SAMPLE CANADA (MATERIAL) SAFETY DATA SHEET_ENGLISH

Prepared to CPR-WHMIS and GHS Standards Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Page 1 of 20 Prepared Date: 07/02/2012 Printing Date: 07/ 07/2012

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 1.1.1 1.1.2 1.1.3 1.2 1.2.1 1.2.2 1.3 1.3.1 1.3.2 Identification of the substance or mixture Mixture name : Fendell Cleaning Solvent Blend No. 3 Product/SDS Code : FCSB No. 3 Product description : Mixture of solvents. Uses of the mixture and uses advised against Uses of the mixture : Flushing and cleaning of proprietary equipments. Uses advised against : For industrial use only. Not for home use. Company Identification Manufacturer/Supplier Contact information Street address

: Sao Boso Chemical Company, Ltd. : Fendell Industrial Park 3729 Bensonville Hwy, # A-1 Complex Any town, Our State, 12345-6789 U.S.A : 1-(877)-000-0000 (USA) : 1-(877)-000-0012 (USA) : Info@Saobosochemco.com : CANUTEC: 1-613-996-6666 (Canada) * 666 on a cellular phone. Poison Control Center: 1-800-268-9017 (ONTARIO)

Telephone number Fax number 1.3.3 1.4 E-mail of contact person Emergency telephone number (s)

1.4.1

Further information obtainable from : Regulatory Affairs Monday to Friday: 6 am - 6 pm (Pacific Time)

2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Product definition : Mixture of solvents. Emergency Overview : Flammable liquid and vapor. Irritating to eyes, skin, and respiratory tract. Harmful or fatal if swallowed, if inhaled, and in contact with skin. May be absorbed through intact skin. Avoid prolonged contact with skin. : WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL! Keep away from open flame, heat, and static discharge sources. Aspiration hazard if swallowed. Irritant and central nervous system depressant. High vapor concentrations are irritating to the nose, throat, and respiratory tract.

2.1.1

Potential Health Effects

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No. 3 Version: 1.00

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Avoid inhalation of vapor and contact with skin and eyes. May be harmful or if swallowed. Remove victim to fresh air if overcome with vapor/mist/fumes due to inhalation. If splashed in eyes, flush with water for 15 minutes. If in contact with skin, flush with water and wash with mild soap. In medical emergency, CALL A PHYSICIAN, OR POISON CONTROL CENTER (1-800-268-9017) IMMEDIATELY. Chronic Effects : No evidence of adverse effects from available information.

CONTACT CANUTEC 24 Hours/day (in the event of emergency involving dangerous goods). EMERGENCY : (613) 996-6666 (call collect) Cellular phone : * 666 FAX : (613) 954-5101 Note : Read product Safety Data Sheet completely and thoroughly before using this product. Classification according to WHMIS and GHS WHMIS Classification WHMIS Classes Class Definition Flammable and combustible material - Flammable liquid Class B-2 Poisonous and infectious material - Other effects Toxic Class D-2B Classification according to GHS GHS Classification Hazard Class Category Hazard Code Flam. Liq. 2 H225 Acute tox. (dermal) 4 H312 Acute tox. (inhalation) 4 H332 Acute tox. (oral) 4 H302 Aspiration hazard 1 H304 Skin corro./irrit. 2 H315 Serious eye dam./Eye irrit. 1 H318 Reprod. tox. D 2 H361d STOT SE: RTI STOT SE: NE STOT SE: RE Other Hazards Potential Hazards 3 3 2 H335 H336 H373 Hazard Statement Highly flammable liquid and vapor. Harmful in contact with skin. Harmful if inhaled. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye damage. Suspected of damaging fertility or the unborn Child. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through Prolonged or repeated exposure.

2.2

EUH066 Repeated exposure may cause skin dryness or cracking. : Highly flammable liquid and vapor. Irritating to eyes, skin, and respiratory tract. A component in the product may cause central nervous system effects. Such central nervous system effects can include drowsiness, headache, and dizziness. Repeated exposure may cause skin dryness or cracking.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Hazard symbol(s)/Indication of Danger F : Flammable. Xi : Irritant. : Harmful. Xn 2.3 2.3.1 Label Elements and Hazard Symbols [WHMIS and GHS] WHMIS Hazard Symbols

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2.3.2

GHS Hazard Symbols/ Label Elements Hazard Pictograms

Signal word: Hazard statement(s) H225 H302 H304 H312 H315 H318 H332 H335 H336 H361d H373 Precautionary statement(s) P210 P233 P261 P264 P280 P310 P403 + P233 P501

Danger

: Highly flammable liquid and vapor. : Harmful if swallowed. : May be fatal if swallowed and enters airways. : Harmful in contact with skin. : Causes skin irritation. : Cause serious eye damage. : Harmful if inhaled. : May cause respiratory irritation. : May cause drowsiness or dizziness. : Suspected of damaging fertility or the unborn child. : May cause damage to organ(s) through prolonged or repeated exposure. : Keep away from heat/sparks/open flames/hot surfaces No smoking. : Keep container tightly closed. : Avoid breathing dust/fume/gas/mist/vapors/spray. : Wash hands with soap and plenty of water after handling. : Wear protective gloves/protective clothing/eye protection/face protection. : Immediately call a POISON CENTER or doctor/physician. : Store in a well-ventilated place. Keep container tightly closed. : Dispose of contents/container to be in accordance with

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 local/regional/national regulations. 2.4 Other hazards Substance meets the criteria for PBT (Persistent, Bioaccumulative, and Toxic) Substance meets the criteria for vPvB (very Persistent and very Bioaccumulative) Other hazards which do not result in classification : No.

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: No.

: Repeated exposure may cause skin dryness or cracking.

This product is considered to be hazardous according to the Canadian Controlled Product Regulation. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of the substance/mixture HAZARDOUS COMPONENTS 3.1.1 WHMIS Classifications Ingredient/Chemical Name CAS No. Butan-2-one 78-93-3 Butan-1-ol Ethyl hydroxide Propan-2-ol Methylbenzene 71-36-3 64-17-5 67-63-0 108-88-3 : Mixture of solvents.

WHMIS Classes* B2 D2B B2 D2B B2 D2B B2 D2B B2 D2A D2B B2 D2A D2B

WHMIS Health Effects Criteria Eye irritation-toxic-other Eye/Skin irritation-toxic-other Eye irritation-toxic-other Eye irritation-toxic-other Teratogenicity and embryotoxicity very toxic other Skin irritation - toxic - other Teratogenicity and embryotoxicity very toxic other Skin irritation - toxic - other

Xylol

1330-20-7

*WHMIS Classification: B2 - Flammable and combustible material - Flammable liquid D2A - Poisonous and infectious material - Other effects - Very toxic D2B - Poisonous and infectious material - Other effects Toxic

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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3.1.2 GHS Classifications Type Component CAS No. EC No. Index No. UN No. Percent GHS Classification Butan-2-one 78-93-3 201-159-0 606-002-00-3 1193 40 - 60 Flam. Liq. 2, H225 [1] Eye Irrit. 2, H319 STOT SE 3, H336 [2] EUH066 Butan-1-ol 71-36-3 200-751-6 603-004-00-6 1120 30 - 60 Flam. Liq. 3, H226 [1] * Acute Tox. 4 , H302 STOT SE 3, H335 Skin Irrit. 2, H315 Eye Dam. 1, H318 [2] STOT SE 3, H336 Ethyl hydroxide 64-17-5 200-578-6 603-002-00-5 1987 10 - 40 Flam. Liq. 2, H225 [2] Propan-2-ol 67-63-0 200-661-7 603-117-00-0 1219 10 - 20 Flam. Liq. 2, H225 [1] Eye Irrit. 2, H319 STOT SE 3, H336 [2] Methylbenzene 108-88-3 203-625-9 601-021-00-3 1294 1 - 5 Flam. Liq. 2, H225 [1] Repr. 2, H361d*** Asp. Tox. 1, H304 STOT RE 2, H373** Skin Irrit. 2, H315 [2] STOT SE 3, H336 Xylol 1330-20-7 215-535-7 601-022-00-9 1307 1 - 5 Flam. Liq. 3, H226 [1] Acute Tox. 4*, H332 Acute Tox. 4*, H312 Skin Irrit. 2, H315 [2] Components in this product are not known or reported to be carcinogenic in humans by any reference source including US OSHA, IARC, US NTP, US ACGIH, or US EPA. 3.2 Additional information [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] Substance meets the criteria for PBT. [4] Substance meets the criteria for vPvB. Occupational exposure limits, if available, are listed in Section 8. See Section 2 for the full text of the H-codes declared above. 4. FIRST AID MEASURES 4.1 4.1.1 Description of first aid measures General information : General first aid measures should be followed. In case of persistent adverse effects, seek immediate medical attention. Remove contaminated clothing and shoes promptly, and wash thoroughly before re-use.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No.3 Version: 1.00 4.1.2 Following inhalation

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: NOTE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. : Emergency responders should use positive air supplied respiratory protection when removing the victim from area. Remove person to fresh air. If not breathing, administer CPR until help arrives, or the victim starts to breathe on their own. Give artificial respiration if breathing has stopped. Seek medical attention immediately.

4.1.3

Following skin contact

: If exposure occurs, immediately flush the affected area thoroughly with water for at least 15 minutes. Use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Wash clothing before re-use. If irritation persists, seek medical attention. : Immediately flush affected eye with water for at least 20 minutes. ilt the head to prevent chemical from transferring to the unaffected eye. Seek medical attention without delay after flushing. : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out with water. Dilute with milk or water. Never give anything to drink if the victim is unconscious or having convulsions. Seek medical attention immediately. Contact Poison Control Center at once. : Appropriate personal protective attire should be worn. : Suitable medical intervention should be provided based on symptoms. : Irritating to eyes, skin, and respiratory tract upon exposure. High vapour concentrations are irritating to eyes, nose, throat, and lungs; may cause unconsciousness or other signs of central nervous system depression. Frequent or prolonged skin contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi (bronchopneumonia). Ingestion may cause irritation of digestive track and diarrhea.

4.1.4

Following eye contact

4.1.5

Following ingestion

4.1.6 4.1.7

Self protection of the first aider Note to the doctor

4.2

Most important symptoms and effects, both acute and delayed

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 4.3 Indication of any immediate medical attention and special treatment needed

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: Always get immediate medical attention/advice when symptoms persist.

5. FIRE FIGHTING MEASURES Fire Fighting Measures : The following applies to Butan-2-one FLASHPOINT: 26oF SPECIFC GRAVITY: 0.806 @ 68o F EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%. AUTOIGNITION TEMPERATURE: 961.0oF.

5.1

Extinguishing media Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or extinguish with alcohol type or all purpose type foam, or dry chemical powder. Try to cover liquid spills with appropriate foam. Use water spray to cool fire exposed surfaces. Avoid spraying water directly into storage containers due to danger of boilover. Shut off fuel to fire if possible to do so without hazard. If a spill has not ignited, use water spray to disperse the vapors. : Do not use high volume water jet. : Flammable liquid; may release vapors that form flammable mixtures when temperatures are at or above the flash point. There is a danger of explosion when container is heated or in fire. Toxic gases will form upon combustion. Vapor may may accumulate in low or confined areas or travel to a considerable distance to a source of ignition and flash back. Avoid runoff into storm sewers and ditches. : Smoke, fumes, oxides of carbon, irritating or toxic vapors or gases.

Unsuitable extinguishing media 5.2 Special hazards arising from the mixture

Hazardous combustion products

5.3

Advice for fire-fighters Protective equipment for fire fighters : Respiratory and eye protection gear is required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Exposure to decomposition products may cause health hazards. Cool containers exposed to fire with water spray. Move unexposed containers from fire area if this can be done without risk.

5.4

Additional information

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 6. ACCIDENTAL RELEASE MEASURES 6.1 6.1.1 Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment

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: : Wear suitable personal protective equipment (e.g. clothing, gloves, safety goggles, and mask/respirator). Ensure adequate ventilation; remove all sources of ignition. Notify the appropriate authorities immediately. : Eliminate ignition source. Shut off leak if safe to do so. Take all additional action necessary to prevent and remedy the adverse effects of the spill. Isolate hazard area and deny entry to unauthorized or unprotected personnel. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as saw dust. Absorb spill with an inert material (e.g., sand or earth). Then place in a chemical waste container. : Respiratory and eye protection gear is required for emergency responders. Full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires. Use portable fire extinguisher for small outdoor fires. Use of SCBA may not be required. : Avoid dispersal of spilt material and runoff into soil, storm sewers and ditches which lead to natural waterways, or the immediate environment. Inform the relevant authorities if the product has entered into the environment.

Emergency procedures

6.1.2

For emergency responders personal protective equipment

6.2

Environmental precautions

6.2 6.3.1

Methods of containment and cleaning up On water : If spill in water, remove from water surface by skimming or with suitable absorbent material and place in appropriate disposal container. If allowed by local environmental regulatory agencies, you may use a suitable dispersant. : Contain spill and absorb with an inert material (e.g., dry sand or earth). Then place in an appropriate waste container for disposal according to local regulations. Large spills should be disposed of via a licensed waste disposal establishment/contractor. : Contaminated absorbent material may pose similar hazard as the spill product.

6.3.2 On ground/floor

6.3.3 6.4

Other information

Reference to other sections See Section 1 for emergency contact information. See Section 8 for information on appropriate personnel protective equipment. See Section 13 for additional disposal information.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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7. HANDLING AND STORAGE 7.1 7.1.1 Precautions for safe handling Protective measures : Wear appropriate personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Do not eat, drink, or smoke when using this product. Use only with adequate ventilation. Keep away from sources of ignition. Keep only in original container. Keep tightly closed when not in use. Do not reuse container. Avoid release to the environment. : Avoid eating, drinking and smoking in areas where this product is handled, used and stored. Wash hands before eating, drinking and smoking, and at the end of the working period. Contaminated work clothing and protective equipment should not be brought into eating, smoking and drinking areas. Wash soiled clothing before re-using.

7.1.2

Advice on general occupational hygiene

7.2

Conditions for safe storage, including any incompatibilities Technical measures and storage conditions : Store at ambient/room temperature. Protect from extreme cold and heat. Store in a segregated and approved area. Store away from strong oxidizing agents. Loosen closure cautiously with non-sparking tools before opening. Keep only in original container. Store and use away from sparks, heat, open flames and other ignition sources. Ground and bond containers and receiving equipment. Store locked up. Store away from direct sun -light in a dry, cool and well-ventilated area. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Ground and bond containers when transferring material. Ventilation required along storage floor. : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic bottles and containers. : For industrial use only. : Not available.

Packaging materials 7.3 Specific end use(s) Recommendations Industrial sector specific solutions

8. EXPOSURE CONTROL/PERSONAL PROTECTION There is no workplace exposure data available on the product itself. 8.1 Control parameters

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 8.1.1 Component Occupational Exposure Limits (OELs) : Butan-2-one CAS#: 78-93-3 Province Alberta British Columbia Ontario Quebec Butan-1-ol CAS#:71-36-3 Province Alberta British Columbia Ontario Quebec Ethyl hydroxide CAS#: 64-17-5 Province Alberta British Columbia Ontario Quebec Propan-2-ol CAS#:67-63-0 Province Alberta British Columbia Ontario Quebec

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Occupational Exposure Limit (OELs) Values Long Term Limit Limit Value Type Short Term Limit (8-hour period) (15-minute(s) period) ppm [mg/m3] ppm [mg/m3] Letter Code 200 50 200 200 100 300 OEL (Canada, 4/2009) TWA/STEL, (Canada, 9/2010) TWA,STEL (Canada, 7/2010) TWAEV,STEV (Canada, 6/2008)

Occupational Exposure Limit (OELs) Values Limit Value Type Short Term Limit Long Term Limit (8-hour period) (15-minute(s) period) ppm [mg/m3] ppm [mg/m3] Letter Code 20 15 20 60 30 50 152 OEL, (Canada, 4/2009) TWA,STEL, (Canada, 10/2009) TWA, STEL, (Canada, 7/2010) TWAEV,STEV (Canada, 6/2008)

Occupational Exposure Limit (OELs) Values Limit Value Type Short Term Limit Long Term Limit (8-hour period) (15-minute(s) period) ppm [mg/m3] ppm [mg/m3] Letter Code 1000 1000 1000 1880 1900 1880 1000 OEL, (Canada, 4/2009) TWA,STEL, (Canada, 10/2009) TWA, STEL, (Canada, 7/2010) TWAEV, STEV,(Canada, 6/2008)

Occupational Exposure Limit (OELs) Values Limit Value Type Short Term Limit Long Term Limit (8-hour period) (15-minute(s) period) ppm [mg/m3] ppm [mg/m3] Letter Code 200 200 200 200 492 983 400 400 400 500 984 1230 OEL, (Canada, 4/2009) TWA,STEL, (Canada, 10/2009) TWA, STEL, (Canada, 7/2010) TWAEV, STEV,(Canada, 6/2008)

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Methylbenzene CAS#:108-88-3 Province Alberta British Columbia Ontario Quebec Xylol

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Occupational Exposure Limit (OELs) Values Limit Value Type Short Term Limit Long Term Limit (8-hour period) (15-minute(s) period) ppm [mg/m3] ppm [mg/m3] Letter Code 50 50 50 100 188 377 150 565 OEL, (Canada, 4/2009) TWA (Canada, 10/2009) TWAEV, (Canada, 7/2010) TWAEV, STEV,(Canada, 6/2008)

Occupational Exposure Limit (OELs) Values Long Term Limit Limit Value Type Short Term Limit CAS#:1330-20-7 (8-hour period) (15-minute(s) period) ppm [mg/m3] Letter Code ppm [mg/m3] Province Alberta British Columbia Ontario Quebec 100 100 100 100 434 435 434 150 150 150 150 651 650 651 OEL, (Canada, 4/2009) TWA,STEL, (Canada, 10/2009) TWA, STEL, (Canada, 7/2010) TWAEV, STEV,(Canada, 6/2008)

Exposure limits provided in the above table above contains generic information and guidance on air contaminants in the workplace. Please consult applicable OEL standards of your Province. Recommended monitoring procedures : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation of chemical agents and national guidance documents for methods for the determination of hazardous substances. : See occupational exposure limits table for guidance. : Not available.

Derived effect levels [DNEL] Predicted effect concentrations (PNEC Summary) 8.1 8.1.1 Exposure controls Appropriate engineering controls

: Provide adequate local exhaust ventilation to maintain worker below exposure limits. The use of mechanical ventilation controls is recommended whenever this product is used in a confined space, is heated above ambient temperatures, or is agitated. Use explosion-proof ventilation equipment.

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 8.2 8.2.1 Personal protective equipment Eye and face protection

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: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mist, or dust. See OSHA Standard (29 CFR 1910.133) or appropriate Canadian Standards. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this in necessary. Refer to 29 CFR 1910.138 or appropriate Standards of Canada. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Consult U.S. OSHA 29 CFR 1910.136. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Provide eyewash stations and quick-drench shower facilities.

8.2.2

Skin protection Hand protection

Body protection

Other skin protection

8.3

Respiratory protection

: Use approved respiratory protection equipment. Respirator selection should be based on the form and concentration of contaminants in the air and in accordance with local regulations. See Canadian CSA Standard Z94.4-93 and applicable standards of Canadian Provinces. : Emission from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Ensure that emission is at the acceptable level.

8.4

Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on physical and chemical properties Physical state : Liquid. Colour : Characteristic. Odour : Solvent odour. Odour threshold : Not determined. pH : Not available . Melting/freezing point [o F] : Not available. Initial boiling point/range [o F] : Not available. Flash point [o F] : Not available. Evaporation rate (n-Butyl Acetate : Not available. = 1)

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Flammability (solid, gas) Upper flammability Lower flammability Vapor pressure, mm Hg @ 75 o F Vapor density (Air = 1) Relative density Solubility in water, Wt % @ 68 o F Partition coefficient: nOctanol/water Auto-ignition temperature Decomposition temperature Viscosity of Liquid, CST @ 25o C Explosive properties Oxidizing properties 9.2 Other information : Not available. : Not available. : Not available. : Not available. : Not available . : Not available. : Not available. : Not available. : Not available. : Not applicable. : Not available. : Not available. : Not available.

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: Experimental material. Certificate of Analysis was not generated.

10. STABILITY AND REACTIVITY 10.1 10.2 10.3 10.4 10.5 10.6 Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : Reactivity does not occur. : Stable under normal conditions. : Hazardous polymerization will not occur. : Open flames and sources of ignition. Incompatible products. : Strong oxidizing agents.

Hazardous decomposition products : Burning can produce oxides of carbon.

11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects : There is no data available on the product itself.

11.1.2 Mixture

11.1.2.1 : Relevant effects: Component Carcinogenicity Carcinogenicity Databases Information on components CAS Registry Constituents/Ingredients CAS No. OSHA-Z NTP IARC ACGIH Butan-2-one 78-93-3 Butan-1-ol 71-36-3 Group A4 Ethyl hydroxide 64-17-5 Group 3 Group A4 Propan-2-ol 67-63-0 Group 3 Group A4 Methylbenzene 108-88-3 Group 3 Group A4 Xylol 1330-20-7 -

EPA
Group D

Group D Group D

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Classifications ACGIH EPA IARC (b) Irritation Inhalation :

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: Group A4: Not classifiable as a human carcinogen. : Group D: Not classifiable as to Human Carcinogenicity. : Group 3: Not classifiable as to its carcinogenicity to humans.

: May cause irritation to the nose, throat, and lungs. High vapor concentrations may cause unconsciousness or other signs of central nervous system depression. : Frequent or prolonged contact may irritate the skin and cause skin rash (dermatitis). May cause skin sensitization, an allergic reaction which becomes evident on re-exposure to this material. : Severely irritating. If not removed promptly will injure eye tissue, which may result in permanent damage. : May cause irritation of the digestive tract and diarrhea. : Severely irritating to eyes. Repeated exposure may cause skin dryness or cracking. : May cause skin sensitization and or respiratory system irritation due to extended exposure of the preparation above stated occupational exposure limits. : No data available. : No data available. : No known significant effects or critical hazards. : No information but adverse effects unlikely. : No known significant effects or critical hazards. : No known significant effects or critical hazards.

Skin contact

Eye contact

Ingestion (c) Corrosivity

(d)

Sensitization

(e) (f) (g) (h) (i)

Single dose toxicity Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction

11.1.2.2 CMR effects (carcinogenic, mutagenic or toxic for reproduction) 11.2 Potential adverse health effects

: Small amounts of this liquid may be drawn into the lungs by either swallowing or vomiting. This may cause severe and delayed health effects such as inflammation of the lungs ( pulmonary edema) and infection of the bronchi(broncho-

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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pneumonia). Ingestion may cause irritation to the digestive tract or diarrhea. 11.3 Potential chronic health effects : There is no evidence that exposure to Butan-2-one alone causes progressive or irreversible neurotoxic effects. However, simultaneous over-exposure to Butan-2-one and n-Hexane can potentiate the known irreversible neurotoxic effects of n-Hexane. There is no reported human evidence that these neurotoxic effects occur when exposure to both chemicals is maintained below established regulatory limits. : The mixture is not likely to be carcinogen in humans.

