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CHNG V : I CNG KIM LOI

V TR CA KIM LOI TRONG BNG HTTH
A. KIN THC K THA
- Vit cu hnh electron t xc nh v tr kim loi trong bng tun hon.
- Tnh cht ha hc chung ca kim loi.
B.
KIN THC C BN TRNG TM:
I. V TR CA KIM LOI TRONG HTTH. CU TO CA KIM LOI
1. V tr ca kim loi:
- Nhm IA (tr H); nhm IIA; nhm IIIA(tr B); 1 phn ca nhm IVA n VIA.
- Nhm IB n VIIIB.
- H Lantan v Actini.
2. Cu to ca kim loi:
- Cu to nguyn t:
+ Nguyn t ca hu ht cc nguyn t kim loi iu c t electron lp ngoi cng ( 1,2 hoc 3).
V d: Na[Ne]3s1,Mg[Ne]3s2, Al[Ne] 3s23p1.
+ Trong cng chu k, nguyn t ca nguyn t kim loi c bn knh nguyn t ln hn v in tch ht nhn nh hn
so vi nguyn t ca nguyn t phi kim.
V d:
11Na
12Mg
13Al
14Si
15P
16S
17Cl
Bn knh: 0,157 0,136 0,125 0,117
0,11 0,104
0,099
- Cu to tinh th:
+ Mng tinh th lc phng: Nguyn t v ion kim loi chim 74% v th tch cn li 26% l khng gian trng. V
d: Be, Mg, Zn,
+ Mng tinh th lp phng tm din: Nguyn t v ion kim loi chim 74% v th tch cn li 26% l khng gian
trng. V d: Cu, Ag, Al,
+ Mng tinh th lp phng tm khi: Nguyn t v ion kim loi chim 68% v th tch cn li 32% l khng gian
trng. V d: Li, Na, K,
=> Kiu mng lp phng tm khi km t kht nht
3. Lin kt kim loi: L lin kt c hnh thnh do lc ht tnh in gia cc ion kim loi v cc electron t do.
II. TNH CHT CA KIM LOI. DY IN HO CA KIM LOI
1. TNH CHT VT L CHUNG: iu kin thng cc kim loi trng thi rn (tr Hg) c tnh do, dn in,
dn nhit v c nh kim.
* Gii thch
a) Tnh do: Do lc ht gia cc e t do vi cc cation kim loi trong mng tinh th nn ch trt ln nhau m khng
tch ri nhau. VD: Au, Ag, Al, Cu, Sn.
b) Tnh dn in: Do cc e t do chuyn ng thnh dng trong kim loi khi ni vi ngun in
VD: Ag, Cu, Au, Al, Fe.
c) Tnh dn nhit: Do cc e t do mang nng lng v truyn nng lng cho cc ion dng vng c nhit thp
hn. VD: Ag, Cu, Au, Al, Fe.
d) Tnh nh kim: Cc e t do trong tinh th kim loi phn x hu ht nhng tia sng nhn thy c.
=> Tm li tnh cht vt l chung ca kim loi gy nn bi s c mt ca cc e t do trong mng tinh th kim loi .
2. TNH CHT VT L RING:
Kim loi khc nhau c khi lng ring, nhit nng chy v tnh cng khc nhau.
- Kim loi c khi lng ring ln nht l: Os
- Kim loi c khi lng ring nh nht l: Li
- Kim loi c nhit nng chy cao nht l: W
- Kim loi c nhit nng chy thp nht l: Hg
- Kim loi c tnh cng ln nht l: Cr
- Kim loi c tnh cng nh nht l: Cs
3. TNH CHT HO HC: Tnh cht ho hc chung ca kim loi l tnh kh. M Mn+ + ne
- Tc dng vi phi kim:
VD: 2Fe + 3Cl2 2FeCl3 ;
3Fe + 2O2 Fe3O4 ;
4Al + 3O2 2Al2O3.
Fe + S FeS;
Hg + S HgS ;
2Mg + O2 2MgO.
Kim loi l cht kh( b oxi ha).
Phi kim l cht oxi ha( b kh)
- Tc dng vi dung dch axit:
+ Vi dd HCl,H2SO4 long . Tr cc kim loi ng sau hidro trong dy in ha :
Fe + 2HCl FeCl2 + H2
2011 2012 TRNG THPT NAM SCH II

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+ Vi dd HNO3 ,H2SO4 c
3Cu +8HNO3 long 3Cu(NO3)2 + 2NO + 4H2O
Cu + 2H2SO4 c CuSO4 + SO2 + 2H2O
Kim loi l cht kh (b oxi ha).
Axit l cht oxi ha( b kh)
* Ch : HNO3 ,H2SO4 c ngui khng tc dng vi Al, Fe, Cr
- Tc dng vi nc:
Ch c cc kim loi nhm IAv IIA(tr Be,Mg) kh H2O nhit thng, cc kl cn li kh c t0cao hoc khng
kh c.
2Na + 2H2O 2NaOH + H2
Kim loi l cht kh( b oxi ha)
Nc l cht oxi ha( b kh)
- Tc dng vi dung dch mui:
Fe + CuSO4 FeSO4 + Cu
Fe cht kh( b oxi ha)
Cu2+ cht oxh( b kh)
4. DY IN HO KIM LOI
- Cp oxi ha kh ca kim loi
VD: Ag+ + 1e Ag
Cu+ + 2e Cu
Fe2+ + 2e Fe
+ Nguyn t kim loi ng vai tr cht kh, cc ion kim loi ng vai tr cht oxi ha
+ Dng oxi ha v dng kh ca cng mt nguyn t kim loi to nn cp oxi ha - kh ca kim loi
VD: Ag+ /Ag , Cu2+/Cu, Fe2+/Fe, . . .
- Dy in ha ca kim loi:
Li+ K+ Ba2+ Ca2+ Na+ Mg2+Al3+ Mn2+Zn2+ Cr2+ Fe2+ Ni2+ Sn2+ Pb2+ H+ Cu2+ Fe3+ Hg2+ Ag+ Pt2+ Au3+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb H Cu Fe2+ Hg Ag Pt Au
Tnh oxi ha ca ion kim loi tng, tnh kh ca kim loi gim
- So snh tnh cht cp oxi ha kh
So snh tnh cht cc cp oxi ha kh: Ag+ /Ag v Cu2+/Cu, Zn2+/Zn. Nhn thy .
Tnh oxh cc ion: Ag+> Cu2+> Zn2+
Tnh kh: Zn>Cu>Ag
- ngha dy in ha
Cho php d on chiu p gia 2 cp oxh kh theo qui tc

Zn2+

Cu2+

Hg22+ Ag+

Zn

Cu => Zn + Cu2+ Zn2++ Cu

Hg

Ag => Hg + 2Ag+ Hg2++ 2Ag

cht oxh mnh +cht kh mnh cht oxh yu + cht kh yu .

