I HC Y DC TP H CH MINH KHOA DC

THI: HA HU C
DC II LN I (NM 2009) Thi gian lm bi: 90 pht (khng k thi gian pht )

Cu I: Ngi ta thc hin phn ng ozon gii mt hp cht trong tinh du hoa hng th thu c hn hp cc cht sau: HOCH2CHO ; (CH3)2C=O ; CH3COCH2CH2CHO Xc nh cng thc cu to ca hp cht trn, gi tn. Hp cht ny c ng phn lp th hay khng? Nu c hy xc nh ng phn cu hnh? Cu II: Vit phng trnh phn ng v gii thch c ch phn ng xy ra:
H 2O A

CH3CH=CH2

+ HBr
+ RCOOR B

Cu III: 1. Vit cng thc cng hng ca acid benzoic 2. Da vo cc hiu ng in t, sp xp mnh tng i tnh acid ca dy hp cht sau: Acid carbonic, nc, phenol, metan, acetylen, ammoniac, acid acetic, alcol etylic, acid benzensulfonic, acid clohydric. Cu IV: Vit v cn bng cc phn ng sau:
1. Metyl vinyl ceton + NaBH4 2. Benzen + propanol/H+ 3. Acetylen + CH3CH2MgBr 4. Etanol + KBr/H+ 5. o-cresol + NaOH + CH3I 6. Isopren + CH2=CHCHO

Cu V: i t cht ban u l cc cht v c cn thit, vit s iu ch: 1. p-nitro phenol

2. n-propyl benzen

Cu VI: Hon thnh cc chuyn ha sau v gi tn cc sn phm to ra:

CH3CHO H3O C6 H 5COCl Mg / ete 1. Benzyl clorid A B C D pyridin
+

Cl / 400 C CO H O HBr Mg / ete 2. propen A B C D E peroxyd

2 2 3

HNO / H (CH CO) O NaOH / t H Sn / HCl 3. Clorobenzen A B C D E

3 o 3 2

- - - - - Ht - - - - -