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pH + pOH = 14
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jhat is the pH, pOH and concentration of all species present in a solution
0.25ï HCN?
HCN is a weak acid and therefore we need to use the weak acid box:
HCN ļ H+ + CNí
Init 0.25 0 0 `
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change -x x x Ú î `
Eq 0.25-x x x ` îÚ
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3olyprotic cids contain more than one
acidic proton.
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Consider 0.10M H2SO4:
Is the approximation valid?
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No!
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jhat about a polyprotic acid with two weak acid
protons, like H2CO3?
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jhat is the pH of 0.20M H2CO3? Look at 1st step 1st
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Try a problem: jhat is the pH of a 0.15 M
solution of ascorbic acid (vitamin C, H2C6H6O6)?
Ka1 = 7.9x10-5
Ka2 = 1.6x10-12
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jater can be both a base or an acid ± it is an
amphoteric substance.
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Salts of polyprotic acids can also be amphoteric:
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H2CO3 HCO3g CO3-2 Ka1 = 4.3x10-7, Ka2 = 5.6x10-11
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jhy is ethanol, CH3CH2OH (pKa 17) so much weaker
an acid than acetic acid, CH3COOH (pKa 4.72)?
The answer lies in the stability of the product of the
Ka reaction:
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Electron withdrawing effects through sigma bonds
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Similarly,
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H+ + OHg H2O
eg eg
acceptor donor
H+ + NH3 NH4+
eg acceptor eg donor
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The Ka for NaH23O4 is
1. 7.5x10-3
2. 6.2 x10-8
3. 4.8 x10-13
The Kb for NaH23O4 is
1. 1.3x10-12
2. 1.6x10-7
3. 0.021
CH3CH2CO2Na is
1.n acid
2. base
3.Neither
4.I¶m lost
(CH3)2NH is
1.n acid
2. base
3.Neither
4.I¶m lost
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CH3NH3Cl is
1.n acid
2. base
3.Neither
4.I¶m lost
jhich of the following could act
as a Lewis cid?
1.NH3
2.H2O
3.NH4+
4.l3+
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jhich of the following could act
as a Lewis Base?
1.NH3
2.BF3
3.NH4+
4.l3+
Gou mix a solution of a strong acid with a
pH of 4 and an equal volume of a strong
acid solution with a pH of 6. Is the final pH
1.less than 4
2.between 4 and 5
3.5
4.between 5 and 6
5.greater than 6
6.I am lost
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Hc + H2O cg + H3O+
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jhich of the following could be used to make a buffer?
1.HF and KF
2.CH3NH2 and CH3NH3Cl
3.NaOH and HCl
4.NaOH and HNO2
5.HCl and NH3
6.K2H3O4 and NaOH
7.K2H3O4 and HNO3
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jhat is the pH of a buffer made by mixing 0.10mol HF and
0.2mol NaF to 1000ml of water?
HF + H2O Fg + H3O+
I 0.1 0.2 0 (ignoring auto-ionization of water)
C -x +x +x
E 0.1-x 0.2-x x
Ka = 7.2x10-4
Make the usual approximations to get:
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° î Solving, x = [H3O+ = 3.6x10-4
pH = -log(3.6x10-4) = 3.4
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Consider a hypochlorous buffer made by adding HOCl and
NaOCl to the same solution.
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s before, the hydrogen ion concentration depends on the
ratio of base and acid:
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This can be rearranged by taking the negative log of both
sides:
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ºeneralizing,
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aka the Henderson-Hasselbalch equation
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jhat acid/base pair would you choose to buffer at pH 6.5?
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jhat acid/base pair would you choose to buffer at pH 5.0?
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jhat is the pH of a buffer containing 0.15M NH3 and 0.40M
NH4ClO3? Ka (NH4+) = 5.55x10-10
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jhat is the approximate pH of a buffer that contains
0.1M KH23O4 and 0.3M KH3O4?
1. 2.6
2. 7.7
3. 12.8
4. 1.7
5. 6.7
6. 11.8 r
small note about nomenclature.
ust to review where we are: