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1a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass.
1b. Students know how to use the periodic table to identify metals, semi-metals {metalloids}, nonmetals, and halogens 1e. Students know the nucleus of the atom is much smaller than the atom yet contains most of its mass.
Purpose
We will use this information to build our chemistry
knowledge. We will use this information as the foundation to calculate limiting reagent problems. The standardized exams in the spring will test you on this information.
Objectives
Know the 3 particles of the atom and where they reside
Know the difference between atomic number and mass number Know how to write nuclide symbols Know the three isotopes of hydrogen Know how to calculate atomic mass Know how to calculate percent composition
Vocabulary
Atom- from the Greek atomos=indivisible. The atom is the
smallest particle of an element that retains the properties of that element. Nucleus: the center of the atom; composed of neutrons and protons. Because the mass of the proton and the neutron is much larger than that of electrons, almost all the mass is located in the nucleus. Ion: a charged particle; # protons # electrons Electrons occupy most of the volume of an atom outside/around the nucleus.
Fundamental Particles
Proton A positively charged particle located in the nucleus. Neutron A neutral particle located in the nucleus. Electron A negatively charged particle located outside the nucleus.
Question
What differentiates one atom from another atom?
The number of PROTONS
A Z
El
Number of protons in the nucleus of an atom This number is found on the Periodic Table Atomic Number identifies an element Always a positive number (b/c it is a counting
Question
What observations can you make about atomic
left to right.
Questions
What is the atomic number of Chlorine? What can you tell me about its protons and electrons? What element has 20 protons?
What is the relationship between the # protons and
Symbol
K B S Y
Atomic #
19 5 16 39
# Protons
19 5 16 39
A Z
El
Total number of protons and neutrons in the nucleus of an atom You can determine the nuclear composition of an atom from its mass number and atomic number
Question
What do the atomic number and the mass number
have in common?
Both Positive integers Both have the same # of protons
Isotopes
Atoms of the same element with differing numbers of
neutrons Atoms with the same atomic number but different mass number Isotopes of an element have different masses Chemical properties of different isotopes are virtually the same
Nuclide Symbol
A Z
A=Mass # Z= Atomic #
El
Nuclide
A specific kind of atom Specification of an element in terms of its nuclear composition/structure Tells number of protons and number of neutrons
# protons Chemical Symbol Nuclide Symbol C 6 # neutrons [6, 7, 8] # electrons 6
13 6
19 9
29 14
47 22
Si
Mn
Ti
55
12
25
6
55 25
12 6
3 Isotopes of Hydrogen
Isotope Of Hydrogen Protium Deuterium Tritium Nuclide Symbol
1 1
# protons
# neutrons # electrons
1 1 1
0 1 2
1 1 1
2 1
3 1
Nuclides
By specifying the nuclear structure, then you call it a
nuclide.
But if you say Carbon atom, you do not know which
Carbon atom it is, therefore you dont know how many neutrons it has
Example: Brothers and Sisters You are members of the Jones family, but you have not specified which Jones member you are referring to.
Nuclide Symbol
37 17
Chlorine-37 Anion
Calcium-40 Cation Uranium-238
Cl
20
20
18
40 20
Ca
92
146
92
238 92
Atomic Mass
A weighted average of the atoms in a naturally
Weight of Each Piece 2 grapefruit 14 oz 4 apples 10 oz 3 pears 7 oz 1 kiwi 3 oz What is the Average Weight?
Fruit Basket
Average weight=9.2oz Each type of fruit makes a different contribution to the overall weight How many pieces of fruit actually weigh 9.2 ounces? None! What does 9.2 oz mean? Fictitious non-existent piece of fruit
Atomic Mass
If you have a recipe, you could count items to put in, say 200 chocolate chips, 3 eggs, etc. But suppose I have a recipe to make a compound.
I need 100 hydrogen atoms and 50 oxygen atoms-you
Question
What accounts for the mass of the atom? # protons & # neutrons in the nucleus
Atomic Mass
Know that 1.0 amu is defined as exactly 1/12 the mass of a 12 6 C atom. Carbon-12 has 6 protons and 6 neutrons, therefore 1 proton or 1 neutron = ~1 amu 1 amu = 1.6606 x 10 -24 grams Since the mass mostly depends on # protons and # neutrons, youd think atomic mass would be a whole number, but it isnt. How come?
Atomic Mass
In nature, most elements exist as a mixture of 2 or more isotopes.
Each isotope of an element has a fixed, constant mass and fixed constant
relative abundance.
Relative abundance(amount) X 100= (how much of each isotope is present) Virginia or Pennsylvania %
Atomic Mass of periodic table takes into account the larger and smaller
masses of the isotopes, just like the average piece of fruit accommodated the larger and smaller masses. Idea of weighted average
Cl-35
34.969
75.77%
Cl-37
36.935
24.23%
(34.969)(.7553) + (36.935)(.2447) =
Question
How many chlorine atoms actually have a mass of
35.45 amu?
NONE
Example
Isotope
B-10
Mass of Isotope
10.013
Relative Abundance
Atomic Mass
B-11
11.009
1- x
10.103 (x) + 11.009 (1 x) = 10.811 10.103x + 11.009 -11.009x = 10.811 -0.996x = -0.198 x = .1987 y= 1-.1987 y= .8013 B-10 = 19.87%
B-11 = 80.13%
The End