Professional Documents
Culture Documents
ANONDHO WIJANARKO
Chemical Engineering Study Program The University of Indonesia
Development Sector Project The 3rd Batch Retooling Program for Un / UnderEmployed Graduates of Chemical Engineering and Related Discilines
Definitions
Safety: Strategy of Accident Prevention
Loss Prevention: Prevention of accidents which result in injury to humans, damage to the environment, loss of production, damage to equipment, or loss of inventory.
Safety Goals
Prevent: Death/injury to workers Death/injury to the general public
Many potential dangerous chemical substances (risk) Death or personal injury High potential magnitude of the occured explosion Financial loss occured after disaster accident (loss, damage or destruction of property other than the product itself) Health-care continuous exposure to error (impact)
$1.35BN
INDUSTRI KIMIA
$1.4BN $1.2BN
$950M
$1BN
$800M $600M $400M $200M $0
$110M $440M $300M
'98
'99
'00
'01
$150M $ 75M $ 70M
'02*
* 02 Loss Exceeding $50M include: Gas, plant fire, Kuwait Refinery fire, Japan Power station flood, Washington State
Chemical Hazards
Definitions
Hazard: An inherent physical or chemical characteristic of a material, system, process or plant that has the potential for causing harm.
Chemicals provide additional hazards due to the toxic, flammable, explosive, and reactive hazards. Risk: For episodic events, risk is a function of probability and consequence.
Statistics
OSHA Chemical Industry Steel Industry Coal Mining Agriculture Staying at Home Travelling by Car Rock Climbing 20 Cigarettes / day Struck by Meteorite Struck by Lightning Fire Run over by Car
OSHA FAR FR Occupational Safety & Health Administration Fatal Accident Rate Fatality Rate
incidence rate per 100 worker years = 200,000 h exposure fatalities per 1000 employees and entire life = 108 h exposure per person per year (exposure poorly defined)
FAR 4 8 40 10
FR
3 57 4000
17 x 10 4 x 10 -5 -5 500 x 10
6 x 10 -7 1 x 10 150 x 10 -7 -7 600 x 10
-11
-5
Statistics
US Accident Fatalities:
Auto: Total Industry:
1990
47,000 6,217
1999
40,800 6,026
6,475
642 601
5,220
Airlines:
Home: Chemical Industry:
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22,500 22
10
30,800
100
500 10.000
Accident Pyramid
Occupational Safety and Health
vapor cloud
11
Nature of Accidents
arson & sabotage
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Nature of Accidents
gages pum ps com pressors tow ers valves heat exchangers holding tanks reactor piping storage tanks unknow n piping system s 0 5 10 15 20 25 30
HARDWARE INVOLVED
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Defeating Accidents
STEP Step Initiation DESIRED Desired Effect EFFECT
Diminish
PROCEDURE
Grounding, bonding Inerting Explosion proof electrical Guardrails and guards Maintenance procedures Hot-work permits Human factors design Process design Awareness properties chemicals Emergency material transfer Reduce inventories of flammables Equipment spacing and layout Nonflammable construction materials Emergency shut-off valves Firefighting Relief systems Sprinklers Emergency shut-off valves
Propagation
Diminish
Termination
Increase
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FLIXBOROUGH, UK (1974) C
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FLIXBOROUGH, UK (1974) C
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FLIXBOROUGH, UK (1974) C
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FLIXBOROUGH, UK (1974)
vapour cloud explosion
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19
20
21
Toxic release
PIPER ALPHA
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PIPER ALPHA
$2 Billion in losses
Occupational Safety and Health 25
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Incident Description
On April 9, 1998, at approximately 11:28 pm, an 18,000gallon propane tank exploded at the Herrig Brothers Feather Creek Farm (the farm) in Albert City, Buena Vista County, Iowa. The explosion killed two volunteer fire fighters and injured seven other emergency response personnel. Several buildings were also damaged by the blast.
Occupational Safety and Health 29
Incident Description On February 19, 1999, a process vessel containing several hundred pounds of hydroxylamine exploded at the Concept Sciences Inc. production facility near Allentown, Pennsylvania. Employees were distilling an aqueous solution of hydroxylamine and potassium sulfate, the first commercial batch to be processed at the facility. After the distillation process was shut down, the HA in the process tank and associated piping explosively decomposed, most likely due to high concentration and temperature. Four CSI employees and a manager of an adjacent business were killed. Two CSI employees survived the blast with moderate-to-serious injuries. Four people in nearby buildings were injured. The explosion also caused significant damage to other buildings in the Lehigh Valley Industrial Park and shattered windows in several nearby homes.
Occupational Safety and Health 30
Leak led to flammable vapor release and explosion 7 people killed, 50 injured $400 Million in losses
Off-shore oil platform explosion 10 people killed, $5 Billion in losses Platform sank into the Atlantic Ocean
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Ammonium Nitrate Explosion in Toulouse - France 21 September 2001 31 People Killed 2442 Injured Losses in Hundreds of millions dollars
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Incident Description On July 17, 2001, an explosion occurred at the Motiva Enterprises LLC Delaware City Refinery (DCR) in Delaware City, Delaware. Jeffrey Davis, a boilermaker with The Washington Group International, Inc. (WGI), the primary maintenance contractor at DCR, was killed; eight others were injured. A crew of WGI contractors was repairing grating on a catwalk in a sulfuric acid storage tank farm when a spark from their hot work ignited flammable vapors in one of the storage tanks. The tank separated from its floor, instantaneously releasing its contents. Other tanks in the tank farm also released their contents. A fire burned for approximately one-half hour; and sulfuric acid reached the Delaware River, resulting in significant damage to aquatic life.
Occupational Safety and Health 35
Incident Description On April 25, 2002, an explosion occurred at Kaltech Industries, a sign manufacturer in the Chelsea neighborhood of New York City, injuring 31 people seriously enough to seek hospital treatment, including 14 members of the public. The explosion, which was the result of a reaction between waste chemicals, originated in the basement of a mixed-use commercial building and caused damage as high as the fifth floor.
Occupational Safety and Health 36
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Incident Description
On October 13, 2002, a violent explosion occurred in a chemical distillation tower at First Chemical Corporation in Pascagoula, Mississippi, sending heavy debris over a wide area. No one was seriously injured or killed in the incident, which occurred early on a Sunday morning. One nitrotoluene storage tank at the site was punctured by explosion debris, igniting a fire that burned for several hours.
Occupational Safety and Health 38
Incident Description On December 11, 2002, one maintenance employee was overcome when he inhaled hydrogen sulfide gas from a waste processing vessel at Environmental Enterprises, a hazardous waste treatment company in Cincinnati, Ohio. No other injuries or damage were reported, and the injured worker was subsequently pulled to safety.
Occupational Safety and Health 39
Incident Description On January 13, 2003, a vapor cloud fire erupted at the BLSR Operating Ltd. oilfield waste disposal facility near Rosharon, Texas, south of Houston. The fire occurred as two vacuum trucks were delivering flammable gas condensate waste for disposal at the facility. Two BLSR employees and one truck driver were fatally burned. Two other workers suffered serious burns but survived. Occupational Safety and Health 40
Incident Description
On January 29, 2003, an explosion and fire destroyed the West Pharmaceutical Services plant in Kinston, NC, causing six deaths, dozens of injuries, and hundreds of job losses. The facility produced rubber stoppers and other products for medical use. CSB investigators have found that the fuel for the explosion was a fine plastic powder used in producing rubber goods. Combustible polyethylene dust accumulated above a suspended ceiling over a manufacturing area at the plant and was ignited by an unknown event. Occupational Safety and Health
41
Incident Description At 7.30 am February 20, 2003, an explosion and fire damaged the CTA Acoustics manufacturing plant in Corbin, KY. 44 workers were injured, 12 were flown to critical care hospitals, and 7 died. The facility produced fiberglass insulation for the automotive industry. CSB investigators have found that the explosion was fueled by resin dust accumulated in a production area, likely ignited by flames from a malfunctioning oven. The resin involved was a phenolic binder used in producing fiberglass mats.
Occupational Safety and Health 42
Incident Description On the morning of April 11, 2003, one worker was killed at the D.D. Williamson food additive plant in Louisville, KY, when a process vessel became overpressurized and failed catastrophically. The failure caused a release of aqueous ammonia as well as extensive damage to the plant, which manufactures caramel coloring.
Occupational Safety and Health 43
Incident Description On July 20, 2003 there was a release of chlorine gas from the Honeywell chemical plant in Baton Rouge, Louisiana. The accident resulted in the hospitalization of four plant workers and required about 600 nearby residents to shelter in their homes. Several residents also sought medical evaluation. The plant manufactures refrigerants using chlorine and other potentially hazardous materials.
Occupational Safety and Health 44
Seveso, Italy (1976) herbicide plant, runaway reaction, chemical release, 447 injured, long term health problems, $50,000,000 Bhopal, India (1984) - pesticide plant, chemical release, 2,500 dead, 200,000 injured, $250,000,000
Chernobyl, USSR (1986) nuclear reactor, 31 dead, 237 injured, long term health problems, $3,000,000,000. Basle, Switzerland (1986) chemical warehouse fire, 0 dead, 0 injured, environmental damage.
Occupational Safety and Health 45
Regulatory Concerns
OSHA - Occupational Safety and Health Administration
Force of law with respect to on-site workplace hazards / accidents.
EPA RMP - Risk Management Plan - Considers offsite impacts due to fires / explosions / toxic release - Must perform risk assessment - Must perform consequence analysis
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ACCIDENTAL PREVENTION
As Rinard (1990) has poignantly noted, The regulatory control system affects the size of your paycheck; the safety control system affects whether or not you will be around to collect it.
Occupational Safety and Health 48
2.
3.
4.
5.
5.
Multiple Layers
Protection
In modern plants, process safety relies on the principle of multiple protection layers; Typical layers of protection in a modern chemical plant (CCPS 1993). Each layer of protection consists of a grouping of equipment and/or human actions, shown in the order of activation.
51
Basic process control system (BPCS) is augmented with two levels of alarms and operator supervision or intervention. An alarm indicates that a measurement has exceeded its specified limits and may require operator action. Safety interlock system (SIS) is also referred to as a safety instrumented system or as an emergency shutdown (ESD) system. The SIS automatically takes corrective action when the process and BPCS layers are unable to handle an emergency, e.g., the SIS could automatically turn off the reactant pumps after a high temperature alarm occurs for a chemical reactor.
Rupture discs and relief valves provide physical protection by venting a gas or vapor if over-pressurization occurs (also flares for combustibles).
Occupational Safety and Health 52
Types of Alarms
Type 1 Alarm: Equipment status alarm. Pump is on or off, or motor is running or stopped. Type 2 Alarm: Abnormal measurement alarm. Measurement is outside of specified limits. Type 3 Alarm: An alarm switch without its own sensor. When it is not necessary to know the actual value of the process variable, only whether it is above (or below) a specified limit. Type 4 Alarm: An alarm switch with its own sensor. This serves as a backup in case the regular sensor fails. Type 5 Alarm: Automatic Shutdown or Startup System.
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Duty Re-Safety
Employer
physical environment
method of performing work
safe
suitable
equipment
co-workers
Occupational Safety and Health 59
competent
60
Peraturan/standar ILO berupa panduan praktis yang ditetapkan di industri dalam upaya mencegah terjadinya kecelakaan-kecelakaan besar seiring dengan kenaikan produksi, penyimpanan dan penggunaan bahan berbahaya Tujuan panduan praktis adalah untuk memberikan arahan tentang pengaturan administasi, hukum dan sistem teknis untuk pengendalian instalasi bersiko tinggi yang dilakukan dengan memberikan perlindungan kepada pekerja, masyarakat dan lingkungan dengan mencegah terjadinya kecelakan besar yang mungkin terjadi dan meminimalisasikan dampak dari kecelakaan tersebut Penerapan panduan praktis dilakukan pada instalasi beresiko tinggi yang diidentifikasikan dengan keberadaan zat-zat berbahaya yang membutuhkan perhatian tinggi.
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Instalasi beresiko tinggi berdasarkan jenis dan kuantitasnya menurut panduan praktis:
Industri kimia dan petrokimia Industri penyulingan minyak Instalasi penyimpanan gas alam cair (LNG) Instalasi penyimpanan gas dan cairan yang mudah terbakar Gudang bahan-bahan kimia Instalasi penyulingan air bersih dengan menggunakan klorin Industri Pupuk dan Pestisida
Instalasi beresiko tinggi berdasarkan jenis dan kuantitasnya diluar cakupan panduan praktis:
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Instalasi beresiko tinggi adalah instalasi industri permanen atau sementara, yang menyimpan, memproses atau memproduksi zatzat berbahaya dalam bentuk dan jumlah tertentu menurut peraturan yang berlaku yang berpotensi menjadi penyebab terjadinya kecelakaan besar. Identifikasi bahan berbahaya menurut jenis dan tingkat kuantitas ambang terjadinya kecelakaan besar Bahan kimia sangat beracun : methyl isocyanate, phosgene Bahan kimia beracun: acrylonitrile, ammonia, chlorine, sulphur dioxide, hydrogen sulphide, hydrogen cyanide, carbon disulphide, hydrogen fluoride, hydrogen chloride, sulphur trioxide Gas dan cairan mudah terbakar Bahan peledak: ammonium nitrate, nitroglycerine, C4, PETN, TNT
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Alur informasi pada instalasi beresiko tinggi Manajemen keseluruhan instalasi beresiko tinggi harus melaporkan secara rinci aktifitasnya kepada pihak yang berwenang Laporan keselamatan kerja instalsi beresiko tinggi harus disiapkan oleh manajemen dan berisi informasi teknis tentang disain dan cara kerja instalasi, penjelasan rinci manajemen keselamatan kerja dalam instalasi, informasi tentang bahaya dari instalasi secara sistematis, teridentifikasi dan terdokumentasi serta informasi tentang bahaya kecelakaan dan ketentuan keadaan darurat yang akan mengurangi dampak dari kecelakaan yang akan terjadi. Semua informasi khususnya yang berkenaan dengan instalasi beresiko tinggi harus disediakan bagi para pihak yang berkepentingan. Informasi keselamatan kerja yang tepat khususnya pada instalasi beresiko tinggi dikomunikasikan melalui pelatihan kepada pekerja, dan dapat digunakan untuk persiapan pekerjaan dan pengendalian dalam keadaan darurat.
Occupational Safety and Health 64
Audit Instalasi beresiko tinggi Instalasi beresiko tinggi diaudit oleh manajemen audit yang ditunjuk pemegang otoritas sesuai dengan ketentuan yang berlaku di wilayah instalasi itu berada Audit mencakup identifikasi kejadian tidak terkendali yang memicu timbulnya kebakaran, ledakan atau terlepasnya zat-zat beracun Audit mencakup estimasi potensi bahaya sebagai konsekuensi dari ledakan, kebakaran maupun terlepasnya zat-zat beracun Audit mempertimbangkan potensi efek lanjutan yang terjadi pada instalasi beresiko tinggi lainnya yang ada disekitarnya Audit mempertimbangkan kesesuaian pengukuran keselamatan kerja yang digunakan dalam identifikasi kemungkinan terjadinya bahaya untuk menjamin validitas hasil audit itu sendiri Audit memperhitungkan analisa resiko secara menyeluruh dari keterkaitan antara kecelakaan besar yang mungkin timbul dengan letak instalasi beresiko tinggi itu sendiri.
Occupational Safety and Health 65
Manajemen pengendalian resiko kecelakaan dan pengamanan pada instalasi beresiko tinggi meliputi: Disain, fabrikasi dan penginstalasian pabrik yang aman, termasuk penggunaan komponen peralatan bermutu tinggi Pemeliharaan pabrik secara rutin Pengoperasian pabrik sesuai prosedur yang berlaku Pengelolaan keselamatan lingkungan kerja secara baik Inspeksi secara rutin terhadap keseluruhan instalasi yang diikuti dengan perbaikan atau penggantian komponen peralatan yang dibutuhkan Pengawasan rutin terhadap keamanan dan sistem pendukungnya Ketersediaan dan inspeksi rutin peralatan keselamatan kerja yang dapat digunakan dalam kondisi darurat Analisa bahaya dan resiko yang terjadi akibat kerusakan komponen peralatan, pengoperasian instalasi yang abnormal, faktor kesalahan manusia dan manajemen, pengaruh kecelakaan yang terjadi di sekitar instalasi, bencana alam, tindakan kejahatan dan sabotase Analisa komprehensif terhadap modifikasi peralatan dan instalasi baru Penyebaran informasi dan pelatihan keselamatan kerja bagi setiap pekerja pada instalasi tersebut Penyebaran informasi secara berkala kepada masyarakat yang tinggal atau bekerja di sekitar lokasi instalasi industri
Occupational Safety and Health 66
Analisa Bahaya dan Resiko meliputi: Identifikasi bahan beracun, reaktif dan eksplosif yang disimpan, diproses atau diproduksi Identifikasi kegagalan potensial yang dapat menyebabkan kondisi pengoperasian abnormal dan menimbulkan kecelakaan Analisa konsekuensi dari kecelakaan yang terjadi terhadap pekerja dan masyarakat sekitar Tindakan pencegahan terhadap terjadinya kecelakaan
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HAZOP (an example of Hazard and Risk Analysis) Identifikasi penyimpangan/deviasi yang terjadi pada pengoperasian suatu instalasi industri dan kegagalan operasinya yang menimbulkan keadaan tidak terkendali Dilakukan pada tahap perencanaan untuk instalasi industri baru Dilakukan sebelum melakukan modifikasi peralatan atau penambahan instalasi baru dari instalasi industri lama Analisa sistematis terhadap kondisi kritis disain instalasi industri, pengaruhnya dan penyimpangan potensial yang terjadi serta potensi bahayanya Dilakukan oleh kelompok para ahli dari multi disiplin ilmu dan dipimpin oleh spesials keselamatan kerja yang berpengalaman atau oleh konsultan pelatihan khusus
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Bertujuan untuk melokalisasi bahaya dan meminimalisasi dampaknya Identifikasi jenis-jenis kecelakaan yang potensial On site emergency
Perencanaan keadaan darurat didasarkan pada konsekuensi yang timbul dari kecelakaan besar yang potensial Penanganan keadaan darurat dilakukan tenaga penanggulangan kecelakaan dalam jumlah yang cukup Perencanaan keadan darurat merupakan uji dan pengidentifikasian kelemahan instalasi industri yang akan secepatnya diperbaiki Antisipasi bahaya dengan memperhatikan: kekerapan terjadinya kecelakaan, hubungan dengan pihak berwenang di luar lokasi, prosedur menghidupkan tanda bahaya, komunikasi internal dan eksternal instalasi serta lokasi dan pola pengaturan dari pusat pengelola gawat darurat Fasilitas penanganan keadaan darurat: telepon, radio dan alat komunikasi internaleksternal yang memadai, peta yang menunjukan keberadaan bahan berbahaya, alat penunjuk arah dan pengukur kecepatan angin, alat penyelamatan diri, daftar lengkap pekerja, ... Perencanaan disiapkan oleh dan merupakan otoritas yang kompeten yang diatur melalui kebijakan, peraturan atau perundangan. Perencanaan ini merupakan antisipasi dari bahaya dalam skala besar dan penanganannya terkait dengan otoritas lokal penanggulangan kecelakaan Perencanaan didasarkan pada informasi atas konsekuensi yang timbul dari kecelakaan besar yang potensial
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Membuat analisa bahaya dan resiko serta mempersiapkan laporan keselamatan kerja bekerjasama dengan manajemen audit
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Menetapkan garis besar disain dan operasi instalasi industri yang aman, serta pengaplikasiannya dalam desain peralatan, proses kendali, pengoperasian secara manual, ... Menganalisa konsekuensi dari kecelakan potensial dengan permodel dampak potensialnya Menetapkan penanganan keadaan darurat on site dan perencanaan keadaan darurat off site Melakukan pelatihan pada pekerja
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3 unsur keberlakuan UU Tempat dimana dilakukan pekerjaan bagi suatu usaha. Adanya tenaga kerja yang bekerja disana. Adanya sumber-sumber bahaya kerja di tempat itu.
Pengawasan Keselamatan Kerja Pengawasan secara langsung dilakukan pegawai pengawas dan ahli keselamatan kerja. Pengawasan secara tidak langsung termasuk oleh manajemen puncak yang hanya melakukan audit terhadap usaha perbaikan dari hasil pelaporan pegawai pengawas dan ahli keselamatan kerja.
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UNDANG-UNDANG KESELAMATAN KERJA mengatur keselamatan kerja disegala tempat kerja baik itu di darat, laut dan udara dalam wilayah NKRI UNDANG-UNDANG KESELAMATAN KERJA bertujuan untuk mengurangi kecelakaan, mengurangi adanya bahaya peledakan, memaksa peningkatan kemampuan pekerja dalam memberikan pertolongan pertama pada kecelakaan dan pemberian alat-alat pelindung kepada pekerja terutama untuk pekerjaan yang memiliki resiko tinggi serta membantu terciptanya lingkungan kerja yang kondusif seperti penerangan tempat kerja, kebersihan, sirkulasi udara serta hubungan yang serasi antara pekerja, lingkungan kerja, peralatan dan proses kerja.
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Sumber bahaya kerja diidentifikasikan terkait erat dengan: Kondisi mesin, pesawat, alat kerja serta peralatan lainnya Bahan berbahaya (Explosive, Flameable, Poison) Lingkungan Sifat pekerjaan Cara kerja Proses produksi
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UNDANG-UNDANG KESELAMATAN KERJA berisi petunjuk teknis mengenai apa yang harus dilakukan oleh dan kepada pekerja untuk menjamin keselamatan pekeja itu sendiri, keselamatan umum dan produk yang dihasilkan karena begitu banyak proses yang dilakukan dengan memperhatikan perkembangan ilmu pengetahuan dan teknologi yang menyebabkan perubahan resikko pekerjaan yang dihadapi pekerja di tempat kerjanya.
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Pengawasan Keselamatan Kerja Monitoring dan pengambil keputusan tindakan perbaikan keselamatan kerja Tindakan perbaikan keselamatan kerja (Continuous Improvement) seperti perbaikan cara dan proses kerja, pemeriksaan rutin kesehatan pekerja, retribusi keselamatan kerja.
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HAZARD MANAGEMENT
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Latar Belakang
Kecelakaan industri terutama disebabkan oleh HUMAN FAILURE, di mana sering ditemukan faktor manusia dalam penelusuran sebab terjadinya kecelakaan. Pencegahan kecelakaan harus menempati perhatian yang khusus dalam fungsi manajerial secara keseluruhan. Bagian manajemen kekhususan (insinyur, teknisi, perancang, field operator, lembaga pelatihan) sering kurang menghargai kebutuhan untuk mengaplikasikan prinsip-prinsip pencegahan terhadap kecelakaan di dalam lingkup kerja mereka. Metode yang tidak aman merupakan proporsi tertinggi dari penyebab terjadi kecelakaan. Keselamatan harus menjadi bagian yang integral dari pelaksanaan industri manapun, dan harus menjadi bahan pertimbangan sejak tahap perancangan, tahap perencanaan produksi, serta pelatihan operator.
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Lapse Mistake
Failure of memory
Omit step Lose place Forget intention Wrong procedure
Intended actions
Rule breaking
Violation Sabotage
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Human Error
Easy to cite human error as a cause for a disaster. Old View Human Error is a major cause of accidents (70%). Complex systems fine if it wasnt for unreliable people (bad apples)
To explain failure investigators seek human failure look for error Today looking at human factors (ergonomics) issues that cause human error Disasters and human error Paddington, Southall, Bhopal, Zeebrugge, Three Mile Island, Kegworth, Kings Cross Fire, Chernobyl, Camelford, Piper Alpha, Hillsborough..... Smaller scale accidents account for > 200 deaths and 180000 injuries each year
Occupational Safety and Health 82
Human Error
Labels such as situation awareness, attention, complacency, stress, workload all human error Lack of situation awareness suggests we know what happened at the time they didnt and made an error Human Error or systems failure not a choice Human error is connected to system Human error is the starting point Need to find enduring features of the operational environment that led to behaviour Human error symptom of trouble in system Dont explain failure by finding where people went wrong Investigate how peoples actions made sense at the time given the circumstances around them Identify patterns of failure across sequences of events.
Occupational Safety and Health 83
Recommendations
To protect systems from human behaviour recommendations include: Tighten procedures = less room for error Often a mismatch between rules & reality More technology to monitor/replace human work Relocates or changes potential for human error Punish those making errors
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Hindsight
Able
to look back on sequence of events that led to outcome you already know Unlimited access to true nature of situation at the time Allows peoples errors to be spotted Hindsight biased towards items now known to be important An external perspective
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Analisa HAZID (Hazard Identification) Proses pengidentifikasian terhadap bahaya yang mungkin terjadi secara umum pada fasilitas operasi sebuah pabrik/ industri.
Analisa HAZOP Identifikasi keselamatan, bahaya & masalah operasi yang berhubungan dengan proses yang secara langsung mengancam keselamatan pekerja produksi/penyebab masalah operasi. Menentukan keseriusan dampak masalah teridentifikasi. Identifikasi secara engineering & procedural safeguards yang sebelumnya telah dibuat. Evaluasi kelayakan engineering & procedural procedural safeguards. Rekomendasi safeguards atau prosedur operasi tambahan jika diperlukan.
Occupational Safety and Health 87
AN ACCIDENT
Can
an
unplanned release of chemical warfare agent into environment at levels which exceed those permitted by state or federal regulations more conservative definition is any unplanned event that could lead to the release of chemical warfare agent
89 CA59
SIZE OF ACCIDENT
Important to know amount of material accidentally released Amount of material released called source term Source term and weather conditions at time of release determine
how far downwind hazardous materials will travel concentration of chemical warfare agent to which people could be exposed
90 CA60
important to know how close people might be to a potential accident site and their location with respect to airborne agent plume
91 CA61
ACCIDENT LIKELIHOOD
Most likely accidents are small ones that do not pose a threat except to someone in very close proximity to accident Large accidents (source terms large enough to pose a threat to community) have much lower probability of occurring Unlikely that an accident will cause injury or death to anyone
92 CA62
Engineers and scientists systematically studied different ways accidents could occur and estimated how likely events were that caused an accident They estimated probabilities of many different accidents and calculated number of fatalities that could occur for each accident They calculated the consequences of each accident
Risk =
Probability of Accident
X
(Times)
Consequences
(Summed)
Calculation of risk
93 CA63
If accident large enough to pose threat to public, dominant hazard is from breathing air in which agent exists as vapor Paths for liquid chemical warfare agent to travel from accident to off-site are limited and relatively easy to block therefore people offsite unlikely to encounter liquid agent
94 CA64
95
CA65
SPILL
Onto
ground or other surfaces Resulting puddle of agent (liquid deposition) can evaporate into vapor and drift downwind
EXPLOSION
Causes droplets of agent to be formed Larger, heavier droplets quickly fall to ground (deposition) Releases vapors and aerosols (smaller droplets and particles) that can travel greater distances
FIRE
Both aerosols and vapors are formed Vapors and aerosols lifted higher into air because of heat from fire Hazard similar to those of an explosion
Think of a chemical agent release in terms of hair spray coming from a spray can:
when spray is release, it is an aerosol larger particles and/or droplets are deposited near point of release particles quickly fall out of air onto hair and skin person across room can smell hair spray from breathing vapors released
99 CA69
is very unlikely the public would be exposed to droplets and aerosols Particles will mostly fall out of plume (via deposition) by time plume reaches installation boundary
100 CA70
VAPOR HAZARD
For
most accidents, the primary health hazard comes from vapors when they are breathed in or come in contact with skin or eyes Agent vapors pose greatest hazard when inhaled because they are rapidly absorbed by lung tissues Lethal dosage for agent vapor breathed in is several times lower than lethal dosage for vapor contact with skin
Occupational Safety and Health 101 CA71
ACCIDENT CATEGORIES
Selection of protective action strategies contingent on characteristics of accident Accident categories are group of accident scenarios bound together by common source terms and meteorological conditions Designed to support grouping of large number of protective action strategies Each installation has set of accident categories
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CA72
Standard chemical accident notification Provides a common language between installation and off-site emergency responders Fosters clear understanding and ready reference for emergency response actions Off-site response consists of 4 levels
nonsurety (does not involve chemical warfare agents) limited area, post-only, and community emergencies (involve chemical warfare agents)
Occupational Safety and Health 103
CA73
NON-SURETY EMERGENCY
General
interest to public Poses no chemical surety hazard Action: Notification to IRZ designated Army Installation Boundary points of contact
Limited Area Boundary
104
CA74
Declared when predicted chemical agent no-effects dosage does not extend beyond chemical limited area Action: Notification of IRZ and State points-of-contact IRZ emergency response officials may go to level of readiness
Army Installation Boundary
105
CA75
POST-ONLY EMERGENCY
Declared when predicted chemical agent noeffects dosage extends beyond chemical limited boundary but not installation boundary Not expected to present danger to off-site public Action: Notification of IRZ, PAZ, Army Installation Boundary and State-designated points-of-contact
IRZ response organizations mobilize precautionary protective actions may be initiated in nearby areas
Plume
106
COMMUNITY EMERGENCY
Declared when predicted chemical agent noeffects dosage extends beyond installation boundary Action: Notification of IRZ, PAZ, and State-designated Army Installation Boundary points-of-contact
all emergency response organizations mobilize IRZ and affected PAZ areas implement specified protective actions
107
CA77
108
109
2. Physical Hazards
1. 2. 3. 4.
1. Chemical Hazards
Noise
Vibration Temperature extremes Electromagnetic Radiation A. Ionizing (X-rays) B. Non-ionizing (Lasers, infrared and radio waves microwaves,) Illumination
the in
from
3. Ergonomic Hazards
Physical Stressors such as repetitive motion, heavy lifting, awkward or static postures, fatigue, excessive force, direct pressure and overexertion. Psychological Stressors such as monotony, perceptual confusion or overload.
Can exist in the form of solids, liquids, gases, mists, dusts, fumes and vapors.
110
4. Biological Hazards
Microbiological, such as bacteria, viruses, fungi, molds, and protozoa; Macrobiological, such as insects, parasites, plants and animals. On occasion, this hazard involves a
111
The Three States of Hazard Matter Solid Solids have a definite shape and volume. Particles can be solid or liquid. Hazardous solid particles include silica, asbestos, lead, fumes, bacteria, fungi, fiberglass, wood, beryllium, phosphorus, and miscellaneous dusts. Liquids have an indefinite shape and take on the shape of the container in which they are contained. Liquid particles vary in size from aerosols, to mists and the much larger drops. Aerosols are an inhalation hazard. Larger particles are a skin absorption or ingestion hazard. Hazardous liquids or liquid particles include solvents such as turpentine, benzene, and alcohol. Flammable or combustible liquids, and numerous organic and inorganic compounds such as paint thinners, coatings, paints, dry cleaning liquids, and pesticides. Gases take on both the shape and volume of their containers. Gases are materials whose physical state is a gas at normal temperature (All materials exist in the gas phase if the temperature is high enough). Vapors are gases formed when liquid evaporates. Hazardous simple asphyxiant gases include helium, nitrogen, hydrogen, and methane. Hazardous chemical asphyxiant gases include carbon monoxide, hydrogen cyanide, and hydrogen sulfide. The hazards of other gases is determined by their health and toxic effects. Some of these include hydrogen fluoride, sulfur dioxide, phosgene and ozone.
Liquid
Gas
112
Chemicals are present in the form of liquids, solids, vapors, gases, dusts, fumes and mists. The hazard potential presented by a chemical depends on which form it takes, as well as characteristics such as solubility, particle size and toxic properties.
Fumes Volatilized solids that condense when they contact air. Very small, solid particles created when hot vapor reacts with the air to form an oxide. Often associated with welding operations
113
Gas vs. Vapor Gases are materials whose physical state is a gas at room temperatures. Commonly formed by arc-welding and internal combustion engines Exist where gases such as chlorine and are being used in a working process. fluorine
Organic molecules such as gasoline, benzene and solvents are commonly observed examples.
Solvents with low boiling points form vapors eadily at room temperature.
Occupational Safety and Health 114
Fibers
Solid particles having a slender, elongated shape several times as great as their diameter. Commonly found in construction, mining, friction products and insulation materials.
Hazardous Material
Materials that were flammable, explosive, corrosive, toxic, radioactive or if it readily decomposes to oxygen at elevated temperatures.
116
MATERIAL WHICH BECAUSE OF ITS QUANTITY, CONCENTRATION, PHYSICAL OR INFECTIOUS CHARACTERISTICS MAY POSE A SUBSTANTIAL HEALTH HAZARD TO HUMANS OR THE ENVIRONMENT WHEN RELEASED OR SPILLED
117
HEALTH HAZARD
HEALTH HAZARDS ARE THOSE WHICH MAY CAUSE MEASURABLE CHANGES IN THE BODY SUCH AS DECREASED PULMONARY FUNCTION
118
HEALTH HAZARD
ACUTE
HEALTH HAZARDS ARE LISTED IN TWO BROAD CATEGORIES
and
CHRONIC
Occupational Safety and Health 119
ACUTE
ACUTE
120
CHRONIC
CHRONIC
121
HEALTH HAZARD
In addition to the aforementioned definition of ACUTE and CHRONIC the following pages also fall into the category of HEALTH HAZARD
122
CARCINOGEN
A carcinogen is a chemical that causes cancer in humans or has the potential to cause cancer (found causes cancer in laboratory animals)
123
CORROSIVE
A corrosive chemical is one that causes visible destruction of or IRREVISBLE alterations in living tissue by chemical action at the site of contact
124
125
Corrosive Materials
Materials that evoke a chemical process which converts minerals and metals into unwanted products
Acidity
(HCl, H2SO4, ClSO3H, HF, HCOOH, CHCOOH) Oxidizing agent (HClO4, H2SO4 , HNO3) Hygroscopic (H2SO4), Alkalis (KOH, NaOH)
Occupational Safety and Health 126
Corrosive Materials
Chemical
substances that, by direct chemical action, are injurious to living tissues or corrosive to metal surfaces The degree of hazard associated with a corrosive material is greatly dependent upon its physical state (solid, liquid, gas) Minor corrosive injury = irritation
127
Corrosive Liquids
Most
common cause of corrosive injury Corrosive liquids will destroy any living tissue but the most frequently injured organs are the skin and eyes. Corrosive vapors can also escape from some solutions (check out the interior of any acid cabinet). Fuming acids are particularly hazardous
Occupational Safety and Health 128
Concentrated alkalies are more damaging to tissues than most strong inorganic acids Alkaline solutions gelatinize and saponify tissues, producing deeply penetrating, painful burns Even weak alkaline solutions can dissolve skin fats and weaken the epidermis, making the skin more permeable to other agents Initial contact may not be painful poor warning property!
Occupational Safety and Health 129
action of acids is different from that of bases. Acids burn largely due to thermal action with moisture in tissues. When acids come into contact with skin, the acid reacts to form a (very slightly) protective barrier, whereas bases dissolve proteins.
130
corrosive liquid need not have a very high or low pH to be capable of causing corrosive injury. Many organic solvents can cause severe irritation of skin and mucus membranes by defatting tissues, which paves the way for secondary infections.
131
HF and gaseous hydrogen fluoride merit special discussion. These are easily the most hazardous corrosive materials encountered in the laboratory HF is extremely dangerous not only because it is an acid but because the fluoride ion is capable of traveling through layers of tissue on its way to the bone, producing severe, slow healing burns Always store/use HF solutions and hydrogen fluoride gas in a chemical fume hood never on the lab bench!
Occupational Safety and Health 132
Corrosive Gases
Most seriously hazardous of all corrosive materials! Readily absorbed into the body by dissolution in tissue moisture (e.g. in skin and/or respiratory tract and/or eyes). Severity of the corrosive effect and the region o the respiratory tract affected by exposure is greatly dependent upon the aqueous solubility of the chemical (see table on next slide). Always use/store corrosive gases in a chemical fume hood never ever on the bench!
Occupational Safety and Health 133
Corrosive Gases
Highly water soluble (upper respiratory tract) Medium aqueous solubility (upper respiratory tract and bronchi) Bromine Chlorine Iodine Phosphorus pentachloride Phosphorus trichloride Low aqueous solubility (easily reaches alveoli, causing delayed pulmonary edema Phosgene Nitrogen dioxide Ozone
Thionyl chloride
Sulfur dioxide
Occupational Safety and Health 134
HIGHLY TOXIC
A chemical which has the median lethal dose of: 50 mg per kg when administered orally 200 mg per kg by continuous contact for 24 hrs A chemical which has the median lethal concentration of: 200 parts per mil of gas or vapor or 2 mg per L of mist, fume or dust when continuously inhaled for one hour IN THE ABOVE DESCRIPTIONS DEATH OCCURS WITHIN THE TIME FRAME DESCRIBED IN LABORATORY ANIMALS
136
IRRITANT
An irritant chemical is one which is not corrosive but which causes a REVERSIBLE inflammatory effect on living tissue by chemical action at the site of contact
Occupational Safety and Health 137
SENSITIZER
A chemical which causes a substantial portion of exposed people to develop an allergic reaction in normal tissue after repeated exposure to the chemical
Occupational Safety and Health 138
139
FLAMMABLE MATERIALS
140
Flammable and combustible liquids are potential fuel sources for fires and are present in almost every workplace. It is actually the vapor created by flammable and combustible liquids that ignites and burns. It is important to understand what materials in your work area are flammable and combustible so that you may properly store and isolate them from ignition sources.
Occupational Safety and Health 141
Methyl formate
Kerosene Ethyl ether MEK Diethyl ether
142
The NFPA diamond is an easy way to determine the safety risks associated with hazardous materials. To determine a For example, An NFPA diamond onthe a red section of the materials flammability refer to can of gasoline A would have 3 in the will indicate the diamond. number in a this section red section indicating that gasoline flammability rating of the material. could ignite at normal working The following numbering system is used to temperatures.
indicate flammability
0- will not burn 1- must be preheated to burn 2-ignites when moderately heated 3-ignites at normal temperature 4-extremely flammable
Occupational Safety and Health
NFPA Diamond
143
Flammable Liquids
Flammable
liquids can cause a fire or explosion, and like many other substances, they can also cause serious health effects from overexposure.
3
Note: On the NFPA diamond label, a fire hazard rating of 3 or 4 denotes a flammable liquid.
Occupational Safety and Health 144
Flammable Liquids
The
The
vapors can easily ignite or explode. Flammable liquid vapors are heavier than air and may settle in low spots, or move a significant distance from the liquid itself.
Occupational Safety and Health 145
Explosive Limits
The
Lower Explosive Limit (LEL) is the lowest concentration that will ignite. The Upper Explosive Limit (UEL) is the highest concentration that will ignite. If the vapor concentration is between the LEL and UEL, there is serious risk of fire or explosion.
Occupational Safety and Health 146
Explosive Limits
Above the Upper Explosive Limit, the mixture is too rich to burn UPPER EXPLOSIVE LIMIT Explosive Range LOWER EXPLOSIVE LIMIT
Below the Lower Explosive Limit, the mixture is too lean to burn
Occupational Safety and Health 147
Flammability Relationships
Vapor Pressure Curve
Vapor pressure / concentration
UFL
Liquid Gas
LFL
Auto-ignition zone
Flash Point
AIT
Ambient Temperature
Temperature
148
Where can I find NFPA diamonds? The flashpoint of a liquid is the Product labels lowest temperature at which the Material Safety Data Sheets (ask your supervisor liquid for them)gives off enough vapor to be ignited. The lower the flashpoint, the How do I determine the flammability of greater the risk for ignition. chemicals that dont use the NFPA classification system?
The flashpoint of a chemical may be used to determine its flammability. Flashpoint information may be found on product Whats a labels or MSDS sheets.
Flashpoint?
Occupational Safety and Health 149
Flammable liquids are considered flammable because their flashpoints are < 100F. This means that flammable liquids burn easily at normal working temperatures. Combustible liquids have a flashpoint at or above 100F. These liquids are less hazardous than flammable liquids but still pose a risk. The volatility of flammable and combustible liquids requires special storage and handling 150 requirements. Occupational Safety and Health
Classification
Flammable Liquids
Class 1A Liquids having flashpoints below 73F and having a boiling point below 100F. Liquids having flashpoints below 73F and having a boiling point at or above 100F. Liquids have flashpoints at or above 73F and below 100F.
Class 1B
Class 1C
152
Combustible Liquids
A combustible
Note: Check your Material Safety Data Sheet (MSDS) sheet for the characteristics or classification of a particular liquid.
153
Combustible Liquids
Class II
Class III Class IIIA Class IIIB
are certain amounts of flammable and combustible liquids stored in each control area that are considered exempt.
If
these amounts are exceeded, then the area or building may have to be reclassified as a Hazardous Use Group under the building code.
155
Flammable liquids must be stored away from ignition sources in cool, well ventilated areas away from incompatible materials Limit the amount of flammable and combustible liquids to the minimum amount necessary. As a general rule, No more than 10 gallons of flammable materials should be outside of approved flammable liquid storage cabinets or approved storage rooms. Room storage limits of flammable and combustible materials depend on various factors such as sprinklers, and storage cabinets. Refer to the table on the following slide for storage guidelines.
Occupational Safety and Health 156
Storage Areas
Flammables should be stored in an approved cabinet in a cool, well ventilated area to avoid pressure buildup and vaporization.
157
Storage Areas
There
storage areas should have a fire protection system installed and must be approved for this use.
158
Storage Cabinets
Use
flammable liquid storage cabinets where greater quantities of liquids are needed.
Contrary to popular belief, these cabinets are not designed to contain a fire, but to prevent an outside fire from reaching the contents for a period of 10 minutes enough time to evacuate the area.
Occupational Safety and Health 159
IA
30 60 60 120 60
Occupational Safety and Health
IB
60 120 120 240 120
IC
90 180 180 360 180
160
II
120 240 240 480 240
IIIA
330 660 660
IIIB
13,200 26,400
unlimited
Limitations on Storage
The maximum storage of flammables and combustibles in any one area under the Virginia Fire Prevention Code is 60 gallons of flammables and 120 gallons of combustibles.
These quantities must be in an approved storage area, i.e. a flammables cabinet or other acceptable means.
Occupational Safety and Health 162
163
Storage Containers
Containers
not in use. Approved safety cans are recommended for smaller quantities.
The
spring-loaded safety cap prevents spillage, prevents vapors from escaping, acts as a pressure vent if engulfed in fire, prevents explosions and rocketing of the can!
Occupational Safety and Health 164
IA
IB
IC 1 5 5 60 660
165
166
Precautions
The
unsafe use, storage, dispensing, or disposal of flammable materials can be a prime source of fires and explosions.
Read
Precautions
Some
flammable liquids have a tendency to accumulate a static electric charge, which can release a spark that ignites the liquid.
Always
168
Precautions
To
bond containers, each container is wired together and one container is connected to a good ground point to allow any charge to drain away safely.
Because
there is no easy way to bond plastic containers, their use should be limited to smaller sizes (no more than 4L).
Occupational Safety and Health 169
Precautions
Overexposure
to flammable liquids may present health hazards. Consult the Material Safety Data Sheet (MSDS) on the material you will be using to identify health hazards and protective measures to be taken.
Occupational Safety and Health 170
Precautions
Effects
Irritation to respiratory passages, nausea, headaches, muscle weakness, drowsiness, loss of coordination, disorientation, confusion, unconsciousness, and death.
171
Precautions
Skin
Contact: irritated, dry, cracked skin, rashes, dermatitis. Eye Contact: burning, irritation, eye damage. Ingestion: irritated digestive tract, poisoning, death.
172
Sprinkled Building
Class 1A, Flammables Class 1B Flammables Class 1C Flammable Class II Combustibles Class III-A Combustibles
Note: Containers other than safety cans shall not be greater capacity than one (1) gallon. The number of two (2) gallon safety cans shall not exceed five (5). The number of one (1) gallon safety cans in use outside storage cabinets shall not exceed ten (10).
173
FIRE BEHAVIOR
174
and Energy are neither created nor destroyed, only changed in state Why Fire Load is a crucial part of scene size up
175
Self-sustaining chemical reaction yielding energy or products that cause further reactions of the same kind Fire rapid, self sustaining oxidation process accompanied by the evolution of heat and light of varying intensities
176
Ignition Temperature
Minimum
temperature to which a fuel, in air, must be heated to start self-sustained combustion without a separate ignition source.
177
Fire Triangle
Appropriate Model for Smoldering Fires
Heat
Fuel
Oxygen
Occupational Safety and Health 178
Fire Tetrahedron
Reducing Oxidizing Agent Agent (Fuel) Chemical Chain React. Heat
179
Oxidizing Agent
O2
fuel must normally be in a gaseous state to burn, putting solids and gasses into this state requires energy. Pyrolosis When a solid is heated, the combustible materials are driven from the material
181
The surface to mass ratio is inversely proportional to the amount of energy needed for ignition Placement of fuel (Horizontal vs. Vertical) Gasses are created by vaporization rather than pyrolosis Require less energy to convert to gas than pyrolizing solids Rate of evaporation is influenced by the material and the temperature
These tend to be the most dangerous, because no energy is necessary to convert them for ignition.
Occupational Safety and Health 182
FLAMMABLE LIMITS
Too Rich, nothing burns
HEAT
Causes
pyrolosis, vaporization, or production of ignitable vapors Provides the energy necessary for ignition Causes the continuous production and ignition of vapors so that the reaction can continue.
Occupational Safety and Health 184
Types of Heat
Chemical Most Common. When combustible is in contact with oxygen oxidation occurs and heat is generated. Electrical include resistance heating, overcurrent/overload, arcing, static, lightning etc. Mechanical Heat of friction (causing a belt on a pulley to burn), or heat of compression (why SCBAs are hot following filling) Nuclear
complex reaction that causes each of the other parts of the system to combine in precisely the right amounts and at the right times to continue
186
Products of Combustion
Heat Light Smoke Fire Gasses CO (Carbon Monoxide) HCN (Hydrogen Cyanide) CO2 (Carbon Dioxide) N2 (Nitrogen) And MANY others
187
188
CONDUCTION
Occurs
when a body is heated as a result of direct contact with a heat source Primary cause for fire spread early in fires Fire spread by heating a pipe in one room and starting a fire in another room
189
CONVECTION
Transfer
of heat energy by movement of heated liquids or gasses Heat you feel when your hand is above a candle/match Produces thermal layering Also can cause fire extension between floors
190
RADIATION
Transfer
medium Holding you hand to the side of a candle Major problem. This is frequently what causes fire extension to other buildings
191
192
PHASES OF FIRE
Incipient Rollover Steady
Phase
193
Steady State Minimal Flames High Temp Ventilation Limited (>15% 02) May be pre backdraft
194
Backdraft
Low
O2, High Heat, Smoldering Fire, High Fuel vapor concentrations Pressurized smoke exiting small openings Dense, gray yellow smoke Little or no visible flame Smoke stained windows Improper ventilation leads to explosion
Occupational Safety and Health 195
Thermal Layering
196
Extinguishment Theory
Remove any part of the Tetrahedron and the fire goes out
Reducing Oxidizing Agent Agent (Fuel) Chemical Chain React.
Heat
197
Fire doors need occasional maintenance and repairs to function properly and should be periodically checked. To test a fire door:
Open the door fully and allow it to swing shut. The door should close and latch completely by itself. Give the door a push after it closes to ensure that the latch has engaged. If the door is not operating properly contact FP&M for repairs. All areas should be properly sealed to prevent the escape of fire, heat and smoke. Common penetrations include holes in walls, around ducts, pipes, etc. These types of penetrations should be sealed with appropriate fire-stopping material.
198
Compartmentalization
Buildings are designed to prevent fire, heat, and smoke from spreading beyond locations of origination. Building elements such as fire walls, fire dampers, and fire doors, are designed to seal off one location from the next. This system is called compartmentalization. Compartmentalization increases the safety of evacuating building occupants because smoke and fire are not able to escape into exit passageways. Containment of fire and smoke reduces property damage and prevents small fires from growing into large fires. In order for compartmentalization efforts to be effective fire barriers must be maintained.
Occupational Safety and Health 199
Fire doors are designed to withstand fire, heat and smoke for a period of 20-minutes to 3 hours. Did you know that corridor office doors are fire doors and should have a 20 minute rating? Corridor laboratory doors should have a 60 minute rating. Fire Doors are required to:
Be Self Closing: fire doors should have a door closure that pulls doors completely shut after the door has been opened Have Positive latching: a positive latch locks a door in place so can open swing open freely.
Occupational Safety and Health 200
If a fire occurs in a location where the fire door has been wedged, smoke and heat will travel freely into exit corridors hindering or preventing occupant evacuation. Periodically Iowas State Fire Marshal inspects our campus and issues numerous citations for wedging or blocking open doors.
Keeping your door shut will keep out smoke or fire originating in other locations.
To hold open your door you may have an electromagnetic device installed.
-
This device releases a fire door upon activation of the fire alarm allowing it to close and latch.
201
Toxic Materials
Materials
which, upon entering an human body is capable of producing disease or death Toxicity factor consist of
(1) The quantity of the material (2) The rate and extent to which the material is absorbed into the bloodstream via intravenous, inhalation, intraperitoneal, intramuscular, subcutaneous, oral or cutaneous (3) The rate and extent to which the material is biologically transformed in the body to breakdown product.
202
Transportation Regulation
Toxic Materials
HEAVY
Botulinum Toxin, Ricin toxin, Epsilon toxin, Staphlococcus enterotoxin B, Shigella toxin (Shigella dysenteriae toxin or Stx , CAS # 75757-64-1), Shigellalike toxins produced by Escherencia coli O 157(Shigalike toxin 1, verotoxin 1, or Stx-1, and Shiga-like toxin 2, verotoxin 2 or Stx-2 )
TOXIC
GASES
Asphyxiant
(CO, HCN, NO), Irritant (NO2, H2S, SO2) Anesthetic (diethyl eter, N2O2)
ORGANIC PESTICIDES
Occupational Safety andParathion, Health 203 INSECTICIDE Aldrin, DDT, Chlordane,
TOXIC CHEMICALS
All
substances are intrinsically toxic (hazard) whether or not the inherent toxicity will become a risk depends on the Dose
received and the Recipients sensitivity to the chemical concentration The Dose received and the Recipients sensitivity can be combined in a dose/response curves to examine the response of a population to different levels of a toxin
Occupational Safety and Health 204
TOXIC CHEMICALS
205
CHEMICALS
The
dose/response curve shows that some exposure is necessary before most individuals respond. Hence, toxic effects of chemicals are concentration dependent
206
Acute toxicity: It involves lethal concentrations and short-term exposures Acute effects of a toxin appear immediately after exposure. The end point is usually death, hence it is used to derive LD50 An LD50 is a dose of a toxic chemical that kills half of the population. LD50 is obtained by plotting, for a given dose the proportion of the population that responded to that dose and all lower doses
Occupational Safety and Health 207
208
toxicity: It involves Sub-lethal concentration and long-term exposure Chronic toxicity test is used to derive Effective Dose (ED50): Is the dose by which half of the population has been affected Effect could be anything but death ED50 is obtained by plotting, for a given dose the proportion of the population that responded to that dose and all lower doses Chronic effects of a toxic response can last a long time or be permanent.
Occupational Safety and Health 209
end points of chronic toxicity could be: biochemical physiological These ends points may lead to responses at organism level (e.g. behavioral and production changes) Responses at organism level could lead to effects on population which could have implications at the community level Responses at community level could also be implicated at ecosystem level.
Occupational Safety and Health 210
Under chronic conditions the organism survives but production or gene frequency could be affected. This is the level (sublethal) of interest in ecotoxicology. Typical example is the effect of DDT on egg shell thinning in birds. Here the birds survived DDT exposure but their reproduction mechanisms was affected Unlike transient pollution which has a passing effect on gene frequency, chronic pollution changes the environment.
Occupational Safety and Health 211
Intentional Poisoning*
Advantages
Silent Precise targeting Depersonalized Safe for attacker
Gender
Male Female Unknown 46% 39% 16%
Profile
Caucasian Male Average or above intelligence Underachiever Personality defect Cowardly, nonconfrontational Nonathletic Neat and orderly, meticulous Careful planner Loner
Background
Public Physician Political Nurse Other Unknown 71% 8% 4% 4% 5% 9%
213
Potencies of Poisons
Agent
Botulinum toxin Ricin
Lethal dose
0.05 mg 0.5 mg
Strychnine
Sodium arsenite Sodium cyanide
100 mg
200 mg 250 mg
Thallium
1000 mg
Sources of Poisons
Commercial
Laboratories
Underground catalogs Antique drug collections
215
Plant-derived Oleander Poison hemlock Mushroom Ricin Atropine/belladonna Nicotine Strychnine Cyanogenic glycosides
Occupational Safety and Health 216
Poison plants readily available from nurseries, arboreta, backyards, wild areas
Datura
Oleander Autumn Poison Lantana crocus hemlock cardiac colchicine coniine glycosides
atropine
lantadene
217
Frequency
31%
9% 6% 3% 2%
Target
Energy generation
Nervous system
218
Poison Symptoms
Constricted/dilated pupils (opioids, organophosphates)
Breath odor (arsenic garlic) Hair loss (thallium)
Convulsions (strychnine)
Paralysis (botulism) Coma (depressants, hypnotics)
221
Arsenic
Can
be used as pesticide Affects skin, liver, nervous system Is a risk factor for lung cancer History and physical exam Urine test (can be affected by seafood consumption)
222
Arsenic As
Abundance
& Use
wood
efficiently
absorbed from gut excreted in urine, does not accumulate binds to SH groups
Occupational Safety and Health 223
Effects
arsine
gas = hemolysis/renal failure G.I. = bloody vomiting & diarrhea renal & vascular necroses--gangrene alopecia, mees lines, bronzing, garlic odor
Assessment
urine,
hair semi-reliable measured by AA, ICP, colorimetry treated with dimercaprol (BAL), DMSA
224
Arsenic Trioxide
1 to 2.5 mg/kg - potentially fatal dose binds to cellular proteins containing sulfhydryl groups decrease in glutathione
necessary for the metabolic detoxification of arsenic Abdominal pain, nausea/vomiting,malaise Neuropathies Pancytopenias Hepatitis Peripheral vascular disease Cardiovascular collapse
Common toxidrome:
225
Arsenic Trioxide
>500 years use in traditional Chinese medicine 1970s investigators in China reported its use in APL but were ignored by mainstream medicine Dual apoptotic and differentiation inducing properties Doses 0.06-0.2 mg/kg (~1/3 fatal dose) CR rates ~90% in de-novo APL
226
Dimercaprol (BAL) DMSO pre-existing renal disease, pregnancy, concurrent use of iron, G6PD
Occupational Safety and Health 227
Contraindications
Cadmium Cd
Abundance
found
& Use
w/Zn in 1:70 ratio no nutritional role used in electroplating, batteries, solder, plastics
Pharmacology
biological
substitutes
228
Effects
emphysema nephrotoxicity,
urine, urinary proteins measured by AA, ICP Zn administration confers protection chelation may increase bioavailability
Occupational Safety and Health 229
230
Dioxins
Dioxins What are they? Dioxin is a general term for hundreds of chemicals formed by burning chlorine based compounds with hydrocarbons (www.ejnet.org/dioxin, 2002) What do they do? They get into the air, then soil and water, and then our food chain They attach and accumulate in our fat cells Dioxin is passed onto our children Through placenta, and breastfeeding We have no defense because it is not metabolized in our bodies It can cause serious health problems at parts per trillion (www.acereport.org,2003)
231
(www.ejnet.org/dioxin,2002)
Occupational Safety and Health 232
234
LD50 (g/kg)
2 40 50 ? 130 200 4000
235
Autopsy samples
Organs (brain, liver, kidney, muscle) Blood (heart, peripheral) Vitreous humor Bile (insoluble metabolites) Urine (soluble) Gastric contents (alkaloids)
Hair Bone Maggots
Occupational Safety and Health 236
Environmental/Accidental Contamination
Differential diagnosis Accidental death or homicide? Compensable injury or carelessness? Background that could confound interpretation Verify authenticity/natural source or show adulteration How did the mass poisoning occur? Substitution of inferior/contaminated component? Track source of environmental contamination Environmental justice for underserved? Safeguards not enforced Children often victims Which companies are breaking the law?
Occupational Safety and Health 237
Mercury
Used
as pesticide, pigment or preservative Can cause central nervous system, behavioral and renal effects History, physical exam Urine testing
240
Mercury Hg
Characteristics
& Use liquid at RT, high vapor pressure Good electrical conductor All forms toxic many uses
dental amalgams seed, paint, wood preservative (mostly banned) lamps, switches, thermometers industrial catalyst medicines (mostly historical)
form important
toxic, but: effects and pharmacology differ influences best samples for assessment
Metallic
mercury Hgo
inhaled
vapor ~80% absorbed ingestion is nontoxic excreted in urine (& respired air) urine best test sample
Occupational Safety and Health 242
mercury Ch3Hg+
100% G.I. absorbed possible dermal absorption excreted in bile, some reabsorbed test blood or hair
Occupational Safety and Health 243
Sources of Hg
Natural
volcanoes
weathering
Anthropogenic
sources = 50-67% of
total
mining
combustion
Hg Exposure Pathways
Hg
vapor precipitates, enters waterways Sediment bacteria methylate Methylmercury biomagnifies in fish
Dietary
246
247
Hg Health Effects
Metallic
Hg
primarily affects CNS, kidneys, & lungs tremor, personality changes, delerium fatigue, anorexia, excess salivation acrodynia, pink disease effects often reversible
248
Inorganic Hg
G.I. tract necrosis
cramps, bloody diarrhea, circulatory collapse
renal failure tooth & jaw necrosis, black gum lines no major CNS effects
249
neurotoxin parasthesias, esp. lips and fingers ataxia, slurred speech, blurred vision confusion & agitation penetrates skin and latex
250
Children: Colic (acute) and mental retardation (chronic) Legacy of leaded paint and gasoline Eating peeling paint (many inner cities) Playing in contaminated yards (e.g., Oakland)
251
Asbestos
Used
in plaster, fire retardants, taxidermy Can can pulmonary fibrosis Can result in lung cancer OSHA Asbestos Standard:
Annual
exam and termination exam History, physical Pulmonary function study Periodic chest x-ray
253
Solvents
Used
to clean and thin paints Can affect skin, liver, blood (benzene), peripheral and central nervous systems History and physical exam Urine for metabolites Carbon monoxide in exhaled air, or carboxyhemoglobin in blood for methylene chloride
254
Psychoactive/Psychedelic
Marijuana
Short term use relaxation; Long term loss of motivation Loss of coordination, slow reaction time, disordered thought Legalized for medical use in some states (controversial) Sometimes contaminated with herbicide paraquat
LSD
Strong hallucinogen, vivid colors Flashbacks common
PCP/Ketamine
At first, feelings of strength, invulnerability, detachment Then confusion, agitation, depression Long term depression, suicide, schizophrenia
Natural sources
Cacti (peyote) mescaline Safety and Health Mushrooms psilocybin,Occupational ibotenic acid
256
Depressants
Alcohol
Responsible for about half of traffic deaths Poor job performance and disrupted family life Health problems: Cirrhosis, Fetal alcohol syndrome
Barbiturates (sedatives)
Sleep inducing, can induce dependence Especially dangerous when used with alcohol
Tranquilizers (anxiolytics)
Benzodiazepines (Valium, Librium) among most used Variants not approved include Rohypnol Causes loss of short term memory Used for personal attacks
Occupational Safety and Health 257
Drugs of Abuse
Opioids, Amphetamines, Cocaine Scope of problem in USA
Half a million heroin addicts Six million cocaine users Personal tragedies common among users Families adversely affected (vicious circle of poverty, crime) 75% of crime lab evidence is drug related Impurities always suspect
Features
Stimulation of reward center: Euphoria (like endorphins) Increase dopamine in nucleus accumbens Tolerance: Require increasing doses (100x, previously fatal) Continued use can lead to psychoses (paranoid schizophrenia) Withdrawal: Dysphoria, depression, craving
Occupational Safety and Health 258
260
Toxic Materials
PROTECTION :
(1) Recirculating oxygen (2) Demand compressed air/O2 (3) Recirculating self generating oxygen (4) Suits wear that made of material impervious to the toxic material
261
O2 Requirement
8 10
262
CHEMICAL THREATS
Chemical
warfare agents (CWAs) Mustard (HD) Nerve agents (G, V) Have seen previous terrorist use (Aum Shinrikyo)
264
265
BIOHAZARD
DEFINITION 1. A biological agent, such as an infectious microorganism, or a condition that constitutes a threat to humans, especially in biological research or experimentation. 2. The potential danger, risk, or harm from exposure to such an agent or condition. MEANING 1. any bacterium or virus or toxin that could be used in biological warfare 2. hazard to humans or the environment resulting from biological agents or
Occupational Safety and Health 266
The biological hazard warning shall be used to signify the actual or potential presence of a biohazard and to identify equipment, containers, rooms, materials, experimental animals, or combinations thereof, which contain, or are contaminated with, viable hazardous Occupational Safety and Health 267 agents.
Bacillus anthracis
Smallpox
day 1
day 2
269
ASSIGNMENT OF PATHOGENS TO BIOHAZARD RISK LEVELS 1-4 Biohazard Risk Level 1: E. coli Unlikely pathogenicity to humans No community risk Biohazard Risk Level 2: Possible pathogenicity to humans Hep. A Unlikely community risk Biohazard Risk Level 3: YF, Hep. C* Serious pathogenicity to humans Moderate community risk Usually prophylaxis / treatment Ebola, Biohazard Risk Level 4: Serious pathogenicity to humans smallpox High risk of spreading to community No available treatment or prevention
Occupational Safety and Health 270
BIOTERRORISM THREATS
Anthrax Plague Tularemia Venezuelan
equine
Smallpox
Brucellosis Q
fever Cholera
Occupational Safety and Health 271
272
ANTHRAX
273
The dormant spore -- the vehicle spreads by air extremely resistant to many challenges can survive in the environment for decades Ingested by animals (herbivores) while grazing Humans are infected through contact with infected animals and their products because of human intervention Spores are not made inside the living body
Occupational Safety and Health 274
The anthrax bacteria live in two forms The growing bacterium -- the weapon causes disease because it produces ver potent toxins (poisons)
ANTHRAX
275
Spores are infectious -- but they are not made in a living body Spores are extremely sturdy Bacteria are made in the body and they produce the killing poisons Spores must have a certain, small size to reach the lower part of the respiratory tree -- they tend to Spores, once clump deposited, tend to stay on the ground It takes ~ 10,000 spores to initiate an infection
IMPORTANT POINTS Anthrax is not transmitted from person to person Spores can sustain lots of stresses, withstand vigorous manipulation, last for very long time Antibiotics block bacteria, but not the poison. Therefore, antibiotics must be given soon after exposure suspected Very challenging to produce large stocks of spores of small size to optimize infection (so-called weapon-grade) Risk of air-borne infection from deposited spores is low Anthrax tends to be rare, even where soil is contaminated
276
GET
are inhaled
anthrax
Inhalation
Spores
Skin
(cutaneous) anthrax
Spores
Gastro-intestinal
277
278
Initial symptoms usually appear a week from exposure Illness begins with non-specific, flu-like symptoms malaise, fatigue, fever, chest discomfort, dry cough Abrupt appearance of respiratory distress severe breathing problems and shock Chest radiograph may show swelling of the soft tissues in the middle of the chest, and fluid in the chestOccupational cavity Safety and Health 279
280
Inhalation outcome
anthrax
--
the
As of 11/21/2001, six of 11 patients with inhalation anthrax have survived Prompt recognition of the early features of inhalation anthrax is important If untreated, the disease is generally fatal within 24 to 36 hours after the onset of severe symptoms
SKIN ANTHRAX
most comm Anthrax by contact Usually affects least common exposed skin areas,such as arms, hands, face, neck About 20% of untreated cases of skin anthrax result in death Deaths are rare Occupational Safety and Health following appropriate
282
Skin Anthrax
Lesions usually appear within a week from exposure Starts as a raised itchy bump that develops into a vesicle and then a painless ulcer The main characteristic is the black area at the center of the ulcer The skin lesion is Occupational Safety and Health 283
Gastrointestinal Anthrax
Anthrax by consumption of contaminated food Initial symptoms are nausea, loss of appetite, vomiting, and fever Later symptoms are abdominal pain, vomiting of blood, and severe diarrhea In some cases, symptoms are swelling and gland enlargement in the neck, accompanied by difficulty to swallow and to breath About 25%-60% of untreated cases result in Occupational Safety and Health 284 death
it is anthrax?
By
recognizing clinical signs and symptoms By recovering spores from nasal swabs By identifying anthrax bacteria from nasal swabs, infected tissues or body fluids
that
person A and person B have been infected by the same/different strain of anthrax?
By
285
Use
286
POST-EXPOSURE PROPHYLAXIS
Initial therapy with ciprofloxacin or doxycycline is recommended for all adults and children Use of tetracyclines and fluoroquinolones in children has adverse effects As soon as penicillin susceptibility of the organism has been confirmed, prophylactic therapy for children should be changed to amoxicillin No evidence that one drug is more or less effective than the other for prevention of anthrax infection Occupational Safety and Health 288
THE ANTHRAX VACCINE The current US vaccine for human use is a cellfree filtrate vaccine, i.e., it contains no dead or live bacteria Multiple immunizations are required Six doses: 0-2-4 weeks and 6-12-18 months Yearly boosters are given to maintain immunity Limited information on efficacy (how protective) Limited information on safety (side effects) with production quality control Problems In the US, anthrax vaccinationand is recommended for reported People who work directly with the organism in the laboratory Veterinarians who handle potentially infected animal products All U.S. military personnel (since 1998) Pregnant women should be vaccinated only if absolutely necessary Occupational Safety and Health 289
290
Clinical Orthopox virus symptoms DNA virus Acute Brick-shaped structure 200 Fever nm in diameter Heada Incubation 8-16 days che Mortality 30% Smallpox - Rash Vomitin Rash g Begins on face, hands, forearms & spreads to lower extremities within 7Backac he days Synchronous progression: Lesions on palms & soles of feet maculesvesicles pustules Occupational Safety and Health 291 scabs
Smallpox, disease
292
Smallpox, disease
293
Smallpox, disease
294
295
296
Septicemic
Similar
297
PLAGUE
Pneumonic
Highest Rapid
mortality
Clostridium Botulinum
C. botulinum spores found in soil worldwide Toxin causative agent of botulism Types A-G; A,B&E most commonly associated with human disease Most potent toxin known (lethal dose 1ng/kg) Inactivated by chlorine (~20min) and sunlight (1-3hrs); destroyed by heat (5min at 85C) Absorbed into circulation via mucosal surface or wound, not intact skin Interferes with nerve transmission paralysis
Occupational Safety and Health 300
BOTULISM, ENVIRONMENTAL
DECONTAMINATION
Botox (botulism) is a white crystalline substance in its pure form. The route of exposure and subsequent decay rates determine the environmental decontamination required. Aerosolized botox is susceptible to environmental factors such as sunlight, humidity, and Occupational Safety and Health form, botox is 301 temperature. In aerosolized
Weaponized by former U.S. and Soviet offensive BW programs Iran, Iraq, N. Korea, Syria believed to have developed/be developing toxin as a weapon Therapeutic botox impractical BT weapon Licensed vial of type A only 0.3% estimated human lethal inhalational dose Aerosol use or food supply sabotage most likely
Occupational Safety and Health 302
Food-borne Toxin produced anaerobically in improperly processed or canned, lowacid foods contaminated by spores Wound Toxin produced by organisms contaminating wound Infant Toxin produced by organisms in intestinal tract *3 accidental cases in veterinary personnel, W. Ge Inhalation botulism Occupational Safety and Health 303 No natural* occurrence, developed as
Approximately 100 reported cases botulism/year in the U.S. Infant most common (72%) Food-borne not common Incubation (food-borne): 12-72 hrs (range 2hr-8d) Dose dependent Could be less following a BT attack No person-to-person transmission Death 60% untreated; <5% treated
Occupational Safety and Health 304
Ingestion of botulinum toxin results in an illness of variable severity. Common symptoms are diplopia, blurred vision and bulbar weakness. Symmetric paralysis may progress rapidly. Laboratory* criteria for diagnosis: Detection of botulinum toxin in serum, stool or patients food (food-borne) or other clinical specimen (botulism, other) OR Isolation of Clostridium botulinum from *Assaystool available at CDC & some state clinical (food-borne) or other public health labs specimen MMWR 1997;46(RR-10)
Occupational Safety and Health 305
Clinically compatible with an epidemiologic link Confirmed: Clinically compatible case that is laboratory confirmed or that occurs among persons who ate the same food as persons who have laboratory-confirmed botulism Botulism, Other Confirmed: Clinically compatible case that *age parameter may not apply in in BT is laboratory confirmed a patient 1 yr* who has no history ofMMWR ingestion of suspect 1997;46(RR-10 food and has no wounds
Occupational Safety and Health 306
Clostridium Botulinum,
PATHOGENESIS
Toxin
absorbed into circulation via mucosal surface or wound, not intact skin acetylcholine receptor irreversibly and blocks release of acetylcholine into neuromuscular junction
Binds
307
BOTULISM, CLINICAL
PRESENTATION
Acute, afebrile, symmetric descending flaccid paralysis Always begins in bulbar musculature --> cranial nerve palsies Skeletal muscle paralysis follows Respiratory failure can occur in as little as 24 hours Clear sensorium: sensation and mental status normal Afebrile patient
Occupational Safety and Health 308
BOTULISM, CLINICAL
PRESENTATION
Gastrointestinal symptoms May precede neurological symptoms in food-borne botulism Thought to be secondary to other substances contaminating the food May not occur in BT attack
ileus,
309
BOTULISM, SYMPTOMS
Diplopia Blurry Fatigue Dizziness Dyspnea GI
vision
Dysphagia Dysarthria
symptoms
310
BOTULISM, SIGNS
Ptosis (drooping of the upper eyelids) Gaze Fixed Diminished
gag
reflex
Tongue
paralysis or dilated
weakness
pupils
Facial
Arm
palsies
Myasthenia gravis
Stroke
*Electromyogram
312
Tick paralysis
313
BOTULISM, DIAGNOSIS
Exclusionary
other causes
Normal
CSF Edrophonium (Tensilon test) Reverses paralysis in myasthenia gravis May have false positive with botulism Normal imaging Occupational Safety and Health Evaluate for presence of ticks
314
BOTULISM, TREATMENT
Ventilatory assistance and supportive care Recovery depends on regeneration of new motor axons and may take weeks to months Botulinum antitoxin Most effective if given early: does not reverse action of already-bound toxin Trivalent equine product against types A,B, and E currently available from CDC
Occupational Safety and Health
315
BOTULISM, TREATMENT
Botulinum antitoxin Single 10ml vial per patient, diluted 1:10 in 0.9% saline & administered by slow IV infusion Screen for hypersensitivity before administering equine antitoxin and desensitize if necessary Monitor closely during treatment Diphenhydramine and epinephrine on hand to treat hypersensitivity reactions Antibiotics for secondary infection
Occupational Safety and Health 316
BOTULISM, TREATMENT
Ventilatory assistance and supportive care Standard precautions Botulinum antitoxin Most effective if given early: does not reverse effect of toxin already bound to nerve receptor Trivalent equine product against types A,B, and E currently available from CDC Heptavalent (A-G) antitoxin - 317 Occupational Safety and Health
BOTULISM, PROPHYLAXIS
Pre-exposure Prophylaxis for at-risk lab workers and military with investigational vaccine No pre-exposure prophylaxis recommended for general public Post-exposure: close monitoring of those exposed; treat with antitoxin at first signs of illness
Occupational Safety and Health 318
BOTULISM,
DECONTAMINATION
Wash
surfaces
with
Decontaminate
BOTULISM, SUMMARY OF
KEY POINTS 1. Botulism presents as symmetric bilateral weakness or paralysis with cranial nerve abnormalities and a clear sensorium. 2. Inhalational botulism does not occur naturally, and any potential cases suggest a deliberate source of infection. 3. Gastrointestinal symptoms may not occur with inhalational botulism or with food-borne botulism (e.g., resulting from deliberate contamination of the food supply). 4. A careful dietary and activity/travel history is important when evaluating potential botulism cases. 5. An outbreak occurring with a common geographic factor, but with no common food exposure, would suggest a deliberate aerosol exposure. 6. Botulinum antitoxin must be administered as soon as
Occupational Safety and Health 320
Ricin
The castor bean plant, Ricinus communis, is a "native of tropical Africa cultivated in several varieties for the oil found in its leaves and for its bold foliage Poisoning by ingestion of the castor bean is due to ricin in the bean Extracted castor oil does NOT contain ricin Perhaps just one milligram of ricin can kill an adult.Occupational Safety and Health
321
322
RICIN POISONING
Accidental exposure to ricin is highly unlikely. Exposure Inhalation. Contamination of water or food. Injection If injected as little as 500 mg could kill an adult. A 500-microgram dose of ricin would be about the size of the head of a pin. Much more Occupational needed Safety and Health to kill if inhaled
323
RICIN POISONING
The symptoms are: abdominal pain vomiting diarrhea, sometimes bloody. Within several days there is: severe dehydration, a decrease in urine, and a decrease in blood pressure. If death has not occurred in 3-5 days, the victim usually recovers. Occupational Safety and Health Children are at high risk
324
Decontamination Supportive medical care depending on route of exposure Ventilation Intravenous fluids Management of seizure and low blood pressure Activated charcoal if the ricin very recently ingested Flushing eyes if irritated
Occupational Safety and Health 325
Disease
No High
8,000-50,000 spores 100-500 organisms 10-50 organisms Assumed low (10-100 organisms) 1-10 organisms 0.001 g/kg is LD50 for type A
3-5 days (usually fatal if untreated) 1-6 days (usually fatal) > 2 weeks 4 weeks
High High unless treated within 1224 hours Moderate if untreated High to moderate
No High
2-10 days (average 3-5) 7-17 days (average 12) 2-21 days
Moderate
Death between 7-16 days Death in 24-72 hours; lasts months if not lethal
No
1-5 days
High for Zaire strain, moderate with Sudan High without respiratory support
ious dose may be less in certain circumstances Modified from: USAMRIIDs Medical Management of Biolo
Occupational Safety and Health 326
Decontamination of exposed persons Showering or washing thoroughly with soap and water adequate for most; bleach not necessary
Infection control Standard precautions all cases Airborne and contact precautions smallpox and viral hemorrhagic fevers Droplet precautions pneumonic Occupational Safety and Health
327
Explosion
Definition: A reaction that produces a change in the state of matter that results in a rapid and violent release of energy. Types: - Mechanical - Chemical - Nuclear
328
Explosive
Definition: A material (chemical or nuclear) that can be initiated to undergo a very rapid, self propagating decomposition, resulting in: a. formation of more stable materials b. the liberation of heat c. development of a sudden pressure effect.
329
Explosions - Definitions
Explosion: A very sudden release of energy resulting in a shock or pressure wave. Shock, Blast or pressure wave: causes damage. Pressure wave that
Deflagration: Reaction wave speed < speed of sound. Detonation: Reaction wave speed > speed of sound.
Speed of sound: 344 m/s, 1129 ft/s at ambient T, P.
Deflagrations are the usual case with explosions involving flammable materials.
330
Explosive Materials
Materials in the form of compound or mixture of compound which suddenly undergoes a very rapid chemical transformation with the simultaneous production of large quantities of heat and gases (CO, CO2, N2, steam, O2) and always accompined by a vigoros shock and an associated noise (brisance)
Nitroglycerin,
TNT, lead trinitroresorcinate (lead styphnate), lead azide Pb(N3)2, mercury fulminate (Hg(CNO)2, cyclonite (RDX), tetryl, pentraerythritol tetranitrate (PETN), dynamite
Occupational Safety and Health 331
Dust
Sufficiently small particle size Sufficient concentration dispersed in air Ignition source Secondary explosions often exceed initial explosion
332
First experimental proof: Nikolay Nikolaevich Semenov (Russian, 1896-1986) Investigation (1926) of the phosphorus vapouroxygen reaction. Explosion occurs, if the partial pressure of O2 is between two limits. Interpretation via a branching chain reaction.
Sir Cyril Norman Hinshelwood (English, 1897-1967) Investigation (1927) of the H2O2 reaction. discovery of the 1st and 2nd explosion limits
The Nobel Prize in Chemistry 1956: Semenov and Hinshelwood: "for their researches into the mechanism of chemical reactions"
Occupational Safety and Health 333
Formation
of Gases. Evolution of Heat. Rapidity of Reaction. Initiation of Further Reaction. (Chain Reaction)
Occupational Safety and Health 334
Chain reactions
Chain carriers (also called chain centres, i.e. reactive intermediates) are generated in the initiation steps.
In the chain propagation steps the chain carriers react with the reactants, produce products and regenerate the chain carriers.
In the inhibition step the chain carriers react with the product, reactants are reformed, and there is no reduction in the number of chain carriers.
In the branching step two or more chain carriers are produced from a single chain carrier.
In the termination steps the chain carriers are consumed.
335
Branched chain reactions Chain reactions that include branching reaction steps Examples: H2+O2 reaction, hydrocarbonair explosions and flames
336
EXPLOSIVE REACTION
337
Blast Wave
338
Categories of Explosives
Low Explosives Normally employed as propellants. Burn rapidly (up to 400 m/s). High Explosives Detonate (1000 - 8500 m/s). Differentiated by Sensitivity: Primary - Extremely sensitive to impact, friction & heat. Secondary - Less sensitive. (May burn in small, unconfined quantities; otherwise will detonate.) No sharp line of demarcation between low & high explosives.
Occupational Safety and Health 339
thermal explosion
Presence of a chain reaction is not needed for a thermal explosion. Branched chain reactions are exothermic and fast dissipation of heat is frequently hindered most branched chain explosions are also thermal explosions
340
Detonation accident
341
BLEVE
BOILING LIQUID EXPANDING VAPOR EXPLOSION
Cryogenenic fluids that have a high expansion rate of vaporazation (LNG around 630 times)
342
BLEVE
BLEVE: Boiling Liquid Expanding Vapor Explosion
Vapor Liquid
Below liquid level - liquid keeps metal walls cool. Above liquid level - metal walls overheat and lose strength. After vessel failure, a large amount of superheated liquid is released, which will flash explosively into vapor. If the liquid is flammable, a fireball may result.
Occupational Safety and Health 343
The train derailment emergency near Belleville, Ontario in February 2003 set a world record in distance for BLEVE of a propane tank car.
344
MEXICO DISASTER
19th NOVEMBER 1984 leak in LPG Storage facility BLEVE occurred, 500 Deaths, Loss US$ 100 Millions
345
FEYZIN DISASTER
January 4th, 1966, France 18 killed, 81 injured. Leak in 1200 m3 propane sphere BLEVE further sphere toppled Adjacent petrol tank caught fire 48 hrs to gain control Sampling removable spanner (I) open fully upper valve (Ii) adjust small drain-off rate by operating the lower valve/20mm sample valve
Occupational Safety and Health 346
347
A Material Safety Data Sheet (MSDS) is designed to provide both workers and emergency personnel with the proper procedures for handling or working with a particular substance. MSDS's include information such as physical data (melting point, boiling point, flash point etc.), toxicity, health effects, first aid, reactivity, storage, disposal, protective equipment, and spill/leak procedures. These are of particular use if a spill or other accident occurs.
Prepared by Chemical Manufacturers or Importers to describe characteristics of the product and to provide information concerning potential hazards
349
SECTION II - HAZARDOUS INGREDIENTS REPORTABLE COMPONENTS *ACETONE CAS NUMBER 67-64-1 VAPOR PRESSURE mm Hg @ temp 185mm Hg @ 68 F 100% *Indicates toxic chemical(s) subject to the reporting requirements of Section 313 of Title III and of 40 CFR 372. WEIGHT PERCENT
352
SECTION III - PHYSICAL CHARACTERISTICS PHYSICAL FORM COLOR ODOR ODOR THRESHOLD : : : : LIQUID COLORLESS ACETONE 13 ppm
:
): ): : : : : : : : : : INSENSITIVE :
0.79
2.0 5.7 2.1 56C/133F. -94C/-137F. NOT APPLICABLE Complete -20C/-4F 2.8 VOLUME % 13.2 VOLUME % 538C/1000F MATERIAL IS UNLIKELY TO ACCUMULATE A STATIC CHARGE WHICH COULD ACT AS
353
SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT(Closed cup) -20oC/-4oF. APPROXIMATE FLAMMABLE LIMITS: 2.8%-13.2% EXTINGUISHING MEDIA : Water Spray, Dry Chemical, Carbon Dioxide (CO2), Alcohol Foam
SPECIAL FIREFIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective clothing. USE WATER WITH CAUTION. The fire could easily be spread by the use of water in an area where the water could not be contained. Use water spray to keep fire-exposed containers cool. Water may be ineffective in fighting the fire.
HAZARDOUS COMBUSTION PRODUCTS: Carbon Dioxide, Carbon Monoxide UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable. Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance to a source of ignition and flash back. Prevent backup of vapors or gases to explosive concentrations. SECTION V - REACTIVITY DATA STABILITY INCOMPATIBILITY HAZARDOUS POLYMERIZATION : Stable : Material can react violently with strong oxidizing agents, strong acids. : Will not occur
354
SECTION VI - HEALTH HAZARD DATA EFFECTS OF EXPOSURE: Extensive human experience and animal data indicate that acetone is of low toxicity. However, ingestion of very large amounts or inhalation of extremely high vapor concentrations can cause irritation, nausea, vomiting, confusion, drowsiness, convulsions and coma with possible liver and kidney injury. Based on animal data and structure-activity relationships, this product is NOT expected to cause nervous system damage. INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: High vapor concentrations may cause drowsiness and irritation. SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Eyes: Causes ittitation to the eyes. However, immediate flushing of the eyes with water will minimize any irritative effect. High vapor concentrations may cause irritation to the eyes. Shin: Prolonged or repeated contact may cause drying, cracking or irritation.
INGESTION HEALTH RISKS AND SYPTOMS OF EXPOSURE: Expected to be a low ingestion hazard.
CARCINOGENICITY CLASSIFICATION: International Agency for Research on Canser (IARC): Not Listed American Conference of Governmental Industrial Hygienists (ACGIH): Not Listed National Toxicology Program (NTP): Not Listed
355
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition(sparks, flames, and hot surfaces). Avoid breathing vapors. Ventilate area. Remove with an inert absorbent and nonsparking tools. WASTE DISPOSAL METHOD: Disposed in accordance with state, federal and local regulations. Do not incinerate closed containers. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep containers tightly closed in a cool, dry well ventilated area away from all possible ignition sources. Store large quantities of material in buildings designed for the storage of flammable liquids. OTHER PRECAUTIONS: Employees should be trained in safety measures that should be taken when using this product. SECTION VIII - CONTROL MEASURES RESPIRATORY PROTECTION: Avoid breathing vapors or spray mist. Wear a properly fitted respirator approved by NIOSH/MSHA (TC-23c)for use with paints during application and until all vapors are exhausted. In confined areas, or where continueuous spray operations are typical, or proper respirator fit is not possible, wear a positive-pressure supplied air respirator (TC-19c). In all cases follow respirator manufactures directions for respirator use. Do not allow anyone without protection in the area. VENTILATION: Provide sufficient ventilation to keep contaminates below applicable OSHA requirements. PROTECTIVE GLOVES: Neoprene gloves impervious to organic solvents recommended. EYE PROTECTION: Use safety eyewear designed to protect against liquid splash. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Impervious coveralls recommended. WORK/HYGIENIC PRACTICES: Eye wash and safety showers in the work place are recommended. Wash hands before eating and smoking. Occupational Safety and Health 356
SECTION IX - DISCLAIMER
The information contained in this safety data sheet is information from our suppliers and other sources. It is believed to be reliable. This data is not to be taken as a warranty or representation for which this company assumes legal responsibility. We appreciate your interest in 5 Star Autobody Products! For more information about these and other 5 Star Autobody Products or for the location of the 5 Star Distributor nearest you, contact us at: 5 STAR AUTOBODY PRODUCTS 9419 E. San Salvador Drive Suite #104 Scottsdale, AZ 85258 Phone: 480-451-4451
357
358
359
360
Eye Protection
When working with chemicals, when working near someone working with chemicals, when working around chemicals, but not directly with chemicals themselves, Please! always wear some form of eye protection!
361
Prescription safety glasses have corrective lenses, but provide only the same degree of protection as regular safety glasses.
Occupational Safety and Health 362
Respirator
Obat P3K
Pelindung lengan
Occupational Safety and Health 364
Hand Protection
Glove materials (PVA nitrile, butyl, PVC) show different degrees of resistance to chemicals Heavier gloves = greater chemical resistance, but less dexterity Thin exam gloves (esp. latex) provide almost NO chemical resistance See MSDS for proper glove selection
365
366
Sepatu kerja PERALATAN KESELAMATAN KERJA Alat Pelindung Kaki (foot guard)
Occupational Safety and Health 367
COVERALLS/JACKET
368
Labcoats
Labcoats provide extremely limited but critical protection from chemical splashes Useful when working with small (i.e., research sized) quantities of hazardous chemicals Heavily contaminated, wellworn labcoats must either disposed of or laundered, before they become sources of exposure themselves
Occupational Safety and Health 369
Tandu
Shower mata
371
If a chemical has splashed on working member, immediately wash it off with copious amounts of water, for at least 15 minutes. Call for medical attention only after washing.
Occupational Safety and Health 372
Flood eyes with copious amounts of water at eyewash for at least 15 minutes, then seek medical attention.
Occupational Safety and Health 373
WARNA LANTAI ATAU BAGIAN MESIN DI TEMPAT KERJA Secara umum warna mengidentifikasikan kondisi tempat kerja, MERAH untuk tombol stop, mematikan mesin dalam keadaan darurat. ORANYE untuk bagian mesin yang berbahaya atau terdapat kemungkinana bahaya listrik. KUNING untuk daerah dimana pekerja harus berhati-hati. HIJAU menunjukkan tempat dimana peralatan keselamatan kerja terdapat seperti kotak P3K, peralatan pelindung.
374
375
1910.157(b)(1)
Where the employer has implemented a written fire safety policy which requires the immediate and total evacuation of employees from the workplace and which includes an emergency action plan and fire prevention planand when extinguishers are not available in the workplace, the employer is exempt from all requirements of this section unless a specific standard in Part 1910 requires that a portable fire extinguisher be provided.
Occupational Safety and Health 377
1910.157 (g)(1)
Where the employer has provided portable fire extinguishers the employer shall provide an educational program to familiarize employees with general principles of fire extinguisher use and the hazards involved with incipient stage fire fighting.
378
OBJECTIVES:
After this training you should be able to:
UNTRAINED PEOPLE Cannot use a fire extinguisher safely because they are:
UNABLE to evaluate a fire
Limitations
INEXPERIENCED
know about the proper type of extinguisher Dont know how to make a Fight or Flight analysis Unfamiliar with the P.A.S.S. method
Dont
Occupational Safety and Health 381
Energized circuits
Electrical equipment and computers
382
duration, and range of discharge on test fires. Area of Class A fire which a non-expert can extinguish, with proper training
1-A is equivalent on Class-A fire to five liters of water. 2-A contains has twice as much extinguishing agent.
Occupational Safety and Health 383
Works by blanketing the fuel. Interrupts chemical reaction at fuel surface. Class B ratings signify the area in square feet
of flammable liquid fire a unit will extinguish when used, by a trained, non-expert.
Occupational Safety and Health 384
imply any capacity. Only indicates that the extinguishing agent is non-conductive, safe on energized equipment. Works by displacing oxygen, smothering fire.
Occupational Safety and Health 385
386
- 1.5 to 25 lbs.
of
extinguishing agent
387
Type (Water, C02, Dry Chemical) Classification (A, B, C) NFPA capacity Rating Instructions
WATER
Water
+ CO2 propellant ONLY for Class fires wood / paper, etc. Spreads burning liquids! DANGER of electric shock if used on on live circuits!
Occupational Safety and Health 390
MULTI-PURPOSE RATED
Either Or
DRY CHEMICAL
Best
A
Reduced
Effective
C02 Best
Rated
on burning liquids / electrical SHORT range - 3 to 8 ft. 10- pound unit empties in 5 to 10 seconds! Use short spurts!
DISPERSES
Continue
QUICKLY!
Halon
Best
Disperses QUICKLY!
after flames are extinguished
Occupational Safety and Health 393
Continue
Notify
and
Floor Monitors
394
REACT
upon discovery of fire or smoke
Remove persons in immediate danger! Ensure doors are closed! (confine fire/smoke) Activate the building alarm ! Call the Fire Department ! Treat ALL fires as DANGEROUS!
Continue a complete building evacuation Do not attempt to fight a fire UNLESS you are OSHA certified in use of a fire extinguisher !
Occupational Safety and Health 395
You use Buddy System - have someone back you up! Get assistance BEFORE trying to fight a fire!
Occupational Safety and Health 396
P.A.S.S.
PULL AIM
SQUEEZE SWEEP
Occupational Safety and Health 397
>>:
398
AIM
LOW at the base of the fire
399
SQUEEZE
the lever
400
SWEEP
from side to side
401
the fire flares up again repeat! If you cant control the fire, LEAVE immediately!
Call the fire department to inspect the scene!
Recharge or replace any used fire extinguisher!
Occupational Safety and Health 402
403
Earthquakes Floods, flash floods Fires: wildland, urban,suburban, industrial, hazardous materials DISEASE:Human/Animal/Vegetation epidemic; food-, water- or air-borne, vector spread, occupational, infectious, contagious, fatal, quarantine response, vaccination issues TERRORISM: Agri-, Bio-, Cyber-, attempted, assassination, threats, hoaxes, domestic vs. international, weaponized planes, trains, automobiles, trucks, boats, cargo containers, mail...
404
Crowd incidents: civil unrest, marches, riots, protests Structure Collapse: bridges, buildings, dams, highways, tunnels, pipelines, underwater tubes Highway/roadway/transit route incidents: multivehicle accidents, jack-knife tractor trailers, spills, lost loads Maritime incidents: collision, explosion, fire, sinking, grounding Mass Transit incidents: collisions, fires Nuclear incidents: power plant, theft, waste transport, weapons accident
405
Hazardous Material: airborne release, spill, explosion, fire, nuclear, radiological, waste removal and transport, medical waste Railroad incidents: collisions, derailments, fires, explosions Mine incidents: explosions, fires, collapse Hijacking: air, train, boat, bus, other conveyance Aviation incidents: crash, collision, space flight accident Critters: insect infestation, cicadas, crickets, ticks, vermin, etc.
406
Economic collapse, genuine and non-genuine destabilization of your currency Landslides/mudslides Mass Murder/Mass Suicide Strike, sick outs, work stoppage School Shootings Seiches Smog, air pollution, air quality, ozone depletion Drought Heat waves
407
Utility Failure: water, electricity, gas, telecommunications, cable Sniper incidents Storm: rain, severe thunderstorm, hail, wind, snow Tornado Tsunami, tidal wave Volcanic Eruption Extra-terrestrial incidents: meteors, space debris, UFOs Other disasters as assigned
408
Are they the best messengers or experienced service providers for special needs communities?
Occupational Safety and Health 409
Top-down command structure Response-driven Inherent bureaucracy issues Father Knows Best syndrome Success depends on compliance, standardization, shared protocols, etc Infrastructure maintenance is critical Challenged by change Exclusionary appearance/practices
410
EMERGENCY PLANNING
411
Desastres qumicos
Emergencias tecnolgicas
Emergencias ambientales
412
413
Seguimiento
Respuesta
Investigacin
Rehabilitacin
414
Identificacin de peligros Evaluacin de la emergencia Evaluacin de los riesgos Reduccin de los riesgos Comunicacin Movilizacin Respuesta Recuperacin
Occupational Safety and Health 416
Plan de emergencia
Entrenamiento
ESTADO
EXPERTOS
INDUSTRIA
COMUNIDAD
417
Coordinacin intersectorial
Plan de Gestin de Sustancias Qumicas
GOBIERNO
INDUSTRIA COMUNIDAD
418
Industria
PROCESO
APELL
Gobierno Local
Awareness and Preparedness for Emergencies on Local Level
Comunidad
APELL
419
Emergency plan
A
series of procedures for handling sudden unexpected situations. Objectives is reduce the possible consequences of the emergency by
Preventing
facilities and injuries Reducing damage to buildings, stock and equipment Accelerating the resumption of normal operations
420
Vulnerability Assessment
Find which hazards pose a threat to any specific enterprise Records of past incidents and occupational experience are not only sources of valuable information Broad the knowledge of both technological and natural hazard by consulting with fire departments, insurance companies, engineering consultants and goverment departments.
421
Technological Hazards
Fire Explosion Building collapse Spills of flamable liquid Accidental release of hazardous biological agents or toxic material Other terrorist activities Exposure to ionizing radiation Loss of electrical power Loss of water supply Loss of communication
Occupational Safety and Health 422
Natural Hazards
Floods Earthquake Tornados Other
severe wind storms Snow or ice storms Severe extremes in temperature (cold or hot) Pandemic diseases
Occupational Safety and Health 423
Date
11/9/01 23/8/92 17/1/94 27/9/91 25/1/90 25/12/99 15/9/89 15/10/87 25/2/90 22/9/99 20/9/98 5/6/01 6/7/88 17/1/95 27/12/99 10/9/99 1/10/95 10/3/93 11/9/92 Aug 02
Event Country
Terrorist attack on WTC, Pentagon United Hurricane Andrew United States, Bahamas Northridge Earthquake United States Typhoon Mireille Japan Winterstorm Daria France, GB, B Winterstorm Lothar France, CH Hurricane Hugo Puerto Rico, United States Storms and floods Europe Winterstorm Vivian Western/Central Europe Typhoon Bart Japan Hurricane Georges United States, Tropical Storm Allison United States Piper Alpha oil platform explosion Great Great Hanshin earthquake, Kobe Japan Winterstorm Martin France, Spain, CH Hurricane Floyd, flooding United States Hurricane Opal United States, Mexico Blizzard, tornadoes United States Hurricane Iniki United States European Floods
Source: Swiss Re, Sigma. At 2001 prices WTC property losses alone estimated at $19BN.
424
Occured Hazards
The possibility of one event triggering others must be considered An explosion may start a fire and caused faliure An earthquake might initiate all the event noted in the list of chemical and physical hazards
425
Damage
to plant infrastructure Loss of vital records or documents Damage to equipment Disruption of work
Occupational Safety and Health 426
Required actions
Declare emergency Sound the alert Evacuate danger zone Close main shutoffs Call for exernal aid Initiate rescue operations Attend to casualties Fight fire
Occupational Safety and Health 427
Medical supplies Auxiliaries communication equipment Power generators Respirators Chemical and radiation detection equipment Mobil equipment Emergency protective clothing Fire fighting equipment Ambulance Rescue equipment Trained Personnel
Occupational Safety and Health 428
possible emergencies, consequences, required action, written procedures and the resources available Detailed list of personnel including their home telephone numbers, their duty and responsibilities Floor plans Large scale maps showing evacuation routes and service condults (such as gas and water lines)
Occupational Safety and Health 429
To reduce human injury and damage to property in an emergency To specifies staff members who may put the plan into action To identifies clearly whose staff members must be on the site at all times when the premises are occupied To indicated clearly the extent of authority of above personnel
430
Emergency Organization
Emergency organization lead by an emergency coordinator Appointed and trained individual act as Emergency Coordinator as key in ensuring that prompt and efficient action is taken to minimize loss, and have possibility to recall off duty employees to help Specific duties, responsibilities, authority and resources of emergency organization must be clearly defined.
431
Reporting the emergency Activating the emergency plan Assuming overal command Establishing communication Alerting staffs Ordering evacuation Alerting external agencies Confirming evacuation complete Alerting outside population of possible risk Requesting external aid Coordinating activities of various group Advising relatives of casualties Providing medical aid Ensuring emergency shut offs are closed Sounding the all clear Advising media Occupational Safety and Health
432
departments Mobile rescue squads Ambulance services Police department Telephone company Hospitals Utility companies Industrial neighbours Goverment agencies
Occupational Safety and Health 433
Pre-planned Coordination
Pre-planned coordinating simulation is necessary to avoid conflicting responsibilities such as fire brigades, police, ambulance service, rescue squads and first aid team which must be on the scene simultaneously. An a pre-determined chain of command in such situation is required to avoid organizational difficulties. Under certain circumstances an outside agency can assume command
434
Communication
Planning
an emergency control center with alternate communication facilities Providing all personnel with alerting or reporting responsibilities with current list of phone number and addresses of those people which may have to contact Maintain communication between key personnel during emergency situation
435
Emergency Procedures
Comprehensive plan procedures for handling emergencies toward preventing disaster Determining factors of needed emergency procedures
The degree of emergency The size of organization The capabilities of the organization in an emergency situation The immediately response of outside aid The physical layout of the premises The number of structures determine procedures that are needed
Occupational Safety and Health 436
preparation Provisions for alerting Evacuating staffs Handling casualties Relocation of personnel with special skills for emergency handling
437
Evacuation Order
Identified evacuation routes, alternate means of escape, make these known to all staffs, keep the routes unobstructed Specify safe location for staff to gather for head counts to ensure that everyone has left the danger zone. Assign individuals to assist handycapped employees in emergency Carry out treatment of the injured and search for the missing simultaneously with efforts to contain the emergency Provide alternate sources of medical aid when normal facilities may be in danger zone Containing the extent of the property loss should begin only when the safety of all staff and neighbours at risk has been clearly established
Occupational Safety and Health 438
Exercise and drills may be conducted to practise all or critical portions such as evacuation of the plan An annual full scale exercise will help in maintaining a high level of profiency Knowledge of individual responsibilities can be evaluated through paper tests or interview A thorough and immediate review after each exercise, drill or after an actual emergency will point out areas that require improvement Revise when shortcoming have become known, and should be reviewed at least annualy Changes in plant infrastructure, processes, material used and key personnel are occasions for updating plan
439
440
BAHAYA
Situasi fisik yang berpotensi menyebabkan kecelakaan pada manusia, kerusakan pada aset, kerusakan pada lingkungan dan kombinasi yang terjadi diantaranya
441
RESIKO
Efek bahaya bersifat tetap terdiri atas HIGH, MEDIUM dan LOW Tingkat kemungkinan bahaya terdiri atas HIGH, MEDIUM dan LOW
Occupational Safety and Health 442
TINGKAT
LOW Satu kali selama pekerjaan itu dilakukan Sekali dalam 100 atau lebih Berpengalaman, memiliki kemampuan yang baik dan sering melakukan pekerjaan itu
443
Kurang berpengalaman
HIGH
Kematian Cacat, disfungsi tubuh Luka berat Kerusakan besar pada peralatan Produksi terhenti
MIDDLE
Luka menengah, tubuh masih dapat melakukan kerja
Kerusakan yang menyebabkan menurunnya tingkat Produksi
LOW
Luka ringan Kerusakan kecil, tidak mempengaruhi produksi
Aset
Alat Proteksi
Alat proteksi tidak ada Berada dalam lingkungan dengan keberadaan zat mudah terbakar
HAZARD ANALYSIS
The identification of undesired event, that leads to the materialisation of the hazard The analysis of the mechanisms by which those undesired event could occur The estimation of the extent, magnitude and relative likehood of any harmful effects
445
HAZARD ANALYSIS
Hazard Analysis
HIRA
Hazard Identification and Risk Assesment
HAZID
Hazard Identification
HAZOP
Hazard and Operability Study
446
HIRA
Identifikasi Bahaya dan Kajian Resiko (Hazard Identification and Risk Assesment), analisa yang dilakukan pada AKTIVITAS HARIAN DAN KHUSUS suatu instalasi industri Tahapan HIRA
Pemilahan kegiatan yang akan dilakukan menjadi sub kegiatan yang lebih kecil dan spesifik Identifikasi potensi bahaya untuk setiap sub kegiatan Determinasi resiko yang mungkin terjadi (efek bahaya dan tingkat kemungkinannya) Determinasi cara pencegahan dan penanggulangan terhadap resiko bahaya Kesimpulan potensi bahaya dan resiko yang dihadapi untuk setiap kegiatan Kesimpulan untuk keseluruhan pekerjaan
447
PT Pertamina (Persero)
Kilang UP VI Balongan
448
Pemeliharaan reaktor dan kolom utama pada RCC Pengisian katalis ke catalyst storage
terjatuh
Pencemaran lingkungan
SOP yang jelas dan pekerja yang terlatih Inspeksi dan monitoring rutin pada perpipaan dengan indikator baik. Sistem pemadam kebakaran yang baik di sekitar unit
Kebocoran pipa
449
HAZID
Identifikasi bahaya (Hazard Indentification), analisa pencegahan terjadinya bahaya pada instalasi industri/pabrik yang DILAKUKAN DENGAN
Keseluruhan aspek dari instalasi industri/pabrik itu adalah: Data informasi instalasi industri (PFD, P&ID, Lay Out, data meteorologi, data sosial kultural masyarakat sekitar, catatan peristiwa) Lokasi (fasilitas operasi, fasilitas pendukung) Resiko (SDM, lingkungan, aset, image) Faktor Pemicu Bahaya (proses operasi, transportasi, geografis dan meteorologi, sosial kultural) Potensi Bahaya (kebakaran dan ledakan besar, tenggelam, pencemaran lingkungan)
Occupational Safety and Health 450
MINOR
Tidak ada kecelakaan
MAJOR
Kecelakaan tidak fatal Kerugian diantara US$ 100000 s/d 1000000
SEVERE
Kecelakaan fatal
Kerugian lebih besar dari US$ 1000000
Aset
Lingkungan
451
LIKELY
Diantara 1 s/d 10 kali dalam 10 tahun
UNLIKELY
Kurang dari 1 kali dalam 10 tahun
452
PT PUPUK SRIWIJAYA
453
POTENSI BAHAYA
EFEK BAHAYA
FREKUENSI BAHAYA
PENCEGAHAN
Pengadaan unit pemadam kebakaran, pengadaan alat detektor kebakaran Pengecekan secara rutin Pengadaan indikator tekanan dan suhu Pengecekan secara rutin Pengadaan indikator tekanan dan suhu Pengecekan secara rutin Pengadaan indikator tekanan dan suhu Pengecekan secara rutin Pengadaan indikator tekanan dan suhu
Perumahan karyawan
Severe
Likely
Unit Ammonia
Unit pembuatan NH3 dan CO dari udara, gas alam dan steam
Severe
Likely
Unit Urea
Severe
Likely
Unit pemenuhan kebutuhan tenaga listrik untuk pabrik, kantor dan perumahan Unit penghasil steam utama untuk berbagai proses, digunakan pada ammonia, urea dan utility plant Unit tempat pengolahan limbah cair hasil proses produksi
Severe
Likely
Severe
Likely
Pencemaran lingkungan
Severe
Likely
454
HAZOP
Hazard Operability Study Identifikasi penyimpangan/deviasi yang terjadi pada pengoperasian suatu instalasi industri dan kegagalan operasinya yang menimbulkan keadaan tidak terkendali Dilakukan pada tahap perencanaan untuk instalasi industri baru Dilakukan sebelum melakukan modifikasi peralatan atau penambahan instalasi baru dari instalasi industri lama Analisa sistematis terhadap kondisi kritis disain instalasi industri, pengaruhnya dan penyimpangan potensial yang terjadi serta potensi bahayanya Dilakukan oleh kelompok para ahli dari multi disiplin ilmu dan dipimpin oleh spesials keselamatan kerja yang berpengalaman atau oleh konsultan pelatihan khusus
455
Air Compressor
Secondary Reformer
101-B
Methanator
Absorber Regenerator
Steam
P-27
456
More
More Flow
Tekanan tinggi
Less
Less Flow
More
More Pressure
Reformer meledak
More
Temperature
457
458
OUTLINE
PENDAHULUAN
PROSES PRODUKSI DI BONTANG LNG PLANT KESELAMATAN KERJA, KESEHATAN DAN LINGKUNGAN
ANALISA KESEHATAN DAN LINGKUNGAN ANALISA KESELAMATAN KERJA
HIRA HAZID HAZOPS
KESIMPULAN
459
KOTA BONTANG
Geografis, keadaan dan SDA
Terletak
di pantai timur propinsi Kalimantan Timur Daerahnya dilalui garis khatulistiwa dan dikelilingi hutan tropis basah dan juga hutan mangroove Beriklim tropis basah Curah hujan cukup tinggi (20003000 mm/tahun) Terdapat kawasan hutan lindung alami dengan pantai yang bersih Sumber daya alam terbesar berupa gas alam dan bahan baku pupuk yang saat ini merupakan komoditas ekspor utama
460
Penduduk bontang terdiri dari suku bugis, banjar, kutai, dayak, madura, dll Jumlah penduduk pada 2002 tercatat 106.225 jiwa Tingkat pertumbuhan penduduk cukup tinggi Mayoritas penduduk bekerja sebagai karyawan, wiraswasta, petani dan nelayan Tingkat kesehatan masyarakat cukup baik
461
Bontang LNG Plant Terletak di Bontang Selatan Bermula dari ditemukannya cadangan gas raksasa di lapangan badak oleh Huffco pada 1972 Bontang LNG plant selesai dibangun dan langsung memulai produksinya dengan 2 train yaitu train A dan B pada tahun 1977 Saat ini Bontang LNG Plant memiliki 8 train yaitu A H Kapasitas produksi saat ini 22 juta ton LNG/tahun dan 1.2 juta ton LPG/tahun Hasil produksi hampir seluruhnya diekspor ke Jepang, Korea dan Taiwan Saat ini, hampir seluruh pekerjanya sebagian besar orang Indonesia
462
463
1986
1987 1988 1989 1990
7.067.191
6.966.899 8.063.054 8.064.536 9.799.297
126
123 145 147 178
464
465
PT Badak NGL
Nama PT badak diambil dari nama lapangan gas raksasa di daerah badak Didirikan pada 26 November 1974 Pada awalnya merupakan perusahaan nonprofit dengan pemegang saham Pertamina, Vico dan Jilco Merupakan operator Bontang LNG Plant Sangat memperhatikan aspek keselamatan kerja dan lingkungan Melakukan program bina masyarakat
466
2 6
7 2 1 2
Pemerintah RI
Instansi Internasional
ISO14001 accreditation Safety Award Zero Accident ISO 9001 version 2000 for Quality Management System
467
468
VICO Lapangan mutiara, sambera, badak dan nilam TOTAL INDONESIA Lapangan tambora, tunu, senipah, bekapai, handil dan peciko UNOCAL INDONESIA Lapangan attaka dan west seno Gas-gas dari sumur-sumur tsb dialirkan menuju bontang LNG Plant dengan pipa transmisi 36 dan 42 dan tiba pada Bontang LNG Plant pada tekanan sekitar 47 kg/cm2 Sebelum dialirkan ke setiap train sebagai feed gas, gas alam tersebut terlebih dahulu dilewatkan ke Knock Out Drum untuk menjalani proses pemisahan awal
469
470
471
473
Sumber pencemar : Limbah gas (CO2 , SOx , NOx ,dll) Limbah cair (Limbah Hg, C5+,dll) Limbah padat (partikulat, Smog, dll) Dampak negatif dari beberapa aspek: biologis : *. flora dan fauna *. manusia fisika kimia : #. kualitas udara #. iklim makro #. kualitas air Sosial ekonomi : +. Demonstrasi warga +. Perkelahian
Occupational Safety and Health 474
Masalah lingkungan
475
ANALISA KESELAMATAN KERJA HIRA Jenis kegiatan yang di buat HIRA: a.Pembersihan Storage Tank b.Pemasangan Instalasi Listrik c.Pemasangan dan fitting pipa d.Pengecekan alat (pemanas, indikator, Heat exchanger,dll) e.Pengangkutan bahan baku dan produk
476
Tabel HIRA
Aktivitas Potensi bahaya Efek bahaya Tingkat efek bahaya Frekuensi bahaya Resiko Pencegahan Resiko akhir Pembersihan tangki penyimpanan Sisa minyak Safety shoes atau boot dengan grip khusus Masker, alat bantu pernapasan
Tergelincir
Cairan Pembersih
Keracun an
...
...
477
HAZID
Lokasi yang dibahas pada HAZID 1. Well Facilities 2. Main Office, gedung serba guna 3. Plant keseluruhan 4. LNG/LPG Tank Storage Facilities 5. Small Refinery Facilities 6. Main Facilities 7. Loading Ship 8. Pipeline Facilities 9. Unit Pengolahan Limbah
478
HAZID
No Lokasi Deskripsi Penyebab
POTENSI BAHAYA
+Plant shut down (gas tidak dapat diambil dari dalam tanah) +Kebakaran (karena gas alam mudah meledak) +Pencemaran lingkungan
EFEK BAHAY A
Servere: Kerugian besar karena Plant shut down, Dapat berakibat kematian bila terjadi ledakan besar
PENCE GAHAN
Peremajaan Kompressor, pengecekan alat secara rutin, menyiapkan aliran bypass agar tidak sampai Plant Shut Down (PSD)
1.
Well Facilities
Kebocora Kompresor
*Korosi, kavitasi atau karena adanya kandungan air yang cukup banyak pada gas alam akibat suhu dan tekanan gas turun (kompressor rusak)
unlikely
2.
*Gaji karyawan dinilai sudah terlalu rendah dengan kondisi bahan-bahan kebutuhan pokok yang terus naik. *pencemaran lingkungan tempat tinggal warga oleh limbah pabrik atau kebocoran gas.
+Hancurnya gedung karena terjadi bentrok dengan warga setempat, bisa pula terjadi kebakaran
Unlikely
479
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCE GAHAN
3.
Plant keseluruh an
*Tempat penampungan air (DAM) rusak, curah hujan terlalu tinggi dengan intensitas yang besar
+Kebanjiran (dapat menyebabkan alat-alat DAM rusak) +Penyakit +Plant Shut Down
Most: Karena daerah Bontang adalah daerah beriklim tropik basah dengan curah hujan yang tinggi
4.
Severe: Fatality kerugian produk yang hilang serta image perusahaan turun
Unlikely
Peremajaan tank, pemerikasaan rutin, penyimpanan storage tank di gedung atau ruangan tertutup
480
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCE GAHAN
Pressure Regulator pd tangki tidak berfungsi dengan baik sehingga tekanan tidak terkontrol
+Kebakaran dan ledakan besar (karena tekanan terlalu tinggi shg suhunya lebih tinggi daripada suhu ignitation)
Unlikely
Peremajaan fasilitas yang sudah rusak, rutin memeriksa tekanan pada tangki
5.
*Korosi, adanya fraksi uap (gelembunggelembung udara) pada aliran inlet pompa sehingga pompa rusak
Minor
Most
Memeriksakan pompa secara rutin, pengecekan dan pengauditan kondisi pompa, menutup aliran ke pompa dan mengaktifkan bypass line
481
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCEG AHAN
Kerusakan boiler
Minor
Unlikely
Valve/katup macet (aliran tidak dapat dibuka atau ditutup dengan baik)
+Plant Shut Down (tidak ada aliran atau aliran tidak dapat ditahan sehingga menimbul-kan kerusakan alat lain)
Likely
Ada aliran bypass atau aliran cabang yang dapat digunakan pada plant
482
No
Lokasi
Deskripsi
Cause
POTENSI BAHAYA +Kualitas produk LNG turun, kemungki-nan terjadi kerusakan alat lain krn masih adanya kondesat liquid
EFEK BAHAYA
PENCEG AHAN
6.
Main utilities
Kebocoran knock out drum sehingga kondesat liquid tidak terpisah dari feed gas
*KOD (knock out drum) mengalami fracture atau fatique karena pemakaian yang terus menerus dengan perawatan yang minim
Unlikely
Peremajaan alat KOD dan pemeriksa-an secara rutin sesuai dengan SOP
Main utilities
*Amine yang mengabsorb CO2 terkontaminasi sehingga kadar CO2 yang dapat diserap kecil, feed gas tercemar *Korosi lebih besar dari korosi allowance absorber (3,2mm)
+Kualitas LNG turun karena adanya kontaminan dapat menyebabkan kerusakan alat lain +Pd P dan T yang terlalu tinggi absorber dapat meledak
Major: Image perusahaan turun, kerugian asset (absorber dan alatalat lain)
Unlikely
Sebelum masuk LNG plant amine mengalami proses pemurnian terlebih dahulu, pemeriksa-an rutin temperatur dan tekanan indikator dan kontroler
483
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCE GAHAN
Main utilities
Amine regenerato r tidak dapat berfungsi dengan baik sehingga regenerasi amine tidak dapat dilakukan
*Korosi, kadar CO2 yang diabsorb amine terlalu besar sehingga larutan MDEA tidak teregenerasi dengan baik
Minor
Unlikely
Main utilities
Kerusakan feed dryer sehingga kandungan outletnya masih mengandung kadar H2O cukup tinggi
*Korosi lebih besar daripada korosi allowance (1,5mm), tekanan kerja lebih besar daripada tekanan kerja maksimum
Minor
Unlikely
Adanya aliran recycle produk untuk pengurangan kadar air lagi, adanya T dan P controler
484
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCE GAHAN
*Penyumbatan partikel endapan, korosi, kekentalan aliran fluida terlalu besar sehingga dapat menjadi penyumbatan pipa
Minor
Likely
Kerusakan scrub column sehingga metana tidak dapat dipisahkan dari fraksi berat lainnya
*Alat pengontrol dan indikator T dan P pada volum tidak berfungsi dengan baik sehingga operator dapat melakukan kesalahan operasi column
+Kerugian alat (scrub column mahal), produk LNG tidak dapat diperoleh (tidak dapat terpisah dari fraksi lain)
Major: Dapat terjadi plant shut down karena LNG tidak dihasilkan
Unlikely
Selalu mengaudit secara rutin T dan P indikator, memilih material scrub column yang tahan korosi dan tekanan tinggi
485
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCEG AHAN
*Korosi, sudah waktunya untuk diganti (telah lama dipakai dengan perawatan yang minim), T dan P indikator dan regulator rusak
+Kerugian sangat besar karena dapat terjadi plant shut down (karena pemisahan C2, C3, C4, C5+ dari fraksi hidrokarbon lain tidak dapat dilakukan
Unlikely
Selalu mengaudit secara rutin T dan P indikator, memilih material scrub column yang tahan korosi dan tekanan tinggi
Heat exchan-ger rusak sehingga C1, C2, C3, C4, C5 tidak dapat dicairkan
*Suhu air pendingin tidak cukup rendah untuk mendinginkan gas alam menjadi LNG dan LPG
+Kerugian besar karena tidak terbentuk LNG, LPG. Gas C1-C5 dengan P tinggi dpt menimbulk-an ledakan
Unlikely
486
No
Lokasi
Deskripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
FREKUEN SI BAHAYA
PENCE GAHAN
7.
Loading ship
*Kecerobohan armada kapal dalam pengoperasian kapal pengangkut *Iklim (badai, hujan keras)
Likely
8.
Pipeline facilities
*Korosi, tekanan gas terlalu besar sehingga dapat terjadi blow out
Likely
Severe: Karena LNG dan LPG dapat mencema-ri daerah pemukiman dan sumber air minum
Unlikely
487
No
Lokasi
Des-kripsi
Sebab
POTENSI BAHAYA
EFEK BAHAYA
PENCE GAHAN
9.
Alat-alat pengo-lah limbah tidak berfungsi dengan baik sehing-ga limbah yang dibuang dapat mencemari lingkungan
+Pencemaran lingkungan
Unlikely
Selalu mengaudit secara rutin T dan P indikator, memilih material unit pengolah-an limbah yang tahan korosi dan tekanan tinggi
488
HAZOPS
PLANT-5 : LIQUEFACTION SYSTEM
5HV-18 5PV-15
B/D
TO 2K-1
LTSS
5PV-2
5Y-5
8"
8"
6"
5TV-45
B/D
5ESDV-2
5HV-2
Q
2" 2"
LPG TO PLT-17
5E-2
LTSS
DRY FLARE
B/D
5HV-3
5Y-4
AR
A K
5FV-2
5TV-2 10" B/D 5TV-1A
5ESDV- 21
AG AJ AF AH
5Y-6
5EDPV- 1
B/D
5PSV-13A/ B
5ESDV- 20
B/D
2"
5C-2
2"
5-E-1
B/D 5HV-6
5C-1
5PV-17
5LV-7
5ESDV- 22
AE
AC
AD
AB
5ESDV-1
5Y-3A/B 20" 5HV-14 5HV-5 5Y-1 5HV-21 12" 5Y-2 5TV-1B REINJ.
4"
LNG TO STG
From 4E-9
5G-1A/B
LTSS
5HV-4
4HV-11 B/D
B/D
5HV-44
4C-7
66"
B/D
FG
FEED GAS
489
Tabel HAZOPS
No No Aliran Kata Panduan Par. Utama Potensi Bahaya Pencegahan Ket.
1.
8-FGBO3-201
Aliran
Tidak ada
5ESDV-20, PI & FI
Sistem shutdown jika tidak ada aliran masuk 5C-1. FI dan PI dipasang pada pipa aliran masuk.
490
No
No Aliran
Kata Panduan
Par. Utama
Potensi Bahaya
Tek. Flash drum separat or 5c-1 turun; Level turun
Pencegahan
Keterangan
Aliran
kecil
Sis. shutdown jika tekanan 5C-1 tidak mcukupi. FI pada pipa aliran masuk. PI di dalam flash drum 5C-1
Blebih
5ESDV-20, FI dan FIC pada pipa aliran masuk 5C1PI dan LI di dalam 5C-1
491
No
No aliran
Kata panduan
Par. Utama
Potensi bahaya
Suhu flash drum naik; Tek. Flash drum naik Suhu flash drum turun; Tek. Flash dum turun Instalasi inhibit, ME tdk dpt bekerja
Pencegahan
Keterangan
Temp
Naik
5esdv-20, Ti&tic
TI di dalam 5C-1
Turun
5esdv-20, Ti&tic
TI di dalam 5C-1
4-fg bo3202
Aliran
Tdk ada
5esdv-21, Pi
492
No
Par. Utama
Potensi Bahaya
Tek MHE 5E1 turun, Suhu MHE turun
Pencegahan
Keterangan
Aliran
Kecil
5ESDV-21 & PI Dipasang pd pipa; TI pd MHE 5E-1 5ESDV-21, PI &PIC pd pipa; TI pd MHE 5E-1
Berlebih
493
No
No Aliran
Kata Panduan
Par. Utama
Potensi Bahaya
Pencegahan
Keterangan
Tekanan
Naik
Turun
Kesimpulan
Keselamatan kerja merupakan salah satu aspek yang harus diperhatikan demi kelancaran proses produksi suatu perusahaan. Perusahaan juga perlu memperhatikan aspek kesehatan dan lingkungan PT Badak NGL sebagai salah satu perusahaan pengolah gas alam, sudah memiliki standar keselamatan dan kesehatan kerja yang baik. Mari kita bersama mewujudkan tempat kerja yang selamat dan sehat
495
KESELAMATAN KERJA
British Petroleum Indonesia
496
Profil Perusahaan
BP Internasional adalah grup petroleum dan petrokimia terbesar di dunia Operasinya global, >100,000 karyawan serta strongholds di Eropa, Amerika Utara & Selatan, Australasia & Afrika. Saat ini bisnis BP sedang berkembang di bidang gas & tenaga, serta pengembangan solar Keuntungan tahun 2001 adalah sebesar US$13 milyar
Occupational Safety and Health 497
Konsumen
bor
Production Separator
Gas Compresor 2
NLG
Well
Proses Produksi
Booster Gas Compresor
Tanker
Crude Oil Pump
Occupational Safety and Health 500
Aspek Kesehatan
Utilitas Lain dalam Proses
Asbes Silika Uap logam NORM Radiasi Ion Glycol Hidrokarbon Aromatik Hidrogen Sulfida Metanol Ashpyxiates
501
Standar Kerja di BP
Fasilitas Panas Masuk Ruangan Tertutup Isolasi Energi Pembukaan & Pemasangan Blind Peralatan Safety yang diNon-aktifkan Tagging & Flagging
502
Contd
Pelatihan untuk Masuk Ruang Tetutup
AGT (Authorized Gas Testers) Tim penyelamat akan menerima peralatan perlindungan perorangan (PPE) dan peralatan penyelamatan (termasuk perangkat BA, Breathing Apparatus) dan dilatih cara penggunaannya. Mereka harus dilatih oleh anggota tim kebakaran. Personil yang baru tidak boleh menangani tugas diatas kecuali jika sedang dalam pelatihan dan didampingi oleh personil yang kompeten yang mengenal bahaya-bahaya masuk ruang tertutup.
504
Aspek Lingkungan
Limbah berbahaya dan beracun Limbah yang tidak Berbahaya Limbah rumahtangga
506
508
Limbah Rumahtangga
Limbah Padat
Semua limbah yang bisa terurai secara alamiah boleh dikirim ke lahan penimbunan / dijadikan kompos. (contoh: sisa makanan, sampah) Semua limbah tidak bisa terurai secara alamiah harus dibuang ke lahan penimbunan tanah yang sehat dan diizinkan. (contoh: plastik, gelas, kaleng logam, besi tua)
509
(contd)
Limbah cair
Limbah sanitasi (limbah manusia dan grey water dari pencucian dan dapur) harus diolah dalam septic tank atau sistem pengolahan lain yang sesuai sebelum dibuang. Limbah cair rumahtangga/kantor bisa terjadi dari larutan detergen pencuci bekas yang sudah lama/tidak digunakan, thinner, toner, dsb. Cairan ini tidak boleh dibuang langsung ke air permukaan dan pada umumnya tidak boleh dikeluarkan melalui tempat pencucian piring atau saluran pembuangan lain.
Occupational Safety and Health 510
Aspek Keselamatan
PPE (Personal Protective Equipment)
511
Penggunaan Peralatan/Fasilitas
Scaffold Pelindung jatuh
Sabuk, tali peredam kejut (self retracting lifeline, sambungan angker, & penyangga angker
Perancah (Scaffold)
Pastikan ground/decking cukup untuk menahan beban Semua tiang standar vertical dibangun tegak lurus terhadap ground Punya ikat depan & samping Ada pagar pengaman Tempat berpijak terbuat dari scaffold boards, papan / batangan besi Tangga akses kencang Terlindung dari angin (clamp logam) Personil memakai life jacket & sabuk keselamatan Memberi tanda peringatan & batas
Occupational Safety and Health 514
Transportasi
Transportasi juga merupakan potensi bahaya peraturan & prosedur Udara Helikopter Dibuat prosedur standar & larangan Air Kapal Dibuat standar penggunaan (pemeriksaan awal & pembatasan, check-in, naik ke kapal, jika ada hambatan cuaca)
Occupational Safety and Health 515
516
HAZOP
Tujuan dilakukan HAZOP : Identifikasi keselamatan, bahaya & masalah operasi yang berhubungan dengan proses yang secara langsung mengancam keselamatan pekerja produksi/penyebab masalah operasi. Menentukan keseriusan dampak masalah teridentifikasi. Identifikasi secara engineering & procedural safeguards yang sebelumnya telah dibuat. Evaluasi kelayakan engineering & procedural procedural safeguards. Rekomendasi safeguards atau prosedur operasi tambahan jika diperlukan.
Occupational Safety and Health 517
Metodologi Studi
Kolom Kepala
No
Guide Word / Deviation
Deskripsi
Nomor yang direferensi
Kata-kata panduan yang dijadikan standard untuk menganalisis dan menentukan potensi masalah Penyebab atau masalah yang teridentifikasi Deskripsi konsekuensi dampak yang mungkin terjadi dari penyebab Tersebut Jenis masalah yang terlibat termasuk operasional, keselamatan, keuangan dan peraturan Deskripsi petunjuk keselamatan Deskripsi kegiatan yg direkomendasi Bagian yang bertanggung jawab atas kejadian
Occupational Safety and Health 519
Type
Probability
Medium
Low
< 1 in 1000, extremely unlikely
Potensial Consequences
1 in 10 1000, sometimes
Hazard
Very High
Personnel
Multiple Fatality Single Fatality Permanent Disability Minor Injuries
Asset
>$5
Environment
1K-10K bbls spill H H H
High
Medium
15-100bbls spills
Low
Very Low
<$0.1
520
Tingkat Resiko
Low Priority resiko tidak serius & aktifitas yang direkomendasi tidak digunakan untuk major modification. Medium Priority resiko cukup signifikan & aktifitas yang direkomendasikan perlu investigasi lanjut untuk dapat solusi terbaik. High Priority resiko signifikan & berhubungan dengan desain / filosofi keselamatan. Aktifitas dilakukan segera untuk dapat solusi optimal & implementasi dilaksanakan secepat mungkin.
Occupational Safety and Health 521
Kata Panduan
Kata Panduan Kata Panduan Kata Panduan Kata Panduan
No Flow
Less Flow
More Level
Less Pressure
Composition
Corrosion/Erosion
Personnel Safety
External Factors
More Flow
More Pressure
Instrumentation
Operations
Reverse Flow
Less Temperature
Relief
Maintenance
Misdirected Flow
More Temperature
Personnel Safety
Drawing
Less Level
Contaminants
Relief
522
Analisa Kerugian
SDM
Semua pembayaran kesehatan karyawan ditangggung penuh oleh perusahaan. Jika kecelakaan kerja terjadi di tempat kerja maka perusahaan menyediakan alat pengangkutan korban menuju rumah sakit, semua biaya pengobatan dan perawatan ditangggung sampai dapat bekerja kembali. Jika pekerja tidak dapat bekerja / cacat karena kecelakaan, meninggal karena kecelakaan / meningggal mendadak di tempat kerja maka perusahaan memberikan santunan untuk pekerja dan atau keluarganya sebesar 72 x Upah.
Occupational Safety and Health 523
Asset
Semua peralatan yang dimiliki perusahaan diasuransikan. Jika kecelakaan tidak besar maka perusahan memperbaiki sendiri.
Lingkungan
Jika terjadi kerusakan lingkungan yang disebabkan oleh kecelakan maupun operasi perusahaan, maka perusahaan berusaha memenuhi kewajiban sesuai dengan klaim yang ada.
Produktivitas
Perusahaan langsung menghentikan aktifitas produksi jika terjadi kecelakaan. Selain itu warning kecil pun juga menjadi perhatian utama. Sangat memungkinkan jika suatu warning kecil dapat menghentikan operasi produksi.
Occupational Safety and Health 524
525
1897 ditemukan sumber minyak di Sanga, Tarakan, Samboja, dan Bunyu 1946 direnovasi karena hancur dalam PD II, membangun PMK I & II, Wax Plant, HVU I 1997 PMK I & II diganti menjadi CDU V, dan HVU I menjadi HVU III Crude Oil berasal dari Minas, Tanjung Sepinggan, Badak, Handil, Bekapai, Arjuna, Attaka, dll. Kadangkadang berasal dari luar negeri : Jabiru, Chalyst, Crude(Auatralia), dan Tapis crude(Malaysia) Produk motor gasoline, kerosene, avtur, solar, minyak diesel, fuel oil, Heavy Naphta, LPG, wax
Occupational Safety and Health 526
IKHTISAR KILANG
KILANG BALIKPAPAN I Crude Distillation Unit Unit Penyulingan Hampa (HVU III) Wax Plant Dehydration Plant KILANG BALIKPAPAN II Hydroskimming Complex (HSC) Hydrocracking Complex (HCC)
527
PLANT PENUNJANG
Fuel Gas System, Plant 15 Flare System, Plant 19 Caustic Soda Plant, Plant 25 BFW and Steam, Plant 31 Cooling Water System, Plant 32
Air and Nitrogen Plant, Plant 35
528
Secara fisik merupakan cairan yang mengandung gas, cairan, dan elemen-elemen padat yang terlarut di dalamnya Terbentuk dari peristiwa dekomposisi berbagai macam hewan dan tumbuhan jutaan tahun yang lalu Umumnya bercampur dengan air garam dan gas alam, yang membentuk 3 lapisan Dipergunakan luas sebagai bahan bakar Berdasarkan strukturnya, dibagi menjadi 4 golongan utama : 1. Senyawa golongan parafin 2. Senyawa golongan naphten 3. Senyawa golongan aromatik 4. Senyawa golongan olefin
529
PROSES
Minyak Mentah
Pemanasan Awal Desalter
Crude heater
Kolom Destilasi Produk
Occupational Safety and Health 530
Produk
Overhead vapor
Overhead Liquid
Reduced Crude
Occupational Safety and Health 531
Material
Penanganan
Jika terkena mata, segera basuh dengan air Jika tertelan jangan dimuntahkan, segera hubungi dokter Bawa korban ke udara segar jika terhirup Jika terbakar, padamkan dengan dry chemical, CO2, water spray
532
Material produk
Potensi Bahaya
Penanganan
LPG
Pada konsentrasi uap yang tinggi dapat menyebabkan iritasi dan rasa terbakar pada mata dan kulit. Jika terhirup dapat menyebabkan asphyxiant, pusing, nausea dan pingsan
Segera cuci dengan air Jika terhirup segera beri udara segar dan perawatan medis Jika terjadi kebakaran gunakan fire extinguisher dry chemical, CO2atau water spray Jauhkan LPG dari sumber api atau panas
533
Kerosene
Menyebabkan iritasi pada kulit jika mengalami kontak yang lama dan berulang. Berakibat fatal jika terbawa dalam respirasi dan menyebabkan iritasi pada gastrointestinal serta diare
Segera cuci kulit yang terkena iritasi dengan air sabun. Jika tertelan jangan muntahkan dengan paksa, beri perawatan medis. Segera padamkan api yang timbul dengan menggunakan extinguisher CO2, dry chemical, foam atau water spray.
534
Light naptha
Iritasi ringan pada mata dan kulit Jika tertelan dapat merusakparuparu dan saluran pernafasan Kontak terlalu lama danberulang dapat menyebabkan kanker kulit dan merusak sistem saraf pheripheral
Segera basahi mata dengan air dan untuk kulit gunakan air sabun (jika terjadi iritasi). Jika terhirup segera beri udara segar Jika tertelan jangan muntahkansecara paksa, segera beri perawatan medis Jauhkan dari sumber api dan panas
535
heavy naptha
Iritasi ringan jika terkena mata dan kulit. Jika tertelan atau terhirup menyebabkan batuk, cegukan, sesak nafas, sakit kepala, nausea dan tidak sadarkan diri (jika tertelan dalam jumlah besar)
Basahi mata atau kulit yang terkena iritasi dengan air bersih. Jika terhirup segera beri udara segar dan jika tertelan segera beri perawatan medis. Jika terjadi kebakaran segera padamkan menggunakan dry chemical, CO2, foam atau water spray.
536
Gas Oil
Iritasi ringan pada mata dan kulit Jika tertelan dapat merusak paru-paru dan saluran pernafasan
Segera basahi mata dengan air dan untuk kulit gunakan air sabun (jika terjadi iritasi). Jika terhirup segera beri udara segar Jika tertelan jangan muntahkan secara paksa, segera beri perawatan medis
537
Lindungan Lingkungan
Effluent Water Treatment Plant Elevatic Flare Stack Alat Peredam Kebisingan Incinerator
538
Merupakan identifikasi resiko terhadap suatu kegiatan Contoh kegiatan yang diidentifikasi antara lain: - Pengecekan berkala kondisi operasi oleh operator lapangan - Memperbaiki pompa - Mengganti sambungan pipa yang dilas
539
No
Jenis kegiatan
Hazard potency
Tingkat kemungkinan
Resiko
Pencegahan
Resiko akhir
Menggunakan google
540
Panas yang besar dari percikan api las Mengganti sambungan pipa yang dilas
541
proses identifikasi bahaya yang mungkin terjadi terhadap plant yang mencakup setiap bagian plant tersebut Contoh bagian plant yang diidentifikasi resiko bahaya yang mungkin terjadi adalah storage tank dan pipe rack
542
No
Description
Location
Cause
Hazard potency
Hazard effect
Hazard frequency
prevention
Major
Likely
LC, FC, PC
Storage tank Tangki pecah Gempa bumi Severe Unlike ly Konstruksi tahan gempa dan pemasangan seismograf
543
Kebakaran
Severe
Unlikely
Korosi
Kebocoran
Major
Likely
Pondasi piperack rubuh karena korosi 2 Tempat meletakkan kumpulan pipa Piperack
Pipa-pipa berjatuh-an
Major
Unlikely
Keba-karan
Pipa terbakar
Major
Unlikely
544
HAZOPS
(Hazard and Operability Study)
Merupakan
proses identifikasi bahaya yang mungkin terjadi terhadap suatu bagian pemrosesan pada pabrik Dilakukan pada saat sebelum membangun pabrik, akan mengganti salah satu atau lebih alat Parameter dasar HAZOPS adalah flow, temperature, pressure
545
Deviasi Para meter Penyebab Kata panduan Akibat Implikasi Pence gahan
Ket.
Peralatan Furnace
No 1
No
Furnace meledak
FC dan TC
LC, LALL
More
TC
LAHH
546
Reverse
PC
Pengecekan berkala
Suhu
Less
TC
547
More
TC
Less
PC
PI
More
Kerusakan furnace
PC
PI
548
KESIMPULAN
Analisis
identifikasi bahaya suatu pabrik perlu dilakukan untuk menjamin keselamatan para pekerja dan investasi pabrik. Peningkatan kinerja pabrik sangat ditentukan oleh keselamatan dan kesehatan kerja.
549
550
Lokasi Pabrik
PT Ecogreen Oleochemicals berlokasi di Kabil, Pulau Batam, Propinsi Riau, Indonesia, sekitar 20 km sebelah tenggara Singapura. Daerah Kabil terietak di tepi laut. bagian tenggara Pulau Batam dengan rata-rata suhu udara 29C dan kelembaban sekitar 85%.
Occupational Safety and Health 552
Lokasi Pabrik
Kapasitas
Di Indonesia, plant saturated fatty alcohol milik Ecogreen yang pertama adalah di Medan dengan kapasitas 30,000 MT/tahun mulai beroperasi secara komersial pada tahun 1991. Tiga tahun kemudian plant kedua didirikan di Batam dengan kapasitas 60,000 MT/tahun untuk fatty alcohol, 9,000MT/tahun untuk gliserin dan 6,000 MT untuk metilester
555
BAHAN BAKU
Minyak
dan lemak nabati Minyak kernel kelapa sawit (CPO) Minyak Kelapa (coconut oil)
556
557
558
Reaksi Trans-esterifikasi
559
Reaksi Dehidrogenasi
560
561
Analisa HIRA(lanjutan)
562
Analisa HAZID
563
564
Analisa HAZID(lanjutan)
565
566
Analisa HIRA
567
568
Analisa Hazops
Pompa
Kompresor
Heat Exchanger
Reaktor (Hidrogenasi) Separator Degasser
Occupational Safety and Health 569
cooler H2
Cooler
Cooler
pump
P3
Hasil2 C3 P4
571
572
573
574
575
576
577
Aspek Keselamatan Kerja : Pembentukan Panitia Pembina Keselamatan dan Kesehatan Kerja (P2K3) untuk membuat program jangka pendek dan jangka panjang demi kepentingan masa depan dan keselamatan kerja seluruh komponen PT Ecogreen Oleochemicals.
578
Program-Program P2K3 :
Pemenuhan
kelengkapan klinik khusus di PT Ecogreen Oleochemicals Membenahi hydran yang ada di dalam maupun diluar areal pabrik Mengadakan pengecekan tabung pemadam secara berkala rutin. Membuat layout area yang dianggap berbahaya Mengadakan training pemadaman kebakaran kepada seluruh karyawan.
Occupational Safety and Health 580
tangan Wearpack Masker Goggle Alat pemadam kebakaran Denah evakuasi dan posisi alat pemadam
Occupational Safety and Health 581
Aspek
-
Lingkungan
Sebagian besar bahan bersifat alami : aman Gas yang dibuang : CO & CO2
582