Giao An Tu Chon 11

Tit 1:
BI TP N TP
I. Mc tiu:
Rn luyn k nng gii bi tp v nguyn t, cn bng phn ng oxi ho kh,
tnh phn trm khi lng.
II. Trng tm:
Nguyn t, cn bng phn ng, % khi lng.
III. Chun b:
Gio n, hc sinh n li kin thc hc lp 10
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
3/ Bi mi
Hot ng ca thy v tr
Hot ng 1:
GV: Chp ln bng, GV yu cu
HS tho lun theo bn, GV gi 1 HS
ln trnh by.
HS: Ln bng trnh by
Hot ng 2:
GV: Chp ln bng
Ni dung
Bi 1:
Nguyn t ca nguyn t X c tng s ht
p, n v e bng 40, tng s ht mang in
nhiu hn tng s ht khng mang in l
12. Xc nh Z, A v vit cu hnh e ca
nguyn t X, cho bit v tr nguyn t X
trong BTH
Gii:
Ta c: p + n + e = 40
M p = e = Z
2p + n = 40 (1)
Theo bi rat ta c 2p n = 12 (2)
T (1) v (2) ta c: p = Z =13, n = 14
A = Z + n = 13 + 14 = 27
Cu hnh electron ca nguyn t X l:
1s22s22p63s23p1
- th 13
- Chu k 3
- Nhm chnh nhm IIIA
Bi 2:
Cn bng cc phng trnh sau y bng
phng php cn bng phn ng oxi ho
kh.
Al + HNO3 Al(NO3)3 + NO + H2O
t
Fe + H2SO4 ()
Fe2(SO4)3 + SO2 + H2O
Gii:
0
+5
+3
+2
GV: yu cu 2 HS ln trnh by, cc Al + HNO3 Al(NO3)3 + NO + H2O

em cn li lm vo v nhp v quan
+3
0
st
1x Al Al + 3e
HS: Ln bng trnh by
+2
+5
1x N + 3e
N
Al + 4HNO3 Al(NO3)3 + NO + 2H2O
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+6
+3
+4
t
Fe + H2SO4 ()
Fe2(SO4)3 + SO2 + H2O
GV: Nhc li 4 bc lp phng trnh

phn ng oxi ho kh cng HS kim
ta li bi lm ca cc bn trn bng
+3
3 Fe Fe + 3e
+4
+6
2 S + 2e S
t
2Fe + 6H2SO4 ()
Fe2(SO4)3 +3SO2 + 6H2O
Bi 3:
Cho 1,5 gam hn hp gm Nhm v Magi
vo dd HCl c nng 1 mol/l ngi ta thu
Hot ng 3:
c 1,68 lt kh ( ktc)
GV: Chp ln bng
a/ Tnh % khi lng mi kim loi.
b/ Th tch axit dung.
Gii:
HS: Hc sinh quan st v suy ngh
2Al + 6HCl
2AlCl3 + 3H2
cch lm bi.
x
3x
3/2x
Mg + 2HCl MgCl2 + H2
y
2y
y
Gi x, y ln lt l s mol ca Al, Mg
GV: Yu cu HS ln trnh by
Ta c:
27x + 24y = 1,5
x = 1/30
3/2x + y = 0,075
y = 0,025
GV: Gi HS nhn xt
% Mg =
0,025.24
.100 = 40%
1,5
% Al = 60 %
n HCl = 3x + 2 y = 3.
V =
1
+ 2.0,025 = 0,15(mol )
30
n
0,15
=
= 0,15(l )
CM
1
Hot ng 4: Cng c - dn d
- Cn bng phng trnh sau y bng phng php cn bng phn ng oxi ho
kh.
Al + HNO3 Al(NO3)3 + N2 + H2O
FexOy + HNO3 Fe(NO3)3 + NO + H2O
- BTVN: Ho tan hon ton 1,12 g kim loi ho tr II vo dd HCl thu c 0,448 lt kh
ktc. Kim loi cho l:
A. Mg
B. Zn
C.Cu
D. Fe
- Chun b bi in li sgk 11
Tit 2:
BI TP S IN LI AXIT, BAZ V MUI
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I. Mc tiu:
Vit phng trnh in li, phn bit c cht in li mnh, yu; gii thch
c tnh axit, baz, theo thuyt Arniut, hiroxit lng tnh.
II. Trng tm:
S in li, axit, baz v hiroxit lng tnh.
III. Chun b:
GV:Gio n
HS: n tp l thuyt cc bi trc
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
- Trnh by nh ngha Axit, baz theo thuyt Arniut . Cho v d
- Trnh by nh ngha hiroxit lng tnh. Vit phng trnh chng minh
Sn(OH)2 l hiroxit lng tnh.
3/ Bi mi
Hot ng ca thy v tr
Hot ng 1:
GV: Chp ln bng, yu cu HS
chp vo v.
Bi 1:
Vit phng trnh in li ca cc
cht trong dd sau: HBrO4, CuSO4,
Ba(NO3)2, HClO, HCN. Cho bit cht
no l cht in li mnh, cht no l
cht in li yu.
HS: Chp
GV: Yu cu 1 HS ln bng gii, cc
HS cn li lm nhp v theo di bi
bn lm.
GV: Yu cu 1 HS nhn xt, GV
nhn xt ghi im.
Ni dung
Bi 1:
Vit phng trnh in li ca cc cht trong
dd sau: HBrO4, CuSO4, Ba(NO3)2, HClO,
HCN. Cho bit cht no l cht in li mnh,
cht no l cht in li yu.
Gii:
HBrO4 H+ + BrO4CuSO4 Cu2+ + SO 24
Ba(NO3)2 Ba2+ + 2NO 3

HClO H+ + ClOHCN H+ + CNHBrO4, CuSO4, Ba(NO3)2 l cht in li mnh.
HClO, HCN l cht in li yu.
Bi 2:
Vit phng trnh in li ca hiroxit lng
tnh Al(OH)3.
Hot ng 2:
chp vo v.
Bi 2:
Vit phng trnh in li ca hiroxit
Gii:
lng tnh Al(OH)3.
HS: Chp
Al(OH)3 Al3+ + 3OHGV: Yu cu HS suy ngh 3 pht,
+
Al(OH)
3 H3O + AlO 2
sau gi 1 HS ln bng gii. GV
quan st cc HS lm bi.
GV: Nhn xt, hng dn li
Bi 3:
Vit phng trnh phn ng xy ra khi cho
Hot ng 3:
H:01:25H:01:25H:01:25

chp vo v.
Bi 3:
Vit phng trnh phn ng xy ra
khi cho Al2(SO4)3 tc dng vi NaOH
d.
HS: Chp
GV: Yu cu HS suy ngh , sau
gi 1 HS ln bng gii. Cc HS cn
li ly nhp ra lm bi v theo di
bi bn lm.
HS: Ln bng trnh by
GV: Nhn xt, hng dn li, lu
cho HS phn hiroxit lng tnh.
Hot ng 4:
chp vo v.
Bi 4:
Da vo thuyt Arniut. Gii thch
NH3 l mt baz.
HS: Chp
bn lm.
HS: Ln bng trnh by
Al2(SO4)3 tc dng vi NaOH d.
Gii:
Al2(SO4)3 + 6NaOH 2Al(OH)3 + 3Na2SO4
Al(OH)3 + NaOH NaAlO2 + 2H2O
Bi 4:
Da vo thuyt Arniut. Gii thch NH3 l mt
baz.
Gii:
NH3 + H2O NH +4 + OH-
Bi 5:
Trong mt dd c cha a mol Ca2+, b mol
Hot ng 5:
GV: Chp ln bng, yu cu HS Mg2+, c mol Cl-, d mol NO 3 .
chp vo v.
a/ Lp biu thc lin h a, b, c, d.
Bi 5:
b/ Nu a = 0,01; c = 0,01; d = 0,03 th b bng
Trong mt dd c cha a mol Ca2+, bao nhiu.
b mol Mg2+, c mol Cl-, d mol NO 3 .

Gii:
a/ Lp biu thc lin h a, b, c, d.
b/ Nu a = 0,01; c = 0,01; d = 0,03
a/ Trong mt dd, tng in tch ca cc cation
th b bng bao nhiu.
bng tng in tch ca cc anion, v vy:
HS: Chp
2a + 2b = c + d
GV: Hng dn HS cch gii.
b/ b =
c + d 2a 0,01 + 0,03 2.0,01

=
= 0,01
2
2
HS: Ch nghe ging

* Cng c:
- Theo thuyt Arniut, cht no di y l axit?
A. Cr(NO3)3
B. HBrO3
C. CdSO4
- Theo thuyt Arniut, cht no di y l baz?
A. Cr(NO3)3
B. HBrO3
C. CdSO4
* Dn d:
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D. CsOH
D. NH3
Chun b bi s in li ca nc. pH. Cht ch th axit baz.
Tit 3:
BI TP. PH.
I. Mc tiu:
Gii c cc bi ton lin quan n tnh pH.
II. Trng tm:
Cc bi tp tnh pH
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
- Trnh by khi nim pH.
- Tnh pH ca dd HCl 0,01 M v dd KOH 0,001 M
3/ Bi mi
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Mt dd axit sunfuric c pH = 2.
a/ Tnh nng mol ca axit sunfuric
trong dd . Bit rng nng
ny, s phn li ca axit sunfuric
thnh ion c coi l hon ton.
b/ Tnh nng mol ca ion OHtrong dd .
HS: Chp
bn lm.

nhn xt ghi im.
Hot ng 2:
chp vo v.
Bi 2:
Cho m gam natri vo nc, ta thu
c 1,5 lt dd c pH = 13. Tnh m.
HS: Chp
GV: Hng dn HS cch gii.
HS: Nghe ging v hiu
H:01:25H:01:25H:01:25
Ni dung
Bi 1:
Mt dd axit sunfuric c pH = 2.
a/ Tnh nng mol ca axit sunfuric trong
dd . Bit rng nng ny, s phn li
ca axit sunfuric thnh ion c coi l hon
ton.
b/ Tnh nng mol ca ion OH- trong dd .
Gii:
a/ pH = 2 [H+] = 10-2 = 0,01M
H2SO4 2 H+ + SO 24
1 +
1
[H ] = .0,01 = 0,005M
2
2
14
10
b/ [OH-] = 2 = 10 12 M
10
[H2SO4] =
Bi 2:
Cho m gam natri vo nc, ta thu c 1,5
lt dd c pH = 13. Tnh m.
Gii:
pH = 13 [H+] = 10-13
[OH-] = 10-1 = 0,1M
S mol OH- trong 1,5 lt dd bng: 0,1.1,5 =

0,15 (mol)
2Na + 2H2O 2Na+ + 2OH- + H2
S mol Na = s mol OH- = 0,15 ( mol)
Hot ng 3:
Khi lng Na = 0,15.23 = 3,45 gam
GV: Chp ln bng, yu cu HS Bi 3:
chp vo v.
Tnh pH ca dd cha 1,46 g HCl trong 400,0
Bi 3:
ml.
Tnh pH ca dd cha 1,46 g HCl
trong 400,0 ml.
HS: Chp
Gii:
GV: Yu cu HS suy ngh , sau
gi 1 HS ln bng gii. Cc HS cn
1,46 1000
1
li ly nhp ra lm bi v theo di CM(HCl) = 36,5 . 400,0 = 0,100 M = 10 M
bi bn lm.
[H+] = [HCl] = 10-1M pH = 1,0
HS: Ln bng trnh by
nhn xt ghi im
Hot ng 4:
chp vo v.
Tnh pH ca dd to thnh sau khi trn 100,0
Bi 4:
ml dd HCl 1,00M vi 400,0 ml dd NaOH
Tnh pH ca dd to thnh sau khi 0,375M.
trn 100,0 ml dd HCl 1,00M vi
400,0 ml dd NaOH 0,375M.
HS: Chp
GV:Hng dn HS cch gii tnh
Gii:
[OH-]
nNaOH = 0,4.0,375 = 0,15 (mol)
nHCl = 0,1.1,000 = 0,10 ( mol)
Sauk hi trn NaOH d
nNaOH (d) = 0,15 0,10 = 0,05 (mol)
S mol NaOH = s mol OH- = 0,05 (mol)
HS: Nghe ging v hiu
GV: Yu cu HS tnh [H+] v pH
HS: Tnh [H+] v pH
0,05
= 0,1M
0,4 + 0,1
1,0.10 14
= 1,0.10 13 M
[H+] =
1,0.10 1
[OH-] =
Vy pH = 13
* Cng c:
pH ca dd CH3COOH 0,1M phi
A. nh hn 1
B. ln hn 1 nhng nh hn 7
C. bng 7
D. ln hn 7
* Dn d:
Chun b bi phn ng trao i ion trong dd cht in li
H:01:25H:01:25H:01:25
Tit 4:
BI TP PHN NG TRAO I ION
TRONG DUNG DCH CC CHT IN LI
I. Mc tiu:
HS vn dng c kin thc hc gii bi tp
II. Trng tm:
Cc bi tp phn ng trao i ion trong dung dch cc cht in li
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
- Trnh by iu kin phn ng trao i ion trong dung dch cc cht in li.
- Vit phng trnh phn t v phng trnh ion rt gn ca phn ng sau:
NaHCO3 + NaOH
3/ Bi mi
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Vit phng trnh dng phn t ng
vi phng trnh ion rt gn sau:
2
a/ Ba2+ + CO 3 BaCO3
b/ Fe3+ + 3OH- Fe(OH)3
+
c/ NH 4 + OH- NH3 + H2O
d/ S2- + 2H+ H2S
HS: Chp
bn lm.
nhn xt ghi im.
Hot ng 2:
chp vo v.
Bi 2:
Vit phng trnh dng phn t ca
cc phn ng theo s sau.
a/ MgCO3 + ? MgCl2 + ?.
b/ Fe2(SO4)3 + ? K2SO4 + ?.
HS: Chp
bn lm. Gi HS nhn xt , ghi im
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Ni dung
Bi 1:
Vit phng trnh dng phn t ng vi
phng trnh ion rt gn sau:
2
a/ Ba2+ + CO 3 BaCO3
b/ Fe3+ + 3OH- Fe(OH)3
+
c/ NH 4 + OH- NH3 + H2O
d/ S2- + 2H+ H2S
Gii:
a/ Ba(NO3)2 + Na2CO3 BaCO3 + 2NaNO3

b/ Fe2(SO4)3 + 6NaOH 2Fe(OH)3 + 3Na2SO4
c/ NH4Cl + NaOH NH3 + H2O + NaCl
d/ FeS + 2HCl FeCl2 + H2S
Bi 2:
a/ MgCO3 + ? MgCl2 + ?.
b/ Fe2(SO4)3 + ? K2SO4 + ?
Gii:
a/ MgCO3 + 2HCl MgCl2 + H2O + CO2

b/ Fe2(SO4)3 + 6KOH 3K2SO4 + Fe(OH)3
Hot ng 3:
chp vo v.
Bi 3:
Ho tan 1,952 g mui BaCl2.xH2O
trong nc. Thm H2SO4 long, d
vo dung dch thu c. Kt ta to
thnh c lm kh v cn c
1,864 gam. Xc nh cng thc ho
hc ca mui.
HS: Chp
GV: Yu cu HS suy ngh tho lun
5 pht, sau cho HS ln bng gii.
Cc HS cn li ly nhp ra lm bi
v theo di bi bn lm.
HS: Ln bng trnh by
Hot ng 4:
chp vo v.
Bi 4:
Trn 250 ml dung dch hn hp HCl
0,08M v H2SO4 0,01M vi 250 ml
dung dch Ba(OH)2 c nng x (M)
thu c m gam kt ta v 500 ml
dung dch c pH = 12. Hy tnh m v
x. Coi Ba(OH)2 in li hon ton c 2
nc.
HS: Chp
GV:Yu cu tnh s mol HCl ban u
, s mol H2SO4 ban u , vit cc
phng trnh phn ng xy ra.
HS: Tr li
Bi 3:
Ho tan 1,952 g mui BaCl2.xH2O trong
nc. Thm H2SO4 long, d vo dung dch
thu c. Kt ta to thnh c lm kh v
cn c 1,864 gam. Xc nh cng thc
ho hc ca mui.
Gii:
BaCl2.xH2O + H2SO4
n BaSO 4 =
BaSO4 + 2HCl + 2H2O (1)
1,864
= 0,008(mol )
233
Theo phng trnh (1) s mol BaSO4 = s

mol BaCl2.xH2O
1,952
= 244
0,008
244 208
=2
x=
18
M=
CTHH ca mui l : BaCl2.2H2O

Bi 4:
Trn 250 ml dung dch hn hp HCl 0,08M v
H2SO4 0,01M vi 250 ml dung dch Ba(OH)2
c nng x (M) thu c m gam kt ta v
500 ml dung dch c pH = 12. Hy tnh m v
x. Coi Ba(OH)2 in li hon ton c 2 nc.
Gii:
S mol HCl ban u = 0,25.0,08 = 0,02 ( mol)
S mol H2SO4 ban u = 0,25.0,01= 0,0025
( mol)
Sau khi phn ng dung dch c pH =12 ngha
Ba(OH)2 cn d v cc axit phn ng ht.
2HCl + Ba(OH)2 BaCl2 + 2H2O
0,02
0,01
H2SO4 + Ba(OH)2 BaSO4 + 2H2O
0,0025 0,0025
0,0025
Khi lng kt ta: m = 0,0025.233 = 0,5825
(gam)
Sau khi phn ng dung dch c pH =12
ngha l: [H+] = 10-12M [OH-] = 10-2M
S mol OH- trong dung dch = 0,01.0,5 =
0,005 (mol)
Ba(OH)2 Ba2+ + 2OH-
GV: Hng dn HS tnh khi lng

1
kt ta, Tnh nng mol ca S mol Ba(OH)2 cn d = s mol OH- =
2
Ba(OH)2 .
0,0025 (mol)
S mol Ba(OH)2 ban u = 0,01 + 0,0025 +
H:01:26H:01:26H:01:26
0,0025 = 0,015 (mol)

HS: Nghe ging v hiu
Nng Ba(OH)2 : x =
0,015
= 0,06( M )
0,25
* Cng c:
Vit phng trnh phn t v phng trnh ion rt gn ca cc phn ng sau.
a/ Pb(NO3)2 + Na2SO4
b/ Pb(OH)2 + H2SO4
* Dn d:
Chun b bi thc hnh s 1
Tit 5: BI TP TNG KT CHNG S IN LI

I. Mc tiu:
II. Trng tm:
Phn ng trao i ion trong dung dch cc cht in li, Ph ca dung dch.
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
Trn 100 ml dung dch HCl 0,1 M vi 200ml dung dch Ba(OH)2 0,1 M c
dung dch A . Tnh nng mol ca cc ion trong dung dch A.
3/ Bi mi
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Trong ba dung dch c cc loi ion
sau:
2
Ba2+, Mg2+, Na+, SO 24 , CO 3 v NO 3

Mi dung dch ch cha mt loi
cation v mt loi anion.
a/ Cho bit l 3 dd mui g
b/ Hy chn dung dch axit thch hp
nhn bit 3 dung dch mui ny.
HS: Chp
bn lm.
H:01:26H:01:26H:01:26
Ni dung
Bi 1:
Trong ba dung dch c cc loi ion sau:
2
Ba2+, Mg2+, Na+, SO 24 , CO 3 v NO 3

Mi dung dch ch cha mt loi cation v
mt loi anion.
a/ Cho bit l 3 dd mui g
b/ Hy chn dung dch axit thch hp nhn
bit 3 dung dch mui ny.
Gii:
a/ V cc mui BaSO4, BaCO3, MgCO3 khng
tan nn ba dung dch phi l dung dch
Ba(NO3)2, dung dch MgSO4 v dung dch
Na2CO3.
GV: Yu cu 1 HS nhn xt, GV b/ Cho dung dch H2SO4 vo c 3 dung dch .

nhn xt ghi im.
dung dch Na2CO3 c si bt:
Na2CO3 + H2SO4 Na2SO4 + H2O + CO2
dung dch Ba(NO3)2, xut hin kt ta
Hot ng 2:
trng.
GV: Chp ln bng, yu cu HS Ba(NO3)2 + H2SO4 BaSO4 + 2HNO3
chp vo v.
Dung dch MgSO4 vn trong sut.
Bi 2:
Bi 2:
150 ml dung dch KOH vo 50 ml 150 ml dung dch KOH vo 50 ml dung
dung dch H2SO4 1M, dung dch tr dch H2SO4 1M, dung dch tr thnh d baz.
thnh d baz. C cn dung dch C cn dung dch thu c 11,5 gam cht
thu c 11,5 gam cht rn. Tnh rn. Tnh nng mol/lt ca dung dch KOH.
nng mol/lt ca dung dch KOH.
Gii
HS: Chp
S mol H2SO4 = 0,05 (mol)
GV: Yu cu HS tho lun , gi 1 V baz d nn axit phn ng ht.
HS ln bng trnh by
2KOH + H2SO4 K2SO4 + 2H2O
0,1
0,05
0,05
(mol)
HS: Ln bng trnh by
C cn dung dch , thu c cht rn gm c
K2SO4, KOH d
m K 2SO 4 = 0,05.174 = 8,7(gam)

mKOH(d) = 11,5 8,7 = 2,8 (gam)
nhn xt ghi im.
nKOH(d) = 2,8:56 = 0,05 (mol)
S mol KOH c trong 150 ml dung dch KOH
l.
Hot ng 3:
0,1 + 0,05 = 0,15 (mol)
Nng mol/l ca dung dch KOH:
chp vo v.
CM(KOH) = 0,15: 0,15 = 1M
Bi 3:
Bi 3:
Thm t t 400 g dung dch H2SO4
Thm t t 400 g dung dch H2SO4 49% vo
49% vo nc v iu chnh lng
nc v iu chnh lng nc thu c
nc thu c ng 2 lt dung
ng 2 lt dung dch A. Coi H2SO4 in li hon
dch A. Coi H2SO4 in li hon ton
ton c 2 nc.
c 2 nc.
a/ Tnh nng mol ca ion H+ trong dung
a/ Tnh nng mol ca ion H+ trong
dch A.
dung dch A.
b/ Tnh th tch dung dch NaOH 1,8M cn
b/ Tnh th tch dung dch NaOH
thm vo 0,5 lt dung dch A thu c
1,8M cn thm vo 0,5 lt dung dch
dung dch .
A thu c dung dch .
+ Dung dch c Ph = 1
+ Dung dch c Ph = 1
+ Dung dch c Ph = 13
+ Dung dch c Ph = 13
Gii
GV: Yu cu 1 HS ln bng gii cu
400.49
= 2(mol)
a, cc HS cn li lm nhp v theo a/ S mol H2SO4:
100.98
di bi bn lm.
H2SO4 2H+ + SO 24
HS: Ln bng trnh by
2
4
(mol)
GV: Gi HS nhn xt
GV: Hng dn HS lm cu b
H:01:26H:01:26H:01:26
Nng H+ trong dung dch A l :
4
= 2M
2
b/ S mol H+ trong 0,5 lt dung dch A l :

2.0,5 = 1 (mol)
t th tch dung dch NaOH l x th s mol
NaOH trong l 1,8x.

