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SAMPLE EU SAFETY DATA SHEET_EN

according to Regulation (EC) No 1907/2006 (REACH) Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 21 Product Code: FCSB No.3 Prepared Date: 07/02/2012 Version: 1.00 Printing Date: 07/ 03/2012 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 1.1.1 1.1.2 1.1.3 1.2 1.2.1 1.2.2 1.3 1.3.1 1.3.2 Identification of the substance or mixture Mixture name : Fendell Cleaning Solvent Blend No. 3 Product/SDS Code : FCSB No. 3 Product description : Mixture of solvents. Uses of the mixture and uses advised against Uses of the mixture : Flushing of proprietary filling equipments. Uses advised against : For industrial use only. Not for home use. Company Identification Manufacturer/Supplier Contact information Street address

: Sao Boso Chemical Company, Ltd. : Fendell Industrial Park 3729 Bensonville Hwy, # A-1 Any town, Our State, 12345-6789 U.S.A : 1-(877)-ABC-EFGH : 1-(877)-ABC-EFKL : Info@Saobosochemco.com : CHEMTREC: 1-800-424-9300 (USA) Poison Control Center: 1-800-222-1222 (USA) National Response Center: 1-800-424-8802 (USA) : Product Steward Monday to Friday: 6 am - 6 pm (Pacific Time)

Telephone number Telefax number 1.3.3 1.4 E-mail of contact person Emergency telephone number (s)

1.4.1

Further information obtainable from

2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Product definition 2.1.1 : Mixture.

Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Flammable liquids, Category 2, Acute toxicity (dermal), Category 4, Acute toxicity (inhalation), Category 4, Acute toxicity (oral), Category 4, Aspiration hazard, Category 1, Skin corrosion/irritation, Category 2, Serious eye damage/Eye irritation, Category 1, H225 H312 H332 H302 H304 H315 H318

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No. 3 Version: 1.00 Reproductive toxicity D, Category 2, Specific Target Organ Toxicity Single exposure: Respiratory tract irritation, Category 3, Specific Target Organ Toxicity Single exposure: Narcotic effects, Category 3, Specific Target Organ Toxicity Repeated exposure, Category 2, 2.1.2 H361d H335 H336 H373

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Classification of the mixture according to European Directives 1999/45/EC or 67/548/EEC Highly flammable liquid and vapour. Irritating to eyes and respiratory tract. Harmful by inhalation, in contact with skin and if swallowed. Risk Phrases: (R-) 10, 11, 20/21, 22, 36, 37/38, 38, 41, 48/20, 63, 65, 66, 67 Safety Phrases: (S-) 2, 7, 7/9, 9, 13, 16, 24/25, 25, 26, 36/37, 37/39, 46, 62 Hazard symbol(s) F Xi Xn

: Flammable. : Irritant. : Harmful.

2.1.3

Additional Information See section 16. Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS] Product identifier: Hazard components for labeling: Hazard Pictograms Mixture 3-Butanone, n-Butanol, Toluene, Xylene

2.2 2.2.1

Signal word: Hazard statement(s) H225 H302 H304 H312 H315 H318

Danger

: Highly flammable liquid and vapour. : Harmful if swallowed. : May be fatal if swallowed and enters airways. : Harmful in contact with skin. : Causes skin irritation. : Cause serious eye damage.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 H332 H335 H336 H361d H373 Precautionary statement(s) P210 P233 P261 P264 P280 P310 P403 + P233 P501 2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII Other hazards which do not result in classification

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: Harmful if inhaled. : May cause respiratory irritation. : May cause drowsiness or dizziness. : Suspected of damaging the unborn child. : May cause damage to organ(s) through prolonged or repeated exposure : Keep away from heat/sparks/open flames/hot surfaces No smoking. : Keep container tightly closed. : Avoid breathing dust/fume/gas/mist/vapours/spray. : Wash hands with soap and plenty of water after handling. : Wear protective gloves/protective clothing/eye protection/face protection. : Immediately call a POISON CENTER or doctor/physician. : Store in a well-ventilated place. Keep container tightly closed. : Dispose of contents/container to be in accordance with local/regional/national regulations. : No. : P: Not available. B: Not available. T: No.