VD: phn ng gia 2 cp Cu2+/Cu v Fe2+/Fe l:
Fe + Cu2+ Fe2++ Cu
5. Hp kim:
- KHI NIM: H p kim l vt liu kim loi c bn v mt s kim loi hoc phi kim khc .
VD: Thp, gang, inox, hp kim uyra, . ..
- TNH CHT: Hp kim c nhiu tnh cht ha hc tng t tnh cht ca cc n cht tham gia to thnh hp kim,
nhng tnh cht vt l v tnh cht c hc ca hp kim li khc nhiu tnh cht cc n cht.
+ Hp kim c nhit nng chy v nhit si thp hn.
+ Hp kim cng v gin hn.
6. S N MN KIM LOI
- S n mn kim loi
Khi nim chung: n mn kim loi l s ph hy kim loi hay hp kim do tc dng ca cc cht trong mi trng.
Bn cht ca s n mn kim loi l s oxi ha kim loi thnh ion kim loi: M Mn+ +ne
Phn loi: n mn ha hc v n mn in ha.
- n mn ha hc: n mn ha hc l qu trnh oxi ho kh, trong cc e ca kim loi c chuyn trc tip n
cc cht trong mi trng.
c im :
+ Khng pht sinh dng in.
+ Nhit cng cao th tc n mn cng nhanh.
-. n mn in ha: n mn in ha l qu trnh oxi ha kh, trong kim loi b n mn do tc dng ca dung
dch cht in li v to nn dng in.
+ C ch
* Kim loi hot ng mnh hn ng vai tr l cc m (anot). y xy ra qu trnh oxi ha: M Mn+ + ne
2011 2012 TRNG THPT NAM SCH II

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* Kim loi hot ng yu hn hoc phi kim ng vai tr l cc dng (catot). y xy ra qu trnh kh:
2H+ + 2e H2 hoc O2 + 2H2O +4e 4OH* Dng in chuyn di t cc m sang dng.
+ iu kin c n mn in ha:
* Cc in cc phi khc nhau: cp kim loi khc nhau.
* Cc in cc phi tip xc trc tip hoc gin tip vi nhau.
* Cc in cc phi cng tip xc vi dd cht in li.
- Cch chng n mn kim loi:
Nguyn tc chung: Hn ch hay trit tiu nh hng ca mi trng i vi kim loi.
Phng php:
* Phng php bo v b mt: Dng cc cht bn vi mi trng ph ln b mt kim loi
* Dng phng php in ho
Nguyn tc: Gn kim loi c tnh kh mnh vi kim loi cn c bo v (c tnh kh yu hn).
7. iu ch kim loi:
- NGUYN TC: Kh ion kim loi thnh nguyn t: Mn+ + ne M
- PHNG PHP:
+ Phng php nhit luyn: Dng cc cht kh nh CO, H2, C, NH3, Al, kh cc ion kim loi trong oxit
nhit cao.
0

t
VD: Fe2O3+3CO
2Fe+ 3CO2

=> Phng php ny dng iu ch cc kim loi c hot ng trung bnh ( sau Al )
+ Phng php thy luyn: Dng kim loi t do c tnh kh mnh hn kh ion kim loi trong dung dch mui.
VD: Fe + CuSO4 FeSO4 + Cu
=> Phng php ny dng iu ch cc kim loi hot ng yu (sau H )
+ Phng php in phn:
* in phn hp cht nng chy: Dng dng in kh ion kim loi trong hp cht nng chy (oxit, hidroxit,
mui halogen)

dpnc

dpnc

4Na + O

Vd1: 2Al2O3
4Al + 3O2
Vd2: 4NaOH
=> Phng php ny dng iu ch kim loi c hot ng mnh (t u n Al)
* in phn dung dch: Dng dng in kh ion trong dung dch mui.

+ 2H2O

dpdd
dpdd
Vd1: CuCl2
Cu + Cl2
Vd2: CuSO4 + H2O
Cu + 1/2O2+ H2SO4
=> Phng php ny dng iu ch cc kim loi trung bnh, yu (sau Al).
* Tnh lng cht thu c cc in cc: m=AIt/n.F
m: Khi lng cht thot ra in cc (gam)
A: Khi lng mol ca cht
n: S electron trao i.
V d: Cu2+ + 2e Cu th n = 2 v A = 64
2OH- O2 + 2H+ + 4e th n = 4 v A = 32.t: Thi gian
in phn (giy, s)
I: Cng dng in (ampe, A)
F: S Faraday (F = 96500).
VD: pdd AgNO3 vi cng dng in l 1,5A, thi gian 30 pht. Khi lng Ag thu c l:
A. 6,00g
B. 3,02g
C. 1,50g
D. 0,05g
..............................................................................................................................................................................................
C. CU HI VN DNG
Cu 1 S electron lp ngoi cng ca cc nguyn t kim loi thuc nhm IIA l ?
A. 3.
B. 2.
C. 4.
D. 1.
Cu 2 S electron lp ngoi cng ca cc nguyn t kim loi thuc nhm IA l ?
A. 3.
B. 2.
C. 4.
D. 1.
Cu 3 Cng thc chung ca oxit kim loi thuc nhm IA l ?
A. R2O3.
B. RO2.
C. R2O.
D. RO.
Cu 4 Cng thc chung ca oxit kim loi thuc nhm IIA l ?
A. R2O3.
B. RO2.
C. R2O.
D. RO.
Cu 5 Cu hnh electron ca nguyn t Na (Z =11) l ?
A. 1s22s2 2p6 3s2.
B. 1s22s2 2p6.
C. 1s22s22p63s1.
D. 1s22s22p6 3s23p1.

