Chuyn III : Amin Amino Axit - Peptit

CHUYN : AMIN-AXIT AMIN

I. nh ngha Cng thc tng qut Tn gi: 1. Khi nim : Khi thay th mt hay nhiu nguyn t hidro trong phn t NH3 bng 1 hay nhiu gchidrocacbon ta c amin . VD: CH3 NH2 ; CH3 NH CH3 . 2. Cng thc . R-NH2 (Amin) ; R-CH-COOH(Amino axit); H2N-CH-CO--NH-CH-COOH(Peptit) Nng cao : n li CT tng qut : CnH2n + 2 2a x (Chc)x CT tng qut ca amino axit : CnH2n + 2 2a x (NH2)x vi a l s lin kt pi v x l s nhm chc. T CT trn => CT amin n chc : CnH2n + 1 2a (NH2) => amin n chc no => a = 0 : CnH2n + 1 NH2 , c 1 lk pi => a = 1 : CnH2n 1NH2 Thay a vo => CT tng ng. CT tng qut ca amino Axit : (H2N)n R (COOH)n : n , n 1 : R l gc hidrocacbon ha tr (n + n) Hoc ( H2N)n CxHy (COOH)n : n , n 1 , x 1 , y + n + n 2x + 2 Amino axit thng gp : Amino axt cha 1 nhm amino (NH2) v mt nhm chc axit (COOH) no mch h : R-COOH NH2 Bc ca amin bng s nguyn t H trong amin b thay th bi gc hidrocabon VD: CH3 NH2 (Bc 1) CH3 NH CH3(Bc 2) (CH3)3N (Bc 3) 3. Tn gi : Tn gc hidrocacbon + amin CH3 NH CH3 : imetyl amin. 4. Tnh cht a) Tnh cht ca nhm NH2 63. Tnh baz: R-NH2 + H2O => [R-NH3]+OHTc dng vi axit cho mui: R-NH2 + HCl => [R-NH3]+Cl64. Tc dng vi HNO2 Amin bo bc I to thnh ancol v kh N2 : R-NH2 + HONO => R-OH + N2 + H2O Amin thm bc I: ArNH2 + HNO2 + HCl => ArN2+Cl hay ArN2Cl Tc dng vi dn xut Halogen R-NH2 + CH3I => R-NHCH3 + HI b) Amino axit c tnh cht ca nhm COOH 65. Tnh axit: RCH(NH2)COOH + NaOH => RCH(NH2)COONa + H2O 66. Phn ng este ho: RCH(NH2)COOH + ROH => RCH(NH2)COOR + H2O c) Amino axit c phn ng gia nhm COOH v nhm NH2 To mui ni H2N-CH-COOH => H3N+-CH-COO Phn ng trng ngng ca cc v amino axit to poliamit: nH2N-[CH2]5-COOH => ( NH-[CH2]5-CO )n + nH2O axit - aminocaproic policaproamit d) Protein c phn ng ca nhm peptit CO-NH Phn ng thu phn: Phn ng mu: Tc dng vi Cu(OH)2 cho dung dch mu xanh tm. e) Anilin c phn ng th d dng 3 nguyn t H ca vng benzen(o , p) => kt ta trng (dng nhn bit anilin) Ch cc cht sau : anilin (C6H5NH2) v amino axit thng dng. Chuyn luyn thi i hc 1

Chuyn III : Amin Amino Axit - Peptit

II) Cc dng bi tp thng gp Dng 1: S ng phn ca amin n :

CTPT Tng s ng Bc 1 phn 4 2 8 4 17 8 Bc 2 Bc3

1 1 C3H9N 3 1 C4H11N 6 3 C5H13N 7 C6H15N 5 4 1 0 C7H9N VD1:Cho amin no n chc c %N = 23,72% . Tm s ng phn bc 3 ca amin A. 1 B.2 C.3 D.4 PP: amin no n chc => CT : CnH2n+1NH2 MN.100% 14.100% %N = 23,72% Gii ra c n = 3 Ma min 14n 17 CT : C3H7N2 => C ng phn bc 3 l 1 ( Bng trn C3H9N)

Dng2 : So snh tnh baz ca cc amin

Nguyn tc : Amin cn d i e cha lin kt trn nguyn t Nit nn th hin tnh baz => c trng cho kh nng nhn proton H+ Nhm ankyl c nh hng lm tng mt e nguyn t Nit =>lm tng tnh baz. >NH3 Nhm phenyl (C6H5-) lm gim mt e trn nguyn t Nit =>lm gim tnh baz. <NH3 Lc baz : CnH2n+1-NH2 > NH3 > C6H5-NH2 Amin bc 2 > Amin bc 1 Gii thch: Do amin bc 2 (R-NH-R) c hai gc HC nn mt y e vo nguyn t N trung tm ln hn amin bc 1 (R-NH2). Amin cng c nhiu gc ankyl, gc ankyl cng ln => tnh baz cng mnh. gc phenyl => tnh baz cng yu. *V D: So snh tnh baz ca cc hp cht hu c sau: NH3 , C2H5NH2 , CH3NH2 , C6H5NH2 , (C6H5)2NH , (C2H5)2NH , C6H5 CH2NH2 ? (C2H5)2NH > C2H5NH2 > CH3NH2 > NH3 > C6H5> CH2NH2 > C6H5NH2 > (C6H5)2NH VD1: Cho cc cht: (1) amoniac. (2) metylamin. (3) anilin. (4) dimetylamin. Tnh baz tng dn theo th t no sau y? A. (1) < (3) < (2) < (4). B. (3) < (1) < (2) < (4). C. (1) < (2) < (3) < (4). D. (3) < (1) < (4) < (2). Amoniac : NH3 ; metyamin : CH3NH2 ; anilin : C6H5NH2 ; dimetyl amin : CH3 NH CH3 Da vo tnh cht trn : anilin c vng benzen(gc phenyl) => Tnh bazo yu nht NH3 mc trung gian > C6H5NH2 Amin bc I (CH3NH2) < Amin bc 2 (NH3 NH NH3) => Th t : C6H5NH2 < CH3 < CH3NH2<(CH3)NH

Dng 3: Xc nh s nhm chc :

Nu bi cho s mol amin v s mol axit (H+) lp t s : S nhm chc = Nu amin ch c 1N => s chc = 1 Chuyn luyn thi i hc

nH nA min

Chuyn III : Amin Amino Axit - Peptit VD: trung ha 50 ml dd amin no , (trong amin c 2 nguyn t Nito ) cn 40 ml dd HCl 0,1 M . CM ca imetyl amin dng l : A.0,08M B.0,04M C.0,02M D.0,06M Amin c 2 N => amin c s chc = 2 ADCT : namin = nHCl/2 = 0,002 mol => CM amin = 0,04 M

Dng 4 : Xc inh s mol ca ca amin nu bit s mol ca CO2 & H2O :

Nu bi cha cho amin no, n chc th ta c gi s l amin no, n. Khi t chy nH2O > nCO2 ,ta ly : nH2O - nCO2 = 1,5namin Cch chng minh nh phn hidrocacbon CT amin no n chc : CnH2n+1NH2 PT : CnH2n+3N2 + O2 => nCO2 + (n+3/2)H2O + N2 x mol n.x mol (n+3/2).x mol Ta ly nH2O nCO2 = 3/2x = 3/2n amin nCO2 1,5.nCO2 T => n (s C trong amin) hoc n = na min nH 2O nCO2 Tng t c CT i vi amin khng no , n chc + C 1 lk pi , C 2 lk pi , Chng minh tng t Nu bi cho amin n chc, m khi t chy to ra bit n CO2 v nN2 . th ta c CT sau V amin n chc => c 1 N . AD LBT nguyn t N => n amin = 2nN2 nCO2 nCO2 M n hoc n = n( n) na min 2nN 2 VD1: t chy hon ton amol hh X gm 2 amin no n chc lim tip nhau thu c 5,6 lt CO2 (ktc) v 7,2 g H2O . Gi tr ca a l : A. 0,05 mol B.0,1 mol C.0,15 mol D.0,2 mol Tm CT 2 amin ? AD CT : namin = (nH2O nCO2)/1,5 ( i vi amin no n chc) = (0,4 0,25)/1,5 = 0,1 mol nCO2 0,25 2,5 => Amin c CT : CnH2n+1NH2 CT amin : n = na min 0,1 n = 2 v n = 3 :C2H5NH2 v C3H7NH2 VD2: Aminoaxit X cha mt nhm chc amin bc nht trong phn t. t chy hon ton mt lng X thu c v theo t l th tch l 4 : 1. X c cng thc cu to l: A.H2N CH2 CH2 COOH B.H2N (CH2)3 COOH C.H2N CH2 COOH D. H2N (CH2)4 COOH Da vo p n => amin X ch c 1 N => 2nN2 = namin (BT NT Nito) nCO2 nCO2 4 n 2 => X Ch c 2 C => C M n na min 2nN 2 2