NaOH Na+ + OH1,8x
1,8x 1,8x
+ Ph = 1
Axit d
H+ + OH- H2O
Ban u : 1
1,8x
Phn ng: 1,8x
Cn d : 1 -1,8x
Nng H+ sau phn ng:
HS: Nghe ging v hiu
1 1,8 x
= 0,1M x = 0,5(l )
0,5 + x
+ Ph = 13 Baz d
H+ + OH- H2O
Ban u : 1
1,8x
Phn ng: 1
1
Cn d :
1,8x 1
Sau phn ng Ph = 13 [H+] = 10-13M
[OH-] = 10-1M
1,8 x 1
= 0,1M x = 0,62(l )
0,5 + x
* Cng c:
Trong dung dch A c cc ion K+, Mg2+, Fe3+ v Cl- . Nu c cn dung dch s thu
c hn hp nhng mui no.
Dn d:
Chun b bi Amoniac v mui Amoni
Tit 6:
BI TP NIT V AMONIAC
I. Mc tiu:
II. Trng tm:
Bi tp nit v Amoniac.
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
Trnh by tnh cht ha hc ca amoniac.
3/ Bi mi
Hot ng ca thy v tr
H:01:26H:01:26H:01:26
Ni dung
Hot ng 1:
chp vo v.
Bi 1:
Trong mt bnh kn dung tch 10 lt
cha 21 gam nit. Tnh p sut ca
kh trong bnh, bit nhit ca kh
bng 250C.
HS: Chp
bn lm.
nhn xt ghi im.
Hot ng 2:
chp vo v.
Bi 2:
Nn mt hn hp kh gm 2 mol nit
v 7 mol hiro trong mt bnh phn
ng c sn cht xc tc thch hp v
nhit ca bnh c gi khng
i 4500C. Sau phn ng thu
c 8,2 mol hn hp kh.
a/ Tnh phn trm s mol nit
phn ng .
b/ Tnh th tch (kt) kh ammoniac
c to thnh.
HS: Chp
GV: Yu cu HS tho lun.
GV: Hng dn HS cch lm bi
HS:Nghe ging v hiu
HS: T tnh phn trm s mol nit
phn ng, th tch (kt) kh
ammoniac c to thnh.
Hot ng 3:
chp vo v.
Bi 3:
Cho lng d kh ammoniac i t t
qua ng s cha 3,2 g CuO nung
nng n khi phn ng xy ra hon
ton, thu c cht rn A v mt
hn hp kh. Cht rn A phn ng
va vi 20 ml dung dch HCl 1 M
a/ Vit pthh ca cc phn ng.
b/ Tnh th tch nit ( ktc) c to
thnh sau phn ng.
H:01:26H:01:26H:01:26
Bi 1:
Trong mt bnh kn dung tch 10 lt cha 21
gam nit. Tnh p sut ca kh trong bnh,
bit nhit ca kh bng 250C.
Gii:
S mol kh N2:
21
= 0,75(mol )
28
p sut ca kh N2:
p=
nRT 0,75.0,082(25 + 273)

=
= 1,83(atm)
V
10
Bi 2:
Nn mt hn hp kh gm 2 mol nit v 7
mol hiro trong mt bnh phn ng c sn
cht xc tc thch hp v nhit ca bnh
c gi khng i 4500C. Sau phn ng
thu c 8,2 mol hn hp kh.
a/ Tnh phn trm s mol nit phn ng .
b/ Tnh th tch (kt) kh ammoniac c to
thnh.
Gii
N2 (k) + 3H2 (k) 2NH3(k)
S mol kh ban u:
2
S mol kh phn ng: x
S mol kh lc cn bng: 2-x
7
3x
7 3x
0
2x
2x
Tng s mol kh lc cn bng: 2 x + 7 3x +

2x = 9 2x
Theo ra: 9 2x = 8,2
x = 0,4
a/ Phn trm s mol nit phn ng
0,4.100%
= 20%
2
b/ Th tch (kt) kh ammoniac c to

thnh: 2.0,4. 22,4 = 17,9 (lt)
Bi 3:
Cho lng d kh ammoniac i t t qua ng
s cha 3,2 g CuO nung nng n khi phn
ng xy ra hon ton, thu c cht rn A v
mt hn hp kh. Cht rn A phn ng va
vi 20 ml dung dch HCl 1 M
a/ Vit pthh ca cc phn ng.
b/ Tnh th tch nit ( ktc) c to thnh
sau phn ng.
Gii
a/ pthh ca cc phn ng.
t C
2NH3 + 3CuO
N2 + 3Cu + 3H2O (1)
Cht rn A thu c sau phn ng gm Cu
GV: Yu cu HS tho lun.

GV: Hng dn HS cch vit pt.
v CuO cn d . ch c CuO phn ng vi

dung dch HCl.
CuO + 2HCl CuCl2 + H2O
HS:Nghe ging v hiu
b/ S mol HCl phn ng vi CuO: nHCl = 0,02(
mol)
Theo (2) s mol CuO d: nCuO = 1/2 s mol
HCl = 0,02: 2 = 0,01 (mol)
S mol CuO tham gia phn ng (1) = s mol
GV:Yu cu HS ln bng trnh by cu CuO ban u s mol CuO d =
b
HS: Ln bng trnh by

GV: Gi HS nhn xt
3,2
0,01 = 0,03(mol )
80
Theo (1), s mol N2=
1
1
s mol CuO = .0,03
3
3
= 0,01 (mol)
Th tch kh nit to thnh : 0,01. 22,4 =
0,224 (lt)
* Cng c:
Amoniac phn ng c vi tt c cc cht trong nhm no sau y.
A. HCl, O2, Cl2, CuO, dd AlCl3
B. H2SO4, PbO, FeO, NaOH
C. HCl, KOH, FeCl3, Cl2
D. KOH, HNO3, CuO, CuCl2
* Dn d:
Chun b tip phn cn li bi Amoniac v mui Amoni
Tit 7:
BI TP AXIT NITRIC
I. Mc tiu:
II. Trng tm:
Bi tp axit nitric.
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
Trnh by tnh cht ha hc ca Axit nitric
3/ Bi mi
H:01:26H:01:26H:01:26
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Khi cho oxit ca mt kim loi ha tr
n t dng vi dung dch HNO3 d th
to thnh 34,0 g mui nitrat v 3,6 g
nc ( khng c sn phm khc ).
Hi l oxit kim loi no v khi
lng ca oxit kim loi phn ng
l bao nhiu
HS: Chp
GV: Hng dn HS cch vit pt, gi
cch gii, yu cu HS lm
HS: Tho lun lm bi
Ni dung
Bi 1:
Khi cho oxit ca mt kim loi ha tr n t dng
vi dung dch HNO3 d th to thnh 34,0 g
mui nitrat v 3,6 g nc ( khng c sn
phm khc ). Hi l oxit kim loi no v
khi lng ca oxit kim loi phn ng l
bao nhiu
Gii:
PTHH.
M2On + 2nHNO3 2M(NO3)n + nH2O (1)
Theo phn ng (1), khi to thnh 1 mol ( tc
(A + 62n) g ) mui nitrat th ng thi to
thnh n/2 mol ( 9n gam ) nc
(A + 62n) g mui nitrat 9n g nc
34,0 g
mui nitrat 3,6 g nc
Ta c:
A + 62n 9n
=
34
3,6
Gii pt: A = 23n.

Ch c nghim n = 1, A = 23
Vy kim loi M trong oxit l natri
GV: Yu cu HS cho bit kt qu
Na2O + 2HNO3 2NaNO3 + H2O (2)
Theo phn ng (2)
C to ra 18 g nc th c 62 g Na2O
GV: Yu cu HS vit pt v tnh khi phn ng
lng ca oxit kim loi phn ng Vy to ra 3,6g nc th c x g Na2O
phn ng
HS: Vit pt v tnh khi lng ca x = (3,6.62) : 18 = 12,4 (g)
oxit kim loi phn ng
Hot ng 2:
Bi 2:
GV: Chp ln bng, yu cu HS Chia hn hp hai kim loi Cu v Al lm 2
chp vo v.
phn bng nhau.
Bi 2:
+ Phn th nht: Cho tc dng vi dung dch
Chia hn hp hai kim loi Cu v Al HNO3 c ngui thu c 8,96 lt kh NO2
lm 2 phn bng nhau.
( ktc)
+ Phn th nht: Cho tc dng vi + Phn th hai: Cho tc dng vi hon ton
dung dch HNO3 c ngui thu c vi dung dch HCl, thu c 6,72 lt kh
8,96 lt kh NO2 ( ktc)
( ktc)
+ Phn th hai: Cho tc dng vi Xc nh thnh phn phn trm v khi
hon ton vi dung dch HCl, thu lng ca mi kim loi trong hn hp
c 6,72 lt kh ( ktc)
Gii
Xc nh thnh phn phn trm v Phn th nht, ch c Cu phn ng vi HNO3
khi lng ca mi kim loi trong c.
hn hp.
Cu + 4HNO3 c Cu(NO3)2 + 2NO2 + 2 H2O (1)
HS: Chp
Phn th 2, ch c Al phn ng vi
GV: Yu cu 1 HS ln bng trnh 2Al + 3HCl AlCl3 + 3H2 (2)
by. Cc HS cn li lm v theo di Da vo (1) ta tnh c khi lng Cu c
bi ca bn
trong hn hp l 12,8 g.
Da vo (2) ta tnh c khi lng Al c
HS:Ln bng trnh by
trong hn hp l 5,4 g.
H:01:26H:01:26H:01:26
GV: Gi HS nhn xt, ghi im
% khi lng ca Cu = 70, 33%

% khi lng ca Al = 29,67%
Hot ng 3:
Bi 3:
GV: Chp ln bng, yu cu HS Cho 12,8 g Cu tc dng vi dung dch HNO3
chp vo v.
c, sinh ra kh NO2. Tnh th tch NO2
Bi 3:
( ktc).
Cho 12,8 g Cu tc dng vi dung
Gii
dch HNO3 c, sinh ra kh NO2. Tnh
Cu + 4HNO3 c Cu(NO3)2 + 2NO2 + 2 H2O
th tch NO2 ( ktc).
0,2
0,4 (mol)
HS: Chp
12
,
8
GV: Yu cu 1 HS ln bng trnh n =
= 0,2(mol )
Cu
64
by. Cc HS cn li lm v theo di
V NO = 0,4.22,4 = 8,96(l )
bi ca bn
HS:Ln bng trnh by
2
* Cng c:
Ha tan 12,8 g kim loi ha tr II trong mt lng va dung dch HNO3 60% (
d = 1,365g/ml), thu c 8,96 lt ( ktc) mt kh duy nht mu nu . Tn ca kim
loi v th tch dung dch HNO3 phn ng l
A. Cu; 61,5 ml
B. Cu; 61,1 ml
C. Cu; 61,2 ml
D. Cu; 61,0 ml
* Dn d:
Chun b tip phn cn li bi Axit v mui nitrat
H:01:26H:01:26H:01:26
Tit 8: BI TP MUI NITRAT

I. Mc tiu:
II. Trng tm:
Bi tp mui nitrat
III. Chun b:
GV:Gio n
HS: n tp l thuyt bi axit nitric v mui nitrat.
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
Trnh by tnh cht ha hc ca mui nitrat
3/ Bi mi:
- n
nh
lp
11B2:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B3:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B4:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B5:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B6:Ngy
ging.........................................S
s...........................................................
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Nhit phn hon ton 27,3 gam hn
hp rn gm NaNO3 v Cu(NO3)2, thu
c hn hp kh c th tch 6,72 lt
( ktc).
Tnh thnh phn % v khi lng ca
mi mui trong hn hp X.
HS: Chp
HS: Tho lun lm bi
Ni dung
Bi 1:
Nhit phn hon ton 27,3 gam hn hp rn
gm NaNO3 v Cu(NO3)2, thu c hn hp kh
c th tch 6,72 lt ( ktc).
Tnh thnh phn % v khi lng ca mi mui
trong hn hp X.
Gii:
2NaNO3 2NaNO2 + O2 (1)
x
0,5x ( mol)
t0
2Cu(NO3)2 2CuO + 4NO2 + O2 (2)
y
y
2y
0,5y ( mol)
Gi x v y l s mol ca NaNO3 v Cu(NO3)2
trong hn hp X. Theo cc phn ng (1) v (2)
v theo bi ra . Ta c.
85x + 188y = 27,3
GV: Yu cu HS ln bng gii
0,5x + 2y + 0,5y = 0,3
x = y = 0,1
85.0,1.100%
HS: Ln bng trnh by
= 31,1%
% m NaNO3 =
27,3
GV: Nhn xt ghi im
188.0,1.100%
= 68,9%
% mCu ( NO3 ) 2 =
27.3
Hot ng 2:
Bi 2:
GV: Chp ln bng, yu cu HS Nung nng 27,3 g hn hp NaNO3 v Cu(NO3)2 ;
chp vo v.
hn hp kh thot ra c dn vo 89,2 ml
Bi 2:
H:01:26H:01:26H:01:26
t0
Nung nng 27,3 g hn hp NaNO3 v

Cu(NO3)2 ; hn hp kh thot ra c
dn vo 89,2 ml nc th cn d 1,12 l
kh(ktc) khng b hp th. ( Lng O2
ha tan khng ng k)
a/ Tnh khi lng ca mi mui trong
hn hp u.
b/ Tnh nng % ca dd axt.
HS: Chp
GV: Hng dn HS cch gii, yu cu
HS ln bng trnh by
HS:Ln bng trnh by
nc th cn d 1,12 l kh(ktc) khng b hp

th. ( Lng O2 ha tan khng ng k)
a/ Tnh khi lng ca mi mui trong hn hp
u.
b/ Tnh nng % ca dd axt
Gii
2NaNO3 2NaNO2 + O2 (1)
2
1 ( mol)
t0
2Cu(NO3)2 2CuO + 4NO2 + O2 (2)
2
4
1 ( mol)
4NO2 + O2 + 2H2O
4 HNO3 (3)
4
1
4 ( mol)
a/ Theo pt (1), (2), (3) , nu cn d 1,12 l kh
( hay 0,05 mol ) th l kh O 2, c th coi lng
kh ny do mui NaNO3 phn hy to ra
T (1) ta c: n NaNO3 = 2.0,05 = 0,1(mol )
t0
m NaNO3 = 0,1.85 = 8,5( g )

mCu ( NO3 ) 2 = 27,3 8,5 = 18,8( g )
nCu ( NO3 ) 2 = 18,8 : 188 = 0,1(mol )

T (2) ta c: n NO2 =
0,1
.4 = 0,2( mol )
2
0,1
.1 = 0,05(mol )
2
( Cc kh ny hp th vo nc)
T (3) ta c : n HNO3 = n NO2 = 0,2(mol )
nO2 =
Khi lng HNO3 l: 0,2.63 = 12,6 (g)

Khi lng ca dung dch = 0,2.46 + 0,05.32 +
89,2 = 100 (g)
C% ( HNO3) = 12,6 %
Hot ng 3:
Nung mt lng mui Cu(NO3). Sau mt thi
chp vo v.
gian dng li, ngui v em cn th thy khi
Bi 3:
lng gim i 54g.
Nung mt lng mui Cu(NO3). Sau
+ Khi lng Cu(NO3) b phn hy.
mt thi gian dng li, ngui v
+ S mol cc cht kh thot ra l
em cn th thy khi lng gim i
54g.
+ Khi lng Cu(NO3) b phn
hy.
Gii
+ S mol cc cht kh thot ra l
0
t
HS: Chp
2Cu(NO3)2 2CuO + 4NO2 + O2
GV: Yu cu 1 HS ln bng trnh by. + C 188g mui b phn hu th khi lng gim
Cc HS cn li lm v theo di bi ca : 188 80 = 108 (g)
bn
Vy x = 94 g mui b phn hu th khi lng
gim 54 g
HS:Ln bng trnh by
Khi lng mui b phn hu
mCu ( NO3 ) 2 = 94( g )
+ nCu ( NO3 ) 2 = 94 : 188 = 0,5(mol )
0,5
n NO2 =
.4 = 1(mol )
2
H:01:26H:01:26H:01:26
nO2 =
0,5
. = 0,25(mol )
2
* Cng c:
Nung nng 66,2 g Pb (NO3)2 thu c 55,4 g cht rn. Hiu sut ca phn ng phn hy
l.
A. 96%
B. 50%
C. 31,4%
D. 87,1%
* Dn d:
Chun b bi Axit photphoric v mui photphat
H:01:26H:01:26H:01:26
Tit 9:
BI TP. AXIT PHOTPHORIC V MUI PHOTPHAT
I. Mc tiu:
II. Trng tm:
Bi tp axit photphori v mui photphat
III. Chun b:
GV:Gio n
HS: n tp l thuyt bi axit photphoric v mui photphat.
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
Trnh by tnh cht ha hc ca axit photphoric v mui photphat
3/ Bi mi
- n
nh
lp
11B2:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B3:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B4:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B5:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B6:Ngy
ging.........................................S
s...........................................................
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Cho 11,76 g H3PO4 vo dung dch
cha 16,8 g KOH. Tnh khi lng ca
tng mui thu c sau khi cho dung
dch bay hi n kh
HS: Chp
GV: Yu cu HS cch vit pt, gi
HS: Tho lun lm bi
GV: Yu cu HS ln bng gii
HS: Ln bng trnh by
GV: Nhn xt ghi im
Hot ng 2:
chp vo v.
Bi 2:
Bng phng php ha hc, hy phn
H:01:26H:01:26H:01:26
Ni dung
Bi 1:
Cho 11,76 g H3PO4 vo dung dch cha 16,8 g
KOH. Tnh khi lng ca tng mui thu c
sau khi cho dung dch bay hi n kh
Gii:
H3PO4 + KOH
KH2PO4 + H2O (1)
H3PO4 + 2KOH K2HPO4 + 2H2O (2)
H3PO4 + 3KOH K3PO4 + 3H2O (3)
S mol H3PO4 0,12 (mol)
S mol KOH 0,3 (mol)
Da vo t l s mol gia KOH v H3PO4
12,72 g K3PO4 v 10,44g K2HPO4
Bi 2:
Bng phng php ha hc, hy phn bit dung
dch HNO3 v dung dch H3PO4
Gii
Cho mnh kim loi Cu vo dung dch ca tng
bit dung dch HNO3 v dung dch

H3PO4
HS: Chp
GV: Yu cu HS ln bng trnh by
HS:Ln bng trnh by
Hot ng 3:
chp vo v.
Bi 3:
Bng phng php ha hc phn bit
cc mui: Na3PO4, NaCl, NaBr, Na2S,
NaNO3. Nu r hin tng dng
phn bit v vit phng trnh ha hc
ca cc phn ng
HS: Chp
GV: Yu cu HS chia nhm tho lun.
Gi i din mt nhm ln trnh by
HS:Ln bng trnh by
Hot ng 4:
chp vo v
Bi 4:
Cho 62 g canxi photphat tc dng vi
49 g dung dch H2SO4 64%. Lm bay
hi dung dch thu c n cn kh th
c mt hn hp rn, bit rng cc
phn ng u xy ra vi hiu sut
100%
HS: Chp
GV: Hng dn HS cch vit pt. Yu
cu HS gii
HS:Ln bng trnh by
H:01:26H:01:26H:01:26
axit
Cu + HNO3 () Cu(NO3)2 + 2NO2 + 2H2O

Cu khng t dng vi H3PO4
Bi 3:
Bng phng php ha hc phn bit cc mui:
Na3PO4, NaCl, NaBr, Na2S, NaNO3. Nu r hin
tng dng phn bit v vit phng trnh
ha hc ca cc phn ng
Gii
Dng dung dch AgNO3 phn bit cc mui:
Na3PO4, NaCl, NaBr, Na2S, NaNO3.
Ly mi mui mt t vo tng ng nghim, thm
nc vo mi ng v lc cn thn ha tan
ht mui. Nh dung dch AgNO3 vo tng ng
nghim
- dung dch no c kt ta mu trng khng
tan trong axit mnh, th l dung dch NaCl
NaCl + AgNO3 AgCl + NaNO3
- dung dch no c kt ta mu vng nht
khng tan trong axit mnh, th l dung dch
NaBr.
NaBr + AgNO3 AgBr + NaNO3
- dung dch no c kt ta mu en, th l
dung dch Na2S
Na2S + 2AgNO3 Ag2S + 2NaNO3
- dung dch no c kt ta mu vng tan trong
axit mnh, th l dung dch Na3PO4
Na3PO4 + 3AgNO3 Ag3PO4 + 3NaNO3
Bi 4:
Cho 62 g canxi photphat tc dng vi 49 g dung
dch H2SO4 64%. Lm bay hi dung dch thu
c n cn kh th c mt hn hp rn,
bit rng cc phn ng u xy ra vi hiu sut
100%
Gii
Ca3(PO4)2 + H2SO4
2CaHPO4 + CaSO4 (1)
Ca3(PO4)2 + 2H2SO4 Ca(H2PO4)2 + 2CaSO4
(2)
Ca3(PO4)2 + 3H2SO4 H3PO4 + 3CaSO4 (3)
62
= 0,2(mol )
S mol Ca3(PO4)2 =
310
49.64
= 0,32(mol )
S mol H2SO4 =
100.98
V t l s mol H2SO4 v Ca3(PO4)2 l 1,6
Nn xy ra phn ng (1) v (2).
Gi a v b l s mol Ca3(PO4)2 tham gia cc
phn ng (1) v (2)
Ta c h pt:
a + 2b =0,32
a + b = 0,2
a = 0,08; b = 0,12
mCaHPO4 = 2.0,08.136 = 21,76( g )
mCa ( H 2 PO4 ) 2 = 0,12.234 = 28.08( g )
mCaSO4 = (a + 2b).136 = (0,08 + 0,24).136 = 45,52( g )
Dung dch H3PO4 c cha cc ion ( khng k ion H+v OH- ca nc)
A. H+, PO 34
B. H+, PO 34 , H2PO 4 C. H+, PO 34 , HPO 4 D. H+, PO 34 , H2PO 4 , HPO 4
Tit 10:
BI TP AXIT NITRIC - MUI NITRAT
I. Mc tiu:
II. Trng tm:
Bi tp axit nitric - mui nitrat
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c
Cn bng phng trnh phn ng sau : R + HNO3 R(NO3)n + NO2 + H2O
3/ Bi mi
- n
nh
lp
11B2:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B3:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B4:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B5:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B6:Ngy
ging.........................................S
s...........................................................
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
Mt lng 8,32 g Cu tc dng va
vi 240 ml dd HNO3 , cho 4,928 l ( o
ktc) hn hp gm hai kh NO v NO2
bay ra.
+ Tnh s mol ca NO v NO2 to ra
l
+ Tnh nng mol/l ca dd axt ban
u l
HS: Chp
H:01:26H:01:26H:01:26
Ni dung
Bi 1:
Mt lng 8,32 g Cu tc dng va vi 240
ml dd HNO3 , cho 4,928 l ( o ktc) hn hp
gm hai kh NO v NO2 bay ra.
+ Tnh s mol ca NO v NO2 to ra l
+ Tnh nng mol/l ca dd axt ban u l
Gii:
Cu + 4HNO3 Cu(NO3)2 + 2NO2 + 2H2O
x
4x
2x
3Cu + 8HNO3 3Cu(NO3)2 + 2NO + 4H2O
y
8/3y
2y
Theo bi ra ta c: ( x + y ).64 = 8,32 (1)

2
4,928
y =
= 0,22 (2)
3
22.4
Gii (1) v (2) c x = 0,1; y = 0,03
HS: Tho lun lm bi
a/ S mol ca NO2 l 2.0,1 = 0,2 (mol)
2
S mol ca NO l .0,03 = 0,02 (mol)
GV: Yu cu 1 HS ln bng gii
3
b/ Tng s mol HNO3 phn ng = 4.0,1 +
HS: Ln bng trnh by, cc HS cn li
8
ly nhp lm bi
.0,03 = 0,48 (mol)
3
Nng mol/l ca dung dch axit
GV: Gi HS nhn xt ghi im
0,48
C M ( HNO3 ) =
= 2( M )
0,24
Hot ng 2:
Bi 2:
GV: Chp ln bng, yu cu HS Mt lng 13,5 g Al tc dng va vi 2,2 l dd
chp vo v.
HNO3 cho bay ra mt hn hp gm hai kh NO
Bi 2:
v N2O. Bit t khi ca hn hp kh so vi hir
Mt lng 13,5 g Al tc dng va
bng 19,2.
vi 2,2 l dd HNO3 cho bay ra mt hn
+ Tnh s mol ca NO v N2O to ra l
hp gm hai kh NO v N2O. Bit t
+ Tnh nng mol/l ca dd axt u.
khi ca hn hp kh so vi hir bng
19,2.
Gii
+ Tnh s mol ca NO v N2O to ra l Al + 4HNO3 Al(NO3)3 + NO + 2H2O
+ Tnh nng mol/l ca dd axt u.
x
4x
2x (mol)
HS: Chp
8Al + 30HNO3
8Al(NO3)3 + 3N2O + 15H2O
GV: Gi hng dn HS cch gii, y
30/8y (= 3,75 y)
3/8y (= 0,375 y)
yu cu 1 HS ln bng trnh by
Theo bi ra ta c: ( x + y ).27 = 13,5 (1)
30.x + 44.0,375 y
d hh / H 2 =
= 19,2
( x + 0,375 y )2
ly nhp lm bi
(2)
2x +
Gii (1) v (2) c x = 0,1; y = 0,4

a/ S mol ca NO l = 0,1 (mol)
S mol ca N2O l 0,375.0,4 = 0,15 (mol)
b/ Tng s mol HNO3 phn ng = 4.0,1 +
3,75.0,4 = 1,9 (mol)
Nng mol/l ca dung dch axit
1,9
C M ( HNO3 ) =
= 0,86( M )
2,2
Bi 3:
Nung 9,4 gam mt mui nitrat trong mt bnh
Hot ng 3:
GV: Chp ln bng, yu cu HS kn. Sau khi phn ng xy ra hon ton cn li 4
gam oxit. Tm cng thc ca mui nitrat
chp vo v.
Bi 3:
Nung 9,4 gam mt mui nitrat trong
Gii
mt bnh kn. Sau khi phn ng xy ra
0
t
hon ton cn li 4 gam oxit. Tm cng 2R(NO3)2 R2On + 2nNO2 + n/2O2
thc ca mui nitrat
a
a/2
na
na/4
HS: Chp
Ta c: a.( MR + 62n) = 9,4 (1)
GV: Yu cu 1 HS ln bng trnh by.
0,5.a( 2MR + 16n) = 4 (2)
Cc HS cn li lm v theo di bi ca Ly (1) : (2) ta c MR = 32n. Khi n = 2 th MR =
bn
64
Vy cng thc mui nitrat Cu(NO3)2
H:01:26H:01:26H:01:26
HS:Ln bng trnh by

* Cng c:
+ Nhit phn hn hp gm 2 mui KNO3 v Cu(NO3)2 c khi lng l 95,4 gam. Khi phn
ng xy ra hon ton thu c hn hp kh c M = 37,82. Vy khi lng mi mui trong
hn hp ban u l
A. 20 v 75,4
B. 20,2 v 75,2
C. 15,4 v 80
D. 30 v 65,4
+ Dung dch HNO3 long tc dng vi hn hp Zn v ZnO to ra dd c cha 8 g NH4NO3
v 113,4 g Zn(NO3)2. Khi lng ca Zn v ZnO trong hn hp l
A. 26; 16,2
B. 27; 23,2
C. 28; 22,2
D. 23; 24,2
* Dn d:
Chun b bi Thc hnh s 2
Tit 11: BI TP TNG KT CHNG NIT - PHOTPHO

I. Mc tiu:
II. Trng tm:
Bi tp tng kt chng nit - photpho
III. Chun b:
GV:Gio n
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c:
(khng kim tra)
3/ Bi mi:
- n
nh
lp
11B2:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B3:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B4:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B5:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B6:Ngy
ging.........................................S
s...........................................................
Hot ng ca thy v tr
Ni dung
Hot ng 1:
Bi 1:
GV: Chp ln bng, yu cu HS Cho 3 mol N2 v 8 mol H2 vo mt bnh kn c
chp vo v.
th tch khng i cha sn cht xc tc ( th
Bi 1:
tch khng ng k ). Bt tia la in cho phn
Cho 3 mol N2 v 8 mol H2 vo mt bnh ng xy ra, sau a v nhit ban u th
kn c th tch khng i cha sn cht thy p sut gim 10% so vi p sut ban u.
xc tc ( th tch khng ng k ). Bt Tm % v th tch ca N2 sau phn ng.
tia la in cho phn ng xy ra, sau
Gii:
a v nhit ban u th thy p
N2 + 3H2 2NH3
sut gim 10% so vi p sut ban u. Trc phn ng
3
8
0 ( mol)
H:01:26H:01:26H:01:26
Tm % v th tch ca N2 sau phn

ng.
HS: Chp
GV: Yu cu HS tho lun lm bi.
HS: Tho lun lm bi
GV: Cho HS xung phong ln bng gii
Phn ng
x
3x
Sau phn ng
3 x 8 - 3x
2x
S mol kh trc phn ng n1= 11 (mol)
S mol kh sau phn ng n2= 11 2x (mol)
Do bnh kn nn p sut t l vi s mol, ta c
n1 P1
11
P
1
=
=
=
x = 0,55
n 2 P2
11 2 x 0,9 P 0,9
3 0,55
ly nhp lm bi
%N 2 =
.100% = 24,75%
11 2.0,55
Bi 2:
Hot ng 2:
GV: Chp ln bng, yu cu HS Khi ha tan hon ton 1,5875 gam mt kim loi
ha tr III trong dung dch HNO3 long thu c
chp vo v.
604,8 ml hn hp kh N2 v NO (ktc) c t
Bi 2:
Khi ha tan hon ton 1,5875 gam mt khi hi so vi H2 l 14,5. Tm tn M
kim loi ha tr III trong dung dch HNO3
Gii
long thu c 604,8 ml hn hp kh
M
+
4HNO
M(NO
)
NO + 2H2O
N2 v NO (ktc) c t khi hi so vi
3
3 3 +
x
4x
2x (mol)
H2 l 14,5. Tm tn M
10M+ 36HNO3 10M(NO3)3 + 3N2 + 18H2O
HS: Chp
3/10y
GV: Gi hng dn HS cch gii, y
3
y = 0,27
Theo bi ra ta c: x +
(1)
10
ly nhp lm bi
3
30.x + 28. y
10 = 14,5.2
d hh / H 2 =
(2)
3
x+ y
10
Gii (1) v (2) c x = 0,0135; y = 0,045
S mol ca M l 0,045 + 0,0135 = 0,0585 (mol)
1,5875
M =
= 27
0,0585
Vy M l Al
Hot ng 3:
Bi 3:
(1)
( 2)
( 3)
GV: Chp ln bng, yu cu HS NH4Cl
NH3
N2
NO
( 4)
( 5)
( 6)
chp vo v.
NO2 HNO3 NaNO3
Bi 3:
(7)
NaNO3
(1)
( 2)
( 3)
NH4Cl NH3 N2 NO
( 4)
( 5)
( 6)
NO2
HNO3
NaNO3
(7)
NaNO3
Gii
GV: Yu cu 1 HS ln bng trnh by. 1/ NH4Cl + NaOH

NH3 + H2O + NaCl
Cc HS cn li lm v theo di bi ca 2/ NH3 + 3O2 t
2 N2 + 6H2O
bn
t
3/ N2 + O2
2NO
4/ 2NO+ O2 2NO2
HS:Ln bng trnh by
5/ 4NO2 + 2H2O + O2 4 HNO3
6/ HNO3 + NaOH NaNO3 + H2O
t
7/ 2NaNO3
2NaNO2 + O2
Hot ng 4:
Bi 4:
GV: Chp ln bng, yu cu HS Cho 500ml dung dch KOH 2M vo 500ml dung
chp vo v.
dch H3PO4 1,5M. Sau phn ng trong dung dch
Bi 4:
thu c cc sn phm no
Cho 500ml dung dch KOH 2M vo
H:01:26H:01:26H:01:26
500ml dung dch H3PO4 1,5M. Sau

phn ng trong dung dch thu c
cc sn phm no
Cc HS cn li lm v theo di bi ca
bn
HS:Ln bng trnh by
Gii
S mol ca NaOH = 0,5.2 =1 (mol)
S mol H3PO4 = 0,5.1,5 = 0,75 (mol)
T l 1/0,75 = 1,333 nn to hai mui NaH2PO4
, Na2HPO4
* Cng c:
Ha tan 4,59 g Al bng dung dch HNO3 long thu c hn hp kh NO v N2O c t khi
V N 2O
i vi H2 bng 16,75. T l th tch kh
trong hn hp l
V NO
1
2
1
3
A.
B.
C.
D.
3
3
4
4
Dn d: Chun b bi Cacbon
Tit 12:
BI TP CACBON V CC HP CHT CA CACBON
I. Mc tiu:
II. Trng tm:
Bi tp cacbon v cc hp cht ca cacbon
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp cc bi cacbon v cc hp cht ca cacbon
IV.Tin trnh ln lp:
1/ n nh lp
2/ Bi c: Trnh tnh cht ca mui cacbonat
3/ Bi mi
- n
nh
lp
11B2:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B3:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B4:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B5:Ngy
ging.........................................S
s...........................................................
- n
nh
lp
11B6:Ngy
ging.........................................S
s...........................................................
Hot ng ca thy v tr
Hot ng 1
chp vo v.
Bi 1:
Nung 52,65 g CaCO3 10000C v cho
H:01:26H:01:26H:01:26
Ni dung
Bi 1:
Nung 52,65 g CaCO3 10000C v cho ton b
lng kh thot ra hp th ht vo 500 ml dung
dch NaOH 1,8 M. Khi lng mui to thnh l
( Hiu sut ca phn ng nhit phn CaCO3 l
ton b lng kh thot ra hp th ht

vo 500 ml dung dch NaOH 1,8 M.
Khi lng mui to thnh l ( Hiu
sut ca phn ng nhit phn CaCO3
l 95% )
HS: Chp
95% )
Gii:
CaCO3 CaO + CO2
52,65
nCO2 = nCaCO3 =
= 0,5265(mol )
100
V phn ng trn c h = 95% nn s mol CO2
thc t thu c
0,5265
HS: Tho lun lm bi
nCO2 =
.95 = 0,5002( mol )
100
nNaOH = 0,5.1,8 = 0,9 (mol)
T l s mol NaOH v CO2
n NaOH
0,9
=
<2
1<
nCO2
0,5002
t 0C
Do phn ng to 2 mui NaHCO3 v Na2CO3

CO2 + 2NaOH Na2CO3 + H2O
ly nhp lm bi
x
2x
CO2 + NaOH NaHCO3
y
y
Theo bi ra ta c :
x + y = 0,5002
2x + y = 0,9
x = 0,3998
y = 0,1004
NaHCO3 8,438 g v Na2CO3 42,38 g

Bi 2:
xc nh hm lng cacbon trong mt mu
thp khng cha lu hunh, ngi ta phi t
mu thp trong oxi d v xc nh CO2 to
thnh. Hy xc nh hm lng cacbon trong
mu thp X, bit rng khi t 10g X trong oxi d
ri dn ton b sn phm qua nc vi trong d
th thu c 0,5 g kt ta
Hot ng 2
chp vo v.
Bi 2:
xc nh hm lng cacbon trong
mt mu thp khng cha lu hunh,
ngi ta phi t mu thp trong oxi
d v xc nh CO2 to thnh. Hy xc
nh hm lng cacbon trong mu
thp X, bit rng khi t 10g X trong
oxi d ri dn ton b sn phm qua
Gii
nc vi trong d th thu c 0,5 g
C
+
O
CO
2
2
kt ta
0,005
0,005 (mol)
HS: Chp
CO
+
Ca(OH)
2
2 CaCO3 + H2O
GV: Gi hng dn HS cch gii,
0,005
0,005 (mol)
nC = nCO2 = 0,005(mol ); mC = 12.0,005 = 0,06( g )
ly nhp lm bi
%C =
0,06
.100% = 0,6%
10
Bi 3:
C a gam hn hp bt X gm CuO, Al2O3 .
Hot ng 3
Ngi ta thc hin cc th nghim sau:
Th nghim 1: Cho X phn ng hon ton vi
chp vo v.
dung dch HCl, c cn dung dch thu c 4,02
Bi 3:
g cht rn khan.
C a gam hn hp bt X gm CuO,
Th nghim 2: Cho X phn ng va vi bt
H:01:26H:01:26H:01:26
Al2O3 . Ngi ta thc hin cc th

nghim sau:
Th nghim 1: Cho X phn ng hon
ton vi dung dch HCl, c cn dung
dch thu c 4,02 g cht rn khan.
Th nghim 2: Cho X phn ng va
vi bt cacbon nhit cao th thu
c 0,112 lt kh (kt)
Tnh a ?
cacbon nhit cao th thu c 0,112 lt kh

(kt)
Tnh a ?
m AlCl3 = 4,02 1,35 = 2,67( g )
Gii
CuO + 2HCl
CuCl2 + H2O
0,01
0,01
Al2O3 + 6HCl
2AlCl3 + 3H2O
0,01
0,02
2CuO + C
2Cu + CO2
GV: Yu cu 1 HS ln bng trnh by. 0,01
0,005 (mol)
0,112
nCO2 =
= 0,005(mol )
bn
22,4
HS:Ln bng trnh by
mCuCl2 = 0,01.135 = 1,35( g )
2,67
= 0,02(mol )
133,5
a = 80.0,01 + 102.0,01 = 1,82 (g)
n AlCl3 =
Hot ng 4: Cng c - dn d: Chun b bi Silic v hp cht ca silic
Tit 13: BI TP SILIC V HP CHT CA SILIC

I. Mc tiu:
II. Trng tm:
Bi tp silic v hp cht ca silic
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp cc bi silic v cc hp cht ca silic
IV.Tin trnh ln lp:
1/ n nh lp:
-Lp 11B2:Ngy ging..Tng s.......
2/ Bi c: Trnh by thnh phn, phng php sn xut ximng.
3/ Bi mi
Hot ng ca thy v tr
Ni dung
Hot ng 1:
Bi 1:
GV: Chp ln bng, yu cu HS T silic ioxit v cc cht cn thit khc, hy vit
chp vo v.
phng trnh u ch axit silixic
Bi 1:
T silic ioxit v cc cht cn thit
khc, hy vit phng trnh u ch
axit silixic
Gii
H:01:26H:01:26H:01:26
HS: Chp
GV: Yu cu 1 HS ln bng trnh by
ly nhp lm bi
Hot ng 2:
chp vo v.
Bi 2:
Vit cc phng trnh ha hc theo s
sau.
Silic ioxit natri silicat axit silixic
silic ioxit silic
HS: Chp
HS: Tho lun lm bi
GV: Gi 1 HS ln bng gii
HS: 1 HS ln bng trnh by, cc HS
cn li ly nhp lm bi
Hot ng 3:
chp vo v.
Bi 3:
Khi t chy hn hp kh SiH4 v CH4
thu c mt sn phm rn cn nng
6 g v sn phm kh. Cho sn phm
kh i qua dung dch Ca(OH)2 ly d
thu c 30 g kt ta. Xc nh thnh
phn % th tch ca hn hp kh
bn
HS:1 HS ln bng trnh by
Hot ng 4:
chp vo v.
Bi 4:
Cho hn hp silic v than c khi
lng 20 gam tc dng vi lng d
dung dch NaOH c, un nng. Phn
ng gii phng ra 13,44 lt kh hiro
( ktc). Xc nh thnh phn % khi
lng ca silic trong hn hp ban u,
hiu sut phn ng 100%.
H:01:26H:01:26H:01:26
t
SiO2 + 2NaOH
Na2SiO3 + H2O
Na2SiO3 + 2HCl
H2SiO3 + 2NaCl
Bi 2:
Silic ioxit natri silicat axit silixic silic
ioxit silic
Gii:
SiO2 + 2NaOH Na2SiO3 + H2O
Na2SiO3 + 2HCl H2SiO3 + 2NaCl
t0
H2SiO3
SiO2 + H2O
t0
2Mg + SiO2
Si + 2MgO
t0
Bi 3:
Khi t chy hn hp kh SiH4 v CH4 thu c
mt sn phm rn cn nng 6 g v sn phm
kh. Cho sn phm kh i qua dung dch
Ca(OH)2 ly d thu c 30 g kt ta. Xc nh
thnh phn % th tch ca hn hp kh
Gii
SiH4 + 2O2 SiO2 + 2H2O
(1)
CH4 + 2O2
2CO2 + 2H2O
(2)
CO2 + Ca(OH)2
CaCO3 + H2O (3)
6
30
n SiO 2 =
= 0,1(mol); n CaCO 3 =
= 0,3(mol)
60
100
n SiH 4 = n SiO 2 = 0,1(mol)
(1)
(2) , (3) n CH 4 = n CaCO 3 = 0,3(mol)
0,1
%VSiH 4 =
.100% = 25%
0,1 + 0,3
%VCH 4 = 100% 25% = 75%
Bi 4:
Cho hn hp silic v than c khi lng 20 gam
tc dng vi lng d dung dch NaOH c,
un nng. Phn ng gii phng ra 13,44 lt kh
hiro ( ktc). Xc nh thnh phn % khi lng
ca silic trong hn hp ban u, hiu sut phn
ng 100%.
Gii
Si + 2NaOH + H2O
Na2SiO3 + 2H2
1
13,44
n Si = n H 2 =
= 0,3(mol)
2
2.22,4
Cc HS cn li lm v theo di bi ca mSi = 28.0.3 = 8,4 (g)

bn
8,4
%Si =
.100% = 42%
HS: 1 HS ln bng trnh by
20
* Cng c:
1/ Silic phn ng c vi tt c cc cht trong dy no sau y
A. O2, C, F2, Mg, HCl, NaOH
B. O2, C, F2, Mg, NaOH
C. O2, C, F2, Mg, HCl, KOH
D. O2, C, F2, Mg, HCl, NaOH
2/ SiO2 tc dng c vi axit no di y
A. HCl
B. HNO3
C. HF
D. HI
3/ Cho cc cht sau
1. MgO
2. C
3. KOH
4. HF
5. HCl
Silic ioxit phn ng c vi tt c cc cht trong nhm no sau y
A. 1, 2, 3, 4, 5
B. 1, 2, 3, 5
C. 1, 3, 4, 5
D. 1, 2, 3, 4
4/ Silic v nhm u phn ng c vi dd cc cht trong dy no sau y
A. HCl, HF
B. NaOH, KOH
C. Na2CO3, KHCO3
D. BaCl2, AgNO3
Dn d: Chun b bi Luyn tp
Tit 14: BI TP TNG KT CHNG CACBON - SILIC

I. Mc tiu:
II. Trng tm:
Bi tp tng kt chng cacbon - Silic
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp cc bi cacbon - silic
IV.Tin trnh ln lp:
1/ n nh lp:
2/ Bi c: Khng kim tra
3/ Bi mi:
H:01:26H:01:26H:01:26
Hot ng ca thy v tr
H:01:26H:01:26H:01:26
Ni dung
Hot ng 1:
chp vo v.
Bi 1:
a/ Hp th hon ton 0,224 lt
CO2(ktc) vo 2 lt dung dch Ca(OH)2
0,01M th c bao nhiu gam kt ta
b/ Gii li cu a nu th tch CO2 l
560ml (ktc)
c/ Hp th hon ton V lt CO2(ktc)
vo 2 lt dung dch Ca(OH)2 0,01M th
c 1 gam kt ta. Tm V.
HS: Chp
Bi 1:
a/ Hp th hon ton 0,224 lt CO2(ktc) vo 2 lt
dung dch Ca(OH)2 0,01M th c bao nhiu
gam kt ta
b/ Gii li cu a nu th tch CO2 l 560ml (ktc)
c/ Hp th hon ton V lt CO2(ktc) vo 2 lt
dung dch Ca(OH)2 0,01M th c 1 gam kt
ta. Tm V.
Gii:
0,224
= 0,01(mol )
a/ nCO2 =
22,4
nCa ( OH ) 2 = 2.0,01 = 0,02(mol )
CO2 + Ca(OH)2 CaCO3 + H2O
0,01 0,01
0,01
nCO2 < nCa (OH ) 2
HS: Tho lun lm bi
Ca(OH)2 d
Khi lng CaCO3 l 100.0,01 = 1 gam
0,56
= 0,025(mol )
GV: Cho HS xung phong ln bng gii b/ nCO2 =
22,4
nCO2
0,025
=
= 1,25 < 2
1<
nCa ( OH ) 2
0,02
ly nhp lm bi
a
a
2CO2 + Ca(OH)2 Ca(HCO3)2
2b
b
Theo bi ra ta c:
a + b = 0,02
a = 0,005
a + 2b = 0,025
b = 0,015
Khi
lng
CaCO
3 l 100.0,015 = 1,5 gam
c/ nCa ( OH ) 2 = 2.0,01 = 0,02(mol )
1
= 0,01( mol )
100
< nCa (OH ) 2 nn c hai trng hp
nCaCO3 =
nCaCO3
TH1:
0,01 0,01
0,01
Th tch CO2 l: 0,01.22,4 = 0,224 (lt)
TH2:
0,02 0,02
0,02
CO2 + CaCO3 + H2O Ca(HCO3)2
0,01
0,01
Th tch CO2 l: 0,03.22,4 = 0,672 ( lt)
Bi 2:
Hot ng 2:
GV: Chp ln bng, yu cu HS Nung 16,8 gam hn hp X gm MgCO3 v
CaCO3 n khi lng khng i, ri dn kh thu
chp vo v.
c vo 180ml dung dch Ba(OH)2 1M th thu
Bi 2:
Nung 16,8 gam hn hp X gm MgCO3 c 33,49 gam kt ta. Xc nh thnh phn %
v CaCO3 n khi lng khng i, khi lng cc cht trong X.
ri dn kh thu c vo 180ml dung
H:01:26H:01:26H:01:26
dch Ba(OH)2 1M th thu c 33,49 Gii

gam kt ta. Xc nh thnh phn % Gi x, y ln lt s mol MgCO3 v CaCO3 trong
khi lng cc cht trong X.
X
t0
HS: Chp
MgCO3
MgO + CO2 (1)
x
x
t0
CaCO3 CaO + CO2 (2)
y
y
33,49
n BaCO3 =
= 0,17(mol )
197
n BaCO3 < n Ba (OH ) 2 nn c hai trng hp
TH1:
CO2 + Ba(OH)2 BaCO3 + H2O
0,01 0,01
0,01
(mol)
HS: Ln bng trnh by, cc HS cn li Theo bi ra ta c:
ly nhp lm bi
x + y = 0,17
x = 0,0125
84x+ 100y = 16,8
y = 0,1575
% CaCO3 = 93,75%
% MgCO3 = 6,25%
TH2:
CO2 + Ba(OH)2 BaCO3 + H2O
0,18 0,18
0,18
(mol)
CO2 + BaCO3 + H2O Ba(HCO3)2
0,01
0,01
(mol)
Theo bi ra ta c:
x + y = 0,19
x = 0,1375
84x+ 100y = 16,8
y = 0,0525
% CaCO3 = 31,25%
% MgCO3 = 68,75%
Bi 3:
Cho 15 gam hn hp gm Silic v Cacbon vo
dung dch NaOH c nng, thot ra 2,24 lt kh
Hot ng 3:
H2 (ktc).Tnh thnh % khi lng Cacbon trong
hn hp.
chp vo v.
Gii
Bi 3:
Si + 2NaOH + H2O Na2SiO3 + 2H2
Cho 15 gam hn hp gm Silic v
2,24
Cacbon vo dung dch NaOH c
nH2 =
= 0,1(mol )
22,4
nng, thot ra 2,24 lt kh H2 (ktc).Tnh
thnh % khi lng Silic trong hn
nSi = 0,05(mol)
hp.
mSi = 0,05.28 = 1,4(g)
HS: Chp
%Si =9,3%
bn
HS:Ln bng trnh by
* Cng c:Cho 1,84 g hn hp 2 mui gm XCO3 v YCO3 tc dng ht vi dung dch HCl
thu c 0,672 lt CO2 (ktc) v dung dch A. Khi lng mui trong dung dch A l
A. 1,17
B. 2,17
C. 3,17
D. 2,71
* Dn d: Chun b bi M u v ha hc hu c
H:01:26H:01:26H:01:26
Tit 15: BI TP LP CTPT HP CHT HU C

I. Mc tiu:
II. Trng tm:
Bi tp lp cng thc phn t hp cht hu c
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp lp cng thc phn t hp ht hu c
IV.Tin trnh ln lp:
1/ n nh lp :
2/ Bi c: Trnh by cc cch lp CTPT hp cht hu c
Bi tp vn dng: 3/sgk trang 95
3/ Bi Mi
Hot ng ca thy v tr
Hot ng 1:
chp vo v.
Bi 1:
t chy hon ton 2,2 g cht hu
c A, ngi ta thu c 4,4 g CO2 v
1,8 g H2O.
a/ Xc nh cng thc n gin nht
ca A.
b/ Xc nh CTPT ca A bit rng khi
lm bay hi 1,1 g cht A th th tch
hi thu c ng bng th tch ca
0,4 g kh O2 cng iu kin nhit
v p sut.
HS: Chp
HS: Tho lun lm bi
GV: Cho HS xung phong ln bng
gii
HS: Ln bng trnh by, cc HS cn
li ly nhp lm bi
Ni dung
Bi 1:
t chy hon ton 2,2 g cht hu c A, ngi ta
thu c 4,4 g CO2 v 1,8 g H2O.
a/ Xc nh cng thc n gin nht ca A.
b/ Xc nh CTPT ca A bit rng khi lm bay hi
1,1 g cht A th th tch hi thu c ng bng
th tch ca 0,4 g kh O2 cng iu kin nhit
v p sut.
Gii:
4,4
.12 = 1,2g
a/ m C =
44
1,8
mH =
.2 = 0,2g
18
mO= 2,2 1,2 0,2 = 0,8 g
Gi CTGN l CxHyOz ( x, y, z nguyn dng)
1,2 0,2 0,8
:
:
= 2 : 4 :1
x: y : z =
12 1 16
CTGN l C2H4O
b/S mol A trong 1,1 g A = smol O 2 trong 0,4 g O2 =
0,4
1,1
= 0,0125(mol ); M A =
= 88(g/mol)
32
0,0125
( C2H4O)n = 88 44n =88 n =2
CTPT l C4H8O2
Hot ng 2:
Bi 2:
GV: Chp ln bng, yu cu HS t chy hon ton 4,1 g cht hu c A ngi ta
chp vo v.
thu c 2,65 g Na2CO3, 1,35 g nc v 1,68 lt
Bi 2:
CO2
( ktc). Xc nh cng thc n gin nht
t chy hon ton 4,1 g cht hu ca A.
c A ngi ta thu c 2,65 g
Gii
H:01:26H:01:26H:01:26
Na2CO3, 1,35 g nc v 1,68 lt CO2 ( Cht A chc chn c C, H, Na, c th c O

ktc). Xc nh cng thc n gin Khi lng C trong 1,68 lt CO2:
nht ca A.
12.1,68
= 0,9( g )
HS: Chp
22,4
Khi lng C trong trong 2,65 g Na2CO3:
GV: Gi hng dn HS cch gii, 12.2,65
= 0,3( g )
106
HS: Ln bng trnh by, cc HS cn Khi lng C trong 4,1 g cht A:
li ly nhp lm bi
0,9 + 0,3 = 1,2(g)
Khi lng Na trong 2,65 g Na2CO3:

46.2,65
= 1,15( g )
106
Khi lng H trong 1,35 g H2O:
2.1,35
= 0,15( g )
18
Khi lng O trong 4,1 g A: 4,1 -1,2 0,15 1,15
= 1,6 (g)
Cht A c dng CxHyOzNat:
1,2 0,15 1,6 1,15
:
:
:
= 2 : 3 : 2 :1
x: y : z : t =
12 1 16 23
CTGN l C2H3O2Na
Bi 3:
Hot ng 3:
t chy hon ton 4,45 g hp cht A cn
GV: Chp ln bng, yu cu HS dung va ht 4,2 lt O2. Sn phm chy gm c
chp vo v.
3,15 g H2O v 3,92 lt hn hp kh gm CO2 v N2
Bi 3:
(ktc). Xc nh CTGN ca A.
t chy hon ton 4,45 g hp
cht A cn dung va ht 4,2 lt O2.
Gii
Sn phm chy gm c 3,15 g H2O
Theo nh lut bo ton khi lng
v 3,92 lt hn hp kh gm CO2 v
m CO2 + m N 2 = m A + mO2 m H 2O =
N2 (ktc). Xc nh CTGN ca A.
4,2
HS: Chp
4,45 +
.32 3,15 = 7,3( g )
GV: Yu cu 1 HS ln bng trnh
22,4
by. Cc HS cn li lm v theo di
bi ca bn
t s mol CO2 l a , s mol N2 l b, ta c:
a + b = 0,175
HS:Ln bng trnh by
44a + 28b =7,3
a = 0,15; b = 0,025
Khi lng C: 0,15.12 = 1,8 (g)
2.3,15
= 0,35( g )
Khi lng H:
18
Khi lng : 0,025.28 = 0,7 (g)
Khi lng O: 4,48 1,8 0,35 - 0,7 = 1,6 (g)
Cht A c dng CxHyNzOt
1,8 0,35 0,7 1,6
:
:
= 3 : 7 :1: 2
x: y : z : t = :
12 1 14 16
CTGN l C3H7NO2
* Cng c:Hp cht X c % khi lng cacbon, hiro v oxi ln lt bng 54,54%, 9,1%
v 36,36 %. MX = 88g/mol. CTPT ca X l
A. C4H10O
C. C4H8O
C. C5H12O
D. C4H10O2
* Dn d: Chun b bi cu trc phn t hp cht hu c
H:01:27H:01:27H:01:27
Tit 16: T
CHN
Ch : BI TP CU TRC PHN T HP CHT HU C
I.
II.
Mc tiu:
Trng tm:
Bi tp cu trc phn t hp cht hu c
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp cu trc phn t hp ht hu c
IV.Tin trnh ln lp:
Hot ng 1: n nh lp :
Bi c: Trnh by ni dung thuyt cu to ha hc. V d minh ha
Trnh by khi nim ng ng, ng phn. V d minh ha
Hot ng ca thy v tr
Hot ng 2:
chp vo v.
Bi 1:
Trong cc cht di y, cht no
l ng ng ca nhau? cht no l
ng phn ca nhau?
1. CH3CH2CH3
2. CH3CH2CH2Cl
3. CH3CH2CH2CH3
4. CH3CHClCH3
5. (CH3)2CHCH3
6. CH3CH2CH=CH2
7. CH3CH=CH2
8. CH2-CH2
CH2-CH2
9. CH3
C=CH2
CH3
HS: Chp
HS: Tho lun lm bi
gii
li ly nhp lm bi
Hot ng 3:
chp vo v.
H:01:27H:01:27H:01:27
Ni dung
Bi 1:
Trong cc cht di y, cht no l ng ng
ca nhau? cht no l ng phn ca nhau?
10. CH3CH2CH3
11. CH3CH2CH2Cl
12. CH3CH2CH2CH3
13. CH3CHClCH3
14. (CH3)2CHCH3
15. CH3CH2CH=CH2
16. CH3CH=CH2
17. CH2-CH2
CH2-CH2
18. CH3
C=CH2
CH3
Gii:
+ Cc cht ng ng:
(1) v (3); (1) v (5); (6) v (7); (7) v (9)
+ Cc cht ng phn:
(2) v (4); (3) v (5); (6) v (7); (6), (8) v (9)
Bi 2:
Khi t chy 1,5 g ca mi cht A hoc B hoc D
u thu c sn phm gm 0,9 g nc v 2,2 g
Bi 2:
Khi t chy 1,5 g ca mi cht A
hoc B hoc D u thu c sn
phm gm 0,9 g nc v 2,2 g kh
CO2. Ba cht trn c phi l ng
phn ca nhau khng? Cho v d.
HS: Chp
GV: Gi hng dn HS cch gii
HS: ch nghe hiu
GV: ly v d minh ha
kh CO2. Ba cht trn c phi l ng phn ca

nhau khng? Cho v d.
Gii
V cc cht c cng s mol C ( cng khi lng
CO2), cng s mol H ( cng khi lng nc) v
cng s mol oxi trong cng mt lng mi cht c
ngha l 3 cht c cng thc n gin ging nhau.
Nu 3 cht c cng phn t khi na th chng mi
l ng phn ca nhau.
V d: Ba cht l axit axetic C2H4O2, glucoz
C6H12O6 v anehitfomic khng phi l ng phn
ca nhau mc d u c cng thc n gin l
CH2O; khi t 30 g mi cht u sinh ra 1 mol CO2
v 1 mol nc.
Bi 3:
Hn hp kh A cha hai hirocacbon k tip nhau
trong mt dy ng ng. Ly 1,12 lt A (ktc) em
t chy hon ton. Sn phm chy c dn qua
bnh (1) ng H2SO4 (c), sau qua bnh (2)
ng dung dch NaOH ( c d). Sau th nghim,
khi lng bnh (1) tng 2,16 g v bnh (2) tng
7,48g. Hy xc nh CTPT v % v th tch ca
tng cht trong hn hp A.
Hot ng 4:
chp vo v.
Bi 3:
Hn hp kh A cha hai
hirocacbon k tip nhau trong mt
dy ng ng. Ly 1,12 lt A (ktc)
em t chy hon ton. Sn phm
chy c dn qua bnh (1) ng
H2SO4 (c), sau qua bnh (2)
ng dung dch NaOH
( c d).
Sau th nghim, khi lng bnh (1)
tng 2,16 g v bnh (2) tng 7,48g.
Hy xc nh CTPT v % v th
Gii
tch ca tng cht trong hn hp A. Hai hirocacbon k tip nhau trong dy ng ng
HS: Chp
c CTPT l CxHy v Cx+1Hy + 2
Gi a l s mol CxHy
Gi b l s mol Cx+1Hy + 2
Ta c: a + b = 0,05 (1)
y
y
CxHy + (x + )O 2 xCO 2 + H 2 O
4
2
a
ax
y/2a
HS: ch nghe hiu
y
y+2
C x +1 H y + 2 + (x + + 1,5)O 2 (x + 1)CO 2 +
H 2O
4
2
y+2
b
(x + 1)b
b
2
S mol CO2: ax + b(x + 1) = 0,17 (2)
ay + b(y + 2)
= 0,12 (3)
S mol H2O:
2
T (2) ta c (a + b)x + b =0,17
b = 0,17 - 0,05x
b l s mol a mt trong hai ht nn 0 < b < 0,05
Do 0 < 0,17 0,05x < 0,05
2,4 < x < 3,4 x = 3
b =0,17 (0,05.3)=0,02 a =0,05 0,02 = 0,03
Thay gi tr ca a v b vo (3) ta c:
0,03y + 0,02( y + 2) = 0 y = 4
CTPT ca 2 cht l C3H4, C4H6
% v th tch ( cng l % v s mol) ca C3H4 trong
H:01:27H:01:27H:01:27
0,03
.100% = 60%
0,05
% v th tch ca C4H6 trong hn hp l 40%
hn hp A.
* Cng c:
Cht no di y l ng phn ca CH3COOCH3?
A. CH3CH2OCH3
B. CH3CH2COOH
C. CH3COCH3
D. CH3CH2CH2OH
* Dn d: Chun b bi Luyn tp
BTVN: Hn hp M th lng,cha 2 hp cht hu c k tip nhau trong mt dy
ng ng. Nu lm bay hi 2,58g M th th tch hi thu c ng bng th tch ca 1,4 g
kh N2 cng iu kin.
t chy hon ton 6,45 g M th thu c 7,65 g H2O v 6,72 lt CO2(ktc). Xc nh CTPT
v % khi lng ca tng cht trong hn hp M.
H:01:27H:01:27H:01:27
Tit 17: T
CHN
Ch : N TP HC K I
III.
IV.
Mc tiu:
Trng tm:
n tp cc bi tp tnh pH, lin quan ti HNO3, nhn bit, s phn ng
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp tnh pH, lin quan ti HNO3, nhn bit, s phn
ng
IV.Tin trnh ln lp:
Hot ng 1: n nh lp + Bi c
Bi c: Trnh by tnh oxi ha ca HNO3. Cho v d minh ha
Hot ng ca thy v tr
Hot ng 2:
chp vo v.
Bi 1:
Trn 200 ml dung dch HCl 0,1 M vi
800ml dung dch HNO3 0,01M. Tnh pH
ca dung dch thu c
HS: Chp
Ni dung
Bi 1:
Trn 200 ml dung dch HCl 0,1 M vi 800ml
dung dch HNO3 0,01M. Tnh pH ca dung dch
thu c
Gii:
Nng cc cht sau khi pha trn
200.0,1
= 0,02 M
CHCl =
200 + 800
HS: Tho lun lm bi
800.0,01
C HNO3 =
= 0,008 M
200 + 800
Phng trnh in li
HCl H+ + Cl0,02 0,02
(M)
+
HNO3
H + NO3ly nhp lm bi
0,008 0,008 (M)
Tng nng ion H+ = 0,028M
pH = -lg0,028 =1,55
Bi 2:
Hot ng 3:
Ha tan hon ton 5,6 g Fe vo dung dch HNO3
c nng, thu c V lt kh (ktc).
chp vo v.
Tm V
Bi 2:
Ha tan hon ton 5,6 g Fe vo dung
Gii
dch HNO3 c nng, thu c V lt kh
Fe
+
6HNO
Fe(NO
3
3)3 + 3NO2 + 3H2O
(ktc). Tm V
0,1
0,3
(mol)
HS: Chp
GV: Gi hng dn HS cch gii, n = 5,6 = 0,1(mol) n
Fe
NO 2 = n Fe = 0,3(mol)
56
HS: Ln bng trnh by, cc HS cn li VNO 2 = 0,3.22,4 = 6,72(l)
ly nhp lm bi
Hot ng 4:
Bi 3:
GV: Chp ln bng, yu cu HS Nhit phn 66,2 gam Pb(NO ) thu c 55,4
3 2
chp vo v.
gam thu c 55,4 gam cht rn. Tnh hiu sut
Bi 3:
ca phn ng phn hy.
H:01:27H:01:27H:01:27
Nhit phn 66,2 gam Pb(NO3)2 thu

c 55,4 gam thu c 55,4 gam
cht rn. Tnh hiu sut ca phn ng
phn hy.
HS: Chp
bn
HS:Ln bng trnh by
Hot ng 5:
chp vo v.
Bi 4:
Ch dng mt ha cht duy nht
phn bit cc l mt nhn ng cc
dung dch sau: NaCl, Na2SO4, NH4Cl,
(NH4)2SO4
HS: Chp
GV: Hng dn HS cch gii, yu cu
HS trnh by
HS:Ln bng trnh by
GV: Gi HS nhn xt
Gii
Pb(NO3)2
PbO+ 2NO2 + 1/2O2
x
2x
x/2
Gi x l s mol Pb(NO3)2 nhit phn
Khi lng kh thot ra = 2x.46 + 0,5x.32 = 66,2
55,4 = 10,8 x = 0,1 (mol)
Hiu sut ca phn ng l:
0,1
.100% = 50%
H=
0,2
Bi 4:
Ch dng mt ha cht duy nht phn bit
cc l mt nhn ng cc dung dch sau: NaCl,
Na2SO4, NH4Cl, (NH4)2SO4
Gii
- Trch mi l ra mt t lm mu th
- Cho Ba(OH)2 ln lt vo cc mu th
+ Mu th khng c hin tng: dung dch
NaCl
+ Mu th c kt ta trng : dung dch Na2SO4
Na2SO4 + Ba(OH)2 BaSO4 + 2NaOH
+ Mu th c kh mi khai : dung dch NH4Cl
2NH4Cl + Ba(OH)2 BaCl2 + 2NH3 + 2H2O
+ Mu th c kt ta trng, c kh mi khai :
dung dch (NH4)2SO4
(NH4)2SO4 + Ba(OH)2 BaSO4 + 2NH3 + 2H2O
Bi 5: Hon thnh s phn ng sau.

0
NaOH
C
A 3000
B C D NaNO3
0
C
N2 + O2 3000
2NO
2NO + O2
2NO2
Hot ng 6:
4NO2 + O2 + 2H2O 4HNO3
HNO3 + NaOH NaNO3 + H2O
chp vo v.
Vy A l N2, B l NO, C l NO2, D l HNO3
Bi 5: Hon thnh s phn ng
sau.
0
NaOH
C
A 3000
B C D NaNO3
HS: Chp
GV: yu cu 1HS trnh by
HS:Ln bng trnh by
GV: Gi HS nhn xt, ghi im.
Hot ng7: Cng c - dn d
* Cng c:
- Cc bi tp tnh pH, lin quan ti HNO3, nhn bit, s phn ng
- Cho 4,8 gam Cu kim loi vo dung dch HNO3 long d n khi phn ng xy ra hon
ton. Lng kh thot ra iu kin chun l
A. 2,24 lt
B. 6,72 lt
C. 1,12 lt
D. 3,36 lt
+
3+
- nhn bit s c mt ca 3 ion Fe , NH 4 , NO 3 c trong dung dch ta c th dng cht
no sau y
H:01:27H:01:27H:01:27
A. NaOH
B. H2SO4
C. Qu tm
D. CaO
t0
- Cho phn ng:2NH4Cl + Ca(OH)2 CaCl2 + A +2H2O. A l cht kh no di
y
A. N2
B. NH3
C. H2
D. N2O
* Dn d: n tp chun b kim tra hc k I
Tit 18: T CHN
Ch : BI
V.
VI.
TP ( Sa bi kim tra hc k I )
Mc tiu:
Trng tm:
Hng dn hc sinh li cc cu trc nghim, gii li cc bi tp
III. Chun b:
GV:Gio n
HS: Xem li bi trc nh
IV.Tin trnh ln lp:
Hot ng 1: n nh lp + Bi c
Bi c: Khng kim tra
Hot ng ca thy v
tr
Hot ng 2:
I.Trc nghim
GV: Yu cu HS tr li li M : 483
cc cu trc nghim
1
HS:Tr li
A
B
C
D
Ni dung
10
11
Hot ng 3:
GV: Hng dn HS cch
tnh im tng cu ca
phn t lun.
Hot ng 4:
GV: Pht bi cho HS
GV: Yu cu HS xem li
tng phn theo thang
im
* Cng c:
Nhc li HS cch lm bi v rt kinh nghim
* Dn d: Chun b bi Ankan
13
14
15
16
x
x
12
x
x
GV: nhn xt hng dn

li
II.T lun:
H:01:27H:01:27H:01:27
x
x
x
x
Ngy son:28/12/2009
Tit 17: BI TP ANKAN

I. Mc tiu:
Bi tp ankan
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp ankan
III.Tin trnh ln lp:
1.n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
H:01:27H:01:27H:01:27
Ghi ch
11B6
2. Kim tra bi c
Bi c: Trnh by cch gi tn mch cacbon phn nhnh. Gi tn CTCT sau
CH3 CH - CH2 CH CH2 CH2 CH3
CH3
C2H5
3. Bi mi
Hot ng ca thy v tr
Ni dung
Hot ng 1:
chp vo v.
Bi 1: Gi tn cc CTCT sau
CH3 CH2 CH CH2 CH3
CH CH3
CH3
CH3
CH3 CH2 CH CH2 CH CH3
CH CH3 CH3
CH3
HS: Chp
HS: Tho lun lm bi
gii
li ly nhp lm bi
Hot ng 2:
chp vo v.
Bi 2:
Vit CTCT thu gn ca
a/ 4-etyl-2,3,3-trimetylheptan
b/ 3,5-ietyl-2,2,3-trimetyloctan
HS: Chp
HS: Ln bng trnh by
GV: Nhn xt ghi im
Hot ng 3
chp vo v.
Bi 3:
Cht A l mt ankan th kh. t
chy hon ton 1,2 lt A cn dng va
ht 6 lt oxi cng iu kin.
a/ Xc nh CTPT ca A.
b/ Cho cht A tc dng vi kh clo
250C v c nh sng. Hi c th thu
c my dn xut monoclo ca
A.Cho bit tn ca mi dn xut .
H:01:27H:01:27H:01:27
CH3 CH2 CH CH2 CH3
CH CH3
CH3
CH3
CH3 CH2 CH CH2 CH CH3
CH CH3 CH3
CH3
Gii:
+ 3-etyl -2-metylpentan.
+ 4-etyl-2,2,5-trimetylhexan
Bi 2: Vit CTCT thu gn ca

a/ 4-etyl-2,3,3-trimetylheptan
b/ 3,5-ietyl-2,2,3-trimetyloctan
Gii
a/
CH3
CH3 CH C CH CH2 CH2 CH3
CH3 CH3 CH2
CH3
b/
CH3 CH3
CH3 C C - CH2 CH CH2 CH2 CH3
CH3 CH2
CH2
CH3
CH3
Bi 3:
Cht A l mt ankan th kh. t chy hon ton
1,2 lt A cn dng va ht 6 lt oxi cng iu kin.
a/ Xc nh CTPT ca A.
b/ Cho cht A tc dng vi kh clo 250C v c nh
sng. Hi c th thu c my dn xut monoclo
ca A.Cho bit tn ca mi dn xut . Dn xut
no thu c nhiu hn.
Gii
Dn xut no thu c nhiu hn.

HS: Chp
HS: Ln bng trnh by
CnH2n + 2 +
1,2lt
3n + 1
t
O2
nCO2 + (n+1)H2O
2
6 lt
6
3n + 1
=5n=3
=
1,2
2
CTPT ca A l C3H8
CH3 CH2 CH3 + Cl2
Hot ng4
chp vo v.
Bi 4:
t chy hon ton 1,45 gam mt
ankan phi dng va ht 3,64 lt
O2( ktc)
a/ Xc nh CTPT ca ankan
b/ Vit CTCT v gi tn tt c cc
ng phn ng vi cng thc .
HS: Chp
HS: Ln bng trnh by
as
CH3 CH2 CH2 - Cl

1- clopropan (43%) + HCl
CH3 CHCl CH3
2- clopropan (57%)
Bi 4:
t chy hon ton 1,45 gam mt ankan phi dng
va ht 3,64 lt O2( ktc)
a/ Xc nh CTPT ca ankan
b/ Vit CTCT v gi tn tt c cc ng phn ng
vi cng thc .
Gii
3n + 1
t
CnH2n + 2 +
O2
nCO2 + (n+1)H2O
2
3n + 1
(14n + 2)g
(mol)
2
1,45 g
0,1625 (mol)
14n + 2
3n + 1
=
n=4
1,45
2.0,1625
CTPT ca A l C4H10
CH3 CH2 CH2 CH3
Butan
CH3 CH CH3
CH3
Isobutan (2-metylpropan)
IV Cng c : Cng c - dn d
* Cng c:
Nhc li cch gi tn mch cacbon phn nhnh. Cho tn gi vit CTCT
V. Dn d: Chun b bi Xicloankan
BTVN: t chy hon ton 2,86 g hn hp gm hexan v octan ngi ta thu c 4,48 lt
CO2 ( ktc). Xc nh % v khi lng ca tng cht trong hn hp.
Ngy son:28/12/2009
Tit 18: BI TP XICLOANKAN

I. Mc tiu:
Bi tp Xicloankan
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp Xicloankan
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
11B1
H:01:27H:01:27H:01:27
Ghi ch
11B2
11B5
11B6
2. Bi c
Bi c: Trnh by tnh cht ha hc ca xicloankan. Ly v d minh ha
3. Bi mi:
Hot ng ca thy v tr
Ni dung
Hot ng 1:
chp vo v.
C2H5
C2H5
H3C
H3C
CH3
CH3
Gii:
HS: Chp
HS: Tho lun lm bi
ly nhp lm bi
Hot ng 2:
chp vo v.
a/ 1,1-imetylxiclopropan
b/ 1-etyl-1-metylxiclohexan
HS: Chp
HS: Tho lun lm bi
ly nhp lm bi
Hot ng 3:
chp vo v.
Bi 3: Mt monoxicloankan c t khi
hi so vi nit bng 3.
a/ Xc nh CTPT ca A.
b/Vit CTCT v tn tt c cc
xicloankan ng vi CTPT tm c
HS: Chp
GV: Yu cu HS ln bng trnh by cu
a
HS: Ln bng trnh by
GV: Hng dn HS vit cc CTCT ca
C6H12
HS: Ch cch vit ng phn
H:01:27H:01:27H:01:27
4-etyl-1,2-imetylxiclohexan

a/ 1,1-imetylxiclopropan
b/ 1-etyl-1-metylxiclohexan
Gii
a/
CH3
CH3
b/
CH3
CH2CH3
Bi 3:
Mt monoxicloankan c t khi hi so vi nit
bng 3.
a/ Xc nh CTPT ca A.
b/Vit CTCT v tn tt c cc xicloankan ng
vi CTPT tm c
Gii
a/ CnH2n = 28.3 = 84
14n = 84 n = 6
CTPT: C6H12
b/ Cc CTCT
CH3
GV: Yu cu HS gi tn cc ng phn
xiclohexan metylpentan
HS: Gi tn cc ng phn
CH3
CH3
CH3
1,1-dimetylxiclobutan
CH3
CH2-CH3
CH3
H3C
1,2-dimetylxiclobutan 1,3-dimetylxiclobutan etylxiclobutan
Hot ng 4:
chp vo v.
Bi 4: Hn hp kh A cha mt ankan
v mt xicloankan. T khi ca A i
vi H2 l 25,8. t chy hon ton
2,58gam A ri hp th ht sn phm
chy vo dung dch Ba(OH)2 d, thu
c 35,46 gam kt ta. Xc nh
CTPT ca ankan v xicloankan
HS: Chp
Tm MA
Vit pthh
Gi x, yln lt l s mol ca ankan,
xicloankan
Lp phng trnh
Gii phng trnh v bin lun tm n, m
HS: Lm bi theo cc bc GV
hng dn
CH3
H3C
CH3
CH3
CH3
CH3
CH3
CH2CH3
1,2,3-trimetylxiclopropan 1,1,2-trimetylxiclopropan 1-etyl-2-metylxiclopropan
CH3
CH2CH3
1-etyl-1-metylxiclopropan
CH2CH2CH3
propylxiclopropan
CHCH3
CH3
isopropylxiclopropan
Bi 4: Hn hp kh A cha mt ankan v mt
xicloankan. T khi ca A i vi H2 l 25,8. t
chy hon ton 2,58gam A ri hp th ht sn
phm chy vo dung dch Ba(OH)2 d, thu c
35,46 gam kt ta. Xc nh CTPT ca ankan v
xicloankan
Gii
Gi s trong 2,58g hn hp A c x mol CnH2n + 2
(n1) v y mol CmH2m (m3) .
MA = 25,8.2 = 51,6(g/mol)
2,58
= 0,05(1)
x+y=
51,6
CnH2n + 2 +
x
(mol)
3n + 1
t
O2
nCO2 + (n+1)H2O
2
nx
3m
t
O2
mCO2 + mH2O
2
y
my (mol)
CO2 + Ba(OH)2
BaCO3 + H2O
35,46
= 0,18(mol )
S mol CO2 = s mol BaCO3 =
197
nx + my = 0,18 (2)
CmH2m +
Khi lng hn hp A: (14n + 2)x + 14my = 2,58 (3)
14(nx + my) + 2x = 2,58 2x = 2,58

14.0,18
x = 0,03; y = 0,02
(2) ta c : 0,03n + 0,02m = 0,18 3n + 2m =
18
Nghim thch hp m = 3; n = 4
CTPT l C4H10; C3H6
IV. Cng c
Nhc li cch gi tn ca xicloankan.Cch gii bi ton tm CTPT ca ankan v

xicloankan
H:01:27H:01:27H:01:27
V. Dn d: Chun b bi v anken
Ngy son:01/01/2010
Tit 21: BI TP ANKEN

I. Mc tiu:
Bi tp anken
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp anken
III.Tin trnh ln lp:
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
2. Bi c
Vit cc CTCT ca C5H10. Gi tn cc CTCT
Trnh by tnh cht ha hc ca anken
3. Bi mi:
Hot ng ca thy v tr
Ghi ch
Ni dung
Hot ng 1:
chp vo v.
CH3
CH3
CH3 - C - CH2 - CH = CH2
CH3 - C - CH2 - CH = CH2

CH3
CH3
CH3 - CH2 - C - CH2 -CH3
CH3 - CH2 - C - CH2 -CH3
CH2
CH2
Gii:
HS: Chp
HS: Tho lun lm bi
ly nhp lm bi
Hot ng 2:
chp vo v.
Bi 2:
Vit CTCT thu gn ca 2,4imetylhex-1en
HS: Chp
HS: Tho lun lm bi
H:01:27H:01:27H:01:27
4,4 imetylpent 1- en
2-etylbut-3-en
Bi 2:
Vit CTCT thu gn ca 2,4imetylhex-1-en
Gii
CH2 = C - CH2 - CH - CH2 - CH3
CH3
CH3

ly nhp lm bi
Hot ng 3:
chp vo v.
Bi 3:
Hn hp kh A cha mt ankan v mt
anken. Khi lng hn hp A l 9 gam
v th tch l 8,96 lt. t chy hon
ton A, thu c 13,44 lt CO2. Cc th
tch c o ktc. Xc nh CTPT v
% th tch tng cht trong A.
HS: Chp
GV: Yu cu HS ln bng trnh by
HS: Ln bng trnh by
Bi 3:
Hn hp kh A cha mt ankan v mt anken.
Khi lng hn hp A l 9 gam v th tch l
8,96 lt. t chy hon ton A, thu c 13,44 lt
CO2. Cc th tch c o ktc. Xc nh
CTPT v % th tch tng cht trong A.
Gii
Gi s hn hp A c x mol CnH2n + 2 v y mol
CmH2m.
8,96
x+ y =
= 0,4(1)
22,4
(14n + 2) x + 14my = 9(2)
CnH2n + 2 +
x
(mol)
3n + 1
t
O2
nCO2 + (n+1)H2O
2
nx
3m
t
O2
mCO2 + mH2O
2
y
my (mol)
13,44
= 0,6 (3)
nx + my =
22,4
T (1), (2), (3) ta c x = 0,3; y = 0,1
Thay x, y vo (3) ta c: 3n + m = 6
Chn m = 3, n =1
CH4 chim 60% th tch A v C3H6 chim 40%
Bi 4: Dn 3,584 lt hn hp X gm 2 anken A
Hot ng 4:
v B lin tip nhau trong dy ng ng vo
nc brom (d), thy khi lng bnh ng
chp vo v.
nc brom tng 10,5 g
Bi 4:
a/ Tm CTPTca A, B ( bit th tch kh o 00C
Dn 3,584 lt hn hp X gm 2 anken
v 1,25 atm ) v tnh % th tch ca mi anken
A v B lin tip nhau trong dy ng
b/ Tnh t khi c hn hp so vi H2
ng vo nc brom (d), thy khi
lng bnh ng nc brom tng 10,5
g
a/ Tm CTPTca A, B ( bit th tch kh
o 00C v 1,25 atm ) v tnh % th
Gii
tch ca mi anken
a/ t ng thc ca 2 anken l CnH2n v Cn+1H2n+2
b/ Tnh t khi c hn hp so vi H2
Cng thc chung ca 2 anken CxH2x
HS: Chp
vi n < x < n + 1
CxH2x + Br2 CxH2xBr2
t cng thc 2 anken, cng thc
tng khi lng ca bnh ng dd chnh l
trung bnh
khi lng ca 2 anken.
Vit pthh
1,25.3,584
Tm gi tr x
n=
= 0,2(mol )
22,4
Tm CTPT ca 2 anken
10,5
Tnh % th tch ca mi anken
M = 0,2 = 52,5 = 14 x x = 3,75 n = 3
Tnh t khi c hn hp so vi H2
CmH2m +
H:01:27H:01:27H:01:27
Hai anken l C3H6 v C4H8

Gi a v b l s mol ca C3H6 v C4H8 trong hn
hp. Ta c:
HS: Lm bi theo cc bc GV a + b = 0,2
a = 0,05
hng dn
42a + 56b = 10,5
b = 0,15
%VC3 H 6 = 25%
%VC4 H 7 = 75%
b/ d X / H 2 = 26,25
IV Cng c
Nhc li cch gi tn ca anken. Tnh cht ha hc ca anken. Cch gii bi ton tm
CTPT ca 2 anken ng ng lin tip nhau.
V.Dn d:
Chun b phn cn li ca bi anken.
Ngy son:01/01/2010
Tit 22: BI TP ANKAN + ANKAIEN

I. Mc tiu
Bi tp ankan + Ankaien
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi tp ankan + Ankaien
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
11B1
11B2
11B5
11B6
2. Bi c
Trnh by tnh cht ha hc ca ankaien
3. Bi mi:
Hot ng ca thy v tr
Ni dung
Hot ng 1
Bi 1:
GV: Chp ln bng, yu cu HS chp Ankan X c cacbon chim 83,33% v khi
vo v.
lng phn t
Bi 1:
a/ Tm CTPT, vit cc CTCT c th c ca
Ankan X c cacbon chim 83,33% v
X.
khi lng phn t
b/ Khi X tc dng vi brom un nng c
a/ Tm CTPT, vit cc CTCT c th c
chiu sng c th to ra 4 dn xut ng
ca X.
phn cha mt nguyn t brom trong phn
b/ Khi X tc dng vi brom un nng c
t. Vit CTCT v gi tn
chiu sng c th to ra 4 dn xut ng
phn cha mt nguyn t brom trong
Gii:
phn t. Vit CTCT v gi tn
H:01:27H:01:27H:01:27
12n
83,33
n = 5
.
100
%
=
HS: Chp
14n + 2
100
CTPT: C5H12
HS: Tho lun lm bi
b/
GV: Cho HS xung phong ln bng gii CH - CH - CH - CH - CH
(1)
3
2
2
2
3
cu a, vit cc CTCT.
HS: Ln bng trnh by, cc HS cn li CH3 - CH - CH2 - CH3
(2)
ly nhp lm bi
a/ %C =
CH3
CH3
CH3 - C - CH3
GV: Hng dn HS chn CTCT ng khi
cho X tc dng vi brom to ra 4 dn
xut.
CH3
HS: Vit pthh minh ha
Bi 2:
(3)
Cht A l mt ankaien lin hp c mch
Hot ng 2
cacbon phn nhnh. t chy hon ton 3,4
GV: Chp ln bng, yu cu HS chp g A cn dng va ht 7,84 lt oxi (ktc). Xc nh
vo v.
CTPT , CTCT, gi tn
Bi 2:
Cht A l mt ankaien lin hp c mch
Gii
cacbon phn nhnh. t chy hon ton
3,4 g A cn dng va ht 7,84 lt oxi (ktc).
Xc nh CTPT , CTCT, gi tn
CnH2n - 2 +
3n 1
t
O2
nCO2 + (n-1)H2O
HS: Chp
0,7
0,35 (mol)
3n 1
HS: Tho lun lm bi
0,7
(14n -2).
= 3,4 n = 5
3n 1
ly nhp lm bi
CTPT: C5H8
CH2 = C - CH = CH2
CTCT:
CH3
2-metylbuta-1,3-dien
Hot ng 3
GV: Chp ln bng, yu cu HS chp
vo v.
Bi 3:
ankaien . t chy hon ton 6,72 lt
A phi dng va ht 28 lt O2 ( cc th
tch kh ly ktc). Dn sn phm chy
qua bnh 1 ng H2SO4 c, sau qua
bnh 2 ng dung dch NaOH d th khi
lng bnh 1 tng p gam, bnh 2 tng
35,2 gam.
Xc dnh CTPT, tnh p.
HS: Chp
H:01:27H:01:27H:01:27
Bi 3:
ankaien . t chy hon ton 6,72 lt A
phi dng va ht 28 lt O2 ( cc th tch kh
ly ktc). Dn sn phm chy qua bnh 1
ng H2SO4 c, sau qua bnh 2 ng
dung dch NaOH d th khi lng bnh 1
tng p gam, bnh 2 tng 35,2 gam.
Xc dnh CTPT, tnh p.
Gii
Gi s hn hp A c x mol CnH2n + 2 v y mol
CmH2m - 2.
6,72
x+ y =
= 0,3(1)
22,4
3n + 1
t
CnH2n + 2 +
O2
nCO2 + (n+1)H2O
t cng thc
ankan, cng thc
3n + 1
x
.x
nx
(n +1)x
ankaien
2
Vit pthh
3m 1
t
CmH2m - 2 +
O2
mCO2 + (m-1)H2O
Da vo d kin ra tm CTPT, tnh p

2
3m 1
y
.y
my
(m-1).y
2
3n + 1
3m 1
S mol oxi:
.x +
.y = 1,25
2
2
(3n + 1)x + (3m -1)y =2,5 (2)
35,2
= 0,8 (3)
S mol CO2: nx + my =
44
HS: Lm bi theo cc bc GV
hng dn
T (1), (2), (3) ta c x = 0,2; y = 0,1
Thay x, y vo (3) ta c: 2n + m = 8
Chn m = 4, n =2
CTPT: C2H6 v C4H6
S mol H2O = (n + 1)x + (m -1)y = 0,9(mol)
p = 0,9.18 = 16,2 (g)
IV. Cng c
Nhc li tnh cht ha hc ca ankan v ankaien. Cch gii bi ton tm CTPT ca
ankan, ankaien .
V. Chun b bi luyn tp
Ngy son:01/01/2010
Tit 23: BI TP ANKIN

I. Mc tiu:
Bi tp ankin
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp ankin
III.Tin trnh ln lp:
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
Ghi ch
2. Bi c
Trnh by tnh cht ha hc ca ankin
3. Bi mi:
Hot ng ca thy v tr
Hot ng
H:01:27H:01:27H:01:27
Ni dung
Bi 1:

chp vo v.
Bi 1:
Trnh by phng php ha hc phn
bit cc cht sau: but -2 en, propin,
butan. Vit cc phng trnh ha hc
minh ha.
HS: Chp
HS: Tho lun lm bi
ly nhp lm bi
Hot ng 2
chp vo v.
Bi 2:
Mt bnh kn ng hn hp kh H2
vi axetilen v mt t bt niken.
Nung nng bnh mt thi gian sau
a v nhit ban u. Nu
cho mt na kh trong bnh sau khi
nung nng i qua dung dch AgNO3
trong NH3 th c 1,2 gam kt ta mu
vng nht. Nu cho na cn li qua
bnh ng nc brom d thy khi
lng bnh tng 0,41 g. Tnh khi
lng axetilen cha phn ng, khi
lng etilen to ra sau phn ng.
HS: Chp
HS: Tho lun lm bi
ly nhp lm bi

Hot ng 3
chp vo v.
Bi 3:
t 3,4 gam mt hirocacbon A to ra
11 gam CO2. Mt khc, khi cho 3,4
gam tc dng vi lng d dung dch
AgNO3 trong NH3 thy to ra a gam kt
ta.
a/ Xc nh CTPT ca A.
H:01:27H:01:27H:01:27
Trnh by phng php ha hc phn bit cc

cht sau: but -2 en, propin, butan. Vit cc
phng trnh ha hc minh ha.
Gii:
- Dn tng kh qua dung dch bc nitrat trong
amoniac: bit c cht to kt ta l propin, do
c phn ng:
CH3 C = CH + AgNO3 + H2O CH3 C = CAg
+ NH4NO3
- Dn hai kh cn li vo dung dch brom: bit
cht lm nht mu dung dch brom l but 2
en, do c phn ng:
CH3CH=CHCH3 + Br2 CH3CHBrCHBrCH3
Kh cn li l butan.
Bi 2:
Mt bnh kn ng hn hp kh H2 vi
axetilen v mt t bt niken. Nung nng bnh
mt thi gian sau a v nhit ban
u. Nu cho mt na kh trong bnh sau khi
nung nng i qua dung dch AgNO3 trong NH3
th c 1,2 gam kt ta mu vng nht. Nu
cho na cn li qua bnh ng nc brom
d thy khi lng bnh tng 0,41 g. Tnh
khi lng axetilen cha phn ng, khi
lng etilen to ra sau phn ng.
Gii
C2H2 + H2
C2H4 (1)
C2H2 + 2H2 C2H6 (2)
C2H4 + H2 C2H6 (3)
CH = CH + 2AgNO3 + 2H2O CAg = CAg +
2NH4NO3 (4)
C2H2 + 2Br2 C2H2Br4 (5)
C2H4 + Br2 C2H4Br2 (6)
S mol C2Ag2 = 0,005 (mol)
T (4) ta c s mol axetilen trong hn hp cn
li l:
2.0,005 =0,01 (mol)
Theo (5), khi lng bnh ng brom tng
0,005.26 = 0,13 gam
Vy khi lng etilen phn ng (6) l: 0,41- 0,13
= 0,28(g)
Khi lng etilen to ra: 2.0,28 = 0,56 gam
Bi 3:
t 3,4 gam mt hirocacbon A to ra 11 gam
CO2. Mt khc, khi cho 3,4 gam tc dng vi
lng d dung dch AgNO3 trong NH3 thy to
ra a gam kt ta.
a/ Xc nh CTPT ca A.
b/ Vit CTCT ca A v tnh khi lng kt ta
to thnh, bit khi A tc dng vi hiro d, c
xc tc Ni to thnh isopentan.
b/ Vit CTCT ca A v tnh khi lng

kt ta to thnh, bit khi A tc dng
Gii
vi hiro d, c xc tc Ni to thnh a/ Gi CTPT ca A l CxHy.
isopentan.
y
y
CxHy + (x + )O2 xCO2 + H2O
HS: Chp
4
2
11
mC = .12 = 3( g )
Vit pthh
44
Tm CTPT
m H = 3,4 3 = 0,4( g )
Da vo d kin ra bin lun tm
3 0,4
CTCT ng
:
= 5:8
x:y =
12 1
HS: Lm bi theo cc bc GV CTGN: C5H8 CTPT (C5H8)n
b/ V A tc dng c vi dung dch AgNO3
hng dn
trong NH3, A c dng R - C = CH
V A tc dng vi H2 to thnh isopentan nn A
phi c mch nhnh.
CTCT: CH = C CH(CH3) CH3
CH = C CH(CH3) CH3 + AgNO3 + H2O
CAg = C CH(CH3) CH3 + NH4NO3
S mol A = s mol kt ta = 3,4 : 68 = 0,05(mol)
Khi lng kt ta = 0,05 . 175 =8,75 (gam)
IV Cng c:
+ Hon thnh s phn ng sau:
CaCO3 CaO CaC2 C2H2 vinylclorua PVC
+ Trnh by phng php ha hc nhn bit but 1-in, but-2-in, metan.
+ Cht no khng tc dng vi dung dch AgNO3 trong amoniac?
A. but 1-in
B. but 2-in
C. Propin
D. Etin
V.Dn d: Chun b bi luyn tp
Ngy son:01/01/2010
Tit 24: BI TP ANKAN +ANKEN + ANKIN

I. Mc tiu
Bi tp ankan + anken + ankin
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi tp ankan + anken + ankin
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
H:01:27H:01:27H:01:27
11B1
11B2
11B5
11B6
2. Bi c: (Lng vo bi mi)
3. Bi mi:
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
t chy hon ton hn hp hai
hirocacbon mch h X, Y lin tip
trong dy ng ng thu c 11,2 lt
CO2 (ktc) v 12,6 gam nc. Tm
CTPT ca X, Y
HS: Chp
HS: Tho lun lm bi
Bi 1:
t chy hon ton hn hp hai hirocacbon
mch h X, Y lin tip trong dy ng ng thu
c 11,2 lt CO2 (ktc) v 12,6 gam nc. Tm
CTPT ca X, Y
Gii:
11,2
nCO2 =
= 0,5(mol )
22,4
12,6
n H 2O =
= 0,7(mol )
18
S mol nc > s mol CO2 X, Y thuc dy
ng ng ca ankan.
3n + 1
t
CnH2n + 2 +
O2
nCO2 + (n+1)H2O
2
0,5
0,7
ly nhp lm bi
Ta c : 0,5(n + 1 ) = 0,7n n = 2,5
CTPT ca X, Y l: C2H6, C3H8
Bi 2:
Hot ng 2
GV: Chp ln bng, yu cu HS Cho 3,5 gam mt anken X tc dng hon
chp vo v.
ton vi dung dch KMnO4 long d, thu
Bi 2:
c 5,2 gam sn phm hu c. Tm CTPT
Cho 3,5 gam mt anken X tc dng ca X.

hon ton vi dung dch KMnO4
long d, thu c 5,2 gam sn
phm hu c. Tm CTPT ca X.
HS: Chp
Gii
3C
H
+
2KMnO
+
4H
O
CnH2n(OH)2 + 2MnO2 + 2KOH
n
2n
4
2
14n
14n + 34
HS: Tho lun lm bi
5,2
GV: Cho HS xung phong ln bng gii 3,5
Ta
c:
3,5(
14n
+
34
)
=
5,2.14n
n = 5
ly nhp lm bi
CTPT ca X l C5H10
Hot ng 3
chp vo v.
t chy hon ton hon hai hirocacbon mch
h M, N lin tip trong dy ng ng thu c
22,4 lt CO2 ( ktc) v 12,6 gam nc. Tm
Bi 3:
CTPT ca M, N.
t chy hon ton hon hai
Gii
hirocacbon mch h M, N lin tip
trong dy ng ng thu c 22,4 lt
H:01:27H:01:27H:01:27
CO2 ( ktc) v 12,6 gam nc. Tm

CTPT ca M, N.
HS: Chp
yu cu HS ln bng trnh by
Hot ng 4
Bi 4:
t chy hon ton a lt (ktc) mt
ankin X th kh thu c CO2 v H2O
c tng khi lng 12,6 gam. Nu cho
sn phm chy qua dung dch nc
vi trong d, thu c 22,5g kt ta.
Tm CTPT ca X.
22,4
= 1(mol )
22,4
12,6
n H 2O =
= 0,7(mol )
18
S mol nc < s mol CO2 M, N thuc dy
ng ng ca ankin.
3n 1
t
CnH2n - 2 +
O2
nCO2 + (n -1)H2O
2
1
0,7
Ta c : (n - 1 ) = 0,7n
n = 3,3
CTPT ca M, N l: C3H4, C4H6
Bi 4:
t chy hon ton a lt (ktc) mt ankin X th
kh thu c CO2 v H2O c tng khi lng
12,6 gam. Nu cho sn phm chy qua dung
dch nc vi trong d, thu c 22,5g kt ta.
Tm CTPT ca X.
Gii
22,5
nCaCO3 =
= 0,225(mol )
100
mCO2 = 44.0,225 = 9,9( gam)
nCO2 =
HS: Chp
HS: Tho lun lm bi
12,6 9,9
GV: Cho HS xung phong ln bng gii n H 2O =
= 0,15(mol )
18
3n 1
ly nhp lm bi
t
CnH2n - 2 +
O2
nCO2 + (n -1)H2O
2
0,225
0,15
Ta c : 0,225(n - 1 ) = 0,15n n = 3
CTPT ca X l: C3H4
IV Cng c:
Khi t chy hirocacbon thu c
- S mol H2O > s mol CO2 hirocacbon thuc dy ng ng ankan
- S mol H2O = s mol CO2 hirocacbon thuc dy ng ng anken
- S mol H2O < s mol CO2 hirocacbon thuc dy ng ng ankin
V.Dn d: Chun b bi tit sau n tp H-C
Ngy son:09/01/2010
Tit 25: BI TP TNG KT CHNG
HIROCACBON NO V HIROCACBON KHNG NO

I. Mc tiu:
Bi tp tng kt chng hirocacbon no v hirocacbon khng no.
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi tp hirocacbon no v hirocacbon khng no.
III.Tin trnh ln lp
H:01:27H:01:27H:01:27
1. n nh t chc
Ngy dy
Lp
11B1
11B2
11B5
11B6
S s
Ghi ch
2. Bi c: (Lng vo bi mi)
3. Bi mi
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
Hon thnh s phn ng sau
Cao su buna C4H4 C4H4
CaCO3 CaO CaC2 C2H2 C2H4 PE
Vinylclorua PVC
HS: Tho lun lm bi
Bi 1:
Hon thnh s phn ng sau
Cao su buna C4H4 C4H4
CaCO3 CaO CaC2 C2H2 C2H4 PE
Vinylclorua PVC
Gii:
t
1/CaCO3
CaO + CO2
t
2/ CaO + 3C
CaC2 + CO
3/ CaC2 + 2H2O
C2H2 + Ca(OH)2
,PbCO3
4/ C2H2 + H2 Pd
CH2 = CH2
,t , p
5/ nCH2 = CH2 xt
(-CH2 CH2 - )n
t
CH2 = CH Cl
HS: Ln bng trnh by, cc HS cn li 6/ C2H2 + HCl
7/
xt,t, p
ly nhp lm bi
nCH2 = CH
(- CH2 - CH - )n
Cl
Cl
8/ 2C2H2 CH2 = CH- C = CH

9/ CH2 = CH- C = CH + H2 Pd
,PbCO
3 CH2 = CH CH = CH2
xt ,t , p
10/ nCH2 = CH CH = CH2
(-CH2 - CH = CH - CH2-)n
Bi 2:
Cho mt lng anken X tc dng vi H2O
(xc tc H2SO4) c cht hu c Y, thy khi
lng bnh ng nc ban u tng 4,2 gam.
Nu cho mt lng X nh trn tc dng vi
HBr, thu c cht Z, thy khi lng Y, Z thu
c khc nhau 9,45gam.
xt ,t
Hot ng 2
chp vo v.
Bi 2:
Cho mt lng anken X tc dng vi
H2O
(xc tc H2SO4) c cht hu
c Y, thy khi lng bnh ng nc
ban u tng 4,2 gam. Nu cho mt
lng X nh trn tc dng vi HBr, thu
c cht Z, thy khi lng Y, Z thu
c khc nhau 9,45gam.
HS: Chp
HS: Tho lun lm bi

H:01:27H:01:27H:01:27
Gii
CxH2x + H2O CxH2x +1 OH (Y) , (1)
CxH2x + HBr CxH2x +1 Br (Z) , (2)
tng khi lng bnh = khi lng anken
4,2
(mol )
phn ng n X =
14 x
4,2
mY =
(14 x + 18)
14 x
mZ =
4,2
(14 x + 81)
14 x
ly nhp lm bi
mZ - mY =
4,2
4,2
(14 x + 81)
(14 x + 18) =9,45
14 x
14 x
x=2
CTPT ca X: C2H4
Bi 3:
Hot ng 3
Khi t mt th tch hirocacbon A mch h cn
GV: Chp ln bng, yu cu HS 30 th tch khng kh, sinh ra 4 th tch kh CO2.
chp vo v.
A tc dng vi H2 ( xt Ni ), to thnh mt
Bi 3:
hirocacbon no mch nhnh. Xc nh CTPT,
Khi t mt th tch hirocacbon A CTCT ca A.
mch h cn 30 th tch khng kh,
Gii
sinh ra 4 th tch kh CO2. A tc dng
vi H2 ( xt Ni ), to thnh mt
y
y
hirocacbon no mch nhnh. Xc nh CxHy + (x + )O2 xCO2 + H2O
4
2
CTPT, CTCT ca A.
20
20
Vkk =
.30 = 6
Th tch oxi phn ng: VO2 =
100
100
(lt)
Ta c phng trnh x = 4, x + y/4 = 6 y = 8
HS: Chp
GV: Gi hng dn HS cch gii, A c CTPT C4H8 mch h nn A thuc loi
anken. V A tc dng vi H2 to thnh mt
yu cu HS ln bng trnh by
hirocacbon no mch nhnh. CTCT ca A.
CH2 = C CH3
CH3
IV Cng c:
1/ t chy hon ton 0,15 mol 2 ankan thu c 9 gam nc.Cho hn hp sn phm sau
phn ng vo dung dch nc vi trong d th khi lng kt ta thu c l bao nhiu
gam.
A. 38g
B. 36 gam
C. 37 gam
D. 35 gam
2/ t chy hon ton m gam, mt hirocacbon thu c 33gam CO2 v 27 gam H2O. Gi
tr ca m l
A. 11g
B. 12g
C. 13g
D. 14g
V. Dn d: Chun b bi Benzen v ng ng ca benzen
Ngy son:09/01/2010
Tit 26: BI TP
BENZEN V NG NG. MT S HIROCACBON THM KHC

I. Mc tiu
H:01:27H:01:27H:01:27

Bi tp benzen v ng ng. Mt s hirocacbon thm khc
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi tp benzen v ng ng. Mt s hirocacbon thm
khc
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
11B2
11B3
11B4
11B5
11B6
2. Bi c:
Trnh by tnh cht ha hc ca benzen
3. Bi mi:
H:01:27H:01:27H:01:27
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
A l mt ng ng ca benzen c t
khi hi so vi metan bng 5,75. A
tham gia cc qu trnh chuyn ha
theo s sau:
Cl 2 (1mol )
+
B
+ H 2 , Ni ,t

C
+ HNO3 ,( 3 mol ), H 2 SO4
A
D
KMnO4 ,t
+
E
Trn s ch ghi cc cht sn phm
hu c ( phn ng cn c th to ra
cc cht v c)
Hy vit phng trnh ha hc ca cc
qu trnh chuyn ha. Cc cht hu c
vit di dng CTCT, km theo tn
gi.
HS: Tho lun lm bi
Bi 1:
A l mt ng ng ca benzen c t khi hi
so vi metan bng 5,75. A tham gia cc qu
trnh chuyn ha theo s sau:
Cl 2 (1mol )
+
B
+ H 2 , Ni ,t

