed deviation for deionized water is 0.03
g/L. Therefore, the pressure sensor must be adjusted:
1. Select the menu "adjustment > auto p-offset".
In the first line, the previously measured CO
2
value (0.05 g/L) is displayed. In
the second line, the pressure value is displayed (e.g. +0.020 bar).
2. Press <Enter>.
The displayed CO
2
value flashes.
3. Change the CO
2
value using the <t> and keys until the value is inside
specification (0 0.03 g/L).
The pressure value is changing corresponding to the CO
2
value.
4. When the required CO
2
value is displayed, press the <Enter> key.
The newly calculated pressure offset is automatically stored in the CarboQC
memory and is used for subsequent measurements.
5. To change to the measuring window, press <ESC> three times.
10 Cleaning the System
C26IB001EN-A 35
10.1 End of the Shift/Day
NOTICE If the instrument is not used for some time (e.g. over the weekend) or if shipping
the instrument, always make sure that the measuring chamber is about half filled
with deionized water to avoid damage of the O-rings.
Rinse the measuring chamber with deionized water.
Rinse with glassware cleaner (pH <10) by pressing <Start> for approx. 5
seconds to clean the entire measuring chamber. Wait 2 minutes for this to
finish and then press <Stop>.
Rinse the measuring chamber with deionized water.
Clean sample residues from the PFD Filling Device and CarboQC with a
wet tissue. Dry with a soft dry tissue. If the PFD Filling Device is very dirty,
spray it with (warm) water, move movable parts up and down in between
spraying and then dry with a soft tissue.
36 C26IB001EN-A
10.2 Weekly Maintenance
Clean the filter (see Chapter 10.3).
Rinse the measuring chamber with warm
deionized water.
Rinse the measuring chamber with glassware
cleaner (pH <10).
Rinse the measuring chamber with deionized
water.
Rinse the measuring chamber with a 60 to 90%
solution of ethanol. Do not use denatured
ethanol!
Rinse the measuring chamber with deionized
water.
Fill deionized water by pressing <Start> for
approx. 5 seconds to clean the entire measuring
chamber. Wait 2 minutes for this to finish.
Check whether gas bubbles enter the measuring
chamber.
Yes Contact your Anton
Paar representative.
No
Press <Stop> and leave deionized water in the
measuring chamber.
Clean sample residues from the PFD Filling
Device and CarboQC with a wet tissue. Dry with
a soft dry tissue. If the PFD Filling Device is very
dirty, spray it with (warm) water, move movable
parts up and down in between spraying and then
dry with a soft tissue.
C26IB001EN-A 37
10.3 Cleaning the Filter
TIP Make sure that the activating lever of the PFD Filling Device is in the "off" position
before disconnecting the filter.
1. Press <Rinse> on CarboQC and wait 20 seconds for the measuring
chamber to open.
2. Disconnect the filter from the hoses and connect it in the reverse direction to
the hose coming from the PFD Filling Device.
3. Put a 0.5 L or similar size PET bottle with deionized water into the PFD
Filling Device (see Chapter 8.4.2).
4. Hold the filter outlet over a sink or waste container and fix it in this position.
5. Pull down the safety shield and pull the activating lever.
Air with sample residues will spray out of the filter.
6. Lower the sample tube to flush the filter with approx. 200 mL of deionized
water.
7. Move the sample tube up to let air flow through the filter for about one
minute.
8. Push the activating lever to the "off" position.
9. Reconnect the filter in the correct flow direction.
10.4 Cleaning the Measuring Chamber
10.4.1 Required Devices
To clean the measuring chamber of CarboQC, fill a 0.5 L or similar size PET
bottle with deionized water or glassware cleaner (pH <10) which removes
protein.
Insert this bottle into the PFD Filling Device the same way as a sample to be
measured.
10.4.2 Rinsing
1. Press the <Rinse> key for approx. 5 seconds.
The measuring chamber is rinsed for the set rinse time.
2. Always rinse with deionized water after rinsing with glassware cleaner.
38 C26IB001EN-A
3. Leave only deionized water in the measuring chamber for extended periods
of time.
10.4.3 Cleaning the Entire Measuring Chamber Volume
1. Press the <Start> key for approx. 5 sec.
After rinsing, the piston will descend to the maximum measuring chamber
volume expansion with the stirrer turned on. This will clean the entire
chamber volume.
If deionized water is used, the pressure in the measuring chamber will
become very low, far below ambient pressure. Air bubbles will enter the
measuring chamber if it is not completely tight. Therefore, this function can
also be used to detect leaks caused by damaged O-rings or valves.
2. Press <Stop> to exit this mode.
3. Always rinse with deionized water after rinsing with glassware cleaner.
4. Leave only deionized water in the measuring chamber for extended periods
of time.
10.5 Cleaning the Instrument Housing and Display
If sample was spilled onto the housing of CarboQC, always wipe it off
immediately.
To clean the instrument housing and/or the keypad, use a soft tissue and
(warm) water.
Dry with a soft, dry tissue.
11 Menu Operation
C26IB001EN-A 39
11 Menu Operation
11.1 Using the Keys on the Keypad
If the measuring window is displayed, the functions <Sample>, <Menu>, <Print>,
<Method>, <Rinse>, <Start> and <Stop> are active.
