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b gio dc v o to

thi tuyn sinh i hc, cao ng nm 2004

Mn thi: Ha hc, Khi A

-------------------------

CHNH THC

Thi gian lm bi: 180 pht, khng k thi gian pht

-----------------------------------------

Cu I (1,5 im)
1. Hon thnh cc phng trnh phn ng sau di dng phn t v ion rt gn (nu c):
FeS
Kh A + ...
HCl
to, xt
KClO3
Kh B + ...
Na2SO3 + HCl
Kh C + ...
2. Cho cc kh A, B, C tc dng vi nhau tng i mt, vit phng trnh phn ng v ghi r iu kin.
Cu II (1,5 im)
1. Vit cc phng trnh phn ng theo s bin ha sau (cc cht hu c vit di dng cng thc cu to):
A1

Br2, Fe

A2

dd HCl

A5

dd HCl

A4

Toluen
Br2, askt

dd NaOH c, d, to cao, p cao

A7

dd NaOH c, d, t cao, p cao

o

dd NaOH, t

A8

CuO, t

A3
A6
o

A9

Ag2O/NH3, t

A10

Bit A1, A4, A7 l cc cht ng phn c cng thc phn t C7H7Br.

2. Cht hu c B l ng phn ca A3 c cha vng benzen. B khng phn ng c vi kim loi kim. Xc nh
cng thc cu to ca B.
Cu III (1,5 im)
1. Cho st tc dng vi dung dch axit clohiric thu c kh X. Nhit phn kali nitrat c kh Y. Kh Z thu
c t phn ng ca axit clohiric c vi kali pemanganat. Xc nh cc kh X, Y, Z v vit cc phng
trnh phn ng.
2. Cho 40 ml dung dch HCl 0,75 M vo 160 ml dung dch cha ng thi Ba(OH)2 0,08M v KOH 0,04M. Tnh
pH ca dung dch thu c. Cho bit [H+] [OH] = 1014.
Cu IV (1,5 im)
1. Trong cc cht: Ru etylic, phenol v axit axetic, cht no c phn ng vi Na, vi dung dch NaOH, v vi
CaCO3? Vit cc phng trnh phn ng xy ra.
2. a) T axit metacrylic (CH2=C(CH3)COOH) v ru metylic, vit cc phng trnh phn ng iu ch
polimetyl metacrylat.
b) iu ch c 120 kg polimetyl metacrylat cn bao nhiu kg ru v axit tng ng? Bit hiu sut ca
c qu trnh l 75%.
Cu V (2,0 im)
Hn hp A gm FeCO3 v FeS2. A tc dng vi dung dch axit HNO3 63% (khi lng ring 1,44 g/ml) theo
cc phn ng sau:
FeCO3 + HNO3 mui X + CO2 + NO2 + H2O
(1)
(2)
FeS2 + HNO3 mui X + H2SO4 + NO2 + H2O
c hn hp kh B v dung dch C. T khi ca B i vi oxi bng 1,425. phn ng va ht vi cc cht trong
dung dch C cn dng 540 ml dung dch Ba(OH)2 0,2M. Lc ly kt ta, em nung n khi lng khng i, c
7,568 gam cht rn (BaSO4 coi nh khng b nhit phn). Cc phn ng xy ra hon ton.
1. X l mui g? Hon thnh cc phng trnh phn ng (1) v (2).
2. Tnh khi lng tng cht trong hn hp A.
3. Xc nh th tch dung dch HNO3 dng (gi thit HNO3 khng b bay hi trong qu trnh phn ng).
Cu VI ( 2,0 im )
Hn hp kh X gm 2 anken k tip nhau trong dy ng ng. t chy hon ton 5 lt hn hp X cn va
18 lt kh oxi (cc th tch kh o cng iu kin nhit , p sut).
1. Xc nh cng thc phn t ca 2 anken.
2. Hirat ha hon ton mt th tch X vi iu kin thch hp thu c hn hp ru Y, trong t l v khi
lng cc ru bc mt so vi ru bc hai l 28:15.
a) Xc nh % khi lng mi ru trong hn hp ru Y.
b) Cho hn hp ru Y th hi qua CuO un nng, nhng ru no b oxi ha thnh anehit? Vit phng
trnh phn ng.
Cho H = 1, C = 12, N = 14, O = 16, S = 32, Fe = 56, Ba = 137.

----------------------------------------------------------------------Cn b coi thi khng gii thch g thm.

H v tn th sinh:.............................................................. S bo danh:................................

b gio dc v o to
------------------ CHNH THC

P N - thang im
thi tuyn sinh i hc, cao ng nm 2004
Mn : Ha hc, Khi A
----------------------------------------(p n - Thang im c 5 trang)

Cu

Ni dung

im
1,50

I
1.