Dng 5: tm CTPT ca amin n, nu bit % khi lng N hoc %H hay %C cng c:

Gi R l gc hidrocacbon ca amin cn tm . VD amin n chc CT : R-NH2 Mt s gc hidrocacbon thng gp : 15 : CH3; 27 : CH2=CH; 29 : C2H5-; 43 :C3H7; 57 : C4H9VD 1: Cho amin no , n chc bc 1 c %N = 31,11% . Tm CT ca amin NH li CT tng qut : CnH2n+2 2a m(CHc)m ( a l tng pi tnh phn trn) y v amin n chc => m = 1 , V amin no => a = 0 => CT: CnH2n+2 1 NH2 = CnH2n+1NH2 14.100% 31,11% Gii ra c n = 2 => CT: C2H5NH2 => %N = 14n 17

Dng 6: Cho amin tc dng vi dd FeCl3, Cu(NO3)2 to kt ta :

Chuyn luyn thi i hc 3

Chuyn III : Amin Amino Axit - Peptit Amin c kh nng tc dng vi dd FeCl3 , Cu(NO3)2 xy ra theo phng trnh : 3RNH2 + FeCl3 + 3H2O => Fe(OH)3 + 3RNH3Cl 2RNH2 + Cu(NO3)2 + 2H2O => Cu(OH)2 + 2RNH2NO3 Thng th bi hay cho m kt ta : Fe(OH)3 hoc Cu(OH)2

Dng 7: tm CTPT ca amin da theo phn ng chy

-Cng thc : AD CT : Tm CT bt k : CnH2n+2 2a m(Chc)m Ta c Amin bt k : CxHyNz vi y 2x + 2 +z y chn th z chn, y l th z l Amin n chc : CxHyN Amin n chc no : CnH2n+1NH2 , CnH2n+3NH2 Amin a chc no : CnH2n+2-z(NH2)z , CnH2n+2+zNz Nu cho phn trm khi lng tng nguyn t th lp CT n gin nht, da vo gi thuyt bin lun. Theo T l : x : y : z Nu bi cho s mol sn phm th lm tng t dng 3, tm c s ngt C trung bnh, da vo yu cu a ra CT ng Nu bi cho m g amin n chc t chy hon ton trong khng kh va (cha 20% oxi, 80% nit) thu c ch k mol CO2 hoc c k mol CO2 ln x mol nit , ta c th lm nh v d: VD1: t chy hon ton 1,18 g amin n chc B bng mt lng oxi va . Dn ton b sn phm wa bnh ng nc vi trong d thu c 6 gam kt ta .CTPT ca B l : Gi cng thc l CxHyN CxHyN + O2 => x CO2 Ta c t l : x.namin =nCO2 1,18 0,46 x 0,84 x. 0,06 y 2x +2+1 x 3 12 x y 14 0,06 Cho x chy t 1=>3 : ch c gi tr x=3 v y=9 l tho k . Vy CTPT l C3H9N VD2:t chy hon ton 1,18 g amin n chc B bng mt lng khng kh va u (cha 20% oxi, 80% nit). Dn ton b sn phm wa bnh ng nc vi trong d thu c 6 gam kt ta v c 9,632 lt kh duy nht thot ra .CTPT ca B l : Gi cng thc l CxHyN . nCO2 = 0,06 mol CxHyN + (x + y/4) O2 => x CO2 + y/2 H2O + N2 y y 0,06( x ) 0,06( x ) 4 nN 2kk 4. 4 nO2 x x y 0,06( x ) 0,03 4 0,03 0,43 0,19 x 0,06 y 0,03(1) Theo pt : nN 2 nN 2 4. x x x 1,18 0,06 0,46 x 0,06 y 0,84(2) 12 x y 14 x Giai(1) & (2) x 3; y 9 Vy CTPT l C3H9N Nu bi ton cho t chy mt amin bng khng kh ,ri thu a mol CO2 ; b mol H2O ; c mol N2.ta lm nh sau : Tm khi lng O trong CO2 ;H2O = khi lng Oxi tham gia phn ng ( BT Nguyn t O) => s mol oxi => s mol Nit trong kk = 4nO2 (Nu bi tp cho t trong khng kh cn Nu t trong O2 th khng phi tnh) => s mol Nit sinh ra trong phn ng chy. T ta s c s mol C, H, N trong amin => Tm CTGN => CTPT VD1: Mt amino axit cha 46,6% C, 8,74% H, 13,59% N,cn li l oxi. Cng thc n gin nht trng vi cng thc phn t. Cng thc phn t ng ca amino axit l A.C3H7O2N B.C4H9O2N C.C5H9O2N D.C6H10O2N % O = 100 - (46,6 + 8,74 + 13,59) = 31,07 % Chuyn luyn thi i hc 4

