THE ASSIGNMENT ABOUT ACID-BASE TITRATION

CREATED BY :

NAME

: ANDRE ANUSTA BARUS

ID NUMBER

: 4103332001

CLASS

: BILLINGUAL CHEMISTRY EDUCATION

SUBJECT

: ANALITICAL CHEMISTRY EDUCATION

PART 1
OH- =
H- =

(0.0200)
=

PH = -log 5

OH- =
H- =

= 12.30

(0.0200)
=

OH- =

= 12.24

(0.0200)
=

= 0.01540 M

PH = -log 5.68

OH- =

= 0.01760 M

PH = -log 5.68

H- =

= 0.0200 M

(0.0200)

= 12.18

= 0.01320 M

H- =

PH = -log 7.57

OH- =
H- =

= 12.12

(0.0200)
=

PH = -log 9.009

OH- =
H- =

= 12.04

(0.0200)
=

OH- =

= 11.95

(0.0200)
=

= 0.00909 M

PH = -log 1.111

H- =

= 0.01110 M

= 0.00714 M

PH = -log 1.40056

OH- =
H- =

(0.0200)
=

OH- =

= 11.77

(0.0200)
=

OH- =

= 0.00345 M

PH = -log 2.8985

H- =

= 0.00526 M

PH = -log 1.90114

H- =

= 11.85

= 11.53

(0.0200)
=

PH = -log 2.8985

= 0.00169 M

=
= 11.22

OH- =
H- =

(0.0200)
=

PH = -log 1.1904
OH- =
H- =

= 10.92

(0.0200)
=

OH- =

= 0.00017 M

PH = -log 5.8823

H- =

= 0.00084 M

= 10.22

(0.0200)
=

PH = -log 5

= 0.00004 M

=
= 9.22

PART 2
H20 H+ + OH(x)

(x)

Kw = x2

x = 1.0 x 10-7 M PH = -log 1.0 x10 -7

PART 3
[H+] = (0.100)

= 2 x 10 -5M

PH = - log [H+] = - log 2 x 10-5 = 4.78 M

[H+] = (0.100)

= 1.7 x 10 -4M

PH = - log [H+] = - log 1.7 x 10-4M = 3.78

[H+] = (0.100)

= 8.3 x 10 -4M

PH = - log [H+] = - log 8.3 x 10-4M = 3.08

[H+] = (0.100)

= 8.3 x 10 -4M

PH = - log [H+] = - log 8.3 x 10-4M = 3.08

[H+] = (0.100)

= 1.64x 10 -3M

PH = - log [H+] = - log 1.64 x 10-3M = 2.79

[H+] = (0.100)

= 3.23x 10 -3M

PH = - log [H+] = - log 3.23 x 10-3M = 2.49

[H+] = (0.100)

= 4.76x 10 -3M

PH = - log [H+] = - log 4.76 x 10-3M = 2.32

[H+] = (0.100)

= 6.25x 10 -3M

PH = - log [H+] = - log 6.25 x 10-3M = 2.20

[H+] = (0.100)

= 7.69x 10 -3M

PH = - log [H+] = - log 7.69 x 10-3M = 2.11

[H+] = (0.100)

= 9.09x 10 -3M

PH = - log [H+] = - log 9.09 x 10-3M = 2.04

TABLE
The position

The addition

The concentration of

The concentration of

in curve

volume of HBr

OH- doensnt react

excess H+

0.00

0.02000

12.30

1.00

0.01760

12.24

2.00

0.01540

12.18

3.00

0.01320

12.12

4.00

0.01110

12.04

5.00

0.00909

11.95

6.00

0.00714

11,85

7.00

0.00526

11.72

8.00

0.00345

11.53

9.00

0.00169

11.22

9.50

0.00084

10.92

9.90

0.00017

10.22

9.99

0.00002

9.22

10.00

7.00

10.01

0.00002

4.78

10.10

0.00017

3.78

10.50

0.00083

3.08

11.00

0.00164

2.79

12.00

0.00323

2.49

13.00

0.00476

2.32

14.00

0.00625

2.20

15.00

0.00769

2.11

Part I

Part II

Part III

pH

16.00

0.00909

B.TTRATION OF WEAK ACID WITH STRONG B ASE

PART 1

HA H+ + A- (Ka = 10-6.15)
(a-x)