Hon thnh cc phn ng di dng phn t v ion rt gn : (0,75 im)

FeS
FeCl2 + H2S
2HCl
Fe2+ + H2S
FeS
2H +

to, xt

2KClO3

2KCl +

Na2SO3 + 2HCl
SO32

2.

3O2

0,25

2NaCl + H2O

SO2

+ 2H

H2O + SO2
Cho cc kh A (H2S), B (O2), C (SO2) tc dng vi nhau: ( 0,75 im)
A tc dng vi B:
to
2 H2O + 2 SO2
2 H2S + 3 O2
hoc khi oxi ho chm:
2 H2S + O2 = 2 H2O + 2 S
A tc dng vi C:
2 H2S + SO2 = 2 H2O + 3 S
B tc dng vi C:
V2O5, 400oC
2 SO2
O2
2 SO3

II
1.

0,25

0,25

0,25
0,25

0,25
1,50

Cc phng trnh phn ng xy ra theo s bin ha: (1,25 im)

1)

CH3 + Br2

2) Br

CH3 + 2NaOH

3) NaO

CH3 + HCl

4)

CH3 + Br2

Fe

to cao, p cao

CH3 + HBr
(A1)

Br

NaO

HO
Fe

CH3 + NaBr + H2O

(A2)

0,25

CH3 + NaCl
(A3)
CH3 + HBr
(A4)
Br

0,25

CH3 + 2NaOH

5)

to cao, p cao

CH3 + NaBr + H2O

(A5)
ONa

Br
6)

CH3

CH3 + NaCl
(A6)
OH

+ HCl

ONa

0,25

askt

7)

CH3

8)

CH2Br + NaOH

+ Br2

CH2Br +
(A7)

9)

CH2OH + CuO

10)

CHO + Ag2O

to

CH2OH
(A8)

to

HBr

+ NaBr

0,25

CHO + Cu
(A9)

NH3
to

COOH
(A10)

+ H2O

+ 2Ag

0,25
2.

Xc nh cng thc cu to ca B: (0,25 im)

Cng thc cu to ca B l:
O

0,25

CH3

1,50

III
1.

Cc phng trnh phn ng: (0,75 im)

X: H2
Fe
+ 2HCl
=
FeCl2 + H2
Y: O2
to
2 KNO2 + O2
2 KNO3

Z: Cl2

2.

2KMnO4 + 16HCl = 2KCl + 2MnCl2 + 5Cl2 + 8H2O

Tnh pH: (0,75 im)

S mol H+ = 0,04 0,75 = 0,03 mol

S mol OH = 0,16 (0,08 2 + 0,04) = 0,032 mol

Phn ng trung ha:

H+
+
0,03 mol

OH
=
0,03 mol

0,25

0,25

0,25

H2O

Vy s mol OH d = (0,032 0,03) mol = 0,002 mol

0,002
= 0,01 mol/l = 102 mol/l.
[OH ] =
0,04 + 0,16
10 14
[H+] =
= 1012 mol/l
pH = 12
10 2
2

0,25

0,25
0,25

1,50

IV
1.

2.

Phn ng ca C2H5OH , C6H5OH, CH3COOH : (0,75 im)

Vi Na:
2C2H5OH
+
2Na
2C2H5ONa
+
H2
2C6H5OH(nng chy) + 2Na
2C6H5ONa
+
H2
2CH3COOH +
2Na
2CH3COONa +
H2
Vi dung dch NaOH:
C6H5OH
+
NaOH
C6H5ONa
+
H2O
CH3COOH + NaOH
CH3COONa +
H2O
Vi CaCO3:
2CH3COOH + CaCO3 (CH3COO)2Ca + H2O + CO2

0,25

0,25
0,25

iu ch polimetyl metacrylat v tnh khi lng axit, ru: (0,75 im)

a) iu ch polimetyl metacrylat
CH3
CH2

CH3

H2SO4 (c), to

COOH

CH2

CH3OH

CH3
n CH2

to
xt

C
COOCH3

COOCH3

H2O

0,25

CH3
CH2

n
COOCH3
Polimetyl metacrylat

0,25

b) Theo cc phng trnh phn ng trn:

c
86 (g) axit
phn ng vi 32 (g) ru cho 100 (g) este
x (kg) axit
phn ng vi y (kg) ru 120 (kg) este
86 120
32 120

x=
= 103,2( kg)
;
y=
= 38,4( kg)
100
100
Do hiu sut 75% nn cn:

103,2 100
= 137,6( kg)
75
38,4 100
= 51,2( kg)
75

axit metacrylic
ru metylic

0,25
2,00

V
1.

