1|P ag e

XI Chemistry
SECTION A (MCQs Multiple Choice Questions) NOTE: Attempt all questions from this Section. Q.1. Choose the correct answer for each from the given options. (17 Marks) i. When gaseous anions and cations are brought closer, the energy involved is (Electron affinity ,Lattice Energy ,Ionization Energy ,Electro Negativity ) ii. The molecules which 64gm SO contains are (1.02 x 10(23) ,2.04 x 10(23) ,3.06 x 10(23) ,6.02 x 10(23)) iii. Faraday s experiment indicates, the existence of (Electron ,Proton ,X-rays ,Positron) iv. The value of Kc is independent of (Initial Concentration of reactants ,Volume ,Catalyst ,Pressure) v. Cabon dioxide (CO ) molecule has zero dipole moment because its structure is (Linear ,Tetrahedron ,Angular ,Triangular) vi. The Molecular Mass of Na CO is (100 a.m.u ,102 a.m.u ,104 a.m.u ,106 a.m.u) vii. Bohr s model of atom is contradicted by (Rutherford s Atomic Model ,Heisenberg s Uncertainty Principle ,Pauli s exclusion Principle ,Plank s quantum Theory ) viii. The bond distance between Carbon-Carbon Single bond (C-C) is (1.54 A ,1.24 A ,1.34 A ,1.20 A) ix. The integar part of logarithm is called (Power ,Characteristic ,Mantissa ,Base) x. The bonds present in one molecule of ethane (C H ) are (Four Sigma two pi ,Two Sigma four pi ,Five Sigma one pi ,Five pi one Sigma) xi. If pH of a Solution is zero, the nature of solution will be (Acidic ,Neutral ,Basic ,Amphoteric) xii. Which of the compound has Sp(2) hybridization (NH ,C H ,C H ,H O) xiii. In hydrogen halides, which of the following possess the largest ionic character? (HF ,HI ,HCl ,HBr) xiv. Which atomic orbital is always involved in sigma bonding? (s-Orbital ,p-Orbital ,d-Orbital ,f-Orbital) xv. The colour of light depends upon its (Wave length ,Velocity ,Source ,None) xvi. The rate of diffusion of C H and CO are the same because (They are gases ,Both Contain Carbon ,Their Molecular Mass are same ,C H is an Organic Compound) xvii. The molecular formula of Vitamin C is C H O . Its empirical formula is (C H O ,C H O ,CH O ,CHO SECTION B (Short Answer Questions) Q.2. Answer any TEN questions from this Section. All questions carry equal marks. The answer to each questions should not exceed 6-8 lines. (40 Marks) i. Define the following terms Atomic Number ,Empirical Formula ,Molecular Formula ,Atomic Mass ,Significant Figures ,Mole,Extensive Properties ,Intensive Properties ,Avogadro s Number ,Limiting Reactant ,Molar Volume ii. Describe Rutherford s Atomic Model and state its defects.OR Write the postulates of Bohr s Atomic Theory.OR Derive an expression for the energy of an electron in nth orbit.OR Bohr s radius is 0.529A. Find the radius of 2nd orbit of hydrogen atom. iii. Define Ionic bond. Explain the formation of ionic bond with the example of Sodium Chloride and give its properties.OR What do you understand by the ionic character of a covalent bond with one example? PREPARED BY: SIR BABER RAFIQ CHISHTI

