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Fibre with diameter in nanometre range. Polymers are processed into nanofibres of 50 to 1000 nanometres in diameter, several orders of magnitude smaller than conventional fibre spinning. Provide new and improved functionalities than conventional fibres.
Electrospinning - accessible method to create polymer nanofibrous media Applications where performance can be improved multifold times. Wide range of applications, from tissue engineering to sound absorptive materials. Properties change as we go from macro to nano level
Inexpensive and easy way to produce nanofibres from wide range of polymers. Uses electrostatic forces to form fine filaments.
Spun through capillary forms Taylor cone produce fine fibres Solidifies when polymer solvent evaporates forms interlinked fiber layer on collector.
Processing Conditions
Applied Voltage Feed rate Needle Dia. Distance b/w Needle & Collector
Solution Properties
Viscosity Polymer Concentration Weight of Polymers Conductivity Elasticity Surface tension
PARAMETERS
Temperature Humidity Pressure
Ambient Conditions
Particle size decreases no. of atoms at surface increases. Surface effects become prominent. Surface area Volume ratio is very high. Applications 1.More reactive sites exposed. 2.High adsorption surface.
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Fewer defects in the form of voids Better mechanical properties than micron fibres when processed similarly.
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Fine diameter High degree of light scattering (e.g. : Electrospun carbon black) Possible to obtain transparent composites. (fibre dia. < of visible light) Excellent optical polarizers.
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Light weight Flexibility Permeability Strength Toughness Difficulty in achieving precise nanofibres deposition Hence deposited around a core filament
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Can be done without core usage- Poly acrylonitrile (PAN) nanofibres, reinforced with carbon nanotubes (CNT). Flame, Chemical and Environmental protections are areas of research.
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Carbon Nanofibres after burn test retain their structure can pave way for flame resistance materials and apparels.
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Electrospun mats made of nanofibres have very small pore sizes, but total porosity is very high. These 2 impart high filtration efficiency. Commercially developed for industrial air filters. Efficiency can be increased by surface modifications of nanofibres. Laid over a filtration medium substrate for support
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Lycopodium Bacteria caught in the nanofibre mesh over the substrate. It can pass through the substrate but, not through the nanofibre mesh.
Material Science and Metallurgy
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Devices in which recognition devices are nanosized Nanolevel property changes increased sensitivity and resolution levels.
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Nanofibrous layer is applied to basic fibrous layer by electrospinning Better acoustical performane Suitable candidate for noise reduction
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Incorporation of a new type of molecules called metal organic polyhedra and metal organic frameworks onto polymeric nanofibres Trap dangerous gases ,then decompose them and capture them for further decontamination
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Faster / more effective healing Biodegradability Nanofibre structures match tissue structures cells grow as in natural environment Hospital personnel protection against infection higher efficiency than traditional materials Much smaller amount of drug required for the same medical effect
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The small pores doesnt allow the microbes to penetrate the dressing and infect wounds better healing, in contrast to normal wound dressings
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Bioactive glass is used to regenerate bone tissue. The laser spinning makes the material flexible, continuous and gives it a nanometric structure, which helps in the proliferation and spread of bone cells.
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Polymer nanofibre membrane capture chemical warfare agents. The nanofibres act as a substrate on which the nerve agents get physically adsorbed followed by chemical decomposition.
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Science and Engineering of Polymer Nanofibres, Ramakrishna, et al., American Scientific Publishers. Nanofibres : Technology and Applications, O. Jirsak. Electrospun Nanofibres, Christopher Calvin Call. Electrospinning http://en.wikipedia.org/wiki/Electrospinnin g
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