11.4

Other information

12. ECOLOGICAL INFORMATION Note: Ecological testing has not been done on the product. Ecotoxicological information on components of this product is presented below. 12.1 Toxicity Butan-2-one [CAS#: 78-93-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC3 Butan-1-ol [CAS#: 71-36-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Ethyl hydroxide [CAS#: 64-17-5] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity LC50 Acute algae toxicity EC50 Propan-2-ol [CAS#: 67-63-0] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 : Exposure time (h) 96 hour (s) 48 hour (s) 7 days Species Pimephales promelas Daphnia magna Scenedesmus quadricauda Value (mg/l) 3220 > 520 4300

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) < 1630 1983 > 500

Exposure time (h) 96 hour (s) 48 hour (s) Not specified

Species Alburnus alburnus Daphnia magna Chlorella pyrenoidosa

Value (mg/l) 10000 - 11500 9268 - 14221 9310

Exposure time (h) 96 hour (s) 48 hour (s) 96 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 9640 13299 > 1000

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 Methylbenzene [CAS#: 108-88-3] Aquatic toxicity Effect dose Acute fish toxicity LC50 Acute Daphnia toxicity EC50 Acute algae toxicity EC50 Xylol [CAS #: 1330-20-7] Aquatic toxicity Acute fish toxicity Acute invertebrate toxicity Acute algae toxicity 12.2

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Exposure time (h) 96 hour (s) 48 hour (s) 48 hour (s)

Species Pimephales promelas Daphnia magna Scenedesmus subspicatus

Value (mg/l) 28 11.5 125 - 160

Effect dose LC50 LC50 Mortality

Exposure time (h) 96 hour (s) 48 hour (s) Unknown

Species Cyprinus carpio Palaemonetes pugio Scenedesmus quadricauda

Value (mg/l) > 780 0.85 > 200

Persistence and degradability

: No data available for this product.

(Biochemical Oxygen Demand BOD values) Substance name Quantity Degradation rate (%) Butan-2-one Unknown 83 Butan-1-ol Unknown 66 Ethyl hydroxide 10 mg/l 74 Propan-2-ol 10 mg/l 78* Methylbenzene Unknown Completely Xylol Isomers 72 * Theoretical Oxygen Demand (ThOD) value. 12.3

Incubation time 5 days 5 days 5 days 20 days Short duration 20 days

Evaluation (inoculum) Sewage Sewage sludge Filtered sewage seed Filtered sewage seed Sewage seed Activated sewage

Bioaccumulative potential : No data available for this product. (BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate Substance name Estimated BCF log Kow Remarks Butan-2-one 3 0.29 Low bioaccumulation Butan-1-ol 3 0.88 Low bioaccumulation Ethyl hydroxide 3 -0.31 Low bioaccumulation Propan-2-ol 3 0.05 Low bioaccumulation Methylbenzene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation Xylol 6 23.4 3.2 Low bioaccumulation Mobility in soil : No data available for this product.

12.4

Koc The soil absorption coefficient Substance name Koc value Butan-2-one 29 Butan-1-ol 72 Ethyl hydroxide 1 Propan-2-ol 25 Methylbenzene variable Xylol 39 365 for individual isomers

Remarks (soil mobility) Very high mobility High mobility Very high mobility Very high mobility High to moderate mobility Very high to moderate mobility

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 12.5 Results of PBT and vPvB assessment PBT : No data available. vPvB : No data available. Other adverse effects

Page 17 of 20 Prepared Date: 07/02/2012 Printing Date: 07/07/2012

12.6

: No known significant effects or critical hazards.

13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product Methods of disposal

: The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Waste product residue should not be disposed of via the foul sewer. Consult an expert on the disposal of recovered and surplus material. Incinerate, or recover by distillation. Ensure disposal is in compliance with current government requirements and ensure conformity with local authority regulations. : The generation of waste should be avoided or minimized whenever possible. Waste packaging should be recycled, or dispose of according to appropriate local and national requirements. : The use of this product should at all times comply with the requirements of environmental protection and waste disposal legislations/statutes and any local authority requirements. : This material and its container must be disposed of according to local authority regulations. Empty containers or packaging may contain some product residue. Avoid dispersal of spill material and runoff to come in contact with soil, waterways, drains and sewers.