2|P ag e OR Define Coordinate Covalent bond and explain it with the formation of (NH ) iv. An organic compound producing air pollution contains 8.73% carbon 77.45% chlorine and 13.82% fluorine; find the molecular formula of the compound if its molecular mass is 137.5. (Atomic Masses: C = 12, Cl = 35.5, F = 19) OR A 500cm(3) vessel contains 2gm of He and 8gm of CH . What is the total pressure of the mixture of these gases at -3C. (Atomic Masses: He = 4, C = 12, H = 1) v. Give the main postulates of Kinetic Molecular Theory of Gases. OR State the following Gas Laws. Boyle s Law ,Charle s Law ,Graham s Law ,Dalton s Law of Partial Pressure ,Avogadro s Law vi. Write the electronic configuration for the ground state Na (Za = 11) and Mg (2) (Z = 12). OR Calculate the wave number of radiation emitted in Lyman series when electron jumps from 2nd to 1st orbit. vii. Give scientific reasons for the following a. The rates of diffusion of CO and C H gases are the same. b. FeSO .7H O and ZnSO . 7H O are isomorphous. c. Graphite is very soft where as diamond is very hard. d. The boiling point of a liquid remains constant although heat is continuously supplied to the liquid. e. A negative catalyst decreases the rate of reaction. f. A falling drop of a liquid is always spherical. g. Ionization potential of oxygen is smaller than that of Nitrogen. h. Evaporation is a cooling process. i. Honey is more viscous than water. j. Zinc dust when reacted with HCl produces hydrogen at a faster rate than a big piece of Zinc. viii. The equilibrium constant for the reaction N (g) + O (g) 2NO(g) at 2000C is the initial concentration of N and O are 10 moles/dm(3). OR Find the molarity of 0.5gm of NaOH in 250cm(3) of aqueous solution. OR The solubility of AgCl at 25C is 1.4 x 10(-3) gm/dm(3). What is its solubility product? OR 600J of heat was given to a gas at 1.01 x 10 N/m(2) pressure. The initial energy was increased by 300 J; find the increase in volume. ix. A 100 cm(3) gas cylinder filled with chlorine under 160 torr pressure is connected by stop-cock with another cylinder of 400 cm(3) filled with nitrogen under pressure of 200 torr. What will be the total pressure when stop cock is opened? OR Calculate the mass of ZnSO , the volume of H and the number of molecules of H which will be produced by reacting 163.5gm of Zn with H SO , at S.T.P. (Atomic Masses: Zn = 65.4, S = 32, O = 16, H = 1). x. Explain Evaporation in liquids and Deformity in solids in terms of the Kinetic Molecular Theory. OR Differentiate between Crytalline solids and amorphous Solids. OR Differentiate between Isomorphism and polymorphism. OR What is an Ideal gas? What are the cause of deviation of the real gases from the ideal behaviour? OR Determine the General Gas Equation from the gas laws. xi. What are Cathode Rays? How are they produced? Write down five properties of Cathode Rays along with their experimental proofs. OR What is the relationship between X-Rays and Atomic Number OR What is Radioactivity? Describe the experiment to distinguish the three types of radio active radiations. OR Write down five properties of each Alpha ( ), Beta ( ), Gamma ( ) rays. xii. In a reaction A + B 2C, 7 moles/dm(3) of B were mixed and allowed to attain equilibrium. If Kc = 2.25; find out the concentration of A, B and C at equilibrium. OR Will PbCrO precipitate from a solution mixing 200cm(3) of 2.5 x 10 M Pb(NO ) and 600cm(3) of 1.5 x 10 M K CrO ? xiii. State the First Law of Thermodynamics and Derive the Equations: a. H = E = P V b. Qp = H c. E = Qv OR State and explain Hess s Law of Constant Heat Summation. OR Give unit cell of a cubic or orthorhombic system. PREPARED BY: SIR BABER RAFIQ CHISHTI

