Nhm 1

Polyme phn hy sinh hc / biocompozit si tre vi cht gn kt sinh hc

Tennessee Sn phm Trung tm Lm nghip, 2506 Jacob Drive, i hc Tennessee, Knoxville, TN 37996-4563, USA nhn 9 thng 12 nm 2004; sa i ngy 28 thng 3 nm 2005; chp nhn 20 thng 4 nm 2005

Tm tt nh hng ca lyzin trn c s diizocyanat (LDI) nh mt cht gn kt trn cc thuc tnh ca biocompozit t poly (lactic acid) (PLA), poly (Butylene succinate) (PBS) v cht si tre (BF) c iu tra. Tnh bn ko, kh nng chu nc, v bm dnh b mt phn pha ca c compozit PLA / BF v PBS / BF c ci thin bng vic b sung cc LDI, trong khi s chy ra nhit tr nn hi kh khn do lin kt ngang gia mch nn polymer v BF. Nhit kt tinh v entanpy trong c hai compozit tng v gim theo lng LDI, tng ng. Nhit ca phn ng tng hp trong c hai compozit b gim do b sung LDI, trong khi khng c s thay i ng k trong nhit nng chy. Nhit phn hy ca c hai compozit thp hn so vi nhng mng chui polymer tinh khit, nhng cc hp vi LDI cho thy nhit phn hy cao hn so vi trng hp khng c LDI. Cc ch phm enzym c kh nng phn hy compozit ca PLA / BF v PBS / BF c iu tra bi proteinaza K v Lipaza PS, tng ng. C hai compozit ny c th c nhanh chng b phn hy bi enzyme v vic thm vo LDI nhm tr hon s phn hy . 2005 Elsevier Ltd- tr quyn tc gi. T kha: Biocompozit ; Poly (lactic acid), Poly (Butylene succinate), si tre, diizocyanat Lyzin, cht gn kt sinh hc. 1. Gii thiu Trong nhng nm gn y, s pht trin ca biocompozits t polyme phn hy sinh hc v cc loi si t nhin thu ht c li s quan tm ln trong khoa hc tng hp, bi v c th cho phn hy hon ton trong t hoc bng cch phn qu trnh v khng pht ra bt k thnh phn c hi, c hi.

Nhm 1

Trong s cc polyme phn hy sinh hc (acid lactic) c bit poly (PLA) v poly (Butylene succinate) (PBS) c quan tm thng mi ngy cng tng. PLA c th c tng hp bng cch trng hp ngng t ca cc dimer lactide theo chu k. Cng ngh tin tin trong cng nghip trng hp c pht trin c th tng hp PLA trng lng phn t ln dn n mt tim nng cho vt liu cu trc vi thi gian sng duy tr cc c tnh c hc m khng c s thy phn nhanh chng ngay c trong mi trng m t, cng nh c kh nng lm phn bn tt. PLA trong sut v tinh th polymer vi im nng chy tng i cao v c c tnh d v, vi cng cao v ko di chm s t. PBS l nha nhit do vi tinh th mu trng c im nng chy khong 90-1200C (tng t nh LDPE), nhit thy tinh ha khong -45 ti -100C (gia PE v PP), chu lc ko gia PE v PP, v cng gia LDPE v HDPE. PBS c kh nng x l tuyt vi v c th c x l trn cc my ch bin polyolefin nhit ca 160-2000C, thnh cc sn phm khc nhau, chng hn nh p n v thi. Hn na, nguyn liu ca n, butanediol v succinec acid, c th sm c tm thy t cc ngun ti nguyn ti to sinh hc. Si t nhin c th c ti to v r hn thay th cho si tng hp, chng hn nh thy tinh v carbon v c rt nhiu li th, chng hn nh chi ph thp, t trng thp, do dai cao, c kh nng chu sc mnh theo t trng , d dng tch v c kh nng phn hu sinh hc. V vy, c rt nhiu nghin cu v compozit ct si t nhin. Tuy nhin, nhc im chnh ca cht si t nhin c th l bn cht a nc ca n, lm gim kh nng tng thch vi mng li (nn) polymer k nc. Trong nhng lnh vc tng hp, do , hu ht cc nghin cu tp trung vo vic ci thin cc thuc tnh trn mt phn pha gia nn polymer v cht n t nhin tng cng cc tnh cht c l ca sn phm cui cng. Mc ch ca nghin cu ny c pht trin biocompozits vi vic c th sp t cc thuc tnh bn trong b mt t polyme phn hy sinh hc, PLA v PBS, v cht si tre bng cch s dng LDI nh mt cht gn kt sinh hc. Cho n nay,cc loi izocyanat chng hn nh methylene diizocyanat (MDI), toluene diizocyanat (hydro ha MDI), v diizocyanat hexamethylene c s dng nh mt cht gn kt [34-38].V d, Wang et al. bo co v nh hng MDI

Nhm 1

ln thuc tnh ca blend PLA/tinh bt. Vic b sung ca MDI em li kt qu l s tng cng ca c tnh c hc v kh nng chng nc. Tuy nhin, nhng izocyanat tm thy c hn ch s dng nh mt vt liu tng hp sinh hc bi v chng l nhng sn phm cui ca qu trnh thy phn, tc l cc diamin tng ng ca chng, chng hn nh 4,4 '-methylenedianiline v 2,4-diaminotoluene c tm thy v nghi ng nh mt tc nhn gy ung th, gy ra bnh vim gan ngi. V vy, vic s dng vt liu khng c hi nh mt tc nhn gho ni, tng hp y cc biocompozits phn hy sinh hc m khng pht thi cc thnh phn c hi. Lyzin-diizocyanat (LDI) c da trn lysine vi hai nhm amin v mt nhm cacboxyl, l mt trong cc axit amin t nhin. LDI c th phn ng vi cc nhm hydroxyl hoc carboxyl trong PLA hoc PBS, sinh ra cc lin kt urethane mt cch d dng v hon ton c th thy phn thnh nguyn liu [41-45]. V d, polyurethane tng hp t LDI, glycerol v acid ascorbic (vitamin C) c th c hon ton b r ra trong dung dch nc v sn lng cht khng c hi c phn ra ca lysine, glycerol v acid ascorbic [46]. Trong thc t, s quan tm ca chng ta ti LDI nh mt cht gn kt sinh hc xut pht t nhng thc t ny, bi s nhim c sinh thi hin ang l mt im quan trng trong biocompozits. 2. Th nghim 2. 1 Ha cht PLA (LACEA H-100J0 v PBS (Enpol G5300) c mua t Mitsui Chemical, Inc (Tokyo, Nht Bn) v Ire Ha cht Ltd (Wonju, Hn Quc). Thi gian trung bnh v ng knh ca si tre (BF) c s dng trong nghin cu ny c khong 500 v 70 m. L-lysine diisocyanate (LDI) c cung cp bi Kyowa Hakko Co, Ltd (Tokyo, Nht Bn). BF c sy kh trong l 1050C trong 6 gi, trong khi PLA v PBS c sy kh trong chn khng 400C 24 gi trc khi s dng. Proteinaza K v Lipaza PS c mua t Nacalai Tesque, INC (Kyoto, Nht Bn). Tt c cc ha cht khc c mua t cc ngun thng mi. 2.2 S tng hp v nn p c

Nhm 1

Cc polyme v BF trc tin c trn di dng cht rn kh. Hn hp ny c t vo mt my trn hng lot (Labo Prostomill, Tokyo Seiki, Nht Bn) quay vi tc ca 30vng/pht. Sau tc quay c tng ln n 70 vng/pht v qu trnh nho trn c thc hin trong 5 pht. Sau , LDI c thm vo hn hp v qu trnh nho trn tip tc thc hin trong 10 pht. Lng LDI thm vo c th hin bng lng NCO nh phng trnh di y : NCO = x100 (%)