Packaging waste Methods of disposal

NOTE

Special precautions

14. TRANSPORTATION INFORMATION

TDG 1210 Printing Ink Related Material ADN/ADNR 1210 Printing Ink Related Material IMDG 1210 Printing Ink Related Material ICAO-TI/IATA-DGR 1210 Printing Ink Related Material

14.1 UN No. 14.2 Proper Shipping Name 14.3 Transport hazard class 14.4 Classification code 14.5 Packing group

3 F1 II

3 F1 II

3 F1 II

3 F1 II

Product Name: Fendell Cleaning Solvent Blend No. 3 Product No: FCSB No. 3 Version: 1.00
TDG 14.6 Hazard label ADN/ADNR IMDG

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ICAO-TI/IATA-DGR

14.7 Environmental hazard 14.8 Special provision(s) Additional Information

No Hazard identification number 33 Ltd. Qty LQ 5 Excpt. Qty E2 Packaging P001, PP1, MP19 Portable Tanks and Bulk Cont. T4; TP1, TP8 -

No -

Marine pollutant: No Emergency schedules (EmS) Fire F-E Spillage S-D

No Passenger and Cargo Aircraft Quantity limitation: 1.0L Packing instructions: Y341 353 5.0L

Ltd. Qty LQ6

Excpt. Qty. E2 -

Ltd. Qty 5l Excpt. Qty E2 -

Cargo Aircraft only Quantity limitation: 60.0 L

Packaging instruction: 364

14.9

Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.

15. REGULATORY INFORMATION 15.1 Regulatory Information : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the (M)SDS contains all information required by CPR. : The components of this mixture are listed on the DSL inventory. : The Methylbenzene, and Xylol components of this mixture are on the CEPA Priorities Substances List. : This mixture is categorized as a Controlled Product, Hazard Classes B2 and D2B, as per the Controlled Product Regulations.

WHMIS Classification

Canadian DSL/NDSL Inventory Status Canadian Environmental Control Act (CEPA) Priorities Substances List WHMIS Regulations

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00

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Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals Not listed Not listed Not listed

16. OTHER INFORMATION NOTE : The information contained within this Safety Data Sheet is for teaching purposes only. The mixture is fictitious.

16.1

Indication of changes Date of previous issue Revisions Nature of version Version Date of issue Prepared by

: : : : : :

No previous validation. New (M)SDS. Conforms to CPR-WHMIS and GHS Standards. 1.00 07 July, 2012. Theodore M. Amet, Regulatory Research Analyst

16.2

Abbreviations and acronyms ACGIH: American Conference of Governmental Industrial Hygienists; ADR: Accord europen sur le transport des merchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road); CAS#: Chemical Abstract Service Registry Number; CEPA: Canadian Environmental Protection Act; EINECS: European Inventory of Existing Commercial chemicals Substances; EHS: Extremely Hazardous Substances; EPA: United States Environmental Protection Agency; GHS: Globally Harmonized System of Classification and Labelling of Chemicals; IARC: International Agency for Research on Cancer; IATA: International Air Transport Association; IATA-DGR: Dangerous Goods Regulations by the International Air Transport Association (IATA); ICAO: International Civil Aviation Organization; ICAO-TI: Technical Instructions by the International Civil Aviation Organization (ICAO); IMDG: International Maritime Code for Dangerous Goods; NTP: National Toxicology Program; OSHA: Occupational Safety and Health Administration; RID: Rglement international concernant le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous goods by Rail); STEL: Short Term Exposure Limit; TDG: Transport of Dangerous Goods TLV: Threshold Limit Value; TWA: Time Weighted Average. Key literature references and sources of data : CAMEO Chemicals; ESIS (Existing chemical Substances Information System); TOXNET; Information from technical literature; Internet research; Substance Material Safety Data Sheets.

16.3

Product Name: Fendell Cleaning Solvent Blend No. 3 Product Code: FCSB No.3 Version: 1.00 DISCLAIMER

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This document was compiled for teaching purposes. Information on this sheet is based on data gathered from many sources. No warranty is expressed or implied as to the accuracy, reliability or completeness of data obtained from various chemical, health, toxicological, and environmental databases. Responsibility for the accuracy and completeness of information contained herein rests with users who must satisfy themselves that the data is appropriate for their teaching needs. It is always a good practice to consult a sectional expert when writing sections of the safety data sheets to clarify and simplify technical matters. The author assumes no responsibility for injury, damage or loss resulting from the use of this material.

END OF SAMPLE (MATERIAL) SAFETY DATA SHEET