Bi tp Ho Phn tch - Chng 1,2

1. Vit phng trnh tnh hng s cn bng cho cc phn ng sau:

a. NH3 + HCl NH4+ + Cl
b. PbI2 + S2 PbS + 2I
c. CdY2 + 4CN Cd(CN)42 + Y4 [Y4 is EDTA]
d. AgCl + 2NH3 Ag(NH3)2+ + Cl
e. BaCO3 + 2H3O+ Ba2+ + H2CO3 + 2H2O

2. Vit phng trnh bo ton nng v bo ton in tch cho cc dung dch sau:
a. 0,1 M NaCl
b. 0,1 M HCl
c. 0,1 M HF
d. 0,1 M NaH2PO4
e. MgCO3 (dung dch bo ha: T=3,5.10-8)
f. 0,1 M Ag(CN)2 (t phn ng ca AgNO3 v KCN)
g. 0,1 M HCl and 0,050 M NaNO2
h. 0.10 M NaHCO3.

3. phn tch ng trong mt mu qung ngi ta lm nh sau: Ha tan 1,25-g mu trong

axit v nh mc thnh 250mL (dd A). Ly 20-mL dd A pha long thnh 50 mL (dd B).
Nng Cu2+ trong dd B phn tch c 4,62 ppm. Tnh hm lng phn trm ca ng
trong mu qung ban u?

4. Trnh by cch pha 3 dung dch sau:

a) 500 mL dung dch NaOH nng gn ng 0,20 M t NaOH rn.
b) 1L dung dch Cu2+ nng 150,0 ppm t ng kim loi.
c) 2L dung dch axit axetic nng th tch 4% t axit axetic c.

5. Mt nh phn tch mun thm 256 mg ion Cl vo mt hn hp phn ng. Hi phi thm
bao nhiu mL dung dch BaCl2 0,217M vo?

6. Nng ch trong nc thi ca mt nh my l 0,28ppm. Hi nng mol/L l bao

nhiu?

7. Nng ca axt HCl c thng mi l 37%, t trng 1,18 g/mL. Tnh nng mol/L
ca HCl c. Tnh khi lng (m) v th tch (V mL) ca dd axit c cha 0,315 mol
HCl.

8. C dung dch 250,0-mL cha 45,1 mg mt loi thuc tr su. Tnh hm lng thuc tr
su ra nng %, ppm, ppb.

9. Mt cng ty cp nc x l nc bng NaF. Mun nng F- l 1,6 ppm th phi thm

bao nhiu mg NaF vo 1L nc nu nng F- c sn trong nc l 0,2ppm?

10. xc nh nng ca etanol trong ru cognac, ly 5.00-mL mu ru pha long

thnh 0,500 L. Phn tch dung dch pha long c nng ca etanol l 0.0844 M.

Hi nng % th tch ( ru) ca etanol trong ru cognac cha pha long l bao
nhiu? (etanol lng c d=0,789g/mL).

Bi tp Ho Phn tch - Chng Cn bng axit baz

1. Vit phng trnh bo ton proton cho cc dung dch sau:

NaCN; CO32-; HCl + CH3COOH; NH4CH3COO;
2. Tnh pH ca cc dung dch sau
a.

0,02M HClO4; 1,2.10-9M HCl; 1,3.10-4M HNO3;

b.

NaOH 0,05M; NaOH 10-4M; NaOH 10-6M; Ba(OH)2 0,14M;

c.

HA c pKa=3, Ca= 10-1; 10-3; 10-5M;

d.

Cl3CCOOH pKa = 0,7 vi C=10-1M; 10-3M

e.

Cl2CHCOOH pKa= 1,3 vi C = 10-1M

f.

CH3COOH 10-2, pKa = 4,75;

g.

HCN 10-4M 10-4M, pKa = 9,13;

h.

HF 10-3M, pKa = 3,17;

i.

NaCN 10-2M, pKb = 9,72;

j.

NH4Cl pKb (NH3) = 4,75; C=0,1M

3. Tnh pH ca cc dung dch m sau:

a.

CH3COOH 0,1M + CH3COONa 0,1M

b.

CH3COOH 0,1M + CH3COONa 0,05M

c.

CH3COOH 0,05M + CH3COONa 0,1M

d.

CH3COOH 10-4 M + CH3COONa 10-4M

e.

CH3COOH 2,5.10-2 M + CH3COONa 7,5.10-2M

f.

e + 10-2M HCl

g.

e + 10-2M NaOH

4. Tnh pH ca dung dch Na3PO4 0,05M; Cho H3PO4 c pK1 = 2,12; pK2 =7,21;

pK3=12,36

Bi tp Ho Phn tch - Chng Chun axit baz

1. Chun 50ml dung dch HCl 0,1M bng NaOH c cng nng . Tnh pH ti cc thi
im V NaOH = 0,0; 5,0; 25,0; 49,5; 50; 50,5; 55,0ml.
2. Tnh bc nhy (chun thiu v tha 0,1%) khi chun 50ml dung dch NaOH bng
HCl c cng nng 0,01; 0,05M; 0,1M; 1M. Cho nhn xt bc nhy ph thuc vo
nng nh th no?
3. Tnh pH ti im tng ng v bc nhy pH (hiu s pH khi chun tha v thiu

0,2% lng axit) khi chun axit yu HA c nng 0,1M bng NaOH c cng nng
; cho pKa=3,0; 4,0; 5,0; 7,0; 9,0. Bc nhy ca ng chun axit yu HA ph thuc
vo pKa nh th no?
4. Cn dng cht ch th c pT trong khong pH no sai s mc phi khng qu 0,2%

trong qu trnh chun baz yu NH3 c pKb=4,75, v nng ln lt l 1,0; 0,5; 0,1;
0,05; 0,01M bng dung dch HCl c cng nng . Nhn xt s ph thuc bc nhy vo
nng baz.
5. Cn thm bao nhiu ml dung dch NaOH 0,1M vo 50ml dung dch CH 3COOH 0,2M

pH dung dch cui bng 4,0; 5,5; 7,0. Cho pKa ca axit acetic l 4,75.
6. Cn 1,25g axit yu HA, ha tan thnh 50ml dung dch. Dng dung dch chun NaOH
0,09M chun dung dch HA . Bit khi thm vo 8,24ml NaOH th pH=4,3 v khi
thm 41,2ml NaOH th t im tng ng
a.

Tnh khi lng phn t HA

b.

Tnh hng s axit HA (Ka)

c.

Tnh pH tng ng
7. 100ml hn hp HCl v H3PO4 c chun bng dung dch NaOH 0,2M. Th tch

NaOH tiu tn khi metyl v bromothymol xanh i mu ln lt l 25,0ml; v 35,0ml.

Tnh nng HCl v H3PO4?
8. 0,527g mu NaHCO3 v Na2CO3 c chun bng HCl 0,109M. Th tch HCl tiu tn

khi cht ch th phenolphthalein i mu l 15,7ml v khi cht ch th metyl da cam i

mu l 43,8ml. Tnh hm lng % ca NaHCO3 v Na2CO3 trong mu.

Bi tp Ho Phn tch - Chng Cn bng to phc

1. Tnh

Y(H)

ca H4Y cc gi tr pH 1;2;3;4;5;6;7;8;9;10;11;12. Cho H4Y c pK1=2,0;

pK2=2,67; pK3=6,16; pK4=10,26.

2. Tnh hng s bn iu kin ca phc MgY2- cc pH sau: 4,0; 8,0; 10,0. Bit logarit

hng s bn ca phc MgY2- l 8,9; Mg(OH)+ l 2,58. H4Y c pK1=2,0; pK2=2,67;

pK3=6,16; pK4=10,26.
3. Tnh hng s bn iu kin ca cc phc CaY2- v ZnY2- trong dung dch NH3 5M
c pH=12, bit rng nng ban u ca ion Ca2+ v Zn2+ khng ng k so vi nng
NH3. CaY2- v ZnY2- c hng s bn ln lt l 1010,57 v 1016,50. Cc phc Zn2+
vi NH3 c logarit hng s bn tng cng ln lt l 2,0; 4,4; 6,7; 8,7. Cc phc ca
Zn2+ vi OH- c logarit hng s bn tng cng ln lt l 4,4; 11,3; 13,1; v 14,7. Ion
Ca2+ thc t khng to phc vi NH3 v OH-.
4. Tnh nng cn bng ca cc ion Fe3+ v FeY- trong dung dch hn hp Fe3+ 10-2M

v Na2H2Y 10-2M c pH=2. ca FeY- l 1025,1.

5. Tnh nng cn bng ca cc ion Al3+ v AlY- trong dung dch hn hp Fe3+ 10-3M

v Na2H2Y 10-2M c pH=1,0; 3,0; 5,0. ca FeY- l 1016,3.

6. Tnh nng cn bng ca ion Mg2+ trong dung dch hn hp sau pH=10
a.

Mg2+ 10-2M + Na2H2Y 5.10-3M;

b.

Mg2+ 10-2M + Na2H2Y 9.10-3M;

c.