In the menu mode (after pressing the <Menu> key) the functions <ESC>, <t>,
 and <Enter> are active.
The key functions in the menu mode accomplish the following tasks:
11.2 Menu Description and Function
11.2.1 Displaying the Measurement Data
The stored measurement data can be displayed. To display the next or previous
data set, press the <t> or key.
Fig. 11 - 1 Displaying the measurement data
ESC Return to the measuring mode
Move to the next higher menu level
Ignore the last entry and return to the next higher menu
level
Ignore the last entry and return to the previous digit or
character
t and u Move to a menu item
Decrease or increase a digit or a character
Enter Select a menu item
Confirm an input or a query
Accept the last entry and return to the next higher menu
level
Accept the last entry and move to the next digit or
character
m e n u
d a t a m e m o r y
m e n u a c c e s s
11 Menu Operation
40 C26IB001EN-A
11.2.2 Accessing the Menu
Press the <Menu> key on CarboQC to initiate the menu access.
Fig. 11 - 2 Main menu (scrolls when arrow is moved down)
For the complete menu tree, see the last pages of this instruction manual.
11.2.3 "adjustment" Submenu
Fig. 11 - 3 Menu/adjustment
menu-access
password A password has to be entered to
access the menu. The default
password is: 0000.
If you use a different password, press
the <Enter> key. Enter the characters
using the <t> and keys, and
confirm each setting with <Enter>.
m e n u
a d j u s t me n t
i n s t r u me n t
m e t h o d s
me n u - a d j u s t me n t
c o mp e n s a t i o n
a u t o p - o f f s e t
compensation
comp air
on To compensate the influence of
dissolved air. CarboQC automatically
performs two volume expansions.
off To deactivate the air compensation.
One volume expansion has to be set.
vexp To set the volume expansion
between 2 and 40%. Default: 10%.
Only valid when comp air is set to off.
11 Menu Operation
C26IB001EN-A 41
11.2.4 "instrument" Submenu
Fig. 11 - 4 Menu/instrument
auto p-offset Offset for the absolute pressure
sensor (values between 0 and 0.5
bar (0 and 7 psi)). For details, see
Chapter 9.5.
C: x.xxx g/L (or respective selected unit)
p: x.xxx bar (psia)
m e n u - i n s t r u m e n t
r i n s e
u n i t
s e r i a l c o m
rinse
time: 03 to 200 seconds for rinsing the
measuring chamber. Default: 20
seconds.
unit To select the units of the displayed
CO
2
content, pressure and
temperature as well as the number of
places after the decimal point.
t To select C or F of the temperature.
p To select bar or psia (=absolute psi)
of pressure.
co2 To select g/L or an arbitrary unit of
CO
2
content.
co2dec To select 2 or 3 places after the
decimal point for the displayed CO
2

result, and 0 or 1 places after the
decimal point for the displayed air
content, respectively.
serial com The settings in this menu are valid for
both the printer and PC interfaces.
baud
1200
2400
4800
9600
19200
11 Menu Operation
42 C26IB001EN-A
format
E71 Even parity, 7 data bits, 1 stop bit
N81 No parity, 8 data bits, 1 stop bit
O71 Odd parity, 7 data bits, 1 stop bit
password
new To define a new password for the
menu access. 4 characters/digits are
available. Default: 0000.
date & time Date and time and the corresponding
formats can be set.
date Two different formats for the date are
available (default: ddmmyy)
ddmmyy Day.month.year, e.g. 13.10.03
mmddyy Month-day-year, e.g. 10-13-03
year To set the current year.
month To set the current month.
day To set the current day.
time Two formats for time are available.
24hrs E.g. 17:08
am/pm E.g. 05:10 pm
hour To set the hour.
min To set the minute.
battery
service
on To perform a battery service
procedure. With the power adapter
connected to the CarboQC supply
inlet and the mains, the battery is
discharged and charged again. This
takes approx. 12 hours.
off Battery service procedure inactive.
device info All the values given under device info
are read only.
print Output of the device info to printer or
PC via the corresponding interface.
off
printer
PC
11 Menu Operation
C26IB001EN-A 43
11.2.5 "methods" Submenu
In this submenu a list of customer adaptable methods is displayed. The names as
specified here are only valid if no changes have been made. Once the method-
specific names have been changed, the changed names will appear in the list.
The corresponding coefficients for these methods will only be explained for the
first method.
The last 10 methods (CM01PROD - CM10PROD) allow to enter a solubility
coefficient ks, too. They can therefore be adapted to customer-specific
beverages which exceed the predefined methods range in Brix, Plato or % alc.
vol. of beverages.