3|P ag e xiv. What do you understand the term Hybridization? Discuss Sp(3), Sp(2) and Sp hybridization with examples. OR Draw the S-orbital and p-orbital. OR Write down the names of the spectral lines of hydrogen atom. OR Write down the values of all the four quantum numbers for each of the two electrons of helium atom. xv. Write short notes on following Viscosity ,Electron Affinity ,Common Ion Effect ,Neutralization ,Ionization Potential ,Hydrolysis Electronegativity ,Surface Tension ,Hydration ,Buffer Solution ,Vapour Pressure SECTION C (Detailed Answer Questions) (28 Marks) Q.3. (a) Write short notes on the following. Hydrogen Bonding ,pH ,Concentration of Solution and its Various Units ,Common Ion Effect Plank s Quantum Theory ,Molarity ,Arrhenius Theory of Ionization ,Heat of Formation Q.3. (b) Define Rate of Reaction, describe the methods to dormine the rate of reaction and also describe the factors on which the rate of reaction depends? OR Differentiate between the following. Neutral Radioactivity and Artificial Radioactivity ,Principal Quantum Number and Azimuthal Quantum Number ,Orbit and Orbital ,Line Spectrum and Continuous Spectrum ,Activation Energy and Threshold Energy ,Rate of Reaction and Rate Constant ,Positive Catalyst and Negative Catalyst Q.3. (c) Describe the following rules of electronic configuration. i. Pauli s Exclusion Principle,ii. Aufbau Principle,iii. (n + 1) Rule,iv. Hund s Rule of Maximum Multiplicity Q.4. (a) For the Chemical reaction F + 2CIO 2FCIO , Calculate the rate constant when initial concentration of F is 0.1 mol/dm(3), of ClO is 0.01 mol/dm(3) and the rate of reaction is 1.2 x 10(-3) mol/dm(3) sec. Q.4. (b) What do you understand by the term Electrode Potential? How is the Electrode Potential of Zinc and Copper discovered? OR Define solubility product and give its examples and applications. Q.4. (c) Write down the points of Electron Pair Repulsion Theory and Hybrid Orbital anode. Describe the shapes and structures of CH , BeCl , H O and NH on the basis of Electron Pair Repulsion Theory. Q.5. (a) What is Dipole Moment? Explain the shapes of CO and H O with the help of Dipole Moment. OR State Le-Chatlier s Principles. Apply the Principle on Haber s Process in terms of pressure and temperature for the maximum yield of NH . N (g) + 3H (g) 2NH (g) + Heat Q.5. (b) State the Law of Mass Action. Derive the equilibrium. Constant Kc for reaction nA + nB nC = yD. Apply the Law of Mass Action on Contact Process to derive its equilibrium expression. 2SO (g) + O (g) 2SO (g) Q.5. (c) Differentiate between the following. Sp(3) Hybridization and Sp(2) Hybridization Atomic Orbital and Molecular Orbital ,Valence Bond Theory and Molecular Orbital Theory ,Polar Covalent Bond and Non-Polar Covalent Bond ,Sigma Bond and Pi Bond ,Exothermic Reactions and Endothermic Reactions.

