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T LUYN THI I HC S 04 MN: HA HC

Thi gian lm bi: 90 pht I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho cc nguyn t: 1H; 3Li; 11Na; 7N; 8O; 9F; 2He; 10Ne; 16S, 6C. S nguyn t c nguyn t ch cha 1 electron c thn l: A. 4. B. 3. C. 2. D. 5. Cu 2: Hn hp X gm mt ankan v mt anken. Cho X tc dng vi 4,704 lt H 2 (ktc) cho n phn ng hon ton thu c hn hp Y gm hai kh trong c H2 d v mt hirocacbon. t chy hon ton Y ri cho sn phm vo nc vi trong d thy khi lng bnh ng nc vi trong tng 16,2 gam v c 18 gam kt ta to thnh. Cng thc ca hai hirocacbon l: A. C2H6 v C2H4. B. C2H8 v C3H6. C. C4H10 v C4H8. D. C5H10 v C5H12. Cu 3: im ging nhau gia lin kt kim loi v lin kt ion l: A. u c to thnh nh cp electron dng chung. B. u c to thnh bng lc ht tnh in gia ion dng v cc electron t do. C. u c to thnh bng lc ht tnh in gia cc nguyn t v ion mang in tch tri du. D. u c to thnh bng lc ht tnh in gia cc tiu phn mang in tch tri du. Cu 4: Cho 3,76 gam hn hp X gm Mg v MgO (c t l mol tng ng l 14:1) tc dng ht vi dung dch HNO3 thu c 0,448 lt mt kh duy nht (ktc) v dung dch Y. C cn cn thn Y thu c 23 gam cht rn khan. S mol HNO3 phn ng l: A. 0,32. B. 0,36. C. 0,28. D. 0,34. Cu 5: Cho cc cht: NaOH, Fe2O3, K2SO4, CuCl2, CO2, Al v NH4Cl. S cp cht c phn ng vi nhau l: A. 5. B. 6. C. 7. D. 8. Cu 6: Tin hnh phn ng nhit phn hn hp X gm butan v heptan (t l mol 1:2) th thu c hn hp Y c t khi so vi H2 l a (gi s ch xy ra phn ng crackinh to thnh ankan v anken vi hiu sut 100%). Kt lun no di y l ng? A. 12,9 a 21,5. B. a = 21,5. C. 16 a 21,5. D. 12,9 a 16. Cu 7: Hp cht X l dn xut ca benzen c cng thc C8H10O2. X tc dng NaOH theo t l mol 1:1. Mt khc, khi cho X tc dng vi Na th s mol H2 thu c ng bng s mol X phn ng. Nu tch 1 phn t nc t X th thu c sn phm c kh nng trng hp to polime. S cng thc cu to ph hp ca X l: A. 6. B. 9. C. 7. D. 2. Cu 8: Cho s phn ng: (X) (A) (B) (C) (D) P.V.A (polivinylaxetat). Cng thc cu to ph hp ca X l : A. CH3 C CH. B. CH3 C C CH3. C. CH3 CH2 C C CH3. D. C A, B, C u c th ng. Cu 9: Cho dung dch Ba(HCO3)2 ln lt tc dng vi cc dung dch sau: NaOH, NaHSO 4, HCl, KHCO3, K2CO3, H2SO4. S trng hp xy ra phn ng v s trng hp c kt ta l: A. 5 v 4. B. 5 v 2. C. 4 v 4. D. 6 v 5. Cu 10: Hiro ho hon ton mt hirocacbon khng no, mch h X thu c ankan Y. t chy hon ton Y thu c 6,6 gam CO2 v 3,24 gam H2O. Clo ho Y (theo t l 1:1 v s mol) thu c 4 dn xut monoclo l ng phn ca nhau. S cng thc cu to ca X tho mn l: A. 4. B. 5. C. 7. D. 6. Cu 11: ng dng no di y khng phi ca glucoz? A. Trng gng, trng rut phch. B. Lm thc phm dinh dng v thuc tng lc. C. Nguyn liu sn xut ancol etylic. D. Nguyn liu sn xut PVC. Cu 12: Cho cc dung dch sau: NaNO3, NH3, HNO3, FeCl2, AgNO3, Fe(NO3)3, hn hp HCl v NaNO3. S dung dch c th ho tan c bt Cu l:
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A. 6. B. 4. C. 5. D. 7. Cu 13: Cho x mol Mg vo dung dch cha a mol Cu(NO3)2 v b mol AgNO3. Mun dung dch thu c ch cha mt mui duy nht th gi tr ca x ti thiu l: a b A. b + B. 2b + a C. a + D. b + 2a 2 2 Cu 14: Cht X c cng thc phn t C4H4O v c cc tnh cht sau: - Tc dng vi AgNO3 trong dung dch NH3 to ra hai cht kt ta. - Tc dng vi Br2 (trong dung dch) theo t l mol ti a 1:3. Cng thc ca X l A. CH2=C=CH-CHO. B. CH C-CO-CH3. C. CH3-C C-CHO. D. CH C-CH2-CHO. Cu 15: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ha 100 ml dung dch X cn dng 200 ml dung dch NaOH 0,15M. Thnh phn phn trm v khi lng nguyn t lu hunh trong oleum trn l: A. 32,65%. B. 35,96%. C. 37,86%. D. 23,97%. Cu 16: ng dng no sau y khng phi ca amin? A. Cng nghip nhum. B. Cng nghip dc. C. Cng nghip tng hp hu c. D. Cng nghip giy. Cu 17: Cho t t 150 ml dung dch HCl 1M vo 200 ml dung dch X gm Na2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH) 2 d th thu c 29,55 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch X ln lt l: A. 0,525M v 0,8M. B. 0,5M v 1,0M. C. 0,525M v 0,45M. D. 2,0M v 0,65M. Cu 18: Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3-COOCH=CH2. C bao nhiu cht khi tc dng vi dung dch NaOH c, d, nhit v p sut cao cho sn phm c 2 mui? A. 3. B. 4. C. 5. D. 6. Cu 19: Hp cht hu c X c cng thc phn t C4H14O3N2. Cho X tc dng vi dung dch NaOH th thu c 2 cht kh iu kin thng u c kh nng lm xanh giy qu m. S cng thc cu to ph hp ca X l: A. 4. B. 5. C. 3. D. 2. Cu 20:
2

: A. . B. . C. . D. . Cu 21: Mnh no di y l ng : A. in phn dung dch NaF c mng ngn thu c kh flo. B. Cho hn hp NaF, NaCl vo dd AgNO3 th thu c 2 kt ta. C. Hn hp CaF2 + H2SO4 ho tan c thu tinh. D. HF c tnh axit mnh hn HCl. Cu 22: Trong cng nghip, ngi ta iu ch HNO3 theo s sau: NH3 NO NO2 HNO3 . Bit hiu sut chung ca ton b qu trnh l 70%. T 22,4 lt NH3 (ktc) iu ch c khi lng HNO3 l: A. 22,05 gam. B. 44,1 gam C. 63,0 gam. D. 31,5 gam. Cu 23: Cho m gam hn hp M gm 2 axit X, Y (Y nhiu hn X 1 nhm COOH) phn ng ht vi dung dch NaOH to ra (m + 8,8) gam mui. Nu cho ton b lng M trn tc dng vi lng d dung dch AgNO3/NH3, sau phn ng thu c 43,2 gam Ag v 13,8 gam mui amoni ca axit hu c. Cng thc ca Y v gi tr ca m ln lt l: A. HOOC-CH2-COOH v 30. B. HOOC-CH2-COOH v 19,6. C. HOOC-COOH v 18,2. D. HOOC-COOH v 27,2. Cu 24: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 30 gam kt ta. Vy gi tr ca V tng ng l:
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A. 8,40 lt. B. 6,72 lt. C. 5,60 lt. D. 8,96 lt. Cu 25: Cho cc cht v ion sau y: NO2-, Br2, F2, O2, SO2, N2, H2O2, HCl, S. S cht v ion c c tnh oxi ha v tnh kh l: A. 5. B. 7. C. 4. D. 6. Cu 26: Hn hp X gm Ag, Fe3O4, Cu, trong Ag chim 20% v s mol. ha tan ti a X (ch cn Ag khng tan) ta cn ti thiu 160 ml dung dch HCl 1M. Khi lng hn hp X l: A. 7,00 gam. B. 10,64 gam. C. 7,44 gam. D. 7,26 gam. Cu 27: Bit hiu sut chuyn ho etanol thnh buta1,3ien l 80% v hiu sut trng hp buta1,3 ien l 90%, khi lng ring ca etanol l 0,8 g/ml. sn xut 1 tn cao su buna cn th tch cn 96o (lit) l: A. 3081. B. 2957. C. 4536. D. 2563. Cu 28: Pht biu no sau y khng ng khi so snh tnh cht ha hc ca nhm v crom? A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui. B. Nhm c tnh kh mnh hn crom. C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. D. Nhm v crom u bn trong khng kh v trong nc. Cu 29: Cho 100 ml dung dch NaOH 1M vi 100 ml dung dch H3PO4 thu c dung dch X c cha 6,12 gam cht tan. Vy cc cht tan trong dung dch X l: A. Na2HPO4 v NaH2PO4. B. Na3PO4 v Na2HPO4. C. Na2HPO4 v H3PO4 d. D. NaOH d v Na3PO4. Cu 30: t chy hon ton a mol mt peptit X to thnh t aminoaxit no mch h (ch c 1 nhm COOH v 1 nhmNH2) thu c b mol CO2; c mol H2O v d mol N2. Bit b c = a. Thy phn hon ton 0,2 mol X bng dung dch NaOH (ly d gp i so vi lng cn thit) ri c cn dung dch sau phn ng th thu c cht rn c khi lng tng m gam so vi peptit ban u. Gi tr ca m l: A. 60,4. B. 76,4. C. 30,2. D. 38,2. Cu 31: Cho a gam bt Zn vo 200 ml dung dch X gm AgNO3 0,1M v Cu(NO3)2 0,15M th thu c 3,44 gam cht rn Y. Gi tr ca a l : A. 2,6 gam. B. 1,95 gam. C. 1,625 gam. D. 1,3 gam. Cu 32: Nh t t 3V1 ml dung dch Ba(OH)2 (dung dch X) vo V1 ml dung dch Al2(SO4)3 (dung dch Y) th phn ng va v ta thu c kt ta ln nht l m gam. Nu trn V2 ml dung dch X trn vo V1 ml dung dch Y th kt ta thu c c khi lng bng 0,9m gam. T l V2/V1 l: A. 2,7 hoc 3,55. B. 2,7 hoc 3,75. C. 2,5 hoc 3,25. D. 2,5 hoc 3,55. Cu 33: Nhit phn hon ton 25 gam hn hp X gm Cu(NO3)2, Fe(NO3)3, Mg(NO3)2 thu c 8,4 lt hn hp kh (ktc) v hn hp cht rn Y. Cho dung dch KOH d vo dung dch cha 25 gam X th thu c m gam kt ta. Gi tr ca m l: A. 10,65. B. 30,4. C. 11,5. D. 13,75. Cu 34: Cho cn bng N2 (k) + 3H2 (k) 2NH3 (k). Khi tng nhit th t khi ca hn hp kh so vi H2 gim. Pht biu ng v cn bng ny l: A. Phn ng nghch thu nhit, cn bng chuyn dch theo chiu thun khi tng nhit . B. Phn ng thun thu nhit, cn bng chuyn dch theo chiu thun khi tng nhit . C. Phn ng thun ta nhit, cn bng chuyn dch theo chiu nghch khi tng nhit . D. Phn ng nghch ta nhit, cn bng chuyn dch theo chiu nghch khi tng nhit . Cu 35: Cho cc cht sau: Al, ZnO, CH3COONH4, KHSO4, H2NCH2COOH, H2NCH2COONa, KHCO3, Pb(OH)2, ClH3NCH2COOH, HOOCCH2CH(NH2)COOH. S cht c tnh lng tnh l: A. 6. B. 8. C. 5. D. 7. Cu 36: X phng ha 265,2 kg cht bo c ch s axit bng 7 cn 56,84 kg dung dch NaOH 15%. Khi lng glixerol thu c l: A. 4,6 kg. B. 4,62 kg. C. 5,52 kg. D. 5,98 kg. Cu 37: Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l: A. 0,090 mol. B. 0,12 mol. C. 0,095 mol. D. 0,06 mol. Cu 38: Cho t t nc brom vo 3,333 gam hn hp gm phenol v stiren n khi ngng mt mu th ht 300 gam dung dch Br2 nng 3,2%. Phn trm khi lng ca phenol trong hn hp ban u l:
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A. 37,59%. B. 64,41%. C. 62,41%. D. 31,59%. Cu 39: Ha tan 86 gam hn hp BaCl2 v CaCl2 vo nc c 400 gam dung dch A. Cho A tc dng vi 500 ml dung dch Na2CO3 1,4M, sau phn ng thu c dung dch B v 79,4 gam kt ta. Nng phn trm ca cc mui trong dung dch A ln lt l: A. 4,45% v 17,05%. B. 20,8% v 5,55%. C. 2,37% v 31,95%. D. 10,4% v 11,1%. Cu 40:
2

25,2 gam H2

H2SO4 : A. 34,2. B. 27,36. C. 22,8. D. 18,24. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Trong qu trnh in phn, cc ion m di chuyn v A. cc m v b in cc kh. B. cc dng v b in cc kh. C. cc dng v b in cc oxi ho. D. cc m v b in cc oxi ho. Cu 42: C th dng H2SO4 c lm kh c cc kh: A. O2, H2, SO3. B. O2, H2, NO2, H2S, Cl2. C. N2, H2, SO2,CO2. D. Cl2, SO2, CO2, NO2, H2S. Cu 43: C 5 gi bt mu tng t nhau l ca cc cht CuO, FeO, MnO2, Ag2O, (Fe + FeO). C th dng dung dch no trong cc dung dch di y phn bit cc cht trn? A. HNO3. B. AgNO3. C. HCl. D. Ba(OH)2. Cu 44: Cng thc tng qut ca este to bi axit no n chc v ancol thm n chc (1 vng benzen) c dng: A. CnH2n6 (vi n 6, nguyn). C. CnH2n8O2 (vi n 7, nguyn). B. CnH2n4O2 (vi n 6, nguyn). D. CnH2n8O2 (vi n 8, nguyn). Cu 45: Cho m gam hp kim Pb Fe phn ng vi dung dch CuSO4, kt thc phn ng thu c (m 3) gam cht rn X. Trong X c cha: A. Cu, Pb, Fe. B. Cu, Fe. C. Cu, Pb. D. Pb, Fe. Cu 46: t chy hon ton 3,24 gam hn hp X gm hai cht hu c A, B trong B hn A mt nguyn t C, thu c H2O v 9,24 gam CO2. Bit t khi hi ca X so vi H2 l 13,5. Cng thc phn t ca A v B ln lt l: A. CH4, C2H4. B. CH2O, C2H2. C. CH4O, C2H2. D. CH4, C2H4O. Cu 47: Bc tr nn en khi tip xc vi khng kh c ln H2S. Nu lng Ag phn ng vi 0,100 mol th lng oxi tham gia phn ng ny bng: A. 0,025 mol. B. 0,075 mol. C. 0,050 mol. D. 0,100 mol. Cu 48: Ancol X no, mch h tc dng c vi Cu(OH)2 to dung dch mu xanh lam. Oxi ha hon ton X th s mol Oxi cn dng gp 5,5 ln s mol X. S cng thc cu to ph hp ca X l: A. 2. B. 4. C. 3. D. 5. Cu 49: Pht biu no di y l khng ng: A. H s trng hp l s lng n v mt xch monome trong phn t monome, c th xc nh mt cch chnh xc. B. Do phn t ln hoc rt ln nn nhiu polime khng tan hoc kh tan trong dung mi thng thng. C. Polime c dng mng li khng gian l dng polime chu nhit km nht. D. Thy tinh hu c l polime c dng mch thng. Cu 50: Khi un mt ancol X vi H2SO4 c 1700C, thu c 3 anken ng phn c cng thc C6H12. Khi hiro ho cc anken th u thu c 2-metyl pentan. Tn gi ca X l: A. 2-metyl pentan-3-ol. B. 2-metyl pentan-2-ol. C. 2-metyl pentan-1-ol. D. 4-metyl pentan-3-ol. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)

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Cu 51: Cho cc cp kim loi nguyn cht tip xc vi nhau trc tip: Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni; Fe v Cu. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hy trc l: A. 3. B. 5. C. 4. D. 2. Cu 52: Mt hn hp X gm mt axit no n chc v mt axit hu c khng no, n chc cha mt lin kt i C=C. Cho 16,8 gam hn hp X tc dng vi NaOH va thu c 22,3 gam hn hp mui. Mt khc, em t chy hon ton 16,8 gam hn hp X thu c 14,56 lt CO2 (ktc). CTCT ca hai axit trong hn hp X l: A. HCOOH v C2H3COOH. B. CH3COOH v C2H3COOH. C. C2H5COOH v C3H5COOH. D. HCOOH v C3H5COOH. Cu 53: Cho cc polime: PE, PVC, polibutaien, poliisopren, amiloz, amilopectin, xenluloz, cao su lu ho. Dy gm cc polime c cu trc mch thng l: A. PE, polibutaien, poliisopren, amiloz, xenluloz, cao su lu ho. B. PE, PVC, polibutaien, poliisopren, xenluloz, cao su lu ho. C. PE, PVC, polibutaien, poliisopren, amiloz, xenluloz . D. PE, PVC, polibutaien, poliisopren, amiloz, amilopectin, xenluloz. Cu 54: Nhm gm cc cht khi tc dng vi H2S cho sn phm cht rn l: A. Dung dch AlCl3, dung dch FeCl3, dung dch Cu(NO3)2, dung dch FeCl2. B. dung dch MgSO4, dung dch KCl, dung dch HCl, dung dch Pb(NO3)2. C. Dung dch Pb(NO3)2, kh Cl2, kh SO2, kh O2. D. Dung dch FeCl3, kh O2, kh N2, kh Cl2. Cu 55: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3CHO, C2H5OH, CH3COOC2H5, C2H5COOCH3. B. CH3OH, C4H10, C2H5Cl, CH3CHO. C. CH3CHO, C6H12O6, C2H5OH, CH3COOC2H5. D. CH3OH, C4H10, C2H5OH, CH3CHO. Cu 56: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l: A. 36,6 gam. B. 38,92 gam. C. 38,61 gam. D. 35,4 gam. Cu 57: Th nghim no sau y khng thu c kt ta sau khi phn ng kt thc: A. Cho dung dch CH3NH3 n d vo dung dch Al(NO3)3. B. Nh dung dch NH3 n d vo dung dch ZnCl2. C. Cho kh CO2 li vo dung dch Na[Al(OH)4] (hoc NaAlO2) cho n d. D. Nh dung dch NH3 n d vo dung dch AlCl3. Cu 58: t chy hon ton 19,03 gam hn hp X gm Ni, Sn ta thu c 24,15 gam hn hp cht rn. Nu cho 19,03 gam hn hp X vo dung dch HCl d th sau khi phn ng kt thc thu c V lt kh (ktc). Gi tr ca V l (Cho Sn = 119 , Ni = 59 ): A. 7,168. B. 7,392. C. 3,808. D. 4,032. Cu 59: Cho phng trnh ha hc: FeO + HNO3 Fe(NO3)3 + NxOy + H2O. Sau khi cn bng phng trnh ha hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l: A. 16x 6y. B. 8x 3y. C. 16x 5y. D. 10x 4y. Cu 60: Cho 15 gam fomalin tc dng hon ton vi lng d Cu(OH)2 trong dung dch NaOH thu c 54,72 gam kt ta gch. Nng phn trm ca cht tan trong fomalin ni trn l: A. 40%. B. 35%. C. 38%. D. 39%.
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