CHEMISTRY CREST

AIEEE ACHIEVER 3

Maximum Marks: 120

Question paper format and Marking scheme: 1. This question paper has 30 questions of equal weight age. Each question is allotted 4(four) marks for each correct response. 2. (one fourth) of total marks allotted to each question i.e., 1 mark will be deducted for indicating incorrect response 3. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. 4. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response and marks for wrong response will be deducted accordingly.

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1.

AIEEE ACHIEVER 3

If the radius of 3rd orbit of Li2+ ion is x cm, then de Broglie wavelength of electrons in the first orbit is (in cm) 2x (2) (1) 6x 9 2x 8x (3) (4) 3 3 How many aromatic carbonyl compounds are possible for the molecular formula C8H8O ? (1) 5 (2) 6 (3) 4 (4) 3 The correct IUPAC name for the compound [Co(NH3)4Cl(ONO)]Cl is : (1) Tetraamminechloridonitrito-N-cobalt(III)chloride (2) Chloridonitrito O - tetraamminecobalt(II)chloride (3) Dichloridonitrito-O-tetraamminecobalt(III) (4) Tetraamminechloridonitrito-O-cobalt(III)chloride 11 For the reaction : 2 FeS 2 + O2 Fe2O3 + 4 SO2 . What will be the equivalent weight of FeS2 , if 2 the molecular weight of FeS2 is M ? (1) M /8 (2) M (3) M /11 (4)Cant be calculated The correct order of rates of nitration in the following is
D D D

2.

3.

4.

5.

NO2

Cl

D D

II

III

IV

V
2) IV < V < I = III < II 4) I < III < II < V < IV

1) II < III < I < IV < V 3) IV < I = III < V < II 6.

Which of the following statement is incorrect? (1) The superoxide ion (i.e., O2-) is stable only in presence of larger cations such as K,Rb, Cs. (2) Alkalimetals are normally kept in kerosene oil. (3) All the alkalimetal hydrides are ionic solids with high melting points. (4) The concentrated solution of alkali metals in liquid ammonia are strong paramagnetic in nature. The bond enthalpy ( in kJ/mol) of one three centre two electron bond in

7.

Given,

(1) 498

(2) 455

(C) 320

(D) 550
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AIEEE ACHIEVER 3

8. (1)

on reaction with NBS in CCl4 gives the major product (2)

CHBr
Br

(3)
Br

(4)
CH2Br

9.

Which of the following statements is correct (1) If an element X has electronic configuration [Xe]5d106s1, then it belongs to s-block in modern periodic table. (2) The addition of an extra electron to Alkali metals is an endothermic process. (3) The first ionisation potential of Nitrogen is greater than that of Oxygen and Fluorine. (4) The removal of electron from gaseous halide ions is an endothermic process. The reaction A ( g ) + 2B ( g ) C + D is an elementary process. In an experiment, the initial (g) (g) pressure of A and B are P = 0.6 atm and P = 0.8atm . When P = 0.2atm, the rate of the
A B C

10.

reaction relative to the initial rate is (1) 1/48

(3) 9/16

(2) 1/24 1 (4) 6

11.

Stability of the following alkenes in increasing order is

12.

Which of the following order is incorrect regarding oxyacids of chlorine and halogen acids ? (1) Thermal stability HClO < HClO2 < HClO3 < HClO4 (2) Acid strength HClO < HClO2 < HClO3 < HClO4 (3) Oxidising power HClO < HClO2 < HClO3 < HClO4 (4) Reducing power HF < HCl < HBr < HI

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AIEEE ACHIEVER 3

13.

The standard reduction potentials in acidic medium are 0.77V and 0.54V respectively for Fe3+ / Fe+2 and I 3 / I . The equilibrium constant for the reaction 2 Fe+3 + 3I 2 Fe2+ + I 3 is (antilog of 7.7834= 6.25 107 , antilog of 9.9123= 8.168 109 , antilog of 4.5011= 3.171104 , antilog of 2.1602= 1.446 102 )
(1) 6.25 107 (3) 3.171104 (2) 8.168 109 (4) 1.446 102

14.