Mg2+ 10-2M + Na2H2Y 5.10-3M;

d.

Mg2+ 10-2M + Na2H2Y 1.10-2M;

e.

Mg2+ 10-2M + Na2H2Y 5.10-3M;

f.

Mg2+ 10-2M + Na2H2Y 1,1.10-2M;

g.

Mg2+ 10-2M + Na2H2Y 1,5.10-2M.

Bi tp Ho Phn tch - Chng Chun to phc

1. Tnh bc nhy khi chun 50ml dung dch Mn+ 0,01M bng EDTA c cng nng
pH=6,0. Nhn xt bc nhy ng cong chun ph thuc hng s bn ca phc
nh th no

Kim loi

Fe(III)

Hg(II)

Zn(II)

Fe(II)

Ca(II)

1,3.1025

6,3.1021

3,2.1016

2,1.1014

5,0.1012

2. Tnh bc nhy khi chun 50ml dung dch Zn2+ 0,05M bng EDTA 0,1M trong

dung dch pH=9, [NH3] = 0,1; 0,01 M. Cho ZnY2- = 3,2.1016. Nhn xt bc nhy
ng cong chun ph thuc nng phi t to phc ph nh th no
3. Tnh pSr v v ng cong chun khi thm 0, 10, 24, 25, 26, 30ml khi chun

50ml dung dch Sr2+ 0,01 M pH=11 bng EDTA 0,02M. Cho SrY2- =108,63
4. xc nh tinh khit ca CaCO3, ngi ta ha tan 0,3892g mu trong axit HCl.
Chnh pH n 10 dng dung dch m amoni. im tng ng t c khi th tch
EDTA tiu tn l 38,26ml. Tnh nng EDTA
5. xc nh hm lng canxi trong mu sa bt, tro ha 1,5g mu v sau chun
bng 12,1ml EDTA. Nng EDTA c xc nh bng dung dch Zn2+ (0,632g Zn ha
tan trong axit v nh mc n 1l), chun 10ml dung dch Zn2+ ny cn 10,8ml EDTA.
Tnh hm lng Ca trong mu sa theo ppm
6. Canxi trong huyt tng c xc nh bng phng php vi chun . 100 l mu

c x l vi 2 git NaOH, thm cht ch th v chun bng EDTA 0,00122M s

dng micro buret. Nu EDTA tiu tn l 0,203ml th hm lng Ca trong mu huyt
tng l bao nhiu g/ml

Bi tp Ho Phn tch - Chng Phn ng to kt ta

1. Trn 1,0 ml dung dch MgCl2 0,02M vi 1,0 ml dung dch hn hp NH 3 2M v NH4Cl

2M. C kt ta Mg(OH)2 xut hin khng? Bit TMg(OH)2= 10-10,9; NH4+ c pKa= 9,24.
2. Dung dch Fe2+ 0,01M v H+ 0,2M c bo ho H2S (0,1M) c kt ta xut hin

khng? Cho TFeS = 3,7.10-19, H2S c Ka1= 10-7; Ka2= 10-14. Nu nng H+ l 10-3M th c
kt ta xut hin khng?
3. Tnh nng H+ ti thiu cn thit lp dung dch CaCl2 0,02 M v K2C2O4 0,1 M

khng c kt ta xut hin. Bit TCaC2O4 = 1,78.10-9, H2C2O4 c pKa1=1,25 v pKa2 = 4,27.
4. Cho Kb 25C ca amoniac l 1,8.10-5.

(a) Hy tnh pH ca dung dch m c NH3 0,10 M v (NH4)2SO4 0,10M?

(b) Hy tnh tan ca Sn(OH)2 theo mol/L trong dung dch m trn, bit tan ca
Sn(OH)2 trong nc l 7,4.10-10 M?
5. Tnh tan ca Cu(OH)2 trong nc. Bit TCu(OH)2 = 10-19.
6. Tnh tan ca CaF2 v SrF2 trong cng mt dung dch. Cho TCaF2 = 3,4.10-11 v TSrF2=

2,9.10-9
7. Tnh [Ag+] trong dung dch bo ho Ag2CrO4 v Ag2C2O4. Cho TAg2CrO4 = 9.10-12 v

TAg2C2O4 = 6.10-12. B qua s thu phn ca cc anion gc axit.

8. C bao nhiu gam BaSO4 tan ra khi ra n bng:

(a) 250 ml nc ct.

(b) 250 ml dung dch c cha 0,825 gam (NH4)2SO4. Bit TBaSO4= 10-10.
9. Trn 50 mL dung dch bo ho PbI2 vi 10 ml dung dch KI 0,5M. Hy tnh nng

cn bng ca I- v Pb2+ trong dung dch thu c? Cho tch s tan ca PbI2 l 7,9 10-9.
10. (a) Tnh tan ca CaC2O4 trong nc ct. Cho TCaC2O4 = 1,3.10-8; Ka1= 5,6.10-2; Ka2=

5,4.10-5.
(b) Tnh pH ca dung dch thu c.
11. Tnh tan ca CuS trong nc bit T CuS = 6,3.10-36; H2S c pK1= 7; pK2= 12,9; hng

s bn tng cng ca cc phc ca Cu2+ vi OH- l

1017;

= 107;

1,2

= 1013,68;

1,3

=1018,5.

1,4

12. (a) Tnh tan ca Zn(OH)2 trong nc v pH ca dung dch thu c. Bit TZn(OH)2 =

2,1.10-16.
(b) Tnh tan ca Zn(OH)2 trong dung dch NaOH 0,1M. Bit

1,4

[Zn(OH)42-]=

2,8.1015.
13. (a) Tnh tan ca HgS trong nc 25oC. Bit THgS= 1,6.10-54; H2S c pK1 = 7 v

pK2 = 15.
(b) Tnh s ion Hg2+ v S2- trong 1L dung dch bo ho HgS 25oC. Bit NA= 6,02.1023.

Bi tp Ho Phn tch - Chng Chun kt ta to phc

1. Tnh bc nhy khi chun 100 mL cc dung dch NaCl, NaBr v NaI c nng

0,10M bng dung dch AgNO3 0,1M (bc nhy c coi l khong pAg khi chun
thiu v tha 0,1%). Cho TAgCl= 10-10; TAgBr= 10-12 v TAgI= 10-16.
2. Tnh bc nhy khi chun 100 mL cc dung dch NaI c nng ln lt l 0,10
M; 0,01M v 0,001M bng dung dch AgNO3 c cng nng (bc nhy c coi l
khong pAg khi chun thiu v tha 0,1%). Cho TAgI= 10-16.
3. Chun 50,00 mL dung dch Hg(NO 3)2 0,0246 M bng dung dch KSCN 0,104 M.
Tnh pHg ti cc thi im thm 0,25Ve, 0,5Ve, 0,75Ve, Ve, 1,05Ve v 1,25Ve (Ve l th
tch dung dch KCSN cn dng t ti im tng ng). Cho THg(SCN)2 = 2,8.10-20.
4. Tnh pAg trong qu trnh chun 10,0 mL dung dch hn hp NaI 0,025M v NaCl
0,025M bng dung dch AgNO3 0,025M ti cc th tch 5, 10, 15, 20 v 25 mL. Cho
TAgCl= 10-10 v TAgI = 10-16.
5. Tnh pSO4 trong qu trnh chun 100,0 mL dung dch hn hp Sr2+ 0,05M v Ra2+
0,05M bng dung dch SO42- 0,25M ti cc th tch 10; 19; 21; 30; 40 v 50 mL. Cho
TSrSO4 = 3,2.10-7 v TRaSO4 = 4,3.10-11.
6. Chun 10 ml dung dch NaBr 0,01 M bng dung dch AgNO3 0,01 M.
(a) Xc nh bc nhy ca ng cong chun . Cho sai s l 0,1%.
(b) Xc nh khong nng CrO42- trong dung dch ban u kt ta Ag2CrO4 xut
hin trong khong bc nhy.
Cho TAgBr = 6.10-13 v TAg2CrO4 = 1,1.10-12.
7. Lm bay hi 1,000 lt nc bin n gn cn ri x l bng lng d kali
tetraphenylboron. Lc, ra kt ta to thnh ri ho tan vo axeton. Tin hnh chun
bng phng php chun Mohr thy dng ht 34,32 mL dung dch AgNO3 0,03875 M.
K+ + NaB(C6H5)4 KB(C6H5)4 (r) + Na+
Ag+ + KB(C6H5)4 AgB(C6H5)4 (r) + K+
Hy tnh hm lng kali trong nc bin theo ppm.
8. Chun dung dch hn hp I-, Cl-, Br- v CrO42- u c nng l 0,1M bng dung
dch chun AgNO3. Hy cho bit th t cc anion b kt ta? Cho TAgI= 8,3.10-17, TAgCl=
1,8.10-10, TAgBr= 5,0.10-13 v TAg2CrO4 = 1,2.10-12.
9. Ho tan 1,00 gam mt mu phn ln vo nc, thm 20 ml dung dch AgNO3 0,2M
kt ta hon ton PO43- dng Ag3PO4. Chun lng Ag+ d thy ht 8,0 ml dung dch
KSCN 0,120M. Tnh % khi lng P2O5 trong mu phn bn trn.
10. Florua trong 250 mL mt mu nc ging khoan c kt ta hon ton di dng
PbClF. Lng clorua trong kt ta c xc nh bng phng php Volhard. Thm
10,00 mL AgNO3 0,0215 M ho tan hon ton PbClF v chun lng bc d vi ch
th Fe3+ thy ht 0,613 mL KSCN 0,0178 M. Hy tnh hm lng florua theo ppm trong
mu nc ging khoan.
11. (a) Thm 50,00 mL AgNO3 0,3650 M vo 30,00 mL dung dch I- cha bit nng .
Tin hnh lc b kt ta AgI, nc lc v nc ra c chun bng dung dch SCN0,2870 M vi ch th l Fe3+ thy ht 37,60 mL th dung dch bt u xut hin mu .
Hy tnh s mg I- c trong 30,00 mL mu ban u (I = 127)?
(b) Hy gii thch c ch i mu ca cht ch th diclofluorescein trong phng php
Fajans xc nh Cl- bng dung dch Ag+.