PREPARED BY: SIR BABER RAFIQ CHISHTI

4|P ag e XII Chemistry SECTION A (MCQs Multiple Choice Questions) Q.1. Choose the correct answers. (15 Marks) i. Ordinary hydrogen is unique in not having ________ (Neutron ,Proton ,Electron ,Atomic Number) ii. The Structure of hydrogen sulphide is ________ (Tetrahedra ,Dihedra ,Traihedra ,All) iii. Riboflayin is vitamin? (B B ,B ,B ) iv. Bakelite is a polymer of phenol and ________. (Ethenal ,Methanal,Beutail ,Vinyl chloride) v. A dipolar charge but an overall neutral-ion is called (Zwittetr ions ,Neo Pantane ,Picric Acid ,None of them) vi. The refractive index of diamond is (1.2 ,1.3 ,1.4 ,1.5) vii. Energy of tg orbitals in ________ than that of orbital (Smaller ,Larger ,Invisible ,None of them) viii. The angle between H-S-H is H S molecule is (92.2 ,102.3 ,89.3 ,72.4) ix. Graphite conduct electricity due to delocealized ________. (p electron ,a paetide ,b pontide ,g particle) x. The general formula of alkene is (CnH n ,CnH n ,CnH n ,CnH n xi. The general formula for aledehyde is (R -OH ,R-COOH ,RCOR ,R-CHO) xii. It is not a nucleophile (OH ,NH ,BF ,CN) xiii. This vitamin is water soluble (Vitamin A ,Vitamin C ,Vitamin D ,Vitamin K) xiv. The metal present in grignard s Reagant is (Mg ,Mn ,Fe ,Cu) SECTION B (Short Answer Questions) INORGANIC CHEMISTRY i. (a) State the modern Periodic Law and discuss the types of elements on the basis of electronic configuration.(b) Identify the groups and Periods of the elements having atomic numbers 11, 15 and 36. ii. Give the balanced equation. a).Chlorine is treated with concentrated solution of sodium hydroxide. b).Sodium hydroxide is added to ammonium chloride c).Litharage is heated with access oxygen d).Chlorine reacts with sulphur dioxide iii. (a) Give the chemical formula of the following Blue vitriol ,Epsom salt ,Water glass ,Red lead iii. (b) Name the following complexes by I.U.P.A.C system [Cr(NH ) Cl ]Cl,[Zn(OH )] iv. Write short note on any one of the following Lunar Caustic (AgNO ) ,Tin Plating v. Give reasons of the following. Boiling Point of Sulphuric acid is high y Sodium ion is smaller than Sodium atom PREPARED BY: SIR BABER RAFIQ CHISHTI

5|P ag e y The metallic character increases down the group y Water and ammonia molecules act as a ligends but H O and NH ions donor. y Explain the reducing action of hydrogen sulphide gas with the help of two chemical reactions. vii. What is plastic sulphur? Why does it show the Behaviour of elasticity? viii. Complete and balance the Equations. Zn + H SO 90%(conc) C H O + H SO (con) CrO + H S + H SO (conc) ORGANIC CHEMISTRY ix. (a) Define the following. Saponification ,Functional Group, Isomerism ix. (b) What is Fermentation? How is ethyl alcohol obtained from molasses? x. Explain how will you prepare following. y Carbolic Acid from Benzene y Acetaldehyde from acetylene y Acetal from formaldehyde xi. What are phenols? How are they classified? Explain why phenols are acedic in nature. xii. What are Organometallic compounds? How will you prepare the following from methyl magnesium bromide. y Vinegar y Isopropyl Alcohol y Ethane xiii. Draw the structures and give the I.U.P.A.C names of the following. Vinyl Chloride ,Neo-pentae ,Ter-butyl methyl ether ,Picric acid xiv. What product or products are formed when the following compound is nitrated. Bromo Benzene ,Nitro Benzene xv. What are detergents? Why are they better cleaning agents than soaps? xvi. What is methylated spirit? Give its composition. SECTION C (Detailed Question Answers) INORGANIC CHEMISTRY Q.3. (a) Describe manufacture of nitric acid by Ostwald s process. Q.3. (b) Write down the auto-oxidation reduction of Chlorine. Q.3. (c) Give the preparation and properties of Ionic Hydrides. Q.4. (a) Give the extraction of aluminium from bauxite ore containing ferric oxide as impurity. Q.4. (b) How is caustic soda obtained by castner kellener s process. Q.4. (c) Give composition uses of the alloys of aluminium. ORGANIC CHEMISTRY Q.5. (a) Why does benzene give electrophilic substitution reaction? Explain the mechanism of halogenations reaction in benzene. Q.5. (b) Give mechanism of chlorination of methane in the presence of Sunlight. Q.5. (c) What are Aldehyde and Ketone? Give one reaction with an equation equation to distinguish them. Q.6. (a) What is cannizaro s reaction? Show it by an equation. Q.6. (b) Draw and discuss the orbital structure of Ethane. Q.6. (c) What are homalogous series? Write down the formulae and names of the first five members of a homologous series.

PREPARED BY: SIR BABER RAFIQ CHISHTI

6|P ag e

PREPARED BY: SIR BABER RAFIQ CHISHTI