Z in the following sequence of reactions is

15.

Which of the following does not react with AgCl (1) Na2S2O3 (2) NH4OH (3) NaNO3

(4) Na3AsO3

16.

How many unit cells are present in a cube shaped ideal crystal of NaCl of mass 1.00 g (1)2.57 x 1021 unit cells (2)5.14 x 1021 unit cells
(3)1.28 x 1021 unit cells (4)1.71 x 1021 unit cells

17.

The reaction of 1-bromo-3-chlorocyclobutane with metallic sodium in dry ether gives

18.

Metaphosphoric acid exists in polymeric form and may have (1) A linear structure (2) A cyclic structure (3) Both linear as well as cyclic structures (4) None Barium ions, CN and Co +2 form an ionic complex. If this complex is 75% ionized in aqueous solution with Vant Hoff factor(i) equal to four and paramagnetic moment is found to be 1.73 BM(due to spin only) then hybridization state of Co(II) in the complex will be

19.

(1) sp3d

(2) d 2sp3

(3) sp3d 2

(4) dsp3

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20. 21.

AIEEE ACHIEVER 3

n-propyl alcohol and iso-propyl alcohol can be chemically distinguished by which of the following (1) PCl5 (2) Reduction (3) Oxidation with potassium dichromate (4) ozonolysis Which of the following statements(s) is false for XeF6 (1) Its partial hydrolysis gives XeOF4. (2) Hybridisation state of Xe is sp3d2. (3) It is prepared by the reaction of XeF4 and O2F2. (4) Its reaction with XeO3 gives XeOF4. 1 litre flask contains nitrogen along with a drop or two of water at 40o C, the total pressure being 760 Torr. If all the contents are transferred to another flask of 0.5L at the same temperature. The total pressure of nitrogen setup in the second flask will be (aqueous tension at 40o C = 55 torr) (1) 1410 Torr (2) 1465 Torr (3) 1520 Torr (4) 1540 Torr During estimation of nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.5 g of the compound in Kjeldahl's estimation of nitrogen,neutralized 10mL of 1M H2SO4 . Find out the percentage of nitrogen in the compound. (1) 50% (2) 32% (3) 56% (4) 36% Which method of purification is represented by the equations

22.

23.

24.

(1) Cupellation 25.

(2) Polling

(3) Van Arkel

(4) Zone refining

The rates of radioactive decay of a sample are 3 108 dps and 3 107 dps after time 20 min and 43.03 minutes respectively. The fraction of radioactive atoms decaying per second is equal to 1 (2)1 (1) 600 (3) 0.5 (4) 0.001 Which of the following is not a reducing carbohydrate `(1) Glucose (2) Fructose (3) Sucrose Select correct option. (1) H2O, H2S, H2Se : increasing order of bond angle. (2) F2, Cl2, Br2 : decreasing order of bond energy. (3) H2O, NH3, CH4 : decreasing order of acidic character. (4) H2O, H2O2, NH3 : decreasing order of extent of H-bonding. The solubility product of Mg(OH)2 is 1.2 10 at 250C. The concentration of Mg 3 precipitation of Mg(OH)2 when added to 1 10 M NaOH solution 1) 1.2 108 2) 1 106 3) 1.2 105
11
2+

26.

(4) None of these

27.

28.

required to start

4) 1.44 106

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29.

AIEEE ACHIEVER 3

Propan-1-ol can be prepared from propene by (1) H2O / H2SO4 (2) Hg (OAc)2 / H2O followed by NaBH4 (4) CH3CO2H / H2SO4 (3) B2H6 followed by H2O2/OH. When potassium ferrocyanide is added to CuSO4 solution (1) White ppt is formed (2) Chocolate brown ppt is formed (3) Prussian blue is formed (4) Turnbull blue is formed

30.

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