Cc nhit nho trn l 1800C v 1400C trong cc trng hp ca PLA v PBS. Cc mu nho trn c nn c thnh cc tm di p sut 150 kgf cm-2 mc 1800C (PLA / BF compozit) v 1400C (PBS / BF compozit). 2.3 Thuc tnh ko gin v th nghim ht nc. Mt mu hnh xng ch (5x0.4x 50 mm) c ct t cc tm c nn v o bn ko c thc hin vi mt my Shimadzu Autograpg AG-1 (5kN) Kyoto, Nht Bn) vi tc u vt qua mc 5 mm pht-1. Cc mu vi kch thc 50 x50x0,5mm c s dng kim tra trng thi hp thu nc sau khi lm kh chn khng ti 450 trong 24h. Cc mu c ngm hon ton trong nc kh Ion ha (250C) v ln lt a ra khi nc. Sau , cc nc d tha trn b mt c loi b bng cch thm vi khn giy v cc mu vt c cn. Lng nc b hp th Mt c tnh nh sau: Mt = (Wt - W0)/ W0 x100 (%) Vi Wt , W0 l trng lng ca mu trc v sau khi ngm trong nc tng ng. 2.4 Vi sai qut nhit lng k (DSC) v phn tch lc hp dn nhit (TGA) DSC o lng c thc hin trn dng c gi l dPerkin-Elmer Diamond DSC. Cc mu (khong 7 mg) c un nng n 200 v 1500C 200C pht-1 trong PLA v PBS/BF vt liu tng hp, tng ng, v gi trong 5 pht loi b cc qu trnh nhit. Sau , cc mu c lm lnh n 400C vi tc 2 v 100C pht-1 trong PLA v PBS/BF tng hp, tng ng, v un nng mt ln na 200 v 1500C vi tc 200C.pht-1 trong PLA v PBS/BF tng hp, tng ng. Vic thu nhit v ta nhit c th hin trong bng 1: Nng lng kch hot cho s tan chy ca compozit PLA v PBS/BF (70/30)

Nhm 1

Nng lng kch hot cho s tan chy PLA/BF tng hp 0 193,9 63,4 0,11 195,1 76,5 0,33 195,3 91,5 0,65 197,0 114,1 1,30 211,9 im cc i c gi l nhit kt tinh (Tc) v nhit nng chy (Tm), tng ng. Entanpy kt tinh ( Hc) v nhit ca phn ng tng hp ( Hm) cng c xc nh t cc cc i ca s kt tinh v s tan chy, tng ng. Nhng gi tr ny trong cc hp c chia theo t l trng lng ca polymer v cc gi tr thu c trong Bng 1. gim phm cht do nhit c o bi mt Perkin-Elmer Pyris 1 TGA. Mu khong 7 mg c un nng t 50 ti 6000C vi tc 100C.pht-1 di dng nit (20mL/pht). 2.5 c tnh tan chy do hiu ng nhit Hin nhin nht tan chy ca compozit c o nhit khc nhau vi mt th nghim dng chy (Shimadzu CFT-500D). Nhng bin dng nhn mnh c p dng l 2,452x104 Pa v cc ming bnh vi ng knh v chiu di cht 1 v 10mm, tng ng. 2.6 Cc ch phm enzym thy phn Mu c sy kh chn khng (10x10x0.4mm3) c cn v nhng vo mt ng nghim 5 ml ca dung dch proteinaza K (50 mM cht m Tris-HCL, pH 8,6) v dung dch Lipaza PS (0,1 M cht m photphat, pH 6,0) trong trng hp ca PLA v PBS / BF tng hp, tng ng. ng nghim c nim phong v gi mc 380C trong mt thi gian nh trc v c thay th mi 48 gi (proteinaza K) v 1 tun (Lipaza PS ), do hot ng ca enzyme vn mt mc mong mun trong sut thi gian th nghim. Mu sau c b ra khi dung dch, ra k bng nc ct v ethanol, v sau sy kh trong chn khng mc 380C. Thi gian qu trnh gim khi lng c nh gi v cc mu cn li c quan st bi SEM 2.7 Hin vi in t quyt Hnh thi hc ca cc mu b gy sau khi th nghim bn ko c kim tra bng cch s dng mt knh hin vi qut JEOL 5900LV JSM.

Lng NCO (%)

Nhm 1

3 Kt qu v tho lun 3.1 Mt phn gii hnh thi hc Nhiu thuc tnh ca vt liu conpozit s b nh hng bi hnh thi hc ca chng. Hnh 1 cho thy SEM

Hnh 1 SEM giao din ca hin vi gia mng li v BF trong compozit PLA / BF (70/30)
khng c (A), hoc c LDI (lng NCO, 0,65%) (B), v compozit PBS / BF (70/30) m khng cn (C), hoc c LDI (lng NCO, 0,65%) (D).

nh hin vi ca b mt ko b gy ca PLA v PBS / BF tng hp c hoc khng c LDI. Tng hp PLA/BF m khng c LDI, hai giai on c th c thy r v nhiu BFs c ko ra khi mng li trong qu trnh nt gy, vi khong trng ln do c to ra. Ngoi ra, khong cch gia PBS v BF trong compozit PBS/BF m khng c LDI c nhn thy. Nhng tm kim cho thy rng s tng tc gia mng li v cht in y rt yu, bm dnh t b mt chung. Nhng tnh nng ny l in hnh ca cc vt liu tng hp polymer khng tng thch. Mt khc, nh hin vi ca c hai vt liu compozit sau khi ha hp vi LDI 0,65% cho thy rng BF xut hin c ph vi mng li polymer. Ci thin bm dnh gia hai b mt ny c th l do tc dng tng thch copolymer ghp vi cc trung gian LDI, m c th c sn xut thng qua mt phn ng ha hc gia cc nhm hydroxyl ca polymer v BF nho trn trong iu

Nhm 1

kin nhit cao hn v p lc [39,40]. Trong bi bo trc y ca chng ti, iu c xc nhn rng nhm isocyanate phn ng vi cc nhm thit b u cui hydroxyl hoc carboxyl ca PLA v cc nhm hydroxyl ca tinh bt, sn xut copolymer ghp ca PLA v CS urethane lin kt c xc nhn bi NMR o lng [15]. Kt qu hnh thi h tr vic ci thin tnh bn ko v kh nng chng nc bng cch thm LDI, m s c tho lun di y. 3.2 Thuc tnh bn ko

Hnh 2: nh hng ca lng NCO n cc thuc tnh cng ca compozit PLA hoc PBS / BF (70/30). #, Ko sc mnh; m un Young; , gin di ph v.

Hnh2 cho thy nh hng ca nhm isocyanate (NCO) cha trn cc thuc tnh cng ca PLA v PBS/BF (70/30 bi wt) compozit. Trong trng hp ca PLA/BF compozit,lng NCO tng 0,33%, bn ko v m un Young tng nhanh chng t 29 n 42 MPa v t 2666 n 2964 MPa, tng ng, v sau san bng-ofF. Tuy nhin, khng c tc dng ng k LDI ngoi ra s ko di t, hin th gi tr di 5%. Tng t, bn ko ca vt liu tng hp PBS / BF tng nhanh t bin t 21 n 34 MPa vi lng NCO cha 0,33%, tng ng, v sau san bng. Tuy nhin, m un Young khng c nhiu thay i bng vic b sung cc LDI. gin di t tng nh nu b sung LDI, nhng vn cho thy gi tr t hn 10%. Lng nhm NCO ti gi tr ca bn ko gi nguyn c th c xem xt tp trung ti b mt phn pha, l gi tr ti thiu ca bo ha ti b mt phn pha cho mt cht gn kt trong giai on phn tn, v kch thc trung bnh ca phn tn BF s khng c thay i vivic b sung cc cht gn kt 15,4749].

Nhm 1

Hnh 3

Hnh 4

Hnh 3 v 4 th hin cc tc dng ca ni dung BF trn cc thuc tnh cng ca PLA v PBS / BF compozit c hoc khng c LDI. Lng NCO c t mc 0,65%. Trong c hai compozit m khng c LDI, bn ko gim dn vi s gia