Chuyn III : Amin Amino Axit - Peptit

%C % H %O % N 46,6 8,74 31,07 13,59 = 3,88 : 8,74 : 1,94 : : : : : : : 12 1 16 14 12 1 16 14 0,97 = 4 : 9 : 2 : 1 => CTG : C4H9O2N => Chn B Nu lm trc nghim nh th th hi lu. Mo dp n: S C u khc nhau v s N ging nhau ( bi hay cho kiu ny) Ch cn xt t l gia C v N thi khng cn O v H Xt t l ta c C : O = 4 : 1 => B VD2: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16)Chn mt p n di y A. C3H7N B. C3H9N C. C4H9N D. C2H7N Cu ny khc xt t l C : H hay hn Tm c t l 1 : 3 => B V p n A v B t l C : N = 3: 1

C:H:O:N=

Dng 8: Cho amin tc dng vi HCl: (PP Gii bi tp dng tng gim khi lng)
VD amin bc 1: Aminno axit : NH2 R COOH + HCl => CLNH3-R-COOH Gii s 1mol 1mol => 1mol => m tng = m mui m amin = 36,5 g (v P cng HCL) Vi xmol => xmol => xmol => m Tng = 36,5x g m mui = mamin + namin (HCl hoc mui).36,5 Hoc dng BT Khi lng : m amin + mHCl = m mui (Chnh l CT trn) Cn nu amino Axit tc dng vi NaOH(Kim) (Hoc Na,K) Th xem li phn Axit nh. CT: m mui = mAmino Axit + m.nNaOH.22 ( m l s chc COOH) i vi Amino Axit c 1 nhm COOH => nNaOH = nAmino Axit = n Mui VD1: Cho 0,01 mol amino axit A tc dng va vi 80 mldung dch HCl 0,125 M. C cn dung dch thu c1,835 gam mui. Khi lng phn t ca A (Tc l M ca A)l A.97 B.120 C.147 D.150 ADCT: m mui = mamin + nHCL .36,5 1,835 =Mamoni . 0, 01 + 0,01.36,5 M amino = 147 VD2: Cho 0,01 mol aminoaxit X phn ng ht vi 40ml dung dch HCl 0,25M to thnh 1,115g mui khan. X c cng thc cu to no sau y: A.NH2 CH2 COOH B.NH2 (CH2)2 COOH C.CH3COONH4 D.NH2 (CH2)3 COOH Da vo p n hoc Xt t l : nHCL / namin = 1 => amino axit c 1 gc chC. p t l 1 :1 => Loi p n C. AD CT : m mui =Mamino axit . 0,01 + nHCL . 36,5 1,115 = MX.0,01 + 0,01.36,5 MX = 75 CT : amino axit : NH2 CnH2n COOH => MR = 14n + 61 = 75 => n = 1 CT : NH2 CH2 COOH VD3: A l mt -amino axit no ch cha mt nhm -NH2 v mt nhm COOH. Cho 3 gam A tc dng vi NaOH d thu c 3,88 gam mui. Cng thc phn t ca A l A.CH3-CH2-CHNH2-COOH B.CH2NH2-CH2-COOH C.CH3-CHNH2-COOH D.H2N-CH2-COOH Cch gii bnh thng : Theo bi ta c gc hirocacbono l CnH2n H2NCnH2nCOOH + NaOH => H2NCnH2nCOONa + H2O bi 3 gam 3,88 gam Theo PT => nH2NCnH2nCOOH = nH2NCnH2nCOONa 3 3,88 Gii ra c : n = 1 => CTCT ca A l H2N-CH2-COOH Chn D 14 n 61 14 n 83 Chuyn luyn thi i hc 5

Chuyn III : Amin Amino Axit - Peptit ADCT trn => nH2NCnH2nCOOH = MH2NCnH2nCOOH = 14n +61 =
mmuoi ma min o 3,88 3 0,04mol 22 22

3 75 n 1 0,04

Dang 9: Trn hn hp gm amin v hirocacbon ri em t chy

Xt v d sau : VD5: t chy hon ton hn hp gm 100 ml hh gm imetylamin v hai hirocacbon ng ng k tip thu c 140 ml CO2 v 250 ml nc ( cc V cng iu kin). CTPT ca hai hirocacbon? Ta thy : Hh gm (C2H5)2NH v CxHy (x l s ngt C trung bnh ca hai HC). 140 Gi n l s nguyn t C trung bnh => n 1,4 100 Vy mt trong hai cht phi c 1 cht c s ngt C > 1,4 , l (C2H5)2NH. Cht cn li c s ngt C nh hn 1,4 => x<1,4 => hai hirocacbon ng ng k tip trn phi thuc dy ng ng ca ankan. Vy 2 hirocacbon cn tm l CH4 v C2H6 BI TP P DNG

Cu 1: Cho cc cht sau: C6H5NH2 (X), (CH3)2NH (Y), CH3NH2 (Z), C2H5NH2 (T), Th t tng dn tnh baz ca cc cht ni trn l A. Y < Z < X < T. B. X < Z < T < Y.

C. T < Y < Z < X. D. T < X < Y < Z. Cu 2: t chy hon ton hn hp 2 amin n chc no bc 1. Trong sn phm chy thy t l mol CO 2 v H2O tng ng l 1: 2. Cng thc ca 2 amin l A. C3H7NH2 v C4H9NH2. B. C2H5NH2 v C3H7NH2.

C. CH3NH2 v C2H5NH2. D. C4H9NH2 v C5H11NH2. Cu 3 (A-2007): Cho hn hp X gm 2 cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp kh Z (ktc) gm 2 kh (u lm xanh giy qu m). T khi hi ca Z so vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 8,9 gam. B. 14,3 gam. Cu 4:Cng thc tng qut ca amin l CxHyNz. C. 16,5 gam. D. 15,7 gam.

A. y cha so snh c vi 2x + 2 v c th chn hoc l do cn ph thuc vo z. B. y 2x + 2 v c th chn hoc l v do cn ph thuc vo z. C. y 2x + 2 v y lun lun chn, khng ph thuc vo z. D. y 2x + 2 v y lun lun chn, khng ph thuc vo z. Cu 5: Cho cc loi hp cht sau: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Cc loi cht va tc dng vi dung dch NaOH, va tc dng vi dung dch HCl l A. X, Y, Z, T. B. X, Y, Z. C. X, Y, T. Cu 6: S lng ng phn ng vi cng thc phn t C4H11N l D. Y, Z, T.

A. 5. B. 6. C. 7. D. 8. Cu 7: Cho cc cht sau: NH3 (X) ; (C6H5)2NH (Y); C6H5NH2 (Z); CH3NH2 (T); C6H5NHCH3 (M). Th t gim dn tnh baz ca cc cht trn l A. T > X > M > Z > Y. B. T > X > Z > M > Y.

C. M > X > Y > Z > T. D. X > M > T > Y > Z. Cu 8: X l mt a- aminoaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 17,8 gam X tc dng vi dung dch HCl d thu c 25,1 gam mui. Tn gi ca X l A. axit amino axetic. B. axit a- amino propionic.

C. axit a- amino butiric. D. axit a- amino glutaric. Cu 9: Cho cc cht: anilin (X), amoniac (Y) v metylamin (Z). Th t tng dn nhit si ca cc cht l