Fig. 11 - 5 Menu/customer
me n u - m e t h o d s
0 1 M I N E R A L c
0 3 D I E T c c c c
0 5 B E E R c c c c
01 MINERALc Customer-specific method for mineral
water.
name To define a customer-specific name for
this method.
sel
man sel The method is available in the method
list.
disable The method is not available in the
method list.
unit An arbitrary unit can be entered (see
Chapter 13.2.2). Factory default: g/L.
fu Division factor which is used to convert
the determined result (in g/L) into a
customer-specific unit, e.g. enter 1.976 to
convert g/L to vol. For calculating
customer-specific polynomials.
k0 Coefficients k0 - k4 convert the CO
2
results based on the built-in solubility
formula to customer-specific results
based on customer-specific tables/
formulae. These parameters are also
used to compensate for the headspace
effect in bottles and cans which causes a
lower amount of dissolved CO
2
at higher
temperatures (see Chapter 13.2.1).
k1
11 Menu Operation
44 C26IB001EN-A
k2
k3
k4
k5 Reference temperature [C].
k6 Coefficients k6 - k7 are used to transform
the air or nitrogen content as determined
into related properties (see Chapter
13.3).
k7
03 DIETcccc Customer-specific method for diet
products (0 to 3Brix).
this method.
sel
list.
method list.
unit For the unit, an arbitrary unit can be
entered (see Chapter 13.2.2). Factory
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
05 BEERcccc Customer-specific method for beer (10 to
14Plato).
this method.
sel
list.
method list.
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
07 ST. BEERc Customer-specific method for strong beer
(>14Plato).
this method.
sel
11 Menu Operation
C26IB001EN-A 45
list.
method list.
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
09 COLAcccc Customer-specific method for sugar
based beverages (8 to 12Brix).
this method.
sel
list.
method list.
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
11 SPARKLcc Customer-specific method for sparkling
wine (9 to 13% vol. alc.).
this method.
sel
list.
method list.
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
13 MIDccccc Customer-specific method for sugar-
based soft drinks (3 to 8 Brix).
11 Menu Operation
46 C26IB001EN-A
this method.
sel
list.
method list.
unit An arbitrary unit with 6 digits maximum
(e.g. mg/cm
3
) can be selected and
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
17 CM01PROD Customer-specific method including
selectable solubility of CO
2
.
this method.
sel
list.
method list.
unit An arbitrary unit with 6 digits maximum
(e.g. mg/cm
3
) can be selected and
default: g/L.
fu See "MINERALc".
k0 See "MINERALc".
....
k7
ks Enter the CO
2
gas absorption coefficient
in g/(L * bar) of CO
2
at 5 bar and 20 C
(e.g. 1.61 g/(L * bar) for a 52 Brix soft
drink).
ka
....
kd
18 CM02PROD See "CM01PROD".
...
26 CM10PROD See "CM01PROD".
11 Menu Operation
C26IB001EN-A 47
11.2.6 "data memory" Submenu
Fig. 11 - 6 Menu/data memory
me n u - d a t a me mo r y
b r o w s e me mo r y
c l e a r me mo r y
browse memory To display the stored measurement
data.
Browse through the memory using
the <t> and keys, starting with
the most recent. To indicate that the
memory browser is activated, the
name of the activated method and
"memory" are alternately displayed in
the upper left corner. A stored
measurement contains the following
information:
Name of the selected method
Sample No.
CO
2
result
Dissolved air
Measuring temperature or
package pressure
99 measurements can be stored. The
latest entry overwrites the oldest
when the memory is full.
clear memory
clear
yes To clear all measuring results in the
memory of CarboQC.
no
11 Menu Operation
48 C26IB001EN-A
11.2.7 "service" Submenu
In this menu, information about the device can be displayed. None of the values
can be changed.
device
SerNo Serial number of the instrument.
FW Firmware version of the instrument.
v-k Slope parameter: counts per 1 %
increase of the volume of the
measuring chamber.
v-I0 Zero volume expansion parameter:
counts at zero volume expansion, i.e.
when measuring chamber valves
close.
v-h Slope parameter for the
determination of the pressure drop at
zero volume expansion for zero
adjustment.
cycle Total number of measurement cycles
performed.
lb0 Solubility parameters for air/nitrogen.
lb1
lb2
ccor Internal correction factor.
t dis Initial or final (internal reference
temperature).
offset
t Offset for the temperature sensor
(values between 0 and 5 C (0 and
9 F)).
p Offset for the absolute pressure
sensor (values between 0 and 0.5
bar (0 and 7 psi)).
gain
t Gain factor for the temperature
sensor (values between 0 and 2).
p Gain factor for the pressure sensor
(values between 0 and 2).
12 Technical Background
C26IB001EN-A 49
12 Technical Background
The working principle of CarboQC is based on the Multiple Volume Expansion
Method and allows the determination of the true CO
2
content.
Fig. 12 - 1 shows the principle of the Multiple Volume Expansion method for
eliminating the influence of dissolved air or nitrogen on the measuring result: The
CO
2
content is measured at two different volume expansions of the measuring
chamber, i.e. at 10 and 30%. If the two results are identical, there is no dissolved
air or nitrogen present and therefore no correction is required. Dissolved air or
nitrogen makes the second result lower than the first. The difference between the
two results is used to calculate a correction which completely eliminates the
influence of dissolved air or nitrogen on the measuring result.
Fig. 12 - 1 Compensation of dissolved air
CO
2
with air
CO
2
without air
13 CarboQC Methods
50 C26IB001EN-A
13 CarboQC Methods
13.1 Available Methods with CarboQC
13.1.1 Standard Methods
The 7 standard methods do not allow to change any parameter at all. It can be
seen from Chapter 8.2 which method is recommended for which beverage
sample. These methods do not provide any means for compensating temperature
effects due to the headspace volume of beverage packages. They are therefore
suitable for determining the true dissolved carbon dioxide content at a given
package temperature.
13.1.2 Customer-Specific Methods
CarboQC provides 17 customer-specific methods. 7 methods, ending with "c",
use solubility coefficients identical to the standard methods, and 10 customer-
specific methods CMxxPROD also allow the entry of the solubility coefficient.
The 7 user-specific methods are named identically to the standard methods with
additional letters "cc" to obtain eight digits altogether (DIETcccc; SPARKLcc and
so on). These 7 methods allow modification of the constants k
0
to k
7
, but these six
methods do not allow access to the solubility coefficient for CO
2
in the respective
sample. The solubility coefficients in these user-specific methods are identical to
the ones in the respective standard methods. The coefficients k
0
to k
7
can be used
to compensate headspace related package temperature effects and to adapt the
measurement results to those based on customer-specific solubility tables or
formulae.
There are also 10 CMxxPROD methods; xx = 01, ..., 10. These 10 customer-
specific methods allow the modification of the constants k
0
to k
7
, but also the
alteration of the solubility coefficient ks of CO
2
in the sample.
13.2 Establishing Customer-Specific Formulae
2
Result into a Customer-Specific
Result
In the customer-specific methods the calculated g/L results can be converted for
user-specific CO
2
tables or formulae. This conversion can also correct the
temperature-dependent changes of the dissolved CO
2
content resulting from the
headspace to liquid volume ratio of the bottles or cans.
13 CarboQC Methods
C26IB001EN-A 51
This equation is used for custom-tailoring a CO
2
result from the original CO
2
content c as determined by CarboQC.
C
cust
is the customer-specific CO
2
result. It is the modified carbon dioxide content
that is calculated and displayed when customer-specific coefficients are used.
k
0
will always be added to the result c. The factory setting of k
0
= 0.
k
1
is a multiplication factor. The factory setting of k
1
= 1.
k
5
is a reference temperature that needs to be keyed in if the result is to be related
to a specific temperature. The factory setting of k
5
is zero, which means that k
5
equals 0 C, regardless of the temperature units selected in the menu.
A simple way of applying a reasonable temperature correction for the headspace
influence is to use the customer-specific methods in CarboQC, rename them
properly and set k
5
equal to the average measuring temperature, and for k
2
a
value of 0.003 (typical range: 0.002 0.004) to get the temperature
compensation to take effect.
k
3
and k
4
can be used for better fine tuning of the final customer-specific result.
The factory setting is 0.
Example:
If the result given by CarboQC is 3 g/L and the desired or expected result is 3.3
g/L, there are two ways CarboQC can be programmed in order to transfer the
CarboQC result into the customer-specific result:
(1) k
0
is set to 0.3
The value c
cust
will be 0.3 g/L higher than the CarboQC result. This will also affect
the zero determination with deionized water. A k
0
of 0.3 will cause an offset as all
results will be 0.3 higher than the determined value: instead of 0 the displayed
result will be 0.3; instead of 2 the displayed result will be 2.3 and so forth.
Therefore setting a positive k
0
offset is a reasonable means to adapt the CarboQC
results to readings of previous methods which were offset by a fairly constant air
content of the samples.
C
cust
.......................... Customer-specific CO
2
result [g/L]
k
0
, k
1
, k
2
, k
3
, k
4
........ Customer-specific coefficients
k
5
............................. Reference temperature [C]
c .............................. Original CO
2
result [g/L]
t ............................... Measured temperature [C]
C
cust
k
0
k
1
*c k
2
*c* t k
5
( ) k
3
*c* t k
5
( )
2
+ + k
4
*c
2
+ + =
13 CarboQC Methods
52 C26IB001EN-A
(2) k
1
is set to 1.1
The CarboQC result will be multiplied by 1.1. Instead of 3 the result will be 3.3 and
instead of 2 the result will be 2.2. If the zero point adjustment works correctly, the
zero reading will be close to zero and multiplication by 1.1 will not affect the zero
reading noticeably. As an example, a factor of approximately 1.1 is often
necessary if the customer-specific solubility table applied is actually a CO
2
solubility table for water, but it is applied to 10 Brix soft drinks.
2
Concentration into a Customer-
Specific Unit
For all customer-specific methods, the measured CO
2
concentration can be
converted from g/L into a customer-specific unit.
Proceed as follows:
1. In the menu "methods", select the desired customer-specific method.
2. Select the menu item "unit" and enter a name for the desired unit (maximum
length of 6 characters).
3. In the menu "methods", change the coefficient "k
1
" so that the desired
conversion is applied. E.g. setting k
1
= 2, results in multiplying the result by 2.
4. Change to the measuring window and select the changed method using the
<Method> key.
The newly set unit is displayed in the line for the CO
2
content. When
measuring, the conversion is carried out according to the entered coefficient
and the calculated result is displayed.
5. The factor "fu" is a division factor which divides a customer-specific
polynomial. E.g. using fu = 1.976 leads to converting the measurement result
from g/L into vol.
13.2.3 Using a Customer-Specific Solubility Coefficient
The 10 CMxxPROD methods allow entry of k
1
to k
7
and, in addition, the solubility
coefficient k
s
in g/(L * bar) at a temperature of 20 C. These 10 methods need to
be used when a sample does not match the ranges as given in Chapter 8.2; e.g.
1.61 g/(L * bar) for a 5 2 Brix soft drink.
13 CarboQC Methods
C26IB001EN-A 53
13.3 Transformation of the Determined Air Content
The following formula serves two purposes:
1. It allows to correct the ppm result with a different slope k
6
.
2. It allows to compensate for the temperature dependent gas distribution in the
beverage container using k
5
, k
7
. The term in brackets is set to 1 if k
7
0.
This formula is used if the "air ppm" result needs to be corrected or the amount of
gas in the head space needs to be taken into consideration. c
trans
is the air content
as a function of head space.
The factory setting for the "slope" k
6
is 1.
c
air
is the air content in ppm as determined by CarboQC.
k
5
is the reference temperature and L
b2
is the solubility of air at the determined
measuring temperature T
2
[K].
L
b
(k
5
) is the solubility of air at the reference temperature k
5
. This value can be
taken from a table.
k
7
is the head space to liquid ratio of the beverage container. If k
7
0 then the
term in brackets equals 1; if k
7
> 0 then the term in brackets is calculated.
C
trans
........... Air content as a function of head space
k
5
............... Reference temperature [C]
k
6
............... Slope
k
7
............... Headspace to liquid ratio of can/bottle
c
air
............. . Air/nitrogen content in ppm as measured
T
2
............... Measuring temperature [K]
L
b2
............. Solubility of air/nitrogen at measuring temperature [-]
L
b
(k
5
) .......... Solubility of air/nitrogen at reference temperature k5 [-]
C
trans
k
6
*c
air
*
k
7
*
273.1
T
2
--------------- L
b2
+
k
7
*
273.1
273.1 k
5
+
--------------------------- L
b
k
5
( ) +
--------------------------------------------------------------- =
13 CarboQC Methods
54 C26IB001EN-A
13.4 Calculation of the Package Pressure at a
Reference Temperature
The 10 CMxxPROD methods CM01PROD to CM10PROD not only allow entry of
coefficients k
0
to k
7
and k
s
, but also of the coefficients k
a
, k
b
, k
c
and k
d
. The
coefficients k
a
, k
b
, k
c
and k
d
can be modified if the package pressure, determined
at sample temperature, needs to be converted into the package pressure at a
reference temperature.
TIP The value for the pressure at a reference temperature p
ref
can be obtained as
relative pressure if the ambient pressure in [bar] is keyed in. If k
d
is zero, the
obtained value of p
ref
will correspond to the absolute pressure.
Example: Calculation of the relative reference pressure of sparkling wine at 20C
(68F)
1. Select the menu "methods".
2. Choose any CMxxPROD method.
3. Re-name the method and give it a significant denotation, e.g. SPARKL20.
4. Leave "fu = 1".
5. Leave "k0" to "k4" and "k6" to "k7" unchanged.
6. Select the reference temperature "k5" and change the entry to "+20.0000".
When setting "k5", always enter the numerical value of C, even if the unit F
is selected.
7. Set "ks = 1.51" (k
s
for SPARKL is 1.51 g/(L*bar)).
p
ref
.............. Package pressure at reference temperature
pt ................ Package pressure as determined by CarboQC
k
a
................ Conversion factor for pressure unit
Factory setting = [bar]. If the unit [bar] is desired, set k
a
= 1.
k
b
, k
c
........... Factor for temperature compensation
Factory setting: +0.00000
Recommendation:
k
b
= -0.028 (negative sign!) and k
c
= 0.00075
k
d
................ Ambient pressure in [bar]. Factory setting: +0.00000
k
5
................ Reference temperature in C
t .................. Sample temperature as determined by CarboQC
p
ref
k
a
pt 1 ( k
b
t ( k
5
) k
c
t ( k
5
)
2
) k
d
+ + [ ] =
13 CarboQC Methods
C26IB001EN-A 55
8. Set "ka" to "kc" as follows:
ka = 1
kb = -0.028
kc = 0.00075
9. Change the preset value of "kd" and enter the average ambient pressure in
[bar].
Then
p
ref, 20
= 1 * {pt
as determined at t
* [1 - 0.028 (t - 20) + 0.00075 * (t - 20)] - 1}
is the relative package pressure had it been measured at 20 C (68 F).
Appendix A: Technical Data
56 C26IB001EN-A
A.1 CarboQC
Measuring range
CO
2
: 0 to 12 g/L (0 to 6 vol.) at 30 C (86 F)
0 to 20 g/L (0 to 10 vol.) < 15 C (59 F)
Temperature: -3 to 30 C (27 to 86 F)
Pressure: 0 to 10 bar relative (0 to 145 psi)
Repeatability, s. d.: 0.01 g/L (0.005 vol.) CO
2
Reproducibility, s. d.: 0.05 g/L (0.025 vol.) CO
2
Resolution: 0.01/0.001 g/L (vol.) selectable
Accuracy of the pressure sensor: 0.01 bar accuracy of adjustment required
Accuracy of the temperature sensor: 0.2 C
Sample volume: > 100 mL
Typical measuring time per sample: approx. 90 seconds
Environmental conditions
Ambient temperature: +0 to +40 C (+32 to +104 F)
Air humidity (CarboQC): 10 to 95 % relative humidity
Degree of protection (CarboQC
without power supply): IP 64
Overvoltage category:
(power supply)
II
Dimensions (L x W x H): 190 x 120 x 305 mm (7.5 x 4.7 x 12 inches)
Weight: approx. 3.1 kg (6.8 lbs)
Power
Power adapter: Input: AC 100 to 240 V, 1.5 A, 50 to 60 Hz
Output: DC 15 V, 3.0 A
Indoor use only
Battery: Nickel metal hydride
7.2 V, 1900 mAh
Integrated protection
Charging time: approx. 2 hours
WARNING
Serious injuries are possible through high voltage if the following hints are not
adhered to.
Only connect devices to the interfaces that comply with PELV (protective
extra-low voltage) according to EN 61140 or with SELV (safety extra-low
voltage) according to EN 60950.
C26IB001EN-A 57
A.2 PFD Filling Device
PC/printer interface
COM1 and COM2:
RS232; 1200 to19200 Baud; 1 stop bit; 7 or 8
data bits; no, odd or even parity
Factory default settings: data bits: 7; stop bits: 1; parity: even; baud rate:
9600
TXD ... transmit data
RXD ... receive data
GND ... signal ground (connected to earth)
TXD
RXD
GND
Specified for the following containers:
Can:
Glass bottle:
PET bottle:
Max. volume:
0.5 L
1 L
3 L
Compressed gas:
Necessary quality of air if used as compressed
gas supply:
60.5 bar (877 psi)
Class 5 from ISO 8573-1
max. particle size: 40 m
max. pressure dew point: +7C (44.6 F)
max. oil content: 25 mg/m
3
Environmental conditions
Ambient temperature
Operation:
Transportation/Storage:
+0 to +40 C (+32 to +104 F)
-20 to +70 C (-4 to +158 F)
Air humidity
Operation/Transportation/
storage: 0 to 100 % relative humidity
Degree of protection: IP 64
Dimensions (L x W x H):
Maximum height with piercing head in highest
position:
190 x 270 x 670 mm (7.5 x 10.6 x 26.4 inches)
1020 mm (40.2 inches)
Weight: 10.1 kg (22.3 lbs)
Appendix B: Wetted Parts
58 C26IB001EN-A
Appendix B: Wetted Parts
The following materials are in contact with the samples to be measured and with
the cleaning agents:
CarboQC:
PFD Filling Device:
Material Part
PU (Polyurethane) Hoses
PSU (Polysulfone) Measuring chamber
Stainless steel Inlet-outlet valve, stirrer, piston
PEEK (Polyetheretherketon) Stirrer bearing
EPDM (Ethylene propylene diene
Terpolymer)
O-rings
Material Part
PU, Nylon Hoses
Stainless steel Sample tube, guide poles
EPDM O-ring
Appendix C: Measuring At-line
C26IB001EN-A 59
C.1 Connecting CarboQC to the Production Line or
Tank
NOTICE Do not place CarboQC on a wet or humid bench because humidity entering the
housing could damage the instrument.
TIP If CarboQC is frequently used for at-line measurements at different locations, we
recommend equipping CarboQC with a protective boot (Mat. No. 90079) for
protection of the instrument during transport.
CarboQC can be connected to the line via filter or filter with male hose filling
nozzle (at-line adapter, Mat. No. 18829). This at-line adapter allows for thicker
diameter hoses between adapter and line.
Fig. C - 1 Optional at-line adapter (filter with male hose filling nozzle, Mat. No.
18829)
TIP For at-line measurements, keep the hoses between the line and the filter as short
as possible to reduce pressure drops and minimize the risk of the sample
outgassing. The correct flow direction is marked with an arrow.
WARNING
Serious injuries through high voltage at instrument parts possible.
The power supply is not suitable for operation under wet at-line
conditions.
Charge the battery of CarboQC only under dry indoor conditions.
If CarboQC is not used for extended periods of time (> 2h), store the
instrument under dry indoor conditions only.
WARNING
Operation under pressure. Serious injuries and damage of goods possible if
the maximum allowable pressure is exceeded.
Do not operate CarboQC with sample pressures higher than 10 bar (145
psi) absolute.
60 C26IB001EN-A
Fig. C - 2 At-line connection
1. Connect the outlet of the line/tank to the filter inlet or the inlet of the at-line
adapter.
2. Connect the inlet of CarboQC to the filter (C) via a polyurethane hose 2.5 x 4
mm (A) (see Fig. C - 2).
3. Connect a polyurethane hose transparent 2.5 x 4 mm (B) to the outlet of
CarboQC.
4. Place the other end in the waste vessel.
TIP A carrying strap (Mat. No. 16012) is optionally available for safe and convenient
operation under at-line conditions.
Setting the correct flow
To set the correct flow, use the PFD Filling Device and proceed as described in
Chapter 8.4.1.
Waste
Sample valve
Filter (C)
B
A
Lugs for
carrying strap
C26IB001EN-A 61
C.2 Measurement
NOTICE Do not disconnect any hoses from CarboQC during the measurement.
TIP The minimum pressure for at-line operation of CarboQC has to be 0.5 bar (7.2 psi)
above saturation pressure of the dissolved gases. Proper functioning is best
determined by practical tests.