Nhm 1

tng ca lng BF. iu ny c th l do kt dnh km b mt phn pha gia mng li polymer v BF ph. y l mt hin tng chung trong compozit khng tng thch vi cc c im khc nhau, chng hn nh tnh k nc ca mng li polymer v tnh a nc ca cht ph [50-53]. Tuy nhin, bn ko ca cc hp PLA / BF vi LDI gi gi tr ca khong 45 MPa bng cch tng lng BF ln n 30% v sau gim. Nhng gi tr ny cao hn so vi nhng cc hp khng c LDI. Hn na, bn ko ca PBS / BF compozit vi LDI tng lng BF ngy cng tng v s ci thin r rt khi lng BF cao hn. iu ny c th l do tng cng bm dnh b mt phn pha gia mng li polymer v ph BF bng cch thm LDI. Tt c cc compozit cho thy s gia tng ca m un Young cng vi lng BF tng ln. iu ny l ph bin trong vt liu compozit c gia c bng mt cht n cng. Mt khc, cc vt liu compozit vi LDI cho thy gi tr cao hn compozit khng c, ch ra rng tng hp c tip tc lm cng bng vic b sung cc LDI. gin di t gim vi vic tng lng BF trong tt c cc vt liu compozit. iu ny c th l do s gia tng trong gin on ca mng li polymer vi s gia tng trong giai on phn tn (BF). Tuy nhin, cc compozit vi LDI cho thy bn ko di t hi cao hn so vi compozit m khng LDI. 3.3. thm nc BF l cht a nc bi v n c cha mt lng ln cc nhm hydroxyl, nhng PLA v PBS l polyme k nc. Hiu qu ca vic b sung cc lng cht LDI v BF vo hnh vi hp th nc ca cccompozit c nghin cu v ch ra trong hnh. 5. S hp thu nc cho tt c cc vt liu compozit tng ng k trong 20 h u tin v sau t cnbng. Khi so snh vi cc hn hp c v khng c LDI, s hp th s lng v thi gian t n s n nh nh hn v lu hn, tng ng, cho tt c cc vt liu compozit vi LDI hn khng c, ch ra rng vic b sung ca LDI lm cho s hp thu nc kh khn. iu ny c th c gii thch bi s ci thin trong bm dnh b mt phn pha gia mng li polymer v cht ph BF do s ghp ni ca LDI v phn ng ca LDI vi cc nhm hydroxyl ca polyme v BF kt qu l t a nc hn. Ngi ta cng c tm ra rng s lng hp th tng ln trong tt c cc vt liu compozit vi lng BF tng ln. Bi v PLA v PBS c th hp th nc khong 1%, lng BF l yu t ch yu nh hng n s hp thu nc ca vt liu

Nhm 1

compozit.S gia tng ca lng BF lm tng tc hp th, bi v tnh a nc mnh m ca n.

Hnh 5: nh hng ca BF lng v b sung ca LDI hp th nc ca cc vt liu compozit

PLA hoc PBS / BF. 0,90 / 10; , 80/20; A, 70/30; , 60/40, 50/50; trng v * (rn dng) LDI (lng NCO, 0,65% ), mu en +, (du gch ngang dng) m khng cn LDI

3.4. Nhit tan chy thuc tnh

Hnh 6 Mi quan h ca logarit nht tan

chy hon ton(Ln) v nhit i ng (07/01) PLA / BF compozit.Lng NCO: , 0%; , 0,11%, 0,33%; , 0,65%, 1,30%.

Nhm 1

Hnh 6 v 7 cho thy mi quan h gia logarit ca nht tan chy hon ton(Ln ) v nhit i ng (l / T) trong PLA v PBS / BF vt liu compozit, tng ng. Di s cng thng ct (4.9X104Pa), nht biu kin ca tt c cc vt liu compozit gim khi nhit tng. .Mi quan h gia Ln v l / T l tuyn tnh, ch ra rng s ph thuc ca vo nhit tun theo phng trnh Arrhenius: =Ax (3) Hnh 7 Mi quan h ca logarit nht tan chy hon ton(Ln tj) v nhit i ng
(l/T) trong PBS / BF compozit. Lng NCO: 9, 0%; . 0,11%; A, 0,33%; , 0,65%.

Vi: A l mt hng s c lin quan n c tnh vt liu E nng lng kch hot cho lu lng R hng s kh l tng T nhit tuyt i. Theo phng trnh Arrhenius, nng lng kch hot cho lu lng c tnh ton v cc gi tr c tm tt trong Bng 1. Cc vt liu tng hp vi LDI trong c hai vt liu tng hp yu cu nng lng kch hot cho lu lng cao hn so vi cc hp khng c LDI, biu th cc gi tr ln hn so vi cc hp khng c LDI. N cng c tm thy vi nng lng kch hot tng khi lng LDI tng ln. iu ny cho thy rng vic b sung ca LDI dn n s gia tng tr ngi v chuyn ng ca phn t ca mng li polymer do cc lin kt ngang vi BF, lm cho s nng chy kh khn. 3.5 Kt tinh v trng thi tan chy Tnh cht nhit c nghin cu bi DSC v cc kt qu thu c tm tt trong bng 2 di y:

