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TRNG I HC CN TH
ti:
CH TO V KHO ST TNH CHT
CA CHT LNG T FERIT CoFe2O4
LUN VN THC S
CHUYN NGNH: VT L K THUT
Cn Th Thng 10/2008
Sng Th Vi
Nc ti 1 cng x bn b ro
4/26/2014
Cng Ty Vedan
Nc bn Cng Ty Vedan
Ferit coban c:
t ha bo ha cao.
Tnh d hng t cao.
t b oxy ha hn ferit st.
CoFe2O4 v Fe3O4 c nhng thng s gn bng nhau:
Vt liu
KLPT
(g)
Cu
trc
Hng s
mng
( Ao)
Fe3O4
231,54
spinel
8,39
858
477
-13
CoFe2O4 234,63
spinel
8,38
793
398
180
TC Ms
( K) (KA.m-1)
K1
(KJ.m-3)
MC TIU CA TI
To ra cht lng t CoFe2O4 c:
t ha v cm t cao.
Cc cht kch hot b mt phi dng huyn ph trong
cht lng mang.
4/26/2014
Ferit t cng.
Cu trc tinh th lp phng spinel
ngc.
L nhng ht n men
men
Vch
men
V tr t din
xi.
V tr bt din
V tr bt din.
V tr t din.
4/26/2014
Cht lng t
Cht lng t l mt huyn ph gm cc ht vt liu t
nh b (kch thc c nano mt) v cht lng mang cc ht
t ny.
Cht lng t gm ba thnh phn chnh:
4/26/2014
Axit Oleic
Cng thc phn t: C18H34O2
Cu trc
Tnh cht vt l:
Cht lng nh du mu vng nht hay vng hi nu, c mi
ging m ln, khng ha tan trong nc m ha tan trong nhexan, kerosene v ethanol
Nhit nng chy: 13- 14oC.
Nhit si: 360oC( 760 mmHg).
T trng: 0.895- 0.947 g/cm3.
4/26/2014
Phng php ng kt ta
MeCl2 + 2FeCl3 + 8NaOH MeFe2O4 + 8NaCl + 4H2O
MeCl2 + 2FeCl3 + 8NH4OH MeFe2O4 + 8NH4Cl + 4H2O
CoCl2.6H2O + 2 FeCl3.6H2O + 8 NaOH CoFe2O4 + 8NaCl + 22H2O
u im:
Ch to n gin.
Phn ng xy ra nhanh.
C th to ra ht nano vi ng nht, phn tn kh cao, rt
thch hp cho phn ln cc ng dng trong nhiu lnh vc.
4/26/2014
10
4/26/2014
11
Cc cht bn
trong nc
phi sau thi
gian di mi
lng ng.
4/26/2014
Al2(SO4)3
to thy
phn to keo
Al(OH)3 ko
cc cht bn
lng ng
xung di.
Ht nano t tnh
gip keo
Al(OH)3 lm
lng ng cht
bn nhanh hn
khi dng mt t
trng ngoi.
12
St kh N2
dd NaOH
80 - 90 oC
Rung siu m 1 h
Khuy trn
Ht CoFe2O4
ng kt ta
Dung dch kt ta mu
en
Cho vi git
HCl lang
Ly tm 15 pht
( 3000 rpm)
4/26/2014
13
Nng NaOH
(mol/l)
VNaOH
(ml)
VMui
(ml)
pH[1]
pH[2]
pH[3]
t(oC)
Thi
gian
(pht)
Ghi ch
HAo
150
20
10
9,1
67
50
60
Sc N2
HA1
150
20
10
9,2
67
80
65
HA2
150
20
10
67
80
65
HA3
150
20
10
67
90
60
HA4
150
20
10
67
90
80
HA5
2,5
60
20
11
9,5
67
80
65
HA6
2,5
60
20
11
9,5
67
80
60
HA7
2,5
60
20
11
9,4
67
90
55
HA8
2,5
60
20
11
9,8
67
90
65
HA9
3,5
43
20
13
11,5
67
80
75
HA10
3,5
43
20
13
11
67
80
60
HA11
3,5
43
20
13
11,5
67
90
60
3,5
43
20
13
12
67
90
45
4/26/2014
HA12
Sc N2
Sc N2
Sc N2
Sc N2
Sc N2
Sc N2
14
15 ml NH4OH
20 ml axit Oleic
Khuy trn 1 h
un nng
100 ml ethanol
Khuy, un nng
n 80oC
Gn, cht
4/26/2014
Cht lng t
CoFe2O4
15
Mu
ht
V
(Oleic)
(ml)
HL4
HA4
16
30
1: 23: 4,8
15
n-hexan(30%)
100
HL4*
HA4
16
30
1: 50: 4,8
15
ethanol (30%)
100
HL8
HA8
20
30
1: 72: 6
n-hexan
100
HL10
HA10
20
30
1: 170: 6
15
ethanol
100
HL10*
HA10
20
80
1: 50: 6
ethanol (30%)
100
HL12
HA12
20
80
1: 170: 6
15
ethanol
100
4/26/2014
t
T l mol V(NH4OH) Dung mi
(Oleic) gia
(ml)
(oC) ht,dung
mi, cht
ph
V (Dung
mi)
(ml)
16
My o ph nhiu x tia X
T k mu rung
CoFe2O4
(113)
CoFe2O4
(220)
CoFe2O4
(220)
CoFe2O4
(024)
CoFe2O4
(110)
CoFe2O4
(033)
CoFe2O4
(110)
Ph X-Ray ca mu HA8
Co
Fe2O4
(220)
CoFe2O4
(110)
CoFe2O4
(024)
CoFe2O4
(033)
Ph X-Ray ca mu HA10
CoFe2O4
(113)
CoFe2O4
(033)
CoFe2O4
(024)
Mu
Nng
NaOH (mol/l)
Nhit
(oC)
Kch thc
(nm)
HA8
HA10
HA12
2,5
3,5
3,5
90
80
90
13,9 15,3
13,1 16,2
15,3 16,2
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18
Kho st t tnh ca ht
t ha bo ha ph thuc vo
nng NaOH.
HA4
HA8
HA12
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Nng
NaOH
(mol/l)
Nhit
(0C)
Ms
(emu/g)
Hc(Oe)
Ghi ch
1
2,5
3,5
90
90
90
57
51
50,5
881
895
920
Sc N2
Sc N2
Sc N2
19
3,5
3,5
80
90
55
50,5
Hc(Oe)
Ghi
ch
828
920
Sc N2
Sc N2
20
Vic sc kh N2 c nh
hng rt ln n t ha
bo ha ca mu
Nng
NaOH
(mol/l)
Nhit
(oC)
Ms (emu/g)
Hc(Oe)
HA11
HA12
3,5
3,5
90
90
31
50,5
1751
920
4/26/2014
Sc N2
Khng
C
21
t ha bo ha ca cc mu ht
60
57
iu kin tng hp ht
tt nht:
55
51
50.5
t ha (emu/g)
50
HA4
40
31
30
20
HA8
HA10
HA11
HA12
Nng NaOH 1 M.
Nhit : 8090oC.
Sc kh nit.
10
0
Biu biu th t ha ca cc mu ht
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22
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23
25
Dung mi
Nhit
(0C)
Ms (emu/g)
Hc(Oe)
HL4
n-hexan (30 %)
80
27
780
HL8
n-hexan
80
21
1450
4/26/2014
26
HL10
ethanol
80
41
1294
Mu
HA4
HL4
HA8
HL8
HA10
HL10
Ms
(emu/g)
57
27
51
21
55
41
HC ( Oe)
881
780
895
1450
828
1294
27
t ha (emu/g)
t ha bo ha ca mu ht
v mu ph
60
40
57
HA4
55
51
41
27
21
20
HL4
HA8
HL8
0
1
HA10
HL10
Biu biu th t ha ca cc mu ht v mu ph
4/26/2014
28
t ha (emu/g)
t ha ca mu nano t ferit
coban v oxit st
80
60
40
20
0
1
Mu
t ha
(emu/g)
HA10
55
HA10
HL10
41
HL10
H6
71,77
H6
DH2
39,7
DH2
Biu biu th t ha ca mu
bin thin t ha
(emu/g)
14
32,07
Mu CoFe2O4 n nh t tnh tt hn
mu Fe3O4
CoFe2O4 v mu Fe3O4
4/26/2014
29
4/26/2014
4/26/2014
31
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32
Ph hp th FT-IR
O
C
O
Ht
nan
S gn kt ca Oleic ln b mt ht
CoFe2O4
s hin din
ca axit Oleic ln b
mt ht.
C
4/26/2014
C s gn
gia lp ph v
th hin qua lin
COO-ht nano
CoFe2O4.
kt
ht
kt
t
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KT LUN
Cht lng t CoFe2O4 c ch to gm:
Cc ht ferit CoFe2O4:
* n pha.
