Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM Toilet Cleaner S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236 24 Hour Transport & Medical Emergency Phone (866) 2315406 24 Hour International Emergency Phone (952) 852-4647

Use of the Substance/Mixture Company

: :

Emergency telephone

2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor Immediate Concerns : : blue green / Liquid absorbed by inert carrier material / pleasant Avoid contact with skin, eyes and clothing.

Potential Health Effects Exposure routes Eyes Skin Inhalation Ingestion

: : : : :

Eye, Skin, Inhalation, Ingestion. May irritate eyes. Prolonged or repeated contact may dry skin and cause irritation. None known. May cause: Abdominal discomfort. None known.

Aggravated Medical Condition

3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Non-woven pad Citric acid CAS-No. Weight percent 60.00 - 100.00 10.00 - 30.00 1/7

Mixture
77-92-9

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

Surfactants Sulfamic acid 4. FIRST AID MEASURES Eye contact

Mixture
5329-14-6

7.00 - 13.00 5.00 - 10.00

Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Wash off with soap and water. Get medical attention if irritation develops and persists. Remove to fresh air. Rinse mouth with water. Drink 1 or 2 glasses of water. Get medical attention immediately.

Skin contact

Inhalation Ingestion

: :

5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Alcohol foam, carbon dioxide, dry chemical, water fog

Further information Flash point Lower explosion limit Upper explosion limit

: : : :

Fight fire with normal precautions from a reasonable distance. Note: not applicable Note: no data available Note: no data available

6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up : Sweep up and shovel into suitable containers for disposal.

7. HANDLING AND STORAGE Handling Advice on safe handling : Do not use for personal hygiene or as a baby wipe. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. 2/7

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

Storage Requirements for storage areas and containers : Keep in a dry, cool and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Personal protective equipment Respiratory protection Industrial setting : No personal respiratory protective equipment normally required. No personal respiratory protective equipment normally required.

Household setting

Hand protection Industrial setting Household setting Eye protection Industrial setting : If prolonged or repeated contact is possible: Safety glasses with side-shields No special requirements. Wash thoroughly after handling. Use with adequate ventilation. : : For prolonged or repeated contact use protective gloves. not required under normal use

Household setting Hygiene measures

: :

9. PHYSICAL AND CHEMICAL PROPERTIES Form Color Odor : : : Liquid absorbed by inert carrier material blue green pleasant 3/7

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

pH Boiling point Freezing point Flash point Evaporation rate Autoignition temperature Lower explosion limit Upper explosion limit Vapour pressure Water solubility Partition coefficient: noctanol/water Viscosity, dynamic Volatile Organic Compounds (California Air Resource Board CARB) Total VOC (wt. %) 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous reactions

: : : : : : : : : : :

2.0 - 3.0 no data available no data available not applicable no data available not applicable no data available no data available no data available negligible

no data available : : no data available 0% - does not include any applicable regulatory exemptions

: : :

None known. Do not mix with bleach or any other household cleaners. Thermal decomposition can lead to release of irritating gases and vapours. Stable

11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 Calculated 4/7

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

> 5,000 mg/kg Acute inhalation toxicity Acute dermal toxicity : : no data available LD50 Calculated > 2,000 mg/kg

Chronic effects Carcinogenicity

no data available

Mutagenicity

no data available

Reproductive effects

no data available

Teratogenicity

no data available

12. ECOLOGICAL INFORMATION Ecotoxicity effects : no data available

13. DISPOSAL CONSIDERATIONS Industrial setting : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Dispose of in accordance with local regulations. Non-hazardous waste SNH: Solid Non-Hazardous

Household setting RCRA waste class SCJ product category

: : :

14. TRANSPORT INFORMATION Land transport

5/7

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

U.S. DOT and Canadian TDG Surface Transportation: UN-Number None. Proper shipping name not regulated None. Class: Packaging group None. Sea transport IMDG: UN-Number: Packaging group: Proper shipping name Class: None. None. not regulated None.

Air transport ICAO/IATA: Class: Packaging group: Proper shipping name UN/ID No.: None. None. not regulated None.

15. REGULATORY INFORMATION Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

Notification status

California Prop. 65

Canada Regulations

16. OTHER INFORMATION HMIS Ratings Health

2

6/7

Material Safety Data Sheet

according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

SCRUBBING BUBBLES FRESH BRUSH MAX TOILET CLEANING SYSTEM

Version 1.0 Revision Date 10/26/2009 Print Date 03/04/2011 MSDS Number 350000005721 SITE_FORM Number 30000000000000004989.001

Flammability Reactivity NFPA Ratings Health Fire Reactivity Special Further information

0 0

2
0

This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by:

SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)

7/7