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Material Safety Data Sheet

Uncontrolled Copy AEROGARD TROPICAL STRENGTH PERSONAL INSECT REPELLANT AEROSOL
Infosafe No. 8AE4O Issue Date July 2006 Status ISSUED by RECKITT
BS: 1.9.40

Classified as hazardous according to criteria of NOHSC

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name Product Code Company Name Address

AEROGARD TROPICAL STRENGTH PERSONAL INSECT REPELLANT AEROSOL

RECKITT BENCKISER (AUSTRALIA) PTY LIMITED (ABN 17 003 274 655) 44 Wharf Road West Ryde NSW 2114 (02) 9857-2444 Tel: (02) 9857 2000 Fax: (02) 858 5721

Emergency Tel. Telephone/Fax Number

Recommended Use Personal insect repellent

Other Names

Name AOG TS PIR AERO

Product Code

2. HAZARDS IDENTIFICATION

Hazard Classification

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. Hazard classification according to the criteria of NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code.

Risk Phrase(s)

R36 Irritating to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse

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effects in the aquatic environment. Safety Phrase (s) S2 Keep out of reach of children. S16 Keep away from sources of ignition - No smoking. S25 Avoid contact with eyes.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Information on Composition

HAZARDOUS COMPONENTS Chemical Name CAS No. Proportion (% w/w) N-N-diethyl-m-toluamide 134-62-3 10 - <30 N-octyl bicycloheptene dicarboximide 113-48-4 1 - <5 Isopropyl myristate 110-27-0 5 - <10 Ethanol 64-17-5 30 - 60 Butane 106-97-8 30 - 60 The other ingredients to 100%w/w are classified as not hazardous according to NOHSC (Australia) Chemical Name CAS No. Declared Level on Label N-N-diethyl-m-toluamide 134-62-3 191 g/kg N-octyl bicycloheptene dicarboximide 113-48-4 40 g/kg Our supplier of butane has provided documentation stating that the butane component contains less than 0.1%w/w 1,3 butadiene.

Ingredients

See Below

4. FIRST AID MEASURES

First Aid Measures

General Advice: Show this safety data sheet to the doctor in attendance. If poisoning occurs, contact a doctor or Poisons Information Centre. (Phone: Australia 13 1126, New Zealand 0800 764 766 or 0800 POISON) Remove to fresh air. If breathing difficulties are experienced, seek medical advice. Give 2 glasses of water to drink. Do not induce vomiting. Contact a doctor or Poisons Information Centre. Wash off contamination with plenty of water. Rinse thoroughly with plenty of water for at least 15 minutes and consult a doctor.

Inhalation

Ingestion

Skin Eye

Advice to Doctor

Treat symptomatically

5. FIRE FIGHTING MEASURES

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Suitable Extinguishing Media Hazards from Combustion Products Special Protective Equipment for fire fighters Specific Methods Hazchem Code Dry chemical Foam Carbon dioxide (CO2)

Thermal decomposition can lead to release of irritating gases and vapours

Use personal protective equipment. See section 8 (EXPOSURE CONTROLS/PERSONAL PROTECTION). Aerosol cans may explode with extreme heat and become projectiles. None allocated

6. ACCIDENTAL RELEASE MEASURES

Emergency Procedures

Emergency and Evacuation Procedures: Ensure adequate ventilation. Contain and signpost spill. Depending on spill size, collect spill according to instructions below. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

Personal Precautions

Clean-up Methods - Small Mop up spill and wash area with detergent and water. Spillages Clean-up Methods - Large Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Spillages Environmental Precautions

Do not let product enter drains or natural waterways.

7. HANDLING AND STORAGE

Precautions for Precautions for Safe Handling: Dangerous goods class 2.1 (AEROSOLS). Handle accordingly. Safe Handling Safe Handling Advice: Keep away from heat and sources of ignition. Conditions for Safe Storage Conditions for Safe Storage: Dangerous goods class 2.1 (AEROSOLS). Store accordingly Incompatible Products: Avoid heat and ignition sources.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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National Exposure Standards

National Exposure Standards: Exposure Standards have been set for the following ingredients: Ethanol (64-17-5) Australian TWA = 1000 ppm = 1880 mg/m Butane (106-97-8) Australian TWA = 1900 mg/m = 800 ppm TWA - The Time-Weighted Average airborne concentration over an eight-hour working day, for a five day working week over an entire working life. According to current knowledge this concentration should neither impair the health or, not cause undue discomfort to, nearly all workers.

Biological Limit Values Engineering Controls Respiratory Protection Eye Protection

No biological limit values allocated. Ensure adequate ventilation. Maintain air concentrations below exposure standards. In case of insufficient ventilation wear suitable respiratory equipment. Safety glasses.

Hand Protection Solvent-resistant gloves (butyl rubber). Personal Protective Equipment

Use the following personal protective equipment when handling bulk quantities of product:

Body Protection Lightweight protective clothing. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Odour Boiling Point Solubility in Water Specific Gravity pH Value

Mist Citrus 0C (Butane)

Insoluble

0.860 @ 25C (Concentrate) Not applicable

Vapour Pressure 240 kPa @16C (Butane) Vapour Density

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(Air=1) Physical State Colour Flash Point Flammable Limits - Lower Flammable Limits - Upper Other Information 2.046 (air =1) (butane gas) Aerosol Colourless -60C (butane)

1.5% v/v (butane)

8.5% v/v (butane)

Fat solubility: Soluble

10. STABILITY AND REACTIVITY

Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions Hazardous Polymerization

Stable under recommended storage conditions.

Prolonged exposure to high or low temperatures.

Oxidizing agents.

Oxides of carbon, nitrogen.

Aerosols can explode and rocket when subjected to extreme heat

Hazardous polymerisation does not occur.

11. TOXICOLOGICAL INFORMATION

Toxicology Information

PRODUCT TOXICITY DATA: The toxicology of this product has not been determined. Clinical testing on a similar product indicates that the product is not irritating to the skin. The hazard identifications in Sections 2, 11 and 15 of the MSDS were derived from the known effects of the individual ingredients and their concentrations in the product. COMPONENT TOXICITY DATA: The following component toxicity data was considered to determine the overall toxicity of this product. N-N-diethyl-m-toluamide (134-62-3) LD50 Oral = 1950 mg/kg Rat LD50 Dermal = 3180 L/kg Rabbit Inhalation LC50 4h = 5950 mg/m3 rat

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Sensitization Non-sensitiser N-octyl bicycloheptene dicarboximide (113-48-4) LD50 Oral = 2800 mg/kg Rat LD50 Dermal = 470 mg/kg Rabbit Inhalation LC50 4h >4.08 mg/L albino rat Eye Irritation Slight irritant Skin Irritation Slightly irritating Sensitization Non-sensitiser Isopropyl myristate (110-27-0) LD50 Dermal = 5 g/kg Rabbit Ethanol (64-17-5) LD50 Oral = 7060 mg/kg rat Eye Irritation Irritating to eyes Skin Irritation Will have a degreasing action on the skin Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system May cause irritation to the upper gastrointestinal tract.

Ingestion

Chronic Effects The chronic toxicity of this product has not been determined. Eye Irritation Will cause irritation to the eye

Skin Irritation May cause irritation of the skin.

12. ECOLOGICAL INFORMATION

Ecological Information

PRODUCT ECOTOXICITY DATA: The ecotoxicity of this product has not been determined. However, the following component information is available. COMPONENT ECOTOXICITY DATA: The following component ecotoxicity data was considered to determine the overall ecotoxicity of this product. N-N-diethyl-m-toluamide (134-62-3) Ecotoxicity Data LC50 = 110 mg/L fathead minnow 96h flow-through EC50 = 67.9 mg/L Photobacterium phosphoreum 5 min EC50 daphnia magna = 75 mg/L 48h LC50 bobwhite quail (bird) = 1375 mg/kg Ethanol (64-17-5) Ecotoxicity Data LC50 = 11200 mg/L LC50 = 12900 mg/L LC50 = 14200 mg/L EC50 = 34634 mg/L

fingerling trout 24h rainbow trout (30 days old) 96h flow-through fathead minnow 96h flow-through Photobacterium phosphoreum 30 min

Ecotoxicity

Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Persistence / Degradability

No information available.

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Mobility No information available

13. DISPOSAL CONSIDERATIONS

Waste Disposal

Bulk quantities of product must be disposed of according to Local, State and Federal regulations. Do not allow bulk product to be disposed of in the sewerage or natural waterways.

Special precautions for landfill or Not suitable for incineration. incineration

14. TRANSPORT INFORMATION

Transport Information

UN Number: UN 1950 ADG (Australian Road and Rail) Australia Road and Rail Transport: Classified as Dangerous Goods for the purpose of transport by road or rail. Refer to relevant regulations for storage and transport requirements. Proper Shipping Name: AEROSOLS Dangerous Good Class: 2.1 Subsidiary Risk: None allocated Packing Group: None allocated Hazchem code: None allocated Special Precautions for Transport: None IMDG / IMO (Sea) Proper Shipping Name: AEROSOLS Dangerous Good Class: 2.1 Subsidiary Risk: None allocated Packing Group: None allocated IMDG Page: 95 Marine Pollutant: Not a marine pollutant EmS: F-D, S-U Maximum Quantity: Not applicable IATA / ICAO (Air) Proper Shipping Name: AEROSOLS Dangerous Good Class: 2.1 Subsidiary Risk: None allocated Packing Group: None allocated Maximum Quantity: Not applicable

U.N. Number

1950

Proper Shipping AEROSOLS Name DG Class Sub.Risk Hazchem Code 2.1 None allocated None allocated

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Packaging Method Packing Group EPG Number IERG Number None allocated 2D1 49

15. REGULATORY INFORMATION

Regulatory Information

Regulatory Approvals: This product has been approved by the Australian Pesticides and Veterinary Medicines Authority (APVMA) Australia Regulatory Approval Numbers: APVMA No. 60098

Poisons Schedule Symbol

Not Scheduled Xi - Irritant

Hazard Category Irritant AICS (Australia) Not all the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).The ingredients not listed on AICS are exempt as they are included by Australian Pesticides and Veterinary Medicines Authority (APVMA) legislation.

16. OTHER INFORMATION

Revisions Highlighted Other Information

Reason for revision: Addition of Product Codes, APVMA No. & Environment Risk Phrase. Customer Product 0050478 Tropical 0050480 Tropical 0050479 Tropical Codes: Variant Name: Sizes: Strength 100g Strength 150g Strength 250g

NEW ZEALAND Reckitt Benckiser (New Zealand) Limited Lincoln Manor 289 Lincoln Road, Henderson, Auckland 1231 TEL: (09) 839 0200 Manufacturer: Reckitt Benckiser Aerosols Plant Australia POISONS CENTRE INFORMATION: Australia - 13 1126 New Zealand - 0800 764 766 or 0800 POISON Version No.: 3 MSDS No.: D0035113 Key: NOHSC = National Occupational Health and Safety Commission

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(Australia) SUSDP = Standard for the Uniform Scheduling of Drugs and Poisons (Australia) ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail ADR = International Regulations Concerning the Carriage of Dangerous Goods by Road RID = European Agreements Concerning the International Carriage of Dangerous Goods by Rail IMDG = International Maritime Organization Rules IATA = International Air Transport Association ICAO = International Civil Aviation Organization Prepared by: Reckitt Benckiser Regulatory, Safety & Environmental Services (Australia) Phone: +61 2 9857 2000 This MSDS has been prepared according to the National Code of Practice for the Preparation of Safety Data Sheets 2nd Edition [NOHSC:2011(2003)]. This MSDS has been transcribed into Infosafe NOHSC format from an original issued by the manufacturer on the date shown. Any disclaimer by the manufacturer may not be included in the transcription.

End of MSDS

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