(x)

(x)
= Ka x = 1.19 x 10-4

[H+] = 1.19 x 10-4

PH = -log 1.19 x 10-4 PH = 3.93

2.04

PART 2
HA + OH- A- + H2O
Initial
After Titration

(1)

: (

( )

(0)

(0)

( )

PH = pKa + log
= 6.15 +

= 4.87

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log
= 6.15 +

= 5.20

HA + OH- A- + H2O

Initial
After Titration

(1)

: (

(0)

(0)
( )

PH = pKa + log
= 6.15 +

= 5.55

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

( )

(0)

(0)

PH = pKa + log
= 6.15 +

= 5.78

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log
= 6.15 +

= 5.97

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log
= 6.15 +

= 6.15

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log

= 6.15 +

= 6.33

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log
= 6.15 +

= 6.52

HA + OH- A- + H2O
Initial
After Titration

(1)

: (

(0)

(0)
(

PH = pKa + log
= 6.15 +

A
HA

9 00
10
10
10

= 7.10

HA + OH- A- + H2O
Initial
After Titration

:
: (

(1)
05
10

9 50
10

(0)

(0)
(

9 50
10

PH = pKa + log

A
HA

9 50
10
05
10

= 6.15 +

= 7.43

HA + OH- A- + H2O
Initial
After Titration

:
: (

(1)
0 10
10

9 90
10

(0)

(0)
(

9 90
10

PH = pKa + log
= 6.15 +

A
HA

9 90
10
0 10
10

= 8.15

PART 3
A- + H2O HA + OH(a-x)
(x)
(x)
Kb =

HA + OH- A- + H2O
: (1)
(1)
(0)
: (0)
(0)
(1)

Initial
Chemical reaction
[A ] = 0.020
x2
a x

= Kb =

K
Ka

50 0
50 0 10 0

= 0.0167M

= 1.43 x 10 -8 x = 1.54

PH = - log [H ] = - log

- log

1 0 x 10 14
1 54 x 10 5

10 -5 M
= 9.18

PART 4
[OH ] = 0.100

50
50 0 10 10

PH = -log

K
OH

= 1.66 x 10 -4 M

= 10.22

[OH ] = 0.100

50
50 0 10 10

PH = -log
[OH ] = 0.100

K
OH

50 0 10 10
K
OH

50 0 10 10

OH

50 0 10 10
K
OH

= 1.66 x 10 -4 M

= 11.67

50

PH = -log

= 1.66 x 10 -4 M

= 11.50

50

= 1.66 x 10 -4 M

= 11.21

50

PH = -log
[OH ] = 0.100

= 10.91

50 0 10 10

PH = -log
[OH ] = 0.100

OH
50

PH = -log
[OH ] = 0.100

= 1.66 x 10 -4 M

= 1.66 x 10 -4 M

= 11.79

[OH ] = 0.100

50
50 0 10 10

PH = -log
[OH ] = 0.100

K
OH

= 11.88

50
50 0 10 10

PH = -log

K
OH

= 1.66 x 10 -4 M

= 1.66 x 10 -4 M

= 11.95
TABLE

The position

The addition volume of NaOH (ml)

pH

Part I

0.00

3.93

Part II

0.50

4.87

1.00

5.20

2.00

5.55

3.00

5.78

4.00

5.97

5.00

6.15

6.00

6.33

7.00

6.52

8.00

6.75

9.00

7.10

9.50

7.43

9.90

8.15

Part III

10.00

9.18

Part IV

10.10

10.22

10.50

10.91

11.00

11.21

12.00

11.50

13.00

11.67

14.00

11.79

15.00

11.88

16.00

11.95

C.TITRATION OF STRONG ACID WITH WEAK BASE

PART 1
B
+
(0.8364-x)

Kb =

x2

(x)
x2

a x 0 08364 x

1.69 x 10
x2

H2O

x2
0 08364 x

0 1410 x 10

x = 1.18 x x2

BH+ +
(x)

OH-

[OH ] = 1.18 x 10

POH = -log 1.18 x 10

= 4.93
PH = 14-4.93
= 9.07

PART 2

10 14

1 69 x 10 9

Ka = =

= 0.59 x 10

Amount of pyridine that titrated =

Amount of pyridine that titrated =
PH

PH

pKa + log
- log

K
K

+ log

0 50
19 60

=0.025

19 60 0 50
19 60

H
0 97
0 025

-log 0 59 x 10

5.23 + 1.58

+ log 38.80

0.97

= 6.81

10 14

1 69 x 10 9

Ka = =

= 0.59 x 10

Amount of pyridine that titrated =

Amount of pyridine that titrated =
PH

PH

pKa + log
- log

K
K

+ log

1 00
19 60

=0.05

19 60 1 00
19 60

0.94

H
0 94
0 05

-log 0 59 x 10

5.23 + 1.27

+ log 18.9

= 6.50
K

10 14

1 69 x 10 9

Ka = =

= 0.59 x 10

Amount of pyridine that titrated =

Amount of pyridine that titrated =
PH

pKa + log

2 00
19 60

=0.10

19 60 2 00
19 60

0.89

PH

- log

K
K

+ log

0 89
0 10

-log 0 59 x 10

5.23 + 0.95

+ log 8.9

= 6.18
K

10 14

1 69 x 10 9

Ka = =

= 0.59 x 10

Amount of pyridine that titrated =

Amount of pyridine that titrated =
PH

PH

pKa + log
- log

+ log

5.23 + 0.596

5.826

1 69 x 10 9

19 60 0 50
19 60

02

=0.20

0 79

-log 0 59 x 10

10 14

19 60

Ka = =

4 00

= 0.59 x 10

+ log 38.80

Amount of pyridine that titrated =

0 50
19 60

=0.25

0.79

Amount of pyridine that titrated =

PH

PH

pKa + log
- log

K
K

19 60 0 25
19 60

0.98

+ log

0 98
0 25

-log 0 59 x 10

5.23 + 0.593

5.823

+ log 3.92

PART 3
BH+

(a-x)
[A-]
Ka
x

(x)
= 0.08364(
=

x2
a x

x2
0 046 x

= 0.52 x 10-3

[H+]

=0.52 x 10-3

PH

= - log 0.52 x 10-3

H+
(x)

) = 0.08364 x 0.56 = 0.046 M

= 3.27

PART 4
[H+]

= (0.1067) (

=1.18 x 10-3 M
PH

= -log 1.18 x 10-3 M

= 2.93

[H+]

= (0.1067) (

=2.10 x 10-3 M
PH

= -log 2.10 x 10-3 M

= 2.67

[H+]

= (0.1067) (
=3.24 x 10-3 M

PH

= -log 3.24 x 10-3 M

= 2.5

[H+]

= (0.1067) (

=4.50 x 10-3 M
= -log 4.50 x 10-3 M

PH

= 2.346
[H+]

= (0.1067) (

=6.66 x10-3 M
= -log6.66 x10-3 M

PH

= 2.17
[H+]

= (0.1067) (

=0.01067M
PH

= -log0.01067M
= 1.9
TABLE

The position

The addition volume of NaOH (ml)

pH

Part I

0.00

9.07

Part II

0.50

6.80

1.00

6.50

2.00

6.18

4.00

5.826

5.00

5.823

Part III

19.60

3.27

Part IV

20.10

2.93

20.50

2.67

21.00

2.5

22.00

2.346

23.00

2.17

25.00

1.9

4.TITRATION OF ACID OR BASE WITH DIFFERENT

STRENGTH

PART 1
B

BH+

H2O

(0.10-x)
Kb=

OH-

(x)

(x)