: Not available.

: Repeated exposure may cause skin dryness or cracking.

This product is classified as dangerous according to Directive 1999/45/EC and its amendments. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of the substance/mixture : Mixture of solvents.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Hazardous ingredients

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Classification
Chemical/ Substance Name 3-Butanone CAS No. EC No. Index No. RRN* Weight (%)

78-93-3

201-159-0

606-002-00-3

40 60

n-Butanol

71-36-3

200-7516

603-004-006

30 60

Ethanol

64-17-5

200-5786
200-661-7

603-002-005
603-117-00-0

10 40

Regulation (EC) No. 1272/2008[ CLP] F; R11 Flam. Liq. 2, Xi; R36-66-67 H225 Eye irrit. 2, H319 STOT SE 3, H336 EUH066 R10 Flam. Liq. 3, Xn; R22 H226 Xi; R37/38, Acute Tox. 4* H302 R41, R67 STOT SE 3 H335 Skin Irrit. 2 H315 Eye Dam. 1 H318 STOT SE 3 H336 F; R11 Flam. Liq. 2 H225 F, R11 Xi; R36, R67 Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H336 Flam. Liq. 2 H225 Repr. 2 H361d*** Asp. Tox. 1 H304 STOT RE 2 H373** Skin Irrit. 2 H315 STOT SE 3 H336

67/548/EEC

Type

[1] [2]

[1] [2]

[2]

Isopropanol 67-63-0

10 20

[1] [2]

Toluene

108-88-3

203-625-9

601-021-00-3

15

F; R11 Repr. Cat. 3 R63 Xn; R48/20, R65 Xi; R38, R67

[1] [2]

Table continued on next page.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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Chemical/ CAS No. Substance Name

EC No.

Index No.

RRN* Weight (%) 67/548/EEC

Xylene

1330-20-7

215-535-7

601-022-00-9

15

R10 Xi; R38

Regulation (EC) Type No. 1272/2008[ CLP] [1] Flam. Liq. 3 H226 Acute Tox. 4* [2] H332 Acute Tox. 4* H312 Skin Irrit. 2 H315 See Section 2 for the full text of the Hstatements declared above.

See Section 16 for the full text of the Rphrases declared above.
*

RRN: REACH Registration Number.

3.2

Additional information [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII Occupational exposure limits, if available, are listed in Section 8.

4. FIRST AID MEASURES 4.1 4.1.1 Description of first aid measures General information : General first aid measures should be followed. In case of persistent adverse effects, seek immediate medical attention. Remove contaminated clothing and shoes promptly, and wash thoroughly before re-use. : NOTE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. : Emergency responders should use positive air supplied respiratory protection when removing the victim from area.

4.1.2

Following inhalation

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00

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Remove person to fresh air. If not breathing, administer CPR until help arrives, or the victim starts to breathe on their own. Give artificial respiration if breathing has stopped. Seek medical attention immediately. 4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area thoroughly with water for at least 15 minutes. Use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Wash clothing before re-use. If irritation persists, seek medical attention. : Immediately flush affected eye with water for at least 20 minutes. ilt the head to prevent chemical from transferring to the unaffected eye. Seek medical attention without delay after flushing. : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out with water. Dilute with milk or water. Never give anything to drink if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center at once. : Appropriate personal protective attire should be worn. : Suitable medical intervention should be provided based on symptoms. : Irritating to eyes, skin, and respiratory tract upon exposure. High vapour concentrations are irritating to eyes, nose, throat, and lungs; may cause unconsciousness or other signs of central nervous system depression. Frequent or prolonged skin contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi (bronchopneumonia). Ingestion may cause irritation of digestive track and diarrhea. : Always get immediate medical attention/advice when symptoms persist.

4.1.4

Following eye contact

4.1.5

Following ingestion

4.1.6 4.1.7

Self protection of the first aider Note to the doctor

4.2

Most important symptoms and effects, both acute and delayed

4.3

Indication of any immediate medical attention and special treatment needed

5. FIRE FIGHTING MEASURES

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Fire Fighting Measures

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: The following applies to 3-Butanone FLASHPOINT: 26oF SPECIFC GRAVITY: 0.806 @ 68o F EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%. AUTOIGNITION TEMPERATURE: 961.0oF.

5.1

Extinguishing media Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or extinguish with alcohol type or all purpose type foam, or dry chemical powder. Try to cover liquid spills with appropriate foam. Use water spray to cool fire exposed surfaces. Avoid spraying water directly into storage containers due to danger of boilover. Shut off fuel to fire if possible to do so without hazard. If a spill has not ignited, use water spray to disperse the vapours. : Do not use high volume water jet. : Flammable liquid; may release vapours that form flammable mixtures when temperatures are at or above the flash point. There is a danger of explosion when container is heated or in fire. Toxic gases will form upon combustion. Vapour may may accumulate in low or confined areas or travel to a considerable distance to a source of ignition and flash back. Avoid runoff into storm sewers and ditches. : Smoke, fumes, oxides of carbon, irritating or toxic vapours or gases.

Unsuitable extinguishing media 5.2 Special hazards arising from the mixture

Hazardous combustion products

5.3

Advice for fire-fighters Protective equipment for fire fighters : Respiratory and eye protection gear is required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Exposure to decomposition products may cause health hazards. Cool containers exposed to fire with water spray. Move unexposed containers from fire area if this can be done without risk.

5.4

Additional information

6. ACCIDENTAL RELEASE MEASURES 6.1 6.1.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel :

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Protective equipment

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: Wear suitable personal protective equipment (e.g. clothing, gloves, safety goggles, and mask/respirator). Ensure adequate ventilation; remove all sources of ignition. Notify the appropriate authorities immediately. : Eliminate ignition source. Shut off leak if safe to do so. Take all additional action necessary to prevent and remedy the adverse effects of the spill. Isolate hazard area and deny entry to unauthorized or unprotected personnel. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as saw dust. Absorb spill with an inert material (e.g., sand or earth). Then place in a chemical waste container. : Respiratory and eye protection gear is required for emergency responders. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Avoid dispersal of spilt material and runoff into soil, storm sewers and ditches which lead to natural waterways, or the immediate environment. Inform the relevant authorities if the product has entered into the environment.

Emergency procedures

6.1.2

For emergency responders personal protective equipment

6.2

Environmental precautions

6.2 6.3.1

Methods of containment and cleaning up On water : If spill in water, remove from water surface by skimming or with suitable absorbent material and place in appropriate disposal container. If allowed by local environmental regulatory agencies, you may use a suitable dispersant. : Contain spill and absorb with an inert material (e.g., dry sand or earth). Then place in an appropriate waste container for disposal according to local regulations. Large spills should be disposed of via a licensed waste disposal establishment/contractor. : Contaminated absorbent material may pose similar hazard as the spill product.

6.3.2 On ground/floor

6.3.3 6.4

Other information

Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personnel protective equipment. See Section 13 for additional disposal information.

7. HANDLING AND STORAGE 7.1 Precautions for safe handling

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 7.1.1 Protective measures

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: Wear appropriate personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapour or mist. Do not eat, drink, or smoke when using this product. Use only with adequate ventilation. Keep away from sources of ignition. Keep only in original container. Keep tightly closed when not in use. Do not reuse container. Avoid release to the environment. : Avoid eating, drinking and smoking in areas where this product is handled, used and stored. Wash hands before eating, drinking and smoking, and at the end of the working period. Contaminated work clothing and protective equipment should not be brought into eating, smoking and drinking areas. Wash soiled clothing before re-using.

7.1.2

Advice on general occupational hygiene

7.2

Conditions for safe storage, including any incompatibilities Technical measures and storage conditions : Store at ambient/room temperature. Protect from extreme cold and heat. Store in a segregated and approved area. Store away from strong oxidizing agents. Loosen closure cautiously with non-sparking tools before opening. Keep only in original container. Store and use away from sparks, heat, open flames and other ignition sources. Ground and bond containers and receiving equipment. Store locked up. Store away from direct sun -light in a dry, cool and well-ventilated area. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Ground and bond containers when transferring material. Ventilation required along storage floor. : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic bottles and containers. : For industrial use only. : Not available.

Packaging materials 7.3 Specific end use(s) Recommendations Industrial sector specific solutions

8. EXPOSURE CONTROL/PERSONAL PROTECTION There is no workplace exposure data available on the product itself. Data for a solvent in the mixture is provided for EU member countries where available. 8.1 8.1.1 Control parameters Occupational Exposure Limits (OELs) :

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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Workplace Occupational Exposure Limit(s) -OELs EC No.: 201-159-0 Occupational Exposure Limit Values CAS No.: 78-93-3 (3-Butanone) Chemical Name: Limit value type Long term limit Short term limit 3-Butanone (8-hour TWA) (15-minutes period) Country ppm mg/m3 ppm mg/m3 Austria 100 295 200 590 MAK Belgium 200 600 300 900 VLEP Bulgaria 590 1000 OEL (MH Decree No 13/2003) Croatia 200 600 300 900 EU OEL (TWA/STEL) Czech Republic 203.4 600 305.1 900 PEL, NPK-P Denmark 50 145 100 290 OEL Estonia 200 600 300 900 EU OEL (TWA/STEL) Finland 100 300 OEL (HTP-arvot) France 200 600 300 900 VLEs Germany 200 600 200 600 MAK Greece 200 600 300 900 EU OEL Hungary 600 900 K, CK Ireland 200 600 300 900 OELV (NAOSH, 8/2007) Italy 200 600 300 900 ACGIH Latvia 67 200 300 900 AER Lithuania 200 600 300 900 IPRV, TPRV Netherlands 590 900 MAC-TGG Norway 75 220 Gjennomsnittsverdier (average values) Poland 450 900 NDS, NDSCh Portugal 200 300 VLE-MP, VLE-CD Romania 63 200 101 300 VLA (TWA, STEL) Slovakia 200 600 900 NPEL Spain 200 600 300 900 VLA-ED, VLA-EC Sweden 50 150 100 300 NGV, KTV Switzerland 200 590 200 590 VME, VLE Turkey 200 600 300 900 TWA, STEL United Kingdom 200 600 300 899 WEL (EH40/2005) Note: Users should refer to the literature for OELs data on other components of this product. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation of chemical agents and national guidance documents for methods for the determination of hazardous substances.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Derived effect levels [DNEL] Predicted effect concentrations (PNEC Summary) 8.1 8.1.1 Exposure controls Appropriate engineering controls

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: See occupational exposure limits table for guidance. : Not available.

: Provide adequate local exhaust ventilation to maintain worker below exposure limits. The use of mechanical ventilation controls is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Use explosion-proof ventilation equipment. (http://www.chemie.de/tools/gebotszeichen/) (93/68/EEC, 93/95/EEC, and 96/58/EC) : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mist, or dust. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this in necessary. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use approved respiratory protection equipment. Respirator selection should be based on the form and concentration of contaminants in the air and in accordance with local regulations. : Emission from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Ensure that emission is at the acceptable level.

8.2

Personal protective equipment (Directives and Amendments) Eye and face protection

8.2.1

8.2.2

Skin protection Hand protection

Body protection

Other skin protection

8.3

Respiratory protection

8.4

Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on physical and chemical properties Physical state : Liquid. Colour : Characteristic. Odour : Solvent odour.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Odour threshold pH Melting/freezing point [o F] Initial boiling point/range [o F] Flash point [o F] Evaporation rate (n-Butyl Acetate = 1) Flammability (solid, gas) Upper flammability Lower flammability Vapour pressure, mm Hg @ 75 o F Vapour density (Air = 1) Relative density Solubility in water, Wt % @ 68 o F Partition coefficient: nOctanol/water Auto-ignition temperature Decomposition temperature Viscosity of Liquid, CST @ 25o C Explosive properties Oxidizing properties 9.2 Other information : Not determined. : Not available . : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available . : Not available. : Not available. : Not available. : Not available. : Not applicable. : Not available. : Not available. : Not available. : Mixture has not been tested.

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10. STABILITY AND REACTIVITY 10.1 Reactivity : Highly flammable. Avoid ignition sources. Strong oxidizing agents. : Stable under normal conditions. : Hazardous polymerization will not occur. : Open flames and sources of ignition. : Strong oxidizing agents.

10.2 10.3 10.4 10.5 10.6

Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials

Hazardous decomposition products : Burning can produce oxides of carbon.

11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects : There are no data available on the product itself. Data on a substance in the mixture is provided. : Relevant effects:

11.1.2 Mixture

11.1.2.1

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 (a) Acute toxicity Substance name:

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: Exposure Remark Test Species Route of Administration Dose/Result LD50 Rat Oral > 636 mg/kg Toluene 50 mg/kg LDLO Human Oral Identifiers: LC50 Mouse Inhalation vapour 6405 -7436 ppm 6 hour (s) TCLO Human Inhalation vapour 200 ppm EC No.: 203-625-9 LD50 Rabbit Dermal 12124 mg/kg CAS No.: 108-88-3 LD50 Mouse Intra-peritoneum (i.p.) 66 mg/kg Index No.: 601-021-00-3 LD50 Rat Intra venous (i.v.) 1960 mg/kg LC50 Rat Inhalation vapour 28.1 mg/l 4 hour (s) Conclusion/Summary : Vapours may cause drowsiness and dizziness. Refer to the literature for toxicology data on other components of this product. (b) Irritation Inhalation : May cause irritation to the nose, throat, and lungs. High vapor concentrations may cause unconsciousness or other signs of central nervous system depression. Skin contact : Frequent or prolonged contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. : Severely irritating. If not removed promptly will injure eye tissue, which may result in permanent damage. : May cause irritation of the digestive tract and diarrhea. : Severely irritating to eyes. Repeated exposure may cause skin dryness or cracking. : May cause skin sensitization and or respiratory system irritation due to extended exposure of the preparation above stated occupational exposure limits. : No data available. : No data available. : No known significant effects or critical hazards. : No information but adverse effects unlikely. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Eye contact

Ingestion (c) Corrosivity

(d)

Sensitization

(e) (f) (g) (h) (i)

Single dose toxicity Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction

11.1.2.2 CMR effects (carcinogenic, mutagenic or toxic for reproduction)

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 11.2 Potential adverse health effects

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: Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs ( pulmonary edema) and infection of the bronchi(bronchopneumonia). Ingestion may cause irritation to the digestive tract or diarrhea. : There is no evidence that exposure to 3-Butanone alone causes progressive or irreversible neurotoxic effects. However, simultaneous over-exposure to 3-Butanone and n-Hexane can potentiate the known irreversible neurotoxic effects of n-Hexane. There is no reported human evidence that these neurotoxic effects occur when exposure to both chemicals is maintained below established regulatory limits. : The mixture is not likely to be carcinogen in humans.

11.3

Potential chronic health effects

11.4

Other information

12. ECOLOGICAL INFORMATION Note: Ecological testing has not been done on the product. Ecotoxicological information on components of this product is presented below. 12.1 Toxicity :

3-Butanone [CAS#: 78-93-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC3 n-Butanol [CAS#: 71-36-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Ethanol [CAS#: 64-17-5] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity LC50 Acute algae toxicity EC50 Isopropanol [CAS#: 67-63-0] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50

Exposure time (h) 96 hour (s) 48 hour (s) 7 days

Species Pimephales promelas Daphnia magna Scenedesmus quadricauda

Value (mg/l) 3220 > 520 4300

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) < 1630 1983 > 500

Exposure time (h) 96 hour (s) 48 hour (s) Not specified

Species Alburnus alburnus Daphnia magna Chlorella pyrenoidosa

Value (mg/l) 10000 - 11500 9268 - 14221 9310

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 9640 13299 > 1000

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Toluene [CAS#: 108-88-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Xylene [CAS #: 1330-20-7] Aquatic toxicity Acute fish toxicity Acute invertebrate toxicity Acute algae toxicity 12.2

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Exposure time (h) 96 hour (s) 48 hour (s) 48 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 28 11.5 125 - 160

Effect dose LC50 LC50 Mortality

Exposure time (h) 96 hour (s) 48 hour (s) Unknown

Species Cyprinus carpio Palaemonetes pugio Scenedesmus quadricauda

Value (mg/l) > 780 0.85 > 200

Persistence and degradability

: No data available for this product.

(Biochemical Oxygen Demand BOD values) Substance name Quantity Degradation rate (%) 3-Butanone Unknown 83 n-Butanol Unknown 66 Ethanol 10 mg/l 74 Isopropanol 10 mg/l 78* Toluene Unknown Completely Xylene Isomers 72 * Theoretical Oxygen Demand (ThOD) value. 12.3

Incubation time 5 days 5 days 5 days 20 days Short duration 20 days

Evaluation (inoculum) Sewage Sewage sludge Filtered sewage seed Filtered sewage seed Sewage seed Activated sewage

Bioaccumulative potential : No data available for this product. (BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate Substance name Estimated BCF log Kow Remarks 3-Butanone 3 0.29 Low bioaccumulation n-Butanol 3 0.88 Low bioaccumulation Ethanol 3 -0.31 Low bioaccumulation Isopropanol 3 0.05 Low bioaccumulation Toluene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation Xylene 6 23.4 3.2 Low bioaccumulation Mobility in soil : No data available for this product.

12.4

Koc The soil absorption coefficient Substance name Koc value 3-Butanone 29 n-Butanol 72 Ethanol 1 Isopropanol 25 Toluene variable Xylene 39 365 for individual isomers

Remarks (soil mobility) Very high mobility High mobility Very high mobility Very high mobility High to moderate mobility Very high to moderate mobility

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 12.5 Results of PBT and vPvB assessment PBT : No data available. vPvB : No data available. Other adverse effects

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12.6

: No known significant effects or critical hazards.

13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Methods of disposal

: The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Waste product residue should not be disposed of via the foul sewer. Consult an expert on the disposal of recovered and surplus material. Incinerate, or recover by distillation. Ensure disposal is in compliance with current government requirements and ensure conformity with local authority regulations. : The generation of waste should be avoided or minimized whenever possible. Waste packaging should be recycled, or dispose of according to state and local authority regulations. Consult your State/Local Land Waste Management Authority. : 08 03 99* 15 01 01 15 01 02 : waste not otherwise specified. : paper and cardboard packaging. : plastic packaging.

Packaging waste Methods of disposal

Waste codes/ waste designation according to EWC/AVV

: The listed waste numbers according to the European Waste Code (EWC) are intended as recommendation for users. The final classification has to be worked out together with the local waste disposal company/authority. Note: An asterisk [*] next to the a code (08 03 99*) indicates it is a hazardous waste. Special precautions : This material and its container must be disposed of according to local authority regulations. Empty containers or packaging may contain some product residue. Avoid dispersal of spilt material and runoff to come in contact with soil, waterways, drains and sewers.

