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Stainless steel
In 1913, English metallurgist Harry Brearly,
accidentally discovered that adding chromium to
low carbon steel gives it stain resistance.
In addition to iron, carbon, and chromium, modern
stainless steel may also contain other elements,
such as nickel, niobium, molybdenum, and titanium.
Nickel, molybdenum, niobium, and chromium
enhance the corrosion resistance of stainless steel.
It is the addition of a minimum of 12% chromium to
the steel that makes it resist rust, or stain 'less' than
other types of steel
Stainless steel
The chromium in the steel combines with oxygen
in the atmosphere to form a thin, invisible layer of
chrome-containing oxide, called the passive film.
The sizes of chromium atoms and their oxides are
similar, so they pack together on the surface of
the metal, forming a stable layer only a few atoms
thick.
If the metal is cut or scratched and the passive
film is disrupted, more oxide will quickly form and
recover the exposed surface, protecting it from
oxidative corrosion.
Stainless steel
(Iron, on the other hand, rusts quickly because
atomic iron is much smaller than its oxide, so
the oxide forms a loose rather than tightlypacked layer and flakes away.)
The passive film requires oxygen to self-repair,
so stainless steels have poor corrosion
resistance in low-oxygen and poor circulation
environments.
In seawater, chlorides from the salt will attack
and destroy the passive film more quickly than
it can be repaired in a low oxygen environment.
Stainless steel
Types of Stainless Steel
The three main types of stainless
steels are:
austenitic,
ferritic, and
martensitic.
These three types of steels are
identified by their microstructure or
predominant crystal phase.
Ferritic
Above 13%Cr in Iron, this binary
alloys are ferritic over the whole
temperature range.
This ferrite is called delta ferrite ,
because it exist from the melting
point to room T.
0.04%C 18% Cr is fully ferritic.
This steel can not be transformed.
Ferritic
Ferritic steels have ferrite (body
centered cubic crystal) as their main
phase.
These steels contain iron and
chromium, based on the Type 430
composition of 17% chromium.
Ferritic steel is less ductile than
austenitic steel and is not hardenable
by heat treatment.
Austenitic
If a Ni is added to low carbon 18%Cr
steel Gama phase field expanded.
At about 8% Ni Gama phase field
exist at room temperature.
8% Ni is the minimum amount which
makes Gama stable at room
temperature.
Austenitic
Austenitic steels have austenite as their primary phase
(face centered cubic crystal).
These are alloys containing chromium and nickel
(sometimes manganese and nitrogen), structured around
the
composition of iron, 18% chromium, and 8% nickel in
low carbon . Type 302
Austenitic steels are not hardenable by heat treatment.
The most familiar stainless steel is probably Type 304,
sometimes called T304 or simply 304. Type 304 surgical
stainless steel is an austenitic steel containing 18-20%
chromium and 8-10% nickel. l
Martensitic
The characteristic orthorhombic martensite
microstructure was first observed by German
microscopist Adolf Martens around 1890.
Martensitic steels are low carbon steels built
around the Type 410 composition of iron,
12% chromium, and 0.12% carbon
They may be tempered and hardened.
Martensite gives steel great hardness, but it
also reduces its toughness and makes it
brittle, so few steels are fully hardened.
Martensite
Austenite - FCC
Ferrite - BCC
Martensite - BCT
Maraging Steels
Applications
Maraging steel's strength and malleability in
the pre-aged stage allows it to be formed
into thinner rocket and missile skins than
other steels, reducing weight for a given
strength
Aerospace, e.g. undercarriage parts and
wing fittings,
Tooling & machinery , e.g. extrusion press
rams and mandrels in tube production, gears
Ordnance components and fasteners