2011 2012 TRNG THPT NAM SCH II

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Cu 6 Hai kim loi u thuc nhm IIA trong bng tun hon l ?
A. Sr, K.
B. Na, Ba.
C. Be, Al.
D. Ca, Ba.
Cu 7 Hai kim loi u thuc nhm IA trong bng tun hon l ?
A. Sr, K.
B. Na, K.
C. Be, Al.
D. Ca, Ba.
Cu 8 Nguyn t Fe c Z = 26, cu hnh electrron ca Fe l ?
A. [Ar ] 3d6 4s2.
B. [Ar ] 4s13d7.
C. [Ar ] 3d7 4s1.
D. [Ar ] 4s23d6.
..............................................................................................................................................................................................
Cu 9 Nguyn t Cu c Z = 29, cu hnh electrron ca Cu l ?
A. [Ar ] 3d9 4s2.
B. [Ar ] 4s23d9.
C. [Ar ] 3d10 4s1.
D. [Ar ] 4s13d10.
..............................................................................................................................................................................................
Cu 10 Nguyn t Cr c Z = 24, cu hnh electrron ca Cr l ?
A. [Ar ] 3d4 4s2.
B. [Ar ] 4s23d4.
C. [Ar ] 3d5 4s1.
D. [Ar ] 4s13d5.
..............................................................................................................................................................................................
Cu 11 Nguyn t Al c Z = 13, cu hnh electrron ca Al l ?
A. 1s22s22p63s23p1.
B. 1s22s22p63s3.
C. 1s22s22p63s23p3.
D. 1s22s22p63s23p2.
Cu 12 Cation M+ c cu hnh electron lp ngoi cng 2s22p6 l ?
A. Rb+.
B. Na+.
C. Li+.
D. K+.
TNH CHT CA KIM LOI DY IN HA CA KIM LOI
Cu 13 Kim loi no sau y c tnh dn in tt nht trong tt c cc kim loi ?
A. Vng.
B. Bc.
C. ng.
D. Nhm.
Cu 14 Kim loi no sau y do nht trong tt c cc kim loi ?
A. Vng.
B. Bc.
C. ng.
D. Nhm.
Cu 15 Kim loi no sau y c cng ln nht trong tt c cc kim loi ?
A. Vonfam.
B. Crom
C. St
D. ng
Cu 16 Kim loi no sau y l kim loi mm nht trong tt c cc kim loi ?
A. Liti.
B. Xesi.
C. Natri.
D. Kali.
Cu 17 Kim loi no sau y c nhit nng chy cao nht trong tt c cc kim loi ?
A. Vonfam.
B. St.
C. ng.
D. Km.
Cu 18 Kim loi no sau y nh nht ( c khi lng ring nh nht ) trong tt c cc kim loi ?
A. Natri
B. Liti
C. Kali
D. Rubidi
Cu 19 Tnh cht ha hc c trng ca kim loi l ?
A. tnh baz.
B. tnh oxi ha.
C. tnh axit.
D. tnh kh.
Cu 20 Hai kim loi u phn ng vi dung dch Cu(NO3)2 gii phng kim loi Cu l ?
A. Al v Fe.
B. Fe v Au.
C. Al v Ag.
D. Fe v Ag.
..............................................................................................................................................................................................
Cu 21 Cp cht khng xy ra phn ng l ?
A. Fe + Cu(NO3)2.
B. Cu + AgNO3.
C. Zn + Fe(NO3)2.
D. Ag + Cu(NO3)2.
..............................................................................................................................................................................................
Cu 22 Hai kim loi Al v Cu u phn ng c vi dung dch ?
A. NaCl long.
B. H2SO4 long.
C. HNO3 long.
D. NaOH long
Cu 23 Kim loi Cu phn ng c vi dung dch ?
A. FeSO4.
B. AgNO3.
C. KNO3.
D. HCl.
Cu 24 Dung dch FeSO4 v dung dch CuSO4 u tc dng c vi ?
A. Ag.
B. Fe.
C. Cu.
D. Zn.
Cu 25 ho tan hon ton hn hp gm hai kim loi Cu v Zn, ta c th dng mt lng d dung dch ?
A. HCl.
B. AlCl3.
C. AgNO3.
D. CuSO4.
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

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Cu 26 Hai dung dch u tc dng c vi Fe l ?
A. CuSO4 v HCl.
B. CuSO4 v ZnCl2.
C. HCl v CaCl2.
D. MgCl2 v FeCl3.
..............................................................................................................................................................................................
Cu 27 Cho cc kim loi: Ni, Fe, Cu, Zn; s kim loi tc dng vi dung dch Pb(NO3)2 l ?
A. 1.
B. 2.
C. 3.
D. 4.
..............................................................................................................................................................................................
Cu 28 Dung dch mui no sau y tc dng c vi c Ni v Pb ?
A. Pb(NO3)2.
B. Cu(NO3)2.
C. Fe(NO3)2.
D. Ni(NO3)2.
Cu 29 Tt c cc kim loi Fe, Zn, Cu, Ag u tc dng c vi dung dch ?
A. HCl.
B. H2SO4 long.
C. HNO3 long.
D. KOH.
Cu 30 Cho cc kim loi: Na, Mg, Fe, Al; kim loi c tnh kh mnh nht l ?
A. Al.
B. Na.
C. Mg.
D. Fe.
Cu 31 Cho phn ng: aAl + bHNO3
cAl(NO3)3 + dNO + eH2O.
H s a, b, c, d, e l cc s nguyn, ti gin. Tng (a + b) bng bao nhiu ?
A. 5.
B. 4.
C. 7.
D. 6.
Cu 32 Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch
AgNO3 ?
A. Zn, Cu, Mg
B. Al, Fe, CuO
C. Fe, Ni, Sn
D. Hg, Na, Ca
Cu 33 Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra ?
A. s kh Fe2+ v s oxi ha Cu.
B. s kh Fe2+ v s kh Cu2+.
C. s oxi ha Fe v s oxi ha Cu.
D. s oxi ha Fe v s kh Cu2+.
Cu 34 Cp cht khng xy ra phn ng ho hc l ?
A. Cu + dung dch FeCl3.
B. Fe + dung dch HCl.
C. Fe + dung dch FeCl3.
D. Cu + dung dch FeCl2.
Cu 35 Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c mui Y.
Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l ?
A. Mg
B. Al
C. Zn
D. Fe
..............................................................................................................................................................................................
Cu 36 kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi ?
A. K
B. Na
C. Ba
D. Fe
3+
2+
Cu 37 kh ion Fe trong dung dch thnh ion Fe c th dng mt lng d ?
A. Kim loi Mg
B. Kim loi Ba
C. Kim loi Cu
D. Kim loi Ag
2+
Cu 38 Th t mt s cp oxi ha - kh trong dy in ha nh sau : Fe /Fe; Cu2+/Cu; Fe3+/Fe2+. Cp cht khng
phn ng vi nhau l ?
A. Cu v dung dch FeCl3
B. Fe v dung dch CuCl2
C. Fe v dung dch FeCl3
D. dung dch FeCl2 v dung dch CuCl2
..............................................................................................................................................................................................
Cu 39 X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch
Fe(NO3)3. Hai kim loi X, Y ln lt l ( bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag )
A. Fe, Cu.
B. Cu, Fe.
C. Ag, Mg.
D. Mg, Ag.
..............................................................................................................................................................................................
Cu 40 Dy gm cc kim loi c xp theo th t tnh kh tng dn t tri sang phi l ?
A. Mg, Fe, Al.
B. Fe, Mg, Al.
C. Fe, Al, Mg.
D. Al, Mg, Fe.
Cu 41 Dy gm cc kim loi u phn ng vi nc nhit thng to ra dung dch c mi trng kim l ?
A. Na, Ba, K.
B. Be, Na, Ca.
C. Na, Fe, K.
D. Na, Cr, K.
Cu 42 Trong dung dch CuSO4, ion Cu2+ khng b kh bi kim loi ?
A. Fe.
B. Ag.
C. Mg.
D. Zn.
Cu 43 Cho dy cc kim loi: Fe, Na, K, Ca. S kim loi trong dy tc dng c vi nc nhit thng l ?
A. 4.
B. 1.
C. 3.
D. 2.
2011 2012 TRNG THPT NAM SCH II

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Cu 44 Kim loi phn ng c vi dung dch H2SO4 long l ?
A. Ag.
B. Au.
C. Cu.
D. Al.
Cu 45 Cho dy kim loi: Na, Cu, Fe, Ag, Zn. S kim loi trong dy phn ng c vi dung dch HCl l ?
A. 5.
B. 2.
C. 3.
D. 4.
Cu 46 ng (Cu) tc dng c vi dung dch ?
A. H2SO4 c, nng.
B. H2SO4 long.
C. FeSO4.
D. HCl.
Cu 47 Cho dy cc kim loi: Na, Cu, Fe, Zn. S kim loi trong dy phn ng c vi dung dch HCl l ?
A. 3.
B. 1.
C. 4.
D. 2.
Cu 48 Cho dy cc kim loi: K, Mg, Na, Al. Kim loi c tnh kh mnh nht trong dy l ?
A. Na.
B. Mg.
C. Al.
D. K.
S N MN KIM LOI
Cu 49 Mt s ho cht c trn ngn t c khung bng kim loi. Sau 1 thi gian, ngi ta thy khung kim loi b
g. Ho cht no di y c kh nng gy ra hin tng trn ?
A. Ancol etylic.
B. Dy nhm.
C. Du ho.
D. Axit clohydric.
2+
Cu 50 Bit rng ion Pb trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau
bng dy dn in vo mt dung dch cht in li th ?
A. c Pb v Sn u b n mn in ho.
B. c Pb v Sn u khng b n mn in ho.
C. ch c Pb b n mn in ho.
D. ch c Sn b n mn in ho.
Cu 51 Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau : Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi
nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hy trc l ?
A. 4
B. 1
C. 2
D. 3
Cu 52 Khi lu trong khng kh m mt vt bng st ty (st trng thic) b sy st su ti lp st bn trong, s xy
ra qu trnh ?
A. Sn b n mn in ha.
B. Fe b n mn in ha.
C. Fe b n mn ha hc.
D. Sn b n mn ha hc.
Cu 53 bo v v tu bin lm bng thp ngi ta thng gn vo v tu (phn ngm di nc) nhng tm kim
loi ?
A. Cu.
B. Zn.
C. Sn.
D. Pb.
Cu 54 C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt
thanh Fe nguyn cht. S trng hp xut hin n mn in ho l ?
A. 0.
B. 1.
C. 2.
D. 3.
Cu 55 Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th
cc hp kim m trong Fe u b n mn trc l ?
A. I, II v III.
B. I, II v IV.
C. I, III v IV.
D. II, III v IV.
IU CH KIM LOI
Cu 56 Khi iu ch kim loi, cc ion kim loi ng vai tr l cht ?
A. b kh.
B. nhn proton.
C. b oxi ho.
D. cho proton.
Cu 57 loi b kim loi Cu ra khi hn hp bt gm Ag v Cu, ngi ta ngm hn hp kim loi trn vo lng d
dung dch ?
A. AgNO3.
B. HNO3.
C. Cu(NO3)2.
D. Fe(NO3)2.
Cu 58 Cht khng kh c st oxit ( nhit cao) l ?
A. Cu.
B. Al.
C. CO.
D. H2.
Cu 59 Hai kim loi c th iu ch bng phng php nhit luyn l ?
A. Ca v Fe.
B. Mg v Zn.
C. Na v Cu.
D. Fe v Cu.
Cu 60 Phng php thch hp iu ch kim loi Ca t CaCl2 l ?
A. nhit phn CaCl2.
B. in phn CaCl2 nng chy.
2+
C. dng Na kh Ca trong dung dch CaCl2.
D. in phn dung dch CaCl2.
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 61 Oxit d b H2 kh nhit cao to thnh kim loi l ?
A. Na2O.
B. CaO.
C. CuO.
D. K2O.
Cu 62 Phng trnh ho hc no sau y th hin cch iu ch Cu theo phng php thu luyn ?
A. Zn + CuSO4 Cu + ZnSO4
B. H2 + CuO Cu + H2O
C. CuCl2 Cu + Cl2
D. 2CuSO4 + 2H2O 2Cu + 2H2SO4 + O2
Cu 63 Phng trnh no sau y biu din cch iu ch Ag t AgNO3 theo phng php thu luyn ?
A. 2AgNO3 + Zn 2Ag + Zn(NO3)2
B. 2AgNO3 2Ag + 2NO2 + O2
C. 4AgNO3 + 2H2O 4Ag + 4HNO3 + O2
D. Ag2O + CO 2Ag + CO2.
Cu 64 Trong phng php thu luyn, iu ch Cu t CuSO4 c th dng kim loi no lm cht kh ?
A. K.
B. Ca.
C. Zn.
D. Ag.
Cu 65 Cho kh CO d i qua hn hp gm CuO, Al2O3, MgO (nung nng). Khi phn ng xy ra hon ton thu c
cht rn gm ?
A. Cu, Al, Mg.
B. Cu, Al, MgO.
C. Cu, Al2O3, Mg.
D. Cu, Al2O3, MgO.
Cu 66 Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn
hp rn cn li l ?
A. Cu, FeO, ZnO, MgO.
B. Cu, Fe, Zn, Mg.
C. Cu, Fe, Zn, MgO. D. Cu, Fe, ZnO, MgO.
Cu 67 Hai kim loi c th c iu ch bng phng php in phn dung dch l
A. Al v Mg.
B. Na v Fe.
C. Cu v Ag.
D. Mg v Zn.
Cu 68 Cp cht khng xy ra phn ng ho hc l ?
A. Cu + dung dch FeCl3.
B. Fe + dung dch HCl.
C. Fe + dung dch FeCl3.
D. Cu + dung dch FeCl2.
Cu 69 Dy kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l ?
A. Ba, Ag, Au.
B. Fe, Cu, Ag.
C. Al, Fe, Cr.
D. Mg, Zn, Cu.
Cu 70 Hai kim loi c th c iu ch bng phng php in phn dung dch l ?
A. Al v Mg.
B. Na v Fe.
C. Cu v Ag.
D. Mg v Zn.
Cu 71 Khi in phn NaCl nng chy ( in cc tr ), ti catt xy ra ?
A. s kh ion Cl-.
B. s oxi ho ion Cl-.
C. s oxi ho ion Na+. D. s kh ion Na+.
Cu 72 Oxit d b H2 kh nhit cao to thnh kim loi l ?
A. Na2O.
B. CaO.
C. CuO.
D. K2O.
Cu 73 Trong cng nghip, kim loi c iu ch bng phng php in phn hp cht nng chy ca kim loi :
A. Na.
B. Ag.
C. Fe.
D. Cu.
Cu 74 Phng php thch hp iu ch kim loi Mg t MgCl2 l ?
A. in phn dung dch MgCl2.
B. in phn MgCl2 nng chy.
C. nhit phn MgCl2.
D. dng K kh Mg2+ trong dung dch MgCl2.
Cu 75 Cho 1 lung kh H2 d ln lt i qua cc ng mc ni tip ng cc oxit nung nng nh hnh v

1
CaO

2
CuO

3
Al2O3

4
Fe2O3

5
Na2O

ng no c phn ng xy ra:
A. ng 1, 2, 3.
B. ng 2, 3, 4.
C. ng 2, 4, 5.
CC DNG BI TP PHN I CNG KIM LOI