Chuyn luyn thi i hc

Chuyn III : Amin Amino Axit - Peptit

A. Y < Z < X. B. Y < X < Z. C. X < Y < Z. D. Z < Y < X. Cu 10: Cho 4 cht ng phn: n-propylamin (X); trimetylamin (Y); etylmetylamin (Z) v iso-propylamin (T). Th t gim dn tnh baz ca 4 ng phn trn l A. Y > Z > X > T. B. Z > Y > T > X. C. Y > Z > T > X. D. Z > Y > X > T. Cu 11: A l hp cht hu c cha C, H, N; trong nit chim 15,054% v khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cng thc ca A l A. CH3-C6H4-NH2. B. C6H5-NH2. C. C6H5-CH2-NH2. D. C2H5-C6H4-NH2. Cu 12: S lng ng phn amin cha vng bezen ng vi cng thc phn t C 7H9N l A. 3. B. 4. C. 5. D. 6. Cu 13: t chy ht 6,72 lt hn hp kh (ktc) X gm 2 amin n chc bc mt A v B l ng ng k tip. Cho hn hp kh v hi sau khi t chy ln lt qua bnh 1 ng H2SO4 c, bnh 2 ng KOH d thy khi lng bnh 2 tng 21,12 gam. Tn gi ca 2 amin l A. metylamin v etylamin. B. etylamin v n-propylamin.

C. n-propylamin v n-butylamin. D. iso-propylamin v iso-butylamin. Cu 14: S lng ng phn aminoaxit ng vi cng thc H2N-C3H6-COOH l A. 4. B. 5. Cu 15: Trong dung dch, H2N-CH2-COOH tn ti dng C. 6. D. 7.

A. phn t trung ho. B. cation. C. anion. D. ion lng cc. Cu 16: t chy hon ton hn hp 2 amin n chc, no, bc 1, l ng ng k tip thu c t l mol CO 2 v H2O tng ng l 1:2. Cng thc ca 2 amin l A. C2H5NH2 v C3H7NH2. B. C4H9NH2 v C3H7NH2. C. CH3NH2 v C2H5NH2. D. C4H9NH2 v C5H11NH2. Cu 17: X l a-aminoaxit mch thng. Bit rng: 0,01mol X tc dng va vi 80ml dung dch HCl 0,125M thu c 1,835g mui. Mt khc, nu cho 2,94g X tc dng va vi NaOH th thu c 3,82g mui. Tn gi ca X l. A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 18: Cho hn hp 2 aminoaxit no cha 1 chc axit v 1 chc amino tc dng vi 110ml dung dch HCl 2M c dung dch A. tc dng ht vi cc cht trong A cn dng 140ml dung dch KOH 3M. Tng s mol 2 aminoaxit l A. 0,1. B. 0,2. C. 0,3. D. 0.4. Cu 19: a-aminoaxit X c phn trm khi lng ca nit l 15,7303%, ca oxi l 35,9551%. Tn gi ca X l A. glyxin. B. alanin. C. axit glutamic. D. lysin. Cu 20 (B-2007): Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng vi dung dch NaOH v dung dch HCl l A. Y, Z, T. B. X, Y, T. C. X, Y, Z, T. D. X, Y, Z. Cu 21: X c cha nhm amino v c cng thc phn t l C3H7O2N. Khi cho X phn ng vi dung dch NaOH, thu c mui C2H4O2NNa. Cng thc cu to ca X l A. H2N-CH(CH3)-COOH. B. H2N-CH2-CH2-COOH. C. H2N-CH2-COOCH3. D. CH3-NH-CH2-COOH. Cu 22 (A-2007): a-aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH. B. H2NCH2COOH.

C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. Cu 23: Nguyn nhn gy nn tnh baz ca C2H5NH2 l do A. C2H5NH2 to lin kt hiro vi nc nn tan nhiu trong nc. B. gc C2H5- y electron v pha N nn phn t C2H5NH2 phn cc. C. m in ca N ln hn H nn cp electron gia N v H b lch v pha N. D. nguyn t N cn c cp electron t do nn c kh nng nhn proton. Cu 24 (A-2007): t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2 ; 0,56 lt kh N2(cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H 2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-C2H5.

Chuyn luyn thi i hc

Chuyn III : Amin Amino Axit - Peptit

C. H2N-CH2-COO-CH3. D. H2N-CH2-CH2-COOH. Cu 25: t chy hon ton mt amin n chc, no, bc 2 thu c CO2 v H2O vi t l mol tng ng l 2:3. Tn gi ca amin l A. etyl metylamin. B. ietylamin. C. metyl iso-propylamin. D. imetylamin. Cu 26: Cho 0,01 mol mt aminoaxit X tc dng va vi 40ml dung dch NaOH 0,25M. Mt khc, 1,5 gam X tc dng va vi 40ml dung dch KOH 0,5M. Tn gi ca X l A. glyxin. B. alanin. C. axit glutamic. D. lysin.

Chuyn luyn thi i hc