Trng THPT Nam Sch II cng n tp Ha Hc 11CB- HK II CNG N TP HC K II NM HC 2012 I.

I. DNG 1: ng phn, danh php: Vit v gi tn cc ng phn ca: 1. Ankan c CTPT: C3H8, C4H10, C5H12 , C6H14 2. Anken c CTPT: C4H8, C5H10 3. Ankin c CTPT: C3H4 , C4H6, C5H8 4. Ankyl benzen c CTPT: C8H8, C8H10 5. Ankadien c CTPT: C4H6, C5H8. 6. Ancol c CTPT: C3H8O, C4H10O , C5H12O I. DNG 2: Vit PTP: Hon thnh cc PTHH ca cc phn ng sau: askt t0 CaO, t0 1). CH3-CH2-CH3+ Br2 2). CH4 + O2 3). CH3COONa +NaOH 4). Al4C3 + H2O 5). CH2=CH-CH3+Br2 6). CH2=C(CH3)-CH3+HBr H+ t0 7). CH2=CH-CH3+H2O 8). CH3-CH=CH-CH3+ HBr 9). C2H4 +O2
p, xt, t 10). nCH2=CH2
0

13). CHCH 16) 3CHCH 19). CH3OH 22). C2H5OH 25). C6H5OH 27). C6H5CH3

+HCl
0

p, xt, t 11). nCH2=CH-CH3

p, xt, t 12). nCH2=CHCl xt ( ha) ime 15). 2CHCH

14). CHCH

600 C, xt (trimeha) +Na

+CuO +Br2

Hg 0 t 17). C6H5CH3 +Br2 20) C3H5(OH)3+ Na 23). C6H5OH +Na

+H2O

2+

18) C6H5CH3 21). C2H5OH 24). C6H5OH

0

Fe, t +Br2
H2SO4 ,140 C +KOH
0

H2SO4 (c), t 26). C6H5OH+HNO3 (c)

0

29). C6H5CH=CH2+ HBr

0

H2SO4 (c), t +HNO3(c)

28). C6H5CH=CH2+ Br2

p, xt, t 30). nC6H5CH=CH2

0

H2SO4 ,170 C H2SO4 ,170 C 31). C2H5OH 32). CH3-CH(OH)-CH2-CH3 II. DNG 3: Thc hin chui P theo s v iu ch 1. Chui P: (1) (2) (3) (4) (5) (6) 1) natri axetat metan axetilen benzen brombenzen A phenol (1) (2) (3) (4) (5) 2) butan etan etyl clorua etanol etilen P.E (7) (6) (8) etanol axit axetic 3) Butan etan etyclorua eten ancoletylic ivinyl butan metan etin benzen. 4) butan metan axetilen andehit X ancol Y A cao su buadien 5) CaCO3 CaO CaC2 C2H2 bc axetilua axetilen vinyl clorua PVC 6) Butan etan etyclorua eten ancoletylic ivinyl butan metan etin benzen. 7) Al4C3 CH4 C2H2 C6H6 C6H5CH3 C6H5COOH C6H5COONa C6H6 666. C4H4 C4H6 Cao su BuNa 8) Benzen brombenzen natri phenolat phenol 2,4,6-tribromphenol 9) Propan metan axetilen vinyl axetilen butan etilen etilen glicol. 10)

C2H5ONa C2H5OH (C2H5)2O

C4H6 CH3COOH C2H5Br

Cao su Buna CH3COONa CH4

IV. DNG 4: Nhn bit: Bang phng phap hoa hoc hay phan biet : a. CH4, C2H4, C2H2 v CO2. b. Axetilen va Etilen; c. Metan, Etilen, Axetilen d.Butan, Butin-1 va Butin-2 e. Benzen, Toluen, Stiren, Hex-1-in; f. Toluen, Hexen-2, Hexin-1, nHexan g. Phenol, etanol, glixerol, nc; h. Axit fomic, andehit axetic, axit axetic, ancol etylic V. DNG 5: Tm CTPT ca hp cht hu c da vo phn tch nguyn t Cu 1. t chy hon ton 0,3 gam cht A (phn t ch cha C, H, O) thu c 0,44 gam kh CO 2 v 0,18 gam nc. Th tch hi ca 0,3 gam cht A bng th tch ca 0,16 gam kh oxi (o cng iu kin). Xc nh CTPT A. Cu 2. t chy hon ton 2,46 gam cht hu c (A) thu c 5,28 gam CO2, 0,9 gam H2O v 224ml N2 (o ktc). T khi hi ca (A) so vi khng kh l 4, 24. Xc nh cng thc phn t ca (A). Cu 3. t chy hon ton 5,6 lt cht kh hu c, th thu c 16,8lt CO2 v 13,5 gam H2O. Cc cht kh (o ktc). Lp cng thc phn t, bit rng 1 lt kh cht hu c ktc nng 1,875 gam. VI. DNG 6: Tm CTPT trong dy ng ng cc cht H tn HS:.. Lp 11 Trang 1