D. ng 2, 4.

DNG 1 : KIM LOI TC DNG VI PHI KIM

Cu 1 Bao nhiu gam clo tc dng va kim loi nhm to ra 26,7 gam AlCl3 ?
A. 21,3 gam
B. 12,3 gam.
C. 13,2 gam.
D. 23,1 gam.
..............................................................................................................................................................................................
Cu 2 t chy bt Al trong bnh kh Clo d, sau khi phn ng xy ra hon ton khi lng cht rn trong bnh tng
4,26 gam. Khi lng Al phn ng l ?
A. 1,08 gam.
B. 2,16 gam.
C. 1,62 gam.
D. 3,24 gam.
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 3 Bao nhiu gam Cu tc dng va vi clo to ra 27 gam CuCl2 ?
A. 12,4 gam
B. 12,8 gam.
C. 6,4 gam.
D. 25,6 gam.
..............................................................................................................................................................................................
Cu 4 Cho m gam 3 kim loi Fe, Al, Cu vo mt bnh kn cha 0,9 mol oxi. Nung nng bnh 1 thi gian cho n khi
s mol O2 trong bnh ch cn 0,865 mol v cht rn trong bnh c khi lng 2,12 gam. Gi tr m dng l ?
A. 1,2 gam.
B. 0,2 gam.
C. 0,1 gam.
D. 1,0 gam.
..............................................................................................................................................................................................
Cu 5 t 1 lng nhm(Al) trong 6,72 lt O2. Cht rn thu c sau phn ng cho ho tan hon ton vo dung dch
HCl thy bay ra 6,72 lt H2 (cc th tch kh o kc). Khi lng nhm dng l ?
A. 8,1gam.
B. 16,2gam.
C. 18,4gam.
D. 24,3gam.
..............................................................................................................................................................................................
DNG 2 : KIM LOI TC DNG VI DUNG DCH AXIT
Cu 1 Cho 10 gam hn hp cc kim loi Mg v Cu tc dng ht vi dung dch HCl long d thu c 3,733 lit
H2(kc). Thnh phn % ca Mg trong hn hp l ?
A. 50%.
B. 35%.
C. 20%.
D. 40%.
..............................................................................................................................................................................................
Cu 2 Mt hn hp gm 13 gam km v 5,6 gam st tc dng vi dung dch axit sunfuric long d. Th tch kh hidro
(ktc) c gii phng sau phn ng l ?
A. 2,24 lit.
B. 4,48 lit.
C. 6,72 lit.
D. 67,2 lit.
..............................................................................................................................................................................................
Cu 3 Cho 4,05 gam Al tan ht trong dung dch HNO3 thu V lt N2O (kc) duy nht. Gi tr V l ?
A. 2,52 lt.
B. 3,36 lt.
C. 4,48 lt.
D. 1,26 lt.
..............................................................................................................................................................................................
Cu 4 Hn hp X gm Fe v Cu, trong Cu chim 43,24% khi lng. Cho 14,8 gam X tc dng ht vi dung dch
HCl thy c V lt kh (ktc) bay ra. Gi tr ca V l ?
A. 1,12 lt.
B. 3,36 lt.
C. 2,24 lt.
D. 4,48 lt.
..............................................................................................................................................................................................
Cu 5 Ho tan hon ton 1,5 gam hn hp bt Al v Mg vo dung dch HCl thu c 1,68 lt H2 (kc). Phn % khi
lng ca Al trong hn hp l ?
A. 60%.
B. 40%.
C. 30%.
D. 80%.
..............................................................................................................................................................................................
Cu 6 Ho tan m gam Fe trong dung dch HCl d, sau khi phn ng kt thc thu c 4,48 lt kh H2 ( ktc). Gi tr
ca m l ? ( Cho Fe = 56, H = 1, Cl = 35,5 )
A. 2,8.
B. 1,4.
C. 5,6.
D. 11,2.
..............................................................................................................................................................................................
Cu 7 Ha tan 6,5 gam Zn trong dd axit HCl d, sau phn ng c cn dung dch th s gam mui khan thu c l
A. 20,7 gam.
B. 13,6 gam.
C. 14,96 gam.
D. 27,2 gam.
..............................................................................................................................................................................................
Cu 8 Ho tan 6,4 gam Cu bng axit H2SO4 c, nng (d), sinh ra V lt kh SO2 (sn phm kh duy nht, ktc). Gi
tr ca V l ?
A. 4,48.
B. 6,72.
C. 3,36.
D. 2,24.
..............................................................................................................................................................................................
Cu 9 Ho tan m gam Al bng dung dch HCl (d), thu c 3,36 lt H2 ( ktc). Gi tr ca m l ?
A. 4,05.
B. 2,70.
C. 5,40.
D. 1,35.
..............................................................................................................................................................................................
Cu 10 Ho tan 5,6 gam Fe bng dung dch HNO3 long (d), sinh ra V lt kh NO (sn phm kh duy nht, ktc).
Gi tr ca V l ?
A. 6,72.
B. 4,48.
C. 2,24.
D. 3,36.
..............................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 11 Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long (d). Sau phn ng thu c 2,24 lt
kh hiro ( ktc), dung dch X v m gam cht rn khng tan. Gi tr ca m l ?
A. 6,4 gam.
B. 3,4 gam.
C. 5,6 gam.
D. 4,4 gam.
..............................................................................................................................................................................................
Cu 12 Cho 20 gam hn hp bt Mg v Fe tc dng ht vi dung dch HCl thy c 1 gam kh H2 bay ra. Lng mui
clorua to ra trong dung dch l bao nhiu gam ?
A. 40,5g.
B. 45,5g.
C. 55,5g.
D. 60,5g.
..............................................................................................................................................................................................
Cu 13 Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh (
ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72
lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l ?
A. 15,6.
B. 10,5.
C. 11,5.
D. 12,3.
..............................................................................................................................................................................
Cu 14 Trong hp kim Al Mg, c c 9 mol Al th c 1 mol Mg. Thnh phn phn % khi lng ca hp kim l ?
A. 80% Al v 20% Mg.
B. 81% Al v 19% Mg.
C. 91% Al v 9% Mg. D. 83% Al v 17% Mg.
..............................................................................................................................................................................................
Cu 15 Ho tan 6 gam hp kim Cu, Fe v Al trong axit HCl d thy thot ra 3,024 lt kh (kc) v 1,86 gam cht rn
khng tan. Thnh phn phn % ca hp kim l ?
A. 40% Fe, 28% Al 32% Cu.
B. 41% Fe, 29% Al, 30% Cu.
C. 42% Fe, 27% Al, 31% Cu.
D. 43% Fe, 26% Al, 31% Cu.
..............................................................................................................................................................................................
Cu 16 Ho tan hon ton 7,8 gam hn hp gm Mg, Al trong dung dch HCl d thy to ra 8,96 lt kh H2 (kc). C
cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l ?
A. 18,1 gam.
B. 36,2 gam.
C. 54,3 gam.
D. 63,2 gam.
..............................................................................................................................................................................................
Cu 17 Cho 11,9 gam hn hp gm Zn, Al tan hon ton trong dung dch H2SO4 long d thy c 8,96 lit kh (kc)
thot ra. Khi lng hn hp mui sunfat khan thu c l ?
A. 44,9 gam.
B. 74,1 gam.
C. 50,3 gam.
D. 24,7 gam.
..............................................................................................................................................................................................
Cu 18 Cho m gam Fe vo dung dch HNO3 ly d ta thu c 8,96 lit(kc) hn hp kh X gm 2 kh NO v NO2 c
t khi hi hn hp X so vi oxi bng 1,3125. Gi tr ca m l ?
A. 0,56 gam.
B. 1,12 gam.
C. 11,2 gam.
D. 5,6 gam.
..............................................................................................................................................................................................
Cu 19 Cho 60 gam hn hp Cu v CuO tan ht trong dung dch HNO3 long d thu c 13,44 lit kh NO (kc, sn
phm kh duy nht). Phn % v khi lng ca Cu trong hn hp l ?
A. 69%.
B. 96%.
C. 44%
D. 56%.
..............................................................................................................................................................................................
Cu 20 Cho 2,8 gam hn hp bt kim loi bc v ng tc dng vi dung dch HNO3 c, d th thu c 0,896 lt
kh NO2 duy nht ( ktc). Thnh phn phn trm ca bc v ng trong hn hp ln lt l ?
A. 73% ; 27%.
B. 77,14% ; 22,86%
C. 50%; 50%.
D. 44% ; 56%
..............................................................................................................................................................................................
Cu 21 Cho 8,3 gam hn hp Al v Fe tc dng vi dung dch HNO3 long d th thu c 45,5 gam mui nitrat
khan. Th tch kh NO (ktc, sn phm kh duy nht) thot ra l ?
A. 4,48 lt.
B. 6,72 lt.
C. 2,24 lt.
D. 3,36 lt.