OH

By substitution we got
[OH-] = 3.11 x 10-3 M

x
0 10 x

= 3 11 x 10

POH = - log 3.11 x 10-3

= 2.507
PH = 14 2.507 = 11.49
Or directly by using formula
[H+] =

PH = 11.49

PART 2
PH

PH

pKa2 + log
=

10.0 + log

11.00

pKa2 + log
=

10.0 + log

10.75

H
9
1

H
85
15

PH

PH

PH

PH

PH

pKa2 + log
=

10.0 + log

10.60

pKa2 + log
=

10.0 + log

10.37

pKa2 + log
=

10.0 + log

10.18

pKa2 + log
=

10.0 + log

10.00

pKa2 + log
=

10.0 + log

H
8
2

H
7
3

H
6
4

H
5
5

H
4
6

=
PH

PH

PH

PH

PH

pKa2 + log
=

10.0 + log

9.63

pKa2 + log
=

10.0 + log

9.40

pKa2 + log
=

10.0 + log

9.05

9.82

pKa2 + log
=

10.0 + log

8.72
pKa2 + log

H
3
7

H
2
8

H
1
9

H
05
19 5

10.0 + log

8.00

01
99

PART 3
[H+] =
Where Ka1 and Ka2 are disosiation constant of acid
BH22+.The concentration of BH+ (C) is determined by the
initial concentration of B solution :
C = (0.1 M) (

) = 0.050 M

Wet got..
[H ] =

)(
(

) (
)

= 3.16 x 10-8M
pH = - log 3.16 x 10-8
= 7.50

)(

In this case, pH =

PART 4

pH

= pKa + log
= 5.0 + log
= 6.995
= 7.00

pH

= pKa + log
= 5.0 + log
= 6.278
= 6.28

pH

= pKa + log
= 5.0 + log
= 5.95

pH

= pKa + log
= 5.0 + log
= 5.6

pH

= pKa + log
= 5.0 + log
= 5.37

pH

= pKa + log
= 5.0 + log

= 5.18

pH

= pKa + log
= 5.0 + log
= 5.0

pH

= pKa + log
= 5.0 + log
= 4.82

pH

= pKa + log
= 5.0 + log
= 4.63

pH

= pKa + log
= 5.0 + log
= 4.40

pH

= pKa + log
= 5.0 + log
= 4.05

pH

= pKa + log
= 5.0 + log
= 3.72

PART 5
C = (0.10 M ) (

) = 0.0333 M

The pH of solution is determined by the disosiation

reaction of BH22+
BH2+2

BH+ +

H+

(C-x)

(x)

(x)

Ka1 =
= 1.0 x 10-5
x = 5.72 x 10-4
[H+] = 5.72 x 10-4 M
pH = - log 5.72 x 10-4
= 3.24

PART 6
[H+] = (0.10 M) (
pH

) = 3.22 x 10-4

= - log 3.22 x 10-4

= 2.49

[H+]= (0.10 M) (
pH

) = 6.25 x 10-3

= - log 6.25 x 10-3

= 2.20

[H+]= (0.10 M) (
pH

) = 9.09 x 10-3

= - log 9.09 x 10-3

= 2.04

[H+]= (0.10 M) (
pH

) = 1.18 x 10-2

= - log 1.18 x 10-2

= 1.92

[H+]= (0.10 M) (
pH

) = 1.43 x 10-2 M

= - log 1.43 x 102= 1.85

TABLE

Part

The addition volume of HCl

pH

Part I

11.49

11.00

1.5

10.75

10.60

10.37

10.18

10.00

9.82

9.63

9.40

9.05

9.5

8.72

9.9

8.00

10

7.50

10.1

7.0

10.5

6.28

11

5.95

12

5.6

13

5.37

Part II

Part III

Part IV

Part V

Part VI

14

5.18

15

5.00

16

4.82

17

4.63

18

4.40

19

4.05

19.5

3.72

20

3.24

21

2.49

22

2.20

23

2.04

24

1.92

25

1.85