C
+ HNO3 ,( 3 mol ), H 2 SO4
A
D
KMnO4 ,t
+
E
Trn s ch ghi cc cht sn phm hu c (
phn ng cn c th to ra cc cht v c)
Hy vit phng trnh ha hc ca cc qu
trnh chuyn ha. Cc cht hu c vit di
dng CTCT, km theo tn gi.
Gii
MA = 5,75.16 = 92 (g/mol) 14n 6 = 92 n
=7
A l C7H8 hay C6H5 CH3 ( Toluen)
t
C6H5 CH3 + Cl2
C6H5 CH2Cl + HCl
B: benzyl clorua
Ni,t
C6H5 CH3 + 3H2 C6H11CH3
C:
Metylxiclohexan
2 SO4
C6H5-CH3 + 3HNO3 H
C6H2(NO2)3CH3 +
HS: Ln bng trnh by, cc HS cn li 3H O

2
ly nhp lm bi
D: TNT
(trinitrotoluen)
t
C6H5 CH3 + KmnO4
C6H5-COOK
Hot ng 2
+ KOH + 2MnO2 + H2O
E: kali benzoat
chp vo v.
Bi 2:
Bi 2:
Cht A l mt ng ng ca benzen. Khi t
Cht A l mt ng ng ca benzen.
chy hon ton 1,5 g cht A, ngi ta thu
Khi t chy hon ton 1,5 g cht A,
c 2,52 lt kh CO2 ( ktc).
ngi ta thu c 2,52 lt kh CO2
a/ Xc nh CTPT.
( ktc).
b/ Vit cc CTCT ca A. Gi tn.
a/ Xc nh CTPT.
c/ Khi A tc dng vi Br2 c cht xc tc Fe v
b/ Vit cc CTCT ca A. Gi tn.
nhit th mt nguyn t H nh vi vng
c/ Khi A tc dng vi Br2 c cht xc
benzen b thay th bi Br, to ra dn xut
tc Fe v nhit th mt nguyn t H
monobrom duy nht. Xc nh CTCT ca A.
nh vi vng benzen b thay th bi
Gii
Br, to ra dn xut monobrom duy nht.
3n 3
Xc nh CTCT ca A.
CnH2n 6 +
O2 nCO2 + (n-3)H2O
2
HS: Chp
C ( 14n -6)g A to ra n mol CO2
2,52
HS: Tho lun lm bi
= 0,1125molCO2
C 1,5 g A to ra
22,4
14n 6
n
=
n=9
1,5
0,1125
CTPT: C9H12
Cc CTCT:
ly nhp lm bi
CH3
CH3
CH3
CH3
CH3
CH3
H3C
H:01:27H:01:27H:01:27
CH3
1,2,3-trimetlybenzen
C2H5
CH3
CH3
CH3
CH3
C2H5
1- etyl - 2 - metylbenzen 1- etyl - 3 - metylbenzen
C2H5
1- etyl - 4 - metylbenzen
IV Cng c:
Nhc li cch gi tn cc ng ng benzen. Cc cch gii bi tp tm CTPT, vit
CTCT
V.Dn d: Chun b bi ngun hirocacbon thin nhin
Ngy son:09/01/2010
Tit 27: BI TP H THNG HA V HIROCACBON

I. Mc tiu
Bi tp h thng ha v hirocacbon
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi tp h thng ha v hidrocacbon
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
11B1
11B2
11B5
11B6
S s
2. Bi c:
Trnh by thnh phn ca du m
3. Bi mi:
H:01:27H:01:27H:01:27
Ghi ch
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
Hn hp M cha hai hidrocacbon k
tip nhau trong mt dy ng ng. Khi
t chy hon ton 13,2 gam hn hp
M thu c 20,72t CO2 ( ktc). Hy
xc nh CTPT v % khi lng tng
cht trong hn hp M.
HS: Tho lun lm bi
Bi 1:
Hn hp M cha hai hidrocacbon k tip nhau
trong mt dy ng ng. Khi t chy hon
ton 13,2 gam hn hp M thu c 20,72t
CO2 ( ktc). Hy xc nh CTPT v % khi
lng tng cht trong hn hp M.

ly nhp lm bi
Gii
20,72
nCO2 =
= 0,925( mol )
22,4
mC = 12.0.925 = 11,1( gam)
m H = 13,2 11,1 = 2,1( gam)
2,1
n H 2O =
= 1,05(mol )
2
V s mol H2O > s mol CO2 nn hai cht trong
hn hp M u l ankan.
3n + 1
CnH2n +2
O2 nCO2 + ( n +1 ) H2O
2
n
0,925
=
n = 7,4
n + 1 1,05
CTPT ca hai cht C7H16( x mol) v C8H18( y
mol)
Khi lng hai cht: 100x + 114y =13,2
S mol CO2: 7x + 8y = 0,925
x = 0,075; y = 0,05
0,075.100
%C 7 H 16 =
.100% = 56,8%
13,2
0,05.114
%C8 H 18 =
.100% = 43,2%
13,2
Bi 2:
Khi cho mt hidrocacbon mch h X tc dng
vi nc brom ( d) sinh ra mt hp cht Y
cha 4 nguyn t brom trong phn t. Trong
Y, phn trm khi lng ca ccbon bng 10%
khi lng ca Y.
a/ Tm CTPT v CTCT ca X.
b/ Trn 2,24 lt X vi 3,36 lt H2 ( ktc) sau
un nng hn hp vi mt t bt Ni n khi
phn ng xy ra hon ton. Tnh % khi lng
ca cc cht sau phn ng.
Hot ng 2
chp vo v.
Bi 2:
Khi cho mt hidrocacbon mch h X
tc dng vi nc brom ( d) sinh ra
mt hp cht Y cha 4 nguyn t
brom trong phn t. Trong Y, phn
trm khi lng ca ccbon bng 10%
khi lng ca Y.
a/ Tm CTPT v CTCT ca X.
b/ Trn 2,24 lt X vi 3,36 lt H2 ( ktc)
sau un nng hn hp vi mt t
bt Ni n khi phn ng xy ra hon
ton. Tnh % khi lng ca cc cht
Gii
sau phn ng.
a/
X
c
CTPT
C
H
n 2n 2, tc dng vi brom:
HS: Chp
CnH2n 2 + 2Br2
CnH2n 2Br4
12
n
10
.100% =
n=3
%C =
14n 2
100
HS: Tho lun lm bi
Vy CTPT ca X l C3H4, CTCT ca X l
GV: Cho HS xung phong ln bng gii CH3- C = CH
b/ Phn ng hiro ha
C3H4 + 2H2 C3H8
x
2x
C3H4 + H2 C3H6
y
y
H:01:27H:01:27H:01:27
Ta
c
h
phng
trnh
x + y = 0,1
ly nhp lm bi
2x + y = 0,15
IV. Cng c
Nhc li cc kin thc hidrocacbon hc
V. Dn d:
Chun b bi: Dn xut halogen ca hirocacbon
Ngy son:09/01/2010
Tit 28: BI TP DN XUT HALOGEN CA HIROCACBON V

ANCOL
I. Mc tiu
Bi tp dn xut halogen ca hirocacbon v ancol
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi dn xut halogen ca hidrocacbon v ancol
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
2. Bi c:
Trnh by s chuyn ha gia cc hirocacbon
3. Bi mi:
H:01:27H:01:27H:01:27
Ghi ch
Hot ng ca thy v tr
Ni dung
Hot ng 1
IV. Cng c
vo v.
Bi 1:
Hon thnh s chuyn ha sau bng cc
phng trnh ha hc.
a/ Etan cloetan etyl magie clorua
b/ Butan 2 brombutan but -2- en
CH3CH(OH)CH2CH3
HS: Tho lun lm bi
Bi 1:
Hon thnh s chuyn ha sau bng cc
phng trnh ha hc.
a/ Etan cloetan etyl magie clorua
b/ Butan 2 brombutan but -2- en
CH3CH(OH)CH2CH3
HS: Ln bng trnh by, cc HS cn li ly

nhp lm bi
Hot ng 2
vo v.
Bi 2:
t chy hon ton 3,96 g cht hu c A,
thu c 1,792 lt CO2 ( ktc) v 1,44 g
H2O. Nu chuyn ht lng clo c trong
2,475 g cht A thnh AgCl th thu c
7,175 g AgCl.
b/ Xc nh CTPT ca A bit rng t khi hi
ca A so vi etan l 3,3.
c/ Vit cc CTCT m A c th c v gi tn
HS: Chp
HS: Tho lun lm bi
Gii
as
a/ C2H6 + Cl2
C2H5Cl + HCl
C2H5Cl + Mg C2H5MgCl
b/ CH3CH2CH2CH3 + Br2 CH3CHBrCH2CH3 +
HBr
2 H 5OH
CH3CHBrCH2CH3 + KOH C
CH3- CH = CH CH3 + KBr + H2O

H+
CH3- CH = CH CH3 + H2O
CH3- CH(OH) CH CH3
Bi 2:
t chy hon ton 3,96 g cht hu c A, thu
c 1,792 lt CO2 ( ktc) v 1,44 g H2O. Nu
chuyn ht lng clo c trong 2,475 g cht A
thnh AgCl th thu c 7,175 g AgCl.
b/ Xc nh CTPT ca A bit rng t khi hi
ca A so vi etan l 3,3.
c/ Vit cc CTCT m A c th c v gi tn
Gii
a/ Khi t chy A ta thu c CO2 v H2O, vy A
phi cha C v H.
Khi lng C trong 1,792 lt CO2:
12.1,792
= 0,96( g )
22,4
Khi lng H trong 1,44 g H2O:
2.1,44
= 0,16( g )
18
nhp lm bi
cng l khi lng C v H trong 3,96 g A
Theo bi ra, A phi cha Cl. Khi lng Cl trong
7,175 g AgCl
35,5.7,175
= 1,775 (g)
143,5
cng l khi lng Cl trong 2,475 g A
Vy, khi lng Cl trong 3,96 g A l:
1,775.3,96
= 2,84( gam )
2,475
Vy cht A c dng CxHyClz
0,96 0,16 2,84
:
:
= 1: 2 :1
x: y: z =
12
1 35,5
CTGN ca A l CH2Cl
b/ MA = 3,3.30 = 99 (g/mol)
(CH2Cl)n = 99 49,5n = 99 n = 2
CTPT ca A l C2 H4Cl2
c/ Cc CTCT
Hot ng 3
GV: Chp
ln bng, yu cu HS chp CH3CHCl2 ; 1,1 icloetan
H:01:28H:01:28H:01:28
CH2Cl CH2Cl; 1,2 - icloetan
vo v.
Bi 3:
Bi 3:
t chy hon ton mt lng hn hp hai t chy hon ton mt lng hn hp hai
Nhc li tnh cht ca dn xut halogen, ancol

V. Dn d:
Chun b bi: Phn cn li bi Ancol
Ngy son:09/01/2010
Tit 29: BI TP ANCOL V PHENOL

I. Mc tiu
Bi tp Ancol v phenol
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi Ancol v phenol
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
11B1
11B2
11B5
11B6
2. Bi c:
Trnh by nh ngha, phn loi, danh php Ancol. Ly VD minh ha.
3. Bi mi
H:01:28H:01:28H:01:28
Hot ng ca thy v tr
Ni dung
Hot ng
chp vo v.
Bi 1:
Hn hp A cha gixerol v mt ancol
n chc. Cho 20,30 gam A tc dng
vi natri d thu c 5,04 lt H2 ( ktc).
Mt khc 8,12 gam A ha tan va ht
1,96 g Cu(OH)2. Xc nh CTPT, Tnh
% v khi lng ca ancol n chc
trong hn hp A.
HS: Tho lun lm bi
Bi 1:
Hn hp A cha gixerol v mt ancol n
chc. Cho 20,30 gam A tc dng vi natri d
thu c 5,04 lt H2 ( ktc). Mt khc 8,12 gam
A ha tan va ht 1,96 g Cu(OH)2. Xc nh
CTPT, Tnh % v khi lng ca ancol n
chc trong hn hp A.
Gii
2C3H5 (OH)3 + Cu(OH)2 [C3H5(OH)2O]2Cu +
2H2O
S mol gixerol trong 8,12 g A = 2 s mol
1,96
= 0,04(mol )
Cu(OH)2 = 2.
98
S mol gixerol trong 20,3 g A:
HS: Ln bng trnh by, cc HS cn li 0,04.20,3
= 0,1(mol )
ly nhp lm bi
8,12
Khi lng gixerol trong 20,3 g A l : 0,1.92 =
9,2 (g)
Khi lng ROH trong 20,3 g A l:
20,3 9,2 =11,1(g)
2C3H5 (OH)3 + Na 2C3H5 (ONa)3 + 3H2
0,1
0,15
2ROH + 2Na RONa + H2
x
0,5x
S mol H2 = 0,15 + 0,5x =
5,04
= 0,225 x = 0,15
22,4
11,1
= 74
Khi lng 1 mol ROH:
0,15
R = 29; R l C4H9
CTPT: C4H10O
Phn trm khi lng C4H9OH =
Hot ng 2
chp vo v.
Bi 2:
un nng hn hp 2 ancol no, n
chc, mch h vi H2SO4 1400C, thu
c 72 gam hn hp 3 ete vi s mol
bng nhau. Khi lng nc tch ra
trong qu trnh to thnh cc ete l
21,6 gam. Xc nh CTCT ca 2 ancol.
HS: Chp
HS: Tho lun lm bi
11,1
.100% = 54,68%
20,3
Bi 2:
un nng hn hp 2 ancol no, n chc,
mch h vi H2SO4 1400C, thu c 72 gam
hn hp 3 ete vi s mol bng nhau. Khi
lng nc tch ra trong qu trnh to thnh
cc ete l 21,6 gam. Xc nh CTCT ca 2
ancol.
Gii
2CnH2n+1OH (2CnH2n +1)2O + H2O
2Cm H2m +1OH (2CmH2m+1)2O + H2O
CnH2n+1OH + Cm H2m +1OH CnH2n+1OCmH2m +1
+ H2O
HS: Ln bng trnh by, cc HS cn li S mol 3 ete = s mol nc = 21,6 = 1,2(mol )
18
ly nhp lm bi
S mol mi ete = 0,4 (mol)
Khi lng 3 ete:
(28n + 18).0,4 + ( 28m +18).0,4 + (14n + 14m
+ 18).0,4=72
H:01:28H:01:28H:01:28
n+m=3
Hot ng 3
GV: Chp ln bng, yu cu HS Hai CTCT ca ancol l: CH3OH, CH3CH2OH
chp vo v.
IV. Cng c:
Nhc li tnh cht ca ancol v phenol
V. Dn d:
Chun b bi: Luyn tp
Ngy son:09/01/2010
DN XUT HALOGEN ANCOL V PHENOL

I. Mc tiu
Bi tp dn xut Halogen + Ancol + Phenol
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi dn xut Halogen + Ancol + Phenol
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
2. Bi c: ( Lng vo bi mi)
3. Bi mi
H:01:28H:01:28H:01:28
Ghi ch
Hot ng ca thy v tr
Hot ng 1
vo v.
Bi 1:
T etilen vit phng trnh iu ch cc
cht sau: 1,2 ibrometan; 1,1
ibrometan; vinylclorua
HS: Tho lun lm bi
nhp lm bi
Hot ng 2
vo v.
Bi 2:
Cho 13,8 g hn hp X gm glixerol v mt
ancol n chc A tc dng vi natri d thu
c 4,48 lt kh hiro (ktc). Lng hidro
do A sinh ra bng 1/3 lng hidro do
glixerol sinh ra. Tm CTPT v gi tn A.
HS: Chp
HS: Tho lun lm bi
nhp lm bi
Hot ng 3
vo v.
Bi 3:
Hn hp M gm ancol metylic, ancol
etylic v phenol. Cho 14,45 g M tc dng
vi natrib d, thu c 2,787 lt H2 (
270C v 750 mm Hg ). Mt khc 11,56 g M
tc dng va ht vi 80ml dung dch
NaOH 1M. Tnh % khi lng tng cht
trong hn hp M.
HS: Chp
Ni dung
Bi 1:
T etilen vit phng trnh iu ch cc cht
sau: 1,2 ibrometan; 1,1 ibrometan;
vinylclorua
Gii
iu ch 1,2 ibrom
CH2 = CH2 + Br2 CH2Br CH2Br
iu ch 1,1 ibrom
CH2Br CH2Br + 2KOH CH = CH + 2KBr +
H2O
CH = CH + 2HBr CH3CHBr2
iu ch vinylclorua
CH2 =CH2 + Cl2 CH2Cl CH2Cl
CH2Cl CH2Cl + KOH CH2= CHCl + KCl + H2O
Bi 2:
Cho 13,8 g hn hp X gm glixerol v mt ancol
n chc A tc dng vi natri d thu c 4,48
lt kh hiro (ktc). Lng hidro do A sinh ra
bng 1/3 lng hidro do glixerol sinh ra. Tm
CTPT v gi tn A.
Gii
2C3H5 (OH )3+ 6Na 2C3H5 (ONa )3 + 3H2
a
3a/2
2ROH + 2Na 2RONa + H2
b
b/2
Ta c phng trnh:
92a + MA.b = 13,8
3a + b = 0,4
a=b
a = b =0,1 (mol); MA = 46(g/mol)
CTPT ca A C2H5OH; etanol
Bi 3:
Hn hp M gm ancol metylic, ancol etylic v
phenol. Cho 14,45 g M tc dng vi natrib d,
thu c 2,787 lt H2 ( 270C v 750 mm Hg ).
Mt khc 11,56 g M tc dng va ht vi 80ml
dung dch NaOH 1M. Tnh % khi lng tng
cht trong hn hp M.
Gii
Khi cho 11,56 g M tc dng vi dung dch NaOH
C6H5OH + NaOH C6H5ONa + H2O
S mol C6H5OH trong 11,56 g M = s mol
NaOH = 0,08 (mol)
S mol C6H5OH trong 14,45 g M =
0,08.14,45
= 0,1(mol )
GV: Gi hng dn HS cch gii, yu
11,56
cu HS ln bng trnh by
C6H5OH + Na C6H5ONa + 1/2H2
0,1
0,05
CH3OH + Na CH3ONa + 1/2H2
x
x/2
C2H5OH + Na C2H5ONa + 1/2H2
H:01:28H:01:28H:01:28
y
y/2
2,787.750
= 0,112(mol )
S mol H2 =
0,082.300.760
IV. Cng c:
Nhc li tnh cht ca dn xut halogen ancol v phenol
V. Dn d:
Chun b bi: Anehit Xeton
Tit 31: BI TP ANEHIT XETON

I. Mc tiu:
Bi tp Anehit - Xeton
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi Anehit - Xeton
III.Tin trnh ln lp:
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
2. Bi c:
Trnh by tnh cht ha hc ca Anehit - Xeton
3. Bi mi:
H:01:28H:01:28H:01:28
Ghi ch
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
Cht A l mt anehit n chc. Cho
10,5 gam A tham gia ht vo phn
ng trng bc. Lng to thnh c
ha tan ht vo axit nitric long lm
thot ra 3,85 lt kh NO ( o 27,30C
v 0,8 atm ).
Xc nh CTPT, CTCT v tn cht A.
HS: Tho lun lm bi
Bi 1:
Cht A l mt anehit n chc. Cho 10,5
gam A tham gia ht vo phn ng trng bc.
Lng to thnh c ha tan ht vo axit
nitric long lm thot ra 3,85 lt kh NO ( o
27,30C v 0,8 atm ).
Xc nh CTPT, CTCT v tn cht A.
Gii
RCHO + 2AgNO3 + 3NH3 + H2O RCOONH4
+ 2NH4NO3 + 2Ag
3Ag + 4HNO3 3AgNO3 + NO + 2H2O
3,85.0,8
n NO =
= 0,125(mol )
0,082.300,3
S mol Ag = 3 s mol NO = 0,375 (mol)
S mol RCHO = s mol Ag = 0,1875(mol)
10,5
= 56
Khi lng 1 mol RCHO =
0,1875
R = 56 -29 = 27 R l C2H3
CTPT l C3H4O
CTCT l CH2 = CH CHO ( propenal )
Bi 2:
t chy hon ton mt lng cht hu c
A phi dng va ht 3,08 lt O2. Sn phm thu
c ch gm 1,8 gam H2O v 2,24 lt CO2.
Cc th tch o ktc.
a/ Xc nh CTGN ca A.
b/ Xc nh CTPT ca A. Bit rng t khi ca
A i vi oxi l 2,25.
c/ Xc nh CTCT ca A, gi tn, bit rng A l
hp cht cacbonyl.
Gii
a/ Theo nh lut bo ton khi lng

ly nhp lm bi
Hot ng 2
chp vo v.
Bi 2:
t chy hon ton mt lng cht
hu c A phi dng va ht 3,08 lt O2.
Sn phm thu c ch gm 1,8 gam
H2O v 2,24 lt CO2. Cc th tch o
ktc.
a/ Xc nh CTGN ca A.
b/ Xc nh CTPT ca A. Bit rng t
khi ca A i vi oxi l 2,25.
c/ Xc nh CTCT ca A, gi tn, bit
rng A l hp cht cacbonyl.
HS: Chp
HS: Tho lun lm bi
m A = mCO2 + mH 2O mO 2 =
+ 1,8
2,24
.44
22,4
3,08
.32 = 1,8( gam)
22,4
Khi lng C trong 1,8 gam A :