..............................................................................................................................................................................................
Cu 22 Cho 1,86 gam hn hp Al v Mg tc dng vi dung dch HNO3 long d th thu c 560 ml lt kh N2O
(ktc, sn phm kh duy nht) bay ra. Khi lng mui nitrat to ra trong dung dch l ?
A. 40,5 gam.
B. 14,62 gam.
C. 24,16 gam.
D. 14,26 gam.
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 23 Cho 5 gam hn hp bt Cu v Al vo dung dch HCl d thu 3,36 lt H2 ktc. Phn trm Al theo khi lng
hn hp u l ?
A. 27%.
B. 51%.
C. 64%.
D. 54%.
..............................................................................................................................................................................................
Cu 24 Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh
NO2 (sn phm kh duy nht, ktc). Phn trm v khi lng ca Cu trong hn hp X l ?
A. 21,95%.
B. 78,05%.
C. 68,05%.
D. 29,15%.
..............................................................................................................................................................................................
Cu 25 Cho a gam bt Al tc dng va vi dung dch HNO3 long thu c dung dch A ch cha mt mui duy
nht v 0,1792 lt (ktc) hn hp kh NO, N2 c t khi hi so H2 l 14,25. Tnh a ?
A. 0,459 gam.
B. 0,594 gam.
C. 5,94 gam.
D. 0,954 gam.
..............................................................................................................................................................................................
Cu 26 Ho tan hon ton 7,8 gam hn hp gm Mg, Al trong dung dch HCl d. Sau phn ng thy khi lng dung
dch tng thm 7 gam. Khi lng ca Al c trong hn hp ban u l ?
A. 2,7 gam.
B. 5,4 gam.
C. 4,5 gam.
D. 2,4 gam.
..............................................................................................................................................................................................
Cu 27 Cho hn hp A gm Cu v Mg vo dd HCl d thu c 5,6 lt kh (kc) khng mu v mt cht rn khng tan
B. Dng dd H2SO4 c, nng ho tan cht rn B thu c 2,24 lt kh SO2 (kc). Khi lng hn hp A ban u ?
A. 6,4 gam.
B. 12,4 gam.
C. 6,0 gam.
D. 8,0 gam.
..............................................................................................................................................................................................
Cu 28 Ho tan hon ton 1,5 gam hn hp bt Al v Mg vo dung dch HCl thu c 1,68 lt H2 (kc). Phn % khi
lng ca Al trong hn hp l
A. 60%.
B. 40%.
C. 30%.
D. 80%.
..............................................................................................................................................................................................
DNG 3 : XC NH CNG THC
Cu 1 Ho tan 2,52 gam mt kim loi bng dung dch H2SO4 long d, c cn dung dch thu c 6,84 gam mui
khan. Kim loi l ?
A. Mg.
B. Al.
C. Zn.
D. Fe.
..............................................................................................................................................................................................
Cu 2 Ho tan ht m gam kim loi M bng dung dch H2SO4 long, ri c cn dung dch sau phn ng thu c 5m
gam mui khan. Kim loi M l ?
A. Al.
B. Mg.
C. Zn.
D. Fe.
..............................................................................................................................................................................................
Cu 3 Ngm mt l kim loi c khi lng 50 gam trong dung dch HCl. Sau khi thu c 336 ml kh H2 (ktc) th
khi lng l kim loi gim 1,68%. Kim loi l ?
A. Zn.
B. Fe.
C. Ni.
D. Al.
..............................................................................................................................................................................................
Cu 4 Nhit phn hon ton 3,5 gam mt mui cacbonat kim loi ho tr 2 thu c 1,96 gam cht rn. Mui cacbonat
ca kim loi dng l ?
A. FeCO3.
B. BaCO3.
C. MgCO3.
D. CaCO3.
..............................................................................................................................................................................................
Cu 5 Ho tan hon ton 0,575 gam mt kim loi km vo nc. trung ho dung dch thu c cn 25 gam dung
dch HCl 3,65%. Kim loi ho tan l ?
A. Li.
B. K.
C. Na.
D. Rb.
..............................................................................................................................................................................................
Cu 6 Cho 9,1 gam hn hp hai mui cacbonat trung ho ca 2 kim loi kim 2 chu k lin tip tan hon ton trong
dung dch HCl d thu c 2,24 lt CO2(ktc). Hai kim loi l ?
A. K v Cs.
B. Na v K.
C. Li v Na.
D. Rb v Cs.
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 7 Ho tan 1,3 gam mt kim loi M trong 100 ml dung dch H2SO4 0,3M. trung ho lng axit d cn 200 ml
dung dch NaOH 0,1M. Xc nh kim loi M ?
A. Al.
B. Fe.
C. Zn.
D. Mg.
..............................................................................................................................................................................................
Cu 8 Lng kh clo sinh ra khi cho dung dch HCl c d tc dng vi 6,96 gam MnO2 oxi ho kim loi M (thuc
nhm IIA), to ra 7,6 gam mui khan. Kim loi M l ?
A. Ba.
B. Mg.
C. Ca.
D. Be.
..............................................................................................................................................................................................
Cu 9 Ho tan hon ton 2 gam kim loi thuc nhm IIA vo dung dch HCl v sau c cn dung dch ngi ta thu
c 5,55 gam mui khan. Kim loi nhm IIA l ?
A. Be.
B. Ba.
C. Ca.
D. Mg.
..............................................................................................................................................................................................
Cu 10 Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA tc dng ht vi dung dch HCl
(d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l ? ( Mg= 24, Ca= 40, Sr= 87, Ba = 137 )
A. Be v Mg.
B. Mg v Ca.
C. Sr v Ba.
D. Ca v Sr.
..............................................................................................................................................................................................
Cu 11 Khi in phn mui clorua kim loi nng chy, ngi ta thu c 0,896 lt kh (ktc) anot v 3,12 gam kim
loi catot. Cng thc mui clorua in phn l ?
A. NaCl.
B. CaCl2.
C. KCl.
D. MgCl2.
..............................................................................................................................................................................................
Cu 12 Cho 19,2 gam kim loi (M) tan hon ton trong dung dch HNO3 long th thu c 4,48 lt kh NO (ktc, sn
phm kh duy nht). Kim loi (M) l ?
A. Cu.
B. Zn.
C. Fe.
D. Mg.
..............................................................................................................................................................................................
DNG 4 : KIM LOI TC DNG VI DUNG DCH MUI
Cu 1 Ho tan 58 gam CuSO4. 5H2O vo nc c 500ml dung dch CuSO4. Cho dn dn mt st vo 50 ml dung
dch trn, khuy nh cho ti khi dung dch ht mu xanh th lng mt st dng l ?
A. 0,65g.
B. 1,2992g.
C. 1,36g.
D. 12,99g.
..............................................................................................................................................................................................
Cu 2 Ngm mt inh st sch trong 200 ml dung dch CuSO4 sau khi phn ng kt thc, ly inh st ra khi dung
dch ra nh lm kh nhn thy khi lng inh st tng thm 0,8 gam. Nng mol/lt ca dd CuSO4 dng l ?
A. 0,25M.
B. 0,4M.
C. 0,3M.
D. 0,5M.
..............................................................................................................................................................................................
Cu 3 Ngm mt l km vo dung dch c ho tan 8,32 gam CdSO4. Phn ng xong ly l km ra khi dung dch, ra
nh, lm kh th thy khi lng l km tng thm 2,35% so vi khi lng l km trc phn ng. Khi lng l
km trc phn ng l ?
A. 80gam
B. 60gam
C. 20gam
D. 40gam
..............................................................................................................................................................................................
Cu 4 Nhng mt inh st c khi lng 8 gam vo 500ml dung dch CuSO4 2M. Sau mt thi gian ly inh st ra
cn li thy nng 8,8 gam. Nng mol/l ca CuSO4 trong dung dch sau phn ng l ?
A. 0,27M
B. 1,36M
C. 1,8M
D. 2,3M
..............................................................................................................................................................................................
Cu 5 Ngm l km trong dung dch cha 0,1 mol CuSO4. Phn ng xong thy khi lng l km (Zn) ?
A. tng 0,1 gam.
B. tng 0,01 gam.
C. gim 0,1 gam.
D. khng thay i.
..............................................................................................................................................................................................
Cu 6 Ho tan hon ton 28 gam bt Fe vo dung dch AgNO3 d th khi lng cht rn thu c l ?
A. 108 gam.
B. 162 gam.
C. 216 gam.
D. 154 gam.
..............................................................................................................................................................................................
Cu 7 Nhng 1 thanh nhm nng 50 gam vo 400ml dung dch CuSO4 0,5M. Sau mt thi gian ly thanh nhm ra cn
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

nng 51,38 gam. Hi khi lng Cu thot ra l bao nhiu ?
A. 0,64gam.
B. 1,28gam.
C. 1,92gam.
D. 2,56gam.
..............................................................................................................................................................................................
Cu 8 Ngm mt l Fe trong dung dch CuSO4. Sau mt thi gian phn ng ly l Fe ra ra nh lm kh, em cn
thy khi lng tng thm 1,6 gam. Khi lng Cu bm trn l Fe l bao nhiu gam ?
A. 12,8 gam.
B. 8,2 gam.
C. 6,4 gam.
D. 9,6 gam.
..............................................................................................................................................................................................
Cu 9 Ngm mt l km trong 100 ml dd AgNO3 0,1M. Phn ng kt thc, khi lng l km tng thm bao nhiu ?
A. 0,65 gam.
B. 1,51 gam.
C. 0,755 gam.
D. 1,3 gam.
..............................................................................................................................................................................................
DNG 5 : NHIT LUYN
Cu 1 Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O 4
nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l ?
A. 0,448.
B. 0,112.
C. 0,224.
D. 0,560.
..............................................................................................................................................................................................
Cu 2 Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit
cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch
Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l ?
A. 1,120.
B. 0,896.
C. 0,448.
D. 0,224.
..............................................................................................................................................................................................
Cu 3 Cho kh CO kh hon ton n Fe mt hn hp gm: FeO, Fe2O3, Fe3O4 thy c 4,48 lt CO2 (ktc) thot ra.
Th tch CO (ktc) tham gia phn ng l ?
A. 1,12 lt.
B. 2,24 lt.
C. 3,36 lt.
D. 4,48 lt.
..............................................................................................................................................................................................
Cu 4 Thi mt lung kh CO i qua ng s ng m gam hn hp Fe3O4 v CuO nung nng thu c 2,32 gam hn
hp rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH)2 d thu c 5 gam kt ta. Gi tr ca
m l ?
A. 3,22 gam.
B. 3,12 gam.
C. 4,0 gam.
D. 4,2 gam.
..............................................................................................................................................................................................
Cu 5 kh hon ton 30 gam hn hp CuO, FeO, Fe2O3, Fe3O4, MgO cn dng 5,6 lt kh CO ( ktc). Khi lng
cht rn sau phn ng l ?
A. 28 gam.
B. 26 gam.
C. 22 gam.
D. 24 gam.
..............................................................................................................................................................................
Cu 6 Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO ( ktc). Khi lng st thu c l
?
A. 5,6 gam.
B. 6,72 gam.
C. 16,0 gam.
D. 8,0 gam.
..............................................................................................................................................................................
Cu 7 Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon ton, thu
c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l ?
A. 0,8 gam.
B. 8,3 gam.
C. 2,0 gam.
D. 4,0 gam.
..............................................................................................................................................................................
Cu 8 Cho dng kh CO d i qua hn hp (X) cha 31,9 gam gm Al2O3, ZnO, FeO v CaO th thu c 28,7 gam
hn hp cht rn (Y). Cho ton b hn hp cht rn (Y) tc dng vi dd HCl d thu c V lt H2 (kc). Gi tr V l ?
A. 5,60 lt.
B. 4,48 lt.
C. 6,72 lt.
D. 2,24 lt.
..............................................................................................................................................................................
Cu 9 kh hon ton 45 gam hn hp gm CuO, FeO, Fe3O4, Fe v MgO cn dng va 8,4 lt CO (ktc).
Khi lng cht rn thu c sau phn ng l ?
A. 39g
B. 38g
C. 24g
D. 42g
..............................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

