1.Nguyn t ca nguyn t X c in tch ht nhn bng +41,652.10-19 C; nguyn t ca nguyn t Y c khi lng bng 1,8.10-22 gam.

Xc nh X, Y v da trn cu hnh electron, hy cho bit (c gii thch) mc oxi ha bn nht ca X v Y trong hp cht. (a) Hy cho bit (c gii thch) theo thuyt lin kt ha tr th lu hunh (S) c th c cng ha tr bng bao nhiu? (b) Cho bit cu to n phn t v dng hnh hc ca hp cht vi hiro, oxit v hiroxit ca lu hunh tng ng vi cc gi tr cng ha tr xc nh cu (a). 2.Nng lng ion ha th nht (I1 - kJ/mol) ca cc nguyn t chu k 2 c gi tr (khng theo trt t) 1402, 1314, 520, 899, 2081, 801, 1086, 1681. Gn cc gi tr ny cho cc nguyn t tng ng. Gii thch 3.Tnh nhit hnh thnh ca ion clorua (Cl-) da trn cc d liu: o H 1 = 92,2 kJ/mol Nhit hnh thnh HCl (k): H o = 0 kJ/mol Nhit hnh thnh ion hidro (H+): 2 o + H 3 = 75,13 kJ/mol HCl (k) + aq H (aq) + Cl (aq) 4.Kh SO3 c tng hp trong cng nghip theo phn ng: H = -192,5 kJ SO2 (k) + 1/2O2 (k) SO3 (k) ngh cc bin php lm tng hiu sut qu trnh tng hp SO3. 5.Cho cn bng ha hc sau: N2O4 (k) 2NO2 (k) (1) Thc nghim cho bit khi lng mol phn t trung bnh ca hai kh trn 35oC bng 72,45 g/mol v 45oC bng 66,80 g/mol. (a) Tnh phn li ca N2O4 mi nhit trn? (b) Tnh hng s cn bng KP ca (1) mi nhit trn? Bit P = 1 atm (c) Cho bit theo chiu nghch, phn ng thu nhit hay ta nhit? 6.Sc kh clo qua dung dch kali iotua mt thi gian di, sau ngi ta cho h tinh bt vo th khng thy xut hin mu xanh. Hy gii thch v vit phng trnh ho hc minh ha. 7. nhn bit ion sunfit, ngi ta cho vo mt ng nghim 1 n 2 git dung dch iot, 3 n 4 git dung dch A c cha ion sunfit (1). Sau cho tip vo 2-3 git dung dch HCl v vi git dung dch BaCl 2 thy xut hin kt ta B (2). (a) Nu hin tng xy ra trong cc giai on 1, 2 ca th nghim v vit phng trnh ha hc minh ha. (b) Cho bit ti sao th nghim nhn bit ion sunfit nu trn thng c tin hnh trong mi trng axit hoc mi trng trung ha, khng c tin hnh trong mi trng baz? 8.Ha tan 8,4 gam kim loi M bng dung dch H2SO4 c nng d, hay ha tan 52,2 gam mui cacbonat kim loi ny cng trong dung dch H2SO4 c nng d, th lng kh sinh ra u lm mt mu cng mt lng brom trong dung dch. Vit cc phng trnh ho hc v xc nh kim loi M, cng thc phn t mui cacbonat. 9.Kali clorat c s dng trong cc ngnh sn xut dim, pho hoa v cht n. Trong cng nghip, kali clorat c iu ch bng cch cho kh clo i qua nc vi un nng, ri ly dung dch nng trn vi KCl v ngui cho kali clorat kt tinh (phng php 1). Kali clorat cn c iu ch bng cch in phn dung dch KCl 25% nhit 70 n 75oC (phng php 2). (a) Vit phng trnh ha hc xy ra trong mi phng php iu ch kali clorat. (b) Tnh khi lng kali clorua v in lng (theo A.gi) cn to ra 100g kali clorat theo phng php 2. 10.Trong cng nghip, brom c iu ch t nc bin theo quy trnh nh sau: Cho mt lng dung dch H2SO4 vo mt lng nc bin, tip theo sc kh clo vo dung dch mi thu c (1), sau dng khng kh li cun hi brom vo dung dch Na2CO3 ti bo ha brom (2). Cui cng cho H2SO4 vo dung dch bo ha brom (3), thu hi brom ri ha lng. a.Hy vit cc phng trnh ha hc chnh xy ra trong cc qu trnh (1), (2), (3). b.Nhn xt v mi quan h gia phn ng xy ra (2) v (3).
11. a, Cho m gam hn hp gm NaBr v NaI phn ng vi dung dch H2SO4 c, nng thu c hn hp kh A iu kin chun. iu kin thch hp, A phn ng va vi nhau to cht rn c mu vng v mt cht lng khng lm chuyn mu qu tm. Cho Na d vo phn cht lng c dung dch B. Dung dch B hp th va vi 2,24 lt CO2 iu kin tiu chun c 9,5 gam mui. Tm m.

b, ngh mt phng php tinh ch NaCl khan c ln cc mui khan NaBr, NaI, Na2CO3.

12.Cho kh Cl2 vo 100 ml dung dch NaI 0,2M (dung dch A). Sau , un si ui ht I2. Thm nc c tr li 100 ml (dung dch B). a, Bit th tch kh Cl2 dng l 0,1344 lt (ktc). Tnh nng mol/l ca mi mui trong dung dch B? b, Thm t t vo dung dch B mt dung dch AgNO3 0,05M. Tnh th tch dung dch AgNO3 dng, nu kt ta thu c c khi lng bng: (1) Trng hp 1: 1,41 gam kt ta. (2) Trng hp 2: 3,315 gam kt ta. Chp nhn rng AgI kt ta trc. Sau khi AgI kt ta ht, th mi n AgCl kt ta. c, Trong trng hp khi lng kt ta l 3,315 gam, tnh nng mol/l ca cc ion trong dung dch thu c sau phn ng vi AgNO3. 13.iu ch clo bng cch cho 100g MnO2 (cha 13% tp cht tr) tc dng vi lng d dung dch HCl m c. Cho ton b kh clo thu c vo m500ml dung dch c cha NaBr v NaI. Sau phn ng, c cn dung dch, thu c cht rn A (mui khan) c khi lng m gam. a, Xc nh thnh phn cht rn A nu m = 117gam b, Xc nh thnh phn cht rn A trong trng hp m = 137,6 gam. Bit rng trong trng hp ny, A gm hai mui khan. T l s mol NaI v NaBr phn ng vi Cl2 l 3: 2. Tnh nng mol ca NaBr v NaI trong dung dch u.Cc phn ng u hon ton.
14. Can bang cac phan ng sau theo phng phap thang bang ion electron: a) MnO4- + SO32- + . Mn2+ +SO42- + .. b) Cr2S3 + Mn(NO3)2 +Na2CO3 Na2CrO4 + Na2MnO4 +CO2 +NO +Na2SO4 15. Mot khoang vat X gom 2 nguyen to A ( kim loai), B( phi kim) .Khi ot X c chat ran Y la A2O3 va kh Z la BO2 , thanh phan phan tram khoi lng cua A trong Y la 70% va B trong Z chiem 50% .Y co the tac dung va u vi 1,8gam H2 , Z co the tac dung va u vi 117,6gam K2Cr2O7 trong moi trng H2SO4 d cho muoi Cr3+ .Hay xac nh ten khoang vat X va khoi lng X a b ot chay. 16.Hoa tan x gam 1 kim loai M trong 200gam ddHCl 7,3% (lng axit dung va u) thu c dung dch A trong o nong o cua muoi M tao thanh la 11,96% (theo khoi lng) a) Tnh x va xac nh kim loai b) Mot hp chat B cha M co so oxi hoa +4 ,hp chat nay co kha nang oxi hoa Br- thanh Br2 va Cl- thanh Cl2 .e B ch oxi hoa Br- thanh Br2 nen dung moi trng nao : H2SO4 loang hay am ac,giai thich s la chon tren,cho biet 4+ M2+ E0 = +1,23 V M + 2e , Br2 +2e 2 BrE0= +1,07 V 0 Cl2 + 2e 2Cl E =+1,36 V 17.Hoa tan 1,086gam muoi cha oxi cua clo vi 1 kim loai kiem vao nc ,axt hoa dung dch bang axit H2SO4 loang roi them t t dung dch KI vao cho en khi khong con I2 thoat ra th thu c 6,096gam I2 ,cung lng muoi tren em nhiet phan hoan toan sau phan ng con lai a gam muoi . Xac nh cong thc muoi va tnh a?.