12.2,24
= 1,2( gam)
22,4
ly nhp lm bi
Khi lng H trong 1,8 gam A :
2.1,8
= 0,2( gam)
18
Khi lng O trong 1,8 gam A: 1,8 1,2 0,2
= 0,4 (gam)
Cng thc cht A c dng: CxHyOz
1,2 0,2 0,4
:
:
= 4 : 8 :1
x:y:z =
12 1 16
CTGN l: C4H8O
b/ MA = 2,25.32 = 72g/mol
H:01:28H:01:28H:01:28
CTPT trng CTGN: C4H8O
c/ Cc hp cht cacbonyl
CH3 CH2 CH2 CHO butanal
IV. Cng c:
Trong phn t anehit no, n chc, mch h X c phn trm khi lng oxi bng 27,586
%. X c CTPT l
A. CH2O
B. C2H4O
C. C3H6O
D. C4H8O
V. Dn d:
Chun b bi: axit cacboxylic
Tit 32: BI TP AXIT CACBOXYLIC

I. Mc tiu
Bi tp Axit cacboxylic
II. Chun b
GV:Gio n
HS: n tp l thuyt, lm bi Axit cacboxylic
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
11B1
11B2
11B5
11B6
2. Bi c:
Trnh by tnh cht ha hc ca Axit cacboxylic
3. Bi mi
H:01:28H:01:28H:01:28
Ghi ch
Hot ng ca thy v tr
Ni dung
Hot ng 1
vo v.
Bi 1:
trung ha 50 ml dung dch ca mt axit
cacboxylic n chc phi dng va ht 30
ml dung dch KOH 2M. Mt khc, khi trung
ha 125 ml dung dch axit ni trn bng mt
lng KOH va ri c cn, thu c
16,8 gam mui khan. Xc nh CTPT,
CTCT, tn v nng mol ca axit trong
dung dch .
HS: Tho lun lm bi
Bi 1:
trung ha 50 ml dung dch ca mt axit
cacboxylic n chc phi dng va ht 30 ml
dung dch KOH 2M. Mt khc, khi trung ha 125
ml dung dch axit ni trn bng mt lng KOH
va ri c cn, thu c 16,8 gam mui khan.
Xc nh CTPT, CTCT, tn v nng mol ca
axit trong dung dch .
Gii
RCOOH + KOH RCOOK + H2O
S mol RCOOH trong 50 ml dung dch axit l:
2.30
= 0,06(mol )
1000
Nng mol ca dung dch axit l:
0,06.1000
= 1,2( mol / l )
50
nhp lm bi
S mol RCOOH trong 125 ml dung dch axit l:
1,2.125
= 0,15( mol )
1000
cng l s mol mui thu c sau khi c cn
dung dch .
16,8
= 112
Khi lng 1 mol mui l:
0,15
RCOOK = 112 R = 29 R l C2H5
CTPT ca axit l: C3H6O2
CTCT: CH3 CH2 COOH axit propanoic
Bi 2:
Hot ng 2
Cht A l mt axit no, n chc, mch h. t
GV: Chp ln bng, yu cu HS chp chy hon ton 2,225 gam A phi dng va ht
vo v.
3,64 lt O2 ( ktc).
Bi 2:
Xc nh CTPT, CTCT v tn gi.
Cht A l mt axit no, n chc, mch h.
t chy hon ton 2,225 gam A phi
dng va ht 3,64 lt O2 ( ktc).
Xc nh CTPT, CTCT v tn gi.
HS: Chp
Gii
3n 2
O2 nCO2 + nH2O
CnH2nO2 +
HS: Tho lun lm bi
2
Theo phng trnh ( 14n + 32)g axit tc dng vi
3n 2
mol O2
2
Theo bi ra 2,25 gam axit tc dng vi 0,1625 mol
O2
14n + 32
3n 2
=
n=5
2,55
0,1625.2
nhp lm bi
CTPT C5H10O2
CH3 CH2 CH2 CH2 COOH axit pentanoic
CH3 CH CH2 COOH axit -3-metylbutanoic
CH3
CH3 CH2 CH COOH axit -2-metylbutanoic
CH3
CH3
GV: Gi
HS
nhn
xt
ghi
im
CH
C
COOH
axit -2,2 -dimetylpropanoic
3
H:01:28H:01:28H:01:28
CH3
Hot ng 3
Bi 3:
GV: Chp ln bng, yu cu HS chp Dung dch X c cha ng thi hai axit cacboxylic
IV. Cng c
Trung ha 10g dung dch axit hu c n chc X nng 3,7% cn dng 50 ml dung dch
KOH 0,1 M. CTCT ca X l
A. CH3CH2COOH
B. CH3COOH
C. HCOOH
D. CH3CH2CH2COOH
V. Dn d:
Chun b bi: Luyn tp
Tit 33: BI TP ANEHIT XETON AXIT CACBOXYLIC

I. Mc tiu:
Bi tp anehit xeton axit cacboxylic
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi anehit xeton axit cacboxylic
III.Tin trnh ln lp:
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
11B1
11B2
11B5
11B6
2. Bi c:
Trnh by tnh cht ha hc ca anehit v axit cacboxylic
3. Bi mi
H:01:28H:01:28H:01:28
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
Hn hp M cha ba cht hu c A, B
v C l 3 ng phn ca nhau. A l
anehit n chc v C l ancol.
t chy hon ton 1,45g hn hp M,
thu c 1,68 lt ( ktc) kh CO2 v
1,35 gam H2O.
Xc nh CTPT, CTCT v tn A, B, C.
HS: Tho lun lm bi
Bi 1:
Hn hp M cha ba cht hu c A, B v C l
3 ng phn ca nhau. A l anehit n chc
v C l ancol.
t chy hon ton 1,45g hn hp M, thu
c 1,68 lt ( ktc) kh CO2 v 1,35 gam H2O.
Xc nh CTPT, CTCT v tn A, B, C.

ly nhp lm bi
Gii
Ba cht A, B, C l ng phn nn c CTPT
ging nhau. A l anehit n chc nn phn
t A ch c 1 nguyn t oxi. Vy A, B v C c
CTPT CxHyO. Khi t chy hon ton hn hp
M
y 1
CxHyO + ( x + )O2 xCO2 + y/2H2O
4 2
Theo phng trnh: (12x + y +16 ) g M to ra x
mol CO2 v y/2 mol H2O.
1,45g M to ra
0,075 mol CO2 v 0,075 mol H2O
12 x + y + 16
x
y
=
=
x = 3, y = 6
1,45
0,075 0,15
CTPT ca A, B v C l C3H6O
A l CH3CH2CHO
propanal
B l CH3COCH3
axeton
C l CH2= CH CH2 OH propenol
Bi 2:
Trung ha 250g dung dch 3,7% ca mt axit
n chc X cn 100ml dung dch NaOH 1,25M
( hiu sut 100%)
a/ Tm CTPT, vit CTCT v tn gi ca X.
b/ C cn dung dch sau khi trung ha th thu
c bao nhiu gam mui khan.
Hot ng 2
chp vo v.
Bi 2:
Trung ha 250g dung dch 3,7% ca
mt axit n chc X cn 100ml dung
dch NaOH 1,25M ( hiu sut 100%)
a/ Tm CTPT, vit CTCT v tn gi ca
X.
b/ C cn dung dch sau khi trung ha
Gii
th thu c bao nhiu gam mui khan.
a/
Axit
n
chc,
cng
thc CxHyCOOH
HS: Chp
CxHyCOOH + NaOH
CxHyCOONa + H2O
HS: Tho lun lm bi
S mol NaOH = 0,125 (mol); khi lng axit X
GV: Cho HS xung phong ln bng gii = 9,25 gam.
Theo phng trnh s mol axit = s mol NaOH
9,25
= 74( g / mol )
Maxit =
0,125
12x + y = 29 suy ra x = 2; y = 5
CTPT l C3H6O2
HS: Ln bng trnh by, cc HS cn li CTCT l CH3CH2COOH axit propionic.
ly nhp lm bi
b/ CH3CH2COOH + NaOH C2H5COONa +
H2O
C cn dung dch sau trung ha thu c
mui khan C2H5COONa c s mol bng s mol
NaOH l 0,125 mol
Khi lng mui khan l 0,125 .96 = 12gam
Hot
ng
3
Bi 3:
H:01:28H:01:28H:01:28
GV: Chp ln bng, yu cu HS Trnh by phng php ha hc phn bit cc
chp vo v.
cht lng: HCOOH, CH3COOH, CH3CH2OH,
Bi 3:
CH2 = CHCOOH. Vit phng trnh minh ha.
IV. Cng c
Trnh by phng php ha hc phn bit cc dung dch trong nc ca cc cht sau:
fomanehit, axit fomic, axit axetic, ancol etylic.
V. Dn d
Chun b bi: Bi thc hnh 6

ANEHIT XETON AXIT CACBOXYLIC
I. Mc tiu:
Bi tp anehit xeton axit cacboxylic
III. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi anehit xeton axit cacboxylic
III.Tin trnh ln lp
1. n nh t chc
Ngy dy
Lp
S s
Ghi ch
11B1
11B2
11B5
11B6
2. Bi c:
(Lng vo bi mi)
3. Bi mi
H:01:28H:01:28H:01:28
Hot ng ca thy v tr
Ni dung
Hot ng 1
chp vo v.
Bi 1:
Mt hp cht hu c Y gm cc
nguyn t C, H, O ch cha mt loi
nhm chc c kh nng tham gia phn
ng trng bc. Khi cho 0,01 mol Y tc
dng vi dung dch AgNO3 trong
ammoniac th thu c 4,32 g Ag. Xc
nh CTPT v vit CTCT ca Y, bit Y
c cu to mch cacbon khng phn
nhnh v cha 37,21% oxi v khi
lng.
HS: Tho lun lm bi
Bi 1:
Mt hp cht hu c Y gm cc nguyn t C,
H, O ch cha mt loi nhm chc c kh
nng tham gia phn ng trng bc. Khi cho
0,01 mol Y tc dng vi dung dch AgNO3
trong ammoniac th thu c 4,32 g Ag. Xc
nh CTPT v vit CTCT ca Y, bit Y c cu
to mch cacbon khng phn nhnh v cha
37,21% oxi v khi lng.

ly nhp lm bi
Gii
nY = 0,01(mol )
n
4,32
0,01 1
n Ag =
= 0,04(mol ) Y =
=
108
n Ag 0,04 4
C 2 trng hp
+ Nu Y l HCHO
16.100%
= 53% 37,21% (loi)
%mO =
30
+ Nu Y l R(CHO)2 = CxHyO2
32.100%
= 37,21% M Y = 86
%mO =
MY
12x + y = 86 suy ra x = 4, y = 6
CTCT: CHO CH2 CH2 CHO
Bi 2:
Cho 10,2 g hn hp X gm anehit axetic v
anehit propioic tc dng vi dung dch AgNO3
trong ammoniac d, thy c 43,2 g bc kt
ta.
a/ Vit phng trnh ha hc ca phn ng
xy ra.
b/ Tnh % khi lng ca mi cht trong hn
hp ban u.
Hot ng 2
chp vo v.
Bi 2:
Cho 10,2 g hn hp X gm anehit
axetic v anehit propioic tc dng vi
dung dch AgNO3 trong ammoniac d,
thy c 43,2 g bc kt ta.
a/ Vit phng trnh ha hc ca phn
ng xy ra.
b/ Tnh % khi lng ca mi cht
trong hn hp ban u.
Gii
HS: Chp
a/
CH3CHO + 2AgNO3 + 4NH3 + H2O
HS: Tho lun lm bi
CH3COONH4 + 2NH4NO3 + 2Ag
C2H5CHO + 2AgNO3 + 4NH3 + H2O
C2H5COONH4 + 2NH4NO3 + 2Ag
b/ Gi x, y ln lt l s mol anehit axetic,
anehit propioic.
44x + 58y = 10,2
2x + 2y = 0,4
ly nhp lm bi
Gii h x = y = 0,1
0,1.44.100%
= 43,14%
%CH3CHO =
10,2
%C2H5CHO = 56,86%
Hot ng 3
Bi 3:
chp vo v.
Ha tan 13,4 g hn hp hai axit cacboxylic no,
Bi 3:
Ha tan 13,4 g hn hp hai axit n chc, mch h vo nc c 50 g dung
cacboxylic no, n chc, mch h vo dch A. Chia A thnh 2 phn bng nhau. Cho
H:01:28H:01:28H:01:28
nc c 50 g dung dch A. Chia A phn th nht phn ng hon ton vi lng
thnh 2 phn bng nhau. Cho phn th d bc nitrat trong dung dch ammoniac, thu
nht phn ng hon ton vi lng d c 10,8 g bc. Phn th 2 c trung ha
IV Cng c
Tnh cht ha hc ca anehit, xeton, axit cacboxylic.
V. Dn d
Chun b bi: n tp cc kin thc hc chun b n tp hc k II
Tit 35: N TP HC K II
I. Mc tiu:
Kin thc chng 5, 6, 7, 8
II. Chun b:
GV:Gio n
HS: n tp l thuyt, lm bi chng 5, 6, 7, 8
III.Tin trnh ln lp:
Hot ng 1:
n nh lp + Bi c
Bi c: Khng kim tra
Bi mi:
H:01:28H:01:28H:01:28
Hot ng ca thy v tr
Hot ng 2:
chp vo v.
Bi 1:
Bng phng php ha hc hy phn
bit cc ha cht sau: Ancol etylic,
phenol, glixerol. Vit phng trnh
minh ha nu c
HS: Tho lun lm bi
Ni dung
Bi 1:
Bng phng php ha hc hy phn bit cc
ha cht sau: Ancol etylic, phenol, glixerol.
Vit phng trnh minh ha nu c
Gii
Trch mi l ra mt t lm mu th
Cho dung dch Br2 ln lt vo cc mu th
+ Mu th no xut hin kt ta trng
Phenol
HS: Ln bng trnh by, cc HS cn li C6H5OH + 3Br2 C6H2Br3OH + 3HBr
ly nhp lm bi
+ Mu th khng c hin tng l: Ancol etylic
v glixerol.
Cho dung dch CuSO4/ NaOH vo 2 mu th
cn li
+ Mu th lm cho dung dch c mu xanh lam
glixerol
CuSO4 + 2NaOH Cu(OH)2 + Na2SO4
2C3H5(OH)3 + Cu(OH)2 [C3H5(OH)2O]2Cu +
2H2O
+ Mu th khng c hin tng Ancol
Hot ng 3:
etylic
chp vo v.
Bi 2:
Bi 2:
T CaC2 v cht v c cn thit c y vit
T CaC2 v cht v c cn thit c y phng trnh iu ch caosu buna, nha PE,
vit phng trnh iu ch caosu PVC, CH3CHO
buna, nha PE, PVC, CH3CHO
HS: Chp
Gii
CaC2 + 2H2O
C2H2 + Ca(OH)2
xt
HS: Tho lun lm bi
2C2H2
CH2 = CH C = CH
Pd
CH2 = CH C = CH + H2
CH2 = CH CH = CH2
xt , p ,t
nCH2 = CH CH = CH2
(- CH2 CH = CH CH2 - )n
Pd
HS: Ln bng trnh by, cc HS cn li C2H2 + H2 CH2 = CH2
, p ,t
nCH2 = CH2 xt
( - CH2 CH2 - )n
ly nhp lm bi
xt
C2H2 + HCl CH2 = CH Cl
, p ,t
CH2 = CH Cl xt
( - CH2 CH - )n
Cl
HgSO4
C2H2 + H2O CH3CHO
Hot ng 4:
chp vo v.
Bi 3:
Cho 21,4 gam hn hp kh A gm
metan, etilen, axetilen qua dung dch
brom, thy c 112 gam brom tham gia
phn ng. Mt khc, nu cho 21,4 gam
kh A trn qua dung dch bc nitrat
trong amoniac thy c 24 gam kt ta.
a/ Vit cc phng trnh ha hc xy
ra.
b/ Tnh thnh phn % theo khi lng
mi cht trong hn hp A.
H:01:28H:01:28H:01:28
HS: Chp
Bi 3:
Cho 21,4 gam hn hp kh A gm metan,
etilen, axetilen qua dung dch brom, thy c
112 gam brom tham gia phn ng. Mt khc,
nu cho 21,4 gam kh A trn qua dung dch
bc nitrat trong amoniac thy c 24 gam kt
ta.
a/ Vit cc phng trnh ha hc xy ra.
b/ Tnh thnh phn % theo khi lng mi
cht trong hn hp A.
Gii
C2H4 + Br2 C2H4Br2
y
y
C2H2 + 2Br2 C2H2Br4
z
2z
* Cng c:
Nhc li cch nhn bit, iu ch, hon thnh s phn ng, gii cc bi ton hn hp
* Dn d:
Chun b bi: n tp bi chun b thi hc k II
H:01:28H:01:28H:01:28

Giao An Tu Chon 11

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Giao An Tu Chon 11

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Tit 1:

HS: Ln bng trnh by

GV: yu cu 2 HS ln trnh by, cc Al + HNO3 Al(NO3)3 + NO + H2O

GV: Nhc li 4 bc lp phng trnh

BI TP S IN LI AXIT, BAZ V MUI

Ba(NO3)2 Ba2+ + 2NO 3

GV: Chp ln bng, yu cu HS

Al2(SO4)3 tc dng vi NaOH d.

b mol Mg2+, c mol Cl-, d mol NO 3 .

c + d 2a 0,01 + 0,03 2.0,01

HS: Ch nghe ging

Chun b bi s in li ca nc. pH. Cht ch th axit baz.

GV: Yu cu 1 HS nhn xt, GV

[OH-] = 10-1 = 0,1M

S mol OH- trong 1,5 lt dd bng: 0,1.1,5 =

a/ Ba(NO3)2 + Na2CO3 BaCO3 + 2NaNO3

a/ MgCO3 + 2HCl MgCl2 + H2O + CO2

BaSO4 + 2HCl + 2H2O (1)

Theo phng trnh (1) s mol BaSO4 = s

CTHH ca mui l : BaCl2.2H2O

GV: Hng dn HS tnh khi lng

0,0025 = 0,015 (mol)

Tit 5: BI TP TNG KT CHNG S IN LI

Ba2+, Mg2+, Na+, SO 24 , CO 3 v NO 3

Ba2+, Mg2+, Na+, SO 24 , CO 3 v NO 3

GV: Yu cu 1 HS nhn xt, GV b/ Cho dung dch H2SO4 vo c 3 dung dch .

GV: Yu cu 1 HS nhn xt, GV

Nng H+ trong dung dch A l :

b/ S mol H+ trong 0,5 lt dung dch A l :

NaOH trong l 1,8x.

HS: Nghe ging v hiu

nRT 0,75.0,082(25 + 273)

Tng s mol kh lc cn bng: 2 x + 7 3x +

b/ Th tch (kt) kh ammoniac c to

GV: Yu cu HS tho lun.

v CuO cn d . ch c CuO phn ng vi

HS: Ln bng trnh by

Theo (1), s mol N2=

Gii pt: A = 23n.

GV: Gi HS nhn xt, ghi im

% khi lng ca Cu = 70, 33%

Tit 8: BI TP MUI NITRAT

Nung nng 27,3 g hn hp NaNO3 v

HS:Ln bng trnh by

nc th cn d 1,12 l kh(ktc) khng b hp

m NaNO3 = 0,1.85 = 8,5( g )

nCu ( NO3 ) 2 = 18,8 : 188 = 0,1(mol )

Khi lng HNO3 l: 0,2.63 = 12,6 (g)

BI TP. AXIT PHOTPHORIC V MUI PHOTPHAT

bit dung dch HNO3 v dung dch

GV: Gi HS nhn xt, ghi im

Cu + HNO3 () Cu(NO3)2 + 2NO2 + 2H2O

BI TP AXIT NITRIC - MUI NITRAT

GV: Hng dn HS cch vit pt, gi

Gii (1) v (2) c x = 0,1; y = 0,4

HS:Ln bng trnh by

Tit 11: BI TP TNG KT CHNG NIT - PHOTPHO

Tm % v th tch ca N2 sau phn

GV: Yu cu 1 HS ln bng trnh by. 1/ NH4Cl + NaOH

500ml dung dch H3PO4 1,5M. Sau

BI TP CACBON V CC HP CHT CA CACBON

ton b lng kh thot ra hp th ht

Do phn ng to 2 mui NaHCO3 v Na2CO3