Bi tp Ho Phn tch - Chng OXH-KH

1.

Vit phng trnh trao i electron ca cc h oxi ho - kh lin hp sau:

(a) O2, H+ / H2O

(g) As, H+ / AsH3

(b) IO3-, H+ / I-

(h) MnO4-, H+ / MnO2, H2O

(c) MnO4-, H+ / Mn2+

(i) H2O2, H+ / H2O

(d) Cr2O72-, H+/ Cr3+

(k) AgCl / Ag

(l) CrO2-, H2O / Cr, OH-

(e) BrO3 , H2O/ HBrO, H2O

(f)

MnO2, H+ / Mn2+

(m) CrO42-, H2O / Cr(OH)3, OH-.

2. Hon thnh cc PTP sau:

(a) Sn2+ + Fe3+ ------- Sn4+ + Fe2+
(b) S2O32- + I2 --------- S4O62- + I-.
(c) PbO2 + Mn2+ + H+ ------- Pb2+ + MnO4- + H2O.
(d) CrO2- + H2O2 + OH- -------- CrO42- + H2O
(e) MnO4- + C2O42- + H+ ------- Mn2+ + CO2 + H2O.
(f)

As2S3 + NO3- + H+ -------- H3AsO4 + SO42- + NO2 + H2O

(g) Zn + NO3- + H+ --------

Zn 2++ N2O + H2O

(h) Zn + NO3- + H+ -------- Zn2+ + NH4+ + H2O .

3. Tnh th oxi ho kh tiu chun iu kin ca h Fe(III) / Fe(II) trong ung dch c d ion
F- to phc FF63- c hng s to phc tng cng B1,6 = 1016,1. Bit Eo ca h:
Fe3+ + 1e ------- Fe2+ Eo = + 0,77 V
4. Tnh th oxi ho - kh iu kin ca cp Cu(II) / Cu(I) trong dung dch c d NH3 to
cc ion phc Cu(NH3)42+ c B1,4 = 1012,0 v Cu(NH3)2+ c B1,2 = 1010,9. Bit Eo ca cc cp:
Cu2+ / Cu l + 0,337V v Cu+ / Cu l + 0,521 V.
5. Th oxi ho - kh tiu chun ca h I2 / I- l + 0,54 V ca h Cu2+ / Cu+ l 0,153 V. Gii
thch ti sao khi trong dung dch c d I- th Cu2+ vn oxi ho c I-. Bit tch s tan ca CuI
bng 1,1.10-12.
6. Tnh th oxi ho - kh ca dung dch hn hp:
(a) Ce4+ 0,01M + Fe2+ 0,1 M
(b) Ce4+ 0,1M + Fe2+ 0,1M
(c) Ce4+ 0,11M + Fe2+ 0,1M
Cho bit Eo ca h Ce4+ / Ce3+ l 1,44 V , ca h Be3+ / Fe2+ l 0, 68 V
7. Tnh th oxi ho - kh ca hn hp:
(a) MnO4- 0,02M + Fe2+ 0,1 M + H+ [H+] = 1M
(b) MnO4- 0,025 M + Fe2+ 0,1M + H+ [H+] = 1M
Cho Eo ca cc h MnO4-,H+/Mn2+ l 1,51 V ca h Fe3+ / Fe2+ l 0,77 V
Tnh t s [Fe3+] / [ Fe2+] trong c 3 trng hp (a) v (b).