Trng THPT Nam Sch II cng n tp Ha Hc 11CB- HK II Cu 1: Mt hn hp 2 ankan ng ng k tip nhau c khi lng 24,8g, th tch tng ng l 11,2 lit(kc). Xc nh CTPT v tnh % th tch ca 2 ankan. Cu 2: t chy hon ton 0,672 lt (ktc) hai hirocacbon k tip nhau trong dy ng ng. Sn phm chy cho ln lt qua bnh 1 ng H2SO4 c v bnh 2 ng KOH rn thy khi lng bnh 1 tng 1,8g v bnh 2 tng 4,4g. Xc nh cng thc phn t ca 2 hirocacbon? Cu 3: t chy hon ton 7,2 gam mt hidrocacbon thu 22 gam CO2 v 13,44 lit hi nc (kc) . a) Tm CTPT hidrocacbon b) Vit ng phn v gi tn bit khi tc dng Cl2 (1:1) cho mt sn phm duy nht. Cu 4: t chy hon ton hn hp 2 ancol no n ng ng k tip thu 5,824 lit CO2 kc v 6,48 gam H2O a) CTPT v khi lng mi ancol trong hn hp? b) Oxi ha hn hp A bng CuO thu hn hp B gm 2 cht hu c. Cho B tc dng AgNO 3 /NH3 thu 8,64 gam Ag. Tm CTCT mi ancol bit phn ng hon ton. Cu 5: t chy hon ton hn hp gm hai ankin l ng ng lin tip c 7,84lt CO 2 (ktc) v 4,5gam hi H2O. CTPT ca 2 ankin l? Cu 6: t chy hon ton mt ancol n chc X thu c 4,4 gam CO2 v 3,6 gam H2O. Xc nh CTPT ca X. Cu 7: Cho 3,7g mt ancol X no, n chc, mch h tc dng vi natri ly d thy c 0,56 lt kh thot ra kc. Cng thc phn t ca X l? Cu 8: Cho 16,6 g hn hp 2 ancol k tip nhau trong dy ng ng ca metanol p vi Natri (d) c 3,36 lt H 2 (kc). Xc nh cng thc CTPT 2 ancol Cu 9: Khi ot chay hoan toan 0,02 mol mot hidrocacbon sinh ra 2,64g CO2. Hidrocacbon nay tac dung vi dung dch AgNO3/NH3 tao ket tua vang nhat. Xac nh CTPT, CTCT. VII. DNG 7: Bi tp tng hp Cu 1: t chy hon ton 6,72 lt hh X gm 2 cht kh CH4 v C3H6 sinh ra 11,2 lit kh CO2. Cc th tch kh o ktc.Tnh % th tch mi kh trong hh X Cu 2: Cho benzen tc dng vi lng d HNO3 c c xc tc H2SO4 c iu ch nitrobenzen. Tnh khi lng nitrobenzen thu c khi dng 1 tn benzen vi hiu sut 78%. Cu 3: Cho etilen vo bnh cha brom lng to ra 1,2-dibrometan. a/ Tnh th tch etilen (kc) tc dng v brom bit rng sau khi cn li thy bnh brom tng thm 4g. b/ Tnh khi lng brom c th kt hp vi 3,36 lit kh etilen (kc). Cu 4: Cho 2,24 lit mt hn hp kh A (kc) gm etan, propan, propilen sc qua dung dch nc brom d, thy khi lng bnh tng thm 2,1g. Nu t chy kh cn li s thu c mt lng CO2 v 3,24g H2O. a/ Tnh % th tch mi kh . b/ Dn lng CO2 ni trn vo bnh ng 200ml dd KOH 2,6M. Tnh nng mol cc cht trong dd sau phn ng. Cu 5: lm kt ta hon ton 7,84lit hn hp X gm axetilen v propin(kc) th cn va 400ml dd AgNO3 1,5M. Xc nh lng kt ta to thnh Cu 6: t chy hon ton 5,36 gam hn hp X gm etilen v benzen th cn va 17,28 gam kh oxi. a/ Tnh % khi lng mi kh trong hh ban u b/ Tnh th tch kh CO2 thu c kc c/ Nu dn ton b lng CO2 thu c vo 300 ml dd KOH 2M th thu c khi lng mi mui l bao nhiu? Cu 7: Dn hn hp X gm etilen v axetilen qua dung dch brom d khi lng bnh brom tng 1,34gam. Cn khi cho tc dng ht vi dung dch AgNO3/NH3 thu c 7,2 gam kt ta. Tnh % th tch ca etilen v axetilen ? Cu 8: Chia hon hp Etilan va Axetilen lam hai phan bang nhau. Phan 1 cho i qua bnh nc brom d thay khoi lng bnh tang 0,68g. Phan 2 em ot chay hoan toan th can 1,568 lt O2 (kc) a) Xac nh % the tch hon hp au b) Tnh t khoi hi cua hon hp so vi Oxi Cu 9: t chy hon ton 10,6 gam hn hp X gm hai ancol C2H5OH v n-C3H7OH. Ton b sn phm chy thu c sc vo bnh ng dung dch nc vi trong d thu c 5 gam kt ta v khi lng bnh tng ln m gam. a. Tnh khi lng mi ancol trong hn hp ban u. b. Tnh gi tr m. Cu 10: Hn hp A gm phenol v ancol benzylic. Cho m gam A tc dng vi Na d thy thot ra 0,336 lt kh hiro (ktc). Mt khc, m gam A tc dng ht vi dung dch brom d, thu c 6,62 gam kt ta trng. Vit PTP ca cc phn ng xy ra v tnh m. Cu 11: Dn t t 3,36 lt (kc) hn hp gm etilen v propilen vo dung dch brom thy dung dch b nht mu v khng cn kh thot ra. Khi lng dung dch sau phn ng tng 7,0 gam. Tnh %V mi kh trong hn hp u. Cu 12: a gam hon hp ru etylic va phenol tac dung het vi Na (ly d) thu c 6,72 lt kh (kc). Mat khac cung a gam hon hp tren tac dung va vi 200 ml dung dch NaOH 2M. a) Tnh gia tr cua a b) Neu cho 1/2 lng hn hp tren vao nc Brom (d) thu c bao nhieu gam ket tua mau trang. CHC CC EM N TP TT H tn HS:.. Lp 11 Trang 2