DNG 6 : IN PHN
Cu 1 Khi cho dng mt chiu I=2A qua dung dch CuCl2 trong 10 pht. Khi lng Cu thot ra catot l ?
A. 40 gam.
B. 0,4 gam.
C. 0,2 gam.
D. 4 gam.
..............................................................................................................................................................................................
Cu 2 in phn n ht 0,1 mol Cu(NO3)2 trong dung dch vi in cc tr, th sau in phn khi lng dung dch
gim bao nhiu gam ?
A. 1,6 gam.
B. 6,4 gam.
C. 8,0 gam.
D. 18,8 gam.
..............................................................................................................................................................................................
Cu 3 in phn dng in cc tr dung dch mui sunfat kim loi ho tr 2 vi cng dng in 3A. Sau 1930
giy thy khi lng catot tng 1,92 gam. Mui sunfat in phn l ?
A. CuSO4.
B. NiSO4.
C. MgSO4.
D. ZnSO4.
..............................................................................................................................................................................................
Cu 4 in phn hon ton 1 lt dung dch AgNO3 vi 2 in cc tr thu c mt dung dch c pH= 2. Xem th tch
dung dch thay i khng ng k th lng Ag bm catot l ?
A. 0,54 gam.
B. 0,108 gam.
C. 1,08 gam.
D. 0,216 gam.
..............................................................................................................................................................................................
Cu 5 in phn 200 ml dung dch mui CuSO4 trong thi gian, thy khi lng dung dch gim 8 gam. Dung dch
sau in phn cho tc dng vi dd H2S d thu c 9,6g kt ta en. Nng mol ca dung dch CuSO4 ban u l ?
A. 1M.
B.0,5M.
C. 2M.
D. 1,125M.
..............................................................................................................................................................................................
Cu 6 in phn dung dch AgNO3 ( in cc tr ) trong thi gian 15 pht, thu c 0,432 gam Ag catot. Sau
lm kt ta ht ion Ag+ cn li trong dung dch sau in phn cn dng 25 ml dung dch NaCl 0,4M. Cng dng
in v khi lng AgNO3 ban u l ? ( Cho Ag=108 )
A. 0,429 A v 2,38 gam.
B. 0,492 A v 3,28 gam.
C. 0,429 A v 3,82 gam. D. 0,249 A v 2,38 gam.
..............................................................................................................................................................................................
Cu 7 in phn 200 ml dung dch AgNO3 0,4M (in cc tr) trong thi gian 4 gi, cng dng in l 0,402A.
Nng mol/l cc cht c trong dung dch sau in phn l ?
A. AgNO3 0,15M v HNO3 0,3M.
B. AgNO3 0,1M v HNO3 0,3M.
C. AgNO3 0,1M
D. HNO3 0,3M
..............................................................................................................................................................................................
Cu 8 Sau mt thi gian in phn 200 ml dung dch CuCl2 thu c 1,12 lt kh X ( ktc). Ngm inh st vo dung
dch sau in phn, khi phn ng xy ra hon ton thy khi lng inh st tng thm 1,2 gam. Nng mol ca
CuCl2 ban u l ?
A. 1M.
B. 1,5M.
C. 1,2M.
D. 2M.
..............................................................................................................................................................................................
Cu 9 in phn bng in cc tr dung dch mui sunfat ca kim loi ho tr II vi dng in c cng 6A. Sau
29 pht in phn thy khi lng catot tng ln 3,45 gam. Kim loi l ?
A. Zn.
B. Cu.
C. Ni.
D. Sn.
..............................................................................................................................................................................................
Cu 10 in phn 400 ml dung dch CuSO4 0,2M vi cng dng in 10A trong 1 thi gian thu c 0,224 lt
kh (kc) anot. Bit in cc dng l in cc tr v hiu sut in phn l 100%. Khi lng catot tng l ?
A. 1,28 gam.
B. 0,32 gam.
C. 0,64 gam.
D. 3,2 gam.
..............................................................................................................................................................................
DNG 7 : SO2, CO2 TC DNG VI DUNG DCH KIM
Cu 1 Cho 4,48 lt CO2 kc tc dng vi 160 ml NaOH 2M sau p thu c mui no ? Khi lng l bao nhiu ?
..............................................................................................................................................................................................
Cu 2 Cho 4,48 lt SO2 kc tc dng vi 240 ml dd KOH 2 M. Sau p thu c mui no ? khi lng l ?
..............................................................................................................................................................................................
2011 2012 TRNG THPT NAM SCH II

Tp Ch Ha Hc & ng Dng www.hoahoc.org

Cu 3 Cho 4,032 lt CO2 kc tc dng hon ton vi 250 ml dd NaOH th thu c 16,88 gam hh mui. Tnh a ?
..............................................................................................................................................................................................
Cu 4 Cho V lt CO2 kc tc dng vi 140 ml dd NaOH 2 M. th thu c 17,32 gam hn hp mui. Tnh V ?
..............................................................................................................................................................................................
Cu 5 Cho 1,344 lt SO2 (kc) tc dng vi dd 130 ml NaOH a M . Th thu c hh 2 mui. Tm iu kin ca a
thu c 2 mui ?
..............................................................................................................................................................................................
Cu 6 Cho V lt CO2 tc dng vi 140 ml dd KOH 2 M. Tm k ca V thu c 2 mui ?
..............................................................................................................................................................................................
Cu 7 Cho 2,688 lt CO2 kc vo 140 ml dd Ca(OH)2 2 M. Tnh m kt ta ?
..............................................................................................................................................................................................
Cu 8 Cho 3,136 lt CO2 kc vo 100 ml dd Ca(OH)2 1 M. Tnh m kt ta ?.
..............................................................................................................................................................................
Cu 9 Tnh V CO2 cn sc vo dd Ba(OH)2 thu c 19,7 gam kt ta v dd (X). un nh dd (X) c xut hin thm
11,28 gam kt ta na ?
..............................................................................................................................................................................................
Cu 10 Tnh th tch CO2 cn cho vo 80 ml Ca(OH)2 2 M thu c 10 gam kt ta.
..............................................................................................................................................................................................
DNG 8 : XC NH KIM LOI V SN PHM KH
Xc nh kim loi trong cc trng hp sau ?
Cu 1 Ly 8,97 gam kim loi kim tc dng hon ton vi H2O th thu c 2,576 lt H2 (ktc)
..............................................................................................................................................................................................
Cu 2 Ly 5,48 gam kim loi kim th tc dng vi H2O th thu c 0,896 lt H2 (ktc)
..............................................................................................................................................................................................
Cu 3 Ly 5,2 gam kim loi c ha tr II tc dng vi HNO3 thu c 7,168 lt NO2 duy nht
..............................................................................................................................................................................................
Cu 4 Ly 15,12 gam kim loi R (cha cho ha tr) tc dng hon ton vi HCl thu c 18,816 lt H2 kc.
..............................................................................................................................................................................................
Cu 5 in phn nng chy 15,54 gam mui clorua kim loi kim th thu c 3,136 lt kh (ktc)
..............................................................................................................................................................................................
Cu 6 in phn nng chy mui clorua kim loi kim c 8,52 gam sn phm anot v 5,52 gam sn phm catot
..............................................................................................................................................................................
Cu 7 Ly kim loi ha tr II tc dng vi dung dch HNO3 th thu c 45,36 gam mui 3,584 lt kh NO duy nht
..............................................................................................................................................................................................
Cu 8 Ly 11,52 gam Cu tc dng hon ton vi HNO3 th thu c 2,688 lt kh kc l sp kh duy nht. Xc nh kh
l sn phm kh duy nht?
..............................................................................................................................................................................................
Cu 9 Ly 5,76 gam Mg tc dng vi dung dch HNO3 th thu c 1,344 lt kh (ktc) l sn phm kh duy nht.
Xc nh kh l sn phm kh duy nht?
..............................................................................................................................................................................................
Cu 10 Ly 16,2 gam Al tc dng vi dung dch HNO3 thu c 4,032 lt kh duy nht (ktc). Xc nh kh l sn
phm kh duy nht?
..............................................................................................................................................................................................

2011 2012 TRNG THPT NAM SCH II