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Chapter 6
Valence electrons are the outer shell electrons of an atom. The valence electrons are the electrons that participate in chemical bonding.
Group 1A 2A 3A 4A 5A 6A 7A e- configuration ns1 ns2 ns2np1 ns2np2 ns2np3 ns2np4 ns2np5 # of valence e1 2 3 4 5 6 7
Lewis Dot Symbols for the Representative Elements & Noble Gases
Lewis dot symbol consists of the symbol of an element and one dot for each valence electron in an atom of the element.
(LiF)
Li e- + Li+ + F F -
Li+ + eF Li+ F -
A covalent bond is a chemical bond in which two or more electrons are shared by two atoms. Why should two atoms share electrons? F 7e+ F 7eF F 8e- 8e-
Lewis structure of F2
single covalent bond lone pairs
lone pairs
lone pairs
F F
lone pairs
A Lewis structure: - a representation of covalent bonding in which shared electron pairs are shown either as lines or as pairs of dots between two atoms, and lone pairs are shown as pairs of dots an individual atoms. Only valence electrons are shown. The formation of the molecules illustrates the octet rule. - Octet rule: An atom other than hydrogen tends to form bonds until it is surrounded by eight valence electrons.
or
or
double bonds
Triple bond two atoms share three pairs of electrons N N 8e-8etriple bond
or
triple bond
Bond Lengths Triple bond < Double Bond < Single Bond
IONIC COMPOUND Solid at room temperature, high melting points Soluble in water Aqueous solution conduct electricity Strong electrolytes
COVALENT COMPOUND Gases, liquids, low melting solids Insoluble in water Aqueous solution do not conduct electricity Nonelectrolytes
N F
C O
FORMAL CHARGE
An atoms formal charge is the difference between the number of valence electrons in an isolated atom and the number of electrons assigned to that atom in a Lewis structure.
formal charge on an atom in a Lewis structure total number of valence electrons in the free atom total number electron assigned to atom
The sum of the formal charges of the atoms in a molecule or ion must equal the charge on the molecule or ion.
Examples:
formal charge on C formal charge on O
= -1 =+1
H H
=0 =0
Resonance Structure
A resonance structure is one of two or more Lewis structures for a single molecule that cannot be represented accurately by only one Lewis structure.
C O
C O -
C O -
BeH2
Be
BF3
B 3e3F 3x7e24e-
B F
NO
The Expanded Octet (central atom with principal quantum number n > 2) F S F F F
SF6
S 6e6F 42e48e-
Hybridization
Hybridization mixing of two or more atomic orbitals to form a new set of hybrid orbitals. 1. Mix at least 2 nonequivalent atomic orbitals (e.g. s and p). Hybrid orbitals have very different shape from original atomic orbitals. 2. Number of hybrid orbitals is equal to number of pure atomic orbitals used in the hybridization process. 3. Covalent bonds are formed by: a. Overlap of hybrid orbitals with atomic orbitals b. Overlap of hybrid orbitals with other hybrid orbitals
How to predict the hybridization of the central atom? 1. Draw the Lewis structure of the molecule. 2. Count the number of lone pairs AND the number of atoms bonded to the central atom # of Lone Pairs + # of Bonded Atoms 2 3 4 5 6
Sigma bond () covalent bonds formed by orbitals overlapping end to-end , with the electron density between the nuclei of the bonding atoms Pi bond () a covalent bond formed by sideways overlapping orbitals with electron density concentrated above and below plane of nuclei of the bonding atoms
How many and bonds are in the acetic acid (vinegar) molecule CH3COOH? H H C H
O
C O H bonds = 6 + 1 = 7 bonds = 1
Intermolecular Forces
Intermolecular forces: attractive forces between molecules. Van der Waals forces: - the attractive or repulsive force between molecules due to covalent bonds or to the electrostatic interaction of ions with one another or with neutral molecules. The term includes: - permanent dipolepermanent dipole forces - instantaneous induced dipole-induced dipole (London dispersion force). Examples: interaction between H2, Cl2, F2, CH4
Hydrogen Bond
The hydrogen bond is a special dipole-dipole interaction between they hydrogen atom in a polar N-H, O-H, or F-H bond and an electronegative O, N, or F atom. A HB or A HA
A & B are N, O, or F