GVHD: GS.TS.

NGUYN KIM PHI PHNG HVTH: NGUYN TN PHT NGUYN TH DIM PHC V TH HNG THM

SC K KH (GC). SC K KH-LNG (GLC). SC K KH-RN (GSC).

NGUYN TC: DA VO S PHN CHIA GIA PHA NG (KH) V PHA TNH RN/LNG. THAY I S PHN CHIA BNG NHIT . TCH THEO P SUT HI V KH NNG HA TAN VO PHA TNH. Ex: PA>PB A RA TRC B.

S DNG PH BIN TRONG PHN TCH HA HC. LOI MU NO ??? SC K KH D BAY HI (tos 350oC), BN NHIT.

HIU QU VI PHN GII CAO. KHNG TN DUNG MI. C TH THC HIN LI TH NGHIM KHNG CN CH CT N NH. PHN TCH C MU C LNG T mL. PHN TCH C MU RT PHC TP. THI GIAN PHN TCH NGN, THCH HP KHI S LNG MU LN.

KHNG THCH HP MU KH BAY HI, KM BN NHIT. I KHI I HI KH NNG CHUN B MU PHC TP.

S DNG KH TR NHIT CT SC K (He, H2, N2,). He S DNG PH BIN. TINH KHIT KHONG 99,995%, TP CHT THNG L O2, H2O V HYDROCACBON. (THNG NH CUNG CP LI LC PHN T HAY C TH S DNG H THNG BY). P SUT: 10 ~ 50 PSI (1 ATM = 14,223 PSI); 25 ~ 150 ML/PHT VI CT NHI, HOC 1 ~ 25 ML/PHT VI CT MAO DN.

BUNG TIM TRC TIP: MU C TIM QUA 1 SEPTUM VO BUNG TIM, MU C LM NNG (>T L), HA HI V CUN THEO KH MANG VO CT. LNG MU 1-20 L VI CT NHI; 0,001 L VI CT MAO DN. THNG S DNG CHO CT NHI.

CT MAO DN C BUNG TIM C TH CHIA THEO K THUT TIM: CHIA DNG (SPLIT), KHNG CHIA DNG (SPLITLESS), TIM TRN CT (ON-COLUMN).

K THUT TIM CHIA DNG (SPLIT) LM GIM LNG MU A VO CT THCH HP VI CT MAO DN, C BIT L NHNG CT C NG KNH RT NH. T L CHIA DNG T 1:10 N 1:1000 PH THUC VO NNG V TNH CHT CA CT. THNG P DNG KHI NNG CHT PHN TCH > 0,1%.

K THUT TIM KHNG CHIA DNG (SPLITLESS) THNG P DNG KHI NNG CHT PHN TCH LNG VT<0,01%. K THUT TIM TRN CT (ON-COLUMN) KHNG C S HA HI BUNG TIM NN HN CH TI A S PHN HY P DNG CHO MU KHNG BN NHIT, D PHN HY GN NHIT SI CA CHT, MU A THNH PHN. C TH GY QU TI CT, GIM HOT TNH PHA TNH, NHIM BN, I HI TIM CHUYN DNG BUNG TIM PTV (Programmable temperature vaporizing) KT HP TT C CC LOI BUNG TIM TUY NHIN PHI TI U NHIU THNG S.

CCH NHIT, GI CT SC K NHIT C NH, IU KHIN BNG 1 CNH QUT.

CT NHI: THNG BNG THY TINH HOC THP (1-5 M DI, 5 MM NG KNH TRONG). TR NHIT CAO, KHNG THAY I KHI B T, BN. NG KNH GIM HIU QU TNG P SUT TNG.

CT MAO DN: CT NG H LP (WCOT): PH BI MT LP MNG PHA TNH LNG. CT NG H CHT MANG (SCOT): PH BI MT MNG MNG (30 M) LP CHT MANG RN HP THU PHA TNH LNG. HIU QU THP HN WCOT NHNG CAO HN CT NHI. CT PLOT PH MT LP HP PH XP..

NHIU LOI U D C TH DNG CHO GC: DN NHIT (THERMAL CONDUCTIVITY TC). ION HA NGN LA (FLAME IONIZATION - FI). BT IN T (ELECTRON CAPTURE EC). NITROGEN-PHOTPHOR (NP). TRC QUANG NGN LA (FLAME PHOTOMETRIC FP). QUANG ION HA (PHOTOIONISATION PI). PHC HP (MISCELLANEOUS). KHI LNG (MASS SPECTROMETER MS). QUANG PH K HNG NGOI (INFRARED SPECTROMETER IR). PHT X NGUYN T (ATOMIC EMISSION AE).

u im : -u d dn nhit c th pht hin tt c cc loi hp cht v c v hu c - Khng lm h hi khi mu i ngang qua b phn u d nn thch hp cho loi sc k kh s dng ct iu ch, n thng c trang b trong my sc k kh. Nhc im: - Km nhy, khng th pht hin hp cht hin din nng nh.

u im : -u d ion ho ngn la c th pht hin hp cht hin din nng rt nh ca tt c cc hp cht h u c . - C tnh tuyn tnh cao - Loi u d ny rt thng dng cho my sc k kh v hu ht cc hp cht hu c c th t chy tht Nhc im: -Khng th phn tch tt c cc loi hp cht, ch pht hin cc hp cht hu c no c th b t chy v phn mnh di ngn la hydrogen. - u d ion ho ngn la khng th pht hin cc hp cht sau : H2 , O2 , N2 , SO2 , NH3 , CO, CO2 , H2O, Ar, Kr, Ne, Cc hp cht HCHO v HCOOH cho tn hiu rt yu. - Ngn la cng t chy thiu hu mu nn khng s dng cho k thut sc k iu ch.

u im : -u d bt in t rt nhy, c th pht hin mt s loi hp cht thuc v mi trng khi chng hin din nng cc nh. Th d d lng cc loi thuc tr su cha clor, thuc dit c - Khng lm h hi mu khi mu i ngang qua b phn u d nn thch cho loi sc k ct iu ch. Nhc im: - Ch nhy i vi mt s t loi hp cht, cn cc loi hp cht khc khng cho tn hiu mi trn sc k .

u im : -u d nitrogen-phosphor dng pht hin d lng cc loi thuc tr su c cha N v P tn ti trong mi trng, cc hp cht phosphat hu c, cc hp cht carbanat - Khi so snh vi u d ion ho ngn la (FID), u d NPD nhy hn gp 50 ln ( pht hin c hp cht c N), nhy hn 500 ln ( pht hin hp cht c P) Nhc im: - Ch nhy i vi loi hp cht c cha N v P, cn cc loi hp cht khng cha N, P s khng cho tn hiu mi c th o s dng - Ngn la cng t chy thiu mu nn khng th s dng cho k thut sc k iu ch.

u im : -u d trc quang ngn la c nhy cao, dng pht hin d cc loi thuc tr su c ch S v P tn ti trong mi trng, phn tch cc cht mu, cc cht thm trong thc phm. phn tch cc hp cht c lu hunh nh tiphen, mercaptan Nhc im: - Ch nhy i vi loi hp cht c cha S v P, cn cc loi hp cht khng cha S, P s khng cho tn hiu mi c th o s dng - Ngn la cng t chy thiu mu nn khng th s dng cho k thut sc k iu ch.

u im : -u d quang ion ho c nhy cao, pht hin mu hin din nng nh. c xem l u d nhy, c th p dng phn tch mt ph rt rng cc loi hp cht v c v hu c. - Khng lm h hi mu khi mu i ngang qua b phn u d nn thch hp cho loi sc k kh s dng iu ch.