14. TRANSPORTATION INFORMATION

Transportation information is provided on the next page.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 ADR/RID 1210 Printing Ink Related Material ADN/ADNR 1210 Printing Ink Related Material

Page 17 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012 IMDG ICAO-TI/IATA-DGR 1210 1210 Printing Ink Printing Ink Related Related Material Material

14.1 UN No. 14.2 Proper Shipping Name 14.3 Transport hazard class 14.4 Classification code 14.5 Packing group 14.6 Hazard label 14.7 Environmental hazard 14.8 Special provision(s) Additional Information

3 F1 II

3 F1 II

3 F1 II

3 F1 II

No 163 640C Hazard identification number 33 EAC 3Y Transport Category 2 Ltd. Qty LQ6 Excpt. Qty E2 Packaging P001, PP1, MP19 Portable Tanks and Bulk Cont. T4; TP1, TP8 Tunnel code D/E

No 163 640C -

Marine pollutant: No 163 Emergency schedules (EmS) Fire F-E Spillage S-D

No Not available Passenger and Cargo Aircraft Quantity limitation: 1.0L Packing instructions: Y341 353 5.0L

Ltd. Qty LQ6

Excpt. Qty. E2 -

Ltd. Qty 5l Excpt. Qty E2 -

Cargo Aircraft only Quantity limitation: 60.0 L

Packaging instruction: 364

14.9

Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 15. REGULATORY INFORMATION 15.1

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Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) REACH Status : In compliance.

Annex XIV List of substances subject to authorization Substances of Very High Concern Candidate List : None of the components in the mixture are listed. Annex XVII Restriction on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles : : Contains Toluene (Note: product is not for sale to the general public and is not intended for use in adhesives and spray paints.) Other EU regulations European inventory Endocrine Disrupters

: All components are listed or exempt. : Components not listed (http://www.chemsec.org/list/sin-list-20) [EU Directive 2000/60/EC, Annex X and Regulation (EEC) No. 793/93] : Components not listed.

Integrated Pollution Prevention and Control List (IPPC) Air Integrated Pollution Prevention and Control List (IPPC) Water International regulations

: Components not listed.

Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals Not listed Not listed Not listed

15.2

Chemical Safety Assessment : No Chemical Safety Assessment has been carried out for this product.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 16. OTHER INFORMATION NOTE

Page 19 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012

: This Safety Data Sheet was created as a guide, teaching aid and training tool for freelance safety data sheet writers. The mixture is fictitious and information in the document is based on suggestions in the Guidance on the Compilation of Safety Data Sheets. The document does not purport to be a legal advice on compiling EU safety data sheets. Guidance on the Compilation of Safety Data Sheets for the European Union is normative. : The product has been classified and marked in accordance with EU Directives/Ordinance on Hazardous Materials.

Product

16.1

Indication of changes Date of previous issue Revisions Nature of version Version Date of issue Prepared by

: : : : : :

No previous validation. To comply with Regulation (EC) No 1272/2008 [CLP/GHS] Conforms to Regulation (EC) 1907/2006 (REACH) 1.00 July 03, 2012 Theodore M. Amet, Regulatory Research Analyst.

16.2

Abbreviations and acronyms ADN: Accord europen relative au transport international des marchandises dangereuses par voie de navigation intrieure. ADNR: Accord europen relative au transport international des marchandises dangereuses par marine sur le Rhin ADR: Accord europen sur le transport des merchandises dangereuses par route (European Agreement concerning the International Carriage of Dangerous Goods by Road) AVV (Austria): Abfallverzeichnis-Verordnung BG RCI (Germany): Berufsgenossenschaft Rohstoffe und chemische Industrie CAS: Chemical Abstracts Service CDC: Centers for Disease Control and Prevention CLP: Regulation on the Classification, Labelling, and Packaging of substances and mixtures1 D/H: Danger/Hazard DGR: Dangerous Goods Regulation DPD: Dangerous Preparations Directive (Directive 1999/45/EC). DSD: Dangerous Substances Directive (Directive 67/548/EEC). EC: European Commission EHS: Environment, Health, and Safety CLP Document - REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December, 2008 on classification, labeling, and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC and amending Regulation (EC) No 1907/2006.
1

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00

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EINECS: European Inventory of Existing Commercial chemicals Substances EmS: Emergency Schedule ESIS: Existing chemical Substances Information System EU: European Union GHS: Globally Harmonized System of Classification and Labelling of Chemicals HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer IATA: International Air Transport Association ICAO: International Civil Aviation Organization IBC Code: International Code for the Construction and equipment of Ships Carrying Dangerous Chemicals in Bulk IUCLID DB: International Uniform Chemical Information Database TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air 16.3 Full text of Risk and Hazard Phrases/Codes in Section 2 Risk (R)-phrase(s) R11 R20/21 R22 R36 R37/38 R38 R41 R48/20 R63 R65 R66 R67 Safety (S)-phrase(s) S2 S7/9 S13 S16 S24/25 S26 S36/37 S37/39 S46 S62

: Highly flammable. : Harmful by inhalation and in contact with skin. : Harmful if swallowed. : Irritating to eyes. : Irritating to respiratory system and skin. : Irritating to skin. : Risk of serious damage to eyes. : Harmful: danger of serious damage to health by prolonged exposure through inhalation. : Possible risk of harm to the unborn child. : Harmful: may cause lung damage if swallowed. : Repeated exposure may cause skin dryness or cracking. : Vapours may cause drowsiness and dizziness.

: Keep out of the reach of children. : Keep container tightly closed and in a well ventilated place. : Keep away from food, drink and animal feedingstuff. : Keep away from sources of ignition No smoking. : Avoid contact with skin and eyes. : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : Wear suitable protective clothing and gloves. : Wear suitable gloves and eye/face protection. : If swallowed, seek medical advice immediately and show this container or label. : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00 16.3 Key literature references and sources of data :

Page 21 of 21 Prepared Date: 07/02/2012 Printing Date: 07/03/2012

ECHA (European Chemicals Agency) http://echa.europa.eu/ ESIS (Existing chemical Substances Information System) http://ecb.jrc.ec.europa.eu/esis/. GESTIS International Limit values Database http://www.dguv.de/ifa/en/gestis/limit_values/index.jsp Guidance for downstream users http://guidance.echa.europa.eu/docs/guidance_document/du_en.pdf Guidance on information requirements and chemical safety assessment, Chapter R.12: Use descriptor system http://guidance.echa.europa.eu/docs/guidance_document/information_requirements_r12_en.pdf Guidance on the compilation of safe data sheets http://guidance.echa.europa.eu/docs/draft_documents/draft_guidance_on_safety_data_sheets_20100324.pdf TOXNET: Toxicology Data Network. http://toxnet.nlm.nih.gov Information from technical literature Internet research Suppliers (Material) Safety Data Sheets. DISCLAIMER This guide was compiled as a service to freelance EU Safety Data Sheets writers. It neither reflects the views of others, nor does it endorse one link over the other. Internet links cited in this guide and views expressed in the various sections are mine alone. Information in this document is based on data gathered from many sites. No warranty is expressed regarding the accuracy of data obtained from various chemical, health, toxicological, and environmental databases. Responsibility for the accuracy and completeness of information contained herein rests with users who must satisfy themselves that the data is appropriate for their needs. It is always a good practice to consult a sectional expert when writing sections of the safety data sheets to clarify and simplify technical matters. END OF SAMPLE SAFETY DATA SHEET

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