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SAFETY DATA SHEET

Trade name:
Version: 3 1.

MOL-LUB Ltd.
Date of issue: 21.10.2004 Page: 1/(9)

EVOX DOT 4+ brake fluid


Latest revision: 20.07.2007

Identification of the substance / preparation and of the company Product name: EVOX DOT 4+ Product type / recommended uses: Preparation / brake fluid Manufacturer / Supplier identification: MOL-LUB Lubricant Production Trade and Service Limited Liability Company H-2931 Almsfzit, F u. 21., Hungary Phone / Fax: (+36-34) 526-330 / (+36-34) 526-391 Request SDS of: MOL-LUB Lubricant Production Trade and Service Limited Liability Company Customer Service Center H-2931 Almsfzit, F u. 21., Hungary Phone / Fax: +36 80 201 296 / +36 34 348 010 Responsible for SDS: MOL-LUB Ltd. Csaba Horvth, head of HSE and QOP Phone: +36 34 526 343; Mobile: +36 20 474 2644 e-mail: csahorvath@mol.hu Technical information: MOL-LUB Ltd. Product Development and Technical Service H-1117 Budapest, Oktber huszonharmadika u. 18., Hungary Phone/Fax: +36 80 201 296 or +36 1 464 0236 / +36 1 464 0304 Emergency telephone (07-1520 h): +36 34 526 210 Health Toxicological Information Service (ETTSZ 1096 Budapest, Nagyvrad tr 2.) Tel.: +36 1 476 6464, or +36 80 201 199

2.

Hazards identification Human health hazards: Xi R 41 Note: (irritant) Risk of serious damage to eyes Prolonged and/or repeated contact may cause irritation and/or skin sensibilization, depending on individual sensitivity (see also Protective equipment).

Safety hazards: Environmental hazards:

Danger symbol not required. Danger symbol not required.

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Trade name:
Version: 3

EVOX DOT 4+ brake fluid


Latest revision: 20.07.2007 Date of issue: 21.10.2004 Page: 2/(9)

3.

Composition / information on ingredients Chemical description: Mixture of glycol ethers, glycols, inhibitors.

Ingredients / Hazardous components:


Name Triethylene glycol monobutyl ether 2-(2-Methoxyethoxy) etanol Diethylene glycol Aliphatic amine 4,4-isopropylidenediphenol EINECS number 205-592-6 203-906-6 203-872-2 confidential 201-245-8 CAS number 143-22-6 111-77-3 111-46-6 80-05-7 Hazard symbol Xi Xn Xn Xi Xi Risk phrase R 41 R 63 R 22 R 36 R 37, R 41, R 43, R 62 Conc. %(m/m) > 10 < 20 >1<5 >3<5 <3 > 0.1 < 0.5

The full text of each relevant R phrase see in Section 16. 4. First aid measures General information: Never give anything by mouth to an unconscious person, or never induce vomiting. Remove contaminated clothing.

Inhalation: Skin contact: Eye contact: Ingestion:

Remove the affected person to fresh air. If rapid recovery does not occur, obtain medical attention. Remove contaminated clothing and wash skin with plenty of water, use soap. If irritation persists, obtain medical attention. Flush eyes with plenty of water for 10-15 minutes. Obtain medical attention. If swallowed rinse mouth, give to drink plenty of water, do not induce vomiting, get medical attention. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Note to physician:

5.

Fire-fighting measures Fire hazards: Moderately hazardous (see also Section 9 - flash point).

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EVOX DOT 4+ brake fluid


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Suitable extinguishing media: Water, foam, carbon dioxide, dry chemical powder. Unsuitable extinguishing media: Hazardous decomposition products: On burning, fume and other toxic gases can be formed. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions: See Section 8. Environmental precautions: Prevent spills from entering into natural water, soil and drains by containing the liquid. All kind of ignition sources should be remove. Notify relevant authority. Clean-up procedures / recovery On soil: Contain spilled liquid with sand, earth or other suitable absorbents. Recover free liquid by pumping. Dispose of according to local regulations. On water: Confine the spillage. Notify local authorities according to regulations. 7. Handling and storage Handling: Keep away from radiant heat and open flame. Ensure thorough ventilation of stores and work areas. Prevent contact with air/oxygen (formation of peroxide). Take precautionary measures against static discharges. Handling temperature: Storage: Keep general measures applied for normal operations with lubricants. Store in cool, dry, well-ventilated area, in original, closed containers. Keep away from strong oxidizing agents. Storage temperature: max. 45C

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EVOX DOT 4+ brake fluid


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8.

Exposure controls / personal protection Engineering control measures: Adequate ventilation. Exposure limits: Personal protection: Respiratory protection: Hand protection: Breathing apparatus not required. Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) 0.7 mm coating thickness Polyethylene-Laminate (PE laminate) ca. 0.1. mm coating thickness Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374): nitrile rubber (NBR) 0.4 mm coating thickness Manufacturers directions for use should be observed because of great diversity of types. Safety glasses with side-shields (frame goggles) (EN 166) Protective clothing.

Eye protection: Skin protection: Other special:

General protective measures / hygiene: Avoid contact with eyes. Avoid prolonged breathing of oil vapours, aerosols or mists. Ensure washing facilities after working hours and before breaks. Take off contaminated or oil-soaked clothing, wash with warm water and soap. Females of childbearing age should not come into contact with the product. Environmental exposure controls: 9. Physical and chemical properties Appearance: Physical state: Colour: Odour: Change in physical state: Solidification point (DIN 51583): Boiling point (ASTM D1120): liquid colourless - yellow typical < -50C > 260C

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EVOX DOT 4+ brake fluid


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Others: Flash point (COC) (DIN 51758): Ignition temperature (DIN 51794): Autoignition temperature: Explosive properties: Oxidizing properties: Vapour pressure at 20C: Density at 20C: Specific density at 20C: Solubility in water at 15C: Solubility in polar solvents: n-Octanol/water partition coefficient: Kinematic viscosity at 20C (DIN 51562): pH: 10. Stability and reactivity Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Notes: 11. Toxicological information Acute toxicity: Oral: Acute toxicity: irritation: Skin: Eye: Mocous membrane: Note: Sensitization: Chronic toxicity: LD50 (rat)

> 130C > 200C not explosive kb. 1.060 g/cm3 soluble soluble not available 14 mm2/s 7.5 9

No decomposition if stored and handled properly. Direct heat or ignition sources. On burning, fume and other toxic gases can be formed. Under normal conditions no dangerous decomposition products are formed.

> 2000 mg/kg

(based on components)

not irritant (based on components) risk of serious damage to eyes (based on components) not irritant (based on components) Prolonged and/or repeated contact may cause irritation and/or skin sensibilization, depending on individual sensitivity not sensitising (based on components), but may produce an allergic reaction not known

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EVOX DOT 4+ brake fluid


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Other information, specific effects: Carcinogen effect: Mutagen effect: Reproduction-damaging effect:

not known, resp. not carcinogen (based on components) not known, resp. not mutagen (based on components) not known, resp. no reproduction-damaging effect (based on components)

12.

Ecological information Mobility: Degradability / persistence: Biodegradability:

OECD 302B; ISO 9888; 88/302/EEC, Part C (DOC-reduction) > 70 %

Bioaccumulative potential: Ecotoxicity: Aquatic organisms: Fish test: Leuciscus idus: LC50 96 h > 100 mg/l Soil organisms: Plants: Effects on activated sludge: Inhibiton of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. Biological oxygen demand: Chemical oxygen demand: Heavy metal content: None. AOX: None. Environmental effects: Water hazard classification (German): 13. Disposal considerations Product disposal: Wastes of the product or used oil should be treated as hazardous waste. EWC cod: 16 01 13* brake fluids Disposal must be in compliance with national and local regulations. Packaging disposal: Containers with product residue should also be treated as hazardous waste according to national and local disposal regulations. EWC cod: 15 01 10* packaging containing residues of or contaminated by dangerous substances Wastewater: Quality of wastewater emitted to natural water must comply with national and local regulations.

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Version: 3

EVOX DOT 4+ brake fluid


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Care should be taken in any case to ensure compliance with EC, national and local regulations. It is the responsibility of the user to know all relevant national and local regulations. 14. Transport information Land transport: Road/ Railway ADR/RID: Not classified. Not classified. Not classified.

Waterways: Inland waterways/ Sea transport ADN/IMDG: Air transport: 15. ICAO / IATA:

Regulatory information Classification and labelling according to EU directives [67/548/EEC and 88/379/EEC, 1999/45/EC (existing versions)] and to Hungarian regulation [44/2000. (XII. 27.) EM rendelet (existing version)] for hazardous substances and hazardous preparations: Danger symbol(s) and indication(s): Xi

irritant Hazardous component(s): Triethylene glycol monobutyl ether 2-(2-Methoxyethoxy) etanol Diethylene glycol < 20 % <5% <5% May

The packaging must bear the inscription: R-phrases: S-phrases: R 41 S 24 S 26 S 39 S 60 S 61

Contains 4,4-isopropylidenediphenol. produce an allergic reaction.

Risk of serious damage to eyes. Avoid contact with skin In case of contact with eyes, rinse immediately with plenty of water and seek medical advice Wear eye/face protection This material and its container must be disposed of as hazardous waste Avoid release to the environment. Refer to special instructions/Safety data sheets

Tactile warning of danger: not required

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Version: 3

EVOX DOT 4+ brake fluid


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16.

Other information Recommended application / restrictions: See product sheets. The information given in this data sheet is based on our best knowledge at the time of publication. The information is related only to this product and is intended to assist its safe transport, handling and use. The given physical and chemical parameters describe the product only for the purpose of safety requirements and therefore should not be construed as guaranteeing any specific property of the product or as being part of a product specification or any contract. The manufacturer or supplier shall not take responsibility for any damages from the use other than recommended or other misuse of the product. It is the responsibility of the user to keep regulatory precautions and observe recommendations for safe use of the product. This safety data sheet has been prepared according to Regulation (EC) No 1907/2006, Directives 88/379/EEC and 1999/45/EC. Source of data presented in this material safety data sheet: Test results of this product Material safety data sheets of products components Hungarian and EU lists of dangerous substances Relevant Hungarian regulation and EU directives

The full text of each relevant R phrase in Section 3.: R 22 R 36 R 37 R 41 R 43 R 62 R 63 Harmful if swallowed Irritating to eyes Irritating to respiratory system Risk of serious damage to eyes May cause sensitisation by skin contact Possible risk of impaired fertility Possible risk of harm to unborn child

Utols nyomtats: 2007.07.27. de. 9:06

Trade name:
Version: 3

EVOX DOT 4+ brake fluid


Latest revision: 20.07.2007 Date of issue: 21.10.2004 Page: 9/(9)

Revision Indicators: Section 1 9 15, 16 2 3 8 9 11 15 16 Subject of change Identification of the substance / preparation and company Physical and chemical properties Regulatory information and other corrections Composition / information on ingredients Hazards identification Exposure controls / personal protection Physical and chemical properties Toxicological information Regulatory information Other information Regulatory informations, other corrections Date 18.05.2006 Version 1

20.03.2007

20.07.2007

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