Effect of LDI on crystallization and melting behavior of the PLA and PBS/BF (70/30) compozits Sample NCO Tc CC) AHC (J/g) 7-m(C) (J/g) content (%) PLA PLA/BF compozit 0 0.11 0.33 0.65 1.30 0 0.11 0.33 0.65 1.30 112.8 115.2 118.4 118.7 119.4 120.2 68.1 74.6 78.0 80.2 82.2 82.6 33.2 165.3 23.5 (33.6) 162.3 21.5 (30.7) 162.7 20.2(28.9) 161.8 16.4(23.4) 162.2 14.5(20.7) 161.6 60.1 112.1 40.8(58.2) 112.0 37.8(54.0) 112.1 38.1 (54.4) 112.3 37.3 (53.3) 112.9 31.2 (44.6) 112.1 41.1 27.4 (39.1) 23.5 (33.6) 23.6 (33.7) 23.1 (33.0) 22.8 (32.6) 65.3 42.3 (60.4) 35.8 (51.1) 29.4 (42.0) 24.5 (35.0) 21.7 (31.0)

Nhm 1

PBS PBS/BF compozit

( ) Values divided by the weight proportion of polymers

C bn PLA v PBS c mt nhit kt tinh (Tc) ca 112,8C v 68,1C, tng ng. Trong c hai PLA v PBS / BF compozit, Tc chuyn sang nhit cao bng cch thm hoc BF hoc LDI, v tip tc tng t l ni LDI. Nhng gi tr TQ ny cao hn ca compozit hn so vi cc polyme tinh khit ch ra rng t l kt tinh hn so vi cc vt liu compozit tr nn nhanh hn trong cc qu trnh nonisothermal. S gia tng trong Tc c th c coi l do hiu ng to mm ca BF v LDI. c bit, mi lin kt urethane gia mng li polymer v BF vic b sung cc LDI c th tng cng hn na mm ca ma trn polymer. Trong c hai vt liu tng hp, tuy nhin, kt tinh entanpy ( Hc) gim bng cch tng lng LDI. Cc chuyn ng phn t ca mng li polymer c th b hn ch bi vic b sung cc LDI, kt qu l gim entanpy kt tinh. Vic b sung cc LDI c th tng cng hn na s to mm ca mng polymer. Trong c hai compozit, tuy nhin, kt tinh entanpy ( Hc) gim bng cch tng lng LDI. Cc chuyn ng phn t ca mng polymer c th b hn ch bi vic b sung cc LDI, kt qu l gim entanpy kt tinh. Nhit nng chy (Tm) tinh khit PLA v PBS l 165,3 v 112,1C, tng ng. Nhng TMS khng b nh hng bi vic b sung ca mt trong hai BF hoc LDI. Tuy nhin, nhit nng chy (A//c) trong c hai vt liu compozit c gim b sung ca BF v LDI. y c th l do s tng tc mnh m gia mng li polymer v BF b mt phn pha, giam gi nh hng chui polymer. 3.6 Nhit phn hy Hnh 8 v 9 hin th cc ng cong TGA v biu nhit phi sinh (DTG) cho PLA, PBS, BF, v PLA v PBS / BF hp vi lng LDI khc nhau. Nhit phn hy ca PLA v PBS cho thy trong mt giai on hon ton duy nht v xy ra ti 376 v 405C, tng ng. Trong trng hp ca BF, mt ba giai on

Nhm 1

chnh ca khi lng c quan st. Giai on u tin vimt khong nh trong phm vi nhit t 250 n 300C l c trng ca cc thnh phn trng lng phn t thp, chng hn nh hemixenluloza v mt trong giai on th hai, xut hin nhit cao trong khong 300 v 400C, tng ng vi phn hy nhit ca cellulose. V 1/3 gn 420C l do lignin phn hy. Trong trng hp ca PLA / BF compozit, s kt hp ca BF trong mng li PLA b nh hng ng k nhit phn hy nhit. Cc vt liu compozit cho thy nhit gim cp thp hn (trn 50C) so vi ca PLA v mt mt hai giai on ca i chng ch yu l quan st cho tt c cc vt liu compozit. l, s gim cp trong phm vi 280 - 340C l do phn hy PLA gn khong nh gn 3500C l do BF phn hy. Nhng nhit gim cp thp hn c th l do gim trng lng phn t ca PLA bi nhit cao nho (180C). Tuy nhin, vi cc compozit nhit gim cp nhit lng LDI. N c th c ni rng s gia tng trng lng phn t bng ccni ngang t phn ng gia mng v BF, s m rng mng phn t ca ma trn ring ca n, c th lm tng nhit phn hy nhit 54-56]. PBS / BF tng hp cho thy mt s n nh nhit trung gian gia nhng ngi ca PBS v BF, b sung ca LDI cng c ci thin s n nh nhit ca hn hp, nhit cao hn phn hy nhit trong compozit vi LDI.

