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Lecture 7 packed beds

Reactor Scale Considerations: Gas-Solid Systems


Solid catalyzed gas reactions are mainly
conducted in

Adiabatic massive packed bed reactors
Wall cooled tubular reactors
Fluidized beds
Risers ( part of circulating fluidized beds)

Reactor models vary from pseudo-homogeneous
to heterogeneous, from one dimensional to three
dimensional, from assumed flow pattern to
computed flow and transport fields. The needed
sophistication depends on the reaction system.

Adiabatic Packed Beds
f
x x T
A ad A
= ,
( )
f
A
p
Ao rA
o ad
x
C
C H
T T

A
+ =
( ) ( )
( ) ( )
b A o A
B p
B g g
B p
B g
R R
d
U E
d
U E
L
P
=

=
A
q
c
c
c
c
3
2
2
3 2
2
1
1 1
bed in the achieved reactant limiting of Conversion
mixture reaction of e unit volum per heat specific Mean
reactant limiting of ion concentrat Feed
reaction of Heat
re temperatu Feed
=
=
=
= A
=
f
A
A
p
Ao
r
o
x
C
C
H
T

0 , =
A Ao o
x C T Key Issues:
- Adiabatic temperature rise
- Pressure drop
- Optimal rate
- Explosion and runaway potential
S5
Permissible Adiabatic Temperature Rise
T
ad
T
int
T
o
T

t

t
-
( )
p
Ao r
o ad ad
C
C H
T T T
A

A
=
= A
max
If is not permissible limit operation to which requires limiting
conversion by having
ad
T
inf
T T s
*
t t <
For n-th order reaction then yields
( ) | |
( )
( )
( )
( )
o
u
t
t
t
t

| o
u
o
u
o
o

u
u u
inf
max
1
*
2 2
inf
inf
;
1
2 4
2
inf
=
=

= =

A
= = =
|
.
|

\
|

=
+ + =

=

+
}
x
C e k
C
R
Da
RT
E
T C
C H
RT
E
d
e
Da
n n
n T
T T
n
Ao o
Ao
o
A
R
o o p
Ao r
o
o
n
o
o
A
(1)
(2)
S6
For n-th order reaction the for which temperature must be kept below inflection
point temperature

inf inf
T T < <u u

The requirement is to keep
*
t t < where
*
t can be obtained from Eq (3) below

( )
( )
*
2
*
o

t
Da
T C R
E H C e k
o p
A
r
n
Ao
o
RT E
o
=
A



Where the numerical value of ( )
*
o Da is calculated from Eq (2).

For a conservative estimate based on zeroth order reaction

( ) 1
*
=
app
Da o

In addition composition of fuel (HC) and oxygen is kept outside explosion limits.
(3)
S7
Exothermicity of Oxidation Reactions Limits Equilibrium Conversion



A
x
eq A
x
m
T
01
T
02
T
T

On
A
x vs T plot
eq
A
x is the locus of
zero rates

Also plotted is the locus of maximum
rates ( ) Line T
m
obtained from 0 = c c T r

Adiabatic lines with two different feed temperatures are also plotted.

The lower the
o
T the higher exit conversion can be reached.

So high exit conversion requires staging of multiple adiabatic beds increasing
the cost.
S8
Observed reaction rate at any point of the reactor is the product of the local overall
effectiveness factor
o
q and the rate attainable at that location in absence of transport
limitations
( ) ( ) ( )
local
bulk
A o
local obs
A
R R = q
e.g. for first order process
0 ;
0
6
tanh
6
1
1
>
>
= .
.
.
=
+
=

| q
o q
q
q
q
|
o
g g o
p o
e
p
p
p
p
g
p
o
U k
d
D
k
d
k
d k

But
( ) ( )
|
A
| | +

=
A
L
P
U d
d
t U E
d
U E
L
P
o g p
p
B g
p
B g
q
c c
c
| |
,
1 1
3
2
3 2
2
1



Compromise between pressure drop and overall effectiveness factor (i.e. volumetric
productivity) is sought.
S9
To allow higher volumetric productivity
v
m at reduced power dissipation ( ) P V A
`
one tries for
a given size of small catalyst particles to use radial flow reactor or flat pane type reactors that
minimize bed depth and superficial gas velocity


Instead of
Use
Or
out
out
out
in
in


Mass of catalyst divided by volumetric federate

up - scale for const. = =
o
w
V
W
`
t
S10
Elaborate designs that combine radial or panel flow and
interstage (between beds) cooling for staged adiabatic reactions is
available in the patent literature.

To improve on conversion per pass use cyclic reverse flow
operation switch flow direction periodically.



In
In
Out
Out

T

t



This yields an inverse
temperature profile conducive
to achieve higher exit conversion

Practiced commercially on sulfuric acid plants and in VOC combustion.
S11
Scale-up of Adiabatic Reactors
Same d
p
, same catalyst, same bed packing
procedure
Same feed composition and same temperature
Ensure good flow distribution in lab scale (e.g. d
t
/d
p
>
30)
Ensure proximity to plug flow in large scale
Same space time
From bench scale data is not straight forward
because lab reactors are rarely adiabatic. The
procedure is to use:
S12
Design of massive adiabatic packed bed reactors
Developed by licensors of technologies that use them and
involves incorporation of staged adiabatic reactors with inter-
stage reactant or inert cold shot cooling as well as cooling of
the recycle streams.

Designs are available for pancake, panel and radial flow
reactors to reduce pressure drop. Flow distribution and
pressure drop evaluated by some level CFD models.

Reactor performance calculated based on plug flow
assumptions; sometimes axial dispersion model is used.
However, large extent of back mixing can arise due to
natural convection effects when temperature rise is large.

Better models for characterization of packed structures and
for computation of the flow field are needed.
Wall Cooled Tubular Reactors
Plug flow is needed to favor the intermediate
Cooling is needed to prevent runaway combustion and other
undesired reactions
These systems are prone to hot spots and extreme
parametric sensitivity.
T
T
o
T
w4
T
w3
T
w2
T
w1
tct

t

A small increase in wall
(T
w
) i.e. coolant
temperature could lead
to enormous increase in
peak temperature
S13
For an n-th order irreversible reaction the temperature variation with conversion is given
by
( )
( )
( )
( )
(

=
+

+
u
o
k
o
u
u u u u
n
A
n
A
A
x e x e
dx
d
1 1
/ 1 / . / 1 /
( )
_
u
1
y
( )

u
2
y


( )
( )
( )
ion concentrat feed
diameter tube
conditions feed at evaluated rate
coeficient fer heat trans overall
4
=
=
= =
=

= =

A
= =

Ao
t
n
Ao
RT E
o
o
A
o
o
p t
o
A
Ao
h
R
o o p
Ao R
C
d
C e k R
U
T
T T
C d R
C U
T R
E
T C
C H
o
A
u
t
t
k

| o


For avoidance of hot spots one needs

( ) ( )
max
2
max
1
max 2
u u
u u
u u u
d
dy
d
dy
y y
i
<
=

S14
, ,
( )
( ) u
u
2
1
y
y
( ) u
1
y
1 max
u
2 max
u
3 max
u
u
0

e
1
are
( ) 0
2
y
for
decreasing
o
k
1 2
3
2
3

This implies that to avoid hot spots
one must have

( )
u
o
k
u u
=
+ 1
e (x)

( )
o
k

u
u u
s
|
.
|

\
|
+
+ 1
2
1
1
e (xx)

Substitute (x) into (xx)
1
1
1
max
2
max
=
|
.
|

\
|
+
u

u

Find
max
u , substitute into (x) and get
|
.
|

\
|
o
k
critical. Using approximations one gets
e T T
o
> |
.
|

\
|
+ =
o
k

and 1
1
max

Resulting in
( )
n
Ao
RT E
o rA
o
t
C e k H E
e RT U
d
o

A
s
1 2
4

Determines maximum permissible tube diameter.
S15
Multi-tubular wall cooled (tube in shell) reactors are used extensively (e.g. ethylene
oxide production etc.).

Lurgi is a key licensor of multitubular reactor technology, up to 40,000 tubes 1 to 2
inches in diameter in a single shell.

Key issues:

- Select safe tube diameter (as discussed)
- Pack each tube with identical amount of catalyst ( )
T
W
- Have perfect flow distribution so that for each tube const V W
o T
=
`


Scale up Trivial (Usually)

- Run one tube in the lab until you get desired result for conversion, selectivity,
determine production rate
L
p
F

- Find number of tubes needed for commercial production rate

L
c
p
p
F
F
N =

- Use identical tubes and coolant, identical
o
V W
`
, in each tube as in the lab
S17
Potential Problems (Troubleshooting)

- Catalyst for plant and lab different
- Tubes not packed carefully with same size of pellets and same amount
as in the lab
- Flow distribution imperfect so ( )
tube
o
V W
`
varies from tube to tube
- Feed temperature different in plant and lab
- Feed of different composition in plant and lab
- Different coolant and coolant circulation rate used (could affect U)
S16
To learn whether tube operates optimally one must:

- Determine whether plug flow is approached
- Assess magnitude of radial temperature differences
- Assess transport effects and determine difference in gas and solid
temperature locally
- Assess internal diffusional effect / and heat effects if needed

Approximate criteria for all of the above are readily available in reaction
engineering text books.

For more detailed analysis need
- Kinetic forms and rate parameters
Use models of increased degree of sophistication
- Pseudo homogeneous 1D
- Pseudo homogeneous 2D
- Heterogeneous 1D
- Heterogeneous 2D

Obtain parameters (e.g.
w p
h h , etc) from a) correlations ; b) detailed CFD
S18
To learn whether tube operates optimally one must:

- Determine whether plug flow is approached
- Assess magnitude of radial temperature differences
- Assess transport effects and determine difference in gas and solid
temperature locally
- Assess internal diffusional effect / and heat effects if needed

Approximate criteria for all of the above are readily available in reaction
engineering text books.

For more detailed analysis need
- Kinetic forms and rate parameters
Use models of increased degree of sophistication
- Pseudo homogeneous 1D
- Pseudo homogeneous 2D
- Heterogeneous 1D
- Heterogeneous 2D

Obtain parameters (e.g.
w p
h h , etc) from a) correlations ; b) detailed CFD
S18
Wall Cooled Packed Tubular Reactors
The key to improved performance is in improving the
heat transfer coefficient on the tube side. Dixon and his
team at Worcester Polytechnic Institute have shown how
to do that by systematic application of CFD to packing of
spheres in tubes. Extensions to extrudates are under
way.

The selection of the right level model for packed beds is
discussed in a series of papers by Balakotiah ( U of
Houston) and his coworkers.

Novel uses of packed beds
Dynamic operation such as in the reverse flow process for
exothermic reactions to achieve better conversion
Coupling of exothermic and endothermic reactions in
directly coupled adiabatic reactors
Coupling of exothermic and endothermic reactions in
indirectly coupled adiabatic reactor in dynamic operation (
reactor regenerator concept)
See doctoral theses at Washington University in St. Louis of
-Milind Kulkarni, and
-R.C. Ramaswamy
and their associated published papers with M.P.Dudukovic and
P.A. Ramachandran from the late 1990s until the present.

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