Cc phng trnh phn ng ( X l Fe(NO3)3): ( 0,5 im)

FeCO3 + 4HNO3 = Fe(NO3)3 + CO2 + NO2 + 2H2O
x
FeS2
y

4x
+ 18HNO3
18y

x
=

(1)

0,25

Fe(NO3)3 + 2H2SO4 + 15NO2 + 7H2O (2)

y

2y

15y

0,25
2.

Dung dch C [HNO3 c th d: z mol; H2SO4: 2y mol; Fe(NO3)3 : (x + y) mol] +

Ba(OH)2 : (1,00 im)
2HNO3 + Ba(OH)2 = Ba(NO3)2 + 2H2O
(3)
z
z/2
H2SO4
+ Ba(OH)2 = BaSO4 + 2H2O
(4)
2y
2y
2y

0,25

2Fe(NO3)3 + 3Ba(OH)2 = 2Fe(OH)3 + 3Ba(NO3)2

x+y
3(x + y)/2
x+y
Nung kt ta :
to
2 Fe(OH)3
Fe2O3 + 3 H2O
x+y
(x + y)/2
(BaSO4 khng b nhit phn).

(5)

(6)

0,25

Theo cc phn ng (1), (2), hn hp kh B [x mol CO2 v (x + 15y) mol NO2]

44x + 46(x + 15y)
d B / O2 =
= 1,425
x = 5y (7)
(2x + 15y)32
Theo cc phn ng (4), (5), (6):
Khi lng cht rn

= khi lng Fe2O3 + khi lng BaSO4

1
= (x + y)160 + 2y 233 = 7,568
2

80x + 546y = 7,568

(8)

0,25

Gii cc phng trnh (7), (8) c:

x = 0,04

3.

y = 0,008

Khi lng cc cht trong hn hp A:

0,04 116 = 4,64 (g)
FeCO3 :
0,008 120 = 0,96 (g)
FeS2 :
Th tch dung dch HNO3: (0,50 im)
Theo cc phn ng (3), (4), (5):
z
3
540 0,2
S mol Ba(OH)2 = + 2y + (x + y) =
= 0,108
2
2
1000

3x + 7y + z = 0,216
(9)
Thay gi tr ca x v y thu c trn vo (9) c z = 0,04

S mol HNO3 = 4x +18y +z = 4 0,04 +18 0,008 + 0,04 = 0,344 (mol)

0,344 63
100 = 34,4 (g)
Khi lng dung dch HNO3 =
63
34,4
Th tch dung dch HNO3 =
23,89 (ml)
1,44

0,25

0,25

0,25
2,00

VI
1.

Tm cng thc phn t ca 2 anken: (0,50 im)

t cng thc chung ca 2 anken l CnH2n (n l s nguyn t cacbon
trung bnh ca hai anken, n > 2). t hn hp hai anken:

2CnH2n + 3nO2
2 mol
3n mol
5 lt
18 lt

2nCO2 +

2nH2O (1)
0,25

i vi cht kh t l th tch cng l t l s mol nn c t l:

2 3n

n = 2,4
=
5 18
Anken duy nht c s nguyn t cacbon < 2,4 l C2H4 v anken k tip l C3H6
2.

a. Phn trm khi lng mi ru trong Y: (1,25 im)

CH2 = CH2
+ HOH
CH3CH2OH
(2)
CH3CH = CH2 + HOH
CH3CH(OH)CH3 (3)
CH3CH = CH2 + HOH
CH3CH2CH2OH (4)
Gi s c 1 mol hn hp X em hirat ha, trong c b mol C3H6 v (1 b)
mol C2H4:
3b + 2(1 b) = 2,4
b = 0,4 mol C3H6 v 1 b = 0,6 mol C2H4

0,25

0,25

0,25

Theo cc phn ng (2), (3), (4): s mol H2O = s mol anken = 1 (mol)
Theo nh lut bo ton khi lng ta c:
Khi lng hn hp ru Y = khi lng hn hp anken X + khi lng nc
= 0,4 42 + 0,6 28 + 1 18 = 51,6 (g)
Theo bi, t l khi lng ca ru bc mt so vi ru bc hai l 28:15.
Vy phn trm khi lng mi ru l:
15
%i-C3H7OH =
100 = 34,88 (%)
28 + 15
0,6 46
%C2H5OH =
100 = 53,49 (%)
51,6
%n-C3H7OH = 100 34,88 53,49 = 11,63 (%)
b. Ru b oxi ha cho sn phm anehit l ru bc mt: (0,25 im)
CH3CH2OH

CuO

to

CH3CHO

Cu

H2O

CH3CH2CHO

Cu

H2O

CH3CH2CH2OH

CuO

0,25

0,25

0,25

0,25