* Hng s mng a = 8,402 Ao.
* Kch thc: 15 20 nm
* Ms = 50 57 emu/g , HC: 828 1751 Oe.
Lp ph: Axit Oleic.
Dung mi: Ethanol gip n nh t tnh tt, Ms: 41 emu/g.
Cc ht sau khi ph c kch thc t 25 30 nm.
T l gia ht, dung mi v cht ph thch hp m bo yu cu
ca cht lng t.
PHN 4: NG DNG
36
A
s
N
i
N
i
N
i
F
e
Niken
F
e
Z
n
Z
n
A
s
HtCoFe2O4
A
s
Km
St
Asen
F
e
Z
n
N
4/26/2014
S
37
Ht CoFe2O4
rung siu m 10
pht (DD1)
Khuy trn
4rpm, 24 h
Lng mu bng
nam chm
Dng mng lc
Ly tm 4000 rpm,
30 pht
4/26/2014
38
Sn phm
250 ml nc b nhim st
Lc th
3 ml
Tris buffer 8.0
Dd nc cn x l pH=8
( DD1)
DD2
Mng lc
Sn phm
4/26/2014
39
Kt qu
Bng kt qu ca cc mu nc c iu ch
trong phng th nghim trc v sau khi x l
K hiu
mu
Ch
tiu
phn
tch
Loi
mu
T
trng
lng
Thi
gian
lng
Nng
trc
x l
(mg/l)
Nng
sau
x l
(mg/l)
Nng
chun
(mg/l)
Hiu
sut
kh
( %)
HZn
Zn
Lng
0,15 T
24 h
9,89
< 0,02
99,8
HNi
Ni
Lng
0,15 T
24 h
5,96
< 0,04
0,1
99,3
HPb
Pb
Lng
0,15 T
24 h
41,3
KPH*
0,015
100
HLPb
Pb
Lng
0,15 T
24 h
41,3
0,067
0,015
99,8
HHH
Zn
Lng
0,15 T
24 h
17,3
KPH*
100
HHH
Ni
Lng
0,15 T
24 h
6,42
KPH*
0,1
100
HHH
As
Lng
0,15 T
24 h
5,448
0,038
0,01
99,3
4/26/2014
40
Ch
tiu
phn
tch
Thi
gian
khuy
(gi)
T
trng
lng
Thi
gian
lng
(gi)
HFeR
HFe1
HFe2
Nng
(mg/l)
Nng
chun
(mg/l)
Hiu
sut
kh
( %)
0,5
99,8
15,07
Fe
12
0,15 T
0,03
0,15 T
17
KPH*
100
Nhn xt
Cc ht CoFe2O4 hp ph tt c cc kim loi nng kho st.
Bm nc ln
Bn cha
nc
B phn lc 1
Ht
CoFe2O4
B phn hp ph
kim loi nng ca
cc ht CoFe2O4
Nc cn
x l
B phn lc 2
Ht CoFe2O4
hp ph kim loi
nng
Thit b
kh trng
4/26/2014
42
Nc sch
KT LUN CHUNG
1. Bng phng php ng kt ta ch to c cc ht nano t CoFe2O4:
* n pha, cu trc tinh th lp phng spinel.
* Kch thc t 15 20 nm, hng s mng a = 8,402 Ao.
* Ms = 50 57 emu/g, HC = 828 1751 Oe
2. tng hp c cht lng t ferit gm:
* Cc ht nano t CoFe2O4, kch thc trung bnh: 25 30 nm.
* Cht ph Oleic.
* Cht lng mang ethanol.
* T l mol gia ht, dung mi, cht ph l 1: 170: 6.
* t ha bo ha cao 41 emu/g.
* nht 13,62 cst.
* T trng: 0,893 mg/l.
3. ng dng cc ht nano t v cc ht cht lng t CoFe2O4 x l mu
nc b nhim asen, ch, km, niken, st vi hiu sut: 99,3 100 %.
43
44
Cc kt qu trong lun vn s c bo co ti
hi ngh Khoa Hc i Hc Quc Gia TP.HCM
thng 11 nm 2008.
Kt qu ny l mt phn ca bi bo
Researching of absorbability of As and heavy
metal of magnetic nano particles coated with Oleic
and Chitosan. s c bo co vo ngy 10-13/12/
2008 ti Hi Ngh Asian Magnetics Conference
2008, Busan, Hn Quc.
4/26/2014
45
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46