Nhm 1

Hnh 8

Hnh 9

Nhm 1

3.7 Cc ch phm enzim phn hy Cc hiu ng ca vic b sung ca LDI trn kh nng phn hu sinh hc ca vt liu tng hp c iu tra bi phn hy enzyme bng cch s dng proteinaza K v Lipaza PS, cng c bit n lm suy gim mt cch d dng PLA v PBS, tng ng [57-59]. Hnh 10 v 11 cho thy trng lng cn li ca PLA v / hoc vt liu tng hp PBS / BF c v khng c LDI cng vi tinh khit PLA v PBS nh mt chc nng ca thi gian tri qua, tng ng. N c quan st thy rng trng lng cn li ca tt c cc mu gim gn nh tuyn tnh vi thi gian tri qua. Phn hy tinh khit PLA v PBS l chm hn so vi tt c cc vt liu compozit, ch ra rng BF ci thin s xung cp ca c hai polyme. Khi so snh gia cc vt compozit c v khng c LDI, tt c cc vt liu compozit c LDI s kh phn hy hn so vi nhng compozit khng c. Bng cch tng lng LDI tc phn hy tr nn chm hn nhiu. Ci thin bm dnh b mt gia mng polymer v BF bng kh nng kt ni ca LDI s lm cho khu vc tip xc vi en Hnh12 cho thy hin vi SEM ca PLA hoc compozit PBS / BF (70/30) vi LDI gim cp trong thi gian phn hy khc nhau. N c th c nhn thy r rng rng ma trn ca c hai vt liu tng hp tr thnh gim nh enzyme phn hy tip tc.Hnh 13 cho thy nh hng ca lng LDI vo phn hy ti cng mt thi gian. Trong trng hp ca cc hp khng c LDI (A v D)zyme nh hn, dn n gim tc phn hy. a s cc mng li b phn hy mc d phn hy thi gian ngn. Tuy nhin, s mt mt ca mng xy ra chm hn trong cc compozit c LDI hn khng cn LDI v rt nhiu cc b phn trong cc compozit c lng LDI nhiu hn . Nh cp trn, b mt phn pha s kt dnh mnh m hn s gim din tch tip xc c thy phn enzyme v iu ny s cho kt qu trong mt thi gian phn hy di hn.

Nhm 1

Hnh 12 SEM hin vi ca PLA hoc compozit PBS / BF vi LDI (lng NCO 0,65%) sau khi
thi gian phn hy enzyme khc nhau. (A) kim sot ca compozit PLA / BF, (B) sau 7 ngy, (C) 9 ngy, (D) kim sot ca compozit PBS / BF, (E) sau 2 ngy, (F) 4 ngy.

Nhm 1

Hnh 13 SEM hin vi ca compozit PLA / BF (sau 7 ngy) v PBS / BF (sau 7 ngy) c hoc
khng c LDI sau khi phn hy enzyme. (A) compozit PLA / BF m khng c LDI, (B) vi LDI (Lng NCO, 0,33%), (C) (0,65%), (D) compozit PBS / BF m khng c LDI, (E) (Lng NCO, 0,33 %), (F) (0,65%).

4. Kt lun Mt nng thp ca LDI l cht gn kt sinh hc c b sung biocompozit thn thin vi mi trng trong qu trnh nho trn. c bit, tnh cht cng ko v kh nng chng nc ng ci thin bng cch ch bin ny phn ng c hc-ha hc, ci m c gi tr cao trong cc ng dng cng nghip. Nhng ci thin ny l do tng cng bm dnh b mt phn pha gia mng chui polymer v BF. Hn na, cc kt qu ca phn hy enzyme cho thy kh nng phn hu sinh hc c th c iu chnh bng cch kim sot mc bm dnh trn b mt s dng LDI. Ti cc khu vc, ni m tnh tng hp sinh hc v yu cu thit k xy dng ph hp vi phng din mi trng c yu cu, nhng biocompozits c tim nng cho s tng trng n tng vi mt khi nim mu xanh l cy. ng dng chnh cho biocompozits bao gm chi cho tr em, ni

Nhm 1

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