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CORROSION PREVENTION
METALS AND ALLOYS
Stainless steel is not stainless, it is not the
most corrosion-resistant material, and it is
not a specific alloy.
( from 11.5 to 30% chromium and from zero
to 22% nickel, together with other alloy
additions).
Passivity
Passivity in a metal refers to a relatively
inactive state in which it (the metal) displays
a more noble behavior than thermodynamic
considerations predict. It is the reason a
metal does not corrode when it should.
For
oxidizing
conditions,
containing alloys are used.
chromium-
METAL PURIFICATION
Pure metals are usually expensive and
relatively soft and weak, but more
corrosion resistant.
Pure aluminum (99.5%+) is used for handling
hydrogen peroxide, where the presence of
other elements may cause decomposition
because of catalytic effects.
NON-METALLICS
Rubber, natural and synthetic.
Plastics.
Ceramics.
Carbon and graphite.
Wood.
ALTERATION OF ENVIRONMENT
** Changing Mediums:
Lowering temperature, decreasing velocity,
removing oxygen or oxidizers and changing
concentration.
Boiling seawater is less corrosive than hot
seawater because of the decrease in oxygen
solubility with temperature.
INHIBITORS:
Adsorption-Type Inhibitors:
These are organic compounds which
adsorbed on the metal surface and suppress
metal dissolution and reduction reactions.
They affect both the anodic and cathodic
processes. (organic amines).
Hydrogen-Evolution Poisons:
Arsenic and antimony ions, retard the
hydrogen-evolution reaction.
They are effective in acid solutions but are
ineffective in environments where other
reduction processes such as oxygen reduction
are the controlling cathodic reactions.
Scavengers:
These substances act by removing corrosive
reagents from solution.
Na2SO3 + O2 2Na2SO4
N2H4 + O2 N2 + 2H2O
Sodium sulfate and hydrazine will not be
effective in strong acid solution, because
oxygen reduction is not the controlling
corrosion cathodic reaction.
Oxidizers:
They inhibit the corrosion of metals and
alloys that demonstrate active-passive
transitions (i.e., iron and its alloys and
stainless steels).
Chromate, nitrate and ferric salts are
oxidizers inhibitors.
Vapor-Phase Inhibitors:
They are usually used in closed spaces such as
inside packages or on the interior of
machinery during shipment, because they are
transferred by sublimation and condensation
to the metal surface.
Design
Mechanical design of a component should be
based on the material of construction.
** Wall Thickness
The wall thickness is usually made twice the
thickness that would give the desired life, to
allow for some variation in the depth of
penetration during uniform corrosion, which
is not always uniform.
adsorb
Design to exclude air, except for activepassive metals and alloys, such as stainless
steel and titanium.
Avoid heterogeneity: Dissimilar metals, vapor
spaces, uneven heat and stress distributions.