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compound requires finding which functional groups it contains and then determining its molecular and three-dimensional structure.
Four basic areas of inquiry are useful for identifying the nature of an unknown compound. 1. Physical Properties of compounds 2. Classification by solubility 3. Elemental analysis 4. Classification test for functional groups
This experiment focuses on the 4th area of inquiry.
The presence of Functional Groups is identified by reacting the compound to a reagent which gives a specific visible result
Test for Aromaticity Test for Acidity and Basicity Test for Alkylhalides
Preparation of Acetylene
compound containing a double or triple bond produces a colorless dibromide. (A positive test!) rich to initiate the reaction. Therefore, minimal electron withdrawing groups (Deactivators), such as Carboxyl Groups attached to molecule, would hinder the reaction. react with the Bromine reagent.
Unsubstituted Aromatic compounds (Benzene) do not Even if the ring has substituted activating groups (donate
electrons to the ring) the reaction would be a substitution and not an addition.
Results:
Redox reaction
Following the oxidation of an unsaturated compound, the Permanganate ion is reduced to Manganese Dioxide (MnO4), a brown precipitate.
The reaction is important because it doesnt work on alkanes (compounds with carbon-carbon single bonds) or aromatic compounds.
Drawbacks:
Easily oxidized compounds give a positive
test: a) Most aldehydes give a positive test. b) Formic acid and its esters give a positive test. Often, the brown precipitate fails to form and the solution turns reddish-brown. Alcohols with trace impurities give a positive test. Phenols and aryl amines give a positive test.
Results:
POSITIVE TEST: The disappearance of the KMnO4's purple color and the appearance of a brown suspension of MnO2 is a positive test.
Aromaticity
a chemical property in which a conjugated
ring of unsaturated bonds, lone pairs, or empty orbitals exhibit a stabilization stronger than would be expected by the stabilization of conjugation alone. It can also be considered a manifestation of cyclic delocalization and of resonance.
Nitration
being spread over two secondary carbons and one tertiary carbon atom (the one bearing the CH3 group).
When reaction of toluene occurs at the meta position, then the resonance
forms of the sigma complex put positive charge over 3 secondary carbons - the same as for benzene.
Appearance of the product (Nitration of toluene) : light yellow to darker yellow-
green liquid
Result:
Acidity
Acidity, from the Bronsted-Lowry concept,
associated with functional groups containing OH alcohols, phenols, and carbonyl compounds
Basicity
Basicity, from the Lewis Concept of
Acids and Bases, is the ability or availability of a compound to donate its electron pair.
Basicity is commonly associated with
amines since nitrogen has a lone pair that can be shared with Lewis acids.
I. AgNO Test
replaceable H+ atoms and the formation of precipitates. acids and silver nitrate. Silver nitrate reacts with carboxylic acids to form salts of the carboxylic acid. should be added. Silver salts are soluble in the aforesaid acid.
Results:
to form compounds with metals are not occur with the alkenes.
These reactions can be used as tests to distinguish
solution of silver nitrate or cuprous chloride, at room temperature, precipitates of silver acetylide (white) or cuprous acetylide (red) are formed.
Result:
Alkyl Halides
Alkyl halides is a group of chemical
compounds, consisting of alkanes, such as methane or ethane, with one or more halogens linked, such as chlorine or fluorine, making them a type of organic halide.
halides.
The reaction of an alkyl halide with silver nitrate in ethanol will result
in the formation of a white or yellow silver halide precipitate that is insoluble in nitric acid. warming is necessary.
This reaction quite often proceeds slowly, and occasionally slight Different rate if silver halide precipitation would be expected from
Alkyl bromides and iodides react more rapidly than chlorides Aryl Halides are unreactive toward the test reagent.
Results: