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Saarland University
Those point groups derived from the space groups of the lattice are the highest symmetry possible for the particular crystal system.
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Saarland University
Subgroups - 1
The point groups of highest symmetry in each crystal system all contain the symmetry elements of one or more point groups of lower symmetry (sub-groups). Triclinic: the only subgroup of 1 is 1. Monoclinic: 2/m has the subgroups 2, m, 1, 1.
Space group of highest symmetry: P2/m: 2 normal to m b
0,0,0
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X,1/2,z
1/2,y,1/2
Saarland University
Subgroups - 2
Orthorhombic: if inversion symmetry is removed from point group 2/m, 2/m, 2/m, each 2/m must be reduced either to 2 or to m. mmm2/m2/m2/m 22m 2/m2/m2/m
Space group of highest symmetry: P2/m 2/m 2/m (P4/mmm) a b c Subgroups: mm2(m2m, 2mm) and 222.
Functional Materials
Saarland University
32 point groups
All crystal systems result in 32 subgroups, called crystallographic point groups
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Saarland University
Crystal forms
A space group reveals the entire symmetry of a crystal structure. If the crystal is bounded by plane faces, the symmetry of its morphology will be the symmetry of that point group. A set of equivalent faces is called a crystal form. PbS-galena crystal: 4/m 3 2/m
<a><111> <110>
Functional Materials
Saarland University
Functional Materials
Saarland University
The pole of the faces have a single degree of freedom The form will remain a tetragonal pyramid as long as the pole remains on the mirror plane ..m
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Saarland University
Functional Materials
Saarland University
Functional Materials
Saarland University
Functional Materials
Functional Materials
Saarland University
Functional Materials
Saarland University
Point group
42m
422
Saarland University
The crystal forms in other crystal systems can be developed in the same way as have done for the tetragonal system.
Functional Materials
Saarland University
Functional Materials
Saarland University