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What is an Explosive?
Chemical compound or mixture that is initiated by heat or shock or a combination of both.
What is an Explosive?
Chemical compound or mixture that is initiated by heat or shock or a combination of both. Decomposes or explodes very rapidly and violently
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What is an Explosive?
Chemical compound or mixture that is initiated by heat or shock or a combination of both. Decomposes or explodes very rapidly and violently Produces a rapid release of heat and large quantities of high pressure gas
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Detonation Process
Primary Reaction Zone
Path of Detonation
Expanding Gases
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Detonation Process
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Detonation Pressure
The application of detonation pressure to the blasthole wall as the reaction zone travels along the charge column that is responsible for the primary shock wave
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Comparative Build Up
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Emulsion Manufacture
Three Primary Components:
ANSOL produced at 94% saturated Solution Pre-blended Fuel Phase Emulsifier
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Emulsion Science
What is an emulsion?
A colloid in which small particles of one liquid are dispersed in another liquid. Usually emulsions involve a dispersion of oil in water, and are stabilised by an emulsifier . Commonly emulsifiers are substances such as detergents, that have hydrophobic (i.e. water repelling) and hydrophilic (i.e. water attracting) parts in their molecule (Oxford Dictionary of Chemistry) A colloid is distinguished from a true solution by the presence of particles that are too small to be observed with a normal microscope yet much larger than normal molecules
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Emulsion Classification
UN Dangerous Goods Classification 5.1 Oxidiser Solution:
Koenen Test Time/Pressure Test UN Gap Test
Tests must be conducted in triplicate in front of a UN Inspector. Only becomes an explosive when sensitised by;
Gassing Solid sensitisers (Microballoons) Blending with ANFO
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Explosive Energy/Strength
Field performance has shown that fragmentation and rock displacement are not exclusively reflected in the numerical values of explosives energy/strength RWS RBS
10kg
ANFO Emulsion
10Lt
Relative to ANFO
(100%)
ANFO
Emulsion
Higher densities of emulsions put more product into the volume area
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100%
Heave Vs Shock
Shock Energy
Explosive Energy
Heave Energy
0%
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QC Checks
An initial cup sample must be taken before any product is loaded into blastholes. This initial cup sample is simply observed to confirm that the gassing process is underway. A subsequent cup sample is taken after the loading of 3 holes and this sample is kept to ascertain a final product density.
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Critical Density
Critical Density is when the product is so dense that there is not sufficient gas voids for the creation of hot spots to allow for the sustainable propagation of detonation Explosives density and sensitivity are related Deadpressing occurs when gas voids are destroyed (by abuse, shock waves) reducing sensitivity
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Sensitivity
Explosives require the creation of hot spots to maintain the reaction
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EXPLOSIVE 0.8 4.99 6.55 7.35 8.19 9.22 10.16 10.65 14.55 15.93 17.15 22.03 25.96 27.78 33.03 39.69 44.91 45.92 49.03 51.53 60.93 76.73 91.44 117.56 0.85 5.30 6.96 7.81 8.70 9.80 10.80 11.31 15.46 16.92 18.22 23.40 27.58 29.52 35.10 42.17 47.71 48.79 52.10 54.75 64.73 81.52 97.16 124.91 0.9 5.61 7.37 8.27 9.21 10.38 11.43 11.98 16.37 17.92 19.29 24.78 29.20 31.25 37.16 44.65 50.52 51.66 55.16 57.97 68.54 86.32 102.87 132.25 1 6.24 8.19 9.18 10.23 11.53 12.70 13.31 18.19 19.91 21.44 27.53 32.45 34.72 41.29 49.61 56.13 57.40 61.29 64.41 76.16 95.91 114.30 146.95
WEIGHT 1.1 6.86 9.01 10.1011.26 12.68 13.97 14.64 20.01 21.90 23.58 30.29 35.69 38.20 45.42 54.57 61.75 63.14 67.42 70.85 83.77 105.50 125.73 161.64
PER
METRE 1.15 7.17 9.42 10.56 11.77 13.26 14.61 15.30 20.92 22.89 24.65 31.66 37.32 39.93 47.49 57.05 64.55 66.01 70.49 74.07 87.58 110.29 131.45 168.99 1.2 7.48 9.83 11.02 12.28 13.83 15.24 15.97 21.83 23.89 25.72 33.04 38.94 41.67 49.55 59.53 67.36 68.88 73.55 77.29 91.39 115.09 137.16 176.34 1.25 7.80 10.24 11.48 12.79 14.41 15.88 16.63 22.74 24.88 26.80 34.42 40.56 43.41 51.62 62.01 70.17 71.75 76.62 80.51 95.20 119.88 142.88 183.69 1.3 8.11 10.65 11.94 13.30 14.99 16.51 17.30 23.65 25.88 27.87 35.80 42.18 45.14 53.68 64.49 72.97 74.62 79.68 83.73 99.01 124.68 148.59 191.03
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(mm) 89 102 108 114 121 127 130 152 159 165 187 203 210 229 251 267 270 279 286 311 349 381 432
NOX Hazard
Nitrous oxide (N2O) Nitric oxide (NO) Converts to nitrogen dioxide in air Nitrogen dioxide (NO2) and its dimer nitrogen tetroxide (N2O4) Nitrogen trioxide (N2O3) Nitrogen pentoxide (N2O5).
Nitrogen dioxide is the principle hazardous nitrous fume Physical Properties of Nitrogen Dioxide
Colourless to reddish brown gas above 21C (70F) On contact with moisture, forms a mixture of nitric and nitrous acids Sweetish to pungent odour and acid taste Heavier than air Gas density 1.5 (air = 1) Non flammable but will accelerate burning of combustible materials
Any atmosphere in which nitrogen dioxide is noticeable by either smell, irritation or colour, should be regarded as dangerous Report exposure to your supervisor immediately and seek medical advise
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(4) Safety
All Operators must be aware of the STRETCH, SNAP and SHOOT phenomenon
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Perform QC Checks
Philippines Fatality with NOX Must determine that Gassing has started Correct density is being loaded Gassing rate not too fast Correct kilos per meter
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Screen Hierarchy
When user starts the PLC the HMI will boot up and move directly to the Dyno Nobel Welcome Page User is asked to enter Password and is taken directly to Production Page From Production Page there are password links to Calibration Page and trends page Trends page is available to all users and displays;
Flow Rates Pressure Data Temperature Data
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Production Screen