1. Press the <Method> key on CarboQC and select the required method.
2. If necessary, change the sample number by pressing the <Sample> key.
3. Open the sample valve of the line or tank.
4. Start the measurement by pressing the <Start> key on CarboQC.
5. Watch the measuring chamber.
After approx. 15 seconds rinsing time it should be free of bubbles.
TIP If the system pressure of the line is too low, the measuring chamber will not be
free of bubbles in time. Fill the measuring chamber of CarboQC manually by
pressing the <Rinse> key before pressing <Start>. After the measuring chamber
opens,
press the <Rinse> key periodically to turn the stirrer on and off,
make sure that a minimum of 100 mL flows through the measuring
chamber,
make sure the measuring chamber becomes free of gas bubbles.
The measuring result is automatically displayed after approx. 90 seconds
and stored in the memory of CarboQC (max. 99 measuring results).
C.3 Cleaning the Measuring Chamber
By connecting CarboQC to a tap with process water
Attach the inlet valve of CarboQC to a tap with process water (NOT with tap
water as the limestone might harm the inlet and outlet valves).
Then hit the <Rinse> key on the instrument to open the valves and rinse the
measuring chamber.
With a peristaltic pump
Connect the outlet tubing of a peristaltic pump to the filter or at-line adapter
that is connected to the inlet valve of CarboQC.
Hit the <Rinse> key on CarboQC.
62 C26IB001EN-A
Then operate the pump as required and rinse the measuring chamber with
detergent and/or deionized water. If detergent is used, the measuring
chamber has to be rinsed carefully with process water or deionized water
afterwards.
By connecting CarboQC to the process line
If the process line is cleaned with water or detergent, leave CarboQC
connected and hit the <Rinse> key.
If detergent is used, the measuring chamber has to be rinsed carefully with
process water or deionized water afterwards.
Appendix D: Interface Commands for Communication between a PC and CarboQC
C26IB001EN-A 63
Appendix D: Interface Commands for
Communication between a
PC and CarboQC
Measurement data stored in the memory can be transferred to a PC via the PC
interface of CarboQC.
1. Connect the CarboQC PC interface to the PC interface using an appropriate
interface cable.
2. Make sure the interface settings of CarboQC and PC agree.
3. Test the communication using a simple interface program, e.g. Windows
Terminal, Procomm or Hyper Terminal.
For data communication software, please contact your local distributor or
Anton Paar GmbH.
PC command CarboQC response Comments
help GetId
GetDataHead
GetDataUnit
GetData
ResetData
If the command "help" is sent
from the PC, CarboQC
responds with a list of available
commands.
get id id:00921503;CarboQC;V2.00A Readout of serial number and
firmware version.
get data head head:date;time;sample;method;
CO2;CO2;air;tm;pt;p0;condition;sol
Response. P0 = system
pressure.
get data unit unit:;;;;g/l;g/l ;ppm;C;bar;bar;;
g/lbar
The units of the measuring
results are transferred,
separated by a semicolon. The
units are displayed according to
the units selected in the
submenu.
get data no new data available
data:10.07.08;17:27; 1;
CM03PROD; 0.332; 0.332;26.9;
28.00; 1.54; 0.747;valid;1.448
No new data available.
Transfer of the first available
measuring result. One result
per entry "get data", starting
with the last result.
reset data reset data successful Resets read data to not fetched
status e.g. for second data
transfer.
Appendix E: Error Messages
64 C26IB001EN-A
Appendix E: Error Messages
Display Cause Correction
air: "error" Air value out of specification. Select the proper method for your
sample.
Rinse the measuring chamber.
Repeat the measurement. If the error
persists, contact your Anton Paar
representative.
Make sure that the CO
2
concentration
of the sample is within specifications
(Appendix A).
"CO2 - - - - - g/L" CO
2
value out of range.
Bubbles in the measuring cell.
The measuring chamber is not
tightly closed during
measurement.
Make sure that the measuring
chamber is free of bubbles.
Contact your Anton Paar
representative.
"air: - - - - - ppm" Air value is not determined, e.g if
"compensation" is set "off".
Activate the compensation in the menu
"adjustment > compensation".
Appendix F: Troubleshooting
C26IB001EN-A 65
Appendix F: Troubleshooting
Q The CO
2
reading of the water check with deionized water shows >0.03 g/L CO
2
.
A Sometimes, deionized water contains absorbed CO
2
and displays the amount
of CO
2
absorbed. Either heat up and boil the water and cover it up while cooling
down or do the water check with tap water but do not forget to rinse the
measuring chamber with deionized water afterwards!
Q The CO
2
reading of the first sample after a water check is low.
A If you go from samples containing very low to very high CO
2
contents, the first
result for the high CO
2
content is slightly lower than the following ones. If only
limited amounts of sample are available, it is a good idea to condition the
instrument by e.g. measuring mineral water after the water check before
measuring the first sample.
Appendix G: Firmware Versions
66 C26IB001EN-A
Appendix G: Firmware Versions
Firmware
version
Date of
release
Document
number
Comments
V 1.00A 09.03.2004 C26IB02A First released firmware.
V1.00B 16.04.2004 C26IB02B Zero adjustment improved (v-h).
V1.00C 09.09.2004 C26IB02C Measuring times at 10% volume expansion and
30% volume expansion optimized.
Total pressure display inside container
introduced.
Printout includes total pressure inside container.
Piston slows down before returning to starting
position.
V1.00D 15.02.2005 C26IB02D First released firmware version for PBA-S.
V1.00E 24.06.2005 C26IB02E
C26IB02F
Improved polynomial function for calculating the
air content.
V2.00A 28.07.2006 C26IB02G New microcontroller for increased performance.
Firmware update simplified.
New method "MID" for soft drinks with 3 to 8
Brix.
10 instead of 4 "CMxxPROD" methods.
Arbitrary selection of CO
2
units.
Selectable if methods are displayed in the
method list ("man sel/disable").
Semiautomatic adjustment of the pressure
offset in the menu "adjustment".
Data memory can be viewed without entering a
password.
V2.00B 28.07.2008 C26IB02H Simplified firmware update for future firmware
versions.
Calculation of package pressure at reference
temperature.
V2.00C 13.01.2010 C26IB02I Improved display controller.
V2.00D 19.05.2010 C26IB001EN-A Rinse time selectable up to 200 seconds.
Numbers added to the methods.
Appendix H: Declaration of Conformity
C26IB001EN-A 67
Appendix H: Declaration of Conformity
Appendix I: Menu Tree
68 C26IB001EN-A
Appendix I: Menu Tree
adjustment compensation comp air: on | off
vexp: 02, ..., 40 %
auto p-offset CO2: x.xxx g/l
p: x.xxx bar (psia)
instrument rinse time: 03, ..., 60 sec
unit t: C | F
p: bar | psia
CO2: g/l | vol
CO2dec: 2dec | 3dec
serial com baud: 9600 | 4800 | 2400 | 1200 | 19200
format: E71 | N81 | O71
password new: 0000
date & time date: ddmmyy | mmddyy
year: xx
month: xx
day: xx
time: 24hrs | am/pm
hour: xx
min: xx
battery service: off | on
device info print: off | printer | PC
methods 01 MINERALc
03 DIETcccc
05 BEERcccc
07 ST.BEERc
09 COLAcccc
11 SPARKLcc
13 MIDccccc
name: MINERALc (xxxxxxxx)
sel: man sel | disable
unit: g/l (xxxxxx)
fu, k1, ..., k7
17 CM01PROD, ...,
26 CM10PROD
name: MINERALc (xxxxxxxx)
unit: g/l (xxxxxx)
fu, k1, ..., k7, ks, ka, ..., kd
00 MINERAL
02 DIET
04 BEER
06 ST.BEER
08 COLA
10 SPARKL.
12 MID
name: MINERAL
data memory browse memory
clear memory clear: no | yes
service device
offset
gain
Index
C26IB001EN-A 69
Index
A
Absorption coefficient 46
Activating lever 28, 37
Air content 53
Air humidity 56, 57
Ambient temperature 56, 57
B
Battery 15, 17, 42, 56, 59
Battery status 15
Bubbles 28, 36, 38, 61
C
Can 26
CO2 content 41, 49, 50
CO2 result 31, 33, 41, 43, 47, 51
Coefficient 43, 51
Compressed gas 9, 18, 57
Compressed gas supply 28
Customer specific 16, 25, 43, 44, 45, 50
D
Date 23, 42
Deionized water 33, 35, 36, 37
Display 15, 38, 47, 64
Dissolved air 40, 47, 49
E
Exhaust 21
F
Filter 12, 20, 21, 36, 37, 60
Flow valve 26
G
Glassware cleaner 33, 35, 36, 37, 38
H
Headspace 24, 43, 50
Hose 12, 58
K
Keypad 16, 38, 39
M
Marking 26
Measurement 25, 27, 48, 61
Measurement data 47, 63
Measuring chamber 14, 16, 28, 35, 36, 37, 38,
41, 48, 49, 58, 61
Measuring mode 16, 39
Measuring range 56
Measuring temperature 47, 53
Memory 16, 28, 47, 61, 63
Menu 16, 23, 39, 40
Menu access 40, 42
Menu mode 16, 23, 39
Method 16, 28, 43, 44, 45, 47, 50, 61
Multiple Volume Expansion method 49
N
Nitrogen 44, 48, 49, 53
O
Offset 48
On/off switch 22
P
Password 23, 40, 42
PC interface 41, 57, 63
PET bottle 26, 37
PFD 25, 26, 35, 36, 37, 57
Piston 28, 38, 58
Power adapter 12, 15, 21, 42, 56
Pressure 21, 23, 28, 38, 41, 56, 61
Pressure sensor 41, 48
Print 16, 28, 42
Printer interface 41
Printout 16
Purified water 35
R
Reference pressure 54
Rinse 16, 33, 35, 36, 37, 41
S
Sample flow 33
Sample inlet 21
Sample number 16, 61
Sample outlet 21
Index
70 C26IB001EN-A
Sample pressure 59
Sample residues 35, 36, 37
Sample tube 28, 37
Sample volume 56
Service 17, 42
Slope 48, 53
Solubility 48, 53
Solubility coefficient 43
Start key 16
Stirrer 16, 28, 38, 58, 61
Stop key 16
Supply inlet 22, 42
T
Temperature 23, 25, 41, 51, 53
Temperature sensor 48
Time 23, 42
U
Unit 23, 41
V
Volume expansion 40, 48, 49
W
Waste vessel 20, 60
Z
Zero point 33

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