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Composition of Matter
Atoms and Molecules Scientific Method
Molecules
are two or more atoms attached together in a specific geometrical arrangement
attachments are called bonds attachments come in different strengths
Chemistry
Chemistry is the science that seeks to
understand the behavior of matter by studying the behavior of atoms and molecules
reasoning and thinking about ideal behavior Scientists try to understand the universe through empirical knowledge gained through observation and experiment
Testing Ideas Ideas in science are tested with experiments An experiment is a set of highly controlled
procedures designed to test whether an idea about nature is valid The experiment generates observations that will either validate or invalidate the idea
single or small number of observations A scientific theory is a general explanation for why things in nature are the way they are and behave the way they do
models pinnacle of scientific knowledge validated or invalidated by experiment and observation
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Scientific Method
Tentative explanation of a single or small number of observations
General explanation of natural phenomena Careful noting and recording of natural phenomena
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Classification of Matter
States of Matter Physical and Chemical Properties Physical and Chemical Changes
Classification of Matter
Matter is anything that occupies space and
has mass We can classify matter based on its state and its composition
whether it is solid, liquid, or gas its basic components
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Classifying Matter by Physical State Matter can be classified as solid, liquid, or gas
based on the characteristics it exhibits
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Solids
The particles in a solid are packed
close together and are fixed in position
though they vibrate
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Liquids
The particles in a liquid are
closely packed, but they have some ability to move around The close packing results in liquids being incompressible The ability of the particles to move allows liquids to take the shape of their container and to flow however, they dont have enough freedom to escape or expand to fill the container
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Gases
In the gas state, the particles
have freedom of motion and are not held together The particles are constantly flying around, colliding with each other and the container In the gas state, there is a lot of empty space among the particles
on average
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Gases
Gases are compressible
because there is a lot of empty space among the particles since they can be squeezed closer together. Because the particles are not held in close contact and are moving freely, gases expand to fill and take the shape of their container, and will flow
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1. made of one type of particle 2. all samples show the same intensive properties
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1. made of multiple types of particles 2. samples may show different intensive properties
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1. made of one type of molecule, or an array of ions 2. units contain two or more different kinds of atoms
Classification of Mixtures
Homogeneous mixtures are mixtures that have
uniform composition throughout
every piece of a sample has identical characteristics, though another sample with the same components may have different characteristics atoms or molecules mixed uniformly
Classification of Mixtures
1. made of multiple substances, whose presence can be seen 2. portions of a sample have different composition and properties 1. made of multiple substances, but appears to be one substance 2. all portions of an individual sample have the same composition and properties
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Properties of Matter
Physical properties are the characteristics of
matter that can be changed without changing its composition
characteristics that are directly observable
changes in the matter C12H22O11(s) that do not change its composition State changes Dry Ice
boiling / condensing melting / freezing subliming
Dissolving
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CO2(s) C12H22O11(aq)
Freezing water to make ice cubes Dry ice evaporating at room temperature Toasting a piece of bread Dissolving sugar in hot coffee Crushing an aluminum can
Freezing water to make ice cubes Dry ice evaporating at room temperature Toasting a piece of bread Dissolving sugar in hot coffee Crushing an aluminum can
a.squeezing oranges to make orange juice b.melting butter for popcorn c.separating sand from gravel d.hydrogen peroxide decomposes to water and
oxygen e.ozone is a gas at room temperature
a.squeezing oranges to make orange juice b.melting butter for popcorn c.separating sand from gravel d.hydrogen peroxide decomposes to water
and oxygen e.ozone is a gas at room temperature
Energy
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Energy of Matter All matter possesses energy Energy is classified as either kinetic or
potential Energy can be converted from one form to another When matter undergoes a chemical or physical change, the amount of energy in the matter changes as well
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Conversion of Energy
potential energy Whatever process you do that converts energy from one type or form to another, the total amount of energy remains the same
Law of Conservation of Energy
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Spontaneous Processes
Materials that possess high
potential energy are less stable Processes in nature tend to occur on their own when the result is material with lower total potential energy
processes that result in materials with higher total potential energy can occur, but generally will not happen without input of energy from an outside source
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Related Units in the SI System All units in the SI system are related to the
standard unit by a power of 10 The power of 10 is indicated by a prefix multiplier The prefix multipliers are always the same, regardless of the standard unit Report measurements with a unit that is close to the size of the quantity being measured
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Length
SI unit = meter
about 3.37 inches longer than a yard
1 meter = distance traveled by light in a specific period of time
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Mass
Time Measure of the duration of an event SI units = second (s) 1 s is defined as the period of time it
takes for a specific number of radiation events of a specific transition from cesium133
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Temperature
Measure of the average amount of kinetic energy
caused by motion of the particles
higher temperature = larger average kinetic energy
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Temperature Scales
Fahrenheit scale, F
used in the U.S.
Celsius scale, C
used in all other countries
Kelvin scale, K
absolute scale
no negative numbers
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Fahrenheit degree The standard used for 0 on the Fahrenheit scale is a lower temperature than the standard used for 0 on the Celsius scale
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Volume
Derived unit Measure of the amount of space
any length unit cubed
occupied SI unit = cubic meter (m3) Commonly measure solid volume in cubic centimeters (cm3)
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Density
Density is the ratio of mass to volume
is an intensive property
Solids = g/cm3
1 cm3 = 1 mL
Density
Calculating Density
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Which of the following would NOT be considered an intensive property describing an unknown sample?
It is a solid at 25 C. It has a density of 1.38 g/ cm3. It melts at 62.0 C. It has a volume of 0.52 cm3. It is shiny.
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Estimating the Last Digit For instruments marked with a scale, you get
the last digit by estimating between the marks
if possible
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When reading a graduated cylinder, read the volume at the bottom of the meniscus. What volume of liquid is in the graduated cylinder? a) b) c) d) e) 4 mL 5 mL 4.5 mL 4.6 mL 4.56 mL
When reading a graduated cylinder, read the volume at the bottom of the meniscus. What volume of liquid is in the graduated cylinder? a) b) c) d) e) 4 mL 5 mL 4.5 mL 4.6 mL 4.56 mL
Significant Figures
The non-place-holding digits in
a reported measurement are called significant figures
some zeros in a written number are only there to help you locate the decimal point 12.3 cm has 3 sig. figs. and its range is 12.2 to 12.4 cm 12.30 cm has 4 sig. figs. and its range is 12.29 to 12.31 cm
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0.04450 m
5.0003 km
4 sig. figs.; the digits 4 and 5, and the trailing 0 5 sig. figs.; the digits 5 and 3, and the interior 0s
10 dm = 1 m infinite number of sig. figs., exact numbers 1.000 105 s4 sig. figs.; the digit 1, and the trailing 0s 0.00002 mm 1 sig. figs.; the digit 2, not the leading 0s
10,000 m
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Practice Determine the number of significant figures, the expected range of precision, and indicate the last significant figure
0.00120 120. 12.00 1.20 x 103
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Practice determine the number of significant figures, the expected range of precision, and indicate the last significant figure
0.00120 120. 12.00 1.20 x 103 3 sig. figs. 0.00119 to 0.00121
5.892
5.9 - 2 . 2 2 1 = 5. 7 5.67 9
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Rounding
When rounding to the correct number of significant figures, if the number after the place of the last significant figure is a) 0 to 4, round down drop all digits after the last sig. fig. and leave the last sig. fig. alone add insignificant zeros to keep the value if necessary b) 5 to 9, round up drop all digits after the last sig. fig. and increase the last sig. fig. by one add insignificant zeros to keep the value if necessary To avoid accumulating extra error from rounding, round only at the end, keeping track of the last sig. fig. for intermediate calculations
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Rounding
Rounding to 2 significant figures 2.34 rounds to 2.3
because the 3 is where the last sig. fig. will be and the number after it is 4 or less
Rounding
Rounding to 2 significant figures 0.0234 rounds to 0.023 or 2.3 102
because the 3 is where the last sig. fig. will be and the number after it is 4 or less
Rounding
Rounding to 2 significant figures 234 rounds to 230 or 2.3 102
because the 3 is where the last sig. fig. will be and the number after it is 4 or less
Example 1.6: Perform the Following Calculations to the Correct Number of Significant Figures
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Example 1.6 Perform the Following Calculations to the Correct Number of Significant Figures
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Precision
Imprecision in measurements is caused by
random errors
errors that result from random fluctuations no specific cause, therefore cannot be corrected
Accuracy
by evaluating how far it is from the actual value Systematic errors do not average out with repeated measurements because they consistently cause the measurement to be either too high or too low
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Looking at the graph of the results shows that Student A is neither accurate nor precise, Student B is inaccurate, but is precise, and Student C is both accurate and precise.
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A student measures the mass of a penny 4 times and records the following data. What can be said about the data if the actual mass of the penny is 2.4987 g?
Trial Number
1 2 3 4
Mass, g
2.5104 2.5106 2.5102 2.5109
A student measures the mass of a penny 4 times and records the following data. What can be said about the data if the actual mass of the penny is 2.4987 g?
Trial Number
1 2 3 4
Mass, g
2.5104 2.5106 2.5102 2.5109
Units
Always write every number with its unit Always include units in your calculations
you can do the same kind of operations on units as you can on numbers
cm cm = cm2 cm + cm = cm cm cm = 1
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relationships to convert one unit of measurement to another Conversion factors are relationships between two units
may be exact or measured
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3. Change equivalence into conversion factors with given unit on the bottom
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Example 1.10: What is the mass in kg of 173,231 L of jet fuel